BR112012007978A2 - nanocomposite compositions, expandable articles obtained from nanocomposite compositions, thermoplastic polymer expanded extruded sheets, and processes for preparing thermoplastic polymer compositions, for mass preparation of thermoplastic polymer compositions and for producing expanded thermoplastic polymer extruded sheets - Google Patents
nanocomposite compositions, expandable articles obtained from nanocomposite compositions, thermoplastic polymer expanded extruded sheets, and processes for preparing thermoplastic polymer compositions, for mass preparation of thermoplastic polymer compositions and for producing expanded thermoplastic polymer extruded sheetsInfo
- Publication number
- BR112012007978A2 BR112012007978A2 BR112012007978A BR112012007978A BR112012007978A2 BR 112012007978 A2 BR112012007978 A2 BR 112012007978A2 BR 112012007978 A BR112012007978 A BR 112012007978A BR 112012007978 A BR112012007978 A BR 112012007978A BR 112012007978 A2 BR112012007978 A2 BR 112012007978A2
- Authority
- BR
- Brazil
- Prior art keywords
- thermoplastic polymer
- compositions
- extruded sheets
- nanocomposite
- expanded
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
- C08J9/0071—Nanosized fillers, i.e. having at least one dimension below 100 nanometers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Carbon And Carbon Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
composições de nanocompósito , artigos expansíveis obtidos das composições de nanocompósitos, folhas extrudadas expandidas de poliméricos termoplásticos , e, processos para preparar composições de polímeros termoplásticos, para preparar em massa as composições de polímeros termoplásticos e para a produção das folhas extrudadas expandidas de polímeros termoplásticos são fornecidas composições de nanocompósito a base de polímero termoplásticos expansíveis que compreendem: a) uma matriz polimérica produzida pela polimerização de uma base que compreende um ou mais monômeros polimerizáveis; b) 1-10% em peso , calculado com relação ao polímero (a) , de um agente de expansão englobado na matriz polimérica; c) 0,004-15 % em peso , calculaldo com relação ao polímero (a), de uma carga atérmica compreendendo placas de grafeno em escala nanométrica com uma espessura (ortogonal para a folha de grafeno) de não mais que 150nm, uma dimensão média (comprimento, largura ou diâmetro) de não mais que 10 micrômetros e uma área de superfície > 50m2/g.nanocomposite compositions, expandable articles obtained from nanocomposite compositions, thermoplastic polymer expanded extruded sheets, and processes for preparing thermoplastic polymer compositions, for preparing bulk thermoplastic polymer compositions and for producing expanded thermoplastic polymer extruded sheets are expandable thermoplastic polymer-based nanocomposite compositions comprising: a) a polymeric matrix produced by polymerizing a base comprising one or more polymerizable monomers; b) 1-10% by weight, calculated with respect to polymer (a), of a blowing agent comprised in the polymeric matrix; (c) 0,004-15% by weight, calculated with respect to polymer (a), of an athermic charge comprising nanoscale graphene plates having a thickness (orthogonal to the graphene sheet) of not more than 150 nm, an average size ( length, width or diameter) of no more than 10 micrometres and a surface area> 50m2 / g.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI2009A001715A IT1396193B1 (en) | 2009-10-07 | 2009-10-07 | EXPANDABLE THERMOPLASTIC NANOCOMPOSITE POLYMER COMPOSITIONS WITH IMPROVED THERMAL INSULATION CAPACITY. |
ITMI2009A001715 | 2009-10-07 | ||
PCT/IB2010/002547 WO2011042800A1 (en) | 2009-10-07 | 2010-10-06 | Expandable thermoplastic nanocomposite polymeric compositions with an improved thermal insulation capacity |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112012007978A2 true BR112012007978A2 (en) | 2016-03-29 |
BR112012007978B1 BR112012007978B1 (en) | 2020-07-07 |
Family
ID=41809061
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012007978-6A BR112012007978B1 (en) | 2009-10-07 | 2010-10-06 | nanocomposite compositions, expandable articles obtained from nanocomposite compositions, expanded extruded sheets of thermoplastic polymers, and processes for preparing thermoplastic polymer compositions, for mass preparing thermoplastic polymer compositions and for the production of expanded extruded sheets of thermoplastic polymers |
Country Status (13)
Country | Link |
---|---|
US (1) | US8969466B2 (en) |
EP (1) | EP2486085B1 (en) |
JP (1) | JP5632003B2 (en) |
CN (1) | CN102666686B (en) |
BR (1) | BR112012007978B1 (en) |
ES (1) | ES2625888T3 (en) |
HU (1) | HUE034340T2 (en) |
IT (1) | IT1396193B1 (en) |
MX (1) | MX343957B (en) |
PL (1) | PL2486085T3 (en) |
PT (1) | PT2486085T (en) |
RU (1) | RU2537311C9 (en) |
WO (1) | WO2011042800A1 (en) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1396918B1 (en) | 2009-11-03 | 2012-12-20 | Polimeri Europa Spa | PROCEDURE FOR THE PREPARATION OF GRAPHENIC NANOPIASTRINES WITH HIGH LEVELABILITY IN LOW POLARITY POLYMER MATRICES AND THEIR POLYMERIC COMPOSITIONS |
NL2004588C2 (en) * | 2010-04-21 | 2011-10-24 | Synbra Tech Bv | PARTICULATE, EXPANDABLE POLYMER, METHOD OF MANUFACTURE, AND APPLICATION. |
JP5685072B2 (en) * | 2010-12-15 | 2015-03-18 | 積水化学工業株式会社 | Thermally foamable particles and foam production method |
EP2770013A4 (en) * | 2011-10-18 | 2015-04-01 | Sekisui Chemical Co Ltd | Method for producing resin composite material, and resin composite material |
KR101318481B1 (en) | 2012-09-19 | 2013-10-16 | 엘에스전선 주식회사 | Insulating composition for dc power cable and dc power cable prepared by using the same |
CN104884243B (en) * | 2012-10-19 | 2017-07-18 | 新泽西鲁特格斯州立大学 | Prepare the stripping method in situ of the polymer matrix composites of graphene reinforcement |
US11479652B2 (en) | 2012-10-19 | 2022-10-25 | Rutgers, The State University Of New Jersey | Covalent conjugates of graphene nanoparticles and polymer chains and composite materials formed therefrom |
DK2938661T3 (en) | 2012-12-28 | 2017-06-06 | Total Res & Technology Feluy | EXPANDABLE VINYLAROMATIC POLYMERS WITH SMALL PLATE-FORMED COOK PARTICLES |
ES2752053T3 (en) | 2012-12-28 | 2020-04-02 | Total Res & Technology Feluy | Expandable vinyl aromatic polymers containing graphite particles that have a polymodal particle size distribution |
CN105452359A (en) * | 2013-03-15 | 2016-03-30 | 瑞来斯实业公司 | Polymer-graphene nanocomposites |
