AU716909B2 - Plant and process for producing pig iron and/or sponge iron - Google Patents

Description

lot I f,

AUSTRALIA

Patents Act 1990 COMPLETE SPECIFICATION STANDARD PATENT Applicant VOEST-ALPINE INDUSTRIEANLAGENBAU GmbH A.R.B.N. 052 122 791 Invention Title: PLANT AND PROCESS FOR PRODUCING PIG IRON AND/OR SPONGE IRON cc The following statement is a full description of this invention, including the best method of performing it known to me/us: A Plant and process for the production of pig iron and/or sponge iron.

This specification is a divisional specification of Australian Patent Application No. 35971/95.

The invention relates to a plant for the production of pig iron and/or sponge iron, comprising at least one fluidized bed reactor intended to receive fine ore, a reducing-gas feed duct leading to said fluidized bed reactor, an offgas discharge duct departing from the fluidized bed reactor and a discharge means, preferably a briquetting means, provided for the reduction product formed in the fluidized bed reactor, wherein the offgas 15 discharge duct of the fluidized bed reactor runs into a purification means, such as a scrubber, subsequently into a heating means and finally into the reducing-gas feed duct of the fluidized bed. The invention further relates to a process for producing pig iron and/or sponge iron using this plant.

The processing of fine ore to sponge iron in a S* fluidized bed reactor, in principle, is known from US-A 5,082,251. There, the reducing gas is produced by catalytic reformation of desulphurized and preheated 25 natural gas with overheated water vapor in a reformer furnace. That process allows for the production of highquality sponge iron from fine ore.

The invention is based on the object to improve a plant of the type initially described in such a manner that the product produced, pig iron and/or sponge iron, complies with a high quality standard at a minimum energy input, in particular exhibits a high degree of metallization and purity, such that further processing will be ensured without any problems.

In a plant of the initially described kind, this object is achieved in that the heating means is constructed such that it comprises two stages and that there are 1B provided a heat exchanger as the heating means for the reducing gas and, connected serially therewith, a partial combustion means for the reducing gas with an oxygen feeding means.

Advantageously, a CO 2 removal means is provided in the reducing-gas feed duct of the fluidized bed reactor, for lowering the CO a content of the offgas formed in the fluidized bed reactor.

The process of the invention for producing pig iron and/or sponge iron is characterized in that fine ore Sis reduced to sponge iron with a reducing gas in a fluidized-bed reduction zone according to the fluidized bed method, wherein a purified offgas forming in the fluidizedbed direct reduction zone is supplied to the fluidized-bed S 15 direct reduction zone as a supplement to freshly supplied reducing gas, and that such offgas supplied to the fluidized-bed direct reduction zone is heated in two stages, preferably together with freshly supplied reducing gas, namely in a first stage through heat exchange and in a 20 second stage through partial *o \\melbl\home$\MCooper\Keep\Speci\P35971.95.1.DOC 1/03/99 combustion by means of oxygen which is fed into at least a partial quantity of the reducing gas.

In order to lower the CO 2 content of the reducing gas supplied to the fluidized bed direct reduction zone to the desired measure, the offgas from the fluidized-bed direct reduction zone suitably is subjected to CO 2 removal.

Advantageously, the freshly supplied reducing gas is fed to the fluidized-bed direct reduction zone while bypassing the CO 2 removal means for the offgas from the fluidized-bed direct reduction zone.

S. Direct reduction in the fluidized bed process may be effected in two or several stages, as is 0* known, for instance, from US-A 5,082,251. Further, it is possible to carry out direct reduction by aid of a circulating fluidized bed, known, for instance, from EP-B 0 364 865.

In the following, the invention will be explained in more detail by way of an exemplary embodiment schematically illustrated in the drawing, wherein the Figure represented in the drawing illustrates the process scheme of a plant according to the invention.

The plant comprises two fluidized bed reactors 1, 2 consecutively connected in series, fine ore being conducted via a fine-ore supply duct 3 to the first fluidized bed reactor 1 and from there S via a conveying duct 4 to the consecutively connected fluidized bed reactor 2. The material completely reduced in one fluidized-bed direct reduction zone 5 each of the fluidized bed reactors 1, 2 (sponge iron), upon emergence from the second fluidized bed reactor 2, is S: supplied to a briquetting plant 6 where it is hot- or cold-briquetted. Prior to introducing the fine ore into the first fluidized bed reactor 1, it is subjected to an ore preparation, such as drying, which, however, is not illustrated in detail.

