BE622789A - - Google Patents

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Publication number
BE622789A
BE622789A BE622789DA BE622789A BE 622789 A BE622789 A BE 622789A BE 622789D A BE622789D A BE 622789DA BE 622789 A BE622789 A BE 622789A
Authority
BE
Belgium
Prior art keywords
desc
page number
clms page
theory
iktxi
Prior art date
Application number
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English (en)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Publication of BE622789A publication Critical patent/BE622789A/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/0008—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain
    • C09B23/005—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain the substituent being a COOH and/or a functional derivative thereof
    • C09B23/0058—Methine or polymethine dyes, e.g. cyanine dyes substituted on the polymethine chain the substituent being a COOH and/or a functional derivative thereof the substituent being CN
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/10—The polymethine chain containing an even number of >CH- groups
    • C09B23/105—The polymethine chain containing an even number of >CH- groups two >CH- groups
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • G03C1/83—Organic dyestuffs therefor
    • G03C1/832—Methine or polymethine dyes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Description


   <Desc/Clms Page number 1> 
 
 EMI1.1 
 



  4#Àppatiéh dé mtiétdd fan di ,l,bift.rlt.àyift. jt!tW'6. tt oebàuit6 ttMt 1 
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 w L tift\i8h'fJ:l.bn e ppO"" i la P'i>atNt"1Í di MtUf* colorâtes de y..b.ir et, 4d Iii', . partir dj 44t's â..1fkr'ht114.n'j it i1 aa'16f'ij coloiJuate9 de piuh.sé ##HYlriii d'úa .fb" iné1ïh!be tif là chaîne ()iYIM,th1flt i. ...atplàUI6 . du .14bOw Gène* Lt t.! 6j'. colorantes lis pôlyiûitldhég, qui Ütid,'n.. ftcrtb 1e grouj  mthlrts eyunooubatitui in poaltloft lif4ft te 

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 EMI2.1 
 ptdf nom d  c4gfno polyaithliiwl (loi 46oiËqàün xbe4gé   U*1 la non clutî4rdt oolhtaaoyht.ibitUoa ht oeuf 3em<tnt davxnuem 1)rél)at4bles par 1b dveuipeiiisnt Ik litr.t du t4trxnodthyl&Mt tcàbjit do lli4tv#oiition bdis Uk o4d& jibui ii pf4'* pM'<'Upn tl tti&a ootohs<'''onoaa<tU!!t & ari de ûomposijo de .

   trü u1 aeyr,lt,,lr de fileiiÉlé 
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 dan# laqu11e <tt Z' raNér#an ou M 8 dis .Ü8tltrtt- pi.bitt QOluU18 par 4x4I11Ili. eh ou bon 4ui piuvbïît !ti"4 '* Mttbita vu diff tentât au un* partie Ioaw.atd aiijaeéttte d'un noyiu à 5 ou 6 atsoraua, 1. Càl bh6nnl BuWi4Uiâ| 06 eCt4 quoi it l"flpt'4sbute Lili a1btlt1;

   Wa:.<ao4 11. 1 .'.vit u 11 et Rtl tÍ1vdbg&b.', uh àlQri-, ,u un 4trl1. été sen fait le COIPOIS ot "1i41(j('*y4hVHd.1' "..t!".'ahhruiMI.i14 4v lfe un donnez d'iona cymâcg4hbi pue Ica,i n d,,,ghu4 4ït,,üi un donntJf d'1una cygnitisi dé di9uiï Jl 1i bDmpû 4 Wdyano- éthylidtmw de formulé 
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 dan  lapilli 2 et Êt i...,i I' katz là i itâtu fi cation qûo dans la 'tit( i tiwy lii. 11 tàît bzz ce compta &Vbc uti composé aU8  ptibie 41 rougir iité Son groupe méthyle pou leemte la Wti4eë . ra dé Pelmàé thyne, ta demie** faeti' dé l'ait pkt1 pki* dûttd#n  nation t.v<6c un r4&cti ,mpb;

