AU680051B2 - Water-borne cross-linkable aminoalkyl-alkoxysilane coatings - Google Patents
Water-borne cross-linkable aminoalkyl-alkoxysilane coatingsInfo
- Publication number
- AU680051B2 AU680051B2 AU78047/94A AU7804794A AU680051B2 AU 680051 B2 AU680051 B2 AU 680051B2 AU 78047/94 A AU78047/94 A AU 78047/94A AU 7804794 A AU7804794 A AU 7804794A AU 680051 B2 AU680051 B2 AU 680051B2
- Authority
- AU
- Australia
- Prior art keywords
- coating composition
- aminoalkyl
- water
- dispersion
- alkoxysilane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000576 coating method Methods 0.000 title description 16
- 239000006185 dispersion Substances 0.000 claims description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 24
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical group CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 21
- 239000008199 coating composition Substances 0.000 claims description 21
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 20
- 229920000642 polymer Polymers 0.000 claims description 19
- 239000000178 monomer Substances 0.000 claims description 13
- 239000003431 cross linking reagent Substances 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 239000004606 Fillers/Extenders Substances 0.000 claims description 3
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 238000004132 cross linking Methods 0.000 description 22
- 239000003973 paint Substances 0.000 description 19
- 239000000945 filler Substances 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000003960 organic solvent Substances 0.000 description 11
- 239000002904 solvent Substances 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 8
- 239000012071 phase Substances 0.000 description 7
- 150000003141 primary amines Chemical group 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 150000002191 fatty alcohols Chemical class 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 239000004971 Cross linker Substances 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 235000010352 sodium erythorbate Nutrition 0.000 description 3
- 239000004320 sodium erythorbate Substances 0.000 description 3
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 3
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000004815 dispersion polymer Substances 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 1
- FHPDNLOSEWLERE-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCCOC(=O)C(C)=C FHPDNLOSEWLERE-UHFFFAOYSA-N 0.000 description 1
- FERWBXLFSBWTDE-UHFFFAOYSA-N 3-aminobutan-2-ol Chemical compound CC(N)C(C)O FERWBXLFSBWTDE-UHFFFAOYSA-N 0.000 description 1
- GZFANJYDVVSIMZ-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCCCOC(=O)C(C)=C GZFANJYDVVSIMZ-UHFFFAOYSA-N 0.000 description 1
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 101100247531 Arabidopsis thaliana RBOHC gene Proteins 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920004896 Triton X-405 Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- GCPWJFKTWGFEHH-UHFFFAOYSA-N acetoacetamide Chemical group CC(=O)CC(N)=O GCPWJFKTWGFEHH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003190 augmentative effect Effects 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- -1 beta-aminoethyl Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920002113 octoxynol Polymers 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Description
WATER-BORNE CROSSLINKABLE AMINOA KYL-ALKOXYSI ANE COATINGS
TECHNICAL FIELD OF THE INVENTION
This invention relates to water-borne coatings and in particular to coatings containing aminoalkyl-al oxysilane or aminoalkyl-silanol in combination with acetoacetate functional groups.
BACKGROUND OF THE INVENTION
Polymeric coatings for use on a variety of substrates for protective and decorative purposes are well known. When in liquid form prior to application they usually have volatile organic solvent or water as the liquid carrier phase which evaporates after application to leave a polymer coating or film on the substrate.
For many protective coating applications film properties such as hardness and solvent resistance are improved by causing them to become crosslinked or cured after application to the substrate. For this purpose it is known to employ crosslinkable coating compositions whereby the composition includes components which react to cause crosslinking of the applied film. Such reaction may be augmented or catalysed by the presence of atmospheric oxygen or water as in the case of alkyd coatings and moisture curable polyurethane coatings respectively. Alternatively the binder may have reactive and co-reactive groups which covalently co-react to form a crosslinked coating.
Such a crosslinking reaction is of course not intended to take place to an unacceptable degree until after the composition is applied to the substrate. As might be imagined, many such coating compositions intended for crosslinking at ambient temperatures may have a short shelf-life, i.e. an unacceptably short period of time before premature crosslinking occurs in the liquid pre- application composition leading to unacceptable application or film properties. In some applications poor shelf-life
can be overcome by storing the composition as a two-pack product and only combining the two packs shortly before application. This is usually not acceptable for DIY decorative products but it is an acceptable compromise for industrial applications such as the refinishing of motor vehicles.
