BR112012000211B1 - PYRIDAZINE COMPOUNDS, METHOD FOR CONTROL OF INVERTEBRATED PEST, METHOD FOR PROTECTING PLANT PROPAGATION MATERIAL AND PLANT PROPAGATION MATERIAL - Google Patents

Abstract

PYRIDAZINE COMPOUNDS, METHOD FOR THE CONTROL OF INVERTEBRATED PEST, METHOD FOR PROTECTING PLANT PROPAGATION MATERIAL AND PLANT PROPAGATION MATERIAL The present invention relates to pyridazine compounds of formula I or II and their salts and N-oxides. wherein A is a substituted or unsubstituted oxazole or thiazole or imidazole radical; V is C (Rv) or N; W is C (Rw) or N; with the proviso that V or W is N; Rt, Ru, Rv, Rw are H, halogen, C1-C4 alkyl and the like; X1 is S, O or NR1a, where R1a is selected from H, C1-C10 alkyl and the like; X2 is OR2a, NR2bR2c, S (O) mR2d, where m is O, 1 or 2, R2 a is C1-C4 alkyl, C1-C4 haloalkyl and the like, R2b, R2c is H, C1-C4 alkyl, C1 haloalkyl -C4 and the like, or R2b and R2c, together with the nitrogen atom to which they are attached, form a heterocycle, and R2d is C1-C4 alkyl, C1-C4 haloalkyl, C3-C5 cycloalkyl and the like; and R1 is H, CN, C1-C1 alkyl (...).

Description

FIELD OF THE INVENTION

[001] The present invention relates to pyridazine compounds that are useful for combating or controlling invertebrate pests, in particular arthropod pests. The invention also relates to a method for controlling invertebrate pests by using these compounds. The invention also relates to a method for protecting plant propagating material and / or plants growing from it through the use of these compounds. The present invention also relates to plant propagating material and an agricultural or veterinary composition comprising said compounds.

BACKGROUND OF THE INVENTION

[002] Invertebrate pests and, in particular, arthropods and nematodes, destroy harvested and growing crops and attack wooden residences and commercial structures, thus causing a great economic loss for food supply and property. Although a large number of pesticidal agents are known, due to the ability of target pests to develop resistance to said agents, there is a constant need for new agents to combat invertebrate pests such as insects, arachnids and nematodes. It is, therefore, an objective of the present invention to provide compounds that have satisfactory pesticidal activity and that exhibit a broad spectrum of activity against a large number of different invertebrate pests, especially against insects, arachnids and nematodes difficult to control.

[003] EP 0419944 describes derivatives of oxazole- and thioxazolcarboxylic acids and their use as herbicides is mentioned.

[004] WO 2007/068373, WO 2007/068375 and WO 2007/068377 describe derivatives of N-aryl- and N-hetarylamides, derivatives of carboxylic acids that comprise a 5- or 6-membered carbocycle or heterocycle. These compounds are said to be useful for the control of microorganisms.

[005] WO 2005/074686 and WO 2005/075411 describe N-arylamide derivatives which are mentioned as being useful in the control of microorganisms such as fungi, bacteria in phytoprotection.

[006] WO 2004/106324, WO 2004/035545 and WO 2005/040152 describe derivatives of N-aryl- and N-hetarylamides, derivatives of carboxylic acids that comprise a 5-membered heterocycle. These compounds are said to be useful as herbicides.

[007] WO 2006/074445 describes biologically active heteropyrrole analogs such as imidazoles, thiazoles, oxazoles and pyrazoles; their pharmaceutical preparation and methods of therapeutic administration are mentioned.

[008] WO 2003/106427, WO 2004/046129 and JP 2007-77106 describe derivatives of N-arylamides, derived from pyridazine carboxylic acids. These compounds are said to be useful for combating invertebrate pests.

[009] WO 2001/00575 describes derivatives of N-aryl- and N-hetarylamides, derivatives of carboxylic acids that comprise a 5- or 6-membered heterocycle that contains an additional function derived from amide in the ortho position. These compounds are said to be useful as insecticides.

[010] WO 2005/073165 describes derivatives of N-aryl- or N-hetarylamides, derived from carboxylic acids comprising phenyl or a heterocycle, in which the N-linked cycle contains an additional function derived from amide at the meta position. These compounds are said to be useful as insecticides.

[011] It is an objective of the present invention, to provide compounds that have satisfactory pesticidal activity, in particular insecticidal activity, and to show a broad spectrum of activity against a large number of different invertebrate pests, especially against insects that are difficult to control.

DESCRIPTION OF THE INVENTION

[012] It was found that these objectives can be achieved by compounds of the formula I and II, as defined below, and by their salts and N-oxides, in particular their salts acceptable for agriculture or veterinary.

em que A é um radical oxazol ou tiazol ou imidazol das fórmulas A1, A2 ou A3, em que

em que # denota o ponto de ligação ao restante das fórmulas I ou II, e em que R41, R42, R43 e R51 são, independentemente um do outro, selecionados a partir de hidrogênio, halogênio, CN, NO2, alquila C1-C10, alquenila C2-C10 e alquinila C2-C10, em que os 3 últimos radicais mencionados podem ser não substituídos, podem ser parcial ou totalmente halogenados ou podem portar 1, 2 ou 3 substituintes Rx idênticos ou diferentes, ou em que R41, R42, R43 e R51 são selecionados ainda a partir de ORa, C(Y)Rb, C(Y)ORc, S(O)mRd, NReRf, heterociclila, heteroarila, cicloalquila C3- C10, cicloalquenila C5-C10 e fenila, em que os cinco últimos radicais mencionados podem ser não substituídos ou podem portar 1, 2, 3, 4 ou 5 substituintes Rx idênticos ou diferentes, em que m é 0, 1, 2 e em que R52, R53 são selecionados a partir de hidrogênio, halogênio, CN, NO2, alquila C1-C10, alquenila C2-C10 e alquinila C2-C10, em que os três últimos radicais mencionados podem ser não substituídos, podem ser parcial ou totalmente halogenados ou podem portar 1, 2 ou 3 substituintes Rx idênticos ou diferentes, ou em que R52, R53 são selecionados ainda a partir de ORa, C(Y)Rb, C(Y)ORc, S(O)mRd, NReRf, heterociclila, heteroarila, cicloalquila C3-C10, cicloalquenila C5-C10 e fenila, em que os cinco últimos radicais mencionados podem ser não substituídos ou podem portar 1, 2, 3, 4 ou 5 substituintes Rx idênticos ou diferentes, em que m é 0, 1 ou 2, e em que R61, R62, R63, se presentes, são selecionados a partir de hidrogênio, halogênio, CN, NO2, alquila C1-C10, alquenila C2-C10 e alquinila C2-C10, em que os 3 últimos radicais mencionados podem ser não substituídos, podem ser parcial ou totalmente halogenados ou podem portar 1, 2 ou 3 substituintes Rx idênticos ou diferentes, ou em que R61, R62, R63, se presentes, são selecionados ainda a partir de ORa, C(Y)Rb, C(Y)ORc, S(O)mRd, NReRf, C(Y)NRgRh, S(O)mNReRf, C(Y)NRiNReRf, heterociclila, heterociclila-C1-C5-alquila, heteroarila, heteroarila-C1-C5-alquila, cicloalquila C3-C10, cicloalquil-C3-C10-alquila-C1-C5, cicloalquenila C5-C10, C5-C10-cicloalquenila-C1-C5-alquila, fenila, fenil-alquila-C1- C5, C1-C5-alquilen-ORa, C1-C5-aquileno-CN, C1-C5-aquileno-C(Y)Rb, C1-C5- aquileno-C(Y)ORc, C1-C5-aquileno-NReRf, C1-C5-aquileno-C(Y)NRgRh, C1-C5- aquileno-S(O)mRd, C1-C5-aquileno-S(O)mNReRf, C1-C5-aquileno-C(Y)NRiNReRf, em que os dezenove últimos radicais mencionados podem ser não substituídos ou podem portar 1, 2, 3, 4 ou 5 substituintes Ry idênticos ou diferentes, em que m é 0, 1 ou 2; Z é O ou S para z = 0 ou Z é N para z = 1; V é C(Rv) ou N, W é C(Rw) ou N; com a condição de que V ou W seja N; Rt, Ru, Rv e Rw são, independentemente um do outro, selecionados a partir de hidrogênio, halogênio, alquila C1-C4, haloalquila C1-C3, alcóxi C1-C4, haloalcóxi C1-C3, alquiltio C1-C4, haloalquiltio C1-C3, alquilsulfinila C1-C4, haloalquilsulfinila C1-C3, alquilsulfonila C1-C4, haloalquilsulfonila C1-C3, cicloalquila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2-C4 ou alcóxi-C1-C4-alquila-C1-C4; X1 é S, O ou NR1a, em que R1a é selecionado a partir de hidrogênio, alquila C1-C10, haloalquila C1-C4, cicloalquila C3-C10, cicloalquilmetila C3-C10, halocicloalquila C3-C10, alquenila C2-C10, haloalquenila C2-C10, alquinila C2-C10, alcóxi C1-C10-alquila C1-C4, ORa, fenila, hetarila, heterociclila, fenil-alquila-C1-C4, hetaril-alquila-C1-C4, heterociclil-alquila C1-C4 em que o anel nos seis últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que, independentemente um do outro, são selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; X2 é OR2a, NR2bR2c, S(O)mR2d, em que m é 0, 1 ou 2, em que R2a é selecionado a partir de alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2- C4, alcóxi-C1-C4-alquila-C1-C4, fenila, hetarila, heterociclila, fenil-alquila-C1-C4, hetaril-alquila C1-C4, heterociclil-alquila-C1-C4 em que o anel nos seis últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que, independentemente um do outro, são selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4, e em que R2b, R2c são, independentemente um do outro, selecionados a partir de hidrogênio, alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2-C4, alcóxi-C1-C4-alquila-C1-C4, alquilcarbonila C1-C4, haloalquilcarbonila C1-C4, alquilsulfonila C1-C4, haloalquilsulfonila C1-C4, fenila, fenilcarbonila, fenilsulfonila, hetarila, hetarilcarbonila, hetarilsulfonila, heterociclila, heterociclilacarbonila, heterociclilassulfonila, fenil-alquila-C1-C4, hetaril-alquila-C1-C4 e heterociclil- alquila-C1-C4 em que o anel nos doze últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que, independentemente um do outro, são selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4, ou R2b e R2c, juntamente com o átomo de nitrogênio ao qual estão ligados, formam um heterociclo saturado ou insaturado com 5 ou 6 membros, que pode portar um heteroátomo adicional sendo selecionado a partir de O, S e N como um átomo membro do anel e em que o heterociclo pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que, independentemente um do outro, são selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4, e em que R2d é selecionado a partir de alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2-C4, alcóxi-C1-C4-alquila-C1-C4, fenila, hetarila, heterociclila, fenil- alquila-C1-C4, hetaril-alquila-C1-C4 e heterociclil-alquila-C1-C4 em que o anel nos seis últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que, independentemente um do outro, são selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; R1 é hidrogênio, CN, alquila C1-C10, haloalquila C1-C10, cicloalquila C3-C10, halocicloalquila C3-C10, alquenila C2-C10, haloalquenila C2-C10, alquinila C2-C10, haloalquinila C3-C10, ORa, C(Y)Rb, C(Y)ORc, S(O)2Rd, NReRf, C(Y)NRgRh, S(O)mNReRf, C(Y)NRiNReRf, fenila, hetarila, heterociclila, alquileno C1-C5-ORa, alquileno C1-C5-CN, fenil-alquila C1-C5, hetarila-alquila C1-C5, heterociclila- alquila C1-C5, cicloalquila C3-C10-alquila C1-C5, alquileno C1-C5-C(Y)Rb, alquileno C1-C5-C(Y)ORc, alquileno C1-C5-NReRf, alquileno C1-C5-C(Y)NRgRh, alquileno C1-C5-S(O)2Rd, alquileno C1-C5-S(O)mNReRf, alquileno C1-C5-C(Y)NRiNReRf, em que os dezesseis últimos radicais mencionados podem ser não substituídos ou podem portar 1, 2, 3, 4 ou 5 substituintes Rx ou Ry idênticos ou diferentes e em que m é 0, 1 ou 2; Y é O ou S; Ra, Rb, Rc são, independentemente um do outro, selecionados a partir de hidrogênio, alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, cicloalquilmetila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2- C4, alquinila C2-C4, alcóxi-C1-C4-alquila-C1-C4, fenila, hetarila, heterociclila, fenil- alquila-C1-C4, hetaril-alquila-C1-C4 e heterociclil-alquila-C1-C4 em que o anel nos seis últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que, independentemente um do outro, são selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; Rd é selecionado a partir de alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, cicloalquilmetila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2-C4, alcóxi-C1-C4-alquila-C1-C4, fenila, hetarila, heterociclila, fenil-alquila-C1-C4, hetaril-alquila-C1-C4 e heterociclil-alquila-C1-C4 em que o anel nos seis últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que são, independentemente um do outro, selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; Re, Rf são, independentemente um do outro, selecionados a partir de hidrogênio, alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, cicloalquilmetila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2- C4, alquinila C2-C4, alcóxi-C1-C4-alquila-C1-C4, alquilcarbonila C1-C4, haloalquilcarbonila C1-C4, alquilsulfonila C1-C4, haloalquilsulfonila C1-C4, fenila, fenilcarbonila, fenilsulfonila, hetarila, hetarilcarbonila, hetarilsulfonila, heterociclila, heterociclilacarbonila, heterociclilassulfonila, fenil-alquila-C1-C4, hetaril-alquila-C1-C4 e heterociclil-alquila-C1-C4 em que o anel nos doze últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que, independentemente um do outro, são selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; ou Re e Rf, juntamente com o átomo de nitrogênio ao qual estão ligados, formam um heterociclo saturado ou insaturado com 5 ou 6 membros, que pode portar um heteroátomo adicional sendo selecionado a partir de O, S e N como um átomo membro do anel e em que o heterociclo pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que são, independentemente um do outro, selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; Rg, Rh são, independentemente um do outro, selecionados a partir de hidrogênio, alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2-C4, alcóxi-C1-C4-alquila-C1-C4, fenila, hetarila, heterociclila, fenil-alquila-C1-C4 e hetaril-alquila-C1-C4, heterociclil-alquila-C1-C4, em que o anel nos seis últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que são, independentemente um do outro, selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; Ri é selecionado a partir de hidrogênio, alquila C1-C4, haloalquila C1-C4, cicloalquila C3-C6, cicloalquilmetila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2-C4, alcóxi-C1-C4-alquila-C1-C4, fenila e fenil-alquila-C1-C4 em que o anel fenila nos dois últimos radicais mencionados pode ser não substituído ou pode portar 1, 2, 3, 4 ou 5 substituintes que são, independentemente um do outro, selecionados a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4 e haloalcóxi C1-C4; Rx são, independentemente um do outro, selecionados a partir de ciano, nitro, alcóxi C1-C4, haloalcóxi C1-C4, alquiltio C1-C4, haloalquiltio C1-C4, alquilsulfinila C1-C4, haloalquilsulfinila C1-C4, alquilsulfonila C1-C4, haloalquilsulfonila C1-C4, alquilcarbonila C1-C10, cicloalquila C3-C6, heterociclila com 5 a 7 membros, fenila, cicloalcóxi C3-C6, heterociclilóxi com 3 a 6 membros e fenóxi, em que os 6 últimos radicais mencionados podem ser não substituídos ou podem portar 1, 2, 3, 4 ou 5 radicais Ry; e em que Ry é selecionado a partir de halogênio, ciano, nitro, alquila C1-C4, haloalquila C1-C4, alcóxi C1-C4, haloalcóxi C1-C4, S(O)mRd, S(O)mNReRf, alquilcarbonila C1-C4, haloalquilcarbonila C1-C4, alcoxicarbonila C1-C4, haloalcoxicarbonila C1-C4, cicloalquila C3-C6, halocicloalquila C3-C6, alquenila C2-C4, haloalquenila C2-C4, alquinila C2-C4 e alcóxi-C1-C4-alquila-C1-C4.[013] In a first aspect, the present invention relates to pyradazine compounds of formulas I or II and their salts and N-oxides,

where A is an oxazole or thiazole or imidazole radical of formulas A1, A2 or A3, where

where # denotes the point of attachment to the rest of formulas I or II, and where R41, R42, R43 and R51 are, independently of each other, selected from hydrogen, halogen, CN, NO2, C1-C10 alkyl, C2-C10 alkenyl and C2-C10 alkynyl, in which the last 3 radicals mentioned may be unsubstituted, may be partially or fully halogenated or may carry 1, 2 or 3 identical or different Rx substituents, or where R41, R42, R43 and R51 are further selected from ORa, C (Y) Rb, C (Y) ORc, S (O) mRd, NReRf, heterocyclyl, heteroaryl, C3-C10 cycloalkyl, C5-C10 cycloalkenyl and phenyl, in which the five latter mentioned radicals may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or different Rx substituents, where m is 0, 1, 2 and where R52, R53 are selected from hydrogen, halogen, CN , NO2, C1-C10 alkyl, C2-C10 alkenyl and C2-C10 alkynyl, where the last three radicals mentioned may be unsubstituted, may be partial or fully halogenated or can carry 1, 2 or 3 identical or different Rx substituents, or where R52, R53 are further selected from ORa, C (Y) Rb, C (Y) ORc, S (O) mRd, NReRf, heterocyclyl, heteroaryl, C3-C10 cycloalkyl, C5-C10 cycloalkenyl and phenyl, where the last five radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or different Rx substituents, where m is 0 , 1 or 2, and where R61, R62, R63, if present, are selected from hydrogen, halogen, CN, NO2, C1-C10 alkyl, C2-C10 alkenyl and C2-C10 alkynyl, where the last 3 mentioned radicals can be unsubstituted, can be partially or totally halogenated or can carry 1, 2 or 3 identical or different Rx substituents, or in which R61, R62, R63, if present, are further selected from ORa, C (Y ) Rb, C (Y) ORc, S (O) mRd, NReRf, C (Y) NRgRh, S (O) mNReRf, C (Y) NRiNReRf, heterocyclyl, heterocyclyl-C1-C5-alkyl, heteroaryl, heteroaryl-C1 -C5-alkyl, ci C3-C10 cloalkyl, C3-C10-cycloalkyl-C1-C5, C5-C10 cycloalkenyl, C5-C10-cycloalkenyl-C1-C5-alkyl, phenyl, phenyl-C1- C5, C1-C5-alkyl-alkyl- ORa, C1-C5-aquylene-CN, C1-C5-aquylene-C (Y) Rb, C1-C5-aquylene-C (Y) ORc, C1-C5-aquylene-NReRf, C1-C5-aquylene-C ( Y) NRgRh, C1-C5-aquylene-S (O) mRd, C1-C5-aquylene-S (O) mNReRf, C1-C5-aquylene-C (Y) NRiNReRf, where the last nineteen radicals mentioned may not be substituted or can carry 1, 2, 3, 4 or 5 identical or different Ry substituents, where m is 0, 1 or 2; Z is O or S for z = 0 or Z is N for z = 1; V is C (Rv) or N, W is C (Rw) or N; with the proviso that V or W is N; Rt, Ru, Rv and Rw are independently selected from hydrogen, halogen, C1-C4 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C4 alkylthio, C1- haloalkylthio C3, C1-C4 alkylsulfinyl, C1-C3 haloalkylsulfinyl, C1-C4 alkylsulfonyl, C1-C3 haloalkylsulfonyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl or C2-C4 alkoxy -C4-C1-C4-alkyl; X1 is S, O or NR1a, where R1a is selected from hydrogen, C1-C10 alkyl, C1-C4 haloalkyl, C3-C10 cycloalkyl, C3-C10 cycloalkylmethyl, C3-C10 halocycloalkyl, C2-C10 alkenyl, C2 haloalkenyl -C10, C2-C10 alkynyl, C1-C10 alkoxy-C1-C4 alkyl, ORa, phenyl, hetaryl, heterocyclyl, phenyl-C1-C4-alkyl, heteryl-C1-C4-alkyl, C1-C4-heterocyclyl where the ring in the last six radicals mentioned can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from halogen, cyano, nitro, C1-C4 alkyl, C1- haloalkyl C4, C1-C4 alkoxy and C1-C4 haloalkoxy; X2 is OR2a, NR2bR2c, S (O) mR2d, where m is 0, 1 or 2, where R2a is selected from C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl, C1-C4-alkoxy-C1-C4-alkoxy, phenyl, hetaryl, heterocyclyl, phenyl-C1-C4-alkyl, hetero-C1-C4, heterocyclyl- C1-C4-alkyl where the ring in the last six mentioned radicals can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from halogen, cyano, nitro, alkyl C1-C4, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy, and where R2b, R2c are, independently of each other, selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3 cycloalkyl -C6, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4 alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-alkyl4-alkylsulfonyl C1-C4 haloalkylsulfonyl, phenyl, phenyl arbonyl, phenylsulfonyl, hetaryl, hetarylcarbonyl, hetarylsulfonyl, heterocyclyl, heterocyclylcarbonyl, heterocyclylsulfonyl, phenyl-C1-C4-alkyl, heteryl-C1-C4-alkyl and heterocyclyl-C1-C4-where the ring can be mentioned in the last twelve radicals unsubstituted or may carry 1, 2, 3, 4 or 5 substituents which, independently of one another, are selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1 haloalkoxy -C4, or R2b and R2c, together with the nitrogen atom to which they are attached, form a 5- or 6-membered saturated or unsaturated heterocycle, which can carry an additional heteroatom being selected from O, S and N as an atom ring member and in which the heterocycle can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which, independently of one another, are selected from halogen, cyano, nitro, C1-C4 alkyl, C1 haloalkyl -C4, C1-C4 alkoxy and C1-C4 haloalkoxy, and where R2d is selected from C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4 alkynyl, C1-C4-alkoxy-C1-C4-alkyl , phenyl, hetaryl, heterocyclyl, phenyl-C1-C4-alkyl, hetaryl-C1-C4-alkyl and heterocyclyl-C1-C4-alkyl in which the ring in the last six mentioned radicals may be unsubstituted or may carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; R1 is hydrogen, CN, C1-C10 alkyl, C1-C10 haloalkyl, C3-C10 cycloalkyl, C3-C10 halocycloalkyl, C2-C10 alkenyl, C2-C10 haloalkyl, C2-C10 alkynyl, C3-C10 haloalkyl, ORa, C ( Y) Rb, C (Y) ORc, S (O) 2Rd, NReRf, C (Y) NRgRh, S (O) mNReRf, C (Y) NRiNReRf, phenyl, hethyl, heterocyclyl, C1-C5-ORa alkylene, alkylene C1-C5-CN, phenyl-C1-C5 alkyl, hethyl-C1-C5 alkyl, heterocyclyl-C1-C5 alkyl, C3-C10-cycloalkyl-C1-C5 alkyl, C1-C5-C (Y) alkylene Rb, C1 alkylene -C5-C (Y) ORc, C1-C5-NReRf alkylene, C1-C5-C (Y) alkylene NRgRh, C1-C5-S (O) 2Rd alkylene, C1-C5-S (O) alkylene mNReRf, alkylene C1-C5-C (Y) NRiNReRf, where the last sixteen mentioned radicals may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or different Rx or Ry substituents and where m is 0, 1 or 2 ; Y is O or S; Ra, Rb, Rc are, independently of each other, selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2 haloalkenyl - C4, C2-C4 alkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl, hetaryl, heterocyclyl, phenyl-C1-C4-alkyl, heteryl-C1-C4-alkyl and heterocyclyl-C1-C4-alkyl in that the ring in the last six mentioned radicals can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from halogen, cyano, nitro, C1-C4 alkyl, C1 haloalkyl -C4, C1-C4 alkoxy and C1-C4 haloalkoxy; Rd is selected from C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4 alkoxy, C2-C1- alkoxy C4-alkyl-C1-C4, phenyl, hetaryl, heterocyclyl, phenyl-alkyl-C1-C4, hetaryl-alkyl-C1-C4 and heterocyclyl-alkyl-C1-C4 where the ring in the last six mentioned radicals can be unsubstituted or it can carry 1, 2, 3, 4 or 5 substituents that are, independently of each other, selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy ; Re, Rf are independently selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkenyl , C2-C4 alkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, phenyl, phenylcarbonyl, phenylsulfonyl, heterocyclyl, heterocyclylcarbonyl, heterocyclyl sulfonyl, phenyl-C1-C4-alkyl, hetaryl-C1-C4-alkyl and heterocyclyl-C1-C4-alkyl where the ring in the last twelve radicals mentioned may be unsubstituted or may carry 1, 2, 3 , 4 or 5 substituents which, independently of each other, are selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; or Re and Rf, together with the nitrogen atom to which they are attached, form a 5- or 6-membered saturated or unsaturated heterocycle, which can carry an additional heteroatom being selected from O, S and N as a ring member atom and where the heterocycle can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which are, independently of one another, selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; Rg, Rh are independently selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4 alkynyl , C1-C4-alkoxy-C1-C4-alkyl, phenyl, hetaryl, heterocyclyl, phenyl-C1-C4-alkyl and heteryl-C1-C4-alkyl, heterocyclyl-C1-C4-alkyl, where the ring in the last six mentioned radicals can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which are, independently of each other, selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1- alkoxy C4 and C1-C4 haloalkoxy; Ri is selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4 alkynyl, alkoxy- C1-C4-alkyl-C1-C4, phenyl and phenyl-alkyl-C1-C4 in which the phenyl ring in the last two radicals mentioned can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which are, independently from each other, selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; Rx are independently selected from cyano, nitro, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylthio, C1-C4 haloalkylthio, C1-C4 alkylsulfinyl, C1-C4 haloalkylsulfinyl, C1-C4 alkylsulfonyl , C1-C4 haloalkylsulfonyl, C1-C10 alkylcarbonyl, C3-C6 cycloalkyl, 5- to 7-membered heterocyclyl, phenyl, C3-C6-cycloalkoxy, 3- to 6-membered heterocyclyl and phenoxy, where the last 6 radicals mentioned may be unsubstituted or they can carry 1, 2, 3, 4 or 5 Ry radicals; and where Ry is selected from halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, S (O) mRd, S (O) mNReRf, C1- alkylcarbonyl C4, C1-C4 haloalkylcarbonyl, C1-C4 alkoxycarbonyl, C1-C4 haloalkoxycarbonyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4-alkaline-4 and alkoxy C1-C4.

[014] An additional aspect of the present invention relates to a method for controlling invertebrate pests whose method comprises treating pests, their food supply, their habitat or their breeding site or a plant, seed, soil, area, material or environment on which pests grow or can grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from pest attack or infestation with a pesticide-effective amount of a pyradazine compound of formulas I or II according to the present invention or a salt or an N-oxide thereof.

[015] A further aspect of the present invention relates to a method for protecting plant propagating material and / or plants growing from it, the method of which comprises treating plant propagating material with an effective amount as a pesticide. a pyradazine compound of formulas I or II according to the present invention, or an agriculturally acceptable salt or an N-oxide thereof.

[016] A further aspect of the present invention relates to the plant propagating material, which comprises at least one compound of the formulas I or II according to the present invention and / or an agriculturally acceptable salt or an N-oxide thereof.

[017] An additional aspect of the present invention relates to a method for treating or protecting an animal from infestation or infection by parasites especially ectoparasites which comprises placing the animal in contact with a parasiticidal effective amount of a compound of formulas I or II of according to the present invention or a veterinarily acceptable salt or an N-oxide thereof. To put the animal in contact with the compound I or II, its salt or the veterinary composition of the invention means to apply or administer it to the animal.

[018] An additional aspect of the present invention relates to an agricultural composition that contains at least one compound of the formulas I or II according to the present invention and / or an agriculturally acceptable salt or an N-oxide thereof and at least one liquid or solid carrier.

[019] The radicals attached to the main chain of the compounds of formulas I or II may contain one or more centers of chirality. In this case, the compounds of formulas I or II are present in the form of different enantiomers or diastereoisomers, depending on the substituents. The compounds of formula II additionally exist as cis or trans isomers with respect to the N = C axis. The present invention relates to each possible stereoisomer of the compounds of formulas I or II, that is, for single enantiomers or diastereoisomers, as well as for mixtures thereof.

[020] The compounds of formulas I or II may be amorphous or may exist in one or more different crystalline states (polymorphs) that may have different macroscopic properties as stability or show different biological properties as activities. The present invention relates to amorphous and crystalline compounds of formulas I or II, mixtures of different crystalline states of the respective compound I or II, as well as amorphous or crystalline salts thereof.

[021] The salts of the compounds of formulas I or II are preferably agricultural and veterinarily acceptable salts. They can be formed in a customary manner, for example, by reacting the compound with an acid from the anion in question if the compound of formulas I or II has basic functionality.

[022] The agriculturally useful salts of the compounds of formulas I and II especially cover the acid addition salts of those acids whose cations and anions, respectively, have no adverse effect on the pesticidal action of the compounds of formulas I or II.

[023] Useful acid addition salt anions are primarily chloride, bromide, fluoride, hydrosulfate, sulfate, dihydrophosphate, hydrophosphate, phosphate, nitrate, bicarbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate, and C1-acid anions -alkanoic, preferably format, acetate, propionate and butyrate. They can be formed by reacting the compounds of formulas I and II with a corresponding anion acid, preferably hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid or nitric acid.

[024] The veterinarily acceptable salts of the compounds of formulas I and II especially cover acid addition salts which are known and accepted in the art for the formation of salts for veterinary use. Suitable acid addition salts, for example, formed by compounds of formulas I or II that contain a basic nitrogen atom, for example, an amino group, which includes salts with inorganic acids, for example, hydrochloric, sulfates, phosphates, and nitrates and salts of organic acids, for example, acetic acid, maleic acid, for example, the monoacid salts or diacid salts of maleic acid, dimaleic acid, fumaric acid, for example, the monoacid salts or diacid salts of fumaric acid, acid difumaric acid, methane sulfenic acid, methane sulfonic acid, and succinic acid.

[025] The term "N-oxide" includes any compound of formulas I or II that has at least one tertiary nitrogen atom that is oxidized to a chemical portion of N-oxide.

[026] The term "invertebrate pest" as used in this invention covers animal populations, such as insects, arachnids and nematodes, which can attack plants thereby causing substantial damage to the attacked plants, as well as ectoparasites that can infest animals, in particular blood animals hot, such as mammals or birds, or other animals such as reptiles, amphibians or fish, thereby causing substantial damage to infested animals.

[027] The term "plant propagation material" as used in this invention includes all plant-generating parts such as seeds and plant vegetative material such as seedlings and tubers (eg potatoes), which can be used for plant multiplication . This includes seeds, roots, fruits, tuberosities, bulbs, rhizomes, seedlings, shoots and other parts of plants. Seedlings and young plants, which must be transplanted after germination or after emergence from the soil, can also be included. These plant propagation materials can be treated prophylactically with a plant protective compound during or before planting or transplanting.

[028] The term "plants" includes any type of plant that includes "uncultivated plants" and in particular "cultivated plants".

[029] The term "uncultivated plants" refers to any species of wild type or related species or related genera of a cultivated plant.

[030] The term "cultivated plants" as used in this invention includes plants that have been modified by reproduction, mutagenesis or genetic engineering. Genetically modified plants are plants, whose genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances it cannot readily be obtained by cross-breeding, mutation or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant to improve certain properties of the plant. Such genetic modifications also include, but are not limited to, targeted post-transitional modification of poly protein (s) (oligo- or polypeptides), for example, by glycosylation or polymer additions such as prenylated, acetylated or farnesyl chemical moieties or chemical moieties PEG (for example, as revealed in Biotechnol Prog. 2001 Jul-Aug; 17 (4): 720-8., Protein Eng Des Sel. 2004 Jan; 17 (1): 57 to 66, Nat. Protoc. 2007; 2 (5): 1225-35., Curr. Opin. Chem. Biol. 2006 Oct; 10 (5): 487-91. Epub 2006 Aug 28., Biomaterials. 2001 Mar; 22 (5): 405-17, Bioconjug Chem. 2005 Jan-Feb; 16 (1): 113-21).

[031] The term "cultivated plants" as used in this invention further includes plants that have been made tolerant to applications of specific classes of herbicides, such as hydroxy-phenylpyruvate dioxigenase (HPPD) inhibitors; acetolactate synthase (ALS) inhibitors, such as sulfonyl ureas (see eg US 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98/02526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073) or imidazolinones (see, for example, US 6,222,100, WO 01/82685, WO 00/26390, WO 97 / 41218, WO 98/02526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073); enolpyruvylchiquimate-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate (see, for example, WO 92/00377); glutamine synthase (GS) inhibitors, such as glufosinate (see, for example, EP-A-0242236, EP-A-242246) or oxyinyl herbicides (see, for example, US 5,559,024) as a result of conventional methods of breeding or genetic engineering. Several cultivated plants have been made tolerant to herbicides by conventional methods of reproduction (mutagenesis), for example Clearfield® summer rape (Canola) being tolerant to imidazolinones, for example, imazamox. Genetic engineering methods have been used to make cultivated plants, such as soybeans, cotton, corn, beets and rapeseed, herbicide-tolerant, such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady® (glyphosate) and LibertyLink® (glufosinate).

[032] The term "cultivated plants" as used in this invention further includes plants that are by the use of recombinant DNA techniques capable of synthesizing one or more insecticidal proteins, especially those known from the bacterial genus bacillus, particularly bacillus thuringiensis, such as- endotoxins, for example, CryIA (b), CryIA (c), CrylF, CryIF (a2), CryIIA (b), CryIIIA, CryIIIB (b1) or Cry9c; vegetative insecticidal proteins (VIP), for example, VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins from bacteria colonizing nematodes, for example Photorhabdus spp. or Xenorhabdus spp .; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; toxins produced by fungi, such as Streptomycetes toxins, plant lecithins, such as pea or barley lecithin; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; ribosome inactivating proteins (RIP), such as ricin, more RIP, abrina, lufina, saporina or briodina; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase; ion channel blockers, such as sodium or calcium channel blockers; juvenile hormone esterase; diuretic hormone receptors (helicokinin receptors); stylben synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention, these proteins, insecticides or toxins should also be expressly understood as pre-toxins, hybrid proteins, truncated or modified proteins. Hybrid proteins are characterized by a new combination of protein domains (see, for example WO 02/015701). Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, for example, in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/018810 and WO 03/052073. Methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. These insecticidal proteins contained in genetically modified plants provide the plants that produce these proteins protection against harmful pests from certain taxonomic groups of arthropod insects, particularly for beetles (Coleoptera), flies (Diptera), and butterflies and moths (Lepidoptera) and for plant parasitic nematodes (Nematoda).

[033] The term "cultivated plants" as used in this invention further includes plants that are, by the use of recombinant DNA techniques, capable of synthesizing one or more proteins to increase the resistance or tolerance of such plants to bacterial, viral or fungal pathogens . Examples of such proteins are the so-called "pathogenesis-related proteins" (PR proteins, see, for example, EP-A 0 392 225), genes for resistance to plant disease (for example potato cultivars, which express resistance genes that act against Phytophthora infestans derived from Mexican wild potato Solanum bulbocastanum) or T4-lysozyme (for example, potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylvora). Methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above.

[034] The term "cultivated plants" as used in this invention further includes plants that are, through the use of recombinant DNA techniques, capable of synthesizing one or more proteins to increase productivity (for example, biomass production, grain yield, starch content, oil content or protein content), drought tolerance, salinity or other growth limiting environmental factors or tolerance to fungal, bacterial or viral pests and pathogens of these plants.

[035] The term "cultivated plants" as used in this invention further includes plants containing, by the use of recombinant DNA techniques, a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, for example , oil crops that produce long-chain healthy omega-3 fatty acids or unsaturated omega-9 fatty acids (eg Nexera® rapeseed).

[036] The term "cultivated plants" as used in this invention further includes plants that contain, by the use of recombinant DNA techniques, a modified quantity of substances of content or new substances of content, specifically to improve production of raw material, for example for example, potatoes that produce increased amounts of amylopectin (for example, Amflora® potatoes).

[037] The organic chemical portions mentioned in the definitions above the variables are - like the term halogen - collective terms for individual listings of individual group members. The prefix Cn-Cm indicates in each case the possible number of carbon atoms in the group.

[038] The term halogen denotes in each case fluorine, bromine, chlorine or iodine, in particular fluorine, chlorine or bromine.

[039] The term "alkyl" as used in this invention and in the chemical portions of alkoxy, alkylcarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl and alkoxyalkyl denotes in each case a straight or branched alkyl group that generally has from 1 to 10 carbon atoms, often from 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms, and in particular from 1 to 3 carbon atoms. Examples of an alkyl group are methyl, ethyl, n-propyl, iso-propyl, n-butyl, 2-butyl, iso-butyl, tert-butyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1, 2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2- trimethylpropyl, 1-ethyl-1-methylpropyl, 1-ethyl-2-methylpropyl, n-heptyl, 1-methylhexyl, 2-methylhexyl, 3-methylhexyl, 4-methylhexyl, 5-methylhexyl, 1-ethylpentyl, 2-ethylpentyl, 3-ethylpentyl, 1-propylpentyl, n-octyl, 1-methyloctyl, 2-methylheptyl, 1-ethylhexyl, 2-ethylhexyl, 1,2-dimethylhexyl, 1-propylpentyl and 2-propylpentyl.

[040] The term "alkylene" (or alkanediyl) as used in this invention in each case denotes an alkyl radical as defined above, in which a hydrogen atom at any position in the main carbon chain is replaced by an additional attachment point, soon forming a divalent chemical portion.

[041] The term "haloalkyl" as used in this invention and in the chemical moieties of haloalkoxy haloalkyl, haloalkylthio, haloalkylcarbonyl, haloalkylsulfonyl and haloalkylsulfinyl, denotes in each case a straight or branched alkyl group that generally has from 1 to 10 carbon atoms, often from 1 to 6 carbon atoms, in which the group's hydrogen atoms are partially or completely replaced with halogen atoms. Preferred haloalkyl chemical moieties are selected from C1-C4 haloalkyl, more preferably from C1-C2 haloalkyl in particular from C1-C2 fluoroalkyl such as fluoromethyl, difluoromethyl, trifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2 , 2-difluoroethyl, 2,2,2-trifluoroethyl, pentafluoroethyl and the like.

[042] The term "alkoxy" as used in this invention denotes in each case a straight or branched alkyl group that is attached by an oxygen atom and generally has from 1 to 10 carbon atoms, often from 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms. Examples of an alkoxy group are methoxy, ethoxy, n-propoxy, iso-propoxy, n-butyloxy, 2-butyloxy, iso-butyloxy, tert-butyloxy, and the like.

[043] The term "haloalkoxy" as used in this invention denotes in each case a straight-chain or branched alkoxy group having from 1 to 10 carbon atoms, often from 1 to 4 carbon atoms, preferably 1 to 3 carbon atoms, in which the hydrogen atoms of this group are partially or completely replaced with halogen atoms, in particular fluorine atoms. Preferred chemical moieties of haloalkoxy include C1-C4 haloalkoxy, in particular C1-C2 fluoroalkoxy, such as fluoromethoxy, difluoromethoxy, trifluoromethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoro chloro-2-fluoroetóxi, 2-chloro-2,2-difluoro-etóxi, 2,2-dichloro-2-fluoretóxi, 2,2,2-trichloroethoxy, pentafluoroetóxi and the like.

[044] The term "cycloalkyl" as used in this invention and in the chemical portions of cycloalkyl of cycloalkoxy and cycloalkylmethyl denotes in each case a mono or bicyclic cycloaliphatic radical that generally has from 3 to 10 carbon atoms or 3 to 6 atoms of carbon, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, bicycles [2.1.1] hexyl, bicycles [3.1.1] heptila, bicycles [2.2.1] heptila, and bicycles [2.2.2] octyl.

[045] The term "halocycloalkyl" as used in this invention and in the chemical moieties of halocycloalkyl of halocycloalkylmethyl denotes in each case a mono or bicyclic cycloaliphatic radical that generally has from 3 to 10 carbon atoms or 3 to 6 carbon atoms, wherein at least one, for example, 1, 2, 3, 4 or 5 of the hydrogen atoms is replaced by halogen, in particular fluorine or chlorine. Examples are 1- and 2-fluorocyclopropyl, 1,2-, 2,2- and 2,3-difluorocyclopropyl, 1,2,2-trifluorocyclopropyl, 2,2,3,3-tetrafluorocyclopropyl, 1- and 2-chlorocyclopropyl, 1,2-, 2,2- and 2,3-dichlorocyclopropyl, 1,2,2-trichlorocyclopropyl, 2,2,3,3-tetrachlorocyclopropyl, 1-, 2- and 3-fluorocyclopentyl, 1,2-, 2 , 2-, 2,3-, 3,3-, 3,4-, 2,5- difluorocyclopentyl, 1-, 2- and 3-chlorocyclopentyl, 1,2-, 2,2-, 2,3-, 3,3-, 3,4-, 2,5- dichlorocyclopentyl and the like.

[046] The term "alkenyl" as used in this invention denotes in each case a solely unsaturated hydrocarbon radical which generally has 2 to 10, preferably 2 to 4 carbon atoms, for example, vinyl, ally (2-propen-1-yl ), 1-propen-1-yl, 2-propen-2-yl, methyl (2-methylprop-2-en-1-yl), 2-buten-1-yl, 3-buten-1-yl, 2 -penten-1-yl, 3-penten-1-yl, 4-penten-1-yl, 1-methylbut-2-en-1-yl, 2-ethylprop-2-en-1-yl and the like.

[047] The term "alkynyl" as used in this invention denotes in each case a solely unsaturated hydrocarbon radical which generally has 2 to 10, preferably 2 to 4 carbon atoms, for example, ethynyl, propargyl (2-propin-1-yl ), 1-propin-1-yl, 1-methylprop-2-in-1-yl), 2-butin-1-yl, 3-butin-1-yl, 1-pentin-1-yl, 3-pentin -1-yl, 4-pentin-1-yl, 1-methylbut-2-in-1-yl, 1-ethylprop-2-in-1-yl and the like.

[048] The term "alkoxyalkyl" as used in this invention refers to alkyl generally comprising 1 to 4 carbon atoms, wherein 1 carbon atom carries an alkoxy radical generally comprising 1 to 10, in particular 1 to 4, carbon atoms carbon as defined above. Examples are CH2OCH3, CH2-OC2H5, n-propoxymethyl, CH2-OCH (CH3) 2, n-butoxymethyl, (1-methylpropoxy) -methyl, (2-methylpropoxy) methyl, CH2-OC (CH3) 3, 2- ( methoxy) ethyl, 2- (ethoxy) ethyl, 2- (n-propoxy) -ethyl, 2- (1-methylethoxy) -ethyl, 2- (n-butoxy) ethyl, 2- (1-methylpropoxy) -ethyl, 2- (2-methylpropoxy) -ethyl, 2- (1,1-dimethylethoxy) -ethyl, 2- (methoxy) -propyl, 2- (ethoxy) -propyl, 2- (n-propoxy) -propyl, 2- (1-methylethoxy) -propyl, 2- (n-butoxy) -propyl, 2- (1-methylpropoxy) -propyl, 2- (2-methylpropoxy) -propyl, 2- (1,1-dimethyloxy) -propyl, 3- (methoxy) -propyl, 3- (ethoxy) -propyl, 3- (n-propoxy) -propyl, 3- (1-methylethoxy) -propyl, 3- (n-butoxy) -propyl, 3- (1 -methylpropoxy) -propyl, 3- (2-methylpropoxy) -propyl, 3- (1,1-dimethylethoxy) -propyl, 2- (methoxy) -butyl, 2- (ethoxy) - butyl, 2- (n-propoxy ) -butyl, 2- (1-methylethoxy) -butyl, 2- (n-butoxy) -butyl, 2- (1-methylpropoxy) -butyl, 2- (2-methyl-propoxy) -butyl, 2- (1 , 1-dimethylethoxy) -butyl, 3- (methoxy) -butyl, 3- (ethoxy) -butyl, 3- (n-propoxy) -butyl, 3- (1-methylethoxy) -butyl, 3- (n - butoxy) -butyl, 3- (1-methylpropoxy) -butyl, 3- (2-methylpropoxy) -butyl, 3- (1,1-dimethylethoxy) -butyl, 4- (methoxy) -butyl, 4- (ethoxy ) -butyl, 4- (n-propoxy) -butyl, 4- (1-methylethoxy) -butyl, 4- (n-butoxy) -butyl, 4- (1-methylpropoxy) -butyl, 4- (2- methylpropoxy ) -butyl, 4- (1,1-dimethylethoxy) -butyl and the like.

[049] The term "alkylcarbonyl" (C-alkyl (= O) -), as used in this invention refers to a saturated straight or branched alkyl group as defined above comprising 1 to 10 carbon atoms (= C1 alkylcarbonyl) -C10), preferably 1 to 4 carbon atoms (= C 1 -C 4 alkyl carbonyl) bonded through the carbon atom of the carbonyl group at any position in the alkyl group.

[050] The term "haloalkylcarbonyl" as used in this invention refers to an alkylcarbonyl group as defined above in which the hydrogen atoms are partially or completely replaced by fluorine, chlorine, bromine and / or iodine.

[051] The term "alkylthio" (also alkylsulfanyl or S-alkyl) as used in this invention refers to a saturated straight or branched alkyl group comprising 1 to 10 carbon atoms (= C1- C10 alkylthio), preferably 1 to 4 carbon atoms (= C1-C4 alkylthio) as defined above, which is attached by a sulfur atom at any position in the alkyl group.

[052] The term "haloalkylthio" as used in this invention refers to an alkylthio group as defined above in which the hydrogen atoms are partially or completely replaced by fluorine, chlorine, bromine and / or iodine.

[053] The term "alkylsulfinyl" (also alkylsulfoxyl or S-alkyl (= O) -), as used in this invention refers to a saturated straight or branched alkyl group as defined above comprising 1 to 10 carbon atoms ( = C1-C10 alkylsulfinyl), preferably 1 to 4 carbon atoms (= C1-C4 alkylsulfinyl) attached through the sulfinyl group sulfur atom at any position in the alkyl group.

[054] The term "haloalkylsulfinyl" as used in this invention refers to an alkylsulfinyl group as defined above in which the hydrogen atoms are partially or completely replaced by fluorine, chlorine, bromine and / or iodine.

[055] The term "alkylsulfonyl" (also S-alkyl (= O) 2-) as used in this invention refers to a saturated straight or branched alkyl group comprising 1 to 10 carbon atoms (= C1-C10 alkylsulfonyl ), preferably 1 to 4 carbon atoms (= C1-C4 alkylsulfonyl), as defined above, which is attached by the sulfon atom of the sulfonyl group at any position in the alkyl group.

[056] The term "haloalkylsulfonyl" as used in this invention refers to an alkylsulfonyl group as defined above in which the hydrogen atoms are partially or completely replaced by fluorine, chlorine, bromine and / or iodine.

[057] The term "heterocyclyl" generally includes 5, 6, 7 or 8 membered monocyclic heterocyclic radicals and 8 to 10 membered bicyclic heterocyclic radicals, mono and bicyclic radicals can be saturated, partially unsaturated or unsaturated. Mono and bicyclic heterocyclic radicals generally comprise 1, 2, 3 or 4 heteroatoms selected from N, O and S as ring members.

[058] Examples of 5- or 6-membered saturated or unsaturated heterocyclic radicals include saturated or unsaturated non-aromatic heterocyclic rings, such as pyrrolidinyl, pyrazolinyl, imidazolinyl, pyrrolinyl, pyrazolinyl, imidazolinyl, tetrahydrofuranyl, dihydrofuranyl, 1,3-dioxolol thiolanil, dihydrothienyl, oxazolidinyl, isoxazolidinyl, oxazolinyl, isoxazolinyl, thiazolinyl, isothiazolinyl, thiazolidinyl, isothiazolidinyl, oxathiolanyl, piperidinyl, piperazinyl, pyranyl, pyrazolidinyl, dihydropyranyl, dihydropyranyl, 1,4 , morpholinyl, thiazinyl and the like. Examples for heterocyclic ring which also comprise 1 or 2 carbonyl groups as ring members comprise pyrrolidin-2-onyl, pyrrolidin-2,5-dionyl, imidazolidin-2-onyl, oxazolidin-2-onyl, thiazolidin-2-onyl and the like .

[059] The term "hetaryl" includes 5- or 6-membered monocyclic heteroaromatic radicals comprising ring members 1, 2, 3 or 4 heteroatoms selected from N, O and S. Examples of 5- or 6-membered heteroaromatic radicals include pyridyl, that is, 2-, 3-, or 4-pyridyl, pyrimidinyl, that is, 2-, 4- or 5-pyrimidinyl, pyrazinyl, pyridazinyl, that is, 3- or 4-pyridazinyl, thienyl, that is , 2- or 3-thienyl, furyl, that is, 2-or 3-furyl, pyrrolyl, that is, 2- or 3-pyrrolyl, oxazolyl, that is, 2-, 3- or 5-oxazolyl, isoxazolyl, or that is, 3-, 4- or 5-isoxazolyl, thiazolyl, that is, 2-, 3- or 5-thiazolyl, isothiazolyl, that is, 3-, 4- or 5- isothiazolyl, pyrazolyl, that is, 1-, 3-, 4- or 5-pyrazolyl, i.e. 1-, 2-, 4- or 5-imidazolyl, oxadiazolyl, for example 2- or 5- [1,3,4] oxadiazolyl, 4- or 5- (1,2,3-oxadiazole) ila, 3- or 5- (1,2,4-oxadiazole) ila, 2- or 5- (1,3,4-thiadiazole) ila, thiadiazolyl, for example 2- or 5- (1,3,4-thiadiazole) ila, 4- or 5- (1,2,3-thiadia zol) ila, 3- or 5- (1,2,4-thiadiazole) ila, triazolyl, for example, 1 H-, 2H- or 3H-1,2,3-triazol-4-yl, 2H-triazole- 3-yl, 1H-, 2H-, or 4H-1,2,4-triazolyl and tetrazolyl, i.e., 1H- or 2H-tetrazolyl.

[060] The term "hetaryl" also includes 8 to 10-membered bicyclic heteroaromatic radicals that comprise ring members 1, 2 or 3 heteroatoms selected from N, O and S, in which a 5- or 6-membered heteroaromatic ring it is fused to a phenyl ring or to a 5- or 6-membered heteroaromatic radical. Examples of a 5- or 6-membered heteroaromatic ring fused to a phenyl or 5- or 6-membered heteroaromatic radical include benzofuranyl, benzothienyl, indolyl, indazolyl, benzimidazolyl, benzoxathiazolyl, benzoxadiazolyl, benzothiadiazolyl, benzoxazinyl, quinolinyl, 1,8-naphthyridyl, pteridyl, pyrido [3,2-d] pyrimidyl or pyridoimidazolyl and the like. These fused hetaryl radicals can be attached to the rest of the molecule by any 5- or 6-membered heteroaromatic ring atom or by a carbon atom of the fused phenyl chemical moiety.

[061] The terms "phenylalkyl" and "phenoxyalkyl" refer to phenyl or phenoxy, respectively, which are linked by an alkyl group, in particular a methyl group (= hetarylmethyl), to the rest of the molecule, examples including benzyl, 1 -phenylethyl, 2-phenylethyl, 2-phenoxyethyl and the like.

[062] The terms "heterocyclylalkyl" and "hetarylalkyl" refer to heterocyclyl or hetaryl, respectively, as defined above which are linked by an alkyl group, in particular a methyl group (= heterocyclylmethyl or hetylmethyl, respectively), to the rest of the molecule .

[063] The comments made below for preferred realizations of the variables of the compounds of the formulas I or II are valid on their own as well as - preferably - in combination with each other. The comments made below with respect to the additional preferred embodiments of the variables are valid with respect to the compounds of the formulas I or II as well as with respect to the uses and methods according to the invention and the composition according to the present invention.

[064] A first preferred embodiment of the invention relates to the pyradazine compounds of formula I, their salts and their N-oxides.

[065] Among the compounds of formula I, preference is given to those compounds, where X1 is oxygen. These compounds are hereinafter also referred to as compounds of the formula I '.

[066] Among the compounds of formula I, preference is also given to those compounds, in which R1 is hydrogen, CN, C1-C10 alkyl, C1-C10 haloalkyl, C2-C10 alkenyl, C2-C10 haloalkenyl, C2-C10 alkynyl, C1-C10 alkoxy-C1-C4 alkyl, C1-C4-CN alkylene, ORa, C (Y) Rb, C (Y) ORc or S (O) 2Rd. Preferably, R1 is hydrogen, C1-C10 alkyl, C1-C10 haloalkyl, C1-C4-CN alkylene, C1-C5-ORa alkylene, C1-C5 heteroaryl, C1-C5 heterocyclyl or C3-C10- cycloalkyl C1-C5 alkyl. More preferably R1 is hydrogen, C1-C4 alkyl, C1-C4 haloalkyl or C1-C4-alkoxy-C1-C4-alkyl. In particular R1 is hydrogen or C1-C3 alkyl.

[067] Another embodiment of the invention relates to the pyradazine compounds of formula II, their salts and N-oxides and the methods and uses of such compounds. In compounds of formula II, preference is given to those compounds, where X2 in formula II is OR2a or SR2a. In these compounds, R2a is preferably C1-C6 alkyl, C3-C6 alkenyl, C3-C6 alkynyl, C3-C6 cycloalkylmethyl or C1-C4-C1-C10-alkoxy.

[068] Another embodiment of the invention relates to the compounds of the formula II, where X2 is NR2bR2c. In these compounds R2b and Rc are preferably selected, independently of each other, from C1-C6 alkyl, C3-C6 cycloalkylmethyl or C1-C4-alkoxy-C1-C10-alkyl or R2b and R2c, together with the nitrogen atom at which these are linked to, form a 5- or 6-membered nitrogen-saturated heterocycle that can comprise an additional heteroatom selected from O, S and N, for example NR2bR2c being 1-pyrrolidinyl, 1-piperidinyl, 1-piperazinyl , 4-morpholinyl or 4-thiomorpholinyl.

[069] Among the compounds of formulas I and II, preference is given to those compounds, in which Ru is selected from hydrogen, halogen, C1-C4 alkyl, C1-C3 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl and C1-C4-alkoxy-C1-C4 alkoxy.

[070] Among the compounds of formulas I and II, preference is given to those compounds, in which Rt is selected from hydrogen, halogen, C1-C4 alkyl, C1-C3 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkenyl, C2-C4 alkynyl and C1-C4-C1-C4-alkoxy.

em que A, X1, X2, R1, Rt, Ru e Rw independentemente uns dos outros são conforme definidos na presente invenção.[071] Among the compounds of formulas I and II, preference is given in addition to those compounds selected from compounds substituted by 4-pyridazine of formulas IA or II.A

wherein A, X1, X2, R1, Rt, Ru and Rw independently of each other are as defined in the present invention.

[072] Among the compounds of formulas I and II, preference is given in addition to those compounds, where W is CRw with Rw being hydrogen, that is, W is CH.

em que A, X1, X2, R1, Rt, Ru e Rw independentemente a partir de cada um são como definidos nesta invenção.[073] Among the compounds of formulas I and II, preference is still given to those compounds selected from substituted 4-pyridazine compounds of formulas IB or II.B

wherein A, X1, X2, R1, Rt, Ru and Rw independently from each other are as defined in this invention.

[074] Among the compounds of formulas I and II, preference is still given to those compounds, where V is CRv with Rv being hydrogen, that is, V is CH.

[075] Among the compounds of formulas I and II, preference is still given to those compounds, in which Rt, Ru and Rv, if present, are selected independently of each other from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy or trifluoromethoxy. More preferably, preference is given to those compounds, in which at least two of the radicals Rt, Ru, Rv or Rw, if present, are hydrogen.

[076] Even more particularly, preference is given to those compounds, in which Rt, Ru, Rv and Rw, if present, are hydrogen.

[077] Another preferred embodiment of the invention relates to the pyridazine compounds of formulas I and II, their salts and N-oxides and the methods and uses of such compounds, where A is an A1 radical. Among the compounds, where A is A1, preference is given to compounds of the formula I, where X1, R1, Rt, Ru, Rv and Rw are as defined above and in particular have one of the preferred meanings.

[078] Among the compounds of formulas I and II, where A is A1, preference is given to those compounds, in which R41 is selected from hydrogen, halogen, CN, C1-C4 alkyl and C2-C10 alkenyl, in whereas the last two radicals mentioned may be unsubstituted, may be partially or entirely halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hethyl, phenyl and phenoxy, in which the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, haloalkoxy C1-C4, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl or where R41 is additionally selected from C3-C6 cycloalkyl, C5-C6 hetaryl and phenyl, where the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or different substituents cated from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[079] Preferably, R41 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where the phenyl may be unsubstituted or may bear 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C- alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. Preferably R41 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. Most preferably R41 is selected from hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. Most preferably R41 is selected from hydrogen, C1-C3 alkyl, C1-C3 haloalkyl and C3-C5 cycloalkyl. Even more preferably R41 is hydrogen or C1-C3 alkyl. In particular, R41 is hydrogen.

[080] Among the compounds of formulas I and II, where A is A1, preference is given in addition to those compounds, in which R51 is selected from hydrogen, halogen, CN, C1-C10 alkyl and C2-C10 alkenyl, wherein the last 2 radicals mentioned may be unsubstituted, may be partially or entirely halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hethyl , phenyl and phenoxy, in which the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl or where R51 is additionally selected from C3-C6 cycloalkyl, C5-C6 hetaryl and phenyl, where the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or di substituents ferents selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[081] Preferably, R51 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where the phenyl may be unsubstituted or may bear 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. Preferably R51 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. Most preferably R51 is selected from hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. Most preferably R51 is selected from hydrogen, C1-C3 alkyl, C1-C3 haloalkyl and C3-C5 cycloalkyl. Even more preferably R51 is hydrogen or C1-C3 alkyl. In particular, R51 is hydrogen.

[082] Among the compounds of formulas I and II, where A is A1, preference is still given to those compounds, where n R61, if present, is selected from hydrogen, C1-C10-alkyl and C2-C10 -alkenyl, in which the last two radicals mentioned may be unsubstituted, may be partially or totally halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3- cycloalkyl C6, hetaryl, phenyl and phenoxy, in which the last three radicals mentioned can be unsubstituted or can carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1 alkoxy - C4, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl, or where R61, if present, is further selected from C3-C6 cycloalkyl, C5-C6 hethyl and phenyl, where the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 3 identical substituents or differ selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[083] Preferably, R61 is selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6-cycloalkyl-C1-C4, heterocyclyl-C1-C4-alkyl, C1-C4-alkoxy C1-C4-alkyl and C1-C4-alkyl-CN. Preferably, R61 is selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where phenyl can be unsubstituted or can carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. More preferably, R61, if present, is hydrogen, C1-C4 alkyl or C1-C4 haloalkyl. In particular, R61, if present, is hydrogen or C1-C3 alkyl.