MX2015014631A (en) | 2013-04-18 | 2016-09-29 | Univ Rutgers | In situ exfoliation method to fabricate a graphene-reninf-orced polymer matrix composite. |
US10107443B2 (en) | 2013-10-04 | 2018-10-23 | Orion Engineered Carbons Gmbh | Micro-domain carbon material for thermal insulation |
EP3055349A1 (en) * | 2013-10-11 | 2016-08-17 | Bewi Styrochem Oy | Polystyrene beads with low thermal conductivity |
JP2015120842A (en) * | 2013-12-24 | 2015-07-02 | 積水テクノ成型株式会社 | Method for producing foam molded body, and foam molded body |
US10138378B2 (en) | 2014-01-30 | 2018-11-27 | Monolith Materials, Inc. | Plasma gas throat assembly and method |
US11939477B2 (en) | 2014-01-30 | 2024-03-26 | Monolith Materials, Inc. | High temperature heat integration method of making carbon black |
US10370539B2 (en) | 2014-01-30 | 2019-08-06 | Monolith Materials, Inc. | System for high temperature chemical processing |
JP6765305B2 (en) | 2014-01-31 | 2020-10-07 | モノリス マテリアルズ インコーポレイテッド | Plasma torch design |
CN107074552A (en) | 2014-07-30 | 2017-08-18 | 新泽西鲁特格斯州立大学 | The enhanced polymer matrix composites of graphene |
EP3245242B1 (en) | 2015-01-14 | 2018-08-29 | Synthos S.A. | Use of a mineral having perovskite structure in vinyl aromatic polymer foam |
MA41344B1 (en) | 2015-01-14 | 2019-01-31 | Synthos Sa | Combination of silica and graphite and its use to reduce the thermal conductivity of a vinyl aromatic polymer foam |
MA41342A (en) * | 2015-01-14 | 2017-11-21 | Synthos Sa | PROCESS FOR THE PRODUCTION OF EXPANDABLE AROMATIC VINYL POLYMER GRANULATES WITH REDUCED THERMAL CONDUCTIVITY |
PL3245172T3 (en) | 2015-01-14 | 2019-06-28 | Synthos S.A. | Expandable vinyl aromatic polymer granulate and expanded vinyl aromatic polymer foam comprising geopolymer composite and its use therein |
BR112017016692A2 (en) | 2015-02-03 | 2018-04-10 | Monolith Materials, Inc. | method and apparatus for regenerative cooling |
US11987712B2 (en) | 2015-02-03 | 2024-05-21 | Monolith Materials, Inc. | Carbon black generating system |
CN111601447A (en) | 2015-07-29 | 2020-08-28 | 巨石材料公司 | DC plasma torch power design method and apparatus |
MX2018002943A (en) * | 2015-09-09 | 2018-09-28 | Monolith Mat Inc | Circular few layer graphene. |
CN105417535B (en) * | 2015-12-29 | 2017-05-31 | 成都新柯力化工科技有限公司 | A kind of method that grapheme material is prepared by stretching |
ITUB20160159A1 (en) * | 2016-01-27 | 2017-07-27 | Versalis Spa | COMPOSITION CONTAINING GRAPHENE AND NANO GRAPHENIC PLATES AND THEIR PREPARATION PROCEDURE. |
CA3211318A1 (en) | 2016-04-29 | 2017-11-02 | Monolith Materials, Inc. | Torch stinger method and apparatus |
CA3060482C (en) | 2016-04-29 | 2023-04-11 | Monolith Materials, Inc. | Secondary heat addition to particle production process and apparatus |
RU2618881C1 (en) * | 2016-05-16 | 2017-05-11 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Тамбовский государственный технический университет" ФГБОУ ВО "ТГТУ" | Method of producing dispersions of carbon nanomaterials |
JP6804222B2 (en) * | 2016-06-14 | 2020-12-23 | 東洋スチレン株式会社 | Styrene resin |
AU2017300726B2 (en) | 2016-07-20 | 2021-12-02 | Synthos S.A. | Use of geopolymeric additive in combination with non-brominated flame retardant in polymer foams |
CN109641798A (en) | 2016-07-20 | 2019-04-16 | 西索斯公司 | Modified geo-polymer and modified geopolymer composite material and its production technology |
