BR112015012823A2 - process for isolating levulinic acid and formic acid - Google Patents
process for isolating levulinic acid and formic acidInfo
- Publication number
- BR112015012823A2 BR112015012823A2 BR112015012823A BR112015012823A BR112015012823A2 BR 112015012823 A2 BR112015012823 A2 BR 112015012823A2 BR 112015012823 A BR112015012823 A BR 112015012823A BR 112015012823 A BR112015012823 A BR 112015012823A BR 112015012823 A2 BR112015012823 A2 BR 112015012823A2
- Authority
- BR
- Brazil
- Prior art keywords
- acid
- levulinic acid
- washing
- isolating
- formic acid
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
- B01D3/40—Extractive distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/185—Saturated compounds having only one carboxyl group and containing keto groups
Abstract
resumo processo para isolar o ácido levulínico e ácido fórmico a invenção proporciona um processo para isolar ácido levulínico e ácido fórmico a partir de uma composição que compreende ácido fórmico e ácido levulínico, o referido processo compreendendo uma etapa de separação sólido-líquido, uma etapa de remoção de vapor, e uma etapa de extração solvente-solvente, em que um condensado de vapor vapor e/ou uma fase aquosa a partir da extração com solvente é utilizada para lavar a fração sólida. lavar com condensado de vapor resulta em maiores rendimentos de ácido levulínico (maior recuperação de ácido levulínico), quando comparado à lavagem com água normal. lavar com fase aquosa resulta em um bolo de filtro menos compressível. lavar primeiro com fase aquosa e subsequentemente com condensado resulta em ainda mais elevados rendimentos de ácido levulínico. o processo é adequado para isolar ácido levulínico e ácido fórmico a partir de composições produzidas por hidrólise ácida de biomassa lignocelulósica, e também a partir de composições produzidas por hidrólise ácida de açúcares tais como glicose e frutose.abstract "process for isolating levulinic acid and formic acid" The invention provides a process for isolating levulinic acid and formic acid from a composition comprising formic acid and levulinic acid, said process comprising a solid-liquid separation step, a steam removal step, and a solvent-solvent extraction step, in which a steam condensate and/or an aqueous phase from the solvent extraction is used to wash the solid fraction. washing with steam condensate results in higher levulinic acid yields (increased recovery of levulinic acid) when compared to washing with normal water. washing with aqueous phase results in a less compressible filter cake. washing first with aqueous phase and subsequently with condensate results in even higher yields of levulinic acid. the process is suitable for isolating levulinic acid and formic acid from compositions produced by acid hydrolysis of lignocellulosic biomass, and also from compositions produced by acid hydrolysis of sugars such as glucose and fructose.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261734523P | 2012-12-07 | 2012-12-07 | |
EP12196080 | 2012-12-07 | ||
EP13168025 | 2013-05-16 | ||
PCT/EP2013/075961 WO2014087015A1 (en) | 2012-12-07 | 2013-12-09 | Process for the isolation of levulinic acid and formic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112015012823A2 true BR112015012823A2 (en) | 2017-07-11 |
Family
ID=50882831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015012823A BR112015012823A2 (en) | 2012-12-07 | 2013-12-09 | process for isolating levulinic acid and formic acid |
Country Status (8)
Country | Link |
---|---|
US (1) | US9908836B2 (en) |
EP (1) | EP2928857B1 (en) |
KR (1) | KR20150091155A (en) |
CN (1) | CN104854075A (en) |
BR (1) | BR112015012823A2 (en) |
CA (1) | CA2891402A1 (en) |
EA (1) | EA201500606A1 (en) |
