AU750577B2 - Apertured film having improved fluid distribution properties, method of forming same, and absorbent products incorporating same - Google Patents

Description

-1-

AUSTRALIA

PATENTS ACT 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT

ORIGINAL

Name of Applicant/s: Actual Inventor/s: Address for Service: Invention Title: McNeil-PPC, Inc.

Judith E. Roller and Thomas Patrick Luchino and David A. Burwell and Sunita Pargass BALDWIN SHELSTON WATERS MARGARET STREET SYDNEY NSW 2000 'APERTURED FILM HAVING IMPROVED FLUID DISTRIBUTION PROPERTIES, METHOD OF FORMING SAME, AND ABSORBENT PRODUCTS INCORPORATING SAME' Details of Original Application No. 68616/96 dated 27 Aug 1996 The following statement is a full description of this invention, including the best method of performing it known to me/us:- File: 29336AUP00

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la- APERTURED FILM HAVING IMPROVED FLUID DISTRIBUTION PROPERTIES, METHOD OF FORMING SAME, AND ABSORBENT PRODUCTS INCORPORATING SAME Field Of The Invention This invention relates to apertured films having primary utility as a cover member for an absorbent article, and to methods and apparatus for forming such apertured films.

Background Of The Invention Any discussion of the prior art throughout the specification should in no way be considered as an admission that such prior art is widely known or forms part of common general knowledge in the field.

For many years it has been common to use nonwoven fabrics as a cover member, or facing layer, for products that are adapted to receive body discharges, such as disposable diapers, sanitary napkins, adult incontinent devices, wound dressings and the like. Such fabrics have typically been formed by air-laying, carding, spun bonding and the like, and it is known to post-treat such fabrics to provide strength and integrity, as by the application of binders or fiber entanglement, either mechanically or by the application of fluid forces. Since such fabrics are often formed of hydrophobic material, it is also known to post-treat such fabrics with surface active agents to promote the passage of body discharges through the fabric. Such fabrics have, or are perceived to have, desirable characteristics such as breathability, drapeability, softness, and pleasant hand and tactile impression.

One of the drawbacks associated with facing layers formed of a nonwoven fabric is that liquid, such as urine, menses, wound exudate, and the like, that passes through the facing layer and into the absorbent core has a tendency to strike back through the facing 0*.

25 layer, particularly under pressure and when the liquid in the absorbent core approaches the volumetric storage capacity of the core. For this reason, and other reasons, it has been known in the past to utilize apertured plastic films as the facing layer in absorbent .articles.

S0 0 -2- The following list includes disclosures of such apertured films in issued U.S. and foreign patents and published patent applications.

U.S. Patent No. 3.632,269 Doviak et al.

U.S. Patent No. 3,929,135 Thompson et al.

U.S. Patent No. 4,324,276 Mullane U.S. Patent No. 4,351,784 Thomas et al.

U.S. Patent No. 4,381,326 Kelly U.S. Patent No. 4,456,570 Thomas et al.

U.S. Patent No. 4,535,020 Thomas et al.

10 U.S. Patent No. 4,690,679 Mattingly et al.

U.S. Patent No. 4,839,216 Curro et al.

U.S. Patent No. 4,950,264 Osborn U.S. Patent No. 5,009,653 Osborn U.S. Patent No. 5,112,690 Cohen et al.

15 U.S. Patent No. 5,342,334 Thompson et al.

U.S. Patent No. 5,352,217 Curro U.S. Patent No. 5,368,910 Langdon U.S. Patent No. 5, 368 ,926 Thompson et al.

U.S. Patent No. 5,376,439 Hodgson et al.

20 U.S. Patent No. 5,382,245 Thompson et al.

Patent No. 5,382,703 Nohr et al.

U.S. Patent No. 5,383,870 Takai et al.

U.S. Patent No. 5,387,209 Yamamoto et al.

EP 0 304 617 Suda et al.

EP 0 432 882 A2 Shipley EP 0 598 204 Al Garavaglia et al.

EP 0 626 158 Al Coles et al.

EP 0 626 159 Al Taki et al.

EP 0 640 328 Tanaka et al.

JP 3-286762 A Yamamoto et al.

WO 92/18078 Al Colbert WO 93/15701 Al Turi et al.

WO 94/18926 Al Perry WO 94/22408 Al Langdon WO 94/28846 Al Steiger et al.

WO 95/00093 A2 Osborn et al.

While certain of such apertured films have functioned reasonably well for their intended purposes, the vast majority of such films have actual and perceived major deficiencies. For example, even though such apertured films may permit fluid to readily pass therethrough, and may minimize strike-back of such fluid, such apertured films nevertheless tend to have the appearance, feel and hand of a film, rather than a fabric. Such film-like characteristics are considered as a negative by the consumer, and thus absorbent products with apertured films as a facing layer have not met with widespread consumer acceptance.

SMajor improvements for apertured film facing layers for absorbent products are disclosed in commonly assigned US Patent 5,567,376 (Turi et In the above-mentioned Turi et al. Patent, an apertured film, and methods and apparatus for forming the film, are disclosed which impart to the film physical characteristics like those ofnonwoven fabrics. This is accomplished by supporting a film formed of stretchable thermoplastic polymeric material on localized support regions of a backing member, and directing a fluid in the form of high pressure, small diameter columnar jets against the upper surface of the film, so that unsupported portions of 25 the film -4are directed downwardly between the support regions to cause the formation of micro-holes and fiber-like elements (fibrils) thereabout to impart to the apertured film physical characteristics of appearance, softness, feel and hand.

like those of a nonwoven fabric. While such apertured films are a marked improvement over prior art apertured films, it is desired to provide further improvements in such apertured films, as by improving the ability of such films to pass viscous fluids, such as menses, and as by improving the ability of such films to wick or transport liquid through the thickness of the film (in the z-direction), and to then wick liquid away (in the x and y direction, 1 0 particularly on the underside of the film, that is, the side of the film facing the absorbent core) from an initially wetted zone so as to promote more efficient utilization of the absorbent capacity of the entire absorbent core.

:.:For use of apertured films as topsheets for sanitary napkins, clean-dry properties are very much desired. This means that the sanitary napkin should appear clean and dry to the user even after it has accepted a flow of menstrual fluid. There are many factors affecting the clean-dry properties of a sanitary napkin, including the aperture characteristics and open area of the napkin cover material. There is a trade-off in the effects of the film aperture size and open area on clean-dry properties. On the one hand, large apertures allow the fluid to be more rapidly transmitted to the absorbent core. On the other hand, apertures that are too large permit the fluid to be transported back through the topsheet from the absorbent core (a phenomenon sometimes referred to as "strike back") and to contact the wearer. Furthermore, large open areas tend to allow the stain on the absorbent core of the napkin to be visible through the topsheet and give the wearer the perception that the product has not kept her clean. To exhibit both clean and dry properties, a topsheet must have a carefully balanced combination of aperture size and open area: large enough apertures to rapidly accept a flow of menstrual fluid and to allow it to pass through to the napkins absorbent core, but small enough to mask the stain on the underlying absorbent core to give the wearer the perception of cleanliness.

Summary of the Invention In accordance with one aspect of the present invention, apertured film of the type disclosed in the above-mentioned Turi et al. patent are improved by providing such films with larger apertures and sufficient open area so that viscous fluids, such as menses, can flow readily through the film. These improved properties are imparted to the film by subjecting the film to fluid forces in the form of columnar streams or jets from at least two sets of orifices, the orifices of one set having a diameter greater than ten mils (0.25 mm), and the fluid supplied to the orifices having a relatively low pressure less than about 500 psig (3,450 kPa), and the orifices of at least one other set having a diameter of less than or equal to ten mils (0.25 mm) and the fluid supplied thereto having a relatively high pressure greater than about 500 psig (3,450 kPa). The present invention can be practiced with 15 selective variation of the sequence to which the film is subjected to fluid forces *oo.

from the low and high pressure orifices, that is, first low pressure then high pressure, or first high pressure then low pressure, or other combinations or variations.

The apertures are, for the most part, irregular in shape and size. They are measured by various techniques that approximate the diameter, which may be expressed as equivalent hydraulic diameter (EHD) or equivalent circular diameter (ECD). The resulting apertured film has a combination of large sized apertures having average EHD's from about 7 mils (0.18 mm) to about 30 mils (0.76 mm), and small sized apertures having average EHD's of from about 1 mil (0.025 mm) to about 7 mils (0.18 mm). Such apertured films have an open area in the range of from about 3% to about 13%.

The improved apertured film of the present invention is preferably formed on a backing member like that shown in Figures 17-19 of the above-mentioned Turi et al. patent, which results in the film having a series of generally parallel ridges formed by generally vertically orientated side walls which define a series of generally parallel valleys. The film thus includes generally parallel alternating solid or closed portions of the film separated by apertured or open portions of the film, that contain the aforementioned combination of large and small sized apertures. Both size apertures are formed as a result of elongating and drawing the stretchable material between the localised support regions of the backing member as a result of the application of fluid pressure, and as the film elongates it undergoes thinning until it finally reaches the point of rupturing splitting and fibrillating) to form the above-mentioned apertures.

