BG109329A - Method for electroextraction of zinc - Google Patents

Method for electroextraction of zinc

Info

Publication number
BG109329A
BG109329A BG109329A BG10932905A BG109329A BG 109329 A BG109329 A BG 109329A BG 109329 A BG109329 A BG 109329A BG 10932905 A BG10932905 A BG 10932905A BG 109329 A BG109329 A BG 109329A
Authority
BG
Bulgaria
Prior art keywords
zinc
sulphite
blende
solution
cathode
Prior art date
Application number
BG109329A
Other languages
Bulgarian (bg)
Inventor
Пенчо ЛЕСИДРЕНСКИ
Иван ГРУЕВ
Никола НИКОЛОВ
Атанас АПОСТОЛОВ
Славея СТОЯНОВА
Никола ПЕТРОВ
Ангел ГРОЗЕВ
Цветан АЛЕКСАНДРОВ
Original Assignee
"Оловно Цинков Комплекс" Ад
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by "Оловно Цинков Комплекс" Ад filed Critical "Оловно Цинков Комплекс" Ад
Priority to BG109329A priority Critical patent/BG109329A/en
Priority to PCT/BG2006/000019 priority patent/WO2007045055A2/en
Publication of BG109329A publication Critical patent/BG109329A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/16Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00Obtaining zinc or zinc oxide
    • C22B19/20Obtaining zinc otherwise than by distilling
    • C22B19/22Obtaining zinc otherwise than by distilling with leaching with acids
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08Sulfuric acid, other sulfurated acids or salts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

The method finds application in the hydrometallurgical zinc production. It helps achieve higher quality of the cathode zinc and improved electrochemical characteristics of the process. Following elimination of admixtures, the sulphuric acid solutions resulting from the sulphuric acid extraction of burnt blende are subjected to electroextraction, as a result of which the zinc gets detached from the cathode, while a part of the exhaust electrolyte is fed for dissolving new blende portions. A dosed quantity of sulphite reagent is continuously added to the purified zinc sulphate solution undergoing electrolysis, such dosed quantity ensuring 300 to 1500 mg/l SO3-2 concentration in the solution. Sulphurous acid or water solutions of its salts (alkaline sulphites or hydrosulphites, ammonium sulphite or hydrosulphite, zinc sulphite), preferably solution of sodium hydrosulphite NaHSO3, are used as a sulphite reagent.
BG109329A 2005-10-20 2005-10-20 Method for electroextraction of zinc BG109329A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
BG109329A BG109329A (en) 2005-10-20 2005-10-20 Method for electroextraction of zinc
PCT/BG2006/000019 WO2007045055A2 (en) 2005-10-20 2006-10-19 Method for electroextaction of zinc

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BG109329A BG109329A (en) 2005-10-20 2005-10-20 Method for electroextraction of zinc

Publications (1)

Publication Number Publication Date
BG109329A true BG109329A (en) 2007-04-30

Family

ID=37872467

Family Applications (1)

Application Number Title Priority Date Filing Date
BG109329A BG109329A (en) 2005-10-20 2005-10-20 Method for electroextraction of zinc

Country Status (2)

Country Link
BG (1) BG109329A (en)
WO (1) WO2007045055A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101824549A (en) * 2010-04-15 2010-09-08 赤峰中色库博红烨锌业有限公司 Method for improving purity of zinc ingot by filtering waste electrolyte
CN103774185B (en) * 2014-01-24 2016-05-04 中国环境科学研究院 The device that a kind of dry method is removed the crystallization of electrolytic zinc anode plate zinc sulfate and collected
CN113249592B (en) * 2021-05-13 2022-09-20 西南科技大学 Method for selectively leaching zinc from zinc ferrite-containing waste residue by mechanical activation and directional reduction
CN117926346A (en) * 2024-03-22 2024-04-26 清华大学 Process for producing electrodeposited zinc by leaching zinc-containing paint slag in ammonium chloride solution

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4053552A (en) * 1976-03-15 1977-10-11 General Mills Chemicals Co. Solvent extraction of zinc from sulfite-bisulfite solution
US4439288A (en) * 1983-07-11 1984-03-27 Exxon Research & Engineering Company Process for reducing Zn consumption in zinc electrolyte purification
US4488942A (en) * 1983-08-05 1984-12-18 Omi International Corporation Zinc and zinc alloy electroplating bath and process
CA1231137A (en) * 1985-09-12 1988-01-05 Ian H. Warren Method for monitoring the quality of znso.sub.4 electrolyte containing sb (v)

Also Published As

Publication number Publication date
WO2007045055A3 (en) 2007-11-15
WO2007045055A2 (en) 2007-04-26

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