BR112016014267A2 - METHOD OF PREPARATION OF A MONO-ETHER FROM A DIOL COMPOUND; AND MANUFACTURING METHOD OF AN ALKYL CARBONATE OF A DIOL COMPOUND - Google Patents

METHOD OF PREPARATION OF A MONO-ETHER FROM A DIOL COMPOUND; AND MANUFACTURING METHOD OF AN ALKYL CARBONATE OF A DIOL COMPOUND

Info

Publication number
BR112016014267A2
BR112016014267A2 BR112016014267A BR112016014267A BR112016014267A2 BR 112016014267 A2 BR112016014267 A2 BR 112016014267A2 BR 112016014267 A BR112016014267 A BR 112016014267A BR 112016014267 A BR112016014267 A BR 112016014267A BR 112016014267 A2 BR112016014267 A2 BR 112016014267A2
Authority
BR
Brazil
Prior art keywords
ether
diol compound
mono
carbonate
preparation
Prior art date
Application number
BR112016014267A
Other languages
Portuguese (pt)
Inventor
Stensrud Kenneth
Venkitasubramaniam Padmesh
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2014/068809 external-priority patent/WO2015094716A1/en
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of BR112016014267A2 publication Critical patent/BR112016014267A2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/15—Unsaturated ethers containing only non-aromatic carbon-to-carbon double bonds
    • C07C43/16—Vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C68/00—Preparation of esters of carbonic or haloformic acids
    • C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/16—Acetic acid esters of dihydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/96—Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/10—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/12—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Furan Compounds (AREA)

Abstract

MÉTODO DE PREPARAÇÃO DE UM MONO-ÉTER A PARTIR DE UM COMPOSTO DIOL; E MÉTODO DE FABRICO DE UM ALQUIL-CARBONATO DE UM COMPOSTO DIOL. É conferido um método de preparação de um mono-éter ou mono-acetato glicólico, ou carbonato envolvendo qualquer uma das duas vias de alquilenoglicóis, HMF ou os seus produtos derivados de redução (isto é, FDM, bHMTHFs ). Em particular, de acordo com uma via, o alquilenoglicol, HMF ou FDM, bHMTHFs são feitos reagir com um carbonato de dialquila na presença de um agente de desprotonação, na ausência substancial de um catalisador extrínseco, de modo a produzir um éter, e subsequentemente fazendo reagir o éter com um ácido base. De acordo com a outra via, são feitos reagir alquilenoglicóis com um doador de acetato na presença de um ácido, base, de modo a gerar um mono-acetato de alquileno, e eterificado com um carbonato, na presença de um agente de desprotonação.METHOD OF PREPARATION OF A MONO-ETHER FROM A DIOL COMPOUND; AND METHOD OF MANUFACTURING AN ALKYL CARBONATE FROM A DIOL COMPOUND. A method of preparing a glycol mono-ether or mono-acetate, or carbonate involving either of the two pathways of alkylene glycols, HMF or their derivative reduction products (i.e., FDM, bHMTHFs) is provided. In particular, according to one route, alkylene glycol, HMF or FDM, bHMTHFs are reacted with a dialkyl carbonate in the presence of a deprotonating agent, in the substantial absence of an extrinsic catalyst, so as to produce an ether, and subsequently reacting the ether with an acid base. According to the other route, alkylene glycols are reacted with an acetate donor in the presence of an acid, base, to generate an alkylene monoacetate, and etherified with a carbonate, in the presence of a deprotonating agent.

BR112016014267A 2013-12-20 2014-12-19 METHOD OF PREPARATION OF A MONO-ETHER FROM A DIOL COMPOUND; AND MANUFACTURING METHOD OF AN ALKYL CARBONATE OF A DIOL COMPOUND BR112016014267A2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201361918795P 2013-12-20 2013-12-20
PCT/US2014/068809 WO2015094716A1 (en) 2013-12-20 2014-12-05 Synthesis of isohexide ethers and carbonates
US201462093683P 2014-12-18 2014-12-18
PCT/US2014/071512 WO2015095710A1 (en) 2013-12-20 2014-12-19 Direct synthesis of bio-based alkyl & furanic diol ethers, acetates, ether-acetates, and carbonates

Publications (1)

Publication Number Publication Date
BR112016014267A2 true BR112016014267A2 (en) 2017-08-08

Family

ID=53403742

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112016014267A BR112016014267A2 (en) 2013-12-20 2014-12-19 METHOD OF PREPARATION OF A MONO-ETHER FROM A DIOL COMPOUND; AND MANUFACTURING METHOD OF AN ALKYL CARBONATE OF A DIOL COMPOUND

Country Status (9)

Country Link
EP (1) EP3083548A4 (en)
JP (1) JP2017507899A (en)
KR (1) KR20160099646A (en)
CN (1) CN105849080A (en)
AU (1) AU2014369062A1 (en)
BR (1) BR112016014267A2 (en)
CA (1) CA2934512A1 (en)
MX (1) MX2016008061A (en)
WO (1) WO2015095710A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6793814B2 (en) 2016-08-16 2020-12-02 ピーピージー・インダストリーズ・オハイオ・インコーポレイテッドＰＰＧ Ｉｎｄｕｓｔｒｉｅｓ Ｏｈｉｏ，Ｉｎｃ． Polymerizable composition for optical articles
US10865172B1 (en) * 2019-09-04 2020-12-15 Eastman Chemical Company Aromatic enol ethers
US10858304B1 (en) * 2019-09-04 2020-12-08 Eastman Chemical Company Aromatic enol ethers
CN111349492B (en) * 2020-02-28 2021-05-25 浙江糖能科技有限公司 Application of 2, 5-tetrahydrofuran dimethyl alcohol fatty acid diester in diesel additive

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2963489A (en) * 1953-07-30 1960-12-06 American Cyanamid Co 3, 4-furandimethanol and derivatives
US4012424A (en) * 1975-08-07 1977-03-15 Chem Systems Inc. Cracking of mixtures containing hydroxyesters
US4170596A (en) * 1976-10-05 1979-10-09 Kowa Company, Ltd. Novel monoesters of cis-cyclopentenediol, process for preparation thereof, and process for preparation of lactones from the monoesters
US4192949A (en) * 1977-06-28 1980-03-11 Basf Aktiengesellschaft Preparation of aralkyl phenyl ethers and alkyl phenyl ethers
JPH07100702B2 (en) * 1987-07-22 1995-11-01 三井石油化学工業株式会社 Method for producing annular carbonate
JPH09227435A (en) * 1996-02-26 1997-09-02 Mitsui Toatsu Chem Inc Production of (poly)ethylene glycol diether
KR100593529B1 (en) * 2004-03-31 2006-06-28 주식회사 엘지생활건강 Process for preparing ester type bleach activator compound
US8604244B2 (en) * 2010-07-02 2013-12-10 Reviva Pharmaceuticals, Inc. Compositions, synthesis, and methods of using cycloalkylmethylamine derivatives
FR2950892B1 (en) * 2009-10-01 2011-11-18 Roquette Freres PROCESS FOR THE PREPARATION OF DIANHYDROHEXITOL DI (ALKYLCARBONATE)

Also Published As

Publication number Publication date
JP2017507899A (en) 2017-03-23
WO2015095710A1 (en) 2015-06-25
KR20160099646A (en) 2016-08-22
EP3083548A1 (en) 2016-10-26
AU2014369062A1 (en) 2016-06-30
CN105849080A (en) 2016-08-10
MX2016008061A (en) 2017-02-27
CA2934512A1 (en) 2015-06-25
EP3083548A4 (en) 2017-08-30

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2545 DE 15-10-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.