As with apertured films disclosed in the Turi et al. patent, the apertures are surrounded by a network of fiber-like elements or micro-strips of drawn plastic material. Such drawn fiber-like elements (fibrils) cooperate with the apertures to provide the apertured film with physical characteristics similar to those of ~nonwoven fabrics. The fiber like elements have lengths varying from about 0.005 inch (0.13 mm) to about 0.05 inch (1.27 mm), widths ranging from about 0.001 inch (0.03 mm) to about 0.035 inch (0.89 mm), and thicknesses ranging from about 0.00025 inch (0.006 mm) to about 0.002 inch (0.05 mm).

In accordance with the present invention, apertured films of the type disclosed in the above mentioned Turi et al. patent, and of the improved type disclosed and claimed in commonly assigned, U.S. Patent No. 5,770,144 are modified so as to provide the film with improved fluid distribution properties in the 25 regions of the film which have been subjected to stretching, by downward deflection of the film into the recessed regions of the support member, during formation of the film.

-7- In accordance with the present invention, the aperaued film is formed from a pre-embossed starting film having a female side with observable cupped recesses and a male side with observable prorusions the male side being smoother than the female side. Preferably, one side of the film is corona discharge treated, and the treated side is disposed against the support regions of the backing member. Following aperturing in accordance with the teachings of the above-mentioned commonly-assigned, U.S. Patent No. 5,770,144 in one embodiment of the present invention, the corona treatment is on the male side of the film and the treated side is disposed against the support to regions of the forming member. A surface active agent, a "surfactant" in a water-based solution is applied to the female side of the film and the film is rolled up so that surfactant is transferred from the female side of the film to the male side thereof. In accordance with another embodiment of the invention, the corona treated male side of the film is disposed against the 15 support regions of the forming member, and following aperturing, surfactant is applied directly on the male side of the aperured film. In both embodiments, the resultant film is used with the corona-treated side facing the absorbent core of an associated absorbent article. It is preferred to have more surfactant on the corona-treated male side of the film to provide a gradient which enhances z-direction flow of liquid through the film, and which enhances x-y direction flow of liquid on the underside of the film.

«These embodiments not only provide for efficient manufacture, but also result in a film having improved fluid distribution properties. In this regard, the resulting film also provides a wicking mechanism for spreading 25 fluid in the x-y direction of the film on the side adjacent the absorbt core, T which promotes more effective use of the absorbent core.

-8- The method for forming an apertured film from a stretchable thermoplastic polymeric material in accordance with the present invention comprises the steps of providing an embossed starting film comprising stretchable thermoplastic polymeric material having an upper side and a lower corona discharge treated side. The method further comprises providing a backing member comprising localized support regions for supporting the starting film, recessed zones into which the film may be deformed by the application thereto of fluids, and means for allowing the applied fluid to be transported away from the backing member.

The starting film is supported on the backing member with portions of the lower side of the film being in contact with the support regions of the backing member and with the upper side of the film facing away from the backing member. The method further comprises directing a fluid in the form of columnar streams from at least two sets of orifices against the upper side of the starting film in a zone of contact, ie., a zone in which the film is subjected to the forces from the fluid streams. The orifices of the first set each have a diameter greater than ten mils (0.25 mm) and the fluid supplied thereto has a pressure less than 500 psig (3,450 kPa) to cause the formation of large sized holes in the starting film. The orifices of the second set each have a diameter less than or equal to ten mils (0.25 mm) and the fluid supplied thereto has a pressure ofat least 500 psig (3,450 kPa) to cause the formation of micro-holes in the starting film, whereby a 20 combination of large sized and micro-holes are formed in the starting film.

The present method further comprises moving the film from the contact zone, coating the upper side of the apertured film with a surface active agent, and winding the apertured film into a roll with the lower and upper sides being in surface-to-surface contact. By this surface-to-surface contact, at least a portion of the surface active agent is transferred from the upper side of the film to the lower side thereof.

Other features and advantages of the present invention will become readily apparent from the following detailed description, the accompanying drawings, and the appended claims.

According to a further aspect of the present invention there is provided a method for forming an apertured film from a stretchable thermoplastic polymeric material comprising: a) providing a starting film comprising said stretchable thermoplastic polymeric material and having a lower side that has been corona discharge treated and an upper side that has not been corona discharge treated; b) providing a backing member comprising localized support regions for supporting said starting film, recessed zones into which said starting film may be deformed by the application thereto of fluids, and means for allowing said fluid to be transported away from said backing member; c) supporting said starting film on said backing member with portions of the lower side of said starting film being in contact with the support regions of said backing member and with the upper side of said starting film facing away from said backing member; d) forming irregular size micro-holes and large sized holes in said starting film by directing a fluid in the form of columnar streams from at least a first set and a second e •20 set of orifices against the upper side of said starting film in a zone of contact, the orifices of the first set each having a diameter greater than ten mils (0.25 mm) and the fluid o° •supplied thereto having a pressure less than 500 psig. (3450 kPa) to cause said starting film to rupture into a multiplicity of said large sized holes in said starting film, the orifices of the second set each having a diameter less than or equal to ten mils (0.25 mm) and the fluid supplied thereto having a pressure of at least 500 psig. (3450 kPa) to cause the starting film to rupture into a multiplicity of said micro-holes in said starting film, whereby a combination of said large sized holes and said micro-holes are formed in said starting film to define an apertured film having a lower side and an upper side; e) moving said apertured film from said contact zone; T 30 f) applying a liquid coating ofa surface active agent from an exterior source to %p the upper side of said apertured film which has not been corona discharge treated; and 9ag) winding said apertured film into a roll with said lower side being in surface contact with said upper side, whereby at least a portion of said surface active agent is transferred from the upper side of the apertured film to the lower side thereof.

According to another aspect of the present invention there is provided a method of forming an apertured film having improved fluid distribution properties and comprising the steps of: a) providing an embossed starting film having a corona discharge treated male side and a female side that has not been corona discharge treated; b) supporting said embossed starting film on a three-dimensional forming member with the corona discharge treated male side of said film facing said forming member; c) directing a fluid in the form of columnar jets against the female side of said starting film with a force sufficient to form apertures in said starting film to define an apertured film having male and female sides corresponding to said starting film male and female sides; d) drying said apertured film; e) applying a liquid surface active agent from an exterior source to said o. apertured film female side which has not been corona discharge treated; and f) winding said apertured film into a roll with said male side being in surface contact with said female side, whereby at least a portion of said surface active agent is transferred from the female side of the apertured film to the male side thereof.

According to another aspect of the present invention there is provided a method of forming an apertured film having improved fluid distribution properties and comprising the steps of: a) providing an embossed starting film having a male side and a female side; b) corona discharge treating the male side of said starting film but not the female side of said starting film; c) supporting said embossed starting film on a three-dimensional forming member with the corona discharge treated male side of said starting film facing said forming member and with the female side facing outwardly away from said forming Smember; 9b d) directing a fluid in the form of columnar jets against the outwardly facing female side of said starting film with a force sufficient to form apertures in said starting film to define an apertured film having male and female sides corresponding to said starting film male and female sides; e) drying said apertured film; f) after step applying a liquid surface active agent from an exterior source onto the exposed surface of one of said apertured film male and female sides; and g) winding said apertured film into a roll.

According to another aspect of the present invention there is provided a method for forming an apertured film from a stretchable thermoplastic polymeric material comprising the steps of: a) providing a starting film comprising said stretchable thermoplastic polymeric material and having an upper side and a corona discharge treated lower side; b) providing a backing member comprising localized support regions for supporting said starting film, recessed zones into which said starting film may be deformed by application thereto of fluids, and means for allowing said fluids to be transported away from said backing member; :loerc) supporting said starting film on said backing member with portions of the ~lower side of said starting film being in contact with the support regions of said backing member and with the upper side of said starting film facing away from said backing member; d) forming irregular size micro-holes and large sized holes in said starting film by directing a fluid in the form of columnar streams from at least a first set and a second set of orifices against the upper side of said starting film in a zone of contact, the orifices of the first set having a diameter greater than ten mils (0.25 mm) and the fluid supplied thereto having a pressure less than 500 psig. (3450 kPa) to cause said starting film to rupture into a multiplicity of said large sized holes in said starting film, the orifices of the second set having a diameter less than or equal to ten mils (0.25 mm) and the fluid supplied thereto having a pressure of at least 500 psig. (3450 kPa) to cause the starting 30 film to rupture into a multiplicity of said micro-holes in said starting film, whereby a combination of large sized holes and micro-holes are formed in said starting film to 9c define an apertured film having lower and upper sides corresponding to said starting film lower and upper sides; e) moving said apertured film from said contact zone and drying said apertured film; and f) after step applying a liquid coating of a surface active agent from an exterior source onto the exposed surfaces of both of said apertured film upper and lower sides.

Unless the context clearly requires otherwise, throughout the description and the claims, the words 'comprise', 'comprising', and the like are to be construed in an inclusive sense as opposed to an exclusive or exhaustive sense; that is to say, in the sense of "including, but not limited to".

