BE568895A - - Google Patents

Info

Publication number

BE568895A

BE568895A BE568895DA BE568895A BE 568895 A BE568895 A BE 568895A BE 568895D A BE568895D A BE 568895DA BE 568895 A BE568895 A BE 568895A

Authority

BE

Belgium

Prior art keywords

sep

aromatic

amino group

arylamide

articles

Prior art date

Links

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• 239000000463 material Substances 0.000 claims description 11
• MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 claims description 9
• 238000000034 method Methods 0.000 claims description 9
• 229920000642 polymer Polymers 0.000 claims description 9
• 239000002253 acid Substances 0.000 claims description 7
• 125000003277 amino group Chemical group 0.000 claims description 7
• 125000003118 aryl group Chemical group 0.000 claims description 7
• 239000000987 azo dye Substances 0.000 claims description 5
• 150000001875 compounds Chemical class 0.000 claims description 5
• 238000010168 coupling process Methods 0.000 claims description 5
• 238000005859 coupling reaction Methods 0.000 claims description 5
• 229920000728 polyester Polymers 0.000 claims description 5
• 125000000623 heterocyclic group Chemical group 0.000 claims description 4
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
• 239000003638 reducing agent Substances 0.000 claims description 2
• 150000007513 acids Chemical class 0.000 claims 2
• 238000004519 manufacturing process Methods 0.000 claims 1
• 229920001098 polystyrene-block-poly(ethylene/propylene) Polymers 0.000 description 38
• HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
• LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Substances [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 21
• 239000000975 dye Substances 0.000 description 13
• 235000011121 sodium hydroxide Nutrition 0.000 description 12
• LRHPLDYGYMQRHN-UHFFFAOYSA-N n-butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 10
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
• 239000000203 mixture Substances 0.000 description 6
• CXWXQJXEFPUFDZ-UHFFFAOYSA-N Tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 5
• 239000004744 fabric Substances 0.000 description 5
• LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
• 238000000859 sublimation Methods 0.000 description 5
• 239000000080 wetting agent Substances 0.000 description 5
• 230000001808 coupling Effects 0.000 description 4
• -1 heterocyclic hydroxy-carboxylic acids Chemical class 0.000 description 4
• YSAVZVORKRDODB-UHFFFAOYSA-N Diethyl tartrate Chemical compound CCOC(=O)C(O)C(O)C(=O)OCC YSAVZVORKRDODB-UHFFFAOYSA-N 0.000 description 3
• JVBXVOWTABLYPX-UHFFFAOYSA-L Sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 3
• UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
• 238000004043 dyeing Methods 0.000 description 3
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
• LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
• FYOWZTWVYZOZSI-UHFFFAOYSA-N Thiourea dioxide Chemical compound NC(=N)S(O)=O FYOWZTWVYZOZSI-UHFFFAOYSA-N 0.000 description 2
• 239000007859 condensation product Substances 0.000 description 2
• 238000009998 heat setting Methods 0.000 description 2
• 238000010438 heat treatment Methods 0.000 description 2
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• 239000001044 red dye Substances 0.000 description 2
• 239000007858 starting material Substances 0.000 description 2
• NNAVBEAARXTLEG-UHFFFAOYSA-N 2-(10-methylundecyl)phenol Chemical compound CC(C)CCCCCCCCCC1=CC=CC=C1O NNAVBEAARXTLEG-UHFFFAOYSA-N 0.000 description 1
• GXJQMKFJQFGQKV-ZHACJKMWSA-N 2-[methyl-[(E)-octadec-9-enoyl]amino]ethanesulfonic acid Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)N(C)CCS(O)(=O)=O GXJQMKFJQFGQKV-ZHACJKMWSA-N 0.000 description 1
• JSCNDCWUFHAJQL-UHFFFAOYSA-N 2-hydroxy-9H-carbazole-3-carboxylic acid Chemical compound N1C2=CC=CC=C2C2=C1C=C(O)C(C(=O)O)=C2 JSCNDCWUFHAJQL-UHFFFAOYSA-N 0.000 description 1
• JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxybutan-1-ol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 description 1
• UYJXRRSPUVSSMN-UHFFFAOYSA-P Ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 1
• SWXVUIWOUIDPGS-UHFFFAOYSA-N Diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
• 108010010803 Gelatin Proteins 0.000 description 1
• 150000001447 alkali salts Chemical class 0.000 description 1
• 125000005037 alkyl phenyl group Chemical group 0.000 description 1
• QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
• 150000004982 aromatic amines Chemical class 0.000 description 1
• JNIGYQOBELCEIZ-MAKDUZDQSA-L barium(2+);5-chloro-4-methyl-2-[(2Z)-2-(2-oxonaphthalen-1-ylidene)hydrazinyl]benzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N\N=C/2C3=CC=CC=C3C=CC\2=O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N\N=C/2C3=CC=CC=C3C=CC\2=O)=C1S([O-])(=O)=O JNIGYQOBELCEIZ-MAKDUZDQSA-L 0.000 description 1
• 239000001045 blue dye Substances 0.000 description 1
• 239000004359 castor oil Substances 0.000 description 1
• 239000007795 chemical reaction product Substances 0.000 description 1
• 239000003795 chemical substances by application Substances 0.000 description 1
• 239000000084 colloidal system Substances 0.000 description 1
• 239000011928 denatured alcohol Substances 0.000 description 1
• 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
• 238000006193 diazotization reaction Methods 0.000 description 1
• 235000014113 dietary fatty acids Nutrition 0.000 description 1
• 239000002270 dispersing agent Substances 0.000 description 1
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
• 239000000194 fatty acid Substances 0.000 description 1
• 150000004665 fatty acids Chemical class 0.000 description 1
• 150000002191 fatty alcohols Chemical class 0.000 description 1
• 229920000159 gelatin Polymers 0.000 description 1
• 239000008273 gelatin Substances 0.000 description 1
• 235000019322 gelatine Nutrition 0.000 description 1
• 235000011852 gelatine desserts Nutrition 0.000 description 1
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
• 229910052757 nitrogen Inorganic materials 0.000 description 1
• IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
• GQKZRWSUJHVIPE-UHFFFAOYSA-N pentan-2-yl acetate Chemical compound CCCC(C)OC(C)=O GQKZRWSUJHVIPE-UHFFFAOYSA-N 0.000 description 1
• 230000001681 protective Effects 0.000 description 1
• 108090000623 proteins and genes Proteins 0.000 description 1
• 102000004169 proteins and genes Human genes 0.000 description 1
• 239000002994 raw material Substances 0.000 description 1
• 235000010288 sodium nitrite Nutrition 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 150000004763 sulfides Chemical class 0.000 description 1
• 238000005406 washing Methods 0.000 description 1