US11702518B2 (en) | 2016-07-22 | 2023-07-18 | Rutgers, The State University Of New Jersey | In situ bonding of carbon fibers and nanotubes to polymer matrices |
MX2019000871A (en) | 2016-07-22 | 2019-06-12 | Univ Rutgers | In situ bonding of carbon fibers and nanotubes to polymer. |
WO2018069186A1 (en) | 2016-10-10 | 2018-04-19 | Total Research & Technology Feluy | Improved expandable vinyl aromatic polymers |
CN109863195B (en) | 2016-10-10 | 2022-08-19 | 道达尔研究技术弗吕公司 | Improved expandable vinyl aromatic polymers |
EP3523363B1 (en) | 2016-10-10 | 2020-07-22 | Total Research & Technology Feluy | Improved expandable vinyl aromatic polymers |
JP6854671B2 (en) * | 2017-03-08 | 2021-04-07 | 株式会社カネカ | Foamable thermoplastic resin particles and their manufacturing method |
CN110603297A (en) | 2017-03-08 | 2019-12-20 | 巨石材料公司 | System and method for producing carbon particles with heat transfer gas |
CN106829935B (en) * | 2017-03-27 | 2023-03-24 | 重庆墨希科技有限公司 | Multi-cavity graphene continuous growth equipment arranged transversely |
CN115637064A (en) | 2017-04-20 | 2023-01-24 | 巨石材料公司 | Particle system and method |
CN110621618A (en) * | 2017-06-05 | 2019-12-27 | 积水化学工业株式会社 | Dispersion liquid containing carbon material, slurry for forming electrode, and method for producing electrode for nonaqueous electrolyte secondary battery |
EP3676220A4 (en) | 2017-08-28 | 2021-03-31 | Monolith Materials, Inc. | Systems and methods for particle generation |
EP3700980A4 (en) | 2017-10-24 | 2021-04-21 | Monolith Materials, Inc. | Particle systems and methods |
US11479653B2 (en) | 2018-01-16 | 2022-10-25 | Rutgers, The State University Of New Jersey | Use of graphene-polymer composites to improve barrier resistance of polymers to liquid and gas permeants |
DE202018106258U1 (en) | 2018-10-15 | 2020-01-20 | Rutgers, The State University Of New Jersey | Nano-graphite sponges |
RU2707601C1 (en) * | 2019-02-05 | 2019-11-28 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный технологический институт (технический университет)" | Method of producing gas-filled polyacrimimides |
US11807757B2 (en) | 2019-05-07 | 2023-11-07 | Rutgers, The State University Of New Jersey | Economical multi-scale reinforced composites |
CN114341256A (en) | 2019-09-04 | 2022-04-12 | 道达尔能源一技术比利时公司 | Expandable vinyl aromatic polymers with improved flame retardancy |
CN114750441B (en) * | 2022-05-12 | 2022-12-13 | 南京航空航天大学 | Magnetic orientation arrangement wave-absorbing thermoplastic wire and preparation method thereof |
Family Cites Families (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3631014A (en) | 1967-05-26 | 1971-12-28 | Sinclair Koppers Co | Suspension polymerization process |
JPS63183941A (en) | 1987-01-27 | 1988-07-29 | Asahi Chem Ind Co Ltd | Heat insulating thermoplastic resin foam |
US5041465A (en) | 1990-09-17 | 1991-08-20 | Arco Chemical Technology, Inc. | Reducing lustrous carbon in the lost foam process |
DE9305431U1 (en) | 1993-04-13 | 1994-08-11 | AlgoStat GmbH & Co. KG, 29227 Celle | Molded body made of polystyrene rigid foam |
US5679718A (en) | 1995-04-27 | 1997-10-21 | The Dow Chemical Company | Microcellular foams containing an infrared attenuating agent and a method of using |