TABELA A

[084] Examples of suitable radicals A1 are the radicals of formulas A1.a, A1.b, A1.c, A1.d, A1.e, A1.f, A1.g, A1.h, A1.i, A1.k, A1.l, A1.m, A1.n, A1.o, A1.p, A1.q, A1.r, A1.s, A1.t, A1.u, A1.v, A1. w, A1.x, A1.y and A1.z, where Z is O and R51, R 41 is a radical as defined in a row in table A. (radicals A1.a1 - A1.a81 to A1.z1 - A1 .z81):

TABLE A

[085] Analogous to the structures listed above, examples of suitable radicals A1 are the radicals of formulas A1.a ', A1.b', A1.c ', A1.d', A1.e ', A1.f', A1.g ', A1.h', A1.i ', A1.k', A1.l ', A1.m', A1.n ', A1.o', A1.p ', A1.q', A1.r ', A1.s', A1.t', A1.u ', A1.v', A1.w ', A1.x', A1.y 'and A1.z', where Z is S and R51, R 41 is a radical as defined in a row in table A (radicals A1.a'1 - A1.a'81 to A1.z'1 - A1.z'81).

[086] Analogous to the structures listed above, examples of suitable radicals A1 are the radicals of formulas A1.a '', A1.b '', A1.c '', A1.d '', A1.e '', A1.f '', A1.g '', A1.h '', A1.i '', A1.k '', A1.l '', A1.m '', A1.n '', A1. o '', A1.p '', A1.q '', A1.r '', A1.s'',A1.t'',A1.u'',A1.v'',A1.w'',A1.x'',A1.y''andA1.z'', where Z is N, R51 is H, and R61 is a radical as defined in a row in table A (radicals A1.a''1 - A1.a''81 to A1.z''1 - A1.z''81). An additional example of radical A1 is

[087] A further embodiment of the invention relates to the pyridazine compounds of formulas I and II, their salts and N-oxides and the methods and uses of such compounds, where A is an A2 radical. Among the compounds of formulas I and II, where A is an A2 radical, preference is given to compounds of formulas I or II, where X1, R1, Rt, Ru, Rv and Rw are as defined above and in particular have one of the preferred meanings.

[088] Among the compounds of formulas I and II, in which A is A2, preference is given to those compounds, in which R42 is selected from hydrogen, halogen, CN, C1-C4 alkyl and C2-C10 alkenyl, in that the last 2 radicals mentioned may be unsubstituted, may be partially or entirely halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hethyl, phenyl and phenoxy, in which the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, haloalkoxy C1-C4, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl or where R42 is additionally selected from C3-C6 cycloalkyl, C5-C6 hetaryl and phenyl, where the last three radicals mentioned may be unsubstituted or may carry 1 , 2, 3, 4 or 5 identical or different substituents selected linked from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[089] Among the compounds of formulas I and II, in which A is A2, preference is given to those compounds, in which R42 is selected from hydrogen, halogen, CN, C1-C3 alkyl and C2-C3 alkenyl, in that the last 2 radicals mentioned may be unsubstituted, may be partially or entirely halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C3 alkoxy, C1-C3 haloalkoxy, C3-C6 cycloalkyl, C5 heteroaryl -C6, phenyl and phenoxy, in which the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C3 alkyl, C1-C3 haloalkyl, C1- alkoxy C3, C1-C3 haloalkoxy, C1-C3 alkylsulfonyl and C1-C3 haloalkylsulfonyl, or where R42 is additionally selected from C3-C6 cycloalkyl, C5-C6 hethyl and phenyl, where the last three radicals mentioned may be unsubstituted or they can carry 1, 2, 3, 4 or 5 identical or different substituents They are selected from halogen, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylsulfonyl and C1-C3 haloalkylsulfonyl. Most preferably R42 is selected from hydrogen, halogen, CN, C1-C3 alkyl, C1-C3 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, in which the phenyl can be unsubstituted or can carry 1, 2 , 3, 4 or 5 radicals selected from halogen, C1-C3 alkyl, C1-C3 haloalkyl, C1-C3 alkoxy and C1-C3 haloalkoxy; in particular, R42 is selected from hydrogen, halogen, CN, C1-C3 alkyl, C1-C3 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl.

[090] Preferably, R42 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where the phenyl may be unsubstituted or may bear 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. Preferably R42 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1- C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. Most preferably R42 is selected from hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. Most preferably R42 is selected from hydrogen, C1-C3 alkyl, C1-C3 haloalkyl and C3-C5 cycloalkyl. Even more preferably R42 is hydrogen or C1-C3 alkyl. In particular, R42 is hydrogen.

[091] Among the compounds of formulas I and II, where A is A2, preference is given in addition to those compounds, in which R52 is selected from hydrogen, halogen, CN, C1-C10 alkyl and C2-C10 alkenyl, wherein the last two radicals mentioned may be unsubstituted, may be partially or entirely halogenated, or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hetaryl , phenyl and phenoxy, in which the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl, or where R52 is additionally selected from C3-C6 cycloalkyl, C5-C6 hetaryl and phenyl, where the last three radicals mentioned may be unsubstituted or may bear 1, 2, 3, 4 or 5 identical substituents or different selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C- alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[092] Preferably, R52 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where the phenyl may be unsubstituted or may bear 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. Preferably, R52 is selected from hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. Most preferably R52 is hydrogen, C1-C4 alkyl or C1-C4 haloalkyl. Even more preferably R52 is hydrogen or C1-C3 alkyl. In particular R52 is hydrogen.

[093] Among the compounds of formulas I and II, in which A is A2, preference is still given to those compounds, in which R62, if present, is selected from hydrogen, C1-C10-alkyl and C2-C10-alkenyl , in which the last two radicals mentioned may be unsubstituted, may be partially or totally halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hetaryl, phenyl and phenoxy, in which the last three radicals mentioned can be unsubstituted or can carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy , C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl, or where R62 is present is further selected from C3-C6 cycloalkyl, C5-C6 hethyl and phenyl, where the last three radicals mentioned may not be substituted or may carry 1, 2, 3, 4 or 5 identical or different substituents cated from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[094] Preferably, R62 is selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, heterocyclyl-C1-C4-alkyl, C1-C4-alkoxy C1-C4-alkyl and C1-C4-alkyl-CN. Preferably, R62 if present is selected from hydrogen, C1-C4 alkyl, C1- C haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where phenyl can be unsubstituted or can carry 1, 2, 3 , 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. More preferably, R62 if present is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. In particular, R62 if present is hydrogen.

[095] Examples of suitable radicals A2 are the radicals of the formulas A2.aa, A2.ab, A2.ac, A2.ad, A2.ae, A2.af, A2.ag, A2.ah, A2.ai, A2.ak, A2.al, A2.am, A2.an and A2.ao, where Z is O and R52 is a radical as defined in a row in table A (radicals A2.aa1 - A2.aa81 to A2. ao1 - A2.ao81):

[096] Similar to the structures listed above, examples of suitable radicals A2 are the radicals of formulas A2.aa ', A2.ab', A2.ac ', A2.ad', A2.ae ', A2.af', A2.ag ', A2.ah', A2.ai ', A2.ak', A2.al ', A2.am', A2.an 'and A2.ao', where Z is S and R52 is a radical as defined in a row in table A (radicals A2.aa'1 - A2.aa'81 to A2.ao'1 - A2.ao'81).

[097] Analogous to the structures listed above, examples of suitable radicals A2 are the radicals of the formulas A2.aa '', A2.ab ', A2.ac'',A2.ad'',A2.ae'', A2 .af '', A2.ag '', A2.ah '', A2.ai '', A2.ak '', A2.al '', A2.am '', A2.an '' and A2.ao '', where Z is S and R52 is a radical as defined in a row in table A (radicals A2.aa''1 - A2.aa''81 to A2.ao''1 - A2.ao''81 ).

[098] Other examples of suitable A2 radicals are the radicals of the formulas A2.ba, A2.bb, A2.bc, A2.bd, A2.ser, A2.bf, A2.bg, A2.bh, A2.bi, A2.bk, A2.bl, A2.bm, A2.bn and A2.bo, where Z is N, R62 is CH3 and R52 is as defined in a row in table A (radicals A2.ba1 - A2.ba81 a A2.bo1 - A2.bo81):

[099] Other examples of suitable A2 radicals are the radicals of the formulas A2.ca, A2.cb, A2.cc, A2.cd, A2.ce, A2.cf, A2.cg, A2.ch, A2.ci, A2.ck, A2.cl, A2.cm, A2.cn and A2.co, where Z is N, R62 is CHF2 and R52 is as defined in a row in table A (radicals A2.ca1 - A2.ca81 a A2.co1 - A2.co81):

[100] Additional examples of suitable A2 radicals are the radicals of the formulas A2.da, A2.db, A2.dc, A2.dd, A2.de, A2.df, A2.dg, A2.dh, A2.di , A2.dk, A2.dl, A2.dm, A2.dn and A2.do, where Z is N, R62 is CF3 and R52 is as defined in a row in table A (radicals A2.da1 - A2.da81 a A2.do1

[101] Additional examples of suitable radicals A2 are the radicals of formulas A2.ea, A2.fa, A2.ga, A2.ha, where Z is N and R52 is as defined in a row in table A (A2 radicals .ea1 - A2.ea81, A2.fa1 - A2.fa81,

[102] A further embodiment of the invention relates to the pyridazine compounds of formulas I and II, their salts and N-oxides and the methods and uses of such compounds, where A is an A3 radical. Among the compounds of formulas I and II, in which A is an A3 radical, preference is given to compounds of formulas I or II, in which X1, R1, Rt, Ru, Rv and Rw are as defined above and in particular have one of the preferred meanings.

[103] Among the compounds of formulas I and II, where A is A3, preference is given to those compounds, where R43 is selected from hydrogen, halogen, CN, C1-C4 alkyl and C2-C10 alkenyl, where The last 2 radicals mentioned may be unsubstituted, may be partially or entirely halogenated, or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hetaryl, phenyl and phenoxy, wherein the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1 alkylsulfonyl -C4 and C1-C4 haloalkylsulfonyl, or where R43 is additionally selected from C3-C6 cycloalkyl, C5-C6 hetaryl and phenyl, where the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or different substituents selected from halo genius, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[104] Preferably, R43 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where the phenyl can be unsubstituted or can carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. More preferably, R43 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. More preferably, R43 is selected from hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 halocycloalkyl and C3-C6 cycloalkyl. More preferably, R43 is selected from hydrogen, C1-C3 alkyl, C1-C3 haloalkyl and C3-C5 cycloalkyl. Even more preferably, R43 is hydrogen or C1-C3 alkyl. In particular, R43 is hydrogen.

[105] Among the compounds of formulas I and II, where A is A3, preference is given in addition to those compounds, where n R53 is selected from hydrogen, halogen, CN, C1-C10 alkyl and C2-C10 alkenyl, in that the last 2 radicals mentioned may be unsubstituted, may be partially or entirely halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hethyl, phenyl and phenoxy, in which the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl, or where R53 is additionally selected from C3-C6 cycloalkyl, C5-C6 hetaryl and phenyl, where the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or different substituents selected halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[106] Preferably R53 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, in which the phenyl can be unsubstituted or can carry 1, 2 , 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. Preferably, R53 is selected from hydrogen, halogen, CN, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. More preferably, R53 is selected from hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. More preferably, R53 is selected from hydrogen, C1-C3 alkyl, C1-C3 haloalkyl and C3-C5 cycloalkyl. Even more preferably, R53 is hydrogen or C1-C3 alkyl. In particular, R53 is hydrogen.

[107] Among the compounds of formulas I and II, where A is A3, preference is given in addition to those compounds, where R63, if present, is selected from hydrogen, C1-C10 alkyl and C2-C10 alkenyl, where the last two radicals mentioned may be unsubstituted, may be partially or entirely halogenated or may carry 1, 2 or 3 identical or different substituents selected from C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, hethyl, phenyl and phenoxy , in which the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, alkylsulfonyl C1-C4 and C1-C4 haloalkylsulfonyl or where R63, if present, is additionally selected from C3-C6 cycloalkyl, C5-C6 hetaryl and phenyl, where the last three radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical substituents or differs selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylsulfonyl and C1-C4 haloalkylsulfonyl.

[108] Preferably, R63 is selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6-cycloalkyl-C1-C4, heterocyclyl-C1-C4-alkyl, C1-C4-alkyl-C1-alkoxy -C4 and C1-C4-alkyl-CN. Preferably, R63, if present, is selected from hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl and phenyl, where the phenyl can be unsubstituted or can carry 1, 2, 3 , 4 or 5 radicals selected from halogen, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy. More preferably, R63, if present, is hydrogen, C1-C4 alkyl or C1-C4 haloalkyl. In particular, R63, if present, is hydrogen or C1-C3 alkyl.

[109] Examples of suitable radicals A3 are radicals of formulas A3.aa, A3.ab, A3.ac, A3.ad, A3.ae, A3.af, A3.ag, A3.ah, A3.ai, A3.ak, A3.al, A3.am, A3.an and A3.ao, where Z is O and R53 is a radical as defined in a row in table A (radicals A3.aa1 - A3.aa81

[110] Similar to the structures listed above, examples of suitable radicals A3 are the radicals of the formulas A3.aa ', A3.ab', A3.ac ', A3.ad', A3.ae ', A3.af', A3.ag ', A3.ah', A3.ai ', A3.ak', A3.al ', A3.am', A3.an 'and A3.ao', where Z is S and R53 is a radical as defined on a row in the

[111] Additional examples of suitable radicals A3 are the radicals of the formulas A3.aa '', A3.ab '', A3.ac '', A3.ad '', A3.ae '', A3.af '' , A3.ag '', A3.ah '', A3.ak '', A3.al '', A3.am '', A3.an '' and A3.a '', where Z is N, R53 is H and R63 is a radical as defined in a row in table A (radicals A3.aa''1 -

[112] Additional examples of suitable radicals A3 are the radicals of the formulas A3.ba, A3.bb, A3.bc, A3.bd, A3.be, A3.bf, A3.bg, A3.bh, A3.bi , A3.bk, A3.bl, A3.bm, A3.bn and A3.bo, where Z is N, R53 is Cl and R63 is a radical as defined in a row of table A (radicals A3.ba1 - A3 .ba81 to A3.bo1 - A3.bo81):

[113] Additional examples of suitable radicals A3 are the radicals of formulas A3.ca, A3.cb, A3.cc, A3.cd, A3.ce, A3.cf, A3.cg, A3.ch, A3.ci , A3.ck, A3.cl, A3.cm, A3.cn and A3.co, where R53 is a radical as defined in a row of table A (radicals A3.ca1 - A3.ca81 to A3.co1 -

[114] Additional examples of suitable radicals A3 are the radicals of formulas A3.da, A3.db, A3.dc, A3.dd, A3.de, A3.df, A3.dg, A3.dh, A3.di , A3.dk, A3.dl, A3.dm, A3.dn and A3.do, where Z is N, R63 is CH3 and R53 is a radical as defined in a row of table A (radicals A3.da1 - A3 .da81

[115] Additional examples of suitable radicals A3 are the radicals of the formulas A3.ea, A3.eb, A3.ec, A3.ed, A3.ee, A3.ef, A3.eg, A3.eh, A3.ei , A3.ek, A3.el, A3.em, A3.en and A3.eo, where Z is N, R63 is CHF2 and R53 is a radical as defined in a row in table A (radicals A3.ea1 - A3 .ea81 to A3.eo1 - A3.eo81):

[116] Additional examples of suitable radicals A3 are the radicals of the formulas A3.fa, A3.fb, A3.fc, A3.fd, A3.fe, A3.ff, A3.fg, A3.fh, A3.fi , A3.fk, A3.fl, A3.fm, A3.fn and A3.fo, where Z is N, R63 is CF3 and R53 is a radical as defined in a row of table A (radicals A3.fa1 - A3 .fa81 to A3.fo1 - A3.fo81):

[117] Additional examples of suitable radicals A3 are the radicals of formulas A3. & 1, A3. & 2, A3.3 where Z is N, R63 is cH2cF3 and R53 is cH3, cF3 and cHF2 respectively:

[118] A very preferred embodiment of the invention relates to the compounds of the formula I and the salts and N-oxides thereof, where X1 is O. These compounds are hereinafter also referred to as compounds I '.

[119] In formula I ', the variables A, R1, Rt, Ru, V and W are as defined in the present invention.

[120] Among the compounds of formula I ', preference is given to those compounds, in which at least one of the radicals R1, Rt, Ru, V and W, preferably at least two of the radicals R1, Rt, Ru, V and W and more preferably, all radicals R1, Rt, Ru, V and W have one of the preferred meanings.

[121] Among the compounds of formula I ', preference is given in addition to those compounds, where A is an A1 radical, for example, a radical, selected from the oxazole radicals A1.a1 to A1.z81.

[122] Among the compounds of formula I ', preference is given in addition to those compounds, where A is an A1 radical, for example, a radical, selected from the thiazole radicals A1.a'1 to A1.z’81.

[123] Among the compounds of the formula I ', preference is given in addition to those compounds, where A is an A1 radical, for example, a radical, selected from the imidazole radicals A1.a''1 to A1.z' ' 81.

A é um radical A1, conforme definido na presente invenção, em particular um radical A1, em que R41, R51 têm os significados preferenciais, em particular, o radical anoxazol das fórmulas A1.a a A1.z, por exemplo um radical selecionado dentre os radicais oxazol A1.a1 a A1.z81; R1 é hidrogênio, alquila C1-C4 ou alcóxi-C1-C4-alquila-C1-C2, mais preferencialmente, hidrogênio, metil ou etil; R1 é ainda mais preferencialmente propila, isopropila, butila, iso- butila, terc-butila, CH2C(CH3)3, CH2CH=CH, CH2CH=CCl2, CH2CH=CBr2, CH2CH2F, CH2CH2Cl, CH2CH2Br, CH2CHF2, CH2CHCl2, CH2CHBr2, CH2CF3, CH2CN, CH2OCH3, CH2OCH2CH3, CH2CH2CN, CH2CHCN2, CH2CH2OCH3, CH2CH2OCH2CH3, etil-ciclopropano, etil-ciclo butano, 2-metil-oxetano, 3-etil- oxetano, 3-metil-tietano, 3-metil-tietano 1,1-dióxido, etil-ciclopentano, 2-etil- tetraidro-furano, 3-etil-tetraidro-furano, metil-ciclopropano, metil-ciclobutano, 2- metil-oxetano, 3-metil-oxetano, 3-metil-tetano, 3-tietano 1,1-dióxido, ciclopentano, 2-metil-tetraidro-furano, tetraidro-furano, tolueno, 2-metil-furano, 3- metil-furano, 2-etil-tiofeno, 3-metil-tiofeno, 5-etil-isotiazol, 4-etil-isotiazol, 3-metil- isotiazol, 3-metil-isoxazol, 5-metil-oxazol, 2-etil-oxazol, 5-etil-tiazol, 2-etil-tiazol, 4-etil-tiazol, 5-metil-1H-pirazol, 4-etil-1H-pirazol, 3-metil-1H-pirazol, 5-etil-1- metil-1H-pirazol, 4-etil-1-metil-1H-pirazol, 3-etil-1-metil-1H-pirazol, 5-metil-1H- imidazol, 4-etil-1H-imidazol, 2-metil-1H-imidazol, 5-etil-1-metil-1H-imidazol, 2- etil-1-metil-1H-imidazol, 1,4-dimetil-1H-imidazol, 2-metil-4,5-diidro-oxazol, 2-etil- 4,5-diidro-tiazol, 2-etil-4,5-diidro-1H-imidazol, 2-etil-1-metil-4,5-diidro-1H- imidazol; Rt, Ru, e Rw são independentemente um do outro selecionados dentre hidrogênio, metila, difluorometila, trifluorometila, metóxi, difluorometóxi e trifluorometóxi; e em que preferencialmente pelo menos um, mais preferencialmente, 2 ou 3 dos radicais Rt, Ru, e Rw são hidrogênio.[124] A particularly preferred embodiment of the invention relates to the compounds of the formula I'.A and their salts and N-oxides, where

A is an A1 radical as defined in the present invention, in particular an A1 radical, in which R41, R51 have the preferred meanings, in particular, the anoxazole radical of formulas A1.a to A1.z, for example a radical selected from among oxazole radicals A1.a1 to A1.z81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkoxy, more preferably, hydrogen, methyl or ethyl; R1 is even more preferably propyl, isopropyl, butyl, iso-butyl, tert-butyl, CH2C (CH3) 3, CH2CH = CH, CH2CH = CCl2, CH2CH = CBr2, CH2CH2F, CH2CH2Cl, CH2CH2Br, CH2CHF2, CH2CHCl2, CH2CHF2 , CH2CN, CH2OCH3, CH2OCH2CH3, CH2CH2CN, CH2CHCN2, CH2CH2OCH3, CH2CH2OCH2CH3, ethyl-cyclopropane, ethyl-cyclo-butane, 2-methyl-oxethane, 3-ethyl-oxethane, 3-methyl-tethane, 3-methyl-ethane -dioxide, ethyl-cyclopentane, 2-ethyl-tetrahydro-furan, 3-ethyl-tetrahydro-furan, methyl-cyclopropane, methyl-cyclobutane, 2-methyl-oxethane, 3-methyl-oxethane, 3-methyl-tetanus, 3 -thiethane 1,1-dioxide, cyclopentane, 2-methyl-tetrahydro-furan, tetrahydro-furan, toluene, 2-methyl-furan, 3-methyl-furan, 2-ethyl-thiophene, 3-methyl-thiophene, 5- ethyl-isothiazole, 4-ethyl-isothiazole, 3-methyl-isothiazole, 3-methyl-isoxazole, 5-methyl-oxazole, 2-ethyl-oxazole, 5-ethyl-thiazole, 2-ethyl-thiazole, 4-ethyl- thiazole, 5-methyl-1H-pyrazole, 4-ethyl-1H-pyrazole, 3-methyl-1H-pyrazole, 5-ethyl-1-methyl-1H-pyrazole, 4-ethyl-1-methyl-1H-pyrazole, 3-ethyl-1-methyl-1H-pyrazole, 5-methyl-1H-imidazole, 4-ethyl-1H-imidazole, 2-methyl-1H-imidazole, 5-ethyl-1-methyl-1H-imidazole, 2-ethyl-1-methyl-1H-imidazole, 1, 4-dimethyl-1H-imidazole, 2-methyl-4,5-dihydro-oxazole, 2-ethyl-4,5-dihydro-thiazole, 2-ethyl-4,5-dihydro-1H-imidazole, 2-ethyl- 1-methyl-4,5-dihydro-1H-imidazole; Rt, Ru, and Rw are independently selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably, 2 or 3 of the radicals Rt, Ru, and Rw are hydrogen.

[125] Examples of compounds of this particularly preferred embodiment are the compounds given in the following tables 1 to 50.

[126] Table 1: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.a1 to A1.a81.

[127] Table 2: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.a1 to A1. a81.

[128] Table 3: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.b1 to A1.b81.

[129] Table 4: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.b1 to A1. b81.

[130] Table 5: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.c1 to A1.c81.

[131] Table 6: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.c1 to A1. c81.

[132] Table 7: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.d1 to A1.d81.

[133] Table 8: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.d1 to A1. d81.

[134] Table 9: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.e1 to A1.e81.

[135] Table 10: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.e1 to A1. e81.

[136] Table 11: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.f1 to A1.f81.

[137] Table 12: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.f1 to A1. f81.

[138] Table 13: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.g1 to A1.g81.

[139] Table 14: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.g1 to A1. g81.

[140] Table 15: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.h1 to A1.h81.

[141] Table 16: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.h1 to A1. h81.

[142] Table 17: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.i1 to A1.i81.

[143] Table 18: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.i1 to A1. i81.

[144] Table 19: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.k1 to A1.k81.

[145] Table 20: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.k1 to A1. k81.

[146] Table 21: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.l1 to A1.l81.

[147] Table 22: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.l1 to A1. l81.

[148] Table 23: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.m1 to A1.m81.

[149] Table 24: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.m1 to A1. m81.

[150] Table 25: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.n1 to A1.n81.

[151] Table 26: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.n1 to A1. n81.

[152] Table 27: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.o1 to A1.o81.

[153] Table 28: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.o1 to A1. o81.

[154] Table 29: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.p1 to A1.p81.

[155] Table 30: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.p1 to A1. p81.

[156] Table 31: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.q1 to A1.q81.

[157] Table 32: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.q1 to A1. q81.

[158] Table 33: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.r1 to A1.r81.

[159] Table 34: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.r1 to A1. r81.

[160] Table 35: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.s1 to A1.s81.

[161] Table 36: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.s1 to A1. s81.

[162] Table 37: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.t1 to A1.t81.

[163] Table 38: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.t1 to A1. t81.

[164] Table 39: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.u1 to A1.u81.

[165] Table 40: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.u1 to A1. u81.

[166] Table 41: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.v1 to A1.v81.

[167] Table 42: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.v1 to A1. v81.

[168] Table 43: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.w1 to A1.w81.

[169] Table 44: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.w1 to A1. w81.

[170] Table 45: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.x1 to A1.x81.

[171] Table 46: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.x1 to A1. x81.

[172] Table 47: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.y1 to A1.y81.

[173] Table 48: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.y1 to A1. y81.

[174] Table 49: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.z1 to A1.z81.

[175] Table 50: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.z1 to A1. z81.

[176] Additional examples of the compounds of this particularly preferred embodiment are compounds in analogy to the compounds listed in table 1 to 50 where R1 is a radical represented by each individual line (85 to 160) in the following table B: TABLE B:

[177] Another particularly preferred embodiment concerns compounds of the formula I'.A and salts and N-oxides thereof, where A is an A1 radical, as defined in the present invention, in particular, an A1 radical, in which R41, R51 have the preferred meanings, in particular, the atiazole radical of formulas A1.a 'to A1.z', for example, a radical selected from the thiazole radicals A1.a'1 to A1.z'81; R1 is hydrogen, C1-C4 or C1-C4-alkoxy-C1-C2-alkyl, more preferably hydrogen, methyl or ethyl; R1 is even more preferably represented by a radical as defined in each row in table B; Rt, Ru, and Rw are, independently of each other, selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably, 2 or 3 of the radicals Rt, Ru, and Rw are hydrogen.

[178] Examples of the compounds of that particularly preferred embodiment are the compounds given in the following tables 51 to 100.

[179] Table 51: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.a'1 to A1. a'81.

[180] Table 52: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.a'1 to A1.a'81.

[181] Table 53: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.b'1 to A1. b'81.

[182] Table 54: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from radicals A1.b'1 a A1.b'81.

[183] Table 55: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.c'1 to A1. c'81.

[184] Table 56: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.c'1 a A1.c'81.

[185] Table 57: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.d'1 to A1. d'81.

[186] Table 58: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.d'1 a A1.d'81.

[187] Table 59: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.e'1 to A1. e'81.

[188] Table 60: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A1.e'1 a A1.e'81.

[189] Table 61: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.f'1 a A1.f'81.

[190] Table 62: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.f ' 1 to A1.f'81.

[191] Table 63: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.g'1 a A1.g'81.

[192] Table 64: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.g ' 1 to A1.g'81.

[193] Table 65: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.h'1 a A1.h'81.

[194] Table 66: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.h ' 1 to A1.h'81.

[195] Table 67: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from radicals A1.i'1 a A1.i'81.

[196] Table 68: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.i ' 1 to A1.i'81.

[197] Table 69: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.k'1 a A1.k'81.

[198] Table 70: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.k ' 1 to A1.k'81.

[199] Table 71: I'.A compounds and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.l'1 a A1.l'81.

[200] Table 72: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.l ' 1 to A1.181.

[201] Table 73: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.m'1 a A1.m'81.

[202] Table 74: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.m ' 1 to A1.m'81.

[203] Table 75: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from radicals A1.n'1 a A1.n'81.

[204] Table 76: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.n ' 1 to A1.n'81.

[205] Table 77: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.o'1 a A1.o'81.

[206] Table 78: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.o ' 1 to A1.o'81.

[207] Table 79: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.p'1 a A1.p'81.

[208] Table 80: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.p ' 1 to A1.p'81.

[209] Table 81: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.q'1 a A1.q'81.

[210] Table 82: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.q ' 1 to A1.q'81.

[211] Table 83: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.r'1 a A1.r'81.

[212] Table 84: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.r ' 1 to A1.r'81.

[213] Table 85: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.s'1 a A1.s'81.

[214] Table 86: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.s' 1 to A1.s'81.

[215] Table 87: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.t'1 a A1.t'81.

[216] Table 88: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.t ' 1 to A1.t'81.

[217] Table 89: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.u'1 a A1.u'81.

[218] Table 90: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.u ' 1 to A1.u'81.

[219] Table 91: I'.A compounds and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.v'1 a A1.v'81.

[220] Table 92: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.v ' 1 to A1.v'81.

[221] Table 93: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.w'1 a A1.w'81.

[222] Table 94: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.w ' 1 to A1.w'81.

[223] Table 95: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and A is selected from radicals A1.x'1 a A1.x'81.

[224] Table 96: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.x ' 1 to A1.x'81.

[225] Table 97: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.y'1 a A1.y'81.

[226] Table 98: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.y ' 1 to A1.y'81.

[227] Table 99: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.z'1 a A1.z'81.

[228] Table 100: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.z ' 1 to A1.z'81.

[229] Other examples of compounds of this particularly preferred embodiment are the compounds in tables 51A to 100A where Rt, Ru and Rv are hydrogen and where A is defined in tables 51 to 100 and where R1 is a radical represented by each line individual (85 to 160) from table B.

[230] Another particular preferred embodiment concerns the compounds of the formula I'.A and their salts and N-oxides,

[231] A is an A1 radical, as defined herein, in particular, an A1 radical, with R41, R51 having the preferred meanings, in particular, an imidazole radical of the formulas A1.a '' to A1.z ' ', for example, a radical selected from the thiazole radicals A1.a''1 to A1.z''81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, most preferably hydrogen, methyl or ethyl; R1 is also, with the utmost preference, represented by a radical as defined in each row of table B; Rt, Ru, and Rw are, independently of each other, selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and, preferably, at least one, more preferably 2 or 3, of the radicals Rt, Ru, and Rw are hydrogen.

