BR112014020344B1 - Fio de multifilamentos de polietileno de ultra-alto peso molecular (uhmw pe), compósito, e processo para produzir um fio de multifilamentos de polietileno de ultra-alto peso molecular (uhmw pe) - Google Patents
Fio de multifilamentos de polietileno de ultra-alto peso molecular (uhmw pe), compósito, e processo para produzir um fio de multifilamentos de polietileno de ultra-alto peso molecular (uhmw pe) Download PDFInfo
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- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920003192 poly(bis maleimide) Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000013047 polymeric layer Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 229920006216 polyvinyl aromatic Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012956 testing procedure Methods 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 230000001131 transforming effect Effects 0.000 description 1
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- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
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- 239000011709 vitamin E Substances 0.000 description 1
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- 238000005303 weighing Methods 0.000 description 1
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/593—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives to layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H13/00—Other non-woven fabrics
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
- D10B2321/0211—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene high-strength or high-molecular-weight polyethylene, e.g. ultra-high molecular weight polyethylene [UHMWPE]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2008—Fabric composed of a fiber or strand which is of specific structural definition
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261602963P | 2012-02-24 | 2012-02-24 | |
| US61/602,963 | 2012-02-24 | ||
| US13/766,112 US9169581B2 (en) | 2012-02-24 | 2013-02-13 | High tenacity high modulus UHMW PE fiber and the process of making |
| US13/766,112 | 2013-02-13 | ||
| PCT/US2013/026124 WO2013126268A1 (en) | 2012-02-24 | 2013-02-14 | High tenacity high modulus uhmwpe fiber and the process of making |
Publications (2)
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| BR112014020344A2 BR112014020344A2 (pt) | 2017-06-20 |
| BR112014020344B1 true BR112014020344B1 (pt) | 2021-09-21 |
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| BR112014020344-0A BR112014020344B1 (pt) | 2012-02-24 | 2013-02-14 | Fio de multifilamentos de polietileno de ultra-alto peso molecular (uhmw pe), compósito, e processo para produzir um fio de multifilamentos de polietileno de ultra-alto peso molecular (uhmw pe) |
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| EP (1) | EP2817440B1 (enExample) |
| JP (1) | JP6392124B2 (enExample) |
| KR (1) | KR101980243B1 (enExample) |
| CN (1) | CN104246036B (enExample) |
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| CA (1) | CA2864551C (enExample) |
| ES (1) | ES2780364T3 (enExample) |
| IL (1) | IL234117B (enExample) |
| IN (1) | IN2014DN06759A (enExample) |
| MX (1) | MX347676B (enExample) |
| RU (1) | RU2612714C2 (enExample) |
| WO (1) | WO2013126268A1 (enExample) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP3460110B1 (en) * | 2011-12-14 | 2021-01-20 | DSM IP Assets B.V. | Process for manufacturing an ultra-high molecular weight polyethylene multifilament yarn |
| US9169581B2 (en) * | 2012-02-24 | 2015-10-27 | Honeywell International Inc. | High tenacity high modulus UHMW PE fiber and the process of making |
| JP6436091B2 (ja) * | 2012-12-20 | 2018-12-12 | 東洋紡株式会社 | ポリオレフィン糸条及び製造方法 |
| BR122020002319B1 (pt) * | 2013-10-29 | 2021-06-15 | Braskem S.A. | Método e sistema contínuo para a produção de pelo menos um fio polimérico |
| US20150164158A1 (en) * | 2013-12-13 | 2015-06-18 | Honeywell International Inc. | Protective overglove for glove-box gloves |
| KR20160135211A (ko) * | 2014-02-20 | 2016-11-25 | 릴라이언스 인더스트리즈 리미티드 | 고강도 고모듈러스 초고 분자량 폴리에틸렌섬유 |
| US10364512B2 (en) * | 2014-03-28 | 2019-07-30 | Toyobo Co., Ltd. | Multifilament and braid |
| CN106133215B (zh) * | 2014-03-28 | 2020-10-23 | 东洋纺株式会社 | 复丝及编带 |
| US9834872B2 (en) | 2014-10-29 | 2017-12-05 | Honeywell International Inc. | High strength small diameter fishing line |
| US9816211B2 (en) * | 2014-10-29 | 2017-11-14 | Honeywell International Inc. | Optimized braid construction |
| BR112017011660B1 (pt) * | 2014-12-02 | 2021-10-19 | Braskem S.A. | Método e sistema contínuo para a produção de pelo menos um fio polimérico, fio polimérico, e, uso de um fio polimérico |
| US20160174616A1 (en) * | 2014-12-18 | 2016-06-23 | Adidas Ag | Athletic jersey with cut-resistant portion |
| WO2016133102A1 (ja) | 2015-02-20 | 2016-08-25 | 東洋紡株式会社 | マルチフィラメント及びそれを用いた組紐 |
| US20170145596A1 (en) * | 2015-10-27 | 2017-05-25 | Tosha Hays | Systems and articles of manufacture employing long-term cooling material in woven and non-woven fabrics and processes to generate the long-term cooling material and articles of manufacture |
| US10857436B2 (en) | 2016-03-04 | 2020-12-08 | Bauer Hockey, Inc. | 3D weaving material and method of 3D weaving for sporting implements |
| US11471736B2 (en) | 2016-03-04 | 2022-10-18 | Bauer Hockey, Llc | 3D braiding materials and 3D braiding methods for sporting implements |
| US10704866B2 (en) | 2016-09-15 | 2020-07-07 | Honeywell International Inc. | High kinetic energy absorption with low back face deformation ballistic composites |
| CN107988632B (zh) * | 2017-11-24 | 2020-04-24 | 龙游龙纤新材料有限公司 | 一种实现连续均匀喂料的uhmwpe纤维生产配料方法 |
| US11306432B2 (en) * | 2018-11-05 | 2022-04-19 | Honeywell International Inc. | HMPE fiber with improved bending fatigue performance |
| CZ2018647A3 (cs) * | 2018-11-23 | 2020-06-03 | Reifenhäuser GmbH & Co. KG Maschinenfabrik | Objemná netkaná textilie se zvýšenou stlačitelností a zlepšenou schopností regenerace |
| MY206320A (en) * | 2019-12-27 | 2024-12-09 | Kolon Inc | Polyethylene yarn, method for manufacturing the same, and skin cooling fabric comprising the same |
| US20210321700A1 (en) * | 2020-04-15 | 2021-10-21 | Chris TREVINO | Protective Glove |
| RU2734546C1 (ru) * | 2020-04-16 | 2020-10-20 | Роман Валерьевич Платонов | Ткань трикотажная для использования при самообороне в боевых контактах и искусствах |
| CN114481343A (zh) * | 2020-10-23 | 2022-05-13 | 中国石油化工股份有限公司 | 一种纤维纺丝方法和聚乙烯纺丝纤维 |
| US20230193518A1 (en) * | 2021-12-17 | 2023-06-22 | Honeywell International Inc. | Ultra-fine denier uhmw pe fiber |
| KR102506254B1 (ko) | 2022-10-28 | 2023-03-07 | (주)유원기술 | 공기청정기능 및 환기기능을 구현하는 냉방제습기 |
Family Cites Families (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4413110A (en) | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
| US4457985A (en) | 1982-03-19 | 1984-07-03 | Allied Corporation | Ballistic-resistant article |
| US4403012A (en) | 1982-03-19 | 1983-09-06 | Allied Corporation | Ballistic-resistant article |
| US4551296A (en) | 1982-03-19 | 1985-11-05 | Allied Corporation | Producing high tenacity, high modulus crystalline article such as fiber or film |
| US4536536A (en) | 1982-03-19 | 1985-08-20 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
| US4440711A (en) * | 1982-09-30 | 1984-04-03 | Allied Corporation | Method of preparing high strength and modulus polyvinyl alcohol fibers |
| JPS59216912A (ja) | 1983-05-20 | 1984-12-07 | Toyobo Co Ltd | 高強度・高弾性率ポリエチレン繊維の製造方法 |
| US4663101A (en) | 1985-01-11 | 1987-05-05 | Allied Corporation | Shaped polyethylene articles of intermediate molecular weight and high modulus |
| US4623574A (en) | 1985-01-14 | 1986-11-18 | Allied Corporation | Ballistic-resistant composite article |
| US4748064A (en) | 1985-01-14 | 1988-05-31 | Allied Corporation | Ballistic-resistant composite article |
| JPH06102847B2 (ja) * | 1985-05-31 | 1994-12-14 | 三井石油化学工業株式会社 | プラスチツクワイヤ−及びその製造方法 |
| US4650710A (en) | 1985-02-25 | 1987-03-17 | Allied Corporation | Ballistic-resistant fabric article |
| US4737402A (en) | 1985-02-28 | 1988-04-12 | Allied Corporation | Complex composite article having improved impact resistance |
| JPS61282417A (ja) * | 1985-06-05 | 1986-12-12 | Toray Ind Inc | ポリエチレンマルチフイラメントヤ−ン |
| DE3675079D1 (de) | 1985-06-17 | 1990-11-29 | Allied Signal Inc | Polyolefinfaser mit hoher festigkeit, niedrigem schrumpfen, ultrahohem modul, sehr niedrigem kriechen und mit guter festigkeitserhaltung bei hoher temperatur sowie verfahren zu deren herstellung. |
| US5032338A (en) | 1985-08-19 | 1991-07-16 | Allied-Signal Inc. | Method to prepare high strength ultrahigh molecular weight polyolefin articles by dissolving particles and shaping the solution |
| US4916000A (en) | 1987-07-13 | 1990-04-10 | Allied-Signal Inc. | Ballistic-resistant composite article |
| US5552208A (en) | 1993-10-29 | 1996-09-03 | Alliedsignal Inc. | High strength composite |
| JP2699319B2 (ja) | 1993-12-16 | 1998-01-19 | 東洋紡績株式会社 | 高強度ポリエチレン繊維 |
| US6448359B1 (en) | 2000-03-27 | 2002-09-10 | Honeywell International Inc. | High tenacity, high modulus filament |
| US6642159B1 (en) | 2000-08-16 | 2003-11-04 | Honeywell International Inc. | Impact resistant rigid composite and method for manufacture |
| US6846758B2 (en) | 2002-04-19 | 2005-01-25 | Honeywell International Inc. | Ballistic fabric laminates |
| US6841492B2 (en) | 2002-06-07 | 2005-01-11 | Honeywell International Inc. | Bi-directional and multi-axial fabrics and fabric composites |
| US7344668B2 (en) | 2003-10-31 | 2008-03-18 | Honeywell International Inc. | Process for drawing gel-spun polyethylene yarns |
| JP4524644B2 (ja) * | 2004-07-08 | 2010-08-18 | 東洋紡績株式会社 | 高強度ポリエチレン繊維の製造方法 |
| US6969553B1 (en) | 2004-09-03 | 2005-11-29 | Honeywell International Inc. | Drawn gel-spun polyethylene yarns and process for drawing |
| DE602005015741D1 (de) * | 2004-09-03 | 2009-09-10 | Honeywell Int Inc | Gezogene gelfaserpolyethylengarne und ziehverfahren |
| US7147807B2 (en) | 2005-01-03 | 2006-12-12 | Honeywell International Inc. | Solution spinning of UHMW poly (alpha-olefin) with recovery and recycling of volatile spinning solvent |
| EP1746187A1 (en) * | 2005-07-18 | 2007-01-24 | DSM IP Assets B.V. | Polyethylene multi-filament yarn |
| US7370395B2 (en) | 2005-12-20 | 2008-05-13 | Honeywell International Inc. | Heating apparatus and process for drawing polyolefin fibers |
| US8444898B2 (en) | 2006-03-30 | 2013-05-21 | Honeywell International Inc | High molecular weight poly(alpha-olefin) solutions and articles made therefrom |
| US7674409B1 (en) * | 2006-09-25 | 2010-03-09 | Honeywell International Inc. | Process for making uniform high strength yarns and fibrous sheets |
| US20100122517A1 (en) * | 2007-05-01 | 2010-05-20 | Joseph Arnold Paul Maria Simmelink | Uhmwpe fiber and process for producing thereof |
| BRPI0702313A2 (pt) * | 2007-05-24 | 2009-01-13 | Profil Ltda Braskem S A | processo para a preparaÇço de fios polimÉricos a partir de homopolÍmeros ou copolimeros de ultra alto peso molecular, fios polimÉricos, artigos polimÉricos moldados, e, uso de fios polimÉricos |
