BE904257A - S, S-DITERTIOBUTYL ETHYLPHOSPHONODITHIOATE, ITS PREPARATION AND ITS USE. - Google Patents
S, S-DITERTIOBUTYL ETHYLPHOSPHONODITHIOATE, ITS PREPARATION AND ITS USE.Info
- Publication number
- BE904257A BE904257A BE0/216291A BE216291A BE904257A BE 904257 A BE904257 A BE 904257A BE 0/216291 A BE0/216291 A BE 0/216291A BE 216291 A BE216291 A BE 216291A BE 904257 A BE904257 A BE 904257A
- Authority
- BE
- Belgium
- Prior art keywords
- halogen atom
- ethylphosphonodithioate
- ditertiobutyl
- preparation
- tert
- Prior art date
Links
- GFTATZBXSYXGRK-UHFFFAOYSA-N ethyl-hydroxy-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical compound CCP(O)(S)=S GFTATZBXSYXGRK-UHFFFAOYSA-N 0.000 title abstract 2
- 238000002360 preparation method Methods 0.000 title abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 3
- BDFAOUQQXJIZDG-UHFFFAOYSA-N 2-methylpropane-1-thiol Chemical compound CC(C)CS BDFAOUQQXJIZDG-UHFFFAOYSA-N 0.000 abstract 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 2
- 241000489975 Diabrotica Species 0.000 abstract 1
- 240000008042 Zea mays Species 0.000 abstract 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 235000005822 corn Nutrition 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000005645 nematicide Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4075—Esters with hydroxyalkyl compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
L'ethylphosphonodithioate de S,S-ditertiobutyle utilisable comme insecticide et nématicide, par exemple pour la lutte contre Corn rootworm (Diabrotica sp.), et son procédé de préparation qui consiste à faire réagir un halogénure d'acide éthylphophonique de formule générale CH3 CH2 - P(=0)(X)-X1 dans laquelle : - X représente un atome d'halogène, - X1 représente un atome d'halogène ou un groupe tertiobutyle avec, quand X1 représente un atome d'halogène, deux équivalents molaire ou, quand X1 représente le groupe tertiobutyle, unéquivalent molaire de méthyl-2 propane thiol 2, en présence d'une base.The ethylphosphonodithioate of S, S-ditertiobutyle usable as insecticide and nematicide, for example for the fight against Corn rootworm (Diabrotica sp.), And its preparation process which consists in reacting an ethylphophonic acid halide of general formula CH3 CH2 - P (= 0) (X) -X1 in which: - X represents a halogen atom, - X1 represents a halogen atom or a tert-butyl group with, when X1 represents a halogen atom, two molar equivalents or , when X1 represents the tert-butyl group, a molar equivalent of 2-methyl propane thiol 2, in the presence of a base.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70360285A | 1985-02-21 | 1985-02-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE904257A true BE904257A (en) | 1986-08-20 |
Family
ID=24826031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE0/216291A BE904257A (en) | 1985-02-21 | 1986-02-20 | S, S-DITERTIOBUTYL ETHYLPHOSPHONODITHIOATE, ITS PREPARATION AND ITS USE. |
Country Status (23)
| Country | Link |
|---|---|
| JP (1) | JPS61194092A (en) |
| KR (1) | KR860006205A (en) |
| CN (1) | CN86101647A (en) |
| AT (1) | ATA45986A (en) |
| AU (1) | AU5373186A (en) |
| BE (1) | BE904257A (en) |
| BR (1) | BR8600725A (en) |
| CA (1) | CA1273355A (en) |
| DD (1) | DD243286A5 (en) |
| DE (1) | DE3605471A1 (en) |
| DK (1) | DK79186A (en) |
| ES (1) | ES8800006A1 (en) |
| FI (1) | FI860758A (en) |
| FR (1) | FR2577555A1 (en) |
| GB (1) | GB2171409B (en) |