[232] Examples of compounds of this particularly preferred embodiment are the compounds given in tables 101 to 150 below:

[233] Table 101: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.a''1 to A1.a''81.

[234] Table 102: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A1.a ' '1 to A1.a''81.

[235] Table 103: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.b''1 to A1.b''81.

[236] Table 104: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A1.b ' '1 to A1.b''81.

[237] Table 105: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.c''1 to A1.c''81.

[238] Table 106: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.c ' '1 to A1.c''81.

[239] Table 107: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.d''1 to A1.d''81.

[240] Table 108: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.d ' '1 to A1.d''81.

[241] Table 109: I'.A compounds and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.e''1 to A1.e''81.

[242] Table 110: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.e ' '1 to A1.e''81.

[243] Table 111: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.f''1 to A1.f''81.

[244] Table 112: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.f ' '1 to A1.f''81.

[245] Table 113: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.g''1 to A1.g''81.

[246] Table 114: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.g ' '1 to A1.g''81.

[247] Table 115: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.h''1 to A1.h''81.

[248] Table 116: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.h ' '1 to A1.h''81.

[249] Table 117: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.i''1 to A1.i''81.

[250] Table 118: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A1.i ' '1 to A1.i''81.

[251] Table 119: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.k''1 to A1.k''81.

[252] Table 120: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.k ' '1 to A1.k''81.

[253] Table 121: I'.A compounds and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.l''1 to A1.l''81.

[254] Table 122: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.l ' '1 to A1.l''81.

[255] Table 123: I'.A compounds and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.m''1 to A1.m''81.

[256] Table 124: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.m ' '1 to A1.m''81.

[257] Table 125: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.n''1 to A1.n''81.

[258] Table 126: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.n ' '1 to A1.n''81.

[259] Table 127: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.o''1 to A1.o''81.

[260] Table 128: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.o ' '1 to A1.o''81.

[261] Table 129: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.p''1 to A1.p''81.

[262] Table 130: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.p ' '1 to A1.p''81.

[263] Table 131: I'.A compounds and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.q''1 to A1.q''81.

[264] Table 132: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.q ' '1 to A1.q''81.

[265] Table 133: I'.A compounds and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.r''1 to A1.r''81.

[266] Table 134: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.r ' '1 to A1.r''81.

[267] Table 135: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.s''1 to A1.s''81.

[268] Table 136: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.s' '1 to A1.s''81.

[269] Table 137: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.t''1 to A1.t''81.

[270] Table 138: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.t ' '1 to A1.t''81.

[271] Table 139: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.u''1 to A1.u''81.

[272] Table 140: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.u ' 1 to A1.u'81.

[273] Table 141: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.v''1 to A1.v''81.

[274] Table 142: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.v ' '1 to A1.v''81.

[275] Table 143: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.w''1 to A1.w''81.

[276] Table 144: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.w ' '1 to A1.w''81.

[277] Table 145: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.x''1 to A1.x''81.

[278] Table 146: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.x ' '1 to A1.x''81.

[279] Table 147: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.y''1 to A1.y''81.

[280] Table 148: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.y ' '1 to A1.y''81.

[281] Table 149: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A1.z''1 to A1.z''81.

[282] Table 150: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A1.z ' '1 to A1.z''81.

[283] Other examples of compounds of this particularly preferred embodiment are the compounds in tables 101A to 150A where Rt, Ru and Rv are hydrogen and A is defined in tables 101 to 126 and R1 is a radical represented by each line individual (85 to 160) from table B.

[284] Another particular preferred embodiment concerns the compounds of the formula I'.A and their salts and N-oxides,

[285] A is an A2 radical as defined herein, in particular an A2 radical, with R42, R52 having the preferred meanings, in particular, an oxazole radical of the formulas A2.aa to A2.do, for example , a radical selected from oxazole radicals A2.aa1 -A2.aa81 to A2.do1 to A2.do81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, most preferably hydrogen, methyl or ethyl; R1 is also, with the utmost preference, represented by a radical as defined in each row of table B; Rt, Ru and Rw are selected, independently of each other, from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and, preferably, at least one, more preferably, two or three of the radicals Rt, Ru and Rw are hydrogen.

[286] Examples of compounds from this particular preferred embodiment are the compounds given in the following tables 151 to 176.

[287] Table 151: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.aa1 to A2. aa81.

[288] Table 152: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.aa1 to A2.aa81.

[289] Table 153: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.ab1 to A2. ab81.

[290] Table 154: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A2.ab1 a A2.ab81.

[291] Table 155: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.ac1 to A2. ac81.

[292] Table 156: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.ac1 to A2.ac81.

[293] Table 157: Compounds of the formula I'.A and their salts and N-oxides, where R1, R2 and R3 are hydrogen and A is selected from radicals A2.ad1 to A2.ad81.

[294] Table 158: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.ad1 to A2.ad81.

[295] Table 159: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.ae1 to A2. ae81.

[296] Table 160: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.ae1 to A2.ae81.

[297] Table 161: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.af1 to A2. af81.

[298] Table 162: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A2.af1 a A2.af81.

[299] Table 163: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.ag1 to A2. ag81.

[300] Table 164: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A2.ag1 a A2.ag81.

[301] Table 165: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and A is selected from the radicals A2.ai1 to A2. ai81.

[302] Table 166: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.ai1 to A2.ai81.

[303] Table 167: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.ak1 to A2. ak81.

[304] Table 168: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A2.ak1 to A2.ak81.

[305] Table 169: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.al1 to A2. al81.

[306] Table 170: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A2.al1 to A2.al81.

[307] Table 171: Compounds of the formula I'.A and their salts and N-oxides, with R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.am1 to A2. am81.

[308] Table 172: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from the radicals A2.am1 a A2.am81.

[309] Table 173: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.an1 to A2. an81.

[310] Table 174: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.an1 a A2.an81.

[311] Table 175: Compounds of the formula I'.A and their salts and N-oxides, R1, Rt, Ru and Rw being hydrogen and A being selected from the radicals A2.ao1 to A2. ao81.

[312] Table 176: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and A is selected from radicals A2.ao1 to A2.ao81.

[313] Examples of additional compounds from this particularly preferred embodiment are compounds from tables 151A to 176A, where Rt, Ru and Rv are hydrogen and where A is as defined in tables 153 to 180 and where R1 is a radical represented by each individual line (from 85 to 160) in table B.

[314] Another particular preferred embodiment relates to compounds of the formula I'.A and the salts and N-oxides thereof, where

[315] A is an A2 radical, as defined in this document, in particular an A2 radical, in which R42, R52 have the preferred means, in particular a thiazole radical of the formula A2.aa 'to A2.do', for example , a radical selected from thiazole radicals A2.aa '1 - A2.aa' 81 to A2.do '1 to A2.do' 81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, most preferably hydrogen, methyl or ethyl; R1 is, most preferably, represented by a radical as defined in each row of table B; Rt, Ru and Rw are, independently of each other, selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein, preferably, at least one, more preferably, two or three of the radicals Rt, Ru and Rw are hydrogen.

[316] Examples of compounds of that particular preferred embodiment are the compounds given in the following tables 177 to 202.

[317] Table 177: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.aa '1 to A2 .aa '81.

[318] Table 178: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.aa '1 to A2.aa '81.

[319] Table 179: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ab '1 to A2 .ab '81.

[320] Table 180: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ab '1 to A2.ab '81.

[321] Table 181: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ac '1 to A2 .ac '81.

[322] Table 182: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ac '1 A2.ac '81.

[323] Table 183: Compounds of the formula I'.A and their salts and N-oxides, where R1, R2 and R3 are hydrogen and where A is selected from the radicals A2.ad '1 to A2.ad '81.

[324] Table 184: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ad '1 to A2.ad '81.

[325] Table 185: Compounds of the formula I'.A and their salts and N-oxides, in which R1, Rt, Ru and Rw are hydrogen and in which A is selected from the radicals A2.a and 1 to A2 .ae '81.

[326] Table 186: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ae '1 to A2.ae '81.

[327] Table 187: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.af '1 to A2 .af '81.

[328] Table 188: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.af '1 to A2.af '81.

[329] Table 189: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ag '1 to A2 .ag '81.

[330] Table 190: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ag '1 to A2.ag '81.

[331] Table 191: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ai '1 to A2 .ai '81.

[332] Table 192: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ai '1 to A2.ai '81.

[333] Table 193: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ak '1 to A2 .ak '81.

[334] Table 194: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ak '1 A2.ak '81.

[335] Table 195: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.al '1 to A2 .al '81.

[336] Table 196: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.al '1 to A2.al '81.

[337] Table 197: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.am '1 to A2 .am '81.

[338] Table 198: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.am '1 to A2.am '81.

[339] Table 199: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.an '1 to A2 .an '81.

[340] Table 200: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.an '1 to A2.an '81.

[341] Table 201: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ao '1 to A2 .to '81.

[342] Table 202: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ao '1 to A2 'to 81.

[343] Additional examples of compounds of this particularly preferred embodiment are compounds from tables 177A to 202A, where Rt, Ru and Rv are hydrogen and where A is as defined in tables 176 to 202 and where R1 is a radical represented by each individual line (from 85 to 160) in table B.

[344] Another particularly preferred embodiment concerns compounds of the formula I'.A and the salts and N-oxides thereof, where A is an A2 radical, as defined in this document, in particular an A2 radical, in which R42, R52, R63 have the preferred means, in particular, an imidazole radical of the formula A2.aa '' to A2.do, for example, a radical selected from the imidazole radicals A2.aa '' 1 - A2.aa '' 81 to A2.do1 to A2.do81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, most preferably hydrogen, methyl or ethyl; R1 is, most preferably, represented by a radical as defined in each row of table B; Rt, Ru and Rw are, independently of each other, selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein, preferably, at least one, more preferably, two or three of the radicals Rt, Ru and Rw are hydrogen.

[345] Examples of compounds of this particular preferred embodiment are the compounds given in the following tables from 203 to 313.

[346] Table 203: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.aa '' 1 a A2.aa '' 81.

[347] Table 204: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.aa '' 1 to A2.aa '' 81.

[348] Table 205: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ab '' 1 a A2.ab '' 81.

[349] Table 206: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ab '' 1 to A2.ab '' 81.

[350] Table 207: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ac '' 1 to A2.ac '' 81.

[351] Table 208: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ac '' 1 to A2.ac '' 81.

[352] Table 209: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, R2 and R3 are hydrogen and where A is selected from the radicals A2.ad '' 1 to A2. ad '' 81.

[353] Table 210: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ad '' 1 to A2.ad '' 81.

[354] Table 211: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ae '' 1 a A2.ae '' 81.

[355] Table 212: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ae '' 1 to A2.ae '' 81.

[356] Table 213: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.af '' 1 a A2.af ''81.

[357] Table 214: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.af '' 1 to A2.af '' 81.

[358] Table 215: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ag '' 1 a A2.ag '' 81.

[359] Table 216: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ag '' 1 to A2.ag '' 81.

[360] Table 217: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ai '' 1 a A2.ai '' 81.

[361] Table 218: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ai '' 1 to A2.ai '' 81.

[362] Table 219: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ak''1 to A2.ak''81.

[363] Table 220: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ak '' 1 to A2.ak '' 81.

[364] Table 221: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.al '' 1 a A2.al '' 81.

[365] Table 222: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.al '' 1 to A2.al '' 81.

[366] Table 223: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.am '' 1 a A2.am '' 81.

[367] Table 224: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.am '' 1 to A2.am '' 81.

[368] Table 225: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.an '' 1 a A2.an '' 81.

[369] Table 226: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.an '' 1 to A2.an '' 81.

[370] Table 227: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ao '' 1 a A2.ao '' 81.

[371] Table 228: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ao '' 1 to A2. '' 81.

[372] Table 229: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ba1 to A2.ba81 .

[373] Table 230: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ba1 to A2 .ba81.

[374] Table 231: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bb1 to A2.bb81 .

[375] Table 232: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw 3 are hydrogen and where A is selected from the radicals A2.bb1 to A2.bb81.

[376] Table 233: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bc1 to A2.bc81 .

[377] Table 234: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bc1 to A2 .bc81.

[378] Table 235: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bd1 to A2.bd81 .

[379] Table 236: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bd1 to A2 .bd81.

[380] Table 237: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.be1 to A2.be81 .

[381] Table 238: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.be1 to A2 .be81.

[382] Table 239: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bf1 to A2.bf81 .

[383] Table 240: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bf1 to A2 .bf81.

[384] Table 241: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bg1 to A2.bg81 .

[385] Table 242: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bg1 to A2 .bg81.

[386] Table 243: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bi1 to A2.bi81 .

[387] Table 244: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bi1 to A2 .bi81.

[388] Table 245: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bk1 to A2.bk81 .

[389] Table 246: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bk1 to A2 .bk81.

[390] Table 247: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bl1 to A2.bl81 .

[391] Table 248: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bl1 to A2 .bl81.

[392] Table 249: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bm1 to A2.bm81 .

[393] Table 250: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bm1 to A2 .bm81.

[394] Table 251: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bn1 to A2.bn81 .

[395] Table 252: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bn1 to A2 .bn81.

[396] Table 253: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bo1 to A2.bo81 .

[397] Table 254: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.bo1 to A2 .bo81.

[398] Table 255: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ca1 to A2.ca81 .

[399] Table 256: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ca1 to A2 .ca81.

[400] Table 257: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cb1 to A2.cb81 .

[401] Table 258: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cb1 to A2 .cb81.

[402] Table 259: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cc1 to A2.cc81 .

[403] Table 260: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cc1 to A2 .cc81.

[404] Table 261: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cd1 to A2.cd81 .

[405] Table 262: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cd1 to A2 .cd81.

[406] Table 263: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ce1 to A2.ce81 .

[407] Table 264: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.c1 to A2 .ce81.

[408] Table 265: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cf1 to A2.cf81 .

[409] Table 266: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cf1 to A2 .cf81.

[410] Table 267: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cg1 to A2.cg81 .

[411] Table 268: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cg1 to A2 .cg81.

[412] Table 269: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ci1 to A2.ci81 .

[413] Table 270: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ci1 to A2 .ci81.

[414] Table 271: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ck1 to A2.ck81 .

[415] Table 272: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ck1 to A2 .ck81.

[416] Table 273: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cl1 to A2.cl81 .

[417] Table 274: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cl1 to A2 .cl81.

[418] Table 275: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cm1 to A2.cm81 .

[419] Table 276: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cm1 to A2 .cm81.

[420] Table 277: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cn1 to A2.cn81 .

[421] Table 278: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.cn1 to A2 .cn81.

[422] Table 279: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.co1 to A2.co81 .

[423] Table 280: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.co1 to A2 .co81.

[424] Table 281: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.da1 to A2.da81 .

[425] Table 282: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.da1 to A2 .da81.

[426] Table 283: Compounds of the formula I'.A and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.db1 to A2.db81 .

[427] Table 284: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.db1 to A2 .db81.

[428] Table 285: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dc1 to A2.dc81 .

[429] Table 286: I'.A compounds and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dc1 to A2 .dc81.

[430] Table 287: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dd1 to A2.dd81 .

[431] Table 288: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dd1 to A2 .dd81.

[432] Table 289: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.de1 to A2.de81 .

[433] Table 290: Compounds of the formula I'.A and their salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.de1 to A2 .de81.

[434] Table 291: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.df1 to A2.df81 .

[435] Table 292: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.df1 to A2 .df81.

[436] Table 293: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dg1 to A2.dg81 .

[437] Table 294: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dg1 to A2 .dg81.

[438] Table 295: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.di1 to A2.di81 .

[439] Table 296: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.di1 to A2 .di81.

[440] Table 297: Compounds of the formula I'.A and its salts and N-oxides, in which R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dk1 to A2.dk81 .

[441] Table 298: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dk1 to A2 .dk81.

[442] Table 299: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dl1 to A2.dl81 .

[443] Table 300: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dl1 to A2 .dl81.

[444] Table 301: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dm1 to A2.dm81 .

[445] Table 302: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dm1 to A2 .dm81.

[446] Table 303: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dn1 to A2.dn81 .

[447] Table 304: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.dn1 to A2 .dn81.

[448] Table 305: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.do1 to A2.do81 .

[449] Table 306: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.do1 to A2 .do81.

[450] Table 307: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ea1 to A2.ea81 .

[451] Table 308: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ea1 to A2 .ea81.

[452] Table 309: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.fa1 to A2.fa81 .

[453] Table 310: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.fa1 to A2 .fa81.

[454] Table 311: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ga1 to A2.ga81 .

[455] Table 312: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ga1 to A2 .ga81.

[456] Table 313: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A2.ha1 to A2.ha81 .

[457] Additional examples of compounds of this particularly preferred embodiment are the compounds of tables 203A to 313A where Rt, Ru and Rv are hydrogen and where A is as defined in tables 203 to 313 and where R1 is a radical represented by each individual row (85 to 160) from table B.

[458] Another preferred embodiment in particular concerns compounds of the formula I'.A and salts and N-oxides thereof, where A is an A3 radical, as defined herein, in particular an A3 radical in which R43 , R53 have the preferred meanings, more particularly an oxazole radical of the formulas A3.aa to A3.do, for example, a radical selected from the oxazole radicals A3.aa1 - A3.aa81 to A3.do1 - A3.do81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, most preferably hydrogen, methyl or ethyl; R1 is also represented with the utmost preference for a radical as defined in each row of table B; Rt, Ru and Rw are selected independently of each other from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably 2 or 3, of the radicals Rt, Ru and Rw are hydrogen.

[459] Examples of compounds of this particular preferred embodiment are the compounds given in the tables below 314 to 341.

[460] Table 314: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.aa1 to A3.aa81 .

[461] Table 315: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.aa1 to A3 .aa81.

[462] Table 316: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ab1 to A3.ab81 .

[463] Table 317: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ab1 to A3 .ab81.

[464] Table 318: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ac1 to A3.ac81 .

[465] Table 319: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ac1 to A3 .ac81.

[466] Table 320: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ad1 to A3.ad81 .

[467] Table 321: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ad1 to A3 .ad81.

[468] Table 322: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ae1 to A3.ae81 .

[469] Table 323: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ae1 to A3 .ae81.

[470] Table 324: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.af1 to A3.af81 .

[471] Table 325: I'.A compounds and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.af1 to A3 .af81.

[472] Table 326: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ag1 to A3.ag81 .

[473] Table 327: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ag1 to A3 .ag81.

[474] Table 328: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ah1 to A3.ah81 .

[475] Table 329: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ah1 to A3 .ah81.

[476] Table 330: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ai1 to A3.ai81 .

[477] Table 331: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ai1 to A3 .ai81.

[478] Table 332: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ak1 to A3.ak81 .

[479] Table 333: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ak1 to A3 .ak81.

[480] Table 334: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.al1 to A3.al81 .

[481] Table 335: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.al1 to A3 .al81.

[482] Table 336: I'.A compounds and their salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.am1 to A3.am81 .

[483] Table 337: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.am1 to A3 .am81.

[484] Table 338: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.an1 to A3.an81 .

[485] Table 339: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.an1 to A3 .an81.

[486] Table 340: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ao1 to A3.ao81 .

[487] Table 341: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ao1 to A3 .ao81.

[488] Additional examples of compounds of this particularly preferred embodiment are the compounds of tables 314A to 341A where Rt, Ru and Rv are hydrogen and where A is as defined in tables 314 to 341 and where R1 is a radical represented by each individual row (85 to 160) from table B.

[489] Another preferred embodiment in particular concerns compounds of the formula I'.A and salts and N-oxides thereof, where A is an A3 radical, as defined herein, in particular an A3 radical in which R43 , R53 have the preferred meanings, more particularly a thiazole radical of the formulas A3.aa 'to A3.do', for example, a radical selected from the thiazole radicals A3.aa'1 - A3.aa'81 to A3.do'1 - A3.do'81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, most preferably hydrogen, methyl or ethyl; R1 is also represented with the utmost preference for a radical as defined in each row of table B; Rt, Ru and Rw are selected independently of each other from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably 2 or 3, of the radicals Rt, Ru and Rw are hydrogen.

[490] Examples of compounds of this particular preferred embodiment are the compounds given in the tables below 342 to 369.

[491] Table 342: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.aa'1 to A3 .aa'81.

[492] Table 343: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.aa'1 to A3.aa'81.

[493] Table 344: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ab'1 to A3 .ab'81.

[494] Table 345: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ab'1 to A3.ab'81.

[495] Table 346: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ac'1 to A3 .ac'81.

[496] Table 347: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ac'1 to A3.ac'81.

[497] Table 348: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ad'1 to A3 .ad'81.

[498] Table 349: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ad'1 to A3.ad'81.

[499] Table 350: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ae'1 to A3 .ae'81.

[500] Table 351: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ae'1 to A3.ae'81.

[501] Table 352: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.af'1 to A3 .af'81.

[502] Table 353: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.af'1 to A3.af'81.

[503] Table 354: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ag'1 to A3 .ag'81.

[504] Table 355: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ag'1 to A3.ag'81.

[505] Table 356: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ah'1 to A3 .ah'81.

[506] Table 357: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ah'1 to A3.ah'81.

[507] Table 358: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ai'1 to A3 .ai'81.

[508] Table 359: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ai'1 to A3.ai'81.

[509] Table 360: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ak'1 to A3 .ak'81.

[510] Table 361: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ak'1 to A3.ak'81.

[511] Table 362: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.al'1 to A3 .al'81.

[512] Table 363: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.al'1 to A3.al'81.

[513] Table 364: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.am'1 to A3 .am'81.

[514] Table 365: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.am'1 to A3.am'81.

[515] Table 366: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.an'1 to A3 .an'81.

[516] Table 367: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.an'1 to A3.an'81.

[517] Table 368: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ao'1 to A3 .ao'81.

[518] Table 369: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ao'1 to A3.ao'81.

[519] Additional examples of compounds of this particularly preferred embodiment are the compounds of tables 342A to 369A where Rt, Ru and Rv are hydrogen and where A is as defined in tables 342 to 369 and where R1 is a radical represented by each individual row (85 to 160) from table B.

[520] Another preferred embodiment in particular concerns compounds of the formula I'.A and the salts and N-oxides thereof, where A is an A3 radical, as defined herein, in particular an A3 radical in which R43 , R53 have the preferred meanings, more particularly an imidazole radical of the formulas A3.aa '' to A3.fo, for example, a radical selected from the thiazole radicals A3.aa''1 - A3.aa''81 to A3.fo1 - A3.fo81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, most preferably hydrogen, methyl or ethyl; R1 is also represented with the utmost preference for a radical as defined in each row of table B; Rt, Ru and Rw are selected independently of each other from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably 2 or 3, of the radicals Rt, Ru and Rw are hydrogen.

[521] Examples of compounds of this particular preferred embodiment are the compounds given in the following tables from 370 to 537.

[522] Table 370: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.aa''1 a A3.aa''81.

[523] Table 371: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.aa '' 1 to A3.aa''81.

[524] Table 372: Compounds of the formula I'.A and its salts and N-oxides, in which R1, Rt, Ru and Rw are hydrogen and in which A is selected from the radicals A3.ab''1 a A3.ab''81.

[525] Table 373: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ab '' 1 to A3.ab''81.

[526] Table 374: Compounds of the formula I'.A and its salts and N-oxides, in which R1, Rt, Ru and Rw are hydrogen and in which A is selected from the radicals A3.ac''1 a A3.ac''81.

[527] Table 375: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ac '' 1 to A3.ac''81.

[528] Table 376: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ad''1 a A3.ad''81.

[529] Table 377: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ad '' 1 to A3.ad''81.

[530] Table 378: Compounds of the formula I'.A and its salts and N-oxides, in which R1, Rt, Ru and Rw are hydrogen and in which A is selected from the radicals A3.ae''1 a A3.ae''81.

[531] Table 379: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ae '' 1 to A3.ae''81.

[532] Table 380: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.af''1 a A3.af''81.

[533] Table 381: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.af '' 1 to A3.af''81.

[534] Table 382: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ag''1 a A3.ag''81.

[535] Table 383: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ag '' 1 to A3.ag''81.

[536] Table 384: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ah''1 a A3.ah''81.

[537] Table 385: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ah '' 1 to A3.ah''81.

[538] Table 386: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ai''1 a A3.ai''81.

[539] Table 387: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ai '' 1 to A3.ai''81.

[540] Table 388: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ak''1 a A3.ak''81.

[541] Table 389: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ak '' 1 to A3.ak''81.

[542] Table 390: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.al''1 a A3.al''81.

[543] Table 391: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.al '' 1 to A3.al''81.

[544] Table 392: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.am''1 a A3.am''81.

[545] Table 393: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.am '' 1 to A3.am''81.

[546] Table 394: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.an''1 a A3.an''81.

[547] Table 395: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.an '' 1 to A3.an''81.

[548] Table 396: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ao''1 a A3.ao''81.

[549] Table 397: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ao '' 1 to A3.ao''81.

[550] Table 398: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ba1 to A3.ba81 .

[551] Table 399: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ba1 to A3 .ba81.

[552] Table 400: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bb1 to A3.bb81 .

[553] Table 401: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bb1 to A3 .bb81.

[554] Table 402: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bc1 to A3.bc81 .

[555] Table 403: Compounds of the formula I'.A and its salts and N-oxides, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bc1 to A3 .bc81.

[556] Table 404: Compounds of the formula I'.A and its salts and N-oxides, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bd1 to A3.bd81 .

[557] Table 405: I'.A compounds and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bd1 to A3 .bd81.

[558] Table 406: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.be1 to A3.be81 .

[559] Table 407: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.be1 to A3 .be81.

[560] Table 408: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bf1 to A3.bf81 .

[561] Table 409: I'.A compounds and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bf1 to A3 .bf81.

[562] Table 410: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bg1 to A3.bg81 .

[563] Table 411: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bg1 to A3 .bg81.

[564] Table 412: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bh1 to A3.bh81 .

[565] Table 413: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bh1 to A3 .bh81.

[566] Table 414: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bi1 to A3.bi81 .

[567] Table 415: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bi1 to A3 .bi81.

[568] Table 416: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bk1 to A3.bk81 .

[569] Table 417: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bk1 to A3 .bk81.

[570] Table 418: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bl1 to A3.bl81 .

[571] Table 419: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bl1 to A3 .bl81.

[572] Table 420: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bm1 to A3.bm81 .

[573] Table 421: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bm1 to A3 .bm81.

[574] Table 422: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals from A3.bn1 to A3.bn81 .

[575] Table 423: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.bn1 to A3 .bn81.

[576] Table 424: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bo1 to A3.bo81 .

[577] Table 425: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.bo1 to A3 .bo81.

[578] Table 426: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ca1 to A3.ca81 .

[579] Table 427: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ca1 to A3 .ca81.

[580] Table 428: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cb1 to A3.cb81 .

[581] Table 429: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cb1 to A3 .cb81.

[582] Table 430: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cc1 to A3.cc81 .

[583] Table 431: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cc1 to A3 .cc81.

[584] Table 432: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cd1 to A3.cd81 .

[585] Table 433: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cd1 to A3 .cd81.

[586] Table 434: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ce1 to A3.ce81 .

[587] Table 435: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.c1 to A3 .ce81.

[588] Table 436: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cf1 to A3.cf81 .

[589] Table 437: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cf1 to A3 .cf81.

[590] Table 438: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cg1 to A3.cg81 .

[591] Table 439: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cg1 to A3 .cg81.

[592] Table 440: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ch1 to A3.ch81 .

[593] Table 441: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ch1 to A3 .ch81.

[594] Table 442: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ci1 to A3.ci81 .

[595] Table 443: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ci1 to A3 .ci81.

[596] Table 444: I'.A compounds and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ck1 to A3.ck81 .

[597] Table 445: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ck1 to A3 .ck81.

[598] Table 446: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cl1 to A3.cl81 .

[599] Table 447: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cl1 to A3 .cl81.

[600] Table 448: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cm1 to A3.cm81 .

[601] Table 449: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cm1 to A3 .cm81.

[602] Table 450: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cn1 to A3.cn81 .

[603] Table 451: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.cn1 to A3 .cn81.

[604] Table 452: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals from A3.co1 to A3.co81 .

[605] Table 453: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals from A3.co1 to A3 .co81.

[606] Table 454: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.da1 to A3.da81 .

[607] Table 455: I'.A compounds and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.da1 to A3 .da81.

[608] Table 456: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.db1 to A3.db81 .

[609] Table 457: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals from A3.db1 to A3 .db81.

[610] Table 458: I'.A compounds and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dc1 to A3.dc81 .

[611] Table 459: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dc1 to A3 .dc81.

[612] Table 460: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dd1 to A3.dd81 .

[613] Table 461: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dd1 to A3 .dd81.

[614] Table 462: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.de1 to A3.de81 .

[615] Table 463: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.de1 to A3 .de81.

[616] Table 464: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.df1 to A3.df81 .

[617] Table 465: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.df1 to A3 .df81.

[618] Table 466: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dg1 to A3.dg81 .

[619] Table 467: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dg1 to A3 .dg81.

[620] Table 468: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dh1 to A3.dh81 .

[621] Table 469: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dh1 to A3 .dh81.

[622] Table 470: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.di1 to A3.di81 .

[623] Table 471: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.di1 to A3 .di81.

[624] Table 472: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dk1 to A3.dk81 .

[625] Table 473: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dk1 to A3 .dk81.

[626] Table 474: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dl1 to A3.dl81 .

[627] Table 475: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.dl1 to A3 .dl81.

[628] Table 476: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dm1 to A3.dm81 .

[629] Table 477: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dm1 to A3 .dm81.

[630] Table 478: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dn1 to A3.dn81 .

[631] Table 479: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.dn1 to A3 .dn81.

