AU781383B2 - Extrudable cementitious material - Google Patents

Description

TITLE: EXTRUDABLE CEMENTITIOUS MATERIAL TECHNICAL FIELD The present invention relates to building products and particularly fibre reinforced cement building products.

BACKGROUND ART Any discussion of the prior art throughout the specification should in no way be considered as an admission that such prior art is widely known or forms part of common general knowledge in the field.

Fibre reinforced cement boards and other products have been widely used as materials for walls, ceilings, roofs, floors etc: of buildings and for substitutes for wood •trim, frames etc.

"..."There are many methods for forming and shaping such FRC products including .Hatschek sheet process. Mazza pipe process, Magnani sheet process, injection moulding, hand lay-up, casting, filter pressing, roll forming etc.

Extrusion of fibre cement products has been performed on a limited basis but it has a number of difficulties which have reduced its commercial viability. In the extrusion process, the cementitious slurry or paste is forced through a die and the material can be *eg.

subjected to elevated pressures. For this reason, it is important that the slurry or paste has good flow characteristics. The cementitious formulation often contains elements that are 20 present almost entirely as process aids, increasing the flow properties, the shape retention properties or enhancing the surface finish. A common type of these additives can be broadly classified as viscosity enhancing agents (VEA) or 'binders'. A principal function of these is to increase the viscosity of the liquid phase, and to counter problems such as segregation of the liquid and solid phases ('water retention'), lack of shape retention, non uniform dispersion of the solid components etc.

For materials such as clays extruded in the brick and tile industry, the inherent good flow properties of the clay mean that the use of such VEA's may be minimised, and therefore cheap. However when the solids suspensions that require forming are not plastic (such as cementitious slurries or pastes), and inherently resistant to flow, the additives are often expensive high molecular weight organic polymers. Further, the demand for viscosity enhancing agents can be increased by the presence of reinforcing fibres, especially if these are hard to disperse or do not have good water retention characteristics.

Asbestos generally has better dispersion and water retention properties than pulp fibres, and when used as reinforcement in cementitious compositions, require less extensive use of viscosity enhancing agents, however, as is well-known in the art, the use of asbestos fibres is outlawed in many countries and is undesirable even in those countries where its use is legal.

Accordingly, previous efforts in finding reinforcing fibres for extrudable cementitious pastes have concentrated on non-asbestos fibres and, in particular, choosing or treating such non-asbestos fibres so that their dispersion and water retention characteristics make them suitable for use in extrusion moulding with minimal use of viscosity enhancing agents. For instance, US patent no 5,891,374 discloses a process for producing a fibre reinforced cement matrix composite. In this document, hydraulic S: cement, water and low quantities of water soluble binder are mixed together with synthetic fibres to produce an extruded and cured composite product. Optionally, a water reducing agent may be added to assist in preferential alignment of the fibres in the load bearing 15 direction.

Such synthetic fibres are commonly used. However, they are expensive and some are unable to be cured at high temperatures such as in an autoclave. Currently, wood pulp fibres remain the primary fibre of choice for reinforcing cement composites for building materials, where they show excellent performance with regard to mechanical strength, toughness and durability at a low cost. However, extrudable cement compositions containing wood pulp fibres have very stringent requirements for rheology modification and require expensive high molecular weight organic polymers as viscosity enhancing agents.

It is believed that the viscosity enhancing agent performs two functions. Firstly, it acts as a high solid suspension thickener to increase the water retention properties of the slurry, and secondly, it also lubricates the suspended particles thereby allowing the high solid suspension to flow under deformation without phase separation and segregation.

The effectiveness of such a viscosity enhancing agent is believed to be a combination of three actions, namely: adsorption of water by long-chain polymer molecules, increasing viscosity of the mixed water, association of adjacent polymer chains, further blocking the motion of water, and -3intertwining and entangling of the polymer chains, thereby behaving in a sheer thinning manner.

For suspensions involving cement and pulp fibre that are processed by extrusion, the commonly used viscosity enhancing agents are high viscosity cellulose ethers such as methyl cellulose, hydroxypropyl methyl cellulose or hydroxyethyl methyl cellulose. US Patent 5,047,086 discloses the use of extremely high viscosity (>80,000 cps 2% solution at 200 C) alkylcellulose and/or hydroxyalkylalkylcellulose at 0.2-1 wt levels in the preparation of these compositions. This patent also discloses that if lower viscosity (12,000-40,000 cps 2% solution at 200 C) grades of these compounds (akin to those used in asbestos fibre/cement extrusion compositions) are used, much higher addition levels are required.

