AU9745198A - Phosphine-substituted cobalticinium salts, production thereof, and use of the same as constituents of catalysts - Google Patents
Phosphine-substituted cobalticinium salts, production thereof, and use of the same as constituents of catalystsInfo
- Publication number
- AU9745198A AU9745198A AU97451/98A AU9745198A AU9745198A AU 9745198 A AU9745198 A AU 9745198A AU 97451/98 A AU97451/98 A AU 97451/98A AU 9745198 A AU9745198 A AU 9745198A AU 9745198 A AU9745198 A AU 9745198A
- Authority
- AU
- Australia
- Prior art keywords
- carbon atoms
- radical
- cycloalkyl
- same
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 150000003839 salts Chemical class 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000470 constituent Substances 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 10
- -1 alkoxy radicals Chemical class 0.000 abstract 9
- 150000005840 aryl radicals Chemical class 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 abstract 1
- GPWHDDKQSYOYBF-UHFFFAOYSA-N ac1l2u0q Chemical compound Br[Br-]Br GPWHDDKQSYOYBF-UHFFFAOYSA-N 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 150000007942 carboxylates Chemical class 0.000 abstract 1
- 238000001311 chemical methods and process Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 abstract 1
- WRTMQOHKMFDUKX-UHFFFAOYSA-N triiodide Chemical compound I[I-]I WRTMQOHKMFDUKX-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The invention relates to phosphine-substituted cobalticinium salts of formula (I), wherein R<1> is the same or different and is hydrogen, alkyl- or alkoxy radicals with 1 to 14 carbon atoms, also cycloalkyl-, aryl- or aroxy radicals with 6 to 14 carbon atoms, an anellated benzol ring, an acid amide radical -C(O)-NR<2>R<3>, wherein R<2> and R<3> are the same or different and represent hydrogen, alkyl radicals with 1 to 14 carbon atoms, cycloalkyl- or aryl radicals with 6 to 14 carbon atoms, the carboxyl group or an ester radical -C(O)-OR<4>, wherein R<4> represents an alkyl radical with 1 to 14 carbon atoms, also a cycloalkyl- or aryl radical with 6 to 14 carbon atoms; n is the same or different and is a whole number between 0 and 4, m is a whole number between 1 and 3, and X is equal to hexafluoroantimonate, tetraphenyl borate, tosylate, tetrafluoroborate, triflate, trifluoroacetate, triiodide, tribromide, nitrate, perchlorate, sulphate, phosphate, sulphonate O-S(O)2-R<5>, R<5> representing an alkyl radical with 1 to 14 carbon atoms, also a cycloalkyl- or aryl radical with 6 to 14 carbon atoms or carboxylate O-(CO)-R<6>, R<6> representing hydrogen, an alkyl radical with 1 to 14 carbon atoms, a cycloalkyl- or aryl radical with 6 to 14 carbon atoms. The invention also relates to a method for producing the inventive phosphine-substituted cobalticinium salts. These compounds are suitable for use as ligands for metal complexes used as catalysts in chemical processes.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742904 | 1997-09-29 | ||
| DE19742904A DE19742904C1 (en) | 1997-09-29 | 1997-09-29 | Phosphine-substituted cobalticinium salts, process for their preparation and use as a catalyst component |
| PCT/EP1998/005989 WO1999016776A1 (en) | 1997-09-29 | 1998-09-19 | Phosphine-substituted cobalticinium salts, production thereof, and use of the same as constituents of catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU9745198A true AU9745198A (en) | 1999-04-23 |
Family
ID=7843958
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU97451/98A Abandoned AU9745198A (en) | 1997-09-29 | 1998-09-19 | Phosphine-substituted cobalticinium salts, production thereof, and use of the same as constituents of catalysts |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1019422B1 (en) |
| AT (1) | ATE217001T1 (en) |
| AU (1) | AU9745198A (en) |
| DE (2) | DE19742904C1 (en) |
| ID (1) | ID20983A (en) |
| TW (1) | TW486481B (en) |
| WO (1) | WO1999016776A1 (en) |
| ZA (1) | ZA988805B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6852229B2 (en) | 2002-10-22 | 2005-02-08 | Exxonmobil Research And Engineering Company | Method for preparing high-purity ionic liquids |
| CN100412081C (en) * | 2006-06-15 | 2008-08-20 | 华中师范大学 | Cobait dipenta cation diphosphine ligand preparation and application thereof |
| CN100451025C (en) * | 2006-07-07 | 2009-01-14 | 华中师范大学 | Cobaltocene cation monophosphine ligand and its synthesis and uses |
-
1997
- 1997-09-29 DE DE19742904A patent/DE19742904C1/en not_active Expired - Fee Related
-
1998
- 1998-09-17 ID IDP981247A patent/ID20983A/en unknown
- 1998-09-19 AU AU97451/98A patent/AU9745198A/en not_active Abandoned
- 1998-09-19 DE DE59803998T patent/DE59803998D1/en not_active Expired - Fee Related
- 1998-09-19 AT AT98951439T patent/ATE217001T1/en not_active IP Right Cessation
- 1998-09-19 WO PCT/EP1998/005989 patent/WO1999016776A1/en active IP Right Grant
- 1998-09-19 EP EP98951439A patent/EP1019422B1/en not_active Expired - Lifetime
- 1998-09-25 ZA ZA988805A patent/ZA988805B/en unknown
- 1998-09-29 TW TW087116124A patent/TW486481B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999016776A1 (en) | 1999-04-08 |
| DE19742904C1 (en) | 1999-08-12 |
| EP1019422A1 (en) | 2000-07-19 |
| EP1019422B1 (en) | 2002-05-02 |
| ID20983A (en) | 1999-04-01 |
| TW486481B (en) | 2002-05-11 |
| DE59803998D1 (en) | 2002-06-06 |
| ZA988805B (en) | 1999-04-06 |
| ATE217001T1 (en) | 2002-05-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK6 | Application lapsed section 142(2)(f)/reg. 8.3(3) - pct applic. not entering national phase |