[632] Table 480: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.do1 to A3.do81 .

[633] Table 481: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.do1 to A3 .do81.

[634] Table 482: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ea1 to A3.ea81 .

[635] Table 483: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.ea1 to A3 .ea81.

[636] Table 484: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eb1 to A3.eb81 .

[637] Table 485: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eb1 to A3 .eb81.

[638] Table 486: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ec1 to A3.ec81 .

[639] Table 487: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ec1 to A3 .ec81.

[640] Table 488: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ed1 to A3.ed81 .

[641] Table 489: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ed1 to A3 .ed81.

[642] Table 490: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ee1 to A3.ee81 .

[643] Table 491: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ee1 to A3 .ee81.

[644] Table 492: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ef1 to A3.ef81 .

[645] Table 493: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.ef1 to A3 .ef81.

[646] Table 494: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eg1 to A3.eg81 .

[647] Table 495: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eg1 to A3 .eg81.

[648] Table 496: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eh1 to A3.eh81 .

[649] Table 497: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eh1 to A3 .eh81.

[650] Table 498: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ei1 to A3.ei81 .

[651] Table 499: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ei1 to A3 .ei81.

[652] Table 500: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ek1 to A3.ek81 .

[653] Table 501: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ek1 to A3 .ek81.

[654] Table 502: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.el1 to A3.el81 .

[655] Table 503: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.el1 to A3 .el81.

[656] Table 504: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.em1 to A3.em81 .

[657] Table 505: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.em1 to A3 .in81.

[658] Table 506: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.en1 to A3.en81 .

[659] Table 507: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.en1 to A3 .en81.

[660] Table 508: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eo1 to A3.eo81 .

[661] Table 509: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.eo1 to A3 .eo81.

[662] Table 510: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fa1 to A3.fa81 .

[663] Table 511: I'.A compounds and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fa1 to A3 .fa81.

[664] Table 512: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fb1 to A3.fb81 .

[665] Table 513: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fb1 to A3 .fb81.

[666] Table 514: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fc1 to A3.fc81 .

[667] Table 515: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fc1 to A3 .fc81.

[668] Table 516: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fd1 to A3.fd81 .

[669] Table 517: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, R2 and R3 are hydrogen and where A is selected from the radicals A3.fd1 to A3.fd81 .

[670] Table 518: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fe1 to A3.fe81 .

[671] Table 519: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fe1 to A3 .fe81.

[672] Table 520: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ff1 to A3.ff81 .

[673] Table 521: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.ff1 to A3 .ff81.

[674] Table 522: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fg1 to A3.fg81 .

[675] Table 523: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fg1 to A3 .fg81.

[676] Table 524: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fh1 to A3.fh81 .

[677] Table 525: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fh1 to A3 .fh81.

[678] Table 526: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fi1 to A3.fi81 .

[679] Table 527: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fi1 to A3 .fi81.

[680] Table 528: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fk1 to A3.fk81 .

[681] Table 529: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fk1 to A3 .fk81.

[682] Table 530: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fl1 to A3.fl81 .

[683] Table 531: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fl1 to A3 .fl81.

[684] Table 532: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals from A3.fm1 to A3.fm81 .

[685] Table 533: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals from A3.fm1 to A3 .fm81.

[686] Table 534: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fn1 to A3.fn81 .

[687] Table 535: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals of A3.fn1 to A3 .fn81.

[688] Table 536: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fo1 to A3.fo81 .

[689] Table 537: Compounds of the formula I'.A and the salts and N-oxides thereof, where R1 is methyl, Rt, Ru and Rw are hydrogen and where A is selected from the radicals A3.fo1 to A3 .fo81.

[690] Additional examples of the compounds of this particularly preferred embodiment are the compounds of tables 370A to 537A where Rt, Ru and Rv are hydrogen and where A is as defined in tables 370 to 357 and where R1 is a radical represented by each individual line (from 85 to 160) in table B.

A é um radical A1, conforme definido neste, em particular ao radical A1, em que R41 e R51 tem os significados preferenciais, em particular um radical oxazol das fórmulas de A1.a a A1.z, por exemplo um radical selecionado a partir dos radicais oxazol A1.a1 a A1.z81; R1 é hidrogênio, alquila C1-C4 ou C1-C4-alcóxi-C1-C2-alquila, mais preferencialmente hidrogênio, metil ou etil; R1 é ainda mais preferencialmente representado por um radical conforme definido em cada linha da tabela B; Rt, Ru e Rv são independentes entre si selecionados dentre hidrogênio, metila, difluorometila, trifluorometila, metóxi, difluorometóxi e trifluorometóxi; e em que preferencialmente pelo menos um, mais preferencialmente 2 ou 3, dos radicais Rt, Ru, e Rv são hidrogênio.[691] Another particularly preferred embodiment of the invention relates to the compounds of the formula I'.B and the salts and N-oxides thereof, where:

A is a radical A1, as defined herein, in particular to radical A1, where R41 and R51 have the preferred meanings, in particular an oxazole radical of the formulas A1.a to A1.z, for example a radical selected from the radicals oxazole A1.a1 to A1.z81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, more preferably hydrogen, methyl or ethyl; R1 is even more preferably represented by a radical as defined in each row in table B; Rt, Ru and Rv are independent from each other selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably 2 or 3, of the radicals Rt, Ru, and Rv are hydrogen.

[692] Examples of the compounds of this particularly preferred embodiment are the compounds provided in the following tables 538 to 588 and in the tables 538A to 588A.

[693] Tables 538 to 588: Compounds of the formula I'.B and the salts and N-oxides thereof, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 1 to 50.

[694] Tables 538A to 588A: Compounds of the formula I'.B and the salts and N-oxides thereof, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 1A to 50A.

[695] Another particularly preferred embodiment concerns a compound of the formula I'.B and the salts and N-oxides thereof, where A is an A1 radical, as defined in this document, in particular an A1 radical, in which R41 and R51 have the preferred meanings, in particular a thiazole radical of formulas A1.a 'to A1.z', for example, a radical selected from the thiazole radicals A1.a'1 to A1.z'81; R1 is hydrogen, C1-C4 or C1-C4-alkoxy-C1-C2-alkyl, more preferably hydrogen, methyl or ethyl; R1 is even more preferably represented by a radical as defined in each row in table B; Rt, Ru and Rv are independently selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably 2 or 3, of the radicals Rt, Ru, and Rv are hydrogen.

[696] Examples of compounds of this particularly preferred embodiment are the compounds given in the following tables 589 to 639 and tables 589A to 639A.

[697] Tables 589 to 639: Compounds of formula I'.B and their salts and N-oxides, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 51 to 100.

[698] Tables 589A to 639A: Compounds of formula I'.B and their salts and N-oxides, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 51A to 100A.

[699] Another particularly preferred embodiment concerns a compound of the formula I'.B and the salts and N-oxides thereof, where A is an A2 radical, as defined in this document, in particular an A2 radical, in which R42 and R52 have the preferred meanings, in particular an oxazole radical of formulas A2.aa to A2.do, for example, a radical selected from the oxazole radicals A2.aa1 - A2.aa81 to A2.ha1 - A2.ha81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, more preferably hydrogen, methyl or ethyl; R1 is even more preferably represented by a radical as defined in each row in table B; Rt, Ru and Rv are independently selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably two or three of the radicals Rt, Ru and Rv are hydrogen.

[700] Examples of compounds of this particularly preferred embodiment are the compounds given in the following tables 640 to 690 and tables 640A to 690A.

[701] Tables 640 to 690: Compounds of formula I'.B and their salts and N-oxides, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 101 to 150.

[702] Tables 640A to 690A: Compounds of formula I'.B and their salts and N-oxides, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in 101A to 150A.

[703] Another particularly preferred embodiment concerns a compound of the formula I'.B and the salts and N-oxides thereof, where A is an A2 radical, as defined in this document, in particular an A2 radical, in which R42 and R52 have the preferred meanings, in particular a thiazole radical of the formulas A2.aa 'to A2.do', for example, a radical selected from the thiazole radicals A2.aa'1 - A2.aa'81 to A2. ha'1 - A2.ha'81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, more preferably hydrogen, methyl or ethyl; R1 is even more preferably represented by a radical as defined in each row in table B; Rt, Ru and Rv are independently selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably two or three of the radicals Rt, Ru and Rv are hydrogen.

[704] Examples of compounds of this particularly preferred embodiment are the compounds given in the following tables 691 to 716 and tables 691A to 716A.

[705] Tables 691 to 716: Compounds of formula I'.B and their salts and N-oxides, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 151 to 176.

[706] Tables 691A to 716A: Compounds of the formula I'.B and the salts and N-oxides thereof, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 151A to 176A.

[707] Another particularly preferred embodiment concerns a compound of the formula I'.B and the salts and N-oxides thereof, where A is an A3 radical, as defined in this document, in particular an A3 radical, in which R43 and R53 have the preferred meanings, more particularly an oxazole radical of formulas A3.aa to A3.do, for example, a radical selected from the oxazole, thiazole, or imidazole radicals A3.aa1 - A3.aa81 to A3.do1 - A3.do81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, more preferably hydrogen, methyl or ethyl; R1 is even more preferably represented by a radical as defined in each row in table B; Ru, Rv and Rt are independently selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably 2 or 3, of the radicals Ru, Rv and Rt are hydrogen.

[708] Examples of compounds of this particularly preferred embodiment are the compounds given in the following tables 717 to 742 and tables 717A to 742A.

[709] Tables 717 to 742: Compounds of the formula I'.B and the salts and N-oxides thereof, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 177 to 202.

[710] Tables 717A to 742A: Compounds of the formula I'.B and the salts and N-oxides thereof, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 177A to 202A.

[711] Another particularly preferred embodiment concerns a compound of the formula I'.B and the salts and N-oxides thereof, where A is an A3 radical, as defined in this document, in particular an A3 radical, in which R43 and R53 have the preferred meanings, more particularly a thiazole radical of formulas A3.aa 'to A3.do', for example, a radical selected from thiazole radicals A3.aa'1 - A3.aa'81 to A3. do'1 - A3.do '81; R1 is hydrogen, C1-C4-alkyl or C1-C4-alkoxy-C1-C2-alkyl, more preferably hydrogen, methyl or ethyl; R1 is even more preferably represented by a radical as defined in each row in table B; Ru, Rv and Rt are independently selected from hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; and wherein preferably at least one, more preferably 2 or 3, of the radicals Ru, Rv and Rt are hydrogen.

[712] Examples of compounds of this particularly preferred embodiment are the compounds given in the following tables 743 to 760 and tables 743A to 760A.

[713] Tables 743 to 760: Compounds of the formula I'.B and the salts and N-oxides thereof, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 342 to 369.

[714] Tables 743A to 760A: Compounds of formula I'.B and the salts and N-oxides thereof, where Rt, Ru and Rv are hydrogen and where A and R1 are as defined in tables 342A to 369A.

[715] The compounds of formula I, where X1 is O or S (compounds I '), can be prepared, for example, according to the method shown in scheme 1 by reacting an oxazole derivative II, thiazole or carboxylic imidazole activated with a 3- or 4-aminopyridazine, compound III (see, for example, Houben-Weyl: "Methoden der organ. Chemie", Methods of Organic Chemistry), Georg-Thieme-Verlag, Stuttgart, New York 1985 , Volume E5, pp. 941 to 1045). Derivatives II of oxazole, thiazole or activated carboxylic imidazole are, for example, acyl halides, activated esters, anhydrides, acyl azides, where X is, for example, chlorine, fluorine, bromine, para-nitrophenoxy, pentanitrophenoxy, N- hydroxysuccinimides, hydroxybenzotriazol-1-yl. In scheme 1, the radicals A, R1, Rt, Ru, V and W have the meanings mentioned above and, in particular, the meanings mentioned as being preferred. SCHEME 1:

[716] The compounds of formula I, where X1 is O or S (compounds I '), can also be prepared, for example, by reacting oxazole IV or thiazole carboxylic acid and compound III of 3- or 4- aminopyridazine, in SCHEME 2:

[717] Suitable coupling agents are, for example: - carbodiimide based coupling agents, for example, N, N'-dicyclohexylcarbodiimide [J.C. Sheehan, G.P. Hess, J. Am. Chem. Soc. 1955, 77, 1067], N- (3-dimethylaminopropyl) -N'-ethylcarbodiimide; - coupling agents that form anhydrides mixed with carbonic esters, for example, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline [B. Belleau, G. Malek, J. Amer. Chem. Soc. 1968, 90, 1651], 2-isobutyloxy-1-isobutyloxycarbonyl-1,2-dihydroquinoline [Y. Kiso, H. Yajima, J. Chem. Soc., Chem. Commun. 1972, 942]; - coupling agents based on phosphonium salts, for example, (benzotriazol-1-yloxy) hexafluorophosphate tris (dimethylamino) phosphonium [B. Castro, J.R. Domoy, G. Evin, C. Selve, Tetrahedron Lett. 1975, 14, 1219], tripyrrolidinophosphonium (benzotriazol-1-yl-oxy) hexafluorophosphate [J. Coste et al., Tetrahedron Lett. 1990, 31, 205]; - coupling agents based on uranium salts or having a guanidine N-oxide structure, for example, N, N, N ', N'-tetramethyl-O- (1H-benzotriazol-1-yl) hexafluorophosphate uranium [R. Knorr, A. Trzeciak, W. Bannwarth, D. Gillessen, Tetrahedron Lett. 1989, 30, 1927], N, N, N ', N'-tetramethyl-O- (benzotriazol-1-yl) uranium tetrafluoroboroate, (benzotriazol-1-yloxy) dipiperidinocarbene hexafluorophosphate [S. Chen, J. Xu, Tetrahedron Lett. 1992, 33, 647]; - coupling agents that form acid chlorides, for example, phosphine bis- (2-oxo-oxazolidinyl) chloride [J. Diago-Mesequer, Synthesis 1980, 547].

[718] Compounds of formula I, where X1 is O (compounds I ') and R1 are different from hydrogen can also be prepared by alkylating amides I (in which R1 is hydrogen and which can be obtained according to scheme 1 or 2) with the use of suitable alkylating agents in the presence of bases. SCHEME 3:

[719] IV oxazole, thiazole or imidazole carboxylic acids and their activated II derivatives as well as 3- or 4-aminopyridazine compounds III, please check that the following names are correct and whether they are known in the art or are commercially available or they can be prepared using methods known in the literature.

[720] Compounds of formula I, where X1 are different from oxygen, can be prepared from compounds of formula I 'using standard methods:

[721] Compounds of formula I, where X1 is S, can be prepared, for example, by reacting a compound of formula I 'with 2,4-bis (4-methoxyphenyl) -1,3,2,4 -ditiadiphosphethane-2,4-disulfide or phosphorus pentasulfide according to the method described by M. Jesberger et al. in Synthesis 2003, 1929.

[722] Compounds of formula I, where X1 is NR1a, can be prepared, for example, by reacting a compound I 'with by reacting a compound I' with 2,4-bis (4-methoxyphenyl) -1 , 3,2,4-dithiadiphosphethane-2,4-disulfide to obtain the corresponding thioamide (compound I, where X1 is S) which is then reacted with a suitable amine, according to the method described by V. Glushkov et al . in Pharmaceutical Chemistry Journal 2005, 39 (10), 533-53.

[723] The compounds of formula II, where X2 = SR2a, can be prepared by alkylating a corresponding thioamide (compound I, where X1 is S) by reacting with an alkylating agent, according to the method described by V. Glushkov et al. in Pharmaceutical Chemistry Journal 2005, 39 (10), 533 to 536. Similarly, compounds I, where X2 is OR2a or NR2bR2c can be obtained. The compounds of formula II, where X2 = SOR2a or SO2R2a can be obtained by oxidizing compounds II with X2 = SR2a.

[724] N-oxides of the compounds of formulas I and II, can be prepared by oxidizing compounds I, according to standard methods of preparing heteroaromatic N-oxides, for example, by the method described by C. Botteghi et al . in Journal of Organometallic Chemistry 1989, 370, 17 to 31.

[725] As a rule, compounds of formulas I or II can be prepared using the methods described above. If individual compounds cannot be prepared using the routes described above, they can be prepared by derivating other compounds I or II or by customary modifications to the described synthesis routes. For example, in individual cases, some compounds I or II can be advantageously prepared from other compounds I or II through ester hydrolysis, amidation, esterification, ether cleavage, olefin, reduction, oxidation and the like.

[726] The reaction mixtures are isolated and purified in the usual way, for example, by mixing with water, separating the phases, and, if appropriate, purifying the crude products by chromatography, for example, on alumina or gel. silica. Some of the intermediate and final products can be obtained in the form of colorless or pale brown viscous oils that are released or purified from volatile components under reduced pressure and at a moderately high temperature. If the intermediate and final products are obtained as solids, they can be purified through recrystallization or crushing.

[727] Due to their excellent activity, the compounds of general formulas I or II can be used to control invertebrate pests.

[728] Consequently, the present invention also provides a method for controlling invertebrate pests whose method comprises treating pests, their food supply, their habitat or breeding site or a cultivated plant, plant propagation materials (such as seed), soil, area, material or environment in which pests grow or can grow, or the materials, cultivated plants, plant propagation materials (such as seed), soil, surfaces or spaces to be protected from infestation or attack by pests with a quantity effective as a pesticide of a compound of the formulas (I) or (II) or a salt or N-oxide thereof or a composition as defined above.

[729] Preferably, the method of the invention serves to protect plant propagation material (such as seed) and the plant growing from it from infestation or attack by invertebrate pests and comprises treating plant propagation material (such as seed) ) with a pesticide-effective amount of a compound of the formulas (I) or (II) or an agriculturally acceptable N-oxide or salt thereof as defined above or with a pesticide-effective amount of an agricultural composition as defined above and below. The method of the invention is not limited to the protection of the "substrate" (plant, plant propagating material, soil material, etc.) that has been treated according to the invention, but it also has a preventive effect, for example , according to the protection of a plant that grows from treated plant propagation materials (such as seed), and the plant itself was not treated.

[730] In the context of the present invention, "invertebrate pests" are preferably selected from arthropods and nematodes, more preferably from harmful insects, arachnids and nematodes, and even more preferably from insects, mites and nematodes.

[731] The invention further provides an agricultural composition to combat such invertebrate pests, which comprises such an amount of at least one compound of the general formulas I or II or at least one agriculturally useful salt or N-oxide thereof and at least an agriculturally acceptable solid and / or inert liquid carrier that has a pesticidal action and, if desired, at least one surfactant.

[732] Such a composition may contain a single compound of formulas I or II or an active salt or N-oxide thereof or a mixture of several active compounds I or II or their salts according to the present invention. The composition according to the present invention can comprise an individual isomer or mixtures of isomers as well as individual tautomers or mixtures of tautomers.

[733] The compounds of formulas I or II and the pesticidal compositions comprising them are effective agents for controlling arthropod and nematode pests. Invertebrate pests controlled by compounds of formulas I or II include, for example,

[734] insects of the order of lepidoptera (Lepidoptera), for example, Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gama, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheimatoistone Chumoroneone occidental, Chimaoristone chumata , Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandiosella, Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bouliana, Feltia subterranea, Galleria mellonella, Grapholitha funebranothis, Helolis, Molecule, Helolha undalis, Hibernia defoliaria, Hyphantria cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lambdina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scitella, Lithocolletis blancardella, Lobesia botrana, Loxostmaniatria, dispariatria, lichostmaniatictice, Lychee Orgyia pseudotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea operculella, Phyllocnistis citrella, Pieris brassicae, Plathypena scabra, Plutella xylostella, Pseudoobylia, Friaga, tropica, Fruta, Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, Tortrix viridana, Trichoplusiani and Zeiraphera canadensis; beetles (Coleoptera), for example, Agrilus sinuatus, Agriotes lineatus, Agriotes obscurus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomorum, Atomaria linearis, Blastophagus piniperda, Blitophaga undata, Bruchus rufimanusus, Brusususuchus, Bruchus Cassida nebulosa, Cerotoma trifurcata, Ceuthorrhynchus assimilis, Ceuthorrhynchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Diabrotica longicornis, Diabrotica 12 punctata, Diabrotica virgifis, Hibiscus, Epilacis, typographus, Lemma bilineata, Lemma melanopus, Leptinotarsa decemlineata, Limonius californicus, Lissorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus, Melolontha hippocastani, Melolontha melolontha, Oulema oryzae, Otter, Chorus, Christina, Orthior Phyllopertha horticola, Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sitophilus granaria; Diptera (Diptera), for example, Aedes aegypti, Aedes vexans, Anastrepha ludens, Anopheles maculipennis, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Chrysomya macellaria, Contarinia sorghicola, Cordylobia anthropophaga, Dylanea, Culexia Fannia canicularis, Gasterophilus intestinalis, Glossina morsitans, Haematobia irritans, Haplodiplosis equestris, Hylemyia platura, Hypoderma lineata, Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia sericata, Lycoria pectoralisina, destructor, May, , Oscinella frit, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phorbia coarctata, Rhagoletis cerasi, Rhagoletis pomonella, Tabanus bovinus, Tipula oleracea and Tipula paludosa; thrips (Thysanoptera), for example, Dichromothrips corbetti, Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmi and Thrips tabaci; Hymenopterans (Hymenoptera), for example, Athalia rosae, Atta cephalotes, Atta sexdens, Atta texana, Hoplocampa minuta, Hoplocampa testudinea, Monomorium pharaonis, Solenopsis geminata and Solenopsis invicta; heteropterans (Heteroptera), for example, Acrosternum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps, Euschistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris, Lygus lineolaris homopterans (Homoptera), for example, Acyrthosiphon onobrychis, Adelges laricis, Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis grossulariae, Aphis schneideri, Aphis spiraecola, Aphis sambuci, Solyrumani, Acyrthani Bemisia tabaci, Brachycaudus cardui, Brachycaudus helichrysi, Brachycaudus persicae, Brachycaudus prunicola, Brevicoryne brassicae, Capitophorus horni, Cerosipha gossypii, Chaetosiphon fragaefolii, ribis Cryptomyzus, Dreyfusia nordmannianae, piceae Dreyfusia, Dysaphis radicola, Dysaulacorthum pseudosolani, plantaginea Dysaphis, Dysaphis pyri, Empoasca fabae , Hyalopterus pruni, Hyperomyzus lactucae, Macrosiphum avenae, Macrosiphum euphorbiae, Macrosiphon rosae, Megoura viciae, Melanaphis pyrarius, Metopolophium dirhodum, Myzodes persicae, Myzus ascalonicus, Myzus cerasi, Myzus persigi, Myzus persige, Myzus persige, Myzus persige , Perkinsiella saccharicida, Phorodon hu muli, Psylla mali, Psylla piri, Rhopalomyzus ascalonicus, Rhopalosiphum maidis, Rhopalosiphum padi, Rhopalosiphum insertum, Sappaphis mala, Sappaphis mali, Schizaphis graminum, Schizoneura lanuginosa, Sitobionia aurea, Furoboxia, and termites (Isoptera), for example, Calotermes flavicollis, Leucotermes flavipes, Reticulitermes flavipes, Reticulitermes lucifugus and Termes natalensis; orthopterans (Orthoptera), for example, Acheta domestica, Blatta orientalis, Blattella germanica, Forficula auricularia, Gryllotalpa gryllotalpa, Locusta migratoria, Melanoplus bivittatus, Melanoplus femur-rubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus spretciaas, Nomadacrista American, Schistocerca peregrina, Stauronotus maroccanus and Tachycines asynamorus; arachnoidea, such as arachnids (Acarina), for example, from the families of Argasidae, Ixodidae and Sarcoptidae, such as Amblyomma americanum, Amblyomma variegatum, Argas persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus microplus, Dermacentorusundvarxum, Hymalum, trump, Hyalum , Ornithodorus moubata, Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus appendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei, and Eriophyidae spp., Such as Aculus schlechtendali, Phyllocoptrata oleivora and Erikphyoni; Tarsonemidae spp., Such as Phytonemus pallidus and Polyphagotarsonemus latus; Tenuipalpidae spp., Such as Brevipalpus phoenicis; Tetranychidae spp., Such as Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, Panonychus citri, and oligonychus pratensis; siphonatera, for example, Xenopsylla cheopsis, Ceratophyllus spp.

[735] The compositions and compounds of formulas I or II are useful for the control of nematodes, especially parasitic nematodes of plants such as gall nematodes, Meloidogyne hapla, Meloidogyne incognita, Meloidogyne javanica, and other Meloidogyne species; cyst-forming nematodes, Globodera rostochiensis and other species of Globodera; Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and other species of Heterodera; Seed gall nematodes, species of Anguina; Stem and leaf nematodes, species of Aphelenchoides; stinger nematodes, Belonolaimus longicaudatus and other species of Belonolaimus; nematodes of pine, Bursaphelenchus xylophilus and other species of Bursaphelenchus; Ring nematodes, Criconema species, Criconemella species, Criconemoides species, Mesocriconema species; Stem and bulb nematodes, Ditylenchus destructor, Ditylenchus dipsaci and other Ditylenchus species; nematodes of Awl, species of Dolichodorus; spiral nematodes, Heliocotylenchus multicinctus and other species of Helicotylenchus; Coating and leafy nematodes, species of Hemicycliophora and species of Hemicriconemoides; Hirshmanniella species; Throw nematodes, species of Hoploaimus; false gall nematodes, species of Nacobbus; Needle nematodes, Longidorus elongatus and other species of Longidorus; pin nematodes, species of Paratylenchus; lesion nematodes, Pratylenchus neglectus, Pratylenchus penetrans, Pratylenchus curvitatus, Pratylenchus goodeyi and other species of Pratylenchus; perforating nematodes, Radopholus similis and other species of Radopholus; reniform nematodes, Rotylenchus robustus and other species of Rotylenchus; Scutellonema species; short-stemmed nematodes, Trichodorus primitivus and other species of Trichodorus, species of Paratrichodorus; atrophy nematodes, Tylenchorhynchus claytoni, Tylenchorhynchus dubius and other species of Tylenchorhynchus; citrus nematodes, Tylenchulus species; perforating nematodes, Xiphinema species; and other species of plant parasitic nematodes.

[736] In a preferred embodiment of the invention, the compounds of formulas I or II are used to control insects or arachnids, in particular insects of the orders of Lepidoptera, Coleoptera, Thysanoptera and Homoptera and arachnids of the order Acarina. The compounds of formulas I or II, according to the present invention, are particularly useful for controlling insects of the order Thysanoptera and Homoptera.

[737] The compounds of formulas I or II of the formula or the pesticidal compositions comprising them can be used to protect growing crops and plants from attack or infestation by invertebrate pests, especially insects, mites or arachnids through contact of a plant / planting with a pesticide-effective amount of the compounds of formulas I or II. The term "plantation" refers to growing and harvested plantations.

[738] The compounds of formulas I or II can be converted into common formulations, for example, solutions, emulsions, suspensions, dust, powders, pastes and granules. The form of use depends on the intended purposes in particular; in each case, a fine and uniform distribution of the compound according to the invention must be ensured.

[739] Formulations are prepared in a known manner (see, for example, for review US 3,060,084, EP-A 707 445 (for liquid concentrates), Browning, "Agglomeration", Chemical Engineering, December 4, 1967, 147 to 48, Perry's Chemical Engineer's Handbook, 4th Ed., McGraw-Hill, New York, 1963, pages 8 to 57 and, in sequence, WO 91/13546, US 4,172,714, US 4,144,050, US 3,920,442 , US 5,180,587, US 5,232,701, US 5,208,030, GB 2,095,558, US 3,299,566, Klingman, Weed Control as a Science, John Wiley and Sons, Inc., New York, 1961, Hance et al ., Weed Control Handbook, 8th Ed., Blackwell Scientific Publications, Oxford, 1989 and Mollet, H., Grubemann, A., Formulation technology, Wiley VCH Verlag GmbH, Weinheim (Germany), 2001, 2. DA Knowles, Chemistry and Technology de Agrochemical Formulations, Kluwer Academic Publishers, Dordrecht, 1998 (ISBN 0-7514- 0443-8), for example, by extending the active compound with suitable auxiliaries for the formulation of agrochemicals, with as solvents and / or carriers, if desired, emulsifiers, surfactants and dispersants, preservatives, antifoam agents, antifreeze agents, for seed treatment formulation also optionally dyes and / or binders and / or gelling agents.

[740] Examples of suitable solvents are water, aromatic solvents (for example, Solvesso products, xylene), paraffins (for example, mineral oil fractions), alcohols (for example, methanol, butanol, pentanol, benzyl alcohol), ketones ( eg, cyclohexanone, gamma-butyrolactone), pyrrolidones (N-methylpyrrolidone [NMP], N-octylpyrrolidone [NOP]), acetates (glycol diacetate), glycols, fatty acid dimethylamides, fatty acids and fatty acid esters. In principle, solvent mixtures can also be used.

[741] Suitable emulsifiers are nonionic and anionic emulsifiers (for example, polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates).

[742] Examples of dispersants are lignin sulfite and methylcellulose residue liquors.

[743] Suitable surfactants used are alkali metals, alkaline earth metal and lignosulfonic acid ammonium salts, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalene sulfonic acid, alkylarylsulfonates, alkyl sulfates, alkyl sulfonates, fatty alcohol sulfates, fatty acids and ether sulfated fatty alcohol glycol, additional condensates of sulphonated naphthalene and naphthalene formaldehyde derivatives, condensates of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octiphenol ether, ethoxylated isylphenylphenyl, polyethylphenol, ethoxyphenol, ethoxylphenol , tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, fatty alcohol ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, polyglycol ether acetal, lauryl alcohol esters, sorbitol esters lignosulfite and methylcellulose.