Even when mouldings are made with such high viscosity grade agents in an effort to minimise the quantity used, the cost ratio of viscosity enhancing agent to the total cost of the extruded moulding can be in the order of one fourth to one half. Thus it is clear that 15 any method of reducing the cost and/or amount of viscosity enhancing agents required to attain excellent mouldability, is greatly to be desired.

In addition to the cost aspect, highly effective viscosity enhancing agents like 0ohydroxypropyl methylcellulose (HPMC) and hydroxyethyl methylcellulose (HEMC) experience a phenomenon known as high temperature gelation. That is, the viscosity of the agent undergoes a sharp increase when the temperature exceeds a specific limiting •temperature, known as the gel temperature. The gel temperature of these viscosity enhancing agents varies with the exact chemistry degree of substitution etc.). Though this phenomenon can be useful in some applications, it is limiting in others. For example, cooling jackets are sometimes required to counter the temperature rise in the extruder barrel during long periods of fast running, to keep the extrudate below the gel temperature of the viscosity enhancing agent being used. As a result, in some instances viscosity enhancing agents with higher gel temperatures are preferred to avoid this complication.

Hence, the ability to use a type of viscosity enhancing agent that does not undergo thermal gelation (like hydroxyethyl cellulose (HEC)) would be a great advantage in certain applications.

The present invention seeks to ameliorate at least some of the disadvantages of the prior art or provide a commercial alternative thereto.

-4- DISCLOSURE OF THE INVENTION The present invention seeks to ameliorate at least some of the disadvantages of the prior art or provide a commercial alternative thereof.

In a first aspect, the present invention provides the use of one or more dispersion agents in the extrusion of a cementitious material for the purpose of increasing the efficacy of a viscosity enhancing agent during extrusion, being a use wherein the viscosity enhancing agent is provided as 0.3 to 5% by weight of dry solids of cementitious material and the dispersion agent is provided as 0.05 to 0.5% by weight of dry solids of the cementitious material.

The applicant has found that by addition of a suitable dispersion agent, the efficacy of the viscosity enhancing agent can be increased. The reference to increasing the efficacy of the viscosity enhancing agent refers to the addition of the suitable dispersion agent sufficient to provide one of three results maintaining extrudability with less viscosity enhancing agent as compared 15 to the conventional dosage without dispersion agent, ii) maintaining extrudability with use of lower grade (cheaper) viscosity S•enhancing agent than is conventionally used, or iii) improving extrudability for the same quantity of viscosity enhancing agent as compared to the conventional dosage.

Unless the context clearly requires otherwise, throughout the description and the claims, the words 'comprise', 'comprising', and the like are to be construed in an inclusive :sense as opposed to an exclusive or exhaustive sense; that is to say, in the sense of S"including, but not limited to".

n a second aspect, the present invention provides a method for extruding a cementitious material, comprising adding a quantity of dispersion agent sufficient to increase the efficacy of a viscosity enhancing agent contained in said cementitious material wherein the viscosity enhancing agent is provided as 0.3 to 5% by weight of dry solids of the cementitious material and the dispersion agent is provided as 0.05 to 0.5% by weight of dry solids of cementitious material.

Dispersion agents, also known as plasticisers or super plasticisers, have long been used in the concrete industry to improve paste workability or to increase fluidity. The attraction forces existing amongst the cement particles that cause agglomeration are neutralised by adsorption of anionic polymers. The dispersion of these cement particles is related to the electrical repulsion produced by the absorption of the negatively charged group. This mechanism has been confirmed in sulphonated-type dispersion agents such as sulphonated melamine formaldehyde and sulphonated naphthalene formaldehyde. The dispersion mechanism for acrylic polymers is believed to be ascribed to a steric hindrance effect rather than electrostatic repulsion. These dispersion agents, however, have not been used as rheology modifiers in fibre reinforced cement slurry.

The applicant has found a surprising synergy between viscosity enhancing agents and dispersion agents. The combination of viscosity enhancing agent and dispersion agent is far superior in terms ofrheology modification than either component alone. The addition of the dispersion agent also allows use of a far broader range of viscosity enhancing agents :than have otherwise been proposed. To explain, as mentioned above, the most common viscosity enhancing agents are hydroxypropylmethyl cellulose, hydroxyethylmethyl cellulose and methyl cellulose. These products are quite expensive and accordingly large additions are preferably avoided.

S: By combining the viscosity enhancing agent with a dispersion agent, the effectiveness of the viscosity enhancing agent is increased, thereby improving its extrudability, ie ability to flow under applied force, or reducing the quantity of viscosity S 20 enhancing agent required to maintain extrudability. Further, cheaper viscosity enhancing agents can be used such as lower grade hydroxypropylmethyl cellulose or hydroxyethyl cellulose. These cheaper viscosity enhancing agents can be around half the cost of high grade cellulose ethers.

The current invention enables the forming of compositions with improved mouldability and workability or alternatively the reduction of cost by allowing the use of less viscosity enhancing agents and/or the use of lower (cheaper) grades of viscosity enhancing agents. The addition of 0.05-0.5 wt. of a dispersion agent, can result in the requirement for viscosity enhancing agents falling by -20% and/or a less potent viscosity enhancing agent being used with equivalent or better extrudability than compositions with the conventional levels of viscosity enhancing agent.

-6- As will be clear to persons skilled in the art, and as discussed above, increasing the effectiveness of the viscosity enhancing agent to improve/maintain extrudability will also avoid or reduce common extrusion problems such as segregation, tearing, phase separation, dewatering, etc. It may also result in an increase in structural integrity and better retention of the shape of the extrudate.

In some cases, the improvement in extrudability has been demonstrated by increasing the speed of extrusion. For example, some cementitious formulations containing viscosity enhancing agent and optionally some dispersion agent may extrude but at a relatively low speed with a relatively high head pressure on the die. The applicant has found that by addition of a suitable quantity of dispersion agent, the speed of extrusion can be increased markedly and the head pressure on the die similarly reduced. Such results are normally achieved by increasing the quantity or grade of the viscosity enhancing agent in the cementitious paste. It is quite unexpected that such improvements can be achieved S: by the simple addition of a dispersion agent.

15 Examples of high grade viscosity enhancing agents are high molecular weight cellulose ethers, for example alkylcellulose or hydroxyalkyl alkylcellulose. Low grade VEA's can be the same compounds at a lower molecular weight. Suitable viscosity enhancing agents for use with the present invention include methyl cellulose, hydroxyethyl cellulose, hydroxyethylmethyl cellulose, hydroxypropylmethyl cellulose, carboxymethyl 20 cellulose, ethyl cellulose, hydroxybutylmethyl cellulose, polyvinyl alcohol, clays, modified clays, Welan gum and other natural gums. The viscosity enhancing agent and/or dispersion agent can be added together or separately to the cementitious slurry or indeed included in the dry formulation prior to slurry preparation. As will be clear to persons skilled in the art, it is important that the dispersion agent and viscosity enhancing agent are thoroughly mixed through the slurry to provide a homogeneous mix.

Suitable dispersion agents include sulphonated melamine formaldehyde, sulphonated naphthalene formaldehyde, amino-sulphonate polymer, modified lignosulfonate materials and acrylic polymers such as copolymer of acrylic acid with acrylic ester, copolymers of acrylic acid with polycarboxylate ester and cross-linked acrylic polymers.

As discussed above, it is important when extruding a cementitious paste or slurry that stringent rheological criteria are met while minimising the cost due to the use of viscosity enhancing agents.

In order to determine suitable quantities of viscosity enhancing agent and dispersion agent, or indeed conduct comparative analysis of different formulations, a simple extrusion test may be conducted whereby a cementitious paste is provided including the viscosity enhancing agent and dispersion agent. The treated paste is then applied to a test die at a test pressure to confirm extrudability. As it will be clear to persons skilled in the art, exact quantities of viscosity enhancing agent and dispersion agent will depend on a number of factors including the type of agent used, the content of the cementitious paste and indeed the extrusion equipment in which the cementitious paste will be used.

It is not entirely clear at this stage why the synergistic effect between the dispersion agent and viscosity enhancing agent is obtained. The effect of the synergy does differ, however, S•between various viscosity enhancing agents and dispersion agents. While in some cases :i 15 the efficacy of the viscosity enhancing agent has only been increased marginally, all mixtures have shown some synergistic effect and the applicant sees no basis on which the synergistic effect should not be maintained in a full scale operation.