EP0902804A1 (en) | 1996-05-28 | 1999-03-24 | Basf Aktiengesellschaft | Expandable styrene polymers containing carbon black |
ATE196158T1 (en) | 1997-05-14 | 2000-09-15 | Basf Ag | EXPANDABLE STYRENE POLYMERS CONTAINING GRAPHITE PARTICLES |
ATE251196T1 (en) | 1998-12-09 | 2003-10-15 | Basf Ag | METHOD FOR PRODUCING EXPANDABLE POLYSTYRENE PARTICLES |
ITMI20012706A1 (en) | 2001-12-20 | 2003-06-20 | Enichem Spa | PROCEDURE FOR THE PRODUCTION OF EXPANDABLE THERMOPLASTIC POLYMER GRANULES AND APPARATUS SUITABLE FOR THE PURPOSE |
ITMI20012708A1 (en) | 2001-12-20 | 2003-06-20 | Enichem Spa | DEVICE FOR HOT GRANULATION OF THERMOLASTIC POLYMERS |
WO2003085681A1 (en) | 2002-04-01 | 2003-10-16 | World Properties, Inc. | Electrically conductive polymeric foams and elastomers and methods of manufacture thereof |
ITSV20020032A1 (en) | 2002-07-09 | 2004-01-09 | Alberto Lodolo | DIAPHRAGM VALVE AND SHUTTER FOR SUCH VALVE |
DE10241298A1 (en) | 2002-09-04 | 2004-03-18 | Basf Ag | Process for the production of polystyrene foam particles with low bulk density |
US7071258B1 (en) | 2002-10-21 | 2006-07-04 | Nanotek Instruments, Inc. | Nano-scaled graphene plates |
ITMI20030627A1 (en) * | 2003-03-31 | 2004-10-01 | Polimeri Europa Spa | EXPANDABLE VINYLAROMATIC POLYMERS AND PROCEDURE FOR THEIR PREPARATION. |
US20080287560A1 (en) * | 2004-12-31 | 2008-11-20 | Loh Roland R | Polymer foams containing multi-functional layered nano-graphite |
US7605188B2 (en) * | 2004-12-31 | 2009-10-20 | Owens Corning Intellectual Capital, Llc | Polymer foams containing multi-functional layered nano-graphite |
US7404888B2 (en) * | 2004-07-07 | 2008-07-29 | Chevron U.S.A. Inc. | Reducing metal corrosion of hydrocarbons using acidic fischer-tropsch products |
DE102004058586A1 (en) | 2004-12-03 | 2006-06-14 | Basf Ag | Halogen-free, flame-retardant, expandable styrene polymers |
WO2006061571A1 (en) | 2004-12-06 | 2006-06-15 | Ineos Europe Limited | Expandable polystyrene composition |
FR2885131B1 (en) | 2005-04-27 | 2008-03-07 | Arkema Sa | POLYMER-BASED CELL STRUCTURE COMPRISING CARBON NANOTUBES, PREPARATION METHOD AND APPLICATIONS THEREOF |
ITMO20050135A1 (en) | 2005-06-03 | 2006-12-04 | Coopbox Europ S P A | PROCEDURE FOR THE PRODUCTION OF EXPANDED POLYSTYRENE. |
WO2008048295A2 (en) | 2005-11-18 | 2008-04-24 | Northwestern University | Stable dispersions of polymer-coated graphitic nanoplatelets |
JP2007154041A (en) * | 2005-12-05 | 2007-06-21 | Nissan Motor Co Ltd | Thermosetting resin composition and foamed thermosetting resin produced by foaming and curing the composition |
US7604049B2 (en) * | 2005-12-16 | 2009-10-20 | Schlumberger Technology Corporation | Polymeric composites, oilfield elements comprising same, and methods of using same in oilfield applications |
CN101528828A (en) | 2006-08-10 | 2009-09-09 | 陶氏环球技术公司 | Polymers filled with highly expanded graphite |
US7745528B2 (en) | 2006-10-06 | 2010-06-29 | The Trustees Of Princeton University | Functional graphene-rubber nanocomposites |
WO2008091308A2 (en) * | 2007-01-19 | 2008-07-31 | Dow Global Technologies Inc. | Polymeric foam containing long carbon nano-tubes |
US7892514B2 (en) | 2007-02-22 | 2011-02-22 | Nanotek Instruments, Inc. | Method of producing nano-scaled graphene and inorganic platelets and their nanocomposites |