[744] Substances that are suitable for the preparation of solutions, emulsions, pastes or oil dispersions directly sprayable are medium to high boiling mineral oil fractions, such as kerosene or diesel oil, in addition tar and coal oils and oils of animal or vegetable origin, aromatic and cyclic, aliphatic hydrocarbons, for example, toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, highly polar solvents, for example , dimethyl sulfoxide, N-methylpyrrolidone or water.

[745] Antifreeze agents such as glycerin, ethylene glycol, propylene glycol and bactericides can also be added to the formulation.

[746] Suitable defoaming agents are, for example, defoaming agents based on magnesium or silicon stearate.

[747] A suitable preservative is, for example, dichlorophene.

[748] Seed treatment formulations can further comprise binders and optionally dyes.

[749] Binders can be added to improve the adhesion of active materials to seeds after treatment. Suitable binders are EO / PO surfactants of block copolymers, but also polyvinylalcohols, polyvinylpyrrolidones, polyacrylates, polymethacrylates, polybutenes, polyisobutylenes, polystyrene, polyethyleneamines, polyethyleneamides, polyethyleneimines (Lupasol®, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene, polyethylene and polyethylene. derived from these polymers.

[750] Optionally, dyes can also be included in the formulation. Suitable dyes or pigments for seed treatment formulation are Rhodamine B, CI Pigment Red 112, CI Solvent Red 1, Blue Pigment 15: 4, Blue Pigment 15: 3, Blue Pigment 15: 2, Blue Pigment 15: 1, Blue Pigment 80, yellow pigment 1, yellow pigment 13, red pigment 112, red pigment 48: 2, red pigment 48: 1, red pigment 57: 1, red pigment 53: 1, orange pigment 43, orange pigment 34, orange pigment 5, green pigment 36, green pigment 7, white pigment 6, brown pigment 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.

[751] An example of a gelling agent is carrageenan (Satiagel®).

[752] Powders, dispersion materials and sprayable products can be prepared by mixing or grinding the active substances concomitantly with a solid carrier.

[753] Granules, for example, coated granules, impregnated granules and homogeneous granules, can be prepared by linking the active compounds to solid carriers.

[754] Examples of solid carriers are mineral lands such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, ocher, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, oxide magnesium, ground synthetic materials, fertilizers, such as, for example, ammonium sulphate, ammonium phosphate, ammonium nitrate, ureas, and products of plant origin, such as cereal flour, tree bark flour, wood flour and wheat flour. nutshell, cellulose powders and other solid carriers.

[755] In general, the formulations comprise from 0.01 to 95% by weight, preferably 0.1 to 90% by weight, of the active compound (s). In this case, the active compound (s) are used in a purity of 90% to 100% by weight, preferably from 95% to 100% by weight (according to the NMR spectrum).

[756] For seed treatment purposes, the respective formulations can be diluted 2- to 10-fold leading to ready-to-use concentrations of preparations from 0.01 to 60% by weight of active compound by weight, preferably 0, 1 to 40% by weight.

[757] The compounds of formulas I or II can be used as such, in the form of their formulations or in the form of uses prepared therefrom, for example, in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, sprayable products, dispersion materials, or granules, by means of dispersion, atomization, spraying, spreading or spilling. The form of use depends entirely on the intended purposes; they are intended to ensure, in each case, the finest possible distribution of the active compound (s) according to the invention.

[758] Forms for aqueous use can be prepared from emulsion concentrates, pastes or wetting powders (dispersion powders, oil dispersions) by adding water. To prepare emulsions, pastes or oil dispersions, substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier. However, it is also possible to prepare concentrates composed of active substance, wetting agent, tackifying agent, dispersant or emulsifier and, if appropriate, solvent or oil, and such concentrates are suitable for dilution with water.

[759] The concentrations of active compound in ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 10%, preferably from 0.01 to 1% by weight.

[760] The active compound (s) can also be used successfully in the ultra-low volume (ULV) process, making it possible to apply formulations that comprise over 95% by weight of active compound, or even apply the active compound without additives.

[761] The following are examples of the formulations: 1. Products for dilution with water for foliar applications. For seed treatment purposes, such products can be applied to diluted or undiluted seed. A) Water-soluble concentrates (SL, LS) 10 parts by weight of the active compound (s) are dissolved in 90 parts by weight of water or a water-soluble solvent. As an alternative, wetting agents or other auxiliaries are added. The active compound (s) dissolves upon dilution with water, through which a formulation with 10% (w / w) of active compound (s) is obtained. B) Dispersible concentrates (DC) 20 parts by weight of the active compound (s) are dissolved in 70 parts by weight of cyclohexanone with the addition of 10 parts by weight of a dispersant, for example, polyvinylpyrrolidone. Dilution with water yields a dispersion, through which the formulation with 20% (w / w) of active compound (s) is obtained. C) Emulsifiable concentrates (EC) 15 parts by weight of the active compound (s) are dissolved in 7 parts by weight of xylene with the addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water yields an emulsion, through which a formulation with 15% (w / w) of active compound (s) is obtained. D) Emulsions (EW, EO, ES) 25 parts by weight of the active compound (s) are dissolved in 35 parts by weight of xylene with the addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is introduced into 30 parts by weight of water by means of an emulsifying machine (for example, Ultraturrax) and transformed into a homogeneous emulsion. Dilution with water yields an emulsion, through which the formulation with 25% (w / w) of active compound (s) is obtained. E) Suspensions (SC, OD, FS)

[762] In a stirred ball mill, 20 parts by weight of the active compound (s) are broken up with the addition of 10 parts by weight of dispersants, wetting agents and 70 parts by weight of water or a solvent organic to yield a suspension of fine active compound (s). Dilution with water yields a stable suspension of the active compound (s), through which the formulation with 20% (w / w) of active compound (s) is obtained. F) Water-dispersible granules and water-soluble granules (WG, SG) 50 parts by weight of the active compound (s) are finely ground with the addition of 50 parts by weight of dispersants and wetting agents and made into water-soluble or water-dispersible granules by means of technical devices (eg extrusion, dispersion tower, fluidized bed). Dilution with water yields a stable dispersion or solution of the active compound (s), through which the formulation with 50% (w / w) of active compound (s) is obtained. G) Water-dispersible powders and water-soluble powders (WP, SP, SS, WS) 75 parts by weight of the active compound (s) are ground in a rotor and stator mill with the addition of 25 parts by weight of dispersants, wetting agents and silica gel. Dilution with water yields a stable dispersion or solution of the active compound (s), through which the formulation with 75% (w / w) of active compound (s) is obtained. H) Gel formulation (GF)

[763] In a stirred ball mill, 20 parts by weight of the active compound (s) are broken up with the addition of 10 parts by weight of dispersants, 1 part by weight of wetting agents of a gelling agent and 70 parts by weight of water or an organic solvent to yield a suspension of fine active compound (s). Dilution with water yields a stable suspension of the active compound (s), through which the formulation with 20% (w / w) of active compound (s) is obtained. 2. Products to be applied undiluted for foliar applications. For seed treatment purposes, such products can be applied to diluted or undiluted seed. I) Sprayable powders (DP, DS) 5 parts by weight of the active compound (s) are finely ground and intimately mixed with 95 parts by weight of finely divided kaolin. This yields a sprayable product that has 5% (w / w) of active compound (s) J) Granules (GR, FG, GG, MG) 0.5 part by weight of the active compound (s) (s) is finely ground and associated with 95.5 parts by weight of carriers, through which the formulation with 0.5% (w / w) of active compound (s) is obtained. Current methods include extrusion, spray drying or the fluidized bed. This yields granules to be applied undiluted for foliar use. K) ULV (UL) solutions [10] parts by weight of the active compound (s) are dissolved in 90 parts by weight of an organic solvent, for example, xylene. This yields a product that has 10% (w / w) of active compound (s), to be applied undiluted for foliar use.

[764] The compounds of formulas I or II are also suitable for the treatment of plant propagation materials (such as seed). Conventional seed treatment formulations include, for example, FS flowable concentrates, LS solutions, DS dry treatment powders, water dispersible powders for treatment with WS water paste, SS water soluble powders and ES and EC emulsion and gel formulation GF. These formulations can be applied to diluted or undiluted seed. The application to the seeds is carried out before sowing, either directly on the seeds or after pre-germinating the last one.

[765] In a preferred embodiment, the FS formulation is used for seed treatment. Typically, the FS formulation can comprise 1 to 800 g / l of active ingredient, 1 to 200 g / l of surfactant, 0 to 200 g / l of antifreeze agent, 0 to 400 g / l of binder, 0 to 200 g / l of a pigment and up to 1 liter of a solvent, preferably water.

[766] Other preferred FS formulations of the compounds of formulas I or II for seed treatment comprise from 0.5 to 80% by weight of the active ingredient, from 0.05 to 5% by weight of a wetting agent, from 0.5 to 15%, by weight, of a dispersant, from 0.1 to 5%, by weight, of a thickener, from 5 to 20%, by weight, of an antifreeze agent, from 0, 1 to 2%, by weight, of a defoaming agent, from 1 to 20%, by weight, of a pigment and / or a dye, from 0 to 15%, by weight, of an adhesive / adhesion agent, from 0 at 75%, by weight, of a filler / vehicle, and from 0.01 to 1%, by weight, of a preservative.

[767] Various types of oils, wetting agents, adjuvants, herbicides, fungicides, other pesticides, or bactericides can be added to the active ingredients, if appropriate almost immediately before use (mixer tank). These agents are usually mixed with addition to the agents, according to the invention, in a weight ratio of 1:10 to 10: 1.

[768] The compounds of formulas I or II are effective through both contact (through soil, glass, wall, bed net, carpet, plant parts or animal parts), and ingestion (bait, or plant part ).

[769] For use against ants, termites, wasps, flies, mosquitoes, crickets, or cockroaches, compounds of formulas I or II are preferably used in a bait composition.

[770] The bait can be a liquid, solid or semi-solid preparation (for example, a gel). Solid baits can be formed in various shapes and forms suitable for the respective application, for example, granules, blocks, rods, discs. Liquid baits can be filled in a variety of devices to ensure proper application, for example, open containers, dispersion devices, drip sources, or evaporation sources. Gels can be based on aqueous or oily matrices and can be formulated for particular needs in terms of stickiness, hydration retention or aging characteristics.

[771] The bait used in the composition is a product, which is attractive enough to incite insects such as ants, termites, wasps, flies, mosquitoes, crickets, etc. or cockroaches to eat it. Attractiveness can be manipulated with the use of food stimulants or sex pheromones. Food stimulants are chosen, for example, but not exclusively, from animal and / or vegetable proteins (meat, fish or blood meal, insect parts, egg yolk), from animal and / or vegetable fats and oils, or mono-, oligo- or polyorganosaccharides, especially from sucrose, lactose, fructose, dextrose, glucose, starch, pectin or even molasses or honey. Fresh or decomposing parts of fruits, crops, plants, animals, insects or specific parts of them can also serve as a food stimulant. Sex pheromones are known to be more specific to insects. Specific pheromones are described in the literature and are known to those skilled in the art.

[772] Formulations of the compounds of formulas I or II as aerosols (for example, in spray cans), oil spray or pump spray are highly suitable for the non-professional user to control pests such as flies, fleas, ticks, mosquitoes or cockroaches. Aerosol recipes are preferably composed of the active compound, solvents such as lower alcohols (for example, methanol, ethanol, propanol, butanol), ketones (for example, acetone, methyl ethyl ketone), paraffin hydrocarbons (for example, kerosenes) that have boiling ranges of approximately 50 to 250 ° C, dimethylformamide, N-methylpyrrolidone, dimethyl sulfoxide, aromatic hydrocarbons such as toluene, xylene, water, additional auxiliaries such as emulsifiers such as monooleate sorbitol, eloyl ethoxylate which has 3 to 7 mol of oxide ethylene, fatty alcohol ethoxylate, perfumed oils such as ethereal oils, esters of medium fatty acids with lower alcohols, aromatic carbonyl compounds, if appropriate stabilizers such as sodium benzoate, amphoteric surfactants, lower epoxides, triethyl orthoformate and, if necessary, propellants such as propane, butane, nitrogen, compressed air, dimethyl ether, carbon dioxide, nitrous oxide, or mixtures of these gases.

[773] Oil spray formulations differ from aerosol recipes in which no propellant is used.

[774] The compounds of formulas I or II and their respective compositions can also be used in fumigation and mosquito coils, smoke cartridges, vaporization or long-term vaporizing plates and also in moth papers, moth pads or other systems heat-independent vaporization

[775] Methods for the control of infectious diseases transmitted by insects (for example, malaria, dengue and yellow fever, lymphatic filariasis, and leishmaniasis) with compounds of formulas I or II and their respective compositions also include treating surfaces of lodgings and houses, air dispersion and impregnation of curtains, tents, clothes, bed net, tsetse fly trap or similar. Insecticidal compositions for application to fibers, fabrics, knitted products, nonwovens, mesh material or sheets and tarpaulins preferably comprise a mixture that includes the insecticide, optionally a repellent and at least one binder. Suitable repellents, for example, are N, N-diethyl-meta-toluamide (DEET), N, N-diethylphenylacetamide (DEPA), 1- (3-cyclohexan-1-yl-carbonyl) -2-methylpiperine, acid lactone acetic (2-hydroxymethylcyclohexyl), 2-ethyl-1,3-hexandiol, indalone, Methylneodecanamide (MNDA), an unused pyrethroid for insect control like {(+/-) - 3-allyl-2-methyl-4- oxocyclipent-2 - (+) - enyl - (+) - trans-crisantemate (Esbiotrin), a repellent derived from or identical to plant extracts such as limonene, eugenol, (+) - Eucamalol (1), (-) - 1 -epi-eucamalol or crude plant extracts from plants such as Eucalyptus maculata, Vitex rotundifolia, Cymbopogan martinii, Cymbopogan citratus (lemongrass), Cymopogan nartdus (citronella). Suitable binders are selected, for example, from polymers and copolymers of vinyl esters of aliphatic acids (such as vinyl acetate and vinyl versatate), acrylic and methacrylic alcohol esters, such as butyl acrylate, 2-ethylhexylacrylate, and acrylate. methyl, mono- and diethylenically unsaturated hydrocarbons, like styrene, and aliphatic dienes, like butadiene.

[776] The impregnation of curtains and mesh beds is usually done by submerging the textile material in emulsions or dispersions of the active compounds of formulas I and II or by dispersing them in the networks.

[777] Methods that can be employed for seed treatment are, in principle, all suitable seed treatments and, especially, seed coating techniques known in the art, such as seed coating (for example, seed pelleting), seed spraying and seed soaking (eg seed soaking). Here, "seed treatment" refers to all methods that bring seeds and compounds of formulas I or II into contact with each other, and "seed pelliculation" to seed treatment methods that provide seeds with a amount of compounds of formulas I or II, that is, that generate a seed comprising the compound of formulas I or II. In principle, the treatment can be applied to the seed at any time from the seed harvest to the sowing of the seed. The seed can be treated immediately before, or during, the planting of the seed, for example, using the "planter box" method. However, the treatment can also be carried out for several weeks or months, for example, up to 12 months, before the planting of the seed, for example, in the form of a seed pelletizing treatment, without substantially reduced effectiveness being observed.

[778] Effectively, the treatment is applied to the unsown seed. As used herein, the term "unsown seed" means to include the seed at any time from harvesting the seed to sowing the seed in the soil for purposes of germination and plant growth.

[779] Specifically, a procedure is followed in the treatment in which the seed is mixed, in a suitable device, for example, a mixing device for solid or solid / liquid mixing partners, with the desired quantity of seed treatment formulations , either as such or after previous dilution with water, until the composition is evenly distributed in the seed. If appropriate, this is followed by a drying step.

[780] The compounds of formula I or II or the veterinary acceptable enantiomers or salts thereof are also suitable to be used to combat parasites in or within animals.

[781] An additional objective of the present invention is, therefore, to provide methods for controlling parasites in and on animals. Another object of the invention is to provide safer pesticides for animals. Another object of the invention is also to provide pesticides for animals that can be used in lower dosages than existing pesticides. Another object of the invention is to provide pesticides for animals, which provide long-term residual control of parasites.

[782] The invention also relates to compositions that contain a parasitically effective amount of compounds of formula I or II or the veterinary acceptable enantiomers or salts thereof and an acceptable carrier, to combat parasites in or on animals.

[783] The present invention also provides a method for the treatment, control, prevention and protection of animals against infestation and parasite infection, which comprises the administration or oral, topical or parenteral application to animals of a parasitic effective amount of a compound of formula I or II or the veterinary acceptable enantiomers or salts thereof or a composition comprising them.

[784] The present invention also provides a non-therapeutic method for treating, controlling, preventing and protecting animals against parasite infestation and infection, which comprises applying a parasitic effective amount of a compound of formula I to a locus P. II or enantiomers or salts acceptable for veterinary and an acceptable carrier or a composition comprising them.

[785] The invention also provides a process for preparing a composition to treat, control, prevent or protect animals against parasite infestation or infection which comprises including a parasite-effective amount of a compound of formula I or II or the enantiomers or veterinary acceptable salts thereof in a composition that comprises them.

[786] The invention also relates to the use of compounds of formula I for the treatment, control, prevention or protection of animals against infestation or infection by parasites. The invention also relates to the use of a compound of formula I or II, or the veterinarily acceptable enantiomers or salts thereof and a carrier or composition comprising them, for the production of a medicament for the therapeutic treatment of animals against parasitic infections or infestations.

[787] The activity of compounds against agricultural pests does not suggest their suitability for the control of endo and ectoparasites in and on animals that require, for example, low dosages, non-emetic in the case of oral application, metabolic compatibility with the animal, low toxicity , and safe handling.

[788] Surprisingly, compounds of formula I or II have recently been found to be suitable for combating endo and ectoparasites in and on animals.

[789] The compounds of formulas I or II or the veterinary acceptable enantiomers or salts thereof and compositions comprising them are preferably used to control and prevent animal infestations and infections, including warm-blooded animals (including humans) and fish. They are, for example, suitable for controlling and preventing infestations and infections in mammals such as cattle, sheep, pigs, camels, deer, horses, pigs, birds, rabbits, goats, dogs and cats, Asian buffaloes, donkeys, deer and reindeer, and also in animals with fur like mink, chinchilla and raccoon, birds like chickens, geese, turkeys and ducks and fish like freshwater and saltwater fish like trout, carp and eel.

[790] The compounds of formulas I or II or the veterinary acceptable enantiomers or salts thereof and compositions comprising them are preferably used to control and prevent animal infestations and infections, such as dogs or cats.

[791] Infestations in warm-blooded animals and fish include, but are not limited to, lice, biting lice, ticks, muscoid dipters, flies, myiasis fly larvae, insects, eye flies, mosquitoes and fleas.

[792] The compounds of formula I or II or the veterinary acceptable enantiomers or salts thereof and compositions comprising them are suitable for the systemic and / or non-systemic control of ecto and / or endoparasites. They are active against all or some stages of development.

[793] Compounds of formulas I or II are especially useful for combating ectoparasites.

[794] Compounds of formulas I or II are especially useful for fighting parasites of the following orders and species, respectively: fleas (Siphonaptera), for example, Ctenocephalides felis, Ctenocephalides cams, Xenopsylla cheopis, Pulex irritans, Tunga penetrans, and Nosopsyllus fasciatus , Cockroaches (Blattaria-Blattodea), for example, Blattella germanica, Blattella asahinae, American Periplaneta, Periplaneta japonica, Periplaneta brunnea, Periplaneta fuligginosa, Periplaneta australasiae, and Blatta orientalis, flies, mosquitoes (Diptera), for example, Aedes aegypti albopictus, Aedes vexans, Anastrepha ludens, Anopheles maculipennis, Anopheles crucians, Anopheles albimanus, Anopheles gambiae, Anopheles freebomi, Anopheles leucosphyrus, Anopheles minimus, Anopheles quadrimaculatus, Calliphora vicina, Chrysomya bezziana, Chrysomya bezziana, Chrysomya bezziana, Chrysomya bezziana, Chrysomya bezziana, Chrysomya bezziana Chrysops atlanticus, Cochliomyia hominivorax, Cordylobia anthropophaga, Culico ides furens, Culex pipiens, Culex nigripalpus, Culex quinquefasciatus, Culex tarsalis, Culiseta inornata, Culiseta melanura, Dermatobia hominis, Fannia canicularis, Gasterophilus intestinalis, Glossina morsitans, Glossina palpalis, Glossina fuscipes, Haematopsychia, glossina tachinoides ., Hypoderma lineata, Leptoconops torrens, Lucilia caprina, Lucilia cuprina, Lucilia sericata, Lycoria pectoralis, Mansonia spp., Musca domestica, Muscina stabulans, Oestrus ovis, Phlebotomus argentipes, Psorophora columbiae, Psorophora discolor, Sarcophaga, Prosarcium ., Simulium vittatum, Stomoxys calcitrans, Tabanus bovinus, Tabanus atratus, Tabanus lineola, and Tabanus similis, lice (Phtiraptera), for example, Pediculus humanus capitis, Pediculus humanus corporis, Ptirus pubis, Haematopinus eurysternus suhni, bovis, Menopon gallinae, Menacanthus stramineus and Solenopotes capil latus. ticks and parasitic mites (Parasitiformes): ticks (Ixodida), for example, Ixodes scapularis, Ixodes holocyclus, Ixodes pacificus, Rhiphicephalus sanguineus, Dermacentor andersoni, Dermacentor variabilis, Amblyommausumismamysmysmamatismismatismismatismamatismismammatismummammatismumma, ), for example, Ornithonyssus bacoti and Dermanyssus gallinae, actinedida (Prostigmata) and Acaridida (Astigmata), for example, Acarapis spp., Cheyletiella spp., Omithocheyletia spp., Myobia spp., Psorergates spp., Tromodex spp. ., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knem Cytodites spp., And Laminosioptes spp, insects (Heteropterida): Cimex lectularius, Cimex hemipterus, Reduvius senilis, Triatoma spp., Rhodnius ssp., Panstrongylus ssp. and Arilus critatus, Anoplurida, for example, Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., and Solenopotes spp., Mallophagida (sub-orders Arnblycerina and Ischnocerina), for example, Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Wemeckiella spp., Lepikentron spp., Trichodectes spp., And Felicola spp,

[795] Nematode ascárides: Trichurids and Trichinosis (Trichosyringida), for example Trichinellidae (Trichinella spp.), (Trichuridae) Trichuris spp., Capillaria spp, Rhabditida, for example Rhabditis spp, Strongyloides spp., For example, Helicephalobus , Strongylus spp., Ancylostoma spp., Necator americanus, Bunosto-mum spp. (hookworm), Trichostrongylus spp., Haemonchus contortus., Ostertagia spp., Cooperia spp., Nematodirus spp., Dictyocaulus spp., Cyathostoma spp., Oesophagostomum spp., Stephanurus dentatus, Ollulanus spp., Chabertia Syngamus trachea, Ancylostoma spp., Uncinaria spp., Globocephalus spp., Necator spp., Metastrongylus spp., Muellerius capillaris, Protostrongylus spp., Angiostrongylus spp., Parelafostrongylus spp. Aleurostrongylus abstrusus, and Dioctophyma renale, Intestinal ascaris (Ascaridida), for example, Ascaris lumbricoides, Ascaris suum, Ascaridia galli, Parascaris equorum, Enterobius vermicularis (Oxiúro), Toxocara canis, Toxascaris leonine, spine, Skrjaban, ehra, einne for example, Dracunculus medinensis (guinea worm), Spirurida, for example, Thelazia spp. Wuchereria spp., Brugia spp., Onchocerca spp., Dirofilari spp., Dipetalonema spp., Setaria spp., Elaeophora spp., Spirocerca lupi, and Hab-ronema spp., Acantocéfalos (Acanthocephala), for example, Acanthocepha. Macracantho-rhynchus hirudinaceus and Oncicola spp,

[796] Planários (Plathelminthes): Tremáodes (Trematoda), for example, Faciola spp., Fascioloides magna, Paragonimus spp., Dicro-coelium spp., Fasciolopsis buski, Clonorchis sinensis, Schistosoma spp., Trichobilhar-zia spp. alata, Paragonimus spp., and Nanocyetes spp, Cercomeromorpha, in particular Cestoda (tapeworm), for example, Diphyllobothrium spp., Tenia spp., Echinococcus spp., Dipilidium caninum, Multiceps spp., Hymenolepis spp., Mesocestoidespp. spp., Moniezia spp., Anoplocephala spp., Sirometra spp., Anoplocephala spp., and Hymenolepis spp.

[797] The compounds of formula I or II and the compositions containing them are particularly useful for pest control of the orders Diptera, Siphonaptera and Ixodida.

[798] In addition, the use of compounds of formula I or II and the compositions containing them to fight mosquitoes is especially preferred.

[799] The use of compounds of formula I or II and the compositions containing them for the control of flies is an additionally preferred embodiment of the present invention.

[800] In addition, the use of compounds of formula I or II and the compositions containing them to combat fleas is especially preferred.

[801] The use of compounds of formula I or II and the compositions containing them for the control of flies is an additionally preferred embodiment of the present invention.

[802] The compounds of formula I or II and the compositions containing them are also especially useful for combating endoparasites (cylindrical worms, nematodes, acanthocephalous and planar worms).

[803] Compounds of formula I or II can be effective through both contact (through soil, glass, wall, bed net, carpet, sheets or animal parts) and ingestion (eg, baits).

[804] The present invention relates to the therapeutic and non-therapeutic use of compounds of formula I or II to control and / or combat parasites in and / or animals.

[805] Compounds of formulas I or II and compositions containing them can be used to protect animals from attack or parasite infestation by placing them in contact with a parasitically effective amount of compounds of formulas I or II and compositions that contain the same. Therefore, "putting in contact" includes both contact (applying the pesticide mixtures / compositions directly to the parasite, which may include an indirect contact at its P locus, and also administering the pesticide mixtures / compositions directly to the animal) and the contact indirect (apply the compounds / compositions to the parasite locus). The contact of the parasite through application in its locus is an example of a non-therapeutic use of compounds of formula I.

[806] "Locus P", as defined above, means the habitat, food supply, breeding area, area, material or environment in which a parasite is growing or can grow outside the animal. The compounds of the invention can also be applied preventively to places where the occurrence of pests or parasites is expected.

[807] Administration can be carried out both prophylactically and therapeutically.

[808] The administration of the active compounds is carried out directly or in the form of suitable preparations, orally, topically / dermally or parenterally.

[809] For oral administration to warm-blooded animals, compounds of formula I or II can be formulated as animal feed, animal feed premixtures, animal feed concentrates, pills, solutions, pastes, suspensions, soaked articles, gels, tablets, boluses and capsules. In addition, compounds of formula I or II can be administered to animals in their drinking water. For oral administration, the chosen dosage form should provide the animal with 0.01 mg / kg to 100 mg / kg of animal body weight per day of compound of formula I or II, preferably with 0.5 mg / kg at 100 mg / kg of animal body weight per day.

[810] Alternatively, the compounds of formula I or II can be administered to animals parenterally, for example, by intraruminal, intramuscular, intravenous or subcutaneous injection. The compounds of formula I or II can be dispersed or dissolved in a physiologically acceptable carrier for subcutaneous injection. Alternatively, compounds of formula I or II can be formulated into an implant for subcutaneous administration. In addition, compounds of formula I or II can be administered to animals in their drinking water. For parenteral administration, the chosen dosage form should provide the animal with 0.01 mg / kg to 100 mg / kg of animal body weight per day of compound of formula I or II.

[811] The compounds of formula I or II can also be applied topically to animals in the form of baths, dust, powders, collars, medallions, sprays, shampoos, in-place and pour formulations and in ointments or oil emulsions in water or water in oil. For topical application, liquids and sprays usually contain 0.5 ppm to 5,000 ppm and preferably 1 ppm to 3,000 ppm of the compounds of formulas I or II. In addition, compounds of formula I or II can be formulated as ear tags for animals, particularly quadrupeds such as cattle and sheep.

[812] Suitable preparations are:

[813] Solutions such as oral solutions, concentrates for oral administration after dilution, solutions for use on the skin or in body cavities, pouring formulations, gels;

[814] Emulsions and suspensions for oral or dermal administration; semi-solid preparations; Formulations in which the active compound is processed into an ointment base or an oil-in-water or water-in-oil emulsion base; Solid preparations such as powders, premixes or concentrates, granules, tablets, tablets, boluses, capsules; aerosols and inhalers, and articles shaped to contain active compound.

[815] Compositions suitable for injection are prepared by dissolving the active ingredient in a suitable solvent and the optional addition of additional ingredients, such as acids, bases, buffer salts, preservatives and solubilizers. The solutions are filtered and filled sterile.

[816] Suitable solvents are physiologically tolerable solvents, such as water, alkanols such as ethanol, butanol, benzyl alcohol, glycerol, propylene glycol, polyethylene glycols, N-methyl-pyrrolidone, 2-pyrrolidone, and mixtures thereof.

[817] The active compounds can optionally be dissolved in physiologically tolerable vegetable or synthetic oils that are suitable for injection.

[818] Suitable solubilizers are solvents that promote the dissolution of the active compound in the main solvent or prevent its precipitation. Examples are polyvinylpyrrolidone, polyvinyl alcohol, polyoxyethylated castor oil, and polyoxyethylated sorbinate ester.

[819] Suitable preservatives are benzyl alcohol, trichlorobutanol, p-hydroxybenzoic acid esters and n-butanol.

[820] Oral solutions are administered directly. Concentrates are administered orally after dilution prior to the use concentration. Oral and concentrated solutions are prepared according to the state of the art and as described above for injection solutions, sterile procedures are not necessary.

[821] Solutions for use on the skin are dripped on, spread over, rubbed over, sprayed on or sprayed on.

[822] Solutions for use on the skin are prepared according to the state of the art and as described above for injection solutions, sterile procedures are not necessary.