The viscosity enhancing agent and dispersion agent can be added simultaneously or separately to the cementitious material. The viscosity enhancing agent and dispersion agent can be added as dry solids, either before or after the addition of water to the other solid components. The viscosity enhancing agent and dispersion agent can also be dispersed in water first and then added to the other solid components. Liquid, solid, sees solution, emulsion or suspension forms of viscosity enhancing agents and dispersion o• agents can be used.

-8- It is also possible to provide the viscosity enhancing agent, dispersion agent and all other components of the product including cementitious material, density modifiers, fibres etc dry mixed together for subsequent mixing with water to form a paste or slurry.

Alternatively, some of the solid components eg cementitious material, lime, silica, density modifiers etc may be dry mixed with the viscosity enhancing agent thoroughly.

Water may then be added to pre-wet the mixture. The dispersion agent may then be dissolved in the rest of the water and added to the solution to the mix. Mixing is generally not required for any longer than five minutes. Total wet mixing time should preferably not exceed 15 minutes. The resultant mixture is then kneaded for say around five minutes depending upon the effectiveness of the kneading facility. In this regard long kneading *times should be avoided. The material is then suitable for use in the extrusion apparatus.

In an alternative form, a cementitious slurry or paste may be provided with the *desired consistency, with suitable quantities of viscosity enhancing agent and dispersion agent be subsequently added as powder, to the paste. In this instance, longer kneading time 15 may be required to thoroughly mix the viscosity enhancing agent and dispersion agent in the paste.

If desired, the viscosity enhancing agent and dispersion agent may be provided to the cementitious slurry or paste via separate components of the FRC mixture. To explain, it may be appropriate to pre-treat the reinforcing pulp fibre with a dispersion agent. The cementitious material could be pre-dosed with a viscosity enhancing agent whereby it is combined with a dispersion agent upon mixing with the fibre.

It should also be understood that more than one viscosity enhancing agent and more than one dispersion agent may be used in the mixture.

The compositions formed in the above mentioned ways may be cured at ambient temperature and pressure or at higher temperatures and pressures. Curing methods such as steaming at high temperatures or autoclaving at high temperatures and pressures are possible. Unlike the prior art, the resultant extruded cementitious material is suitable for autoclave curing. This is a further distinction over the prior art which use synthetic fibres unsuitable for autoclaving.

The exact regime of curing, such as pre-cure times, temperatures, pressures and cure times must be optimised for the specific formulation. As is well known, to achieve optimum strength it is important to avoid the cementitious products drying out during curing.

Compositions formed using the method of this invention show no adverse effects in terms of physical or mechanical properties during curing or afterwards when compared to specimens made with conventional techniques using high grade viscosity enhancing agents.

In fact the use of dispersion agents appears to aid the forming of a superior surface finish.

The disclosed method and treatment agent are also particularly suitable for producing low density composite articles, that contain a high proportion of density modifying additives. Examples of such additives would be perlite, vermiculite, low density calcium silicate hydrate, ceramic hollow spheres, fly-ash etc. This invention can also be used with the addition of air entraining agents to modify density. Densities of 1.2 g/cm 3 or below may be achieved using the present invention.

In still a further aspect, the present invention provides a method of forming a low density cementitious article comprising adding a cementitious material, density modifying additive, a viscosity enhancing agent and dispersion agent to water, extruding the resultant paste and curing the extruded article, wherein the dispersion agent is added in a quantity sufficient to increase the efficacy of the viscosity enhancing agent.

This invention also is suitable for compositions containing a variety of reinforcing fibres. Examples of such fibres would be wood pulp (cellulose) fibres, asbestos fibres, polymer fibres, glass or metal fibres. This is another advantage arising from the present °-°invention. The prior art extrusion techniques are limited to particular fibres and particular oo S"fibre contents. The present invention allows an operator to choose the type and quantity of fibre to specifically match the article to its desired use eg up to around 25% vol.

Further, it has been found that the addition of viscosity enhancing agent and dispersion agent provides an extruded product with an improved surface finish. It is not entirely clear why this occurs, however, the applicant has found clear visible improvement in surface finish between extruded articles according to the present invention and those of the prior art. This is even true for articles with higher fibre contents ie 15% and above.

The present invention will now be described with reference to the following nonlimiting examples: EXAMPLE 1 A composition was prepared according to the materials and proportions indicated in Table 1, the solid components blended in a high speed Eirich mixer and then kneaded together with the water in a Hobart mixer. The paste produced was then extruded into sheets 50mm wide and 10mm thick using a Handle laboratory extruder with 75mm barrel.

For each type of viscosity enhancing agent, repeat experiments were carried out with different addition levels to ascertain the minimum required for good extrusion, surface finish and shape retention. Table 2 lists the viscosity enhancing agents and dispersion agents trialed with some detail as to their origin, chemistry and cost. Table 3 lists the addition levels of viscosity enhancing agents and combinations of viscosity enhancing agents and dispersion agents that have equivalent performance in extrusion moulding and enables comparisons of the effect of the dispersion agent.

Table 1 Material Details Amount used Fibre Bleached softwood Kraft pulp from 11% wt of solids Weyerhaeuser.

Cement OPC Type 1 from Blue Circle Southern Cement: Silica 60:40 Silica 200G milled quartz Cement: Silica 60:40 Water 30% of total weight Table 2 S 0 500 S

S

S

S

S

5* Type VEAl VEA2 VEA3 VEA4 Details Shin-Etsu 90SHV-WF Hydroxyethyl methyl cellulose (HEMC) (12,000 mPas, 1% solution 200 C, Brookfield) Wolff Walsrode Walocel VP-M20677 Hydroxyethyl methyl cellulose (HEMC) (75,000-85,000 mPas 2% solution 20° C, Haake Rotovisko) Dow J75 Hydroxypropyl methyl cellulose (HPMC) (75,000 mPas, 2% sol. And 3000 mPas, 1% sol.@ 20 0 C, Ubbelohde tube) Union Carbide Cellosize QP 100MH Hydroxyethyl cellulose (HEC) (4000-6000 mPas, 1% solution 25° C, Brookfield) Dow Hydroxypropyl methyl cellulose (HPMC) (20,000 mPas, 2% sol. And 900 mPas, 1% sol.@ 20 0 C, Ubbelohde tube) US$7.41/kg US$8.50/kg US$6.50/kg Cost US$8.00/kg -11 VEA6

DAI

Sigma Aldrich- 41,933-8 Carboxy methyl cellulose (CMC) Av Mol. Wt 700,000 Degree of substitution 0.9 SKW Melment F15 Sulfonated melamine formaldehyde (SMF) US$2.80/kg Table 3 6@ 5 0

SS

S

S

S.

S

000 0

OS

S.

OSS@

0

S

0@

OSS

Amount required Amount required with Cost of formulation without DA1 0.2% DA1 US$/tonne OLD NEW VEAl 1.5% 1.2% 158.22 145.38 VEA2 1.5% 1.2% 151.98 140.39 VEA3 1.75% 1.5% 163.89 149.92 VEA4 Inadequate performance 1.2% 132.77 EXAMPLE 2 5 A composition was prepared according to the materials and proportions specified in Table 4. The solid components were blended in a high speed Eirich mixer and subsequently mixed with a water/VEA solution in a Hobart mixer. The paste produced was then extruded into sheets 50mm wide and 10mm thick using a Handle laboratory extruder with 75mm barrel. For each type of viscosity enhancing agent, repeat experiments 10 were carried out with different addition levels to ascertain the minimum required for good extrusion, surface finish and shape retention. Table 6 shows the levels of viscosity enhancing agent required using the method of the new invention and without.

Table 4 Material Details Amount used Fibre Bleached softwood Kraft pulp from 9% wt. of solids Weyerhaeuser.

Cement OPC Type 1 from Blue Circle Southern Cement: Silica 60:40 Silica 200G milled quartz Cement: Silica 60:40 Density Low density calcium silicate hydrate 10% wt of solids Modifier Water 38% of total weight (41% when VEA6 is used).

-12- Table Amount required without DA1 Amount required with Cost of Formulation 0.3% DA1 US$/tonne OLD NEW 1.8% 183.11 177.68 1 8O/ 1 5484 VEA3 2% VEA4 Inadequate performance Inadequate performance VEA6 Inadequate performance Estimated price 2% 2.2% 147.63* EXAMPLE 3 Two compositions, one containing VEA3 (Mix 1) and the other VEA4/DA1 (Mix 2) were prepared according to the materials and proportions specified in Table 6. VEA3 is a high grade HPMC and VEA4 is a cheaper HEC compound. For each, all the solid components were blended in a high speed Eirich mixer. The dry solids were then kneaded together with the water in a Hobart mixer till a homogenous paste was formed. The paste produced was then extruded into sheets 50mm wide and 10mm thick using a Handle laboratory extruder with 75mm barrel. Half the samples were pre-cured at ambient conditions for 8 hours and the other half at ambient conditions for 36 hours. The strips were then cured in an autoclave under saturated steam pressure at 1770 C for 8 hours. The mechanical properties of the two compositions were tested, and Graph 1 shows the results. It can be seen that there is no significant difference in the measured mechanical properties between samples made with VEA3 and VEA4/DA1. It was also observed that the sample made with VEA4/DA1 had the better surface finish of the two.

Table 6 Material Details Amount used Fibre Bleached softwood Kraft pulp from 9% wt. of solids Weyerhaeuser.

Cement OPC Type 1 from Blue Circle Southern Cement: Silica 60:40 Silica 200G milled quartz Cement: Silica 60:40 Density PQ Extendospheres (hollow ceramic spheres, 10% wt of solids Modifier effective density -0.7 g/cc) Water 30% of total weight VEA3 As in Table 2 2% in Mix 1 VEA4 As in Table 2 2% in Mix 2 DAI As in Table 2 0.3% in Mix 2 13- Graph 1 12.0 10.0 4 g MOE (GPa) U" Stress (M 0.0 I VEA3 36hr Precure VEA4 8hr PreCUre VEA3 8hr Preojre VEA4 36hr Precure EXAMPLE 4 A composition was prepared according to the materials and proportions indicated in Table 7, the solid components blended in a high speed Eirich mixer and then kneaded together with the water in a Hobart mixer. The paste produced was then extruded into sheets 50mm wide and 10 mm thick using Handle laboratory extruder with a 75mm barrel.

Table 8 describes the viscosity enhancing agent and dispersion agent used and Table 9 shows the levels of viscosity enhancing agent required with and without the dispersion agent and demonstrates the synergy.

Table 7 Material Details Amount Used Fibre Bleached softwood Kraft pulp from Weyerhaeuser 9% wt of solids Cement OPC Typel from Blue Circle Southern 60:40 cement:silica Silica 200G milled quartz 60:40 cement:silica Density Low density calcium silicate hydrate 30% wt of solids Modifier Water 52% of total weight -14- Table 8 Type Details Cost VEA 7 Rheolate 101 from Elementis US$6.28/kg Alkali swellable modified polyacrylate emulsion Pa.s, 1% sol.@ 1 1/S (shear rate) and PH=7.0, 25 deg. C Brookfield) DAl SKW Melment F15 US$2.80/kg Sulfonated Melamine Formaldhyde (SMF) Table 9 Amount required Amount required Cost of Formulation without DA1 with 0.3% DA1 (US$/tonne) OLD NEW VEA 7 5.5% 4.5% 233.87 206.63 It will be understood by persons skilled in the art that the following embodiments are shown by way of example only and that other applications/embodiments may be developed without departing from the spirit or scope of the present invention.

Claims (16)

1. The use of one or more dispersion agents in the extrusion of a cementitious material for the purpose of increasing the efficacy of a viscosity enhancing agent during extrusion, being a use wherein the viscosity enhancing agent is provided as 0.3 to 5% by weight of dry solids of cementitious material and the dispersion agent is provided as 0.05 to 0.5% by weight of dry solids of the cementitious material.

2. Use as claimed in claim 1 wherein the dispersion agent is added in a quantity sufficient to maintain extrudability of the cementitious material with a reduced dosage of viscosity enhancing agent as compared to a conventional dosage.

3. Use as claimed in claim 1, wherein the dispersion agent is added in a quantity sufficient to maintain extrudability of the cementitious material with a lower grade or lower molecular weight viscosity enhancing agent as compared to a conventional dosage.

4. Use as claimed in claim 1, wherein the dispersion agent is added in a quantity sufficient to improve extrudability for a quantity of viscosity enhancing agent *o substantially equivalent to a conventional dosage.

5. Use as claimed in any one of claims 1 to 4 wherein the viscosity enhancing agent is a cellulose ether.

6. Use as claimed in any one of claims 1 to 5 wherein the viscosity enhancing agent is hydroxy alkyl cellulose, hydroxy alkyl alkyl cellulose, carboxy alkyl cellulose or alkyl cellulose, or mixtures thereof.

7. Use as claimed in any one of claims 1 to 6 wherein the viscosity enhancing agent is selected from the group consisting of hydroxy propyl methyl cellulose, hydroxy ethyl methyl cellulose, methyl cellulose, hydroxy ethyl cellulose, carboxy methyl cellulose, ethyl cellulose and hydroxy butyl methyl cellulose, or mixtures thereof.

16- 8. Use as claimed in any one of claims 1 to 7 wherein the viscosity enhancing agent is selecting from the group consisting of polyvinyl alcohols, gums including Welan gum, locust bean gum and guar gum, sodium alginate, swellable alkali emulsions of acrylic co-polymers, clays or modified clays, polyethylene glycol and acrylic based polymers or mixtures thereof. 9. Use as claimed in any one of claims 1 to 8 wherein the dispersion agent is a sulphonated type dispersion agent. Use as claimed in any one of claims 1 to 9 wherein the dispersion agent is sulphonated melamine formaldehyde or sulphonated naphthalene formaldehyde. 11. Use as claimed in any one of claims 1 to 10 wherein the viscosity enhancing agent and dispersion agent are combined prior to treating the cementitious material. S 12. Use as claimed in any one of claims 1 to 11 wherein the viscosity enhancing S S agent and dispersion agent are combined in situ with the cementitious material. 13. A method for extruding a cementitious material, comprising adding a quantity of 15 dispersion agent sufficient to increase the efficacy of a viscosity enhancing agent contained in said cementitious material wherein the viscosity enhancing agent is provided as 0.3 to 5% by weight of dry solids of the cementitious material and the dispersion agent is provided as 0.05 to 0.5% by weight of dry solids of cementitious material. 14. A method as claimed in claim 13 wherein the dispersion agent is added in a quantity sufficient to maintain extrudability of the cementitious material with a reduced dosage of viscosity enhancing agent as compared to a conventional dosage. A method as claimed in claim 13, wherein the dispersion agent is added in a quantity sufficient to maintain extrudability of the cementitious material with a lower -17- grade or lower molecular weight viscosity enhancing agent as compared to a conventional dosage. 16. A method as claimed in claim 13, wherein the dispersion agent is added in a quantity sufficient to improve extrudability for a quantity of viscosity enhancing agent substantially equivalent to a conventional dosage.

17. A method as claimed in any one of claim 13 to 16 wherein the viscosity enhancing agent is a cellulose ether.

18. A method as claimed in any one of claims 13 to 17 wherein the viscosity enhancing agent is hydroxy alkyl cellulose, hydroxy alkyl alkyl cellulose, carboxy alkyl cellulose or alkyl cellulose, or mixtures thereof. A method as claimed in any one of claims 13 to 18 wherein the viscosity enhancing agent is selected from the group consisting of hydroxy propyl methyl cellulose, hydroxy ethyl methyl cellulose, methyl cellulose, hydroxy ethyl cellulose, carboxy methyl cellulose, ethyl cellulose and hydroxy butyl methyl cellulose, or mixtures 15 thereof.

20. A method as claimed in any one of claims 13 to 19 wherein the viscosity o: enhancing agent is selecting from the group consisting ofpolyvinyl alcohols, gums include Welan gum, locust bean gum and guar gum, sodium alginate, swellable alkali emulsions of acrylic co-polymers, clays or modified clays, polyethylene glycol and acrylic based polymers or mixtures thereof.

21. A method as claimed in any one of claims 13 to 20 wherein the dispersion agent is a sulphonated type dispersion agent.

22. A method as claimed in any one of claims 13 to 21 wherein the dispersion agent is sulphonated melamine formaldehyde or sulphonated naphthalene formaldehyde. 18-

23. A method as claimed in any one of claims 13 to 22 wherein the viscosity enhancing agent and dispersion agent are combined prior to treating the cementitious material.

24. A method as claimed in any one of claims 13 to 23 wherein the viscosity enhancing agent and dispersion agent are combined in situ with the cementitious material. The use substantially as herein described with reference to any one of the embodiments of the invention illustrated in the accompanying examples.

26. The method substantially as herein described with reference to any one of the embodiments of the invention illustrated in the accompanying examples. DATED this 2 3 rd day of March 2005 g*o Shelston IP Attorneys for: James Hardie Research Pty Limited *1