BR112015022007A2 - crivos moleculares de boroaluminosilicato e métodos para a utilização do mesmo para isomerização de xileno - Google Patents

crivos moleculares de boroaluminosilicato e métodos para a utilização do mesmo para isomerização de xileno

Info

Publication number
BR112015022007A2
BR112015022007A2 BR112015022007A BR112015022007A BR112015022007A2 BR 112015022007 A2 BR112015022007 A2 BR 112015022007A2 BR 112015022007 A BR112015022007 A BR 112015022007A BR 112015022007 A BR112015022007 A BR 112015022007A BR 112015022007 A2 BR112015022007 A2 BR 112015022007A2
Authority
BR
Brazil
Prior art keywords
xylene isomerization
methods
boroaluminosilicate molecular
molecular sieves
isomerization
Prior art date
Application number
BR112015022007A
Other languages
English (en)
Inventor
Allen Amelse Jeffrey
Original Assignee
Bp Corp North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Corp North America Inc filed Critical Bp Corp North America Inc
Publication of BR112015022007A2 publication Critical patent/BR112015022007A2/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/86—Borosilicates; Aluminoborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/13—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation with simultaneous isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/027—Beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/86—Borosilicates; Aluminoborosilicates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)

Abstract

resumo “crivos moleculares de boroaluminosilicato e métodos para a utilização do mesmo para isomerização de xileno” catalisadores de crivo molecular de boroaluminosilicato são fornecidos e são úteis para reações de conversão de hidrocarbonetos incluindo a isomerização de xilenos aromáticos c8 em matérias-primas para produzir p-xileno. de um modo vantajoso, verificou-se que os catalisadores de crivo molecular de boroaluminosilicato da invenção são mais seletivos do que os catalisadores convencionais de isomerização xileno comerciais, resultando em formação reduzida de subprodutos de transmetilação (c7 e c9 aromáticos), proporcionando simultaneamente um elevado grau de xileno isomerização.
BR112015022007A 2013-03-15 2014-03-12 crivos moleculares de boroaluminosilicato e métodos para a utilização do mesmo para isomerização de xileno BR112015022007A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361793180P 2013-03-15 2013-03-15
PCT/US2014/024421 WO2014150863A1 (en) 2013-03-15 2014-03-12 Boroaluminosilicate molecular sieves and methods for using same for xylene isomerization

Publications (1)

Publication Number Publication Date
BR112015022007A2 true BR112015022007A2 (pt) 2017-07-18

Family

ID=50588832

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112015022236A BR112015022236A2 (pt) 2013-03-15 2014-03-12 peneiras moleculares de aluminosilicate ifm e métodos para usar isomerização para o xileno da mesma
BR112015022007A BR112015022007A2 (pt) 2013-03-15 2014-03-12 crivos moleculares de boroaluminosilicato e métodos para a utilização do mesmo para isomerização de xileno

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BR112015022236A BR112015022236A2 (pt) 2013-03-15 2014-03-12 peneiras moleculares de aluminosilicate ifm e métodos para usar isomerização para o xileno da mesma

Country Status (11)

Country Link
US (2) US20160031771A1 (pt)
EP (2) EP2969194A1 (pt)
JP (2) JP2016512788A (pt)
KR (2) KR20150132458A (pt)
CN (2) CN105102122A (pt)
BR (2) BR112015022236A2 (pt)
CA (2) CA2906498A1 (pt)
MX (2) MX2015012209A (pt)
RU (2) RU2015142878A (pt)
SG (2) SG11201507342VA (pt)
WO (2) WO2014150875A1 (pt)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9643897B2 (en) 2015-03-03 2017-05-09 Uop Llc Enhanced propylene production in OTO process with modified zeolites
US10010878B2 (en) 2015-03-03 2018-07-03 Uop Llc High meso-surface area, low Si/Al ratio pentasil zeolite
PT3368501T (pt) 2015-10-28 2021-06-01 Ineos Us Chemicals Company Catalisador melhorado para conversão de etilbenzeno num processo de isomerização de xileno
US10173950B2 (en) * 2017-01-04 2019-01-08 Saudi Arabian Oil Company Integrated process for the production of benzene and xylenes from heavy aromatics
WO2021041021A1 (en) * 2019-08-23 2021-03-04 Exxonmobil Chemical Patents Inc. Processes for isomerizing c8 aromatic hydrocarbons

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4163028A (en) * 1977-07-22 1979-07-31 Mobil Oil Corporation Xylene isomerization
US4269813A (en) 1977-09-26 1981-05-26 Standard Oil Company (Indiana) Crystalline borosilicate and process of preparation
US4268420A (en) 1978-04-18 1981-05-19 Standard Oil Company (Indiana) Hydrocarbon-conversion catalyst and its method of preparation
US4285919A (en) 1978-12-26 1981-08-25 Standard Oil Company (Indiana) Method of preparing a metal-cation-deficient crystalline borosilicate
US4327236A (en) 1979-07-03 1982-04-27 Standard Oil Company (Indiana) Hydrocarbon-conversion catalyst and its method of preparation
CA1185953A (en) 1981-06-30 1985-04-23 Muin S. Haddad Method for manufacture of ams-1b crystalline borosilicate molecular sieve
US4962258A (en) 1988-12-15 1990-10-09 Amoco Corporation Liquid-phase xylene isomerization
US5030788A (en) 1989-09-21 1991-07-09 Amoco Corporation Catalyzed xylene isomerization under supercritical temperature and pressure conditions
US5877374A (en) * 1997-04-02 1999-03-02 Chevron Chemical Company Low pressure hydrodealkylation of ethylbenzene and xylene isomerization
US6573418B2 (en) 2000-07-10 2003-06-03 Bp Corporation North America Inc. Process for production of para-xylene incorporating pressure swing adsorption and simulated moving bed adsorption
US7081556B2 (en) * 2002-11-01 2006-07-25 Exxonmobil Chemical Patents Inc. Aromatics conversion with ITQ-13
US7247762B2 (en) * 2003-09-12 2007-07-24 Exxonmobil Chemical Patents Inc. Process for xylene isomerization and ethylbenzene conversion
US7411103B2 (en) * 2003-11-06 2008-08-12 Haldor Topsoe A/S Process for the catalytic isomerisation of aromatic compounds
CA2823391A1 (en) * 2011-01-12 2012-07-19 Bp Corporation North America Inc. Method of making and using a hydrocarbon conversion catalyst
CN102897791B (zh) * 2011-07-29 2014-12-31 中国石油化工股份有限公司 Zsm-5分子筛的制备方法

Also Published As

Publication number Publication date
EP2969200A1 (en) 2016-01-20
US20160039726A1 (en) 2016-02-11
JP2016512788A (ja) 2016-05-09
KR20150132513A (ko) 2015-11-25
SG11201507342VA (en) 2015-10-29
US20160031771A1 (en) 2016-02-04
WO2014150875A1 (en) 2014-09-25
MX2015012209A (es) 2015-12-01
KR20150132458A (ko) 2015-11-25
BR112015022236A2 (pt) 2017-07-18
CN105102121A (zh) 2015-11-25
EP2969194A1 (en) 2016-01-20
SG11201507220SA (en) 2015-10-29
RU2015142878A (ru) 2017-04-19
RU2015142880A (ru) 2017-04-21
CA2906498A1 (en) 2014-09-25
CN105102122A (zh) 2015-11-25
JP2016517415A (ja) 2016-06-16
MX2015012212A (es) 2015-12-01
WO2014150863A1 (en) 2014-09-25
CA2905937A1 (en) 2014-09-25

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2505 DE 08-01-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.