WO (1) | WO2014087015A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK3022170T3 (en) * | 2013-07-17 | 2018-02-26 | Dsm Ip Assets Bv | Process for isolating levulinic acid |
EP3115351A1 (en) | 2015-07-10 | 2017-01-11 | GFBiochemicals Ltd. | Levulinic acid compositions |
EP3689847A1 (en) | 2018-11-15 | 2020-08-05 | CMP-Cimentos Maceira e Pataias S.A. | Catalytic and continuous thermochemical process of production of valuable derivatives from organic materials and waste |
BR112022024686A2 (en) | 2020-06-02 | 2023-03-07 | Secil Companhia Geral De Cal E Cimento S A | CATALYTIC AND CONTINUOUS THERMOCHEMICAL PROCESS FOR THE PRODUCTION OF VALUABLE DERIVATIVES FROM ORGANIC MATERIALS AND WASTE |
EP4265592A1 (en) | 2022-04-22 | 2023-10-25 | Indian Oil Corporation Limited | Method for producing levulinic acid |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2305738A (en) * | 1939-04-29 | 1942-12-22 | Scheuing Georg | Process for the production of levulinic acid |
US2257389A (en) * | 1939-10-02 | 1941-09-30 | Du Pont | Recovery of levulinic acid |
GB583533A (en) | 1944-05-30 | 1946-12-20 | Walter Norman Haworth | Improvements relating to the manufacture of levulinic acid |
US2648704A (en) | 1949-08-22 | 1953-08-11 | Ogawa Tetsuwo | Process of treating protein hydrolysis liquor |
FR1105538A (en) | 1953-08-05 | 1955-12-05 | Quaker Oats Co | Improved process for the continuous preparation of levulinic acid |
US2840605A (en) * | 1957-04-26 | 1958-06-24 | Heyden Newport Chemical Corp | Method of making levulinic acid |
US5892107A (en) | 1996-11-08 | 1999-04-06 | Arkenol, Inc. | Method for the production of levulinic acid |
DE602004029827D1 (en) | 2004-06-23 | 2010-12-09 | Lone Knight Ltd | PROCESS FOR EXTRACTION OF FULVIC ACID MOLECULES |
US7520905B1 (en) | 2006-02-06 | 2009-04-21 | Gene E Lightner | Additives derived from biomass extracted by biodiesel fuel oil |
WO2010030617A1 (en) | 2008-09-09 | 2010-03-18 | Meadwestvaco Corporation | A method of recovering levulinic acid |
US8138371B2 (en) | 2009-03-11 | 2012-03-20 | Biofine Technologies Llc | Production of formic acid |
US20100312006A1 (en) | 2009-06-09 | 2010-12-09 | Meadwestvaco Corporation | Production of levulinic acid and levulinate esters from biomass |
US8148553B2 (en) | 2009-06-23 | 2012-04-03 | Wisconsin Alumni Research Foundation | Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities |
US8962867B2 (en) * | 2011-05-25 | 2015-02-24 | Wisconsin Alumni Research Foundation | Solute-enhanced production of gamma-valerolactone (GVL) from aqueous solutions of levulinic acid |
US9073841B2 (en) * | 2012-11-05 | 2015-07-07 | Segetis, Inc. | Process to prepare levulinic acid |
-
2013
- 2013-12-09 US US14/648,437 patent/US9908836B2/en active Active
- 2013-12-09 BR BR112015012823A patent/BR112015012823A2/en not_active IP Right Cessation
- 2013-12-09 EP EP13802369.2A patent/EP2928857B1/en active Active
- 2013-12-09 CN CN201380063521.5A patent/CN104854075A/en active Pending
- 2013-12-09 EA EA201500606A patent/EA201500606A1/en unknown
- 2013-12-09 WO PCT/EP2013/075961 patent/WO2014087015A1/en active Application Filing
- 2013-12-09 CA CA2891402A patent/CA2891402A1/en not_active Abandoned
- 2013-12-09 KR KR1020157017593A patent/KR20150091155A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP2928857B1 (en) | 2019-01-23 |
CN104854075A (en) | 2015-08-19 |
CA2891402A1 (en) | 2014-06-12 |
US9908836B2 (en) | 2018-03-06 |
US20150299087A1 (en) | 2015-10-22 |
EP2928857A1 (en) | 2015-10-14 |
WO2014087015A1 (en) | 2014-06-12 |
EA201500606A1 (en) | 2015-09-30 |
KR20150091155A (en) | 2015-08-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
B04C | Request for examination: application reinstated [chapter 4.3 patent gazette] | ||
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 6A ANUIDADE. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2544 DE 08-10-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |