AU734974B2 - Fluidized bed roasting process - Google Patents

Description

Our Ref: 744440 P/00/011 Regulation 3:2

AUSTRALIA

Patents Act 1990

ORIGINAL

COMPLETE SPECIFICATION STANDARD PATENT to Applicant(s): Address for Service: Invention Title: Cominco Ltd Suite 500 200 Burrard Street Vancouver British Columbia V6C 3L7

CANADA

DAVIES COLLISON CAVE Patent Trade Mark Attorneys Level 10, 10 Barrack Street SYDNEY NSW 2000 Fluidized bed roasting process The following statement is a full description of this invention, including the best method of performing it known to me:- 5020 1 'FLUIDIZED BED ROASTING PROCESS FIELD OF THE INVENTION This invention relates to a fluidized bed roasting process for metal sulphide concentrates, such as zinc sulphide concentrate, or a blend of such concentrates, and in particular, a method of stabilizing the roaster bed and reducing carryover by inducing and controlling the size distribution of the bed.

BACKGROUND OF THE INVENTION Even though certain commercially available roasters, such as the Lurgi T fluidized bed roasters, are designed to handle a high solids loading in the gas stream, the fineness of some concentrates has been 20 identified as a significant contributor to low on-line operating times, and the resulting decrease in zinc S'.production. Fine materials have a higher tendency to leave the roaster bed with the fluidizing combustion gases, and as a consequence, a greater percentage of the 25 concentrate will react in the roaster freeboard. This increases the boiler inlet temperature and results in the formation of sticky calcine which can foul the boiler tubes and cyclones. The fine-sized solids in the gas stream are also carried further along the gas handling system. Though these solids are finally removed at the electrostatic precipitators and scrubbers, the higher solids loading increases the maintenance frequency and the workload on these units.

Improving the fluidising properties of a fluidized bed roaster has been attempted. For example, EP-A-274187 describes a process for improving fluidizing properties of materials 2 in the bed of a fluidized-bed roaster by increasing the proportion of material of an intermediate size range in the feed to the bed.

In the extractive metallurgical industry, pelletization of concentrate is known. The iron ore industry has pelletized taconite-type iron ore feeding the blast furnaces since the 1950's. The problem, however, is whether pellets made with fine metal sulphide concentrates, such as zinc sulphide concentrate, can be made strong enough to withstand handling and roasting in a fluidized bed roaster.

S0". SUMMARY OF THE INVENTION According to the invention there is provided a method of stabilizing a fluidized bed in a fluidized bed roasting process for metal sulphide concentrate, comprising the step of controlling the particle size 20 distribution of the particulate material in the bed so that a minimum amount of no less than about 30% of the material falls in a size range of from about.100 to about 420 pm(micrometers). The minimum amount is preferably no less than about 35%. Preferably, the minimum amount falls within the range of from about 35% to about The controlling of the particle size distribution may comprise maintaining an amount of agglomerating agent in a concentrate feed to the bed to produce said particle size distribution in the bed. The agglomerating agent may comprise a metal sulphide, such as PbS, FeS, or FeS, which is present in the concentrate.

The controlling of the particle size distribution may also comprise maintaining an amount of lead in the concentrate in a range of from about 3% to 3 about 4% by weight of the concentrate. The amount of lead is preferably from about 3.7% to about 3.8% by weight of the concentrate.

The controlling of the particle size distribution may also comprise feeding concentrate to the bed which has been subjected to pelletization to increase the particle size thereof. The controlling of the particle size distribution may comprise either controlling the lead content of the concentrate or using a pelletized feed, or both of these methods in combination.

Also according to the invention there is provided a pelletization process comprising the steps of mixing a predetermined amount of a fine metal sulphide concentrate with a predetermined amount of a liquid binder to achieve a resulting mixture with a moisture content of less than 11.5% by weight, wherein said mixing is effected in a batch-wise fashion for a predetermined period of time with a high shear mixer and wherein the moisture content of the resultant mixture is adjusted to produce pellets within a size range of from about 100 gm to about 3300 pm during said mixing. The moisture content is preferably adjusted to produce pellets, a proportion of which falls within a size range of from about 100 pm to about 1000 pm, and preferably, from about 100 pm to about 420 pam.