[823] Additional suitable solvents are polypropylene glycol, phenyl ethanol, phenoxy ethanol, ester, such as ethyl or butyl acetate, benzyl benzoate, ethers, such as alkylene glycol alkylether, for example, dipropylene glycol monomethylether, ketones, such as acetone, methylethylketones, hydrocarbons , synthetic and vegetable oils, dimethylformamide, dimethylacetamide, transcutol, solcetal, propylene carbonate, and mixtures thereof.

[824] It may be advantageous to add thickeners during preparation. Suitable thickeners are inorganic thickeners, such as bentonites, colloidal silicic acid, aluminum monoesterate, organic thickeners such as cellulose derivatives, polyvinyl alcohols and their copolymers, acrylates and methacrylates.

[825] Gels are applied to or spread on the skin or introduced into body cavities. Gels are prepared by treating solutions that have been prepared as described in the case of injection solutions that are thick enough to result in a clear material that has an ointment-like consistency. The thickeners used are the thickeners provided above.

[826] Spill formulations are poured over limited areas of the skin, with the active compound penetrating the skin and acting systemically.

[827] Spill formulations are prepared by dissolving, suspending or emulsifying the active compound in suitable skin-compatible solvents or solvent mixtures. If appropriate, other auxiliaries such as dyes, substances promoting bioabsorption, antioxidants, light stabilizers, adhesives are added.

[828] Suitable solvents are water, alkanols, glycols, polyethylene glycols, polypropylene glycols, glycerol, aromatic alcohols, such as benzyl alcohol, phenylethanol, phenoxyethanol, esters, such as ethyl acetate, butyl acetate, benzyl benzoate, ethers, such as alkylene glycol, alkyl ethers, such as dipropylene glycol monomethyl ether, diethylene glycol mono-butyl ether, ketones, such as acetone, methyl ethyl acetone, cyclic carbonates, such as propylene cabonate, ethylene carbonate, aliphatic and / or aromatic hydrocarbons, vegetable or synthetic oils , DMF, dimethylacetamide, N-alkylpyrrolidones, such as N-Methylpyrrolidone, N-butylpyrrolidone or N-octylpyrrolidone, 2-pyrrolidone, 2,2-dimethyl-4-oxymethyl-1,3-dioxolane and formal glycerol.

[829] Suitable dyes are all dyes permitted for use in animals and which can be dissolved or suspended.

[830] Suitable absorption enhancing substances are, for example, DMSO, spreading oils, such as isopropyl myristate, dipropylene glycol pelargonate, silicone oils and copolymers thereof with polyethers, fatty acid esters, triglycerides, fatty alcohols.

[831] Suitable antioxidants are sulfites or metabisulfites, such as potassium metabisulfite, ascorbic acid, butylhydroxytoluene, butylhydroxyanisole, tocopherol.

[832] Suitable light stabilizers are, for example, novantisolic acid.

[833] Suitable adhesives are, for example, cellulose derivatives, starch derivatives, polyacrylate, natural polymers such as alginates, gelatin.

[834] Emulsions can be administered orally, dermally or as injections.

[835] Emulsions are water-in-oil or oil-in-water type.

[836] They are prepared by dissolving the active compound either in the hydrophobic or hydrophilic phase and homogenizing this with the solvent from the other phase with the aid of suitable emulsifiers and, if appropriate, other auxiliaries such as dyes, absorption-promoting substances, preservatives, antioxidants, light stabilizers, viscosity enhancing substances.

[837] Suitable hydrophobic phases (oils) are: liquid arafins, silicone oils, natural vegetable oils, such as sesame oil, almond oil, castor oil, synthetic triglycerides, such as caprylic / capric bigliceride, mixture of triglyceride with vegetable fatty acids of chain length C8-C12 or other specially selected natural fatty acids, partial glyceride mixtures of saturated or unsaturated fatty acids possibly also containing hydroxyl, mono and diglycerides of C8-C10 fatty acids, fatty acid esters such as stearate of ethyl, di-n-butyryl adipate, hexyl laurate, dipropylene glycol perlargonate, esters of a medium chain length branched fatty acid with C16-C18 chain length saturated fatty alcohols, isopropyl myristate, isopropyl palmitate, esters of caprylic / capric acid saturated fatty alcohols of chain length C12-C18, isopropyl stearate, oleyl oleate, oleate of decila, ethyl oleate, ethyl lactate, wax fatty acid esters, such as synthetic duck coccygeal gland fat, dibutyl phthalate, diisopropyl adipate and ester mixtures related to the latter, fatty alcohols such as isotridecyl alcohol, 2-octyldododecanol , cetilstearyl alcohol, oleyl alcohol and fatty acids such as oleic acid and mixtures thereof.

[838] Suitable hydrophilic phases are: water, alcohols such as propylene glycol, glycerol, sorbitol and mixtures thereof.

[839] Suitable emulsifiers are: non-ionic surfactants, for example, polyethoxylated castor oil, polyethoxylated sorbitan monooleate, sorbitan monostearate, glycerol monostearate, polyoxyethyl stearate, polyphenol alkyl phenol; ampholytic surfactants such as di-sodium N-lauryl-p-iminodipropionate or lecithin; anionic surfactants, such as sodium lauryl sulfate, fatty alcohol ether sulphates, monoethanolamine salt of polyglycol mono / dialkyl orthophoric acid ester; active cation surfactants, such as cetyltrimethylammonium chloride.

[840] Additional suitable auxiliaries are: substances that improve viscosity and stabilize the emulsion, such as carboxymethylcellulose, methylcellulose and other cellulose and starch derivatives, polyacrylates, alginates, gelatin, arabic gum, polyvinylpyrrolidone, polyvinyl alcohol, methyl vinyl ether copolymers and maleic anhydride, polyethylene glycols, waxes, colloidal siliceous acid or mixtures of the substances mentioned.

[841] Suspensions can be administered orally or topically / dermally. They are prepared by suspending the active compound in a suspending agent, if appropriate with the addition of other auxiliaries such as wetting agents, dyes, substances promoting bio-absorption, preservatives, antioxidants, light stabilizers.

[842] Liquid suspending agents are all homogeneous solvents and solvent mixtures.

[843] Suitable wetting agents (dispersants) are the emulsifiers given above.

[844] Other auxiliaries that may be mentioned are those given above.

[845] Semi-solid preparations can be administered orally or topically / dermally. They differ from the suspensions and emulsions described above only in their higher viscosity.

[846] For the production of solid preparations, the active compound is mixed with suitable excipients, if appropriate with the addition of auxiliaries, and placed in the desired form.

[847] Suitable excipients are all physiologically tolerable solid inert substances. Those used are inorganic and organic substances. Inorganic substances are, for example, sodium chloride, carbonates such as calcium carbonate, hydrogen carbonates, aluminum oxides, titanium oxide, silicic acids, clayey earth, colloidal or precipitated silica, or phosphates. Organic substances are, for example, sugar, cellulose, foodstuffs and foods such as milk powder, animal meal, meals and pieces of grains, starches.

[848] Suitable auxiliaries are preservatives, antioxidants and / or dyes that have been mentioned earlier.

[849] Other suitable auxiliaries are lubricants and glidants such as magnesium stearate, stearic acid, talc, bentonites, disintegrating promoting substances such as starch or cross-linked polyvinylpyrrolidone, binders such as starch, gelatin or linear polyvinylpyrrolidone, and dry binders such as microcrystalline cellulose.

[850] In general, "effective parasite amount" means the amount of active ingredient needed to achieve an observable effect on growth, including the effects of necrosis, death, delay, prevention and removal, destruction, or, otherwise, decreased occurrence and activity of the target organism. The effective amount for parasites can vary for the various compounds / compositions used in the invention. An effective parasite amount of the compositions will also vary according to the prevailing conditions depending on the desired parasiticidal effect and its duration, target species, mode of application, and the like.

[851] The compositions that can be used in the invention can comprise, in general, from about 0.001 to 95% of the compound of formula I or II.

[852] In general, it is favorable to apply the compounds of formula I or II in total amounts from 0.5 mg / kg to 100 mg / kg per day, preferably from 1 mg / kg to 50 mg / kg per day.

[853] Ready-to-use preparations contain compounds that act against parasites, preferably ectoparasites, in concentrations of 10 ppm to 80 per cent by weight, preferably from 0.1 to 65 per cent by weight, more preferably from 1 to 50 weight percent, more preferably 5 to 40 weight percent.

[854] Preparations that are diluted before use contain compounds that act against ectoparasites in concentrations of 0.5 to 90 weight percent, preferably 1 to 50 weight percent.

[855] Furthermore, the preparations comprise compounds of formula I or II against endoparasites in concentrations of 10 ppm to 2 weight percent, preferably from 0.05 to 0.9 weight percent, most particularly preferably from 0.005 to 0.25 percent by weight.

[856] In a preferred embodiment of the present invention, compositions comprising compounds of formula I or II are applied dermally / topically.

[857] In an additional preferred embodiment, topical application is conducted in the form of articles formatted to contain compost such as collars, medallions, ear tags, bands to attach to body parts, and adhesive strips and sheets.

[858] In general, it is favorable to apply solid formulations that release compounds of formula I or II in total amounts from 10 mg / kg to 300 mg / kg, preferably 20 mg / kg to 200 mg / kg, more preferably, 25 mg / kg to 160 mg / kg in body weight of the treated animal over the course of three weeks.

[859] For the preparation of shaped articles, thermoplastic and flexible plastics, as well as elastomers and thermoplastic elastomers, are used. Suitable plastics and elastomers are polyvinyl, polyurethane, polyacrylate resins, epoxy resins, cellulose, cellulose derivatives, polyamides and polyester that are sufficiently compatible with the compounds of formula I or II. A detailed list of plastics and elastomers, as well as preparation procedures for shaped articles is given, for example, in WO 03/086075.

[860] The compositions to be used according to this invention may also contain other active ingredients, for example, other pesticides, insecticides, herbicides, fungicides, other pesticides, or bactericides, fertilizers such as ammonium nitrate, urea, potash, and superphosphate. , phytotoxicants and plant growth regulators, protectors and nematicides. These additional ingredients can be used sequentially or in combination with the compositions described above, if appropriate, they are also added only immediately to use (tank mix). For example, the plant (s) can be sprayed with a composition of that invention or before or after being treated with other active ingredients.

[861] These agents can be mixed with the agents used according to the invention in a weight ratio of 1:10 to 10: 1. Mixing the compounds of formula I or II or the compositions comprising them in the form of use as pesticides with other pesticides often results in a broader pesticidal spectrum of action.

M.7. Ativadores de canal de cloreto: abamectina, benzoato de emamectina, milbemectina, Iepimectina; M.8. Compostos METI I: fenazaquina, fenpiroximato, pirimidifeno, piridabeno, tebufenpirade, tolfenpirade, flufenerim, rotenona; M.9. Compostos METI II e III: acequinocil, fluaciprim, hidrametilnon; M.10. Desacopladores de fosforilação oxidativa: clorfenapir, DNOC; M.11. Inibidores de fosforilação oxidativa: azociclotina, cihexatina, diafentiuron, óxido de fenbutatin, propargite, tetradifon; M.12. Interruptor de muda: curomazina, cromafenozida, halofenozida, metoxifenozida, tebufenozida; M.13. Sinergistas: butóxido de piperonil, tribufos; M.14. Compostos bloqueadores de canal de sódio: indoxacarbe, metaflumizona; M.15. Fumigantes: brometo de metila, fluoreto de cloropicrina sulfuril; M.16. Bloqueadores de alimentação seletiva: crilotia, pimetrozina, flonicamida; M.17. Inibidores de crescimento de ácaro: clofentezina, hexitiazox, etoxazola; M.18. Inibidores de síntese de quitina: buprofezina, bistrifluron, clorfluazuron, diflubenzuron, flucicloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, triflumuron; M.19. Inibidores de biossíntese de lipídeo: espirodiclofeno, espiromesifeno, espirotetramato; M.20. Agonistas octapaminérgicos: amitraz; M.21. Moduladores de receptor de rianodina: flubendiamida e o composto de ftalamídico (R)-,(S)-3-Clor-N1-{2-metil-4-[1,2,2,2-tetrafluor-1- (trifluormetil)etil]fenil}-N2-(1-metil-2-metilsulfoniletil)ftalamida (M21.1 ) M.22. Vários: Fosfeto de alumínio, amidoflumeto, benclotiaz, benzoximato, bifenazato, borax, bromopropilato, cianida, cienopirafeno, ciflumetofeno, chinometionato, dicofol, fluoroacetato, fosfina, piridalila, pirifluquinazon, enxofre, compostos de enxofre orgânicos, tártaro emético, sulfoxaflor , 4-But-2-inilóxi-6-(3,5-dimetil-piperidin-1-il)-2-fluoro-pirimidina 3-Benzoilamino-N-[2,6-dimetil-4-(1,2,2,2-tetrafluoro-1- trifluorometil-etil)-fenil]-2-fluoro-benzamida (M22.2), 4-[5-(3,5-Dicloro-fenil)- 5-trifluorometil-4,5-diidro-isoxazol-3-il]-2-metil-N-piridin-2-ilmetil-benzamida (M22.3),4-[5-(3,5-Dicloro-fenil)-5-trifluorometil-4,5-diidro-isoxazol-3-il]-2- metil-N-(2,2,2-trifluoro-etil)-benzamida (M22.4),4-[5-(3,5-Dicloro-fenil)-5- trifluorometil-4,5-diidro-isoxazol-3-il]-2-metil-N-tiazol-2-ilmetil-benzamida (M22.5), 4-[5-(3,5-Dicloro-fenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-il]-2- metil-N-(tetraidro-furan-2-ilmetil)-benzamida (M22.6), 4-{[(6-Bromopirid-3- il)metil](2-fluoroetil)amino}furan-2(5H)-ona (M22.7), 4-{[(6-Fluoropirid-3- il)metil](2,2-difluoroetil)amino}furan-2(5H)-ona(M22.8), 4-{[(2-Cloro1,3- tiazolo-5-il)metil](2-fluoroetil)amino}furan-2(5H)-on (M22.9), 4-{[(6- Cloropirid-3-il)metil](2-fluoroetil)amino}furan-2(5H)-on (M22.10), 4-{[(6- Cloropirid-3-il)metil](2,2-difluoroetil)amino}furan-2(5H)-ona(M22.11), 4-{[(6- Cloro-5-fluoropirid-3-il)metil](metil)amino}furan-2(5H)-ona(M22.12), 4-{[(5,6- Dicloropirid-3-il)metil](2-fluoroetil)amino}furan-2(5H)-ona(M22.13), 4-{[(6- Cloro-5-fluoropirid-3-il)metil](ciclopropil)amino}furan-2(5H)-ona(M22.14), 4- {[(6-Cloropirid-3-il)metil](ciclopropil)amino}furan-2(5H)-ona(M22.15), 4-{[(6- Cloropirid-3-il)metil](metil)amino}furan-2(5H)-ona(M22.16), Éster de ácido ciclopropanoacético, 1,1'-[(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-[[(2- ciclopropilacetil)oxi]metil]-1,3,4,4a,5,6,6a,12,12a,12b-decahidro-12-hidróxi- 4,6a,12b-trimetil-11-oxo-9-(3-piridinil)-2H,11H-nafto[2,1-b]pirano[3,4- e]piran-3,6-diil] (M22.17), 8-(2-Ciclopropilmetóxi-4-metil-fenóxi)-3-(6-metil- piridazin-3-il)-3-aza-biciclo[3.2.1]octano (M22.18),; M.23. N-R'-2,2-dihalo-1-R''ciclo-propanecarboxamida-2-(2,6- dicloro-α,α,α-tri-fluoro-p-tolil)hidrazona ou N-R'-2,2-di(R''')propionamida-2-(2,6- dicloro-α,α,α-trifluoro-p-tolil)-hidrazona, em que R' é metil ou etil, halo é cloro ou bromo, R'' é hidrogênio ou metil e R''' é metil ou etil; M.24. Antranilamidas: clorantraniliprol,ciantraniliprol, [4-ciano-2-(1- ciclopropil-etilcarbamoíla)-6-metil-fenil]-amida de ácido 5-Bromo-2-(3-cloro- piridin-2-il)-2H-pirazol-3-carboxílico (M24.1), [2-cloro-4-ciano-6-(1-ciclopropil- etilcarbamoíla)-fenil]-amida de ácido 5-Bromo-2-(3-cloro-piridin-2-il)-2H-pirazol- 3-carboxílico (M24.2), [2-bromo-4-ciano-6-(1-ciclopropil-etilcarbamoíla)-fenil]- amida de ácido 5-Bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carboxílico (M24.3), [2-bromo-4-cloro-6-(1-ciclopropil-etilcarbamoíla)-fenil]-amida de ácido 5-Bromo- 2-(3-cloro-piridin-2-il)-2H-pirazol-3-carboxílico (M24.4), [2,4-dicloro-6-(1- ciclopropil-etilcarbamoíla)-fenil]-amida de ácido 5-Bromo-2-(3-cloro-piridin-2-il)- 2H-pirazol-3-carboxílico (M24.5), [4-cloro-2-(1-ciclopropil-etilcarbamoíla)-6- metil-fenil]-amida de ácido 5-Bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3- carboxílico (M24.6); M.25. Compostos de Malononitrila: CF2HCF2CF2CF2CH2C(CN)2CH2CH2CF3, (2-(2,2,3,3,4,4,5,5-octafluoropentil)-2- (3,3,3-trifluoro-propil)malononitrila), CF3(CH2)2C(CN)2CH2(CF2)5CF2H, (2- (2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptil)-2-(3,3,3-trifluoro-propil)- malononitrila), CF3(CH2)2C(CN)2(CH2)2C(CF3)2F, (2-(3,4,4,4-Tetrafluoro-3- trifluorometil-butil)-2-(3,3,3-trifluoro-propil)-malononitrila), CF3(CH2)2C(CN)2(CH2)2(CF2)3CF3 (2-(3,3,4,4,5,5,6,6,6-Nonafluoro-hexil)-2- (3,3,3-trifluoro-propil)-malononitrila), CF2H(CF2)3CH2C(CN)2CH2(CF2)3CF2H (2,2-Bis-(2,2,3,3,4,4,5,5-octafluoro-pentil)-malononitrila), CF3(CH2)2C(CN)2CH2(CF2)3CF3 (2-(2,2,3,3,4,4,5,5,5-Nonafluoro-pentil)-2-(3,3,3- trifluoro-propil)-malononitrila), CF3(CF2)2CH2C(CN)2CH2(CF2)3CF2H (2- (2,2,3,3,4,4,4-Heptafluoro-butil)-2-(2,2,3,3,4,4,5,5-octafluoro-pentil)- malononitrila), CF3CF2CH2C(CN)2CH2(CF2)3CF2H (2-(2,2,3,3,4,4,5,5-Octafluoro- pentil)-2-(2,2,3,3,3-pentafluoro-propil)-malononitrila), CF2HCF2CF2CF2CH2C(CN)2CH2CH2CF2CF3 (2-(2,2,3,3,4,4,5,5- octafluoropentil)-2-(3,3,4,4,4-pentafluorobutil)-malonodinitrila), CF3(CH2)2C(CN)2CH2(CF2)3CF2H (2-(2,2,3,3,4,4,5,5-octafluoropentil)-2-(3,3,3- trifluoro-butil)-malononitrila); M.26. Interruptores microbianos: Bacillus thuringiensis subsp. Israelensi, Bacillus sphaericus, Bacillus thuringiensis subsp. Aizawai, Bacillus thuringiensis subsp. Kurstaki, Bacillus thuringiensis subsp. Tenebrionis;[862] The following list M of pesticides, together with which the compounds of formulas I or II of the invention can be used and with which potential synergistic effects can be produced, is intended to illustrate the possible combinations, but does not impose any limitation: M.1. Organo (thio) phosphates: acefati, azametiphos, azinfos-ethyl, azinfos-methyl, chloretoxifos, chlorfenvinfos, chlormefos, chlorpyrifos, clorporifosmetil, coumafos, cyanofos, demeton-S-methyl, diazinon, dichloros, dichlorides, dichloros, DDVP, disulfoton, EPN, etion, etoprofos, fanfur, fenamiphos, fenitrotion, fention, flupirazofos, fostiazato, heptenofos, isoxation, malation, mecarbame, metamidofos, metidation, mevinfos, monocrotofos, naled, meteto, paration, paroxylation, oxidation-par fentoate, phorate, fosalone, fosmet, fosfamidon, foxim, pirimiphos-methyl, profenofos, propetanfos, protiofos, piraclofos, piridafention, quinalfos, sulfotep, tebupirinfos, temefos, terfufos, tetrachlorvinfos, tietron, trostros, trifon, trifon, trometz, trifon, trifon, trifon, trifon, tromon, trifon, tromon, tromon, tromon; M.2. Carbamate compounds: aldicarb, alanicarb, bendiocarb, benfuracarb, butocarboxy, butoxycarboxy, carbaryl, carbofuran, carbosulfan, etiofencarb, phenobucarb, formethanate, furatiocarb, isoprocarb, metiocarb, metomil, metycaroxy, metoloxycar, tar, carbamide XMC, xylylcarb, triazamate; M.3. Pyrethroid compounds: acrinatrine, alletrin, d-cis-trans alethrin, d-trans alethrin, bifenthrin, bioallethrin, bioalethrin S-cilclopentenyl, bioresmethrin, cycloprotrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-chalotin, gamma-chalothrin alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empentrine, sphenopherine, etofenprox, fenpropatrin, fenvalerate, flucitrinate, flumetrin, tau-fluvalin, methoprine, praline, halprine, praline, estrogen proflutrin, pyrethrin (pyrethrum), resmetrin, RU 15525, silafluofen, teflutrin, tetramethrin, tralometrine, transflutrin, ZXI 8901; M.4. Imitations of youth hormone: hydroprene, cyinoprene, methoprene, phenoxycarb, pyriproxifen; M.5. Nicotinic receptor agonist / antagonist compounds: acetamiprid, bensultap, cartap hydrochloride, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpiram, nicotine, spinosad (allosteric agonist), spinol (allosteric agonist), thioclamide, tioclidid, and thioclamid, tiocamid, 10 M.6. Chloride channel antagonist compounds linked to GABA: chlordane, endosulfan, gamma-HCH (lindane); ethiprole, fipronil, pirafluprole, pyriprole, vaniliprole, the phenylpyrazole compound of formula M6.1

M.7. Chloride channel activators: abamectin, emamectin benzoate, milbemectin, Iepimectin; M.8. METI I compounds: phenazaquin, fenpyroximate, pyrimidifene, pyridabene, tebufenpirade, tolfenpirade, flufenerim, rotenone; M.9. METI II and III compounds: acequinocil, fluaciprim, hydramethylnon; M.10. Oxidative phosphorylation decouplers: chlorfenapyr, DNOC; M.11. Oxidative phosphorylation inhibitors: azocyclotine, cyhexatin, diafentiuron, fenbutatin oxide, propargite, tetradifon; M.12. Seedling switch: curomazine, chromafenozide, halofenozide, methoxyfenozide, tebufenozide; M.13. Synergists: piperonyl butoxide, tribufos; M.14. Sodium channel blocking compounds: indoxacarb, metaflumizone; M.15. Fumigants: methyl bromide, sulfuryl chloropicrin fluoride; M.16. Selective feeding blockers: crilotia, pimetrozina, flonicamide; M.17. Mite growth inhibitors: clofentezine, hexithiazox, ethoxazole; M.18. Chitin synthesis inhibitors: buprofezin, bistrifluron, chlorfluazuron, diflubenzuron, flucicloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, triflumuron; M.19. Lipid biosynthesis inhibitors: spirodiclofen, spiromesifene, spirotetramate; M.20. Octapaminergic agonists: amitraz; M.21. Ryanodine receptor modulators: flubendiamide and the phthalamide compound (R) -, (S) -3-Chlor-N1- {2-methyl-4- [1,2,2,2-tetrafluor-1- (trifluormethyl) ethyl] phenyl} -N2- (1-methyl-2-methylsulfonylethyl) phthalamide (M21.1) M.22. Miscellaneous: Aluminum phosphide, amidoflumide, benclothiaz, benzoxide, biphenazate, borax, bromopropylate, cyanide, cyienopyraphene, ciflumetophen, chinomethionate, dicofol, fluoroacetate, phosphine, pyridyl, pyrifluquinone, sulfur, sulfur, sulfur But-2-inyloxy-6- (3,5-dimethyl-piperidin-1-yl) -2-fluoro-pyrimidine 3-Benzoylamino-N- [2,6-dimethyl-4- (1,2,2,2 -tetrafluoro-1-trifluoromethyl-ethyl) -phenyl] -2-fluoro-benzamide (M22.2), 4- [5- (3,5-Dichloro-phenyl) - 5-trifluoromethyl-4,5-dihydro-isoxazole -3-yl] -2-methyl-N-pyridin-2-ylmethyl-benzamide (M22.3), 4- [5- (3,5-Dichloro-phenyl) -5-trifluoromethyl-4,5-dihydro- isoxazol-3-yl] -2-methyl-N- (2,2,2-trifluoro-ethyl) -benzamide (M22.4), 4- [5- (3,5-Dichloro-phenyl) -5-trifluoromethyl -4,5-dihydro-isoxazol-3-yl] -2-methyl-N-thiazol-2-ylmethyl-benzamide (M22.5), 4- [5- (3,5-Dichloro-phenyl) -5- trifluoromethyl-4,5-dihydro-isoxazol-3-yl] -2-methyl-N- (tetrahydro-furan-2-ylmethyl) -benzamide (M22.6), 4 - {[(6-Bromopyrid-3-yl ) methyl] (2-fluoroethyl) amino} fu ran-2 (5H) -one (M22.7), 4 - {[(6-Fluoropyrid-3-yl) methyl] (2,2-difluoroethyl) amino} furan-2 (5H) -one (M22.8 ), 4 - {[(2-Chloro1,3-thiazolo-5-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -on (M22.9), 4 - {[(6- Chloropyrid -3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -on (M22.10), 4 - {[(6- Chloropyrid-3-yl) methyl] (2,2-difluoroethyl) amino} furan-2 (5H) -one (M22.11), 4 - {[(6-Chloro-5-fluoropyrid-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (M22 .12), 4 - {[(5,6- Dichloropyrid-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (M22.13), 4 - {[(6- Chlorine -5-fluoropyrid-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (M22.14), 4- {[(6-chloropyrid-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (M22.15), 4 - {[(6-Chloropyrid-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (M22.16), ester of cyclopropanoacetic acid, 1.1 '- [(3S, 4R, 4aR, 6S, 6aS, 12R, 12aS, 12bS) -4 - [[(2-cyclopropylacetyl) oxy] methyl] -1,3,4,4a, 5 , 6.6a, 12.12a, 12b-decahydro-12-hydroxy-4,6a, 12b-trimethyl-11-oxo-9- (3-pyridinyl) -2H, 11H-naphtho [2,1-b] pyran [3,4- e] pyran-3,6-diyl] (M22.17), 8- (2-Cyclopropylmethoxy -4-methyl-phenoxy) -3- (6-methyl-pyridazin-3-yl) -3-aza-bicyclo [3.2.1] octane (M22.18); M.23. N-R'-2,2-dihalo-1-R'cyclo-propanecarboxamide-2- (2,6-dichloro-α, α, α-tri-fluoro-p-tolyl) hydrazone or N-R'- 2,2-di (R ''') propionamide-2- (2,6-dichloro-α, α, α-trifluoro-p-tolyl) -hydrazone, where R' is methyl or ethyl, halo is chlorine or bromine, R '' is hydrogen or methyl and R '''is methyl or ethyl; M.24. Anthranilamides: chlorantraniliprol, cyantraniliprol, [4-cyano-2- (1-cyclopropyl-ethylcarbamoyl) -6-methyl-phenyl] -amide of 5-Bromo-2- (3-chloro-pyridin-2-yl) -2H -pyrazol-3-carboxylic (M24.1), [2-chloro-4-cyano-6- (1-cyclopropyl-ethylcarbamoyl) -phenyl] -acid of 5-Bromo-2- (3-chloro-pyridin- 2-yl) -2H-pyrazol-3-carboxylic (M24.2), [2-bromo-4-cyano-6- (1-cyclopropyl-ethylcarbamoyl) -phenyl] - 5-Bromo-2- ( 5-chloro-pyridin-2-yl) -2H-pyrazol-3-carboxylic (M24.3), [2-bromo-4-chloro-6- (1-cyclopropyl-ethylcarbamoyl) -phenyl] -amide 5 -Bromo- 2- (3-chloro-pyridin-2-yl) -2H-pyrazol-3-carboxylic (M24.4), [2,4-dichloro-6- (1-cyclopropyl-ethylcarbamoyl) -phenyl] - 5-Bromo-2- (3-chloro-pyridin-2-yl) - 2H-pyrazol-3-carboxylic acid amide (M24.5), [4-chloro-2- (1-cyclopropyl-ethylcarbamoyl) -6 - 5-Bromo-2- (3-chloro-pyridin-2-yl) -2H-pyrazol-3-carboxylic acid methyl-phenyl] -amide (M24.6); M.25. Malononitrile Compounds: CF2HCF2CF2CF2CH2C (CN) 2CH2CH2CF3, (2- (2,2,3,3,4,4,5,5-octafluoropentyl) -2- (3,3,3-trifluoro-propyl) malononitrile), CF3 (CH2) 2C (CN) 2CH2 (CF2) 5CF2H, (2- (2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptil) -2- (3.3 , 3-trifluoro-propyl) - malononitrile), CF3 (CH2) 2C (CN) 2 (CH2) 2C (CF3) 2F, (2- (3,4,4,4-Tetrafluoro-3-trifluoromethyl-butyl) - 2- (3,3,3-trifluoro-propyl) -malononitrile), CF3 (CH2) 2C (CN) 2 (CH2) 2 (CF2) 3CF3 (2- (3,3,4,4,5,5, 6,6,6-Nonafluoro-hexyl) -2- (3,3,3-trifluoro-propyl) -malononitrile), CF2H (CF2) 3CH2C (CN) 2CH2 (CF2) 3CF2H (2,2-Bis- (2 , 2,3,3,4,4,5,5-octafluoro-pentyl) -malononitrile), CF3 (CH2) 2C (CN) 2CH2 (CF2) 3CF3 (2- (2,2,3,3,4, 4,5,5,5-Nonafluoro-pentyl) -2- (3,3,3-trifluoro-propyl) -malononitrile), CF3 (CF2) 2CH2C (CN) 2CH2 (CF2) 3CF2H (2- (2,2 , 3,3,4,4,4-Heptafluoro-butyl) -2- (2,2,3,3,4,4,5,5-octafluoro-pentyl) - malononitrile), CF3CF2CH2C (CN) 2CH2 (CF2 ) 3CF2H (2- (2,2,3,3,4,4,5,5-Octafluoro-pentyl) -2- (2,2,3,3,3-pentafluoro-propyl) -malononitrile), CF2HCF2CF2CF2CH2C ( CN) 2CH2CH2CF2CF3 (2- (2,2,3,3, 4,4,5,5- octafluoropentyl) -2- (3,3,4,4,4-pentafluorobutyl) -malonodinitrile), CF3 (CH2) 2C (CN) 2CH2 (CF2) 3CF2H (2- (2,2 , 3,3,4,4,5,5-octafluoropentyl) -2- (3,3,3-trifluoro-butyl) -malononitrile); M.26. Microbial switches: Bacillus thuringiensis subsp. Israelensi, Bacillus sphaericus, Bacillus thuringiensis subsp. Aizawai, Bacillus thuringiensis subsp. Kurstaki, Bacillus thuringiensis subsp. Tenebrionis;

[863] The commercially available compounds of the M group can be found in The Pragaicide Manual, 14th Edition, British Crop Protection Council (2006) among other publications.