For example, a hydroxyl containing polyester can be combined with a multi functional isocyanate shortly before application to provide a crosslinkable composition that cures at ambient temperatures after application to give a hard crosslinked film. Unfortunately some crosslinking systems that achieve good film properties at ambient temperature have accompanying occupational health problems,
In an endeavour to prepare compositions with alternative crosslinking mechanisms a potentially useful coating composition comprising an acetoacetate functional polymer, e.g. an acrylic polymer or a polyester, and a polyamine have been disclosed. Examples of such compositions are described, for example, in Journal of Coating Technology, Vol. 61 (771) pages 31-37 1989. These compositions relate to solution polymers containing acetoacetate groups in organic solvents and a range of crosslinking agents, with particular reference to hexamethoxymethylmelamine.
Crosslinking has been reported with solution acrylic polymers containing acetoacetate functional groups which have been combined with crosslinking agents having aminoalkyl-alkoxysilane functional groups. For example, Japanese patent application Jpn. Kokai Tokyo Koho JP 04,189,874 filed on 22 November 1990 and published 8 July 1992 discloses crosslinkable high solids coating compositions prepared from a solution polymer containing acetoacetate groups combined with an aminoalkyl- alkoxysilane. The compositions are prepared and used in the presence of organic solvent. The curing mechanism is said to include the silyl group of the amino alkyl - alkoxysilane undergoing a self-bridging reaction. To meet
the high solids requirement the solution polymers containing the acetoacetate groups are low molecular weight. The number average molecular weight of all the examples is 3000. Clearly it is necessary for water to be kept away from these compositions until the composition has been applied to the substrate as moisture is part of the curing mechanism.
Similarly a recent US patent by Bayer AG, US Patent No 5,242,978 discloses the combination of a specific class of aminoalkyl-alkoxysilane as hardeners for plastic precursors containing at least two acetoacetate and/or acetoacetamide groups. Again as for the Japanese citation discussed above these relate to polymers or oligomers carried in organic solvents. The advantages of these compositions are that good pot life is obtained and that crosslinking does not rely on contact with atmospheric moisture. The molecular weight of the plastic precursor is between 400 and 25,000 to achieve their desired properties. The ratio of primary amine groups to acetoacetate groups is from 0.5:1 to 1:1 and preferably from 8:1 to 1:1. Again, this patent teaches that the presence of water before the composition is applied must be avoided.
Water-borne coatings are preferred from safety and environmental perspectives compared to coating compositions containing volatile organic solvents. Accordingly, water- borne coatings have been widely used for many years in the decorative coatings area. However in the motor vehicle refinish area, where paint systems used for the repairing and repainting of motor vehicles are required to match the performance of the original paint system, water-borne- coatings have had little impact.
One particularly demanding application is for primer/fillers for application over bare metal and previously painted surfaces in the motor vehicle refinish area. In the case of such coatings early film properties such as sandability and substrate and intercoat adhesion and longer term properties such as corrosion and humidity
performance have been very difficult to achieve with water- borne systems compared to conventional solvent-based paints. Furthermore, flash rusting over bare steel can sometimes be a problem with water based primers.
In practice it is often very difficult to adapt and use crosslinking reaction systems that are used in organic solution systems to corresponding water-borne systems because of the presence of water which may interfere with the crosslinking reaction scheme. For example, some organic solvent based systems rely on atmospheric moisture to unblock amine/aldehydes so that they may react after film formation. Clearly such systems would have no application in water based coatings as the unblocking and crosslinking reaction would then occur before application.
Water based crosslinkable binders based on acetoacetate functional groups and polyamines as disclosed in our co-pending Australian patent application No. PM1525 have not been able to produce rapid enough crosslinking to provide adequate early film properties for some applications. This is particularly evident in the area of primer/fillers in the refinishing of motor vehicles where rapid crosslinking is required at pigment volume concentrations (PVCs) of 30% and above.
SUMMARY OF THE INVENTION
This invention provides in one form a coating composition comprising an aqueous film-forming dispersion of addition polymer comprising acetoacetate functional groups and a water soluble aminoalkyl-alkoxysilane or aminoalkyl-silanol crosslinking agent having at least one primary amine group.
Preferably the acetoacetate groups are provided by copolymerising addition polymerisable monomers containing acetoacetate functional groups.
More preferably the acetoacetate groups are incorporated by polymerisation of a monomer selected from
the group consisting of allyl acetoacetate, acetoacetoxyethyl methacrylate, acetoacetoxypropyl methacrylate and acetoacetoxybutyl methacrylate and the corresponding acrylates.
Most preferably the acetoacetate groups are incorporated by polymerisation of acetoacetoxyethyl methacrylate (AAEM) .
Preferably the aminoalkyl-alkoxysilane crosslinking agent has three alkoxy groups bound to the silicon atom.
Preferably the aminoalkyl-alkoxysilane crosslinking agent comprises a secondary amine group in addition to the primary amine group.
Preferably the coating composition includes an acid accelerator which increases the rate of crosslinking and which is preferably a carboxylic acid group covalently bonded to the addition polymer.
Preferably the aqueous dispersion is sterically stabilised and more preferably it has covalently bonded alkylene oxide chains that confer steric stability.
Preferably the coating composition includes pigments and extenders to a PVC of at least 30%.
DETAILED DESCRIPTION OF THE INVENTION
The aqueous film-forming dispersions of this invention are usually copolymers of the acetoacetate functional monomers and other addition polymerisable comonomers.
Examples of useful comonomers include alkyl acrylates and methacrylates where the alkyl group has 1 to 20 (and more preferably 1 to 8) carbon atoms, styrene, vinyl acetate, acrylonitrile and simple or substituted olefins. Monomers containing other functional groups such as hydroxyl or carboxyl groups may be used.
In practice, in paint formulations best results in terms of crosslinking rate and adhesion are achieved when carboxylic acid groups are included by, for example, copolymerisation of methacrylic acid.
Minor amounts of functional monomers directed towards specific objectives such as adhesion promotion may also be incorporated. However this may be unnecessary as we believe the acetoacetate functional groups may provide beneficial adhesion properties as well as sites for crosslinking. The selection of comonomers and their relative proportions is based on well established principles in the art and generally balance properties such as flexibility, hardness and water resistance as well as cost. In some applications advantageous properties can be achieved by combining polymer dispersions of differing Tgs. For example, when formulated as a primer/filler, improved sanding can be achieved by using more than 5% of a hard dispersion, for example 20% of Tg 70°C dispersion combined with 80% of Tg 17°C dispersion. However, in some formulations one needs to take into account that the hard dispersion may affect other properties by contributing to the overall PVC of a paint composition.
The minimum film forming temperature (MFT) of the aqueous dispersion in this invention is usually in the range of 0 - 30°C. In general the MFT of an aqueous dispersion of film forming polymer is determined by the Tg of the copolymer of the dispersion. When formulated as a refinish primer/filler we have found the Tg of the copolymer dispersion affects the early sanding properties as well as later film properties and should usually be in the range of 10-40°C for the best balance of film properties.
The aqueous dispersions of the present invention may be prepared by known means, especially emulsion polymerisation. However best results are achieved where the aqueous dispersion is prepared such that it is sterically stabilised. The term sterically stabilised is
an art-recognised term in colloid science and means that, in aqueous systems, colloidal stability is conferred by the presence of a sheath of water soluble polymeric or uncharged oligomeric chains anchored to the particle surface. By sterically stabilised dispersions it is meant that whilst other types of stability, such as anionic or cationic, may be present there is also colloidal stability conferred by steric stabilisation. For the purposes of this invention a convenient test to ascertain whether the dispersion is sterically stabilised or not is to increase the ionic concentration of the aqueous phase to such an extent that ionic stabilisation is nullified and then to assess the stability of the dispersion.
Examples of the preparation of dispersions suitable for the working of the present invention are described in Australian Patent No. 618,176. Also within the scope of the present invention are polymer dispersions which have a core/shell structure whereby the polymer properties at the outer shell of the particle differ from those towards the centre of the particle. In the case of core/shell structure dispersion particles rather than relying upon the Fox equation to calculate Tg we prefer to use practical values as determined using temperature gradient bars and assessing the temperature of discontinuity in film formation. Typically the molecular weights of the dispersion polymer are at least 25,000 (Mn) and usually about 50,000 which are generally substantially higher than the molecular weight of polymers prepared in organic solvents.
While a number of monomers may be used to introduce the acetoacetate functionality, AAEM is our preferred monomer and in practice 10-25% w/w of total addition monomers and more preferably 15-20% w/w give best results. As this monomer is relatively expensive, in practice we minimise its level consistent with achieving the rate and extent of crosslinking desired to give coatings with acceptable film properties.
Because of the rapid crosslinking of compositions of the present invention they are usually used as two-pack systems. Generally the aqueous dispersion phase is separately packaged from the aminoalkyl-alkoxysilane phase until shortly before application is desired when mixing of the two packs takes place. It is therefore most convenient for mixing that the aminoalkyl-alkoxysilane crosslinker is a relatively low viscosity liquid so that the use of additional organic solvent is not required to dissolve or reduce the viscosity of the crosslinker before it can be conveniently mixed with the aqueous disperse phase. However also within the scope of the present invention is the use of prehydrolysed aminoalkyl-alkoxysilane or aminoalkyl-silanol. In this case it is acceptable to use an aqueous solution of the aminoalkyl-silanol, usually prepared by adding the aminoalkyl-alkoxysilane to water. In some embodiments it is convenient to use the aminoalkyl- alkoxysilane component diluted with water-miscible organic solvents. In practice this can be used to increase the volume of the aminoalkyl-silanol component for more convenient mixing ratios such as 2:1 or 4:1 by volume where the aminoalkyl-alkoxysilane is the smaller of the two packs. Despite the presence of organic solvents these coatings are still regarded as water-borne as the majority of the volatile solvent present in the combined two pack paint is water.
The aminoalkyl-alkoxysilane is required to have at least one primary amine group. Better results in terms of crosslinking rate have been achieved when the aminoalkyl- alkoxysilane also has a secondary amine present. Best results have been achieved with a diamine, Dow Corning material Z6020, which is gamma-[N- (beta-aminoethyl) amino]propyltrimethoxysilane. This provides more rapid crosslinking than the monoamine A-1100, [(gamma- aminopropyl) triethoxysilane] supplied by Union Carbide.
The aminoalkyl-alkoxysilane is required to be water soluble and by this we mean it is water soluble when visually assessed sixty minutes after adding lg to lOg of water at 25°C under gentle agitation. Obviously in the case of
aminoalkyl-alkoxysilane, reaction can take place with the water in this test and it is the solubility after reaction that is important. This is believed to be substantially complete after one hour.
In practice a working pot life of at least a few hours is required so that minor touch up to applied primer/filler can be made without the necessity to mix a new batch of paint. Compositions prepared according to our invention can have a satisfactory pot-life of 24 hours at ambient temperatures. This is a surprising result as when the aminoalkyl-alkoxysilane crosslinking agent is used and known to occur, reaction with water prior to application is expected. Nevertheless, a favourable balance of pot-life and film properties can be achieved.
It is believed in our preferred compositions that the steric stabilisation of the particles may contribute to good spray application properties as the good colloidal stability of the steric stabilisation of the dispersion is not adversely affected by addition of the aminoalkyl- alkoxysilane crosslinker.
The relative proportions of disperse phase and crosslinker are selected so that the mole ratio of acetoacetate functional group to primary amine group of the aminoalkyl-alkoxysilane are in the range 10:1 to 1:2, and more preferably 5:1 to 1:1 and most preferably 4:1. The extent and rate of cross-linking is affected by this ratio. In a refinish primer/filler at ratios of 1:1 early sanding is very good but water resistance properties such as humidity performance may be compromised. Changing the ratio of acetoacetate to amine varies the humidity performance, the rate of crosslinking and early sandability properties. The best balance appears to be the 4:1 ratio as later exemplified in Example 1. This is a surprising result as it would normally be expected that balanced or close to balanced stoichiometry would produce the optimum result. This may be a consequence of the lack of accessibility of the acetoacetate groups in the dispersion poly
The coating compositions of the present invention are pigmented when used as a refinish primer/filler and typically have a pigment volume concentration of 40-48%. Normally the pigment is dispersed in the aqueous polymer dispersion phase.
In this specification the terms aqueous and water- borne have their art-recognised meaning which includes minor amounts of co-solvents and other volatile organic material provided water constitutes more than 50%, and preferably at least 80% of the volatile phase.
The invention will be further illustrated by the following examples of preferred embodiments.
Example 1
Preparation of a refinish primer/filler having a mole ratio of acetoacetate to primary amine groups of 4:1.