In this specification, a high shear mixer, refers to a mixer which provides intensive mixing action and homogenization of the feed materials. This would generally be achieved by specific mixer design characteristics that could include proprietary geometrical parameters, deflectors, rotors, high speed motors and the like. Applicant has found that the

II

4 commercially available Eirich" Type R Intensive Mixer is one such suitable device.

The liquid binder may comprise water or an aqueous sulphate solution. Preferably, the liquid binder comprises a zinc sulphate solution.

The process may further comprise the step of mixing a solid binder with the metal sulphate concentrate and the liquid binder.

In one embodiment of the invention the amount of solid binder is from 0.5% to about preferably from about 1% to about by weight of the amount of concentrate. In another embodiment, the amount of solid binder is no more than about 1% by weight of the amount of concentrate.

The solid binder may comprise a material which is internal to a fluidized bed roasting process, such as effluent treatment plant (ETP) residue or cyclone/electrostatic precipitator (ESP) catch.

:Further advantages which the invention seeks to provide will become apparent 25 from the description of a preferred embodiment of the invention below.

BRIEF DESCRIPTION OF DRAWINGS 0: 30 Figure 1 is a graph of availability and rates of a roaster operating over a 12 month period under unstable conditions.

:Figure 2 is a graph of the same paramaters in respect of two roasters operating over a 6 month period during which the lead content was controlled according to the method of the invention.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENT In carrying out the roasting process according to the invention, a Lurgi m turbulent bed roaster, with a bed area of 84m was used. This type of roaster is well known in the industry, particularly with respect to the roasting of zinc concentrates. Accordingly, the roaster will not be described in any further detail herein.

For the sake of comparison, typical operating conditions that exist with an unstable fluidized bed, 15 using a fine zinc sulphide concentrate, are as follows: Fluidized bed Fine Intermediate Coarse Very Coarse size distribution: (<105 Pm) (105-420 fm) (420-1100 Pm) (>1100 Pm) 5-15% Bed Overflow Dust Load to ESP Boiler Outlet Temperature Windbox pressure 5-15% of calcine produced 4-6% of calcine produced (12-18gms/m) 450-500 deg.C (fouling) 2100-2200 mmHO In carrying out the method according to one aspect of the invention, using a fine zinc sulphide concentrate, feed to the roaster is assayed and controlled so that the lead content thereof is maintained at about 3.7 to 3.8% of Pb by weight of the concentrate.

However, a broader range of from about 3% up to a maximum of 4% can be tolerated. From the known assays of 6 concentrate, the make up of the feed to the bed can be controlled, e.g. by a combination or blending of different concentrates, to produce a resulting feed to the bed containing the desired amount of agglomerating agent.

Any shortfall of lead in the zinc concentrate making up the roaster mix can be supplemented with the addition of lead concentrate, if necessary.

This feed strategy has resulted in less day-today variation of the intermediate size fraction in the feed and much more stable roaster operation. With this method, there has been a marked improvement in roaster 15 rate and availability as illustrated by Figures 1 and 2, respectively.

Roaster "availability" refers to the time the roaster is operated expressed as a percentage of the time 20 that the roaster is available for operation. The term "rate" refers to the feed rate of material to the roaster, expressed as metric tonnes per hour.

The results obtained are as follows: Fluidized bed size distribution: Fine (<105 pm) 15-25% Intermediate (105-420 pm) Coarse (420-1100 pm) Very Coarse (>1100 pm) 15-30% Bed Overflow 25-35% of calcine produced Dust Load to ESP 2-3% of calcine produced (4-8gms/m 3 7 Boiler Outlet Temperature <425 deg.C (significantly less fouling) Windbox pressure 2500-2800 mmH 2

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It can be seen that no less than 30% of the roaster bed material falls in a size range of from 100 to 420 pm, compared with 5 to 15% under unstable conditions.

The bed overflow is increased to 25 to 35% of calcine produced, compared with 5 to 15% under unstable conditions. In addition the dust load to the electrostatic precipitator is reduced and the boiler outlet temperature has also dropped significantly. The .owindbox pressure has increased to 2500 to 2800 nmH 2 O from 15 2100 to 2200 0mmO.

A pelletization process according to the invention will now be described by way of an example.

20 An accurately weighed amount, e.g. by way of a weigh feeder, of fine zinc sulphide concentrate, or a blend of two or more different zinc sulphide concentrates, is accumulated in a holding bin. In the present example, the amount is 3800 kg. The 3800 kg batch is then fed, over a 30 second period to a constantly mixing Eirich' mixer.

Binder material in the form of cyclone/ESP catch, in the present example, at typically 1-2% by weight of the concentrate, is also fed to the Eirich T M mixer simultaneously with the concentrates, over the second period.

Liquid phase, typically an aqueous zinc sulphate solution, is fed to the mixer after the solid materials have been added to the mixer. Sufficient 8 liquid phase is added to produce a moisture content of about 11% for the concentrate being used. For example, the concentrate used in this example already contained some moisture.

The material is continuously mixed in batch mode for a total time of about 5 minutes, measured from the start of the addition of the concentrate to the mixer. The material is then discharged and a new mixing cycle is commenced. The process is carried out at ambient temperature and no heating is required.

The process produces pellets with a size range from about 200-3300 pm, with an average size of about 15 1500 pm.' With a lower moisture content, particulates with sizes down to 100 Cm can be produced. The moisture content determines the size distribution of the agglomerates. Thus, the particle size distribution can be controlled by adjusting the moisture content.

20 However, a moisture content of more than about 11.5% is to be avoided since above this value undesirable globs are formed.

A variety of materials can be used as binders.

A sulphate containing solution, e.g. a solution which is internal to the zinc production process, such as clarifier overflow (COF) or neutral feed (NF) both of which contain zinc sulphate, when used alone as a binder, i.e. without the addition of a solid binder, was more effective than water used alone as a binder. Such solutions typically contain about 150 g/l zinc as zinc sulphate. An essentially neutral solution (pH 5.0) of 150 g/l zinc sulphate is preferred but other suitable solutions can be used.

-9- It has been found that solid binders and a sulphate solution result in better performance than just a sulphate containing solution alone. The addition of a solid binder provides for a higher capacity for liquid phase binder addition, and as a result, yields higher strength pellets. Preferably a sulphate containing material is selected.

For economic reasons, desirable solid binders are selected from materials which are internal to the zinc production process. The following have been found to be useful: Effluent treatment plant (ETP) residue.

15 Usefulness as a binder has been demonstrated and, as such, it can be satisfactorily recycled to the roasters (carry-over to the gas stream is minimized). The material is an endothermic load in roasting, thereby providing roaster bed 20 cooling.

Cyclone/ESP catch. This material has been found to be particularly useful as a binder.

-Roaster calcine. This roaster product material has also been found to be useful.

Bentonite. This has been found satisfactory, but is not desirable, as it introduces superfluous material. Testwork has indicated that bentonite can generally be eliminated in the present process.

Quicklime. This material has also been found to be satisfactory, but, again is not 10 desirable, as it introduces superfluous material.

The amount of solid binder used is typically from about 0.5% to about 3.0% by weight of the concentrate. Preferably, the amount ranges from 0 to about based on the desire to minimize solids handling and recycle, but if ETP residue is used, it is desirable to recycle larger quantities. Table 1 gives some examples: Table 1. Ranking of Binding Agents in order of effectiveness 15 Ranking Pellet Type 1 1% bentonite, 1% ESP, COF 2 3% ZnSO 4

COP

3 1% bentonite, 2% ESP, NF 20 4 1% lime, 1% calcine, COF 5 1% "Red Dog" sludge, 1% bentonite, COF 6 0.5% bentonite, 1% calcine, COF 7 0.1% bentonite, 1% calcine, COF 8 1% bentonite, 1% calcine, COF 9 1% ETP sludge, COF In the above table, "Red Dog" sludge refers to sludge from applicant's Red Dog mine in Alaska.

The typical cyclone/ESP catch which is suitable for use as a solid binder is a variable blend of dusts captured from the fluidized bed roaster off-gas. The dusts are collected in cyclones and electrostatic precipitators. An approximate analysis is shown in Table 2.

11 Table 2. Analysis of Cyclone/ESP catch SO,/S Zn ESP 3.8 6.6 48 Cyclone 2.4 3.8 52 58 It is believed that the sulphate content assists the binding process and that material higher in sulphate content, such as ESP catch, is beneficial.

The retention time in the batch pelletization 15 process may be from about 1 to 30 minutes, preferably to 10 minutes and, typically, a retention time of at least 5 minutes is preferred.

It has been found that the pelletized material 20 can be stored for an indefinite period before roasting.

Storage temperatures can vary. The storage temperature can be below freezing point. It has also been found that pellet compressive strength does not change with the number of freeze/thaw cycles.

In carrying out the method according to another aspect of the invention, pelletized concentrate is included in the feed to the roaster to maintain the desired particle size distribution of particulate material in the bed. While this method can be used as an alternative to controlling the amount of agglomerating agent in the concentrate, it can also be carried out in conjunction with control of the agglomerating agent, depending on the type of concentrate used.

1, ,I 12 While only preferred embodiments of the invention have been described herein in detail, the invention is not limited thereby and modifications can be made within the scope of the attached claims.

Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.

The reference to any prior art in this specification is not, and should not be taken as, an acknowledgement or any form of suggestion that that prior art forms part of the common general knowledge in Australia.

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Claims (12)

1. A pelletization process including the steps of mixing a predetermined amount of a fine metal sulphide concentrate with a predetermined amount of a liquid binder to achieve a resulting mixture with a moisture content of less than 11.5% by weight, wherein said mixing is effected in a batch-wise fashion for a time period of between 1 to 30 minutes with a high shear mixer and wherein the moisture content of the resultant mixture is adjusted with said liquid binder to produce pellets within a size range of from 100 pim to 3300 rpm during said mixing.

2. The process according to claim 1, further including the step of mixing a solid binder with said metal sulphide concentrate and said liquid binder.

3. The process according to claim 2, wherein the amount of said solid binder is from 0.5% to 3% by weight of the amount of concentrate.

4. The process according to claim 3, wherein the amount of said solid binder is from 18 to 2% by weight of the amount of concentrate. 20 °O o oo°« o° oo* o The process according to claim 2, wherein the amount of solid binder is no more than 1% by weight of the amount of concentrate.

6. The process according to claim 2, wherein the solid binder includes effluent treatment plant residue. a

7. catch. The process according to claim 2, wherein the solid binder includes cyclone/ESP

8. The process according to claim 2, wherein said solid binder includes calcine.

9. The process according to claim 2, wherein said solid binder includes a sulphate P:\WPDOCS\AMD\SPECI\744440.COM 30/8/99 14 The process according to claim 1, wherein said predetermined period of time is from 1 to 30 minutes.

11. The process according to claim 10, wherein said predetermined period of time is from 5 to 10 minutes.

12. The process according to claim 1, wherein the moisture content is adjusted to produce pellets a proportion of which is within a size range of from 100 Am to 1000 Am.

13. The process according to claim 12, wherein the moisture content is adjusted to produce pellets a proportion of which is within a size range of from 100 Am to 420 m.

14. A pelletisation process, substantially as herein described. 15 DATED this 30th day of August, 1999 COMINCO LTD By Their Patent Attorneys DAVIES COLLISON CAVE S S S S. S S S S S. 5 *5 .5.5 S S