US20080242752A1 (en) * | 2007-03-28 | 2008-10-02 | Yadollah Delaviz | Polystyrene foams incorporating nanographite and HFC-134 |
US8132746B2 (en) | 2007-04-17 | 2012-03-13 | Nanotek Instruments, Inc. | Low-temperature method of producing nano-scaled graphene platelets and their nanocomposites |
US20090022649A1 (en) | 2007-07-19 | 2009-01-22 | Aruna Zhamu | Method for producing ultra-thin nano-scaled graphene platelets |
US8524067B2 (en) | 2007-07-27 | 2013-09-03 | Nanotek Instruments, Inc. | Electrochemical method of producing nano-scaled graphene platelets |
WO2009018204A1 (en) | 2007-08-01 | 2009-02-05 | Dow Global Technologies Inc. | Highly efficient process for manufacture of exfoliated graphene |
WO2009029984A1 (en) | 2007-09-03 | 2009-03-12 | Newsouth Innovations Pty Limited | Graphene |
EP2212248B1 (en) | 2007-10-19 | 2017-05-24 | University Of Wollongong | Process for the preparation of graphene |
US7790285B2 (en) | 2007-12-17 | 2010-09-07 | Nanotek Instruments, Inc. | Nano-scaled graphene platelets with a high length-to-width aspect ratio |
IT1392391B1 (en) * | 2008-12-19 | 2012-03-02 | Polimeri Europa Spa | COMPOSITIONS OF VINYLAROMATIC POLYMERS EXPANDABLE TO IMPROVED THERMAL INSULATION CAPACITY, PROCEDURE FOR THEIR PREPARATION AND ITEMS EXPANDED BY THEM OBTAINED |
WO2011028924A2 (en) * | 2009-09-02 | 2011-03-10 | University Of Washington | Porous thermoplastic foams as heat transfer materials |
US8314177B2 (en) * | 2010-09-09 | 2012-11-20 | Baker Hughes Incorporated | Polymer nanocomposite |
-
2009
- 2009-10-07 IT ITMI2009A001715A patent/IT1396193B1/en active
-
2010
- 2010-10-06 BR BR112012007978-6A patent/BR112012007978B1/en not_active IP Right Cessation
- 2010-10-06 WO PCT/IB2010/002547 patent/WO2011042800A1/en active Application Filing
- 2010-10-06 PL PL10782373T patent/PL2486085T3/en unknown
- 2010-10-06 US US13/500,763 patent/US8969466B2/en not_active Expired - Fee Related
- 2010-10-06 CN CN201080052870.3A patent/CN102666686B/en active Active
- 2010-10-06 JP JP2012532678A patent/JP5632003B2/en not_active Expired - Fee Related
- 2010-10-06 ES ES10782373.4T patent/ES2625888T3/en active Active
- 2010-10-06 MX MX2012004081A patent/MX343957B/en active IP Right Grant
- 2010-10-06 PT PT107823734T patent/PT2486085T/en unknown
- 2010-10-06 RU RU2012116879/05A patent/RU2537311C9/en active
- 2010-10-06 HU HUE10782373A patent/HUE034340T2/en unknown
- 2010-10-06 EP EP10782373.4A patent/EP2486085B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
JP2013507477A (en) | 2013-03-04 |
IT1396193B1 (en) | 2012-11-16 |
US20120264836A1 (en) | 2012-10-18 |
CN102666686B (en) | 2014-03-26 |
MX343957B (en) | 2016-11-30 |
PL2486085T3 (en) | 2017-08-31 |
PT2486085T (en) | 2017-05-29 |
ITMI20091715A1 (en) | 2011-04-08 |
MX2012004081A (en) | 2012-10-03 |
EP2486085A1 (en) | 2012-08-15 |
US8969466B2 (en) | 2015-03-03 |
EP2486085B1 (en) | 2017-02-22 |
JP5632003B2 (en) | 2014-11-26 |
WO2011042800A1 (en) | 2011-04-14 |
CN102666686A (en) | 2012-09-12 |
ES2625888T3 (en) | 2017-07-20 |
RU2012116879A (en) | 2013-11-20 |
HUE034340T2 (en) | 2018-02-28 |
RU2537311C2 (en) | 2014-12-27 |
BR112012007978B1 (en) | 2020-07-07 |
RU2537311C9 (en) | 2015-05-20 |
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