[864] The thioamides of formula M6.1 and their preparation have been described in WO 98/28279. Lepimectin is known from Agro Project, PJB Publications Ltd, November 2004. Benclothiaz and its preparation have been described in EP-A1 454621. Metidation and Paraoxon and their preparation have been described in Farm Chemicals Handbook, Volume 88, Meister Publishing Company, 2001. Acetoprole and its preparation was described in WO 98/28277. Metaflumizone and its preparation were described in EP-A1 462 456. Flupirazophos were described in Pesticide Science 54, 1988, pages 237 to 243 and in US 4822779. Pirafluprola and its preparation were described in JP 2002193709 and WO 01/00614. Pyriprole and its preparation have been described in WO 98/45274 and US 6335357. Amidoflumet and its preparation have been described in US 6221890 and JP 21010907. Flufenerim and its preparation have been described in WO 03/007717 and WO 03/007718. AKD 1022 and its preparation have been described in US 6300348. Chloranthranilprola has been described in WO 01/70671, WO 04/067528 and WO 05/118552. Cyantraniliprola has been described in WO 01/70671, WO 04/067528 and WO 05/118552. Anthranilamides M23.1 to M23.6 have been described in WO 2008/72743 and WO 200872783, those M23.7 to M23.12 in WO2007 / 043677. Anthranilamides M 24.1 to M 24.6 have been described in WO 2008/72743 and WO 200872783. Phthalamide M21.1 is known from WO 2007/101540. Cyflumetophen and its preparation have been described in WO 04/080180. The aminoquinazolinone compound pyrifluquinazon has been described in EP A 109 7932. Sulfoximine sulfoxaflor has been described in WO 2006/060029 and WO 2007/149134. The alkynyl ether compound M22.1 is described, for example, in JP 2006131529. Organic sulfur compounds have been described in WO 2007060839. The carboxamide compound M 22.2 is known from WO 2007/83394. The oxazoline compounds M 22.3 to M 22.6 have been described in WO 2007/074789. Furanon compounds M 22.7 to M 22.16 have been described, for example, in WO 2007/115644. The pyripiropene derivative M 22.17 has been described in WO 2008/66153 and WO 2008/108491. The pyridazine compound M 22.18 has been described in JP 2008/115155. Malononitrile compounds have been described in WO 02/089579 WO 02/090320, WO 02/090321, WO 04/006677, WO 05/068423, WO 05/068432 and WO 05/063694.

[865] Partners of fungicidal mixtures are, in particular, those selected from the group consisting of acylalanines, such as benalaxyl, metalaxyl, ofurace, oxadixyl, amine derivatives, such as aldimorf, dodine, dodemorf, fenpropimorf, fenpropidina, guazatina, iminoctadina , spiroxamine, tridemorf, anilinopyrimidines, such as pyrimethanil, mepanipyrim or cirodinil, antibiotics, such as cycloheximide, griseofulvin, casugamycin, natamycin, polyoxin or streptomycin, azoles, such as bitertanol, bromoconazole, cyproconazole, fluoconazole, fluiconazole, difenazazol, dinoxazol, fluiconazole, difnazazol, fluoxazol, zinc, zazolazole hexaconazole, imazalil, metconazole, miclobutanil, penconazole, propiconazole, prochloraz, protioconazole, tebuconazole, triadimefon, triadimenol, triflumizole, triticonazole, flutriafol, dicarboximides, such as iprodione, manioc, zinc, manioc, metam, metiram, propineb, polycarbamate, remove, ziram, zineb, heterocyclic compounds , such as anilazine, benomyl, boscalide, carbendazim, carboxine, oxycarboxine, cyzofamide, dazomet, dithianone, famoxadone, fenamidone, fenarimol, fuberidazole, flutolanil, furametpir, isoprothiolan, mepronil, nuarimol, pyridine, pyridine, pyridine, pyridine, pyridine, pyridine, pyridine thiabendazole, tifluzamide, thiophanate-methyl, thiadinyl, tricyclazole, triforin, copper fungicides, such as Bordeaux mixture, copper acetate, copper oxychloride, basic copper sulphate, nitrophenyl derivatives, such as binapacril, dinocap, dinobutone, nitrophthalisopropyl, phenyl such as fenpiclonil or fludioxonil, sulfur, other fungicides, such as acibenzolar-S-methyl, bentiavalicarb, carpropamide, chlorotalonil, ciflufenamide, cymoxanil, diclomezine, diclocimet, dietofencarb, edifenfós, etaboxam, fluhezamine, fenhezamide -aluminum, iprovalicarb, hexachlorobenzene, metrafenon, pencicuron, propamocarb, phthalite, toloclofos-methyl, quintozene, zoxamide, est robilurines, such as azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, cresoxim-methyl, metominostrobin, orisastrobin, picoxystrobin, pyraclostrobin, pyribencarb or trifloxystrobin, sulfenic acid derivatives, such as captafol, captan, dicloflidan, dicloflide flumetover or flumorfe.

[866] The invertebrate pest, that is, arthropods and nematodes, the plant, soil or water in which the plant is growing can be brought into contact with the compound (s) of formula I or II or the composition (s) containing the same (s) by any application method known in the art. Therefore, "putting in contact" includes both direct contact (apply the compounds / compositions directly on the invertebrate pest or plant - typically on the foliage, stem or roots of the plant) and indirect contact (apply the compounds / compositions to the pest locus) invertebrate or plant).

[867] In addition, invertebrate pests can be controlled by bringing the target pest, its food supply, habitat, breeding site or locus into contact with an effective amount as a pesticide of the compounds of formulas I or II. Therefore, the application can be carried out before or after infection of the locus, growing season, or harvest harvested by the pest.

[868] "Locus" generally means a habitat, breeding site, cultivated plants, plant propagating material (such as seed), soil, area, material or environment in which a pest or parasite is growing or can grow.

[869] In general, "effective parasite amount" means the amount of active ingredient needed to achieve an observable effect on growth, including the effects of necrosis, death, delay, prevention and removal, destruction, or, otherwise, decreased occurrence and activity of the target organism. The effective amount for plague may vary for the various compounds / compositions used in the invention. An effective pest amount of the compositions will also vary according to the prevailing conditions depending on the desired parasiticidal effect and its duration, climate, target species, method of application, and the like.

[870] The compounds of formulas I or II and the compositions comprising said compounds can be used to protect wooden materials, such as trees, fences, cabins, etc. and constructions, such as houses, external bathrooms, factories, but also building materials, furniture, leather, fibers, vinyl articles, electrical wires and cables, etc. ants and / or termites, and to prevent ants and termites from harming the crop or humans (for example, when pests invade public houses and facilities). Compounds are applied not only to the surrounding soil surface or to the soil below the floor to protect wooden materials, but can also be applied to wooden articles, such as concrete surfaces below the floor, niche posts, beams, plywood, furniture , etc., wooden articles, such as particle boards, half panels, etc. and vinyl items, such as coated electrical wires, vinyl sheets, heat insulating material, such as styrene foams, etc. in case of application against ants harming the crop or human beings, the ant controller of the present invention is applied to the crop or to the surrounding soil, or is directly applied to the ant's nest or similar.

[871] The compounds of formulas I and II can also be applied preventively to places where the occurrence of pests or parasites is expected.

[872] Compounds of formulas I or II can also be used to protect growing plants from attack or pest infestation by bringing the plant into contact with a pesticide-effective amount of compounds of formula I or II. Therefore, "putting in contact" includes both direct contact (apply the compounds / compositions directly on the pest and / or plant - typically on the foliage, stem or roots of the plant) and indirect contact (apply the compounds / compositions to the locus of the invertebrate pest or plant).

[873] In the case of soil treatment or application to the place of stay or nesting of pests, the amount of ingredient varies from 0.0001 to 500 g per 100 m2, preferably from 0.001 to 20 g per 100 m2.

[874] Usual application rates for materials are, for example, 0.01 g to 1,000 g of active compound per m2 of treated material, desirably from 0.1 g to 50 g per m2.

[875] Insecticidal compositions for use in impregnating materials typically contain from 0.001 to 95% by weight, preferably from 0.1 to 45% by weight, and more preferably from 1 to 25% by weight of at least one repellent and / or insecticide.

[876] For use in bait compositions, the typical active ingredient content is 0.001% by weight to 15% by weight, desirably 0.001% by weight to 5% by weight of active compound.

[877] For use in spray compositions, the active ingredient content is from 0.001% to 80% by weight, preferably from 0.01% to 50% by weight and, more preferably, from 0.01 to 15% by weight. Weight.

[878] For use in the treatment of crop plants, the application rate of active ingredients of this invention can be in the range of 0.1 g to 4,000 g per hectare, desirably from 25 g to 600 g per hectare, more desirably from 50 g to 500 g g per hectare.

[879] In seed treatment, the rates of active ingredients are, in general, from 0.1 to 10 kg per 100 kg of seed, preferably from 1 to 5 kg per 100 kg of seed, in particular from 1 to 200 g per 100 kg of seed.

[880] The present invention is now illustrated in greater detail by the following examples.

I. PREPARATION EXAMPLES

[881] The procedures described in the following preparation examples were used to prepare compounds of formulas I and II by appropriate modification of the starter material. The resulting compounds, along with the physical data, are listed in table C below.

[882] The products were characterized by HPLC (high performance liquid chromatography mass spectrometry). HPLC was performed using an analytical RP-18 column (Chromolith Speed ROD, from Merck KgaA, Germany) that was operated at 40 ° C. Acetonitrile with 0.1% by volume of a mixture of trifluoroacetic acid / water and 0.1% by volume of trifluoroacetic acid served as a mobile phase; flow rate: 1.8 ml / min and injection volume: 2 μl. EXAMPLE 1: 2-CHLORO-THIAZOL-4-CARBOXYLIC ACID METHYL-PYRIDAZIN-4-IL-AMIDE 2-Chlorothiazole-4-carboxylic acid

[883] 14.0 g (73.1 mmol) of 2-chlorothiazole-4-carboxylic acid ethyl ester were slowly added to a solution of 11.0 g (0.17 mol, 85% purity) of hydroxide potassium in ethanol / water (1: 3, 200 ml) at 0 ° C. The reaction mixture was stirred at room temperature for 16 hours, diluted with water and washed twice with diethyl ether. The aqueous layer was acidified (pH = 5.5) with concentrated HCl and stirred at room temperature for three days. The precipitate formed was collected by filtration and dried at 40 ° C under vacuum to yield 7.0 g (56%, 95% purity) of the title compound as a brown solid. 2-Chloro-thiazol-4-carboxylic acid methyl-pyridazin-4-yl-amide

[884] 200 mg (1.2 mmoles) of 2-chlorothiazole-4-carboxylic acid and 96.1 mg (0.9 mmol) of pyridazin-4-yl-amine were dissolved in 6 ml of dimethyl formamide. 0.15 ml (1.1 mmoles) of triethyl amine, followed by 382 mg (0.73 mmol) of 1H-Benzotriazol-1-yloxythri-pyrrolidinophosphonium hexafluorophosphate (PyBOP), were added and the reaction mixture was stirred at temperature environment for 16 hours. brine was added and the reaction mixture was extracted three times with dichloromethane. The combined organic layers were dried over sodium sulfate, filtered and the solvent was removed under reduced pressure. The obtained residue was purified by flash column chromatography (silica, elution of gradient cyclohexane ^ ethyl acetate ^ methanol) to yield 200 mg (61%, 95% purity) of the title compound. EXAMPLE 2: 2-METHYL-THIAZOL-4-CARBOXYLIC ACID METHYL-PYRIDAZIN-4-IL-AMIDE

[885] 250 mg (1.8 mmoles) of 2-methyl-thiazol-4-carboxylic acid were suspended in 20 ml of toluene and two drops of dimethylformamide were added to the mixture. 0.16 ml of thionylchloride (2.2 mmoles) was added at room temperature and the reaction mixture was stirred at 65 ° C for two hours. After removing the solvent, toluene was added and evaporation was repeated. The residue obtained was then dissolved in 10 ml of dichloromethane and the solution was added dropwise to a solution containing 166 mg of pyridazin-4-ylamine (1.8 mmoles) and 0.27 ml of triethyl amine ( 1.9 mmoles) in 40 ml of dichloromethane. The mixture was stirred at room temperature for 16 hours and the solvent was removed in vacuo. The obtained residue was purified by flash column chromatography (silica, gradient elution cyclohexane ^ ethyl acetate ^ methanol) to yield 50 mg (13%, 99% purity) of the title compound.

[886] The compounds of formula I and the salts or N-oxides thereof, where Rt, Ru and W are CH, V is N and X1 is O, are hereinafter referred to as I'.Aa compounds.

r.t. = tempo de retenção de HPLC 11. Avaliação de atividade pesticida: II.1 Atividade contra afídeo de algodão (Aphis Gossypii, estágios de vida misturados)[887] The compounds of the formula I'.Aa prepared according to the method mentioned above, together with their physico-chemical data, are compiled in table C below. R1 and A, in each case, have the meanings given in the corresponding row in table C. TABLE C. COMPOUNDS OF FORMULA I'.AA PREPARED ACCORDING TO THE Aforementioned METHOD

rt = HPLC retention time 11. Assessment of pesticidal activity: II.1 Activity against cotton aphid (Aphis Gossypii, mixed life stages)

[888] The active compounds were formulated in cyclohexane as a 10.0000 ppm solution supplied in 1.3 ml ABgene® tubes. These tubes were inserted into an automated electrostatic sprinkler equipped with an atomizing nozzle and they served as stock solutions for which smaller dilutions were made in 50% acetone: 50% water (v / v). A nonionic surfactant (Kinetic®) was included in the solution in a volume of 0.01% (v / v).

[889] Cotton plants in the cotyledon stage were infested with aphids prior to treatment by placing a heavily infested leaf from the main aphid colony on top of each cotyledon. Aphids were allowed to transfer overnight to reach an infestation of 80 to 100 aphids per plant and the host leaf was removed. The infested plants were then sprayed by an automated electrostatic plant sprinkler equipped with an atomizing spray nozzle. The plants were dried in the sprinkler chapel, removed from the sprinkler, and then kept in a growing environment under fluorescent lighting for 24 hours at 25 ° C and 20 to 40% relative humidity. The aphid mortality in treated plants, in relation to mortality in untreated control plants, was determined after 5 days.

[890] In that test, compounds 2, 4, 6 and 11, respectively, at 300 ppm showed a mortality of at least 75% compared to untreated controls. II.2 Activity against Peach Aphid (Myzus persicae, mixed life stages)

[891] The active compounds were formulated in cyclohexane as a 10.0000 ppm solution supplied in 1.3 ml ABgene® tubes. These tubes were inserted into an automated electrostatic sprinkler equipped with an atomizing nozzle and they served as stock solutions for which minor dilutions were made in 50% acetone: 50% water (v / v). A nonionic surfactant (Kinetic®) was included in the solution in a volume of 0.01% (v / v).

[892] Pepper plants, in the first true leaf stage, were infested prior to treatment by placing heavily infested leaves from the main colony on top of the treatment plants. The aphids were allowed to be transferred overnight to infest 30 to 50 aphids per plant and the host leaves were removed. The infested plants were then sprayed by an automated electrostatic plant sprinkler equipped with an atomizing spray nozzle. The plants were dried in the sprinkler chapel, removed, and then kept in a growing environment under fluorescent lighting for a 24-hour photoperiod at 25 ° C and 20 to 40% relative humidity. The aphid mortality in the treated plants, in relation to the mortality in untreated control plants, was determined after 5 days.

[893] In that test, compounds 2, 4, and 11, respectively, at 300 ppm showed a mortality of at least 75% compared to untreated controls. II.3 Activity against black bean aphid (Aphis craccivora)

[894] The active compounds were formulated in a 50:50 (vol: vol) acetone: water ratio. The test solution was prepared on the day of use.

[895] Potted black bean plants colonized with 100 to 150 aphids of various stages were sprinkled after the plague population was reported. Population reduction was assessed after 24, 72 and 120 hours.

[896] In that test, compounds 2, 3, 5, 6, and 7, respectively, at 300 ppm showed a mortality of at least 90% compared to untreated controls. II.4 Activity against vetch aphids (Megoura viciae)

[897] The active compounds were formulated at a ratio of 1: 3 (vol: vol) DMSO: water with different concentrations of formulated compounds.

[898] Bean leaf discs were placed on microtiter plates loaded with 0.8 agar agar and 2.5 ppm OPUS ™ (from BASF SE, conazole). The plant discs were sprayed with 2.5 μl of the test solution and 5 to 8 adult aphids were placed on microtiter plates, which were then closed and maintained at 23 ± 1 ° C and 50 ± 5% relative humidity under fluorescent light for 6 days. Mortality was assessed on the basis of vital reproduced aphids. The aphid mortality and fertility were then visually assessed.

[899] In this test, compounds 4, 6, and 7, respectively, at a concentration of the test solution of 2500 mg / L showed a mortality of at least 90%. II.5 Activity against Green Peach Aphid (Myzus persicae)

[900] To assess the control of green peach aphid (Myzus persicae) through systemic media, the test unit consisted of 96-well microtiter plates containing liquid artificial diet under an artificial membrane.

[901] The compounds were formulated using a solution containing 75% v / v water and 25% v / v DMSO. Different concentrations of formulated compounds were pipetted into the aphid diet, using a custom built pipette, in two replications. After application, 5 to 8 adult aphids were placed on the artificial membrane inside the microtiter plate wells. The aphids were then allowed to be absorbed into the treated aphid diet and incubated at about 23 + 1 ° C and about 50 + 5% relative humidity for 3 days. The aphid mortality and fertility was then visually assessed.

[902] In that test, compounds 2, 4, 6 and 7, respectively, at 2500 ppm showed 100% mortality compared to untreated controls.

Claims (23)

1. PYRIDAZINE COMPOUND, characterized by formula I

where A is an oxazole or thiazole or imidazole radical of the formula A1, A2 or A3

where # denotes the point of attachment to the rest of formula I; Z is O or S for z = 0 or Z is N for z = 1; R41, R42, R43 and R51 are, independently of each other, selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C10 alkyl, C2-C10 alkenyl and C2-C10 alkynyl, where the last three mentioned radicals may be unsubstituted, may be partially or totally halogenated or may carry 1, 2 or 3 identical or different Rx substituents, or in which R41, R42, R43 and R51 are further selected from the group consisting of ORa, SRa , C (Y) Rb, C (Y) ORc, S (O) 2Rd, NReRf, heterocyclyl, C3-C10 cycloalkyl, C5-C10 cycloalkenyl and phenyl, in which the last four radicals mentioned may be unsubstituted or may carry 1 , 2, 3, 4 or 5 identical or different Rx substituents; R52, R53 are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C10 alkyl, C2-C10 alkenyl and C2-C10 alkynyl, in which the last three radicals mentioned may be unsubstituted, may be partial or totally halogenated or can carry 1, 2 or 3 identical or different Rx substituents, or in which R52 and R53 are further selected from the group consisting of ORa, SRa, C (Y) Rb, C (Y) ORc, S (O) 2Rd, NReRf, heterocyclyl, C3-C10 cycloalkyl, C5-C10 cycloalkenyl and phenyl, in which the last four radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical or different Rx substituents, and where R61, R62 and R63 are selected from the group consisting of hydrogen, CN, NO2, C1-C10 alkyl, C2-C10 alkenyl and C2-C10 alkynyl, where the last three radicals mentioned may be unsubstituted, they may be partially or fully halogenated or they may carry 1, 2 or 3 identical or different Rx substituents, or where R61, R62 and R63 are further selected from the group consisting of ORa, SRa, C (Y) Rb, C (Y) ORc, S (O) 2Rd, NReRf, C (Y) NRgRh, S (O ) mNReRf, C (Y) NRiNReRf, heterocyclyl, C3-C10 cycloalkyl, C5-C10 cycloalkenyl and phenyl, where the last four radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 identical Ry substituents or many different; V is N; W is C (Rw); with Rw being hydrogen; Rv is selected from the group consisting of hydrogen, halogen, C1-C4 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C4 alkylthio, C1-C3 haloalkylthio, C1-C4alkylsulfinyl, haloalkylsulfinyl C1-C3, C1-C4 alkylsulfonyl, C1-C3 haloalkylsulfonyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4 alkynyl and C1-C4-alkyl-4-C4-alkoxy ; Rt and Ru are selected independently of each other from the group consisting of hydrogen, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy; X1 is O, R1 is hydrogen, C1-C10 alkyl, C1-C10 haloalkyl, C1-C4-alkylen CN, heterocyclyl-C1-C5-alkyl, C1-C5-heteryl-alkyl-C1, C1-C5-alkylen-ORa or C3-C10-cycloalkyl-C1-C5-alkyl; m is 0, 1 or 2; Y is O or S; Ra, Rb, Rc are, independently of each other, selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2- alkenyl C4, C2-C4 haloalkenyl, C2-C4 alkynyl, C1-C4-alkoxy-C1-C4-alkoxy, phenyl, hetaryl, phenyl-C1-C4-alkyl and heteryl-C1-C4-alkyl, where the aromatic ring in the last four radicals mentioned can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1 haloalkyl -C4, C1-C4 alkoxy and C1-C4 haloalkoxy; Rd is selected from the group consisting of C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4 alkynyl, alkoxy-C1-C4-alkyl-C1-C4, phenyl, hetaryl, phenyl-alkyl-C1-C4 and hetaryl-alkyl-C1-C4, in which the aromatic ring in the last four radicals mentioned may be unsubstituted or may carry 1 , 2, 3, 4 or 5 substituents which, independently of each other, are selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy ; Re, Rf are independently selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, halo C2-C4 alkenyl, C2-C4 alkynyl, C1-C4 alkoxy-C1-C4 alkyl, C1-C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C1-C4 alkylsulfonyl, C1-C4 haloalkylsulfonyl, phenyl, phenyl, phenyl, phenylcarbonyl hetarylcarbonyl, hetarylsulfonyl, phenyl-alkyl-C1-C4 and hetaryl-alkyl-C1-C4, in which the aromatic ring in the last eight mentioned radicals can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents that, independently from each other, they are selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; or Re and Rf, together with the nitrogen atom to which they are attached, form a 5- or 6-membered saturated or unsaturated heterocycle, which can carry an additional heteroatom which is selected from the group consisting of O, S and N as an atom member of the ring and in which the heterocycle can be unsubstituted or can carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from the group consisting of halogen, cyano, nitro, alkyl C1-C4, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; Rg, Rh are, independently of each other, selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2-C4 alkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl, hetaryl, phenyl-C1-C4-alkyl and hetaryl-C1-C4-alkyl, where the aromatic ring in the last four radicals mentioned may not be substituted or can carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; Ri is selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkylmethyl, C3-C6 halocycloalkyl, C2-C4 alkenyl, C2-C4 haloalkyl, C2- C4, C1-C4-alkoxy-C1-C4-alkyl, phenyl and phenyl-C1-C4-alkyl, where the phenyl ring in the last two radicals mentioned may be unsubstituted or may carry 1, 2, 3, 4 or 5 substituents which, independently of each other, are selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy; Rx are independently selected from the group consisting of cyano, nitro, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylthio, C1-C4 haloalkylthio, C1-C4 alkylsulfinyl, C1- C4 haloalkylsulfinyl, C1-C4 alkylsulfonyl, C1-C4 haloalkylsulfonyl, C1-C10 alkylcarbonyl, C3-C6 cycloalkyl, 5- to 7-membered heterocyclyl, phenyl, C3-C6-cycloalkoxy, 3- to 6-membered heterocyclyl and phenoxy, in which the last six radicals mentioned they can be unsubstituted or they can carry 1, 2, 3, 4 or 5 radicals Ry; and where Ry is selected from the group consisting of halogen, cyano, nitro, C1-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C4 alkylthio, C1-C4 haloalkylthio, C1-C4 haloalkylthio C1-C4, C1- C4 haloalkylsulfinyl, C1-C4 alkylsulfonyl, C1-C4 haloalkylsulfonyl, C1-C4 alkylcarbonyl, C1-C4 haloalkylcarbonyl, C3-C6 cycloalkyl, C3-C6 halo, C4-alkylen C2-C4 and C1-C4-C4-alkyl-C1-C4-alkoxy; wherein said heterocyclyl is a monocyclic heterocyclic radical with 5, 6, 7 or 8 saturated, partially unsaturated or unsaturated members, or bicyclic heterocyclic radical with 8 to 10 saturated, partially unsaturated or unsaturated members; wherein the monocyclic and bicyclic heterocyclic radicals comprise, as ring members, 1, 2, 3 or 4 heteroatoms selected from the group consisting of N, O and S; wherein said hetaryl is a monocyclic heteroaromatic radical with 5 or 6 members or a bicyclic heteroaromatic with 8 to 10 members; and wherein the monocyclic and bicyclic heteroaromatic radicals comprise, as ring members, 1, 2, 3 or 4 heteroatoms selected from the group consisting of N, O and S; or its agriculturally or veterinarily acceptable salts, N-oxides, enantiomers or diastereoisomers thereof. 2. COMPOUND according to claim 1, characterized in that R1 is hydrogen or C1-C3 alkyl. COMPOSITE according to any one of claims 1 to 2, characterized in that Rt and Ru are hydrogen. COMPOSITE according to any one of claims 1 to 3, characterized in that Z is O. COMPOSITE according to any one of claims 1 to 3, characterized in that Z is S. 6. COMPOSITE according to any one of claims 1 to 3, characterized in that Z is N. COMPOSITE according to any one of claims 1 to 6, characterized in that A is an A1 radical. 8. COMPOUND, according to claim 7, characterized in that R41 is selected from the group consisting of hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. 9. COMPOUND according to any one of claims 7 to 8, characterized in that R51 is selected from the group consisting of hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl . 10. COMPOUND according to any one of claims 7 to 9, characterized in that R61 is selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl , heterocyclyl-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkyl and C1-C4-CN-alkyl. COMPOSITE according to any one of claims 1 to 6, characterized in that A is an A2 radical. 12. COMPOUND, according to claim 11, characterized in that R42 is selected from the group consisting of hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. 13. COMPOUND according to any one of claims 11 to 12, characterized in that R52 is selected from the group consisting of hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl . COMPOSITE according to any one of claims 11 to 13, characterized in that R62 is selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl , heterocyclyl-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkyl and C1-C4-CN-alkyl. COMPOSITE according to any one of claims 1 to 6, characterized in that A is an A3 radical. 16. COMPOUND, according to claim 15, characterized in that R43 is selected from the group consisting of hydrogen, halogen, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl. 17. COMPOUND according to any one of claims 15 to 16, characterized in that R53 is selected from the group consisting of hydrogen, halogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6 cycloalkyl and C3-C6 halocycloalkyl . 18. A COMPOUND according to any one of claims 15 to 17, characterized in that R63 is selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 haloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl , heterocyclyl-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkyl and C1-C4-CN-alkyl. 19. METHOD FOR INVERTEBRATE PEST CONTROL, in which invertebrate pests are arthropod pests, characterized by the method of understanding to treat pests, their food supply, their habitat or their breeding site or a plant, seed, soil, area, material or environment in which pests grow or can grow, or the materials, plants, seeds, soil, surfaces or spaces to be protected from pest attack or infestation with an amount effective as a compound pesticide, or a salt or an N-oxide thereof, as defined in any one of claims 1 to 18. 20. METHOD, according to claim 19, characterized by the invertebrate pests being insects. 21. METHOD, according to claim 20, characterized by the invertebrate pests being insects of the order Homoptera. 22. METHOD FOR PROTECTING PLANT PROPAGATION MATERIAL and / or the plants that grow from it, characterized by the method comprising treating the plant propagating material with an effective amount as a compound's pesticide, or an agriculturally acceptable salt or a N-oxide thereof, as defined in any of claims 1 to 18. 23. PLANT PROPAGATION MATERIAL, characterized in that it is treated with at least one compound, as defined in any one of claims 1 to 18, and / or an agriculturally acceptable salt or an N-oxide thereof.