  ,a bu éoptiiètifin oxtdâaé** Les cempoi4a dt toimule il hen cependant ? a Boin dtttre isolés à ghâque cohUinsufeioh il a. 3.ri Au contraires il$ peUfett #te  ûmàèuk m dit ',a n3,sultdrd d'un compoàt dé rrmtr i à ufi àbiîiibuë diidhil cyanogènn et un réactif 4lotteopiàiég 1 condition* de tiaatietlë du 1eiudddi dûnt'ormi-, ment à ,inv;,r, âoât dirt4e*dteâ aul\ant le  cao. îles 

 <Desc/Clms Page number 3> 

 
 EMI3.1 
 j $UY<j! ftµ pa 4 teMp4r#tmro ambiant* ou à tompé- en prègenof de qolv'ba et/o4 4ÇA40ntes d<t dmaaa.', ph# htâna 1ra,pa, tea 4vanegese du procédé, contorm4m4nt l'.vam4, m,.ar4 aa â et 1 diversité 401q nynthèmen de m4t:t&<!  <!>l >f|flï fc#?f pO8 î-bi? s partir 49 pr<a4uii;

  i inteynA4dte. l>df 4  H  jl4wit 4 ?? roefciftrça oopantoa, connus 1 IHoileraents pirépfliRWfi è% d'un d  flf*ur 4 lon yanoi5ñ !  h**  tpas 4<le<(yyd< en Qenvr< cc'm'M Mr )!t p)aj.e!! Ot li#laa et Avec Fr#ndo sta,,# dt fttûrç  " a.a par P44ottpa d'un patpr trt4qoyle de iU44i phtr#. xaa dçn composés qui contiennent un aF9ttPt 9. iab,m c r4aero ççmte le B,5.odipAti?Htf 4#41 'onerg 4* lfgol4*  y nAft étlciu4| don pyiiftiooy) * r5j, dee in4*an9 |.t |i don d4rty4g do IA rltodgntnt, doo 5-Oîiyfchio  tfrîwrlqftlm 1*tt$ 94 don 44rivée do 1#4çtds bar.

   ponts 4f prf4il'o r4egttot dont lq* groupti as thy1q |\wlâ.ephi3.i* titre coiidqnq4o 'fça.,eur av dal çprApoe4j 45-f FOpl fl? #ont connu  par 14 obtg4o dom MMMM èeq flptflfl, C9<ww gels de 9*gQX44go dwo) 4dww, Poe feis 40 )OQypoapne)oyclo<nM)0 ou d t dérivés 4e VttiyUne pendus po UU i #  etre copule  p çiyUon avec des êeatnen 014 eeg çonipouée analogues aux aminés* çn colorantee d polYM414no PftttVit zaza fmployafg guem bien darp 14 phot|ocwp*4* oomrç* p4t4r* 03,0- ranpe 40 ''a <">H  Wf?f nolersniîe d que dina la etpt4re d fifjt3.e8, en particulter pour la teinture de tes pl< om4ntq expll'luont la piroc46# montOV4 ..Mi',|,((H nprm'-iiirii/\ G xl,rhx4PY+MOhd -tpyrazQ, 

 <Desc/Clms Page number 4> 

 
 EMI4.1 
 
 EMI4.2 
 mot jpy on 9F# bzz 4' x 4< ph.nY3. tY''^"''r d'n, ne rtlt1pn Qt ttr. '4nQ. 4pr' 1tQn Ù, 3.;

   9 . p.t{.p fi, W9d\d." .'p,r I1P1' 11:IrtP"t,ré at $ 4 c dt. ,²q a 'rf' 4''Q ,q .j throh pr4pptt < ÁFbl z Ir A,l'..ij, q" 469' . f.d 4'$' 4. 1i!' '.R'-I' 11'jA 1 '-t' Q"4r. +"qlqr A 9'ij"tr Pt'", t r )4 09 Mrv,",p PQrPJ fp"Ra. F14#  1 4p, "'-,;4. 