| US8747715B2 (en) * | 2007-06-08 | 2014-06-10 | Honeywell International Inc | Ultra-high strength UHMW PE fibers and products |
| US8889049B2 (en) | 2010-04-30 | 2014-11-18 | Honeywell International Inc | Process and product of high strength UHMW PE fibers |
| US7638191B2 (en) | 2007-06-08 | 2009-12-29 | Honeywell International Inc. | High tenacity polyethylene yarn |
| US9365953B2 (en) | 2007-06-08 | 2016-06-14 | Honeywell International Inc. | Ultra-high strength UHMWPE fibers and products |
| KR101522051B1 (ko) | 2007-10-05 | 2015-05-20 | 디에스엠 아이피 어셋츠 비.브이. | Uhmwpe 섬유 및 이의 제조 방법 |
| JP5333952B2 (ja) | 2007-12-17 | 2013-11-06 | ディーエスエム アイピー アセッツ ビー.ブイ. | Uhmwpeの紡糸法 |
| CN101230501B (zh) * | 2008-02-26 | 2010-06-02 | 山东爱地高分子材料有限公司 | 一种采用超高分子量聚乙烯与低密度聚乙烯共混熔融制备高强聚乙烯纤维的方法 |
| CN101230499B (zh) * | 2008-02-26 | 2010-10-06 | 山东爱地高分子材料有限公司 | 一种有颜色的高强聚乙烯纤维及其制造方法 |
| HUE039515T2 (hu) * | 2009-02-09 | 2019-01-28 | Dsm Ip Assets Bv | Vágással szemben ellenálló szövet |
| SI2462275T1 (sl) * | 2009-08-04 | 2016-10-28 | Dsm Ip Assets B.V. | Oplaščena vlakna, prameni in vrvi z visoko trdnostjo in postopek njihove izdelave |
| US8236119B2 (en) * | 2009-08-11 | 2012-08-07 | Honeywell International Inc. | High strength ultra-high molecular weight polyethylene tape articles |
| US8993087B2 (en) * | 2009-12-23 | 2015-03-31 | Teijin Aramid B.V. | Ballistic-resistant articles |
| US9169581B2 (en) * | 2012-02-24 | 2015-10-27 | Honeywell International Inc. | High tenacity high modulus UHMW PE fiber and the process of making |
-
2013
- 2013-02-13 US US13/766,112 patent/US9169581B2/en active Active
- 2013-02-14 JP JP2014558768A patent/JP6392124B2/ja active Active
- 2013-02-14 RU RU2014137552A patent/RU2612714C2/ru active
- 2013-02-14 MX MX2014009998A patent/MX347676B/es active IP Right Grant
- 2013-02-14 IN IN6759DEN2014 patent/IN2014DN06759A/en unknown
- 2013-02-14 WO PCT/US2013/026124 patent/WO2013126268A1/en not_active Ceased
- 2013-02-14 EP EP13751802.3A patent/EP2817440B1/en active Active
- 2013-02-14 CA CA2864551A patent/CA2864551C/en active Active
- 2013-02-14 CN CN201380020047.8A patent/CN104246036B/zh active Active
- 2013-02-14 KR KR1020147023561A patent/KR101980243B1/ko active Active
- 2013-02-14 BR BR112014020344-0A patent/BR112014020344B1/pt active IP Right Grant
- 2013-02-14 ES ES13751802T patent/ES2780364T3/es active Active
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2014
- 2014-08-13 IL IL234117A patent/IL234117B/en active IP Right Grant
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2015
- 2015-10-26 US US14/922,339 patent/US9765447B2/en active Active
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2017
- 2017-09-14 US US15/704,105 patent/US10450676B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| IN2014DN06759A (enExample) | 2015-05-22 |
| US20130225022A1 (en) | 2013-08-29 |
| RU2612714C2 (ru) | 2017-03-13 |
| JP2015508849A (ja) | 2015-03-23 |
| US9765447B2 (en) | 2017-09-19 |
| US20160130730A1 (en) | 2016-05-12 |
| MX2014009998A (es) | 2014-09-12 |
| CA2864551C (en) | 2020-03-10 |
| WO2013126268A1 (en) | 2013-08-29 |
| EP2817440B1 (en) | 2020-01-01 |
| KR20140129050A (ko) | 2014-11-06 |
| RU2014137552A (ru) | 2016-04-10 |
| CA2864551A1 (en) | 2013-08-29 |
| US20180016710A1 (en) | 2018-01-18 |
| IL234117B (en) | 2018-12-31 |
| US10450676B2 (en) | 2019-10-22 |
| MX347676B (es) | 2017-05-09 |
| BR112014020344A2 (pt) | 2017-06-20 |
| CN104246036B (zh) | 2017-03-08 |
| EP2817440A1 (en) | 2014-12-31 |
| US9169581B2 (en) | 2015-10-27 |
| ES2780364T3 (es) | 2020-08-25 |
| JP6392124B2 (ja) | 2018-09-19 |
| EP2817440A4 (en) | 2016-01-06 |
| KR101980243B1 (ko) | 2019-05-21 |
| CN104246036A (zh) | 2014-12-24 |
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