BR0006685A - Catalyst for the production of alpha-olefins and production method of alpha-olefins - Google Patents

Catalyst for the production of alpha-olefins and production method of alpha-olefins

Info

Publication number
BR0006685A
BR0006685A BR0006685-0A BR0006685A BR0006685A BR 0006685 A BR0006685 A BR 0006685A BR 0006685 A BR0006685 A BR 0006685A BR 0006685 A BR0006685 A BR 0006685A
Authority
BR
Brazil
Prior art keywords
catalyst
olefins
alpha
production
clay
Prior art date
Application number
BR0006685-0A
Other languages
Portuguese (pt)
Inventor
Haruhito Sato
Masahiko Kuramoto
Masami Watanabe
Shinji Tanaka
Original Assignee
Idemitsu Petrochemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Petrochemical Co filed Critical Idemitsu Petrochemical Co
Publication of BR0006685A publication Critical patent/BR0006685A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B01J35/40—
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Patente de Invenção: <B>"CATALIZADOR PARA A PRODUçãO DE ALFA-OLEFINAS E MéTODO DE PRODUçãO DE ALFA-OFELINAS"<D>. A invenção proporciona um catalisador para produção de <244>-olefinas e um método de uso do catalisador para produção de <244>-olefinas, cujas vantagens são que o catalisador exibe alta atividade de oligomerização de etileno e a quantidade dos produtos secundários tais como componentes pesados e componentes cerosos que poderão ser produzidos no método é reduzida. Em um aspecto, o catalisador é preparado contactando (a) qualquer de argila, minerais de argila e compostos de troca iónica em camadas com (b) um complexo de metal de transição cujo metal central é um metal de transição dos Grupos 8 a 10 da Tabela Periódica, por um período de pelo menos 10 minutos, e o catalisador é usado para oligomerização de etileno para produzir <244>-olefinas. Em outro aspecto, o catalisador é preparado contactando (a') qualquer de argila, minerais de argila ou compostos de troca iónica em camadas que foram processados com uma alquilação, com (b) um complexo de metal de transição cujo metal central é um metal de transição dos Grupos 8 a 10 da Tabela Periódica, onde o componente (a') é tal que sua suspensão formada por meio de adição de um meio inerte a ele libera no máximo 1 mmol por grama do componente (a'), do agente de alquilação do meio, e o catalisador é usado para oligomerização de etileno para produzir <244>-olefinas.Invention Patent: <B> "CATALYST FOR THE PRODUCTION OF ALPHA-OLEFINS AND METHOD OF PRODUCTION OF ALPHA-OFELINAS" <D>. The invention provides a catalyst for producing <244> -olefins and a method of using the catalyst for producing <244> -olefins, the advantages of which are that the catalyst exhibits high ethylene oligomerization activity and the quantity of by-products such as heavy components and waxy components that could be produced in the method is reduced. In one aspect, the catalyst is prepared by contacting (a) any of clay, clay minerals and layered ion exchange compounds with (b) a transition metal complex whose central metal is a transition metal of Groups 8 to 10 of the Periodic Table, for a period of at least 10 minutes, and the catalyst is used for ethylene oligomerization to produce <244> -olefins. In another aspect, the catalyst is prepared by contacting (a ') any of clay, clay minerals or layered ion exchange compounds that have been processed with an alkylation, with (b) a transition metal complex whose central metal is a metal of transition from Groups 8 to 10 of the Periodic Table, where the component (a ') is such that its suspension formed by adding an inert medium to it releases a maximum of 1 mmol per gram of the component (a'), of the agent alkylation medium, and the catalyst is used for ethylene oligomerization to produce β-olefins.

BR0006685-0A 1999-06-11 2000-06-08 Catalyst for the production of alpha-olefins and production method of alpha-olefins BR0006685A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP16499999 1999-06-11
PCT/JP2000/003724 WO2000076659A1 (en) 1999-06-11 2000-06-08 CATALYST FOR α-OLEFIN PRODUCTION AND PROCESS FOR PRODUCING α-OLEFIN

Publications (1)

Publication Number Publication Date
BR0006685A true BR0006685A (en) 2001-05-02

Family

ID=15803931

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0006685-0A BR0006685A (en) 1999-06-11 2000-06-08 Catalyst for the production of alpha-olefins and production method of alpha-olefins

Country Status (9)

Country Link
EP (1) EP1106249A4 (en)
JP (1) JP4532045B2 (en)
KR (1) KR20010074817A (en)
CN (1) CN1313789A (en)
AU (1) AU5246200A (en)
BR (1) BR0006685A (en)
CA (1) CA2337055A1 (en)
ID (1) ID28180A (en)
WO (1) WO2000076659A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1054021A4 (en) * 1998-12-02 2002-10-16 Idemitsu Petrochemical Co Catalyst for olefin polymerization and process for producing olefin polymer with the catalyst
CN1267191C (en) * 1999-12-30 2006-08-02 菲利浦石油公司 Organic metal catalyst composition
KR20020084170A (en) 2000-03-06 2002-11-04 이데미쓰세끼유가가꾸가부시끼가이샤 Catalyst for vinyl compound polymerization and process for producing vinyl polymer
EP1305271B1 (en) * 2000-08-03 2009-03-04 E.I. Du Pont De Nemours And Company Continuous manufacturing process for alpha-olefins
US7037988B2 (en) * 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
JP4996779B2 (en) * 2006-02-22 2012-08-08 日本ポリプロ株式会社 Olefin polymerization catalyst component, method for producing the catalyst component, and method for producing an olefin polymer with a polymerization catalyst using the catalyst component
KR101579880B1 (en) 2012-05-10 2016-01-04 주식회사 엘지화학 Process for oligomerization of ethylene
CN103724146B (en) * 2013-12-20 2016-06-15 浙江大学 A kind of reduce the method for content of polyethylene wax in ethylene oligomerization reaction
AR124333A1 (en) * 2020-12-15 2023-03-15 Shell Int Research A PROCESS TO PRODUCE a-OLEFINS

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08332390A (en) * 1995-04-05 1996-12-17 Nippon Oil Co Ltd Oligomerization catalyst of olefin and preparation of olefin oligomer
JPH1081635A (en) * 1996-07-16 1998-03-31 Idemitsu Kosan Co Ltd Production of catalyst for producing olefin oligomer and production of olefin oligomer using the same catalyst
JPH11269224A (en) * 1998-03-20 1999-10-05 Idemitsu Petrochem Co Ltd Catalyst for olefinic polymer preparation and preparation of olefinic polymer
JP2000086717A (en) * 1998-09-14 2000-03-28 Idemitsu Petrochem Co Ltd Catalyst for polymerizing olefin or styrene, and production of polymer
EP1054021A4 (en) * 1998-12-02 2002-10-16 Idemitsu Petrochemical Co Catalyst for olefin polymerization and process for producing olefin polymer with the catalyst

Also Published As

Publication number Publication date
EP1106249A1 (en) 2001-06-13
EP1106249A4 (en) 2003-06-04
ID28180A (en) 2001-05-10
CN1313789A (en) 2001-09-19
KR20010074817A (en) 2001-08-09
JP4532045B2 (en) 2010-08-25
WO2000076659A1 (en) 2000-12-21
CA2337055A1 (en) 2000-12-21
AU5246200A (en) 2001-01-02

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Legal Events

Date Code Title Description
FA10 Dismissal: dismissal - article 33 of industrial property law
B11Y Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette]