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Priority to BG102896ApriorityCriticalpatent/BG64169B1/en
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Publication of BG64169B1publicationCriticalpatent/BG64169B1/en
Low-Molecular Organic Synthesis Reactions Using Catalysts
(AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof
(AREA)
Abstract
The invention relates to a method for the preparation of ivermectine by the application of rhodium-containing catalytic system for selective hydration of ivermectine B1a and B1b. The ivermectine has considerable antiparasitic activity and is used as antihelminth agent, ektoparasiticide, insecticide and acaricide.The catalytic system is produced in situ, by adding an activator,trimethylaminooxide (CH3)3NO or dichlorbis (acetonitrile) palladium Pd Cl2(CH3CN)2, which can accept triphenylphosphinic ligands,to the RhCl(Ph3)3 Wilkinson complex for selective hydration of double carbon-carbon bonds. In this way the time needed for the activation of the complex, and the total time of the process are reduced. 2 claims
BG102896A1998-11-041998-11-04Method for the preparation of ivermectine by making use of a rhodium-containing catalytic system for selective hydration
BG64169B1
(en)