A. Preparation of an aqueous film forming dispersion of Tg 17°C containing 15% AAEM by weight.
Stage Material Wt.%
A Fatty alcohol ethoxylate surfactant* 0.048
B Water 6.564
C t-butyl perbenzoate 0.015
D 30% hydrochloric acid trace
E Ferrous sulphate 0.010
Water 0.965
F Fatty alcohol ethoxylate surfactant 0.787 t-butyl perbenzoate 0.375
Water 2.17
Feeds 1 2 3
G Methyl methacrylate 3.02 5.07 16. 661
Butyl acrylate 2.10 3.54 11. 279
Methacrylic acid 0.032 0.053 0. 162
AAEM 1.04 1.74 4. ,532
Feeds (continued) 1 2 3
H Fatty alcohol ethoxylate surfactant 0.334 0 . 568 1 . 070
I Water 3.25 8 . 130 24 . 625 J Sodium erythorbate 0.027 0 . 046 0 . 146 Water 0.275 0 .462 1.430
* as described in Example 2 of International Patent Application No. PCT/AU90/00565.
Stages E, F and J were each premixed. Stages A-C were charged to a reaction vessel equipped with stirrer, condenser, nitrogen blanket and feed facilities. The pH was adjusted to pH 3 with D, warmed to 30°C, and then E was added. Feeds, designated 1, 2 and 3 were each emulsified under high shear and added successively over 50 minutes, 45 minutes and 120 minutes respectively. Stage F was added at the same time as Feed 1. The reaction mixture was maintained at 30°C throughout the reaction process. After polymerisation the solids content was 51% and this dispersion was designated 1A. The number average molecular weight of this polymer was measured and found to be 61,000.
B. Preparation of primer/filler using dispersion 1A with PVC 48%.
Stage Material
Wt.% A Triton X405 (octyl phenol ethoxylate) 0.285
AMP 95 (2-amino methyl propanol) 0.571
Bevaloid 4226 (antifoam) 0.100
B Water 14.847
C RHD2 Ti02 13.636 Aerosil (Silica) 1.235
Barytes B4AA (Coarse) 12.967
Talc micromist (fine) 14.115
Zinc oxide 5.014
Zn phosphate 2.495 D Dispersion 1A 31.767
E Texanol 1.588
(Continued) Stage Material wt . . % F Black tinter 0 , .05 Yellow tinter 1. . 30 Red tinter 0 , .03
100 . . 00
Stage C was added in sequence with stage B to premixed stage A. Dispersion of pigment and fillers was achieved by high speed dispersion. Stage D was added slowly to the millbase and mixing continued for 5 mins. Stage E was then added, followed by Stage F and the paint stirred for 20 mins. before filtering.
This composition was designated the "first" pack.
The "second" pack consisted of the aminoalkyl- alkoxysilane curing agent (Dow Z6020).
To 100 parts of the "first" pack 0.64 parts by weight of the "second" were added with stirring. The combined packs were then adjusted to suitable spray viscosity by the addition of water.
C. Test Methods for primer/filler
Dry Sanding
The primer/filler was spray applied over a mild steel panel substrate to give a dry film build of approximately 50 μm.
The primer was hand sanded using P360 paper after two hours drying at ambient temperature and assessed for powder, clogging and ease of removal.
Panels were topcoated with a commercial acrylic/isocyanate paint after sanding (after two hours drying) .
Solvent Resistance (primer/filler only)
Films of 50 μm dry film build were assessed for swelling and rub through using damped cotton wool. Two solvents were utilised: Prekleano (95% white spirit, 5% isopropanol) and xylene.
Humidity (top coated system)
Test panels (suitably backed) were placed in a fog cabinet (38°C, 100% RH) for 10 days. Panels were assessed daily for blistering/corrosion/sinkage. Panels were removed after 10 days and adhesion tested at two hours and twenty-four hours recovery.
Hardness (primer/filler only)
This was measured using a microindentation instrument (Knoop hardness) after the paint film was aged for 4.5 hours at 25°C
Salt Spray Corrosion (top coated system)
After ageing the panel for 7 days a "X-cut" was scribed onto the test panels which were subsequently placed in the salt spray cabinet for 500 hours. Panels were regularly assessed for blistering, corrosion and undercut. At the end of the test, the area around the X-cut was stripped and examined for corrosion.
Water Immersion (top coated system)
Test panels were immersed in distilled water at 40°C for 5 days after which time they were assessed for adhesion, blistering, corrosion and sink back. If satisfactory, they were returned for a further 5 days and reassessed.
