BE444655A - - Google Patents

Info

Publication number

BE444655A

BE444655A BE444655DA BE444655A BE 444655 A BE444655 A BE 444655A BE 444655D A BE444655D A BE 444655DA BE 444655 A BE444655 A BE 444655A

Authority

BE

Belgium

Prior art keywords

pyrophoric

nickel

catalyst

hydrogen

catalysts

Prior art date

Links

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• 239000003054 catalyst Substances 0.000 claims description 17
• 239000000203 mixture Substances 0.000 claims description 8
• 239000001257 hydrogen Substances 0.000 claims description 7
• 229910052739 hydrogen Inorganic materials 0.000 claims description 7
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
• 238000000034 method Methods 0.000 claims description 6
• 238000010531 catalytic reduction reaction Methods 0.000 claims description 5
• 150000001408 amides Chemical class 0.000 claims description 4
• 239000002184 metal Substances 0.000 claims description 4
• 229910052751 metal Inorganic materials 0.000 claims description 4
• 150000008064 anhydrides Chemical class 0.000 claims description 2
• 238000004519 manufacturing process Methods 0.000 claims description 2
• 230000007935 neutral effect Effects 0.000 claims description 2
• 230000003647 oxidation Effects 0.000 claims description 2
• 238000007254 oxidation reaction Methods 0.000 claims description 2
• 238000006722 reduction reaction Methods 0.000 claims description 2
• 150000002736 metal compounds Chemical class 0.000 claims 1
• 230000000737 periodic effect Effects 0.000 claims 1
• 150000007519 polyprotic acids Polymers 0.000 claims 1
• 238000000926 separation method Methods 0.000 claims 1
• 239000002904 solvent Substances 0.000 claims 1
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
• WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 15
• 229910052759 nickel Inorganic materials 0.000 description 8
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
• 239000001301 oxygen Substances 0.000 description 6
• 229910052760 oxygen Inorganic materials 0.000 description 6
• 239000010941 cobalt Substances 0.000 description 5
• 229910017052 cobalt Inorganic materials 0.000 description 5
• 239000002253 acid Substances 0.000 description 4
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
• 239000007789 gas Substances 0.000 description 4
• BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 3
• BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
• 239000007795 chemical reaction product Substances 0.000 description 3
• 238000002485 combustion reaction Methods 0.000 description 3
• 229910052757 nitrogen Inorganic materials 0.000 description 3
• 150000003141 primary amines Chemical class 0.000 description 3
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
• CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
• 238000006243 chemical reaction Methods 0.000 description 2
• 238000001816 cooling Methods 0.000 description 2
• 229910052802 copper Inorganic materials 0.000 description 2
• 239000010949 copper Substances 0.000 description 2
• 150000002148 esters Chemical class 0.000 description 2
• 150000004679 hydroxides Chemical class 0.000 description 2
• BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 2
• KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• VXRSJNWYTPYKKR-UHFFFAOYSA-N 3,3-diaminodecane-2,9-dione Chemical compound C(C)(=O)C(CCCCCC(C)=O)(N)N VXRSJNWYTPYKKR-UHFFFAOYSA-N 0.000 description 1
• 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
• 229910008293 Li—C Inorganic materials 0.000 description 1
• 150000008065 acid anhydrides Chemical class 0.000 description 1
• 150000007513 acids Chemical class 0.000 description 1
• 206010000496 acne Diseases 0.000 description 1
• 239000004480 active ingredient Substances 0.000 description 1
• 150000003855 acyl compounds Chemical class 0.000 description 1
• 150000001412 amines Chemical class 0.000 description 1
• 229910021529 ammonia Inorganic materials 0.000 description 1
• 150000003863 ammonium salts Chemical class 0.000 description 1
• 239000007864 aqueous solution Substances 0.000 description 1
• 238000006555 catalytic reaction Methods 0.000 description 1
• 150000001868 cobalt Chemical class 0.000 description 1
• UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
• 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
• ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
• 238000010924 continuous production Methods 0.000 description 1
• XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
• 150000004985 diamines Chemical class 0.000 description 1
• 238000004821 distillation Methods 0.000 description 1
• 238000001035 drying Methods 0.000 description 1
• 150000002431 hydrogen Chemical class 0.000 description 1
• 238000005984 hydrogenation reaction Methods 0.000 description 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
• 150000003949 imides Chemical class 0.000 description 1
• 150000002500 ions Chemical class 0.000 description 1
• 238000002844 melting Methods 0.000 description 1
• 230000008018 melting Effects 0.000 description 1
• 150000002815 nickel Chemical class 0.000 description 1
• LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
• 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
• 150000002825 nitriles Chemical class 0.000 description 1
• 239000000741 silica gel Substances 0.000 description 1
• 229910002027 silica gel Inorganic materials 0.000 description 1
• 229910052708 sodium Inorganic materials 0.000 description 1
• 239000011734 sodium Substances 0.000 description 1
• 229910000029 sodium carbonate Inorganic materials 0.000 description 1
• 230000000087 stabilizing effect Effects 0.000 description 1
• 239000000126 substance Substances 0.000 description 1
• 239000000725 suspension Substances 0.000 description 1
• 238000005406 washing Methods 0.000 description 1