AU7275791A - Method of preparing an alkylated aromatic product with an alkylation zeolite and a dealkylation zeolite - Google Patents

Method of preparing an alkylated aromatic product with an alkylation zeolite and a dealkylation zeolite

Info

Publication number
AU7275791A
AU7275791A AU72757/91A AU7275791A AU7275791A AU 7275791 A AU7275791 A AU 7275791A AU 72757/91 A AU72757/91 A AU 72757/91A AU 7275791 A AU7275791 A AU 7275791A AU 7275791 A AU7275791 A AU 7275791A
Authority
AU
Australia
Prior art keywords
zeolite
alkylation
alkylated aromatic
dealkylation
preparing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU72757/91A
Other versions
AU634033B2 (en
Inventor
Annie Finiels
Patrick Geneste
Patrice Moreau
Jonis Solofo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Michelin Recherche et Technique SA France
Original Assignee
Michelin Recherche et Technique SA Switzerland
Michelin Recherche et Technique SA France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michelin Recherche et Technique SA Switzerland, Michelin Recherche et Technique SA France filed Critical Michelin Recherche et Technique SA Switzerland
Publication of AU7275791A publication Critical patent/AU7275791A/en
Application granted granted Critical
Publication of AU634033B2 publication Critical patent/AU634033B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/47Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing ten carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Process for preparing an alkylated aromatic product (12) by alkylation of an aromatic compound (1), the alkylation giving a number of alkylated aromatic products, this process being characterised by the following points:   a) the aromatic compound (1) is reacted with an alkylating agent (2) in the presence of an alkylation zeolite (4);   b) the alkylated aromatic product (12) is separated from the alkylation products by crystallisation;   c) the uncrystallised part (13) of the alkylated aromatic products is subjected to a dealkylation in the presence of a dealkylation zeolite (15);   d) the regenerated aromatic compound (1b) is recycled to make it react again with the alkylating agent (2) in the presence of the alkylation zeolite (4). Alkylated aromatic compounds (12) obtained by this process, especially 2,6-dicyclohexylnaphthalene. <IMAGE>
AU72757/91A 1990-03-13 1991-03-11 Method of preparing an alkylated aromatic product with an alkylation zeolite and a dealkylation zeolite Ceased AU634033B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9003309A FR2659648B1 (en) 1990-03-13 1990-03-13 PROCESS FOR PREPARING AN ALKYLATED AROMATIC PRODUCT WITH AN ALKYLATION ZEOLITE AND A DEALKYLATION ZEOLITE.
FR9003309 1990-03-13

Publications (2)

Publication Number Publication Date
AU7275791A true AU7275791A (en) 1991-09-19
AU634033B2 AU634033B2 (en) 1993-02-11

Family

ID=9394760

Family Applications (1)

Application Number Title Priority Date Filing Date
AU72757/91A Ceased AU634033B2 (en) 1990-03-13 1991-03-11 Method of preparing an alkylated aromatic product with an alkylation zeolite and a dealkylation zeolite

Country Status (13)

Country Link
US (1) US5210350A (en)
EP (1) EP0446758B1 (en)
JP (1) JP3140077B2 (en)
KR (1) KR100223128B1 (en)
CN (1) CN1028513C (en)
AT (1) ATE115531T1 (en)
AU (1) AU634033B2 (en)
BR (1) BR9100975A (en)
CA (1) CA2038196C (en)
DE (1) DE69105785T2 (en)
ES (1) ES2065563T3 (en)
FR (1) FR2659648B1 (en)
RU (1) RU2056398C1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU631673B2 (en) * 1989-07-26 1992-12-03 Michelin Recherche Et Technique S.A. Selectively cycloalkylating naphtalene on zeolites

Families Citing this family (18)

* Cited by examiner, † Cited by third party
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US20030129724A1 (en) 2000-03-03 2003-07-10 Grozinger Christina M. Class II human histone deacetylases, and uses related thereto
US6436882B1 (en) 2001-06-29 2002-08-20 King Industries, Inc. Functional fluids
GB0504079D0 (en) * 2005-02-28 2005-04-06 Davy Process Techn Ltd Process
SG171690A1 (en) 2005-03-22 2011-06-29 Harvard College Treatment of protein degradation disorders
KR101068374B1 (en) * 2005-04-27 2011-09-28 엘지전자 주식회사 Cleanser tank of vacuum cleaner for wet and dry cleaning
WO2008091349A1 (en) * 2006-02-14 2008-07-31 The President And Fellows Of Harvard College Bifunctional histone deacetylase inhibitors
CN101910094B (en) * 2007-12-12 2013-09-18 国际壳牌研究有限公司 Process for the conversion of ethane or mixed lower alkanes to aromatic hydrocarbons
MY156207A (en) 2008-02-18 2016-01-29 Shell Int Research Process for the conversion of ethane to aromatic hydrocarbons
US8809608B2 (en) * 2008-02-18 2014-08-19 Shell Oil Company Process for the conversion of lower alkanes to aromatic hydrocarbons
UA98537C2 (en) * 2008-02-18 2012-05-25 Шелл Интернационале Рисерч Маатшаппидж Б.В. Process for producing aromatic hydrocarbons
AU2009215655B2 (en) 2008-02-20 2012-03-15 Shell Internationale Research Maatschappij B.V. Process for the conversion of ethane to aromatic hydrocarbons
KR101708946B1 (en) 2008-07-23 2017-02-21 다나-파버 캔서 인스티튜트 인크. Deacetylase inhibitors and uses thereof
WO2011019393A2 (en) 2009-08-11 2011-02-17 President And Fellows Of Harvard College Class- and isoform-specific hdac inhibitors and uses thereof
EA022457B1 (en) 2009-11-02 2016-01-29 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Process for the conversion of mixed lower alkanes to aromatic hydrocarbons
WO2011143306A2 (en) 2010-05-12 2011-11-17 Shell Oil Company Process for the conversion of lower alkanes to aromatic hydrocarbons
RU2544017C1 (en) * 2014-01-28 2015-03-10 Ольга Васильевна Малова Catalyst and method for aromatisation of c3-c4 gases, light hydrocarbon fractions of aliphatic alcohols, as well as mixtures thereof
RU2016133191A (en) * 2014-02-07 2018-03-13 Сауди Бейсик Индастриз Корпорейшн REMOVAL OF AROMATIC IMPURITIES FROM ALKEN FLOW USING ACID CATALYST
CN105980529A (en) 2014-02-07 2016-09-28 沙特基础工业公司 Removal of aromatic impurities from an alkene stream using an acid catalyst, such as an acidic ionic liquid

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3251897A (en) * 1962-12-20 1966-05-17 Socony Mobil Oil Co Inc Alkylation of aromatic compounds in the presence of an alumino-silicate catalyst
US3716596A (en) * 1968-04-18 1973-02-13 Mobil Oil Corp Alkylation and dealkylation of aromatics in the presence of crystalline aluminosilicates
US4230894A (en) * 1978-12-14 1980-10-28 Mobil Oil Corporation Method for producing 3-alkylphenols and 1,3-hydroxybenzene
US4560820A (en) * 1981-04-13 1985-12-24 Chevron Research Company Alkylaromatic dealkylation
US4570027A (en) * 1984-04-27 1986-02-11 Exxon Research And Engineering Co. Alkylation of aromatic molecules using a silica-alumina catalyst derived from zeolite
JPS6147425A (en) * 1984-08-10 1986-03-07 Sumitomo Chem Co Ltd Method of dealkylation selectively in para-position
FR2650273B1 (en) * 1989-07-26 1992-12-24 Michelin Rech Tech CYCLOALKYLATION OF AROMATIC COMPOUNDS ON ZEOLITHS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU631673B2 (en) * 1989-07-26 1992-12-03 Michelin Recherche Et Technique S.A. Selectively cycloalkylating naphtalene on zeolites

Also Published As

Publication number Publication date
KR910016651A (en) 1991-11-05
AU634033B2 (en) 1993-02-11
JP3140077B2 (en) 2001-03-05
FR2659648B1 (en) 1993-02-12
RU2056398C1 (en) 1996-03-20
US5210350A (en) 1993-05-11
CA2038196C (en) 2002-05-14
CN1028513C (en) 1995-05-24
JPH04217929A (en) 1992-08-07
CN1054763A (en) 1991-09-25
EP0446758A1 (en) 1991-09-18
DE69105785T2 (en) 1995-04-27
FR2659648A1 (en) 1991-09-20
EP0446758B1 (en) 1994-12-14
BR9100975A (en) 1991-11-05
KR100223128B1 (en) 1999-10-15
CA2038196A1 (en) 1991-09-14
ES2065563T3 (en) 1995-02-16
DE69105785D1 (en) 1995-01-26
ATE115531T1 (en) 1994-12-15

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