Reducing gas is conducted through a gas duct 7 in counterflow to the ore flow, from the fluidized bed reactor 2 to the fluidized bed reactor 1, to the fluidized-bed direct reduction zones 5 provided in the fluidized bed reactors 1 and 2 and is carried off the first fluidized bed reactor 1 viewed in the ore flow direction as an offgas through an offgas discharge duct 8.

The offgas drawn off the fluidized bed reactor 1 is cooled and scrubbed in a purification means 9 preferably designed as a wet scrubber and subsequently is mixed with the freshly supplied reducing gas by running together with a reducing-gas feed duct 10 supplying fresh reducing gas and the offgas discharge duct 8. The mixed gas thus formed is passed through a

CO

2 removal means 11, preferably designed as a CO 2 scrubber, and is freed from CO 2 After this, heating of the mixed gas to a temperature of about 400°C is effected in two stages in a heat exchanger 12. Following upon the same, there is an afterburning means 13, in which part of the mixed gas is burnt under oxygen supply, the mixed gas thus attaining the temperature required for the direct reduction in the fluidized bed reactors 1, 2 of up to about 850°C. This heated mixed gas then is available to the fluidized bed reactors 1, 2 as a reducing gas.

According to a preferred embodiment, only the offgas of the fluidized bed reactors 1, 2 is subjected to CO 2 scrubbing and the reducing gas freshly supplied via a duct 14 is mixed with the offgas only after CO 2 scrubbing of the same.

The briquetted sponge iron is processed in a compact steel works, for instance equipped with electric furnaces and converters. If necessary, briquetted sponge iron also may be charged into a melter gasifier through a conveying means and melted there. This is advantageous, in particular, if excess energy is available in a melter gasifier.

Advantageously, the heat exchanger 12 is operated with part of the offgas from the fluidized bed reduction, which is fed through a duct 15. Offgas that is not required for the reduction process or the heat exchanger 12 is supplied to other consumers through an export-gas discharge duct 16. The discharge duct 16 advantageously run into a gas collection tank, such as a gasometer, for the intermediate storage of the export gas. Thus, differences in gas production and deviations in pressure within the system may be checked and balanced out in an advantageous manner.

The briquetting plant 6 may be replaced with a discharge means 17, such as, a cold discharge means.

All of the conveying means and gas ducts are equipped with control organs or compressors, respectively, in a usual manner.

Example: The fine ore charged into the fluidized bed reactor 1 is comprised of ore having a maximum grain size of 8 mm. It is reduced to sponge iron in two stages and subsequently is hotbriquetted. The hot-briquetted sponge iron has a degree of metallization (Femc/Feot) of 92 The reducing gas introduced into the fluidized bed reactors 1, 2 is formed by mixing a top gas drawn off a reduction shaft furnace serving for the direct reduction of lump ore with a portion of the offgas drawn off the fluidized bed reactor 1 arranged first in the flow direction of the fine ore. This offgas incurs in an amount of 189,766 Nm'/h and has the chemical composition indicated below.

Table I CO 41.41

CO

2 25.28 H2 17.10

H

2 0 1.50

H

2 S ppm 22.31

CH

4 3.50

N

2 ,Ar 11.21 o• Its calorific value is 8,337 kJ/ Nm 3 20,905 Nm 3 of this offgas are branched off as an export gas for other purposes of use via the export-gas discharge duct 16. 151,000 Nm 3 /h of this offgas are mixed with the top gas drawn off the reduction shaft furnace after both the top gas and the offgas have been subjected to wet scrubbing.

The mixed gas thus formed (311,000 Nm 3 has a calorific value of 7,873 kJ/ Nm 3 Its chemical composition is as follows: Table II CO 41.87

CO

2 30.73

H

2 16.43

H

2 0 1.89 H2S ppm 75.14

CH

4 2.24

N

2 ,Ar 6.83 After CO, scrubbing of this mixed gas in the CO 2 scrubber 11, its chemical composition is as follows: Table III CO 61.34

CO

2 0.45

H

2 24.07

H

2 0 0.70

H

2 S ppm 1.11

CH

4 3.32

N

2 10.11 It amounts to 210,140 Nm 3 its calorific value being 11,547 kJ/ Nm 3 The gas carried off the

CO

2 scrubber 11, which mainly contains CO 2 incurs in an amount of 100,860 Nm 3 Its chemical composition is indicated in Table IV below.

Table IV CO 1.29

CO

2 93.81 H2 0.51

H

2 0 4.37

H

2 S ppm 229.38

CH

4 0.00

N

2 ,Ar 0.00 After this, heating of the mixed gas is effected in the heat exchanger 12 by burning offgas carried off the fluidized bed reactor 1 through gas duct 15 in an amount of 17,861 Nm 3 For such burning the feeding of air in an amount of 32,184 Nm 3 /h is necessary.

In the afterburning means 13, oxygen in an amount of 5,083 Nm 3 /h is fed into the mixed gas thus heated in the heat exchanger 12 such that a partial combustion of the mixed gas takes place. This mixed gas heated to a temperature of 820 0 C then is available as a reducing gas for Sthe direct reduction of fine ore in the fluidized bed reactors 1 and 2 in an amount of 210,846 Nm 3 having a calorific value of 10,947 kJ/ Nm 3 Its chemical composition is indicated in Table V below.

Table V CO 58.16

CO

2 3.60 H2 22.82

H

2 0 2.19

H

2 S ppm 1.11

CH

4 3.15

N

2 ,Ar 10.09 6 In this specification, except where the context requires otherwise, the words "comprise", "comprises" and "comprising" mean "include", "includes" and "including", respectively, ie. when the invention is described or defined as comprising specified features, various embodiments of the same invention may also include additional features.

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Claims (8)

1. A plant for the production of pig iron and/or sponge iron, comprising at least one fluidized bed reactor intended to receive fine ore, a reducing-gas feed duct leading to the or each fluidized bed reactor, an offgas discharge duct departing from the or the last of the fluidized bed reactors and a discharge means provided for the reduction product formed in the or each fluidized bed reactor, wherein the offgas discharge duct runs into a purification means and subsequently into a two-stage heating means and finally into the reducing-gas feed duct -°of the or each fluidized bed reactor, characterized in that the heating means is constructed such that it comprises two i stages and that there are provided a heat exchanger as the heating means for the reducing gas and, connected serially therewith, a partial combustion means for the reducing gas with an oxygen feeding means.

2. A plant according to claim 1, characterized in that the purification means is a scrubber. eeoc

3. A plant according to claim 1 or 2, characterized in that the discharge means is a briquetting means. A plant according to any one of claims 1 to 3, characterized in that a CO2 removal means is provided in the reducing-gas feed duct of the or each fluidized bed reactor. A process for the production of pig iron and/or sponge iron comprising a plant according to any one of the claims 1 to 4, characterized in that fine ore is reduced to sponge iron with a reducing gas in a fluidized-bed direct reduction zone according to the fluidized bed method, wherein a purified offgas forming in the fluidized-bed direct reduction zone is supplied to the fluidized-bed direct reduction zone as a supplement to freshly supplied reducing gas, and that such offgas supplied to the fluidized-bed direct reduction zone is heated in two stages 8 namely in a first stage through heat exchange and in a second stage through partial combustion by means of oxygen which is fed into at least a partial quantity of the reducing gas.

6. A process according to claim 5, characterized in that the offgas and the freshly supplied reducing gas are together heated in the two stages and supplied to the fluidized-bed direct reduction zone.

7. A process according to claim 5 or 6, characterized in that the offgas from the fluidized-bed direct reduction zone is subjected to CO 2 removal.

8. A process according to any one of claims 5 to 7 characterized in that the freshly supplied reducing gas is fed to the fluidized-bed direct reduction zone while 15 bypassing the CO 2 removal means for the offgas from the fluidized-bed direct reduction zone.

9. A process according to any one of claims 5 to 8, characterized in that direct reduction is carried out in the fluidized bed process in two or more stages. 20 10. A plant substantially as hereinbefore described with reference to the accompanying drawing.

11. A process substantially as hereinbefore described with reference to the accompanying drawing. Dated this 1st day of March 1999 VOEST-ALPINE INDUSTRIEANLAGENBAU GMBH By their Patent Attorneys GRIFFITH HACK Fellows Institute of Patent and Trade Mark Attorneys of Australia \\melbO1\homeS\MCooper\Keep\Speci\P35971.95.1 DOC 1/03/99