Chip Resistance (top coated system) The test panel was placed into the "gravelometer machine," being magnetically held vertically at 90° to the airflow. The airstream was adjusted to the specified air pressure and 250 ml of stone chips poured into the airstream, which blows them onto the panel surface. Total test time was 15 sec. The panel was taken out and loose
paint removed by means of filament tape adhesion. Assessment was against standard photographs (0 = total failure, 10 = no damage) .
D. Test Results Property Example 1 Commercial Control*
Dry sanding Fair Very good Humidity resistance Excellent Very good
Water immersion Excellent Excellent
Salt spray Good Very Good Knoop Hardness 1.6 3.2
Chip Resistance Excellent Fair
These results show a favourable balance of properties compared to the organic solvent-borne control. The early sanding properties of the composition according to this invention are worse than the control but the chip resistance is considerably improved.
* Commercial organic solvent borne two-pack acrylic/isocyanate primer/filler.
Example 2 and 3 These examples show the effect of varying the acetoacetate to primary amine mole ratio.
Example 1 was followed, except that the proportion of crosslinker was increased to provide mole ratios of AAEM to NH2 of 2:1 (Example 2) and 1:1 (Example 3). The paints were prepared and tested as for Example 1 to give the following results.
Property Example 2 Example 3
Dry sanding Very Good Very Good
Humidity resistance Good Fair Water immersion Good Fair
Salt spray Fair Good
Knoop hardness 1.9 2.3
Chip resistance Good Fair
Both these paints were judged to be useful primer/fillers with very good sanding properties.
Example 4
This example shows the effect of having copolymerised methacrylic acid in the dispersion.
A dispersion was prepared as for 1A but without the presence of the 0.5% methacrylic acid. When formulated as a paint as in Example 1 the xylene solvent resistance after two hours drying was 20 double rubs compared to 80 double rubs for the composition of Example 1. This example illustrates the accelerating effect of copolymerised carboxyl groups.
Example 5-12
These examples illustrate the effect of varying levels of AAEM in the dispersion and varying ratios of AAEM to NH2 and the effect of these variations have on xylene solvent resistance. Example 5 and 9 are comparative examples outside the scope of the present invention.
Dispersions were prepared as for dispersion 1A but with 10% AAEM (dispersion 5A) and 25% AAEM/dispersion
(dispersion 9A) . Solvent (xylene) resistance was assessed after two hours drying. The results are set out below.
-ample Dispersion % AAEM: Xylene Solvent No. AAEM NH2 Resistance
5* 5A 10 1:0 5
6 5A 10 4:1 64
7 5A 10 2:1 81
8 5A 10 1:1 77
9* 9A 25 1:0 9
10 9A 25 4:1 78
11 9A 25 2:1 112
12 9A 25 1:1 112 comparative example
A commercial water-borne one-pack primer was also tested for solvent resistance and found to have eight double rubs.
Example 13 This example illustrates the preparation of paint using a combination of film forming dispersions of differing Tg's and the evaluation of such paint.
A Preparation of MMA/BA/AAEM (5%) dispersion of Tg 70°C.
Stage Material Wt.%
A Fatty alcohol ethoxylate surfactant* 1.29
B Water 7.48
C t-butyl perbenzoate 0.38
D 30% hydrochloric acid trace
E Ferrous sulphate 0.009
Water 0.948
Feeds 1 2
F Methyl methacrylate 14.39 26.77
Butyl acrylate 1.53 2.85
AAEM 0.84 1.56
G Fatty alcohol ethoxylate surfactant* .07 1.23
H Water 13.24 24.06
I Sodium erythorbate 0.075 0.14
Water 0.746 1.39
* As described in Example 3 of International Patent Application No. PCT/AU90/00565
Stages E and I were each premixed. Stages A-C were charged to a reaction vessel equipped with stirrer, condenser, nitrogen blanket and feed facilities. The pH was then adjusted to pH 3 with D, warmed to 70°C, and then E was added. Feeds, designated 1 and 2 were each emulsified under high shear and added successively over 95 minutes and 120 minutes respectively. The reaction mixture was maintained at 70°C throughout the reaction. After
polymerisation the solids content was 51% and this was designated dispersion 13A. The number average molecular weight of the polymer was 38,000.
B. Preparation of MMA/BA/MAA (0.5%)/AAEM (25%) dispersion of Tg 17°C.
The method for preparing dispersion 1A was repeated except that the monomer composition was varied by using the following feed stages.