Brief Description Of The Drawings FIG.1 is a schematic side elevational view of a production line for forming apertured film in accordance with the present invention; FIG. 2 is a schematic side elevational view, on an enlarged scale, of the unwind section of the apparatus for producing the apertured film of the present invention; FIG. 3 is an enlarged side elevational view of the aperturing section of the apparatus used to form the apertured film of the present invention; FIG. 4 is an enlarged side elevational view of the dewatering section of the 20 apparatus used to form the apertured film of the present invention; FIG. 5 is an enlarged side elevational view of the drying section of the apparatus used to form the apertured film of the present invention; FIG. 6 is an enlarged side elevational view of the slitter/rewinder section of the apparatus used to form the apertured film of the present invention; 25 FIG. 7A is a schematic view of an orifice strip used in the apparatus to form one of the apertured films of the present invention; FIG. 7B, C, D and E are enlarged views of orifice patterns which can be used in the apparatus to form the apertured films of the present invention; a FIG. 8 is an exploded perspective view of a starting film positioned on a backing member for processing in accordance with the present invention; FIG. 9 is a top plan view of the backing member shown in the lower portion of FIG. 8; FIG. 10 is an enlarged cross-sectional view taken along line of FIG. 9; FIGS. 11A-D are views similar to FIG. 10 showing sequential stages in the drawing of the starting film to form apertures in accordance 10 with the teachings of the present invention; FIG. 12 is a photograph in top plan of an apertured film formed at a magnification of 7.5 times; FIG. 13 is an end elevational view of the apertured film of FIG. 12; FIG. 14 is an end elevational view of the apertured film of FIG. 13 at a magnification of 15 times; FIG. 15 is a top plan view of another apertured film at a magnification of 7.5 times; FIG. 16 is an end elevational view of the apertured film of FIG. FIG. 17 is an end elevational view of the apertured film of FIG. 15 at a magnification of 15 times; FIGS. 18A and B are photographs taken at a magnification of X of apertured film formed in accordance with the invention, formed from an embossed starting film with the male side thereof against the associated forming member, wherein FIG. 18A is the side thereof against which water jets were directed, and FIG. 18B is the side thereof positioned against the associated forming member; -11 FIG. 19 is a block diagram showing the various steps of the process for producing the apertured film in accordance with the present invention; FIG. 20 is a perspective view of a sanitary napkin comprised of an apertured film according to the present invention; and FIG. 21 is a view, in section, taken along line 21-21 of FIG. FIG. 22 is a graph depicting aperture size distribution in a sample of apertured film made at 875 psig (6,000 kPa) on an apparatus using three orifice strips each having a plurality of orifices, all of the orifices being 5 mils (0.127 mm) in diameter, said orifice strip being shown in FIG. 7A; FIG. 23 is a graph depicting aperture size distribution in a sample of apertured film made on an apparatus comprising a single orifice strip having a plurality of orifices each 20 mils (0.51 mm) in diameter, said orifice strip being shown in FIG. 7C; FIG. 24 is a graph depicting aperture size distribution in a sample of apertured film made on an apparatus comprising a first orifice strip (shown in FIG. 7C) having a plurality of orifices, all of which have a diameter of 20 mils ~(0.51 mm), and a second orifice strip (shown in FIG. 7A), downstream of the first strip, wherein the second strip has a plurality of orifices all of which have a diameter of 5 mils (0.127 mm); FIG. 25 is a graph depicting aperture size distribution in a sample of apertured film made in accordance with the invention; and FIG. 26 is a graph depicting the results of comparison in which the spacing of the orifices comprising the orifice strip is varied.

Description of the Preferred Embodiments 25 While the present invention is susceptible of embodiment in various forms, there is shown in the drawings and will hereinafter be *OOC -12described presently preferred embodiments, with the understanding that the present disclosure is to be considered as an exemplification of the invention, and is not intended to limit the invention to the specific embodiments illustrated.

Referring now to the drawings, FIG. 1 is a schematic, side elevational view of one embodiment of a production line that may be utilised to produce apertured films in accordance with the teachings of the present invention. As is indicated by the direction arrow, the process flow proceeds from right to left in FIG. 1. As is shown in FIG. 1, the production line has five major stations; a film unwinding station 30, an aperturing station 40, a dewatering station 50, a drying station 60, and a slitting, rewinding, and surfactant application station As shown in FIG. 2 in the film unwinding station, two rolls 31 of starting film material 33 are mounted for rotation on frame F. The film from rolls 31 is fed over guide rollers and into festoon 32 which has an automatic (closed loop) tension control system. Film 33, under suitable tension, eg. between 0.1 to 1 pound per linear inch (17.8 to 178 grams per cm), emerges from festoon 32, and proceeds to the aperturing station oo..

While many different starting film materials are suitable for use in the present invention, one of the preferred materials is a polyethylene film commercially Soo* available from Exxon Chemical under product designation EMB-631. This film is an 1:4 20 embossed, white pigmented polyethylene film. The polyethylene component consists of a blend of 40% by weight low density polyethylene and 60% by weight linear low density polyethylene. The film has 6.5% by weight titanium dioxide.

The starting film is embossed with a diamond pattern at 165 lines per ~inch (66 per cm) to provide on one side of the film, referred to as the male side, a •25 plurality of discontinuous observable protrusions separated by a continuous, interconnected grooved pattern. The other side of the embossed starting film,

O

13referred to as the female side, has a plurality of observable, cupped recesses separated by a continuous, interconnected rib pattern. The cupped recesses in the female side of the film are in respective registration with the protrusions on the male side of the film. The starting film is electrostatically treated with a corona discharge treatment on one side, preferably the male side. The film has an.ultimate tensile strength of 1750 grams in the machine direction (with 500% elongation at break), and 1300 grams in the cross direction (with 650% elongation at break), as determined using ASTM test D-882.

The process for making the film of the invention may be either batch or continuous, generally similar to the batch and continuous processes disclosed in U.S. Patent No. 5,567,376. The preferred embodiment is a continuous apparatus, as further disclosed herein.

With reference to FIG. 3, the film 33 from the unwind station is shown entering aperturing station 40 at the right hand side thereof.

Aperuring station 40 includes a honeycomb-type support drum 41 rotatably mounted on a frame Fl. The drum 41 has a three-dimensional backing or forming member, described in detail hereinafter, mounted on its outer peripheral surface. Four water jet manifolds 42 are also supported on frame 20 F1 and four suction slots, one for each manifold 42, are provided interiorly of the support drum, as is also hereinafter described in detail. The suction slots are mounted within the drum and are aligned with the water jet manifolds located outside of the drum. Each water jet manifold comprises a metallic strip, hereinafter sometimes referred to as an orifice strip, having a 25 plurality of orifices having predetermined size and spacing. Specific examples of such orifice strips are described in more detail hereinafter. A given manifold 42 may comprise one or more orifice strips. The orifice size preferably remains constant for each strip. However, the orifice size may vary on a given strip. The distance between the lower surface of the orifice -14strip and the outer surface of the backing member of the aperturing drum is preferably in the range of between 0.50 to 1.0 inches (1.25 to 2.5 cm).

Hot water under pressure is pumped to the manifolds 42, and the pressurised water exits through the plurality of orifices in the orifice strip in the form of columnar waterjets. The water pressure in each manifold 42 may be separately regulated. The entering film 33 is trained over a guide roller 43, and then over the outer periphery of the three dimensional forming member mounted over the support drum 41, with the male side of the film being disposed against the forming member.

The columnar streams of water exiting the orifice strips impinge on the film and cause the film to deflect downwardly into the recessed regions of the backing member mounted on the support drum, thereby causing the film to stretch and rupture into a multiplicity of irregular sized holes. The now-apertured film 44 emerges from aperturing station 40 at the left-hand side thereof and passes to dewatering section As is shown in FIG. 4, in the dewatering section 50, two dewatering drums 51 are mounted for rotation on frame F3. Drums 51 have a honeycomb configuration, and each drum has two vacuum slots associated therewith, capable of drawing vacuum up to 7 inches (17.5 cm) Hg. Twelve air knives 52 are provided, six air knives being provided for each drum 51. The suction slots associated with the :dewatering drums 51 are located internally of the drums, whereas air knives 52 are located outside of the drums 51. Excess water is removed from the apertured film by the impingement of high velocity air from knives 52 and by suction through the suction slots in drums 51. Air knives 52 operate at an air temperature range between about 150'-180' F (66'-82' Total air flow through the twelve air knives 52 is between about 1,000 to about 2,000 cubic feet per minute per linear foot (1,550 to about 3,100 litres per second per metre) of apertured film width. The dewatered film 53 emerges from the dewatering station 50, at the left-hand side thereof, and passes to the drying section.

With reference to FIG. 5, the air drying station 60 is illustrated as including two vacuum drums 61 mounted on frame F4. Each drum 61 has a suction slot, which has an arc of 300' around the drum. Twenty air knives 62 are positioned outwardly of each vacuum drum 61 and the air knives 62 operate at a temperature between 150'-180' F (66-82°C). The combined air flow for all forty air knives 62 is between about 5,000 to about 7,000 cfm per linear foot (7,750 to about 10,800 litres per second per metre) of apertured film width.

The pressure drop caused by the vacuum in drums 61 is about 2 inches (5 cm) of water measured across the film. The dried film 63 emerges from drying section 60 at the left-hand side thereof and passes to slitter/rewinder section Referring now to FIG. 6, the film 63 from the drying section enters the slitter/rewinder station 70 at the right hand side thereof. A slitter 71, consisting of spaced score cut type slitting knives, cuts the dried apertured film to the desired width. The dried and slit apertured film then passes to a surfactant applicator 72, where a suitable surfactant, eg., Tween 20, is applied to the film by kiss-coating. The surfactant is preferably provided in an aqueous solution consisting of about 48.8 1.5 percent surfactant. In an exemplary .ol.

o embodiment of the invention, the surfactant roller coating speed is 15 3 inches (38.1 7.6 cm) per minute. Preferably, the surfactant is applied to the 20 female side of the film. Alternatively, the surfactant can be applied to the male side of the film, or to both sides of the film. The above-mentioned parameters result in a surfactant solution add-on of 0.25 mg/in 2 0.07 (0.039 mg/cm 2 0.011). The surfactant coated slit apertured film, while still wet, then passes to a center driven rewind unit 73 mounted on frame F5 where the coated slit 25 apertured film is wound into a roll.

When the film is wound into a roll, the male and female sides of the film come into contact with each other. The surfactant on one side is still wet when the film is wound into a roll, and some of the surfactant transfers to the other side of the film to which surfactant has not been g.

-16applied. It is believed that when the surfactant is initially applied to the side of the film that is not corona treated (with no surfactant being applied directly to the corona treated side), approximately 65% or more of such applied surfactant transfers to the corona treated side of the film when the film is wound into a roll. It is believed that when the surfactant is initially applied to the corona treated side of the film (with no surfactant being directly applied to the non-corona treated side), approximately 25% or less of the applied surfactant transfers to the side of the film that is not corona treated when the film is wound into roll. Therefore, regardless of which side 10 initially receives the surfactant application, a transfer of surfactant from one side to the other occurs when the film is wound into a roll, and the surfactant is distributed between the corona treated and non-corona treated sides such S.that the corona treated side retains approximately 65-75% or more, and the non-corona treated side retains approximately 25-35% or less, of the surfactant. The resulting apertured film material has a wettability gradient between the corona treated side and the non-corona treated side.

Testing of distilled water contact angles in Exxon EMB-631 film with male side corona treatment (unapertured) has resulted in a contact angle on the female side of 78 degrees when the surfactant was initially 20 applied to the male side, and 76 degrees when the surfactant was initially applied to the female side. In both cases, the surfactant was applied in the manner in which it was applied to an apertured film, and the film was rolled up after application of the surfactant solution while the film was still wet.

Transfer of the solution from the side on which it was initially applied to the opposite side of the film was as described above approximately 65-75% of the surfactant was retained by the corona-treated side). The measured contact angle on the male side in both cases was zero degrees When no surfactant was applied, the contact angle was 102 degrees on the female side and 72 degrees on the male side. See Table 9 below.

17 Since the contact angle is an indicator of the wettability of the surface (with a lower contact angle indicating a higher degree of wetability), it is believed that a gradient in contact angle from the non-corona treated side to the corona treated side, as discussed above, facilitates the ability of the apertured film material to draw liquid from the non-corona treated side to the corona treated side. Further, it is believed that the reduction in contact angle to zero degrees on the corona treated side, which, in the absorbent articles of the present invention, is the side that normally faces the absorbent core of an absorbent article (such as a sanitary napkin) facilitates wicking for the spreading fluid in the x-y direction along the surface of the film that faces the absorbent core.

In prior art apertured films, it has been desirable to apply surfactant only to the side of the film facing the skin of the user of the absorbent article. The application of surfactant on the body facing side of the film facilitates the spreading of liquid on the body facing side of the film, and thereby increases absorption through the film and into the absorbent core.

Further, the application of surfactant on the body side of the film provides a better tactile feeling for the user. A film processed according to the above method, wherein surfactant is distributed on both the body facing side and the absorbent core facing side of the apertured film, has not heretofore been thought to be desirable. Therefore, the film of the present invention has been found to have surprising, unexpected results regarding the ability of the apertured film to draw liquid from the body side to the absorbent side. See discussion regarding Tables 11-14below.

Referring to FIGS. 7A-7E, the columnar jets of water are discharged from one or more orifice strips having a plurality of orifices.

Preferably, the orifices are formed by drilling a precursor metallic strip to form cylindrical holes. However, it is anticipated that holes of various shapes may be used.

-18- FIG. 7A shows that an orifice strip 80 for delivering columnar jets of water each having a relatively small cross-section to form micro-holes in the film.

The orifices 82 in the manifold have a diameter of 5 mils (0.127 mm), and are spaced 0.020 inch (0.51 mm) apart. This manifold strip is available from the Nippon Nozzle Co., of Kobe, Japan.

FIGS. 7B-7E show orifice strips for producing columnar jets of water, each having a relatively large cross section, to form large sized holes in the film. FIG. 7B shows an orifice strip having two rows, 84, 86 of orifices 84', 86' that are spaced apart on opposite sides of a center tangent line. The orifices in each row have a diameter of 15 mils (0.38 mm), and are spaced 0.022 inch (0.56 mm) apart, center-to-center. The spacing of the orifices in the top row is offset from the spacing of the orifices in the bottom row by 0.011 inch. The strip contains 90.9 orifices per inch (35.8 orifices per cm).

FIG. 7C shows an orifice strip having two rows 88, 90 of orifices 88', 90' that are spaced apart on opposite sides of a center tangent line. The orifices in each row have a diameter of 20 mils (0.51 mm), and are spaced 0.032 inch (0.81 mm) apart. The spacing of the orifices in the top row is offset from the spacing of the orifices in the bottom row by 0.016 inch (0.41 mm). The strip contains 62.5 orifices per inch (24.6 orifices per cm).

FIG. 7D shows an orifice strip having two rows 92, 94 of orifices 92', 94' that are spaced apart on opposite sides of a center tangent line. The orifices in each row have a diameter of 25 mils (0.64 mm), and are spaced 0.038 inch (0.97 mm) apart. The spacing of the orifices in the top row is offset from the spacing of the orifices in the bottom row by 0.019 inch (0.48 mm). The strip 25 contains 52.6 orifices per inch (20.7 orifices per cm).

eaFIG. 7E shows an orifice strip for delivering columnar jets of water each having a relatively large cross-section for forming large sized holes in film.

r 7A The orifices each have a diameter of 0.025 inches (0.64 mm), and are spaced 0.083 inches (2.1 mm), center-to-center. While the orifice strip shown in FIG.

-19- 7E is suitable for forming film in accordance with the present invention, use of orifice strips such as shown in FIG. 7B-7D is presently preferred for use in combination with one or more orifice strips having relatively small orifices for formation of micro-sized holes.

The small orifices (see FIG. 7A) preferably have a diameter under mils (0.25 mm). The larger orifices (see FIGS. 7B-7E) preferably have a diameter greater than 10 mils (0.25 mm).

An apparatus for making apertured films of the present invention is described in detail in co-pending patent application Serial No. 08/417,404.

The apparatus for making the film of the present invention contains certain additional features, including a second set of orifice strips as discussed above with reference to FIGS. 7B-7E. The pressure of the water delivered to the small orifices is generally greater than 500 psig (3,450 kPa), preferably on the order of 500-1,600 psig (3,450-11,000 kPa) or higher. The pressure of water delivered to the large orifices is generally less than 500 psig (3,450 kPa), preferably on the order of 125-200 psig (860-1,400 kPa).

V00 *ooo C In a preferred embodiment, the aperturing equipment consists 0040 .000. of a honeycomb type support drum, a three dimensional forming member, 0 several water jet manifolds, and corresponding suction slots arranged interiorly 20 of and sequentially along a section of the circumference of the drum. The forming member is an engraved sleeve, as shown in FIGS. 8-10, which is mounted onto the honeycomb support drum. The suction slots are mounted within the drum and they are lined up with the waterjet manifolds located .o outside the drum. Each water jet manifold contains a metallic strip having a 925 plurality of orifices. For a given manifold, the orifice size remains constant ~throughout the strip. The distance between the orifice strip and the surface of the engraved sleeve is preferably between 0.50 to 1 inch (1.25 to 2.5 cm).

The manifolds are pressurised by pumping in heated water. The pressurised water exits through the series of orifices in the orifice strip, thus creating substantially columnar water jets. The energy of the columnar hot water jets impinging on the film causes the film to contour toward the surface of the engraved sleeve thereby causing the film to stretch and rupture into a multiplicity of irregular size holes. The pressure and temperature of the water supplied to each manifold may be separately regulated. The process parameters are as follows: Line Speed (yards/min): 50-200 (45-185 m/min) Water Temperature: 155°-165° F (68-74° C) Maximum Number of Manifolds Used: 3 Distance between Manifold Strip and Surface of Sleeve: 0.50"-1" (1.27-2.54 cm) Low Pressure Manifold: Number of Manifolds: 1 Orifice Size Range (inch): 0.0145 to 0.030 (0.37 to 77 mm) Pressure (psig): 150 25 (1,030 172 kPa) Water Flow: 8.0 2.0 gallons per minute per inch of orifice strip (gpm/in) (20.3 4.97 litres per second per metre) Suction Slot Vacuum (inch ofHg): 5.0 2.0 (-17 10.2 kPa) .*ee High Pressure Manifold: Number of Manifolds: Maximum of 2 Orifice Size Range (inch): 0.005 to 0.007 (0.127 to 0.18 mm) Pressure (psig): 1,150 350 (7,920 2,410 kPa) Water Flow: 0.9 0.22 gallons per minute per inch of orifice strip (2.23 0.55 litres per second per metre) Suction Slot Vacuum (inch ofHg): 5 3 (-17 10.2 kPa) Manifold Usage Sequence: The pressurized water jet manifolds and their associated orifice strips can be arranged in a variety of sequences relative to the direction of 21 continuous travel of the film on the drum. Any of the following five sequences may be used to aperture the film: 1. Low Pressure, High. Pressure 2. Low. Pressure, High Pressure. High Pressure 3. High Pressure, Low Pressure 4. High Pressure, Low Pressure, High Pressure High Pressure, High Pressure, Low Pressure Referrng to FIGS.- 8-10, -the forming member is a three dimensional surface having a plurality of radially extending support elements that rise from the base of the forming or backing member. These elements are substantially similar to the corresponding elements disclosed in U.S. Patent No. 5,567,376.

FIG. 8 is an exploded perspectve view of starting film 100 supported on backing member 102. The starting film may be either embossed or unemnbossed. Alternatively, a portion 104 of starting film 100 comprises embossments 106, and uneinbossed regions 108 as shown in the upper portion of FIG. 8.

Backing member 102 comprises a base portion 110 having an upper surface I10ba and a lower surface I 10b. Backing member 102 further ~comprises a plIurlty of apew 112~ running through the thcness of base 110 from upper surface 110a to lower surface 110b. As will be seen hereinafter, apertures 112 are provided to allow for removal of water during the manufacture of apertured film according to the invention. Backing member 102 also includes a plurality of radially-extending support elements 114. These support elements comprise a base 116 coinciding with the plane of upper surface 1 10 of portion 110 and a pair of angled side walls 118, 120 (best seen in FIGS. 9 and 10). Side walls 118, 120 extend outwardly from base 116 to meet at a la~pd portion or ridge 122. Support elements 114 are aligned in parallel and spaced equidistantly from one another. They may run -22either parallel to, perpendicular to, or at any angle to the sides Of the baccing member. As shown in FIGS. 8 and 9, these support elements 114, When viewed in plan, are generally sinusoidal-like or wavy in configuration. it will be understood that the spport elements may Ibe provided in other S configurations, msrightline, zig-zag and the Ike. A detailed description of the forming member is disclosed in U.S. Patent..

No. 5,567,376.

Referring to FIGS. 1 1A-D, the progression of the drawing of the starting film.124 to form apertues in acordance with the teachings of Present nventon are shown. Referring to FIG. hA, the starting film 124 is initially laid on the backing member. Referring to FIG. I the film 124 deforms in response to the application of columnar jets of water and is drawn stretched) downwardly and partially into the space between ~support elements. Referring to FIG. lIIC, as the film 1 24'is drawn. it becomes thinne. Referring to FIG. 111), as the film is further drawn and becomes thinei begins to break aVar and form holes 126. This process is fiurther described in U. S. Patent No. 5,567,3 76 wherein the formation of micro-holes surrounded by micro-strips, or fibrils, of film material, is described.

Due to the vertical elemens on the forming member, the flmn Of the Present &ion is expanded QJ.e., Js give significant dimensionality in the z-dhrection relative to the original thikness of the precursor unapernzredj film) immediately as it comes off the process. In some prior art Processes' expansion in the z-drctin must be accomplished in a separate ~=25 emig step (See for example, U.S. Patent No. 4,609,518). An expanded Uopseet limits the contact between the wearer and the absorbent layer and thus enhances the feeling of -dryness in products that incorporate it.

In the. films, absorbent products and methods disclosed herein, the holes in the film include both microholes and large sized holes, or may -23include large sized holes only. It is believed that the micro-holes are formed primarily from the drawing of film material in response to application of columnar jets of water coming from the smaller orifices of the orifice strip discussed above. It is believed that the large sized holes, also formed from the drawing of film material, are formed primarily in response to application of the columnar jets of water coming from the larger orifices, rather than the smaller orifices, of the orifice strip discussed above.

The resulting apertured film has a combination of large sized holes or apertures having average EHD's of from about 7 mils (0.18 mm) to about mils (0.76 mm), and small sized apertures or holes, sometimes referred to as micro-sized holes, having average EHD's of from about 1 mil (0.025 mm) to about 7 mils (0.18 mm). Such apertured films have an open area in the range of from about 3% to about 13%. It has been found that using orifice strips having orifices whose diameters range from about 10 to 25 mils (0.25 to 0.64 mm) results in the formation of apertures in the film having an average EHD of about 7 mils to about 17 mils (0.18 mm to about 0.43 mm). The fibrils surrounding and defining the micro-holes and the large sized holes are described in detail in U.S. Patent No. 5,567,376. The fibrils have lengths ranging from about 0.005 inch (0.13 mm) to about 0.05 inch (1.27 mm); widths ranging from about 0.001 inch (0.03 mm) to about 0.035 inch (0.89 mm); and thicknesses ranging from about 0.00025 inch (0.06 mm) to about 0.002 inch (0.05 mm). Photographs in FIGS. 12-18 show the combination of micro-holes and large sized holes of an apertured film.

The combination of large sized holes and micro-holes of the dimensions discussed above yield an improvement in the clean and dry properties of the film when used as a topsheet for a sanitary napkin. The resulting open area is in the range of 3 to 13%. In the prior art film having micro-holes only Patent No. 5,567,376), when 5 mil (0.127 mm) diameter columnar jets of water are used, the resulting apertured film has -24micro-holes with an average EHD of 3 mils (0.076 mm), and has an open area of about The increased aperture size and open area in an apertured film having large sized holes in combination with micro-holes in accordance with the invention provides an improved level of aperture size and open area so as to strike an advantageous balance: large enough apertures to rapidly accept a flow of menstrual fluid and to allow it to pass through the napkin's absorbent core, but small enough to mask the stain on the absorbent pad to give the consumer the perception of cleanliness. Thus, the absorbent products of the present invention made with the apertured films of the present invention have much improved clean and dry properties.

In a preferred embodiment of the invention, the starting film is apertured by large diameter, low pressure columnar water jets and small diameter, high pressure columnar water jets. This combination of jets at both high and low pressure produces larger apertures and greater open area than films made with small diameter high pressure jets alone. Films made by this embodiment also appear softer to the user than films made only with large diameter, low pressure jets.

FIG. 19 is a block diagram showing the several steps in the process for producing the novel apertured films of the present invention.

The first step in the process is to position a piece of thin, stretchable film of thermoplastic polymer material on a backing or support member (Box The support member with the stretchable film thereon is passed under high pressure fluid ejecting nozzles (Box The preferred fluid is water. The water is transported away from the support member, preferably using a vacuum *25 (Box The film is de-watered, suction being preferred for this purpose (Box The de-watered apertured film is removed from the support member (Box Residual water is removed from the apertured film, by applying ~a stream of air thereto (Box Surfactant is next applied to the apertured film (Box The apertured film is then rolled up to await use as 25 is or as a structural component of another product such as a sanitary. napkin, disposable diaper or wound dressing (Box 8).

Referring to FIGS. 20 and 21, there is shown a sanitry napkin 130 comprising an absorbent core 132 of wood pulp fibers, a thin. fluidimpermeable barrier film 134 and a cove-ring material 136 which may be any of the apertured films of the invention. Preferably, the covering film material has dhe structure shown and described herein. Barrier film 134, which may comprise, a thin film of polyethylene, contacts the lower .surface of absorbent core 132 and runs part way up the longitudinal sides of the absorbent core. Covering material 136 has a length somewhat longer than the length of the absorbent core and is wrapped around the absorbent core and barrier film as shown in FIG. 21. The longitudinal edges of the cover material are overlapped and sealed together on the- lower surface of the napkin in the usual manner. In die embodiment illustrated, the cover mnaterial is sealed to itself at die ends 138, 1 4 0 of the saniary napkin. As illustrated in FIG. 21, sanitary napkin 130 has a layer of adhesive 142 for adhering the napkin to the undergarment of the user. Adhesive 142 is protected prior to use by a removable release strip 144.

In one enmbodiment of the apertured film in accordance with the invention, the starting material is an embossed film supplied by Exxon Chemical under the designation EMVB-63 1, and having a thickness of 0.95 mils. This film is corona. discharge treated on its male side. The film is 25 placed on the forming member shown in FIGS. 8-10 which is mounted on a support drum as described in, U.S. Patent No. 5,567,376 (Turi et al.) with the corona-treated male side of the film facing the forming member. Two o manifolds for directing columnar streams of water at the film were used.

The first, or upstream, manifold has the -26orifice configuration shown in FIG. 7D of the drawings, ie, there are two offset rows 92, 94 of orifices 92', 94', each of the orifices having a diameter of 0.025 inches (0.64 mm). The orifices are spaced a distance of 0.038 inches (0.97 mm) center-to-center to provide a total of 52.6 holes per inch (20.7 holes per cm). The second, or downstream, manifold has the orifice configuration shown in FIG. 7A of the drawings, ie, there is a single row of orifices each having a diameter of 0.005 inches (0.127 mm). The orifices are spaced 0.020 inches (0.51 mm) on a center-to-center basis. There is a total of 50 such orifices per inch (19.7 such orifices per cm). Water having a temperature of 1650 F (740 C) is supplied at a pressure of 165 psig (1,140 kPa) to the first manifold, and at a pressure of 1,400 psig (9,650 kPa) to the second manifold. The film is passed under the manifolds at a speed of 435 feet per minute (2.22 metres per second). The suction pressure inside the drum is minus 50 inches (127 cm) of water. The film is dewatered with the apparatus shown in FIG. 4 and is dried with the apparatus shown in FIG. Following drying, the female side of the film is kiss-coated with a 48.8% solution of Tween-20 in water to a solution add-on of 0.25 mg/in 2 (0.039 mg/cm 2 Subsequent rolling of the film effects transfer of the surfactant solution from the female side to the corona-treated male side. After the surfactant solution ultimately dries, the film has a bulk surfactant add-on (including all surfaces of the film) of 0.12 mg/in 2 (0.019 mg/cm 2 The resulting apertured film has an air permeability of approximately 325 cubic feet per minute per square foot (cfm/ft) (1,650 litres per second per square metre) at a pressure differential (AP) of inches (1.25 mm) of water. The film has a measured open area of 6.24% and an average ECD of 10-11 mils (0.254-0.279 mm). ECD (Equivalent Circular Diameter) is calculated aperture diameter that is based on a measurement of the area of the aperture. The area is measured using the disclosed hardware and software for measuring EHD in U.S. Patent No. 5,567,376. The formula for ECD is ECD 4A where A is the measured area of an aperture.

30 There is an average of 500 apertures per square inch (78 apertures per square cm). The bulk thickness is 14.5 mils (0.37 mm).

27 The characteristics of the orifice strips used in the experiments described below are shown in Table 1: Table 1. Characteristics of Orifice Strips Orifice Orifice Number of Rows Intra-Row Spacing Number of Strip Size of Orifices Per Between Orifices Orifices Per Strip ID inches (mm) Orifice Strip center-to-center, Per Inch (cm) of inches (mm) Orifice Strip a 0.005 (0.127) 1 0.020 (0.508) 50 (20.0) b 0.010 (0.254) 2 0.015 (0.381) 133 (53.5) c 0.015 (0.381) 2 0.022 (0.559) 90.9 (36.4) d 0.020 (0.508) 2 0.032 (0.813) 62.5 e 0.025 (0.635) 2 0.038 (0.965) 52.6 (21) f 0.025 (0.635) 1 0.083 (2.108) 12 (13.2) Experimentation With Batch Formation of Films The batch film aperturing apparatus used in the experiments reported in Table 2 below was similar to that shown in FIG. 3 of the drawings. However, only one water manifold 42 was used, and only one of the available vacuum slots was used. Each of the orifice strips labelled through in Table 1 was in turn mounted in the single water jet manifold and used to make one or more apertured films as shown in Table 2. The starting film and forming member were the same as those used in Example 1.

A piece of starting film was mounted to the outer surface of the forming member by a series of pins projecting from the forming member. The honeycomb support drum was rotated so that the mounted film was out of line with the single orifice strip.

15 Vacuum was applied to the inside of the honeycomb support drum. Heated, pressurised water was supplied to the manifold. The honeycomb support drum motor was rotated to pass the starting film once under the orifice strip. The resultant film was removed a.

a a a b a a -28from the forming member and air dried. Process conditions used to make films and the resultant film properties are shown in Table 2 below.

Table 2. Batch Film Aperturing Experiments Mean Equivalent Water Film Hydraulic Pressure Water Vacuum* Speed Open Diameter Orifice psi Temp. in. water ft/min Area (EHD)** Ex.# ID (kPa) OF (cm water) (m/min) mils (mm) 1 b 350 (2411.5) 160 (71.2) 60(150) 150(45.7) 3.6 10.7 (0.271) 2 b 550 (3789.5) 160 (71.2) 60(150) 150(45.7) 6.5 10.3 (0.262) 3 b 1000 (6890) 160 (71.2) 60(150) 150(45.7) 8.5 7.7 (0.196) 4 c 200 (1378) 160 (71.2) 60(150) 150(45.7) 2.9 11.7(0.297) c 400 (2756) 160 (71.2) 60(150) 150(45.7) 8.7 16.3 (0.414) 6 c 550 (3789.5) 160 (71.2) 60(150) 150(45.7) 11.7 14.3 (0.363) 7 c 850 (5856.5) 160 (71.2) 60(150) 150 (45.7) 11.5 8.7 (0.221) 8 d 160(1102.4) 160 (71.2) 60(150) 150(45.7) 1.5 11.1 (0.282) 9 d 250 (1722.5) 160 (71.2) 60(150) 150(45.7) 8.1 17.1 (0.434) d 350 (2411.5) 160 (71.2) 60(150) 150(45.7) 9.4 14.7 (0.373) 11 d 550 (3789.5) 160 (71.2) 60(150) 150(45.7) 13.2 13.7 (0.348) 12 e 150 (1033.5) 160 (71.2) 60(150) 150(45.7) 2.0 10.1 (0.257) 13 e 240 (1653.6) 160 (71.2) 60(150) 150(45.7) 7.4 14.9 (0.378) 14 e 375 (2583.75) 160 (71.2) 60(150) 150(45.7) 12.8 17.2 (0.437) 14a f 150 (1033.5) 160 (71.2) 60(150) 150(45.7) 3.5 13.0 (0.330) 14b f 200 (1378) 160 (71.2) 60(150) 150(45.7) 5.7 12.8 (0.325) 14c f 250 (1722.5) 160 (71.2) 60 (150) 150(45.7) 6.0 11.5 (0.292) vacuum value is inches (cm) of water below atmospheric pressure.

Open Area and EHD were measured according to the method disclosed in U.S. Patent No. 5,567,376 which is incorporated herein by reference.

ECD

r r u 29 The data indicate the following trends: Increasing the fluid pressure with an orifice strip of a given size increases open area.

Increasing the orifice diameter increases open area at a given fluid pressure.

Due to stretch of material that occurs during the process of forming apertures, the weight per area of the film is reduced to about 0.47 oz/sq.yd (15.9 g/sq metre), which is of the initial film weight per unit area. When the 0.025 inch (0.64 mm) diameter orifice strips spaced at 0.038 inch (0.97 mm), 0.050 inch (1.27 mm), 0.062 inch (1.57 mm) and 0.075 inch (1.91 mm) of Table 8 were used, the open area decreased from 13.1% to 12.0, 11.2, and 10.1% respectively.

Experimentation with Continuous Formation of Film Additional embodiments of the film were made using the starting film, forming member and general procedure of Example 1. The characteristics of the strips are described in Table 1 above. All of the runs were made using water at 160" F (71.20 C), with the corona treated male side of the starting film facing away from the forming oooo member. The number of strips used, and their characteristics and operating conditions are shown in the following table: oooo.

Table 3. Continuous Film Aperturing Experiments Orifice Strip 1 Orifice Strip 2 Orifice Strip 3 Line Speed Orifice Pressure Orifice Pressure Orifice Pressure ft/min Ex.# Strip ID psi (kPa) Strip ID psi (kPa) Strip ID psi (kPa) (cm/min) d 150 (1033.5) 120 (3657) 16 d 150(1033.5) a 1000 (6890) 120 (3657) 17 d 150(1033.5) a 1000 (6890) a 1000(6890) 120 (3657) 18 a 1000(6890) 120(3657) 19 a 1000(6890) a 1000 (6890) 120(3657) a 875 (6028.75) a 875 (6028.75) a 875 (6028.75) 120(3657) 21 a 875 (6028.75) a 875 (6028.75) a 875 (6028.75) 150(4572) 22 a 1000(6890) d 150(1033.5) 120(3657) 23 a 1000(6890) d 150 (1033.5) a 1000 (6890) 120 (3657) Following air drying, the films were kiss-coated with an aqueous solution of Tween 20 surfactant at a concentration of 48.8% on the corona-treated male side to produce a bulk surfactant add-on of 0.12 mg/in 2 (0.019 mg/cm 2 of film as described hereinabove in connection with Example 1.

The apertured films produced in these experiments were evaluated for air permeability, aperture size, open area, strikethrough and bending length S(a measure of film stiffness). Tests were run according to the following methods S. 10 well known in the art. Air permeability was tested according to ASTM D737. Film aperture size and open area were determined and used to calculate Equivalent Circular Diameter (ECD). Strikethrough is the time required for 5 cc of a test fluid to be absorbed through the film supported on the ground fluff wood pulp. The test fluid is a mixture of 75% by weight of defibrinated bovine blood and 25% by weight of 0 15 a 10% by weight aqueous solution of polyvinylpyrrolidone (GAF Povidone K-90). Bending length in the machine direction (MD) and cross direction -31 (CD) were measured according to ASTM D1388. The properties of the film produced in continuous runs are shown in Tables 4-7 below.

Table 4. Continuous Apertured Film Properties Air Permeability Air Permeability CFM/SQFT 0.5 in. H 2 0 AP) Experiment 1.25 cm H 2 0 AP) 139.33 (707.93) 16 222.00 (1127.98) 17 246.67 (1253.33) 18 107.00 (543.66) 19 143.67 (729.98) 173.67 (882.41) 21 170.67 (867.17) 22 214.33 (1089.01) 23 212.67 (1080.57) The data in Table 4 show that the combination of large diameter and small diameter orifices (experiments 16, 17, 22 and 23) produces a more permeable, open film than films made with small diameter orifices alone (experiments 18-21). It is believed that the use of large diameter orifices, albeit used at lower water pressure, is the primary cause for the creation of large holes. Further, it is believed that the use of smaller diameter orifices is the primary cause for the creation of the smaller micro-holes.

-32- Table 5. Continuous Apertured Film Properties Aperture Size and Open Area Average Average ECD Standard No. Of Equivalent Circular Deviation Open Area Apertures/square Experiment Diameter (mm) mils (mm) inch (cm) Diameter mils (mm) 16.46 (0.418) 10.12 (0.257) 4.55 197 (77.56) 16 8.62 (0.219) 9.22 (0.234) 5.34 515 (202.76) 17 7.48 (0.189) 8.47 (0.215) 5.34 715 (281.50) 18 4.65 (0.118) 2.66 (0.068) 2.31 1125 (442.91) 19 4.53 (0.115) 2.65 (0.067) 2.48 1283 (505.12) 4.00 (0.102) 2.25 (0.057) 2.38 1635 (643.70) 21 4.16 (0.106) 2.48 (0.063) 2.53 1519 (598.03) 22 6.49 (0.165) 5.59 (0.142) 4.15 806 (317.32) 23 6.88 (0.175) 6.18 (0.157) 4.88 856 (337.00) The data in Table 5 show that the combination of large diameter and small diameter orifices (experiments 16, 17, 22, and 23) produce a film with larger aperture size and increased open area than films made with small diameter orifices alone 5 (experiments 18-21).

FIGS. 22, 23 and 24 are graphs that show the aperture size distribution of films produced in these experiments with a 5 mil (0.127 mm) diameter orifice strip (Experiment No. 20), a 20 mil (0.51 mm) diameter orifice strip (Experiment No. and the combination of a 20 mil (0.51 mm) orifice strip followed by a 5 mil (0.127 mm) orifice strip (Experiment No. 16), respectively (see Table 3 above).

As seen from these graphs, the apertured films produced with orifice strips of different diameters have aperture sizes that reflect the effects of various of the individual orifice diameters. The film (Experiment No. 20) produced with only a 5 mil (0.127 mm) orifice strip has apertures most of which have a diameter 0 00* 000* 0 :o: oo.

0 0 r r -33 under 10 mils (0.254 mm) (FIG. 22). The film (Experiment No. 15) produced by a mil (0.51 mm) orifice strip only has a broader distribution of aperture diameters, with peak concentrations at approximately 9 mils (0.006 mm) and at approximately 23 mils (0.58 mm) (FIG. 23). The film (Experiment No. 16) produced by a combination of a mil (0.127 mm) orifice strip and a 20 mil (0.51 mm) orifice strip has a distribution of aperture diameters that is primarily concentrated under 12 mils (0.31 mm), and has a slight concentration of holes with a diameter of around 23 mils (0.58 mm) (see FIG. 24).

These three graphs indicate that the 5 mil (0.127 mm) orifices create micro-holes primarily, that the 20 mil (0.51 mm) orifices create larger sized holes primarily, and that a combination of 5 mil (0.127 mm) orifices and 20 mil (0.51 mm) orifices creates a combination of micro-holes and large sized holes. Comparable data is shown in FIG. which shows aperture size distribution in a sample of apertured film having micro-holes and large-sized holes in accordance with the invention that was made on a commercial production line.

Table 6. Continuous Apertured Film Properties Strikethrough Time Experiment Strikethrough Time (sec) 16.3 16 17.6 17 13.5 18 28.8 19 25.6 20 20.2 21 22.9 22 15.8 23 17.10 S S The data in Table 6 show that either large diameter orifices alone, or the combination of large diameter and small diameter orifices -34- (experiments 15, 16, 17, 22 and 23) produce a film with faster strikethrough times than films made with small diameter orifices alone (experiments 18- 21).

Table 7. Continuous Apertured Film Proeries Film Stiffness Experiment MD Bending Length (mm) CD Bending Length (mm) 22.8 6 16 26.3 17 22.3 18 27 6.3 19 26.8 26 2 21 25.5 2 5 22 23.5 5.8 23 27.30 comparable commercial product 21.8 21.8 14.8 The data indicate that the MD bending length of the films of experiments 15-23 is comparable to those of other commercial sanitary napkin plastic covers, and that the CD bending length of the films is lower than comparable commercial films. Hence, stiffness and expected comfort of the films of the present invention are expected to be comparable or superior to that of other commercial apertured films.

Results of additional experimentation are shown in FIG. 26. In these experiments, the spacing of the orifices was varied to determine the effect on film open area. Two water jet manifolds were used in these experiments. The first, or upstream, manifold had one orifice strip with two rows of orifices on respective sides of the longitudinal center line of the strip, the two rows of orifices being offset as shown in FIGS. 7B-7D, ie, the offset distance was one-half the intra-row, center-to-center spacing of the orifices. All orifices had a diameter of 0.025 inch (0.64 mm). The center-to-center spacing of the orifices for each experiment was varied as reported in Table 8.

The second, or downstream, manifold had one orifice strip with a single row of orifices therein. The orifices each had a diameter of 0.005 inch (0.127 mm) and were spaced 0.020 inch (0.51 mm) on a center-to-center basis. Water was supplied to the first manifold at 150 psig (1,030 kPa). Water was supplied to the second manifold at 1,000 psig (6,890 kPa). The film travelled at 150 ft/min (4,572 cm/min). The drum vacuum was 60 inches (150 cm) water. The following Table 8 indicates the open area, number of apertures per in 2 (cm 2 ECD and air permeability for the resulting apertured films.

Table 8 Large Equivalent Orifice* Circular Film Spacing, inch Open Number of Diameter, Air Number (mm) Area, Apertures inch (mm) Permeability 24 0.038 (0.965) 13.1 914 (143) 0.0099 (0.251) 505 (2565.90) 0.050 (1.270) 12.0 1136(177) 0.0085 (0.216) 476(2418.55) 26 0.062 (1.575) 11.2 1151(180) 0.0081 (0.206) 465(2362.66) 27 0.075 (1.905) 10.1 1299 (203) 0.0072 (0.183) 435(2210.23) Two rows of 25 mil (0.64 mm) diameter orifices.

Air permeability was measured per ASTM D737; results are reported in Table 8 in cubic feet per minute per square foot (litres per second per square metre) of film. The air permeabilities of film apertured at 150 psig (1,030 kPa) and 150 ft/min (4,572 cm/min) were 310 cfm/sf (1,575 1/s/m 2 for the 25-mil (0.64 mm) diameter orifice strip (only) (0.038 inch (0.97 mm) spacing) control, which decreased nearly linearly to 245 cfm/sf (1,245 1/s/m 2 for the 0.075 inch (1.91 mm) spacing. When the 5-mil (0.127 mm) diameter orifice strip was added, the air permeability increased to 505 cfm/sf (2,565 1/s/m 2 for the control spacing. There was a nearly linear -36decrease with spacing to a value to 435 cfm/sf (2,210 1/s/m 2 at 0.075 inches (1.91 mm).

At 150 ft/min, (4,572 cm/min), the combination of the large diameter, 25 mil (0.64 mm) diameter control strip with the 5-mil (0.127 mm) strip provides about 195 cfm/sf (990 1/s/m 2 beyond the measured air permeability of the large hole strip alone. The above data indicates that as large orifice spacing increases, fewer large-sized holes are produced, and the open area is accordingly reduced.

Wettability of Non-Apertured Film with Surfactant Treatment The following Table 9 shows the results of testing Exxon EMB-631 with the male side having been corona discharge treated. The contact angle and surfactant distribution between the male and female sides, after roll-up, were tested. The contact angle was also measured on the male and female sides when there was no surfactant supplied to the film.

Table 9. Distilled Water Contact Angles and Surfactant Distribution of Processed Exxon EMB-631 Films EMB-631 With Male Corona Treatment No Surfactant Male Surfactant Female Surfactant Treatment Treatment Treatment Male Female Male Female Male Female Contact Angle aver. 72 102 0 78 0 76 std. dev. 6 7 0 11 0 3 Surfactant Distribution aver. 0.000 0.000 0.869 0.249 0.775 0.429 std. dev. 0.107 0.089 0.093 0.040 The above data indicates that corona discharge treatment reduces the contact angle of the film. The above data further indicates that the application of surfactant to either the corona treated or non-corona treated side, followed by a roll-up of the film 20 results in a distribution of surfactant wherein over 65% of the surfactant ends up on the corona treated side.

r r r r r r r r r -37.

Further, the data shows .that the application of surfactant lowers substantially the contact angle on the non-corona treated side, and lowers the contact angle on the corona treated side to zero. It is believed that the gradient in the contact angle, wherein the contact angle is substantially lower on the coronatreated side of the film, establishes a desirable hydrophilicity gradient" that facilitates z-direction flow through the film. Further, the lowering of the contact angle on both sides of the film is believed to substantially improve x and y direction flow along the top and bottom surfaces of the film. In a sanitary napkin in which the corona-treated side of the apertured film faces the absorbent core, improved spreading of fluids in the x and y direction is expected to enhance the z-direction flow of fluids to the absorbent core that is adjacent the lower surface of the film.

Top surface contact angle, bottom surface contact angle, film aperture pattern, and embossing pattern can be combined in various ways to yield the desired fluid distribution properties. Employing a cupped female emboss pattern on the body facing side of the film, a top surface film/air/synthetic menstrual fluid contact angle less than or equal to 70°, and a bottom contact angle less than or equal to 400, with bottom contact angle less than or equal to top contact angle in an apertured film having microholes and large-sized holes in accordance with the invention (and which has the surfactant applied to the top female side and the film is rolled up to S transfer surfactant to the male corona treated side), results in a film with limited fluid spreading in the non-apertured contiguous regions on the body facing side (see FIGS. 29 and 30), yet with a z-directional wettability differential or "hydrophilicity gradient", and excellent fluid wicking properties on the absorbent core side of the apertured film. These factors combine to deliver an absorbent article cover material that provides reduced leakage occurrence, and excellent fluid penetration and clean/dry properties.

-38- Th's cover maY be especially useful in cotumin with Odier intenal absorbent oniponerns designed to enhance horiMOnta] wicking.

The example discussed inmaely above oftse a fluid penetraio rate (as measured by 5cc synthetic nlerstru fluid times est raezlioc dscribed in' Patent N 5,567,376.-sirtmg which is improved .over non-sU14Ctantfte fiMs by approximatey 45 in either a pulp absorb= core consmrction or a peat moss based absorbent construction.

10 The following Table 10 contaim te results f a drop -test measuring the time needed for absorption of one drop of synthetic menstrual fluid. In Table 10, the Cover refers to aperlued film maMTr. All of the covers contain micro-holes andlarge-sized hOles. Covers 3 and 4 are made in accordance with thle Present invention,. but differ with respect to) tie surface on which surfacnt was initially applied. The test dezemines the time elapsed for the absorption of fluid, with a lower time being preferable and mndicatiig greater absorption, capacity.

Table 10. Effects Of COroMz Orientation, 20**a20 Dfnp_ Tes (sm) Cover On Put .25 udatm u~mded Moss Baned I CoronaPosidon Appikadft CIe (bon Care 30>6 3 39 As seen from the reduced absorption times for covers 3 and 4, the above data confirms the advantages of applying surfactant to the bottom, corona treated surface of an apertured film topsheet.

Claims (29)

1. A method for forming an apertured film from a stretchable thermoplastic polymeric material comprising: a) providing a starting film comprising said stretchable thermoplastic polymeric material and having a lower side that has been corona discharge treated and an upper side that has not been corona discharge treated; b) providing a backing member comprising localized support regions for supporting said starting film, recessed zones into which said starting film may be deformed by the application thereto of fluids, and means for allowing said fluid to be transported away from said backing member; c) supporting said starting film on said backing member with portions of the lower side of said starting film being in contact with the support regions of said backing member and with the upper side of said starting film facing away from said backing member; d) forming irregular size micro-holes and large sized holes in said starting film by directing a fluid in the form of columnar streams from at least a first set and a second set of orifices against the upper side of said starting film in a zone of contact, the orifices of the first set each having a diameter greater than ten mils (0.25 mm) and the fluid ***supplied thereto having a pressure less than 500 psig. (3,450 kPa) to cause said starting film to rupture into a multiplicity of said large sized holes in said starting film, the orifices of the second set each having a diameter less than or equal to ten mils (0.25 mm) and the fluid supplied thereto having a pressure of at least 500 psig. (3450 kPa) to cause the starting film to rupture into a multiplicity of said micro-holes in said starting film, whereby a combination of said large sized holes and said micro-holes are formed in said 25 starting film to define an apertured film having a lower side and an upper side; e) moving said apertured film from said contact zone; applying a liquid coating of a surface active agent from an exterior source to the upper side of said apertured film which has not been corona discharge treated; and g) winding said apertured film into a roll with said lower side being in surface contact with said upper side, whereby at least a portion of said surface active agent is r, transferred from the upper side of the apertured film to the lower side thereof. -41-

2. The method of claim 1 wherein said starting film is embossed to define a male side and a female side.

3. The method of claim 2 wherein the lower side of the starting film is the male side and the upper side of said starting film is the female side.

4. The method of claim 1 wherein said step of directing a fluid includes directing said fluid from said first set of orifices against said starting film before directing said fluid from said second set of orifices against said starting film.

The method of claim 1 wherein the step of coating said apertured film is performed by applying the surface active agent in a water-based solution.

6. The method of claim 1 wherein the surface active agent is uniformly applied to the upper side of the apertured film.

7. A method of forming an apertured film having improved fluid distribution properties and comprising the steps of: a) providing an embossed starting film having a corona discharge treated male side and a female side that has not been corona discharge treated; supporting said embossed starting film on a three-dimensional forming member with the corona discharge treated male side of said film facing said forming member; c) directing a fluid in the form of columnar jets against the female side of said starting film with a force sufficient to form apertures in said starting film to define an apertured film having male and female sides corresponding to said starting film male and female sides; d) drying said apertured film; applying a liquid surface active agent from an exterior source to said apertured film female side which has not been corona discharge treated; and f) winding said apertured film into a roll with said male side being in surface g i contact with said female side, whereby at least a portion of said surface active agent is transferred from the female side of the apertured film to the male side thereof. -42-

8. A method of forming an apertured film having improved fluid distribution properties and comprising the steps of: a) providing an embossed starting film having a male side and a female side; b) corona discharge treating the male side of said starting film but not the female side of said starting film; c) supporting said embossed starting film on a three-dimensional forming member with the corona discharge treated male side of said starting film facing said forming member and with the female side facing outwardly away from said forming member; d) directing a fluid in the form of columnar jets against the outwardly facing female side of said starting film with a force sufficient to form apertures in said starting film to define an apertured film having male and female sides corresponding to said starting film male and female sides; e) drying said apertured film; f) after step applying a liquid surface active agent from an exterior source onto the exposed surface of one of said apertured film male and female sides; and g) winding said apertured film into a roll.

9. The method of claim 8 wherein said surface active agent is applied directly on the male side of said apertured film.

10. The method of claim 8 wherein said winding step includes transferring at least a portion of said surface active agent to the other of said apertured film male and female sides of said apertured film.

11. The method of claim 8 wherein said surface active agent is applied by coating the female side of said apertured film. 25

12. The method of claim 11, including transferring at least a portion of said surface active agent to the male side of said apertured film when said apertured film is wound into said roll.

13. The method of claim 12 wherein more than 50% of the surface active agent is transferred to the male side of the apertured film. a C. C C CC 43

14. The method of claim 8 wherein said apertures include large sized holes.

The method of claim 8 wherein said surface active agent is applied to both of said apertured film male and female sides.

16. The method of claim 15 wherein greater than 50% of the applied surface active agent is distributed to said male side.

17. The method of claim 15 wherein greater than 75% of the applied surface active agent is distributed to said male side.

18. The method of claim 8 wherein said apertures include large sized holes and micro-holes.

19. The method of claim 8 wherein the step of coating said apertured film is performed by applying the surface active agent in a water-based solution.

The method of claim 8 wherein the surface active agent is uniformly applied to the corona discharge treated side of the apertured film.

21. A method for forming an apertured film from a stretchable thermoplastic 15 polymeric material comprising the steps of: a) providing a starting film comprising said stretchable thermoplastic polymeric material and having an upper side and a corona discharge treated lower side; b) providing a backing member comprising localized support regions for supporting said starting film, recessed zones into which said starting film may be deformed by application thereto of fluids, and means for allowing said fluids to be transported away from said backing member; .o c) supporting said starting film on said backing member with portions of the lower side of said starting film being in contact with the support regions of said backing member and with the upper side of said starting film facing away from said backing member; d) forming irregular size micro-holes and large sized holes in said starting film 3/ by directing a fluid in the form of columnar streams from at least a first set and a second t of orifices against the upper side of said starting film in a zone of contact, the orifices et of orifices against the upper side of said starting film in a zone of contact, the orifices -44- of the first set having a diameter greater than ten mils (0.25 mm) and the fluid supplied thereto having a pressure less than 500 psig. (3,450 kPa) to cause said starting film to rupture into a multiplicity of said large sized holes in said starting film, the orifices of the second set having a diameter less than or equal to ten mils (0.25 mm) and the fluid supplied thereto having a pressure of at least 500 psig. (3,450 kPa) to cause the starting film to rupture into a multiplicity of said micro-holes in said starting film, whereby a combination of large sized holes and micro-holes are formed in said starting film to define an apertured film having lower and upper sides corresponding to said starting film lower and upper sides; e) moving said apertured film from said contact zone and drying said apertured film; and f) after step applying a liquid coating of a surface active agent from an exterior source onto the exposed surfaces of both of said apertured film upper and lower sides.

22. The method according to claim 21 wherein said step of applying a liquid coating of a surface active agent onto the exposed surfaces of both of said apertured film upper and lower sides comprises applying said coating of said surface active agent to one eoeo of the upper and lower sides of said apertured film to form an apertured film having a surface active agent coated side and an uncoated side, and winding said apertured film having said surface active agent coated side and said uncoated side into a roll with said surface active agent coated side being in surface-to-surface contact with said uncoated side, whereby at least a portion of said coating of said surface active agent is transferred from said surface active agent coated side to said uncoated side.

23. A method according to claim 22 wherein the corona discharge treated lower side is said surface active agent coated side.

~24. A method according to claim 22 wherein the upper side of said apertured film is said surface active agent coated side.

A method according to claim 21 wherein said starting film is embossed to Sdefine a male side and a female side.

26. The method of claim 21 wherein the step of coating said apertured film is performed by applying the surface active agent in a water-based solution.

27. The method of claim 21 wherein the surface active agent is uniformly applied to the corona discharge treated lower side of the apertured film.

28. A method for forming an apertured film from a stretchable thermoplastic polymeric material, substantially as hereinbefore described with reference to any one or more of the examples but excluding comparative examples.

29. A method of forming an apertured film having improved fluid distribution properties, substantially as hereinbefore described with reference to any one or more of the examples but excluding comparative examples. DATED 23rd day of May 2002 JOHNSON JOHNSON RESEARCH PTY LIMITED Attorney: JACINTA FLATTERY-O'BRIEN Registered Patent Attorney of The Institute of Patent and Trade mark Attorneys of Australia of BALDWIN SHELSTON 9 9* 9 4 9. 9