| GR (1) | GR860459B (en) |
| HU (1) | HUT39979A (en) |
| IT (1) | IT1188702B (en) |
| LU (1) | LU86313A1 (en) |
| NL (1) | NL8600440A (en) |
| OA (1) | OA08208A (en) |
| PL (1) | PL258040A1 (en) |
| ZA (1) | ZA861245B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4752604A (en) * | 1985-07-29 | 1988-06-21 | Stauffer Chemical Company | S,S-di-(tertiary alkyl) thiophosphonate insecticides |
| AU6963387A (en) * | 1986-03-10 | 1987-09-17 | Sumitomo Chemical Company, Limited | Trithiophosphonic acid esters |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4472390A (en) * | 1980-12-31 | 1984-09-18 | Rhone-Poulenc Agrochimie | S-Alkyls-(tertiary alkyl) alkylphosphonodithioate insecticides and nematocides |
-
1986
- 1986-02-18 IT IT19442/86A patent/IT1188702B/en active
- 1986-02-18 GR GR860459A patent/GR860459B/en unknown
- 1986-02-19 FR FR8602456A patent/FR2577555A1/en active Pending
- 1986-02-19 CN CN198686101647A patent/CN86101647A/en active Pending
- 1986-02-19 CA CA000502199A patent/CA1273355A/en not_active Expired - Fee Related
- 1986-02-19 DD DD86287160A patent/DD243286A5/en not_active IP Right Cessation
- 1986-02-19 AU AU53731/86A patent/AU5373186A/en not_active Abandoned
- 1986-02-19 ZA ZA861245A patent/ZA861245B/en unknown
- 1986-02-20 ES ES552210A patent/ES8800006A1/en not_active Expired
- 1986-02-20 KR KR1019860001207A patent/KR860006205A/en not_active Application Discontinuation
- 1986-02-20 GB GB08604233A patent/GB2171409B/en not_active Expired
- 1986-02-20 BE BE0/216291A patent/BE904257A/en not_active IP Right Cessation
- 1986-02-20 FI FI860758A patent/FI860758A/en not_active IP Right Cessation
- 1986-02-20 LU LU86313A patent/LU86313A1/en unknown
- 1986-02-20 DE DE19863605471 patent/DE3605471A1/en not_active Withdrawn
- 1986-02-20 HU HU86712A patent/HUT39979A/en unknown
- 1986-02-20 PL PL25804086A patent/PL258040A1/en unknown
- 1986-02-20 DK DK79186A patent/DK79186A/en not_active Application Discontinuation
- 1986-02-21 OA OA58790A patent/OA08208A/en unknown
- 1986-02-21 AT AT0045986A patent/ATA45986A/en not_active IP Right Cessation
- 1986-02-21 BR BR8600725A patent/BR8600725A/en unknown
- 1986-02-21 NL NL8600440A patent/NL8600440A/en not_active Application Discontinuation
- 1986-02-21 JP JP61037135A patent/JPS61194092A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CA1273355A (en) | 1990-08-28 |
| JPH0574597B2 (en) | 1993-10-18 |
| GB2171409B (en) | 1988-07-20 |
| GR860459B (en) | 1986-05-27 |
| DD243286A5 (en) | 1987-02-25 |
| ATA45986A (en) | 1988-07-15 |
| IT1188702B (en) | 1988-01-28 |
| BR8600725A (en) | 1986-11-04 |
| LU86313A1 (en) | 1987-09-10 |
| IT8619442A0 (en) | 1986-02-18 |
| ES552210A0 (en) | 1987-10-16 |
| DK79186D0 (en) | 1986-02-20 |
| GB8604233D0 (en) | 1986-03-26 |
| DK79186A (en) | 1986-08-22 |
| AU5373186A (en) | 1986-08-28 |
| PL258040A1 (en) | 1987-10-19 |
| OA08208A (en) | 1987-10-30 |
| ZA861245B (en) | 1986-10-29 |
| IT8619442A1 (en) | 1987-08-18 |
| JPS61194092A (en) | 1986-08-28 |
| FR2577555A1 (en) | 1986-08-22 |
| HUT39979A (en) | 1986-11-28 |
| NL8600440A (en) | 1986-09-16 |
| GB2171409A (en) | 1986-08-28 |
| DE3605471A1 (en) | 1986-08-21 |
| FI860758A0 (en) | 1986-02-20 |
| FI860758A (en) | 1986-08-22 |
| CN86101647A (en) | 1986-11-26 |
| ES8800006A1 (en) | 1987-10-16 |
| KR860006205A (en) | 1986-09-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RE | Patent lapsed |
Owner name: MAY ET BAKER LTD Effective date: 19890228 |