BE549642A - - Google Patents

Info

Publication number

BE549642A

BE549642A BE549642DA BE549642A BE 549642 A BE549642 A BE 549642A BE 549642D A BE549642D A BE 549642DA BE 549642 A BE549642 A BE 549642A

Authority

BE

Belgium

Prior art keywords

fraction

column

product

carbazol

fluoranthene

Prior art date

Links

• Espacenet
• Global Dossier
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• 238000000034 method Methods 0.000 claims description 28
• GZSUIHUAFPHZSU-UHFFFAOYSA-N 9-ethyl-2,3-dihydro-1h-carbazol-4-one Chemical compound C12=CC=CC=C2N(CC)C2=C1C(=O)CCC2 GZSUIHUAFPHZSU-UHFFFAOYSA-N 0.000 claims description 27
• 239000000470 constituent Substances 0.000 claims description 23
• DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 claims description 18
• 238000009835 boiling Methods 0.000 claims description 15
• 238000005194 fractionation Methods 0.000 claims description 14
• YSDMAZWOTSTTDC-UHFFFAOYSA-N fluoranthene pyrene Chemical compound C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1.C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 YSDMAZWOTSTTDC-UHFFFAOYSA-N 0.000 claims description 13
• 239000007789 gas Substances 0.000 claims description 5
• 238000005406 washing Methods 0.000 claims description 4
• LJZJHELAFLRVSU-UHFFFAOYSA-N anthracene;phenanthrene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21.C1=CC=C2C3=CC=CC=C3C=CC2=C1 LJZJHELAFLRVSU-UHFFFAOYSA-N 0.000 claims description 3
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
• 238000011144 upstream manufacturing Methods 0.000 claims 1
• MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 32
• 239000011280 coal tar Substances 0.000 description 28
• GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 24
• BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 20
• 238000004821 distillation Methods 0.000 description 12
• 239000011269 tar Substances 0.000 description 11
• 238000011282 treatment Methods 0.000 description 10
• 238000001704 evaporation Methods 0.000 description 9
• 230000008020 evaporation Effects 0.000 description 8
• YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 8
• 238000000926 separation method Methods 0.000 description 7
• 238000000354 decomposition reaction Methods 0.000 description 5
• 239000000126 substance Substances 0.000 description 5
• HIAGSPVAYSSKHL-UHFFFAOYSA-N 1-methyl-9h-carbazole Chemical compound N1C2=CC=CC=C2C2=C1C(C)=CC=C2 HIAGSPVAYSSKHL-UHFFFAOYSA-N 0.000 description 4
• 238000012545 processing Methods 0.000 description 4
• 238000010438 heat treatment Methods 0.000 description 3
• 239000000463 material Substances 0.000 description 3
• 238000010992 reflux Methods 0.000 description 3
• 238000007711 solidification Methods 0.000 description 3
• 230000008023 solidification Effects 0.000 description 3
• UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical class C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
• 229910052799 carbon Inorganic materials 0.000 description 2
• 239000003245 coal Substances 0.000 description 2
• 239000000203 mixture Substances 0.000 description 2
• 239000012808 vapor phase Substances 0.000 description 2
• 239000004484 Briquette Substances 0.000 description 1
• 238000000998 batch distillation Methods 0.000 description 1
• FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 239000000571 coke Substances 0.000 description 1
• 230000000052 comparative effect Effects 0.000 description 1
• 230000000295 complement effect Effects 0.000 description 1
• 238000009833 condensation Methods 0.000 description 1
• 230000005494 condensation Effects 0.000 description 1
• 238000001944 continuous distillation Methods 0.000 description 1
• 238000001816 cooling Methods 0.000 description 1
• 238000013461 design Methods 0.000 description 1
• 239000003599 detergent Substances 0.000 description 1
• 239000003085 diluting agent Substances 0.000 description 1
• 230000002349 favourable effect Effects 0.000 description 1
• 238000000227 grinding Methods 0.000 description 1
• 229930195733 hydrocarbon Natural products 0.000 description 1
• 150000002430 hydrocarbons Chemical class 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 238000012805 post-processing Methods 0.000 description 1
• 239000011347 resin Substances 0.000 description 1
• 229920005989 resin Polymers 0.000 description 1
• 230000000717 retained effect Effects 0.000 description 1
• 238000005070 sampling Methods 0.000 description 1
• 238000012360 testing method Methods 0.000 description 1
• 238000012546 transfer Methods 0.000 description 1
• 238000005292 vacuum distillation Methods 0.000 description 1