Feeds 1 2 3
G Methyl methacrylate 2.62 4.40 14.42
Butyl acrylate 1.82 3.05 10.00
Methacrylic acid 0.031 0.053 0.164
AAEM 1.72 2.90 7.55
H Fatty alcohol ethoxylate surfactant 0.33 0.565 1.08
I Water 3.26 5.13 24.63
J Sodium erythorbate 0.027 0.057 0.156
Water 0.276 0.57 1.56
This dispersion was designated 13B. The number average molecular weight of this polymer was 50,000.
C. Preparation of paint.
Paint was prepared as in Example 1 except that the pigment and extender levels were adjusted to provide a PVC of 40%, and 20% of dispersion 13A and 80% of dispersion 13B were used as the binder. The mole ratio of AAEM to NH2 was
4:1.
The test results are as follows: Property Example 13
Dry sanding Excellent Humidity resistance Excellent
Salt Spray Very good
Knoop Hardness 2.5
Chip Resistance Very good
This paint demonstrates a favourable balance of early properties.
Claims (12)
1. A coating composition comprising an aqueous film forming dispersion of addition polymer comprising acetoacetate functional groups and a water soluble aminoalkyl-alkoxysilane or aminoalkyl-silanol crosslinking agent having at least one primary amine group.
2. A coating composition as defined in claim 1 wherein the crosslinking agent is an aminoalkyl-alkoxysilane having three alkoxy groups bonded to the silicon atom.
3. A coating composition as defined in claim 2 wherein the crosslinking agent includes a secondary amine group in addition to the primary amine group.
4. A coating composition as defined in any one of claims 1-3 wherein the aqueous dispersion is sterically stabilized by having covalently bound alkylene oxide chains.
5. A coating composition as defined in claim 4 further comprising pigments and extenders to a PVC of at least 30%.
6. A coating composition as defined in claim 1 wherein the acetoacetate functional groups are provided by copolymerising 10-25% w/w of total addition monomers of acetoacetoxyethyl methacrylate.
7. A coating composition as defined in any one of claims 1-6 wherein the mole ratio of acetoacetate functional groups to primary amine groups of the crosslinking agent is in the range 5:1 to 1:1.
8. A coating composition as defined in claim 7 wherein the mole ratio of the acetoacetate functional groups to primary amine groups of the crosslinking agent is approximately 4:1.
9. A coating composition as defined in any one of claims 1-8 wherein the molecular weight (Mn) of the addition polymer is at least 25,000.
10. A coating composition as defined in claim 9 wherein the aqueous dispersion of film forming polymer comprises a mixture of aqueous polymer dispersions one having a low Tg and one having a high Tg.
11. A coating composition as defined in claim 6 wherein the acetoacetate functional groups are provided by copolymerising 15-20% w/w of total addition monomer of acetoacetoxyethyl methacrylate.
12. A coating composition as defined in any one of claims 1-11 wherein the aqueous dispersion further comprises copolymerised carboxylic acid monomer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU78047/94A AU680051B2 (en) | 1993-09-29 | 1994-09-29 | Water-borne cross-linkable aminoalkyl-alkoxysilane coatings |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPM152493 | 1993-09-29 | ||
AUPM1524 | 1993-09-29 | ||
PCT/AU1994/000598 WO1995009208A1 (en) | 1993-09-29 | 1994-09-29 | Water-borne cross-linkable aminoalkyl-alkoxysilane coatings |
AU78047/94A AU680051B2 (en) | 1993-09-29 | 1994-09-29 | Water-borne cross-linkable aminoalkyl-alkoxysilane coatings |
Publications (2)
Publication Number | Publication Date |
---|---|
AU7804794A AU7804794A (en) | 1995-04-18 |
AU680051B2 true AU680051B2 (en) | 1997-07-17 |
Family
ID=25638823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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AU78047/94A Expired AU680051B2 (en) | 1993-09-29 | 1994-09-29 | Water-borne cross-linkable aminoalkyl-alkoxysilane coatings |
Country Status (1)
Country | Link |
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AU (1) | AU680051B2 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5242978A (en) * | 1990-10-27 | 1993-09-07 | Bayer Aktiengesellschaft | Alkoxysilylamines as curing agents for plastics precursors containing acetoacetate or acetoacetamide groups |
-
1994
- 1994-09-29 AU AU78047/94A patent/AU680051B2/en not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5242978A (en) * | 1990-10-27 | 1993-09-07 | Bayer Aktiengesellschaft | Alkoxysilylamines as curing agents for plastics precursors containing acetoacetate or acