BE1014058A5 - DERIVATIVES OF 2,2,6,6-DIETHYL-DIMETHYL-1-ALCOXYPIPERIDINES AND CORRESPONDING 1-OXIDES - Google Patents

DERIVATIVES OF 2,2,6,6-DIETHYL-DIMETHYL-1-ALCOXYPIPERIDINES AND CORRESPONDING 1-OXIDES Download PDF

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Publication number
BE1014058A5
BE1014058A5 BE2001/0181A BE200100181A BE1014058A5 BE 1014058 A5 BE1014058 A5 BE 1014058A5 BE 2001/0181 A BE2001/0181 A BE 2001/0181A BE 200100181 A BE200100181 A BE 200100181A BE 1014058 A5 BE1014058 A5 BE 1014058A5
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BE
Belgium
Prior art keywords
diethyl
derivatives
alkoxy
alcoxypiperidines
oxides
Prior art date
Application number
BE2001/0181A
Other languages
French (fr)
Inventor
Peter Nesvadba
Andreas Kramer
Marie-Odile Zink
Original Assignee
Ciba Sc Holding Ag
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Publication date
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Publication of BE1014058A5 publication Critical patent/BE1014058A5/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

La présente invention concerne certains dérivés de 1-alcoxy-2,2-diéthyle-6,6-diméthylpipéridines et de 1-alcoxy-2,6-diéthyl-2,3,6-triméthylpipéridines substituées en position 4 par un atome d'oxygène ou d'azote; une composition polymérisable comprenant a) au moins un monomère à insaturation éthylénique et b) lesdits dérivés de pipéridine. D'autres aspects de la présente invention concernent un procédé de polymérisation de monomères à insaturation éthylénique et l'utilisation éthylénique et l'utilisation de dérivés de 1-alcoxy-2,2-diéthyl-6,6-diméthylpipéridines et de 1-alcoxy-2,6-diéthyl-2,3,6-triméthylpipéridines substituées en position 4 par un atome d'oxygéne ou d'azote pour une polymérisation contrôlée...The present invention relates to certain derivatives of 1-alkoxy-2,2-diethyl-6,6-dimethylpiperidines and of 1-alkoxy-2,6-diethyl-2,3,6-trimethylpiperidines substituted in position 4 with an atom of oxygen or nitrogen; a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Other aspects of the present invention relate to a process for the polymerization of ethylenically unsaturated monomers and the ethylenic use and the use of 1-alkoxy-2,2-diethyl-6,6-dimethylpiperidines and 1-alkoxy derivatives -2,6-diethyl-2,3,6-trimethylpiperidines substituted in position 4 by an oxygen or nitrogen atom for a controlled polymerization ...

BE2001/0181A 2000-03-22 2001-03-20 DERIVATIVES OF 2,2,6,6-DIETHYL-DIMETHYL-1-ALCOXYPIPERIDINES AND CORRESPONDING 1-OXIDES BE1014058A5 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP00810246 2000-03-22

Publications (1)

Publication Number Publication Date
BE1014058A5 true BE1014058A5 (en) 2003-03-04

Family

ID=8174612

Family Applications (1)

Application Number Title Priority Date Filing Date
BE2001/0181A BE1014058A5 (en) 2000-03-22 2001-03-20 DERIVATIVES OF 2,2,6,6-DIETHYL-DIMETHYL-1-ALCOXYPIPERIDINES AND CORRESPONDING 1-OXIDES

Country Status (16)

Country Link
US (3) US6624306B2 (en)
JP (1) JP2001316365A (en)
KR (1) KR100743975B1 (en)
CN (1) CN1319590A (en)
AU (1) AU784894B2 (en)
BE (1) BE1014058A5 (en)
BR (1) BR0101108A (en)
CA (1) CA2341791C (en)
DE (1) DE10113209A1 (en)
ES (1) ES2173046B1 (en)
FR (1) FR2806720B1 (en)
GB (1) GB2361235B (en)
IT (1) ITMI20010546A1 (en)
NL (1) NL1017635C2 (en)
NO (1) NO20011436L (en)
TW (1) TW541303B (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
TW557305B (en) * 2000-12-14 2003-10-11 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
CN1249035C (en) * 2001-06-13 2006-04-05 西巴特殊化学品控股有限公司 4-imino-N-alkoxy or oxy-polyalkyl-piperidine compounds and their use as polymerization regulators
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
DE60233349D1 (en) * 2001-12-21 2009-09-24 Basf Se NEW FLAME HEMMER
WO2003062293A1 (en) * 2002-01-22 2003-07-31 Atofina Method of producing and using materials which are reinforced against impact and which contain block copolymers that are obtained by means of controlled radical polymerisation in the presence of nitroxides
ES2263957T3 (en) * 2002-03-05 2006-12-16 Ciba Specialty Chemicals Holding Inc. OPEN CHAIN ALCOXIAMINS AND THEIR CORRESPONDING NITROXIDS FOR RADICAL CONTROLLED POLYMERIZATION AT LOW TEMPERATURE.
US7531555B2 (en) * 2003-10-01 2009-05-12 University Of Florida Research Foundation, Inc. Compositions and methods for selective inhibition of nicotine acetylcholine receptors
EP1675629A1 (en) * 2003-10-07 2006-07-05 Coloplast A/S An adhesive composition and use of such composition
WO2005118651A1 (en) * 2004-05-27 2005-12-15 Ciba Specialty Chemicals Holding Inc. Alkoxyamines containing a radically polymerizable group
WO2006074969A1 (en) 2005-01-11 2006-07-20 Ciba Specialty Chemicals Holding Inc. Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes
CN105998028A (en) * 2007-02-22 2016-10-12 科尔比制药公司 Hydroxylamine compounds and methods of their use
MX2009010535A (en) * 2007-04-05 2009-10-22 Basf Se Sunscreen and personal care compositions comprising a select copolymer.
WO2008145595A1 (en) * 2007-06-01 2008-12-04 Basf Se Modified printable surfaces
US8664324B2 (en) 2008-06-23 2014-03-04 Basf Se Pigment dispersants with modified copolymers
US8377192B2 (en) * 2008-08-28 2013-02-19 Basf Se Stabilisers for inanimate organic materials
US10316114B2 (en) 2010-03-30 2019-06-11 Basf Se End-functionalized polymers
JP4821916B1 (en) * 2010-05-07 2011-11-24 横浜ゴム株式会社 Process for producing modified polymers
US9309391B2 (en) 2010-06-29 2016-04-12 Basf Se Process for improving the flow of properties of polymer melts
EP2771445B1 (en) 2011-10-25 2018-12-12 Henkel AG & Co. KGaA Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
EP2817370B1 (en) 2012-02-23 2020-08-19 Basf Se Fluorinated acrylate block copolymers with low dynamic surface tension
KR20150135489A (en) 2013-03-27 2015-12-02 바스프 에스이 Block copolymers as soil release agents in laundry processes
CN111278934B (en) 2017-10-23 2022-04-12 巴斯夫欧洲公司 Aqueous silicone polymer emulsions
WO2022200398A1 (en) 2021-03-26 2022-09-29 Basf Se Polymer composition comprising polyacrylic block copolymer and aromatic based polyalkyleneoxide as dispersant

Citations (2)

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DE2621870A1 (en) * 1975-05-28 1976-12-16 Ciba Geigy Ag NEW DERIVATIVES OF 4-AMINOPIPERIDINE
DE19909767A1 (en) * 1998-03-09 1999-09-16 Ciba Geigy Ag New 1-alkoxy-polyalkyl-piperidine derivatives used as initiators in free radical polymerization processes

Family Cites Families (11)

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US4141883A (en) 1975-05-28 1979-02-27 Sankyo Company, Limited Stabilization of synthetic polymers by penta-or-hexa-substituted 4-piperidinol derivatives
US4191683A (en) 1975-05-28 1980-03-04 Ciba-Geigy Corporation Derivatives of 4-aminopiperidine as stabilizers for polymers
DE3486145T2 (en) 1983-07-11 1993-09-23 Commw Scient Ind Res Org METHOD FOR POLYMERIZATION AND POLYMERS PRODUCED BY THIS METHOD.
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DE19909767A1 (en) * 1998-03-09 1999-09-16 Ciba Geigy Ag New 1-alkoxy-polyalkyl-piperidine derivatives used as initiators in free radical polymerization processes

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Publication number Publication date
KR20010092697A (en) 2001-10-26
AU784894B2 (en) 2006-07-20
ITMI20010546A1 (en) 2002-09-15
US7160966B2 (en) 2007-01-09
NO20011436L (en) 2001-09-24
FR2806720A1 (en) 2001-09-28
CN1319590A (en) 2001-10-31
ES2173046B1 (en) 2004-06-16
AU2804901A (en) 2001-09-27
NO20011436D0 (en) 2001-03-21
NL1017635C2 (en) 2001-09-25
US6891008B2 (en) 2005-05-10
CA2341791A1 (en) 2001-09-22
US20030166939A1 (en) 2003-09-04
GB2361235B (en) 2002-06-12
DE10113209A1 (en) 2001-09-27
CA2341791C (en) 2010-02-23
US20030065184A1 (en) 2003-04-03
US20050143539A1 (en) 2005-06-30
FR2806720B1 (en) 2006-12-08
ES2173046A1 (en) 2002-10-01
KR100743975B1 (en) 2007-07-30
GB0105678D0 (en) 2001-04-25
JP2001316365A (en) 2001-11-13
TW541303B (en) 2003-07-11
BR0101108A (en) 2001-11-06
GB2361235A (en) 2001-10-17
US6624306B2 (en) 2003-09-23

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Effective date: 20110331