  4 Ta^i+;1 thk % (rJ\YI.". l" 4,. h r';?'.r t !t< mttr. 1 c t'r' 'n4pl. 
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  'P'!'jr dkit'''' 1 1< trqpret4i 1Îp,"A'l. 4; - 1414t 
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 Acet d<t M{I1Irt 'il.b" 'J' p, "''r'JI!'1I''I!'P''''''''' """'I' ",,,,,t"!!' '"'"""""""7' l .J"II\ '-tt"",",,,, 1'/' 'T"J r" J ' " '"""'1\' ' a34-p .\ t;1 t .P 

 <Desc/Clms Page number 5> 

 
 EMI5.1 
  211$ ;s'1 l14th4b.i OH il3 0.(1 lr dU3 11t-:.U!b  i 
 EMI5.2 
 li1 Sh tfl1FJnrtt btH.d1Hi' A ..httt4htAubt tih quut c:ltÍu .1j w dé ;wh.'riY, mbhbau1ttitij ave<ï 0 e. d.Q$te 'b1iqu' d. 1..dldi.'thO"  th)'l1.Mu.cyunc.luo&t:

  t.qije eti 0.9 Et de ttJ.dtt dU 1d . ,..1co<>1. nfll.nÙ6mont 1.0 54 (environ 6$ de 18 th4er.1t) tt En tútaU"t'bDu1i1! 1.&5 . dj dby1aptG. lily'rifdrl.c,,nitu.utr à . 0,6$ III dp'llirt' l1dêfi.M4iGirL1. t 0,¯, 14 i UadlJ doh. 11 . 4'licco1 " #4 ps c. 4ij 1.4 mi. d. tth11ft.i 6hd., 0,S 1. thft bj til lÀ théorie'), d) Ëh ld.aht .uim 1 à. de .lifii"hlbilU"'Q,t()1Iot ltrtrail.its+a.n aYid 1.61 J. du  â&|)dé4 . pr'4prAr4 'onrlj'm61rl6nt à ieicapîé 1 dans là 811. tlt&li*'\\oni-\t111 .n pHdatitàh dt 1,4 mil de tï*lâthyiandn*é hèndfcmittt t,3 g. 



  '.nYl "1\ t.1 &. 1a 1illr'J ËXLË ht LI jd\,h"' Un* mâtiné colorante de .ffoj'lw1t 
 EMI5.3 
 
 EMI5.4 
 feat préparé  pur iaacï".i;ar 1jendâht i ddeui6o d# 106 do et 3* 'y Iribttrtc,Kc..rilj.liôilt l'14 1 ici. di sulfate do dïm4theld à 140dd ttâ iüâà4ité, 6kfXÜittbà krec 

 <Desc/Clms Page number 6> 

   0,65 g. d'or-éthyoxyéthylidène-malodinitr@le et 0,25 g. de NaCN   
 EMI6.1 
 c1;U18 10 Mit d*al0eel< Rohdianient <0 ejt [,vc6'tri 1 d th4or1.). p.Ft 260.&'.O dé 1*1oool <Mtjd.uuM<fabttoi dans l'acétone 570 m  . 



   EXEMPLE 4. 
 EMI6.2 
 



  Lta tt&ti&ï dolorah\.1i a- kbàlé nra11" 
 EMI6.3 
 
 EMI6.4 
 sont Cal&bt&ri.4i8 dihS Itn i4<t prépati...o suit : 
 EMI6.5 
 M4 'th' Vit toiltoio   .&. 1i'111tltiri .qrptt9n4a. 



  1114ithy rQrm. ' tkd$ ' L.M JHff11 30 'là> '-TOU- '..16ô.1 "St, <;$M ; Ab"II)" j 8   4j..Tâ .) ftJb"'O...01-i'" #i )-Otl a4ti.a' l'W..twt, tUt 411) a424 Pdtt ï c6HS Qu tI.N " 1$04U' 4cI4t."u u. 0 ' J Én faisant bÓ'd.t1it' i.b? tf*f de 1Jlh4"Y1";JJIh,ioi 
 EMI6.6 
 4w,yh,, ô'le C4 dé pmdiâ6,tylâà 

 <Desc/Clms Page number 7> 

 
 EMI7.1 
 o44obingAldéhyde dans 10 roi, d'anhydride acétique. Rendement 0, It t ( ln vh"flJ\ 1Z 4 de 14 théorie), b) Coiffl 4) sans ,c,mhylr.i.ncrbnal.d3hydo, mais cependant finq 1,6 IZ- de .âtl2,.nt,ly.ënebaa3.nzol,in.. 



  "'",..1d.4hydar:t.. R nd*ffient bzz e. (environ 13 % do la théorie), c) En faisant bouillir 4 reflux pendant 5 minutes 4 gf d .pdny.wGhyl..x,Glzoaalylidxr PYaolone- avae îî|7'µ  4  lphnyl.rn3thyl.  anilinomxathy,nepyrazo-. 



  StOnfwS e Q,j5 gt d# cyanure de sodium dans 10 m1. de pyridino, m \1r4ftrHU" 4 mt. de ppriQ.in" fît en MQ4.t1.fiH't Ano HC3,, Rir>4 wñt} Qtf (-nvi.rQn. 'i' dt't la .théorie). 



  -- - dj pAr addition dlgne uplution <quou8  cM.orhyddquc dq Q#l mole do chlorure de qen,;old1c,:onium à une solution de 2f1, . Q h:xy.'lthyl,,.tr [d''cytnaSth lidèn  pyraaolone  µ t.laa at pféeemoe de 0,1 Mole dltthylate do sodium glcoolMue h g 4 Q00e Bondownti .tl.(unv1r'on 33 de la th6o,  rif, ) . 
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  REVENDICATIONS, 
 EMI7.3 
 1. PrQc64 Pour 19 )rijpaX'i.!.t1ol1 de mat;1lirel co3.o. rentoq d* rolymâthinlt Of ",oy.:mo8\.lb:stituéo raz I),rt1r de composée d' 'aloo3<yhyl.id&ifta de .formée 
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 1 G!" Igoyle 1 0 Zi 
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 dans laquelle 2 ab Z' relJretentent4 ou bien des eubatituante foai t1 vnnto, comme par exemple ON ou COR, qui. peuvent 8tre ou différents t ou upe partie coneti tl,u,nte adjacente d'un noyau à 5 çu 6 atotaea, le cae chllnt l!Iubst11.nU, ce à c;:8tÓ (ie nuot R f'epr6sente un alocyla, o...atcúYlo, aryle, 0- 4rylef oh 3' et nt lthydrl.'lg,nt, %in alcoyle ou urylp, enr4e. t4fiaâ par le JPflt que l'on trajisforroe le composa o{< aleo;r/j- thll1dno uvec un âcmnaur d'ions cynnocène, en un composa a1 de rorroule 
 EMI7.6 
 

 <Desc/Clms Page number 8> 

 
 EMI8.1 
 OÇ elq1.t. avec un 7a3 fI",tl,Jt.;lQh e rÓagi:

  r avec ..on CrQupo thy, en 4 IQrp" 41t frQ4@ .tQij r'VPdqi9n !., çrc6. ' pur le t4t4p que 11pn e4t fsf 9PMp<)aa9thyU 4voq 40 4nn@"r 4a cynpEt "lu. 1 'Qn tv&nfQrl1' 1 ',> W41IAn Q;;.nA e"1tr h lI+p;34 "''''Qfnoth²4.M, fiYi Y!t:I ttaacs av"l;t \ont (:p)48 i;G'.)''"iMi.i M r&gip ' r 8Y':;V'Qf\ c;rQpO mt;hf1t. en <wi'ï'9 ?.a #,13* lt\UrM Af1nO..11 1#, 9ü ')'0"'46 e4$Yi4fl Hy, Q4 4e#ltr 4a .voWIR'P 1I
BE622789D 1962-01-22 BE622789A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD7786762 1962-01-22

Publications (1)

Publication Number Publication Date
BE622789A true BE622789A (fr)

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Family Applications (1)

Application Number Title Priority Date Filing Date
BE622789D BE622789A (fr) 1962-01-22

Country Status (1)

Country Link
BE (1) BE622789A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0317308A2 (fr) * 1987-11-19 1989-05-24 EASTMAN KODAK COMPANY (a New Jersey corporation) Elément photographique contenant des colorants filtres jaunes ayant des groupes tricyanovinyles

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0317308A2 (fr) * 1987-11-19 1989-05-24 EASTMAN KODAK COMPANY (a New Jersey corporation) Elément photographique contenant des colorants filtres jaunes ayant des groupes tricyanovinyles
EP0317308A3 (en) * 1987-11-19 1989-11-08 Eastman Kodak Company (A New Jersey Corporation) Photographic element containing yellow filter dyes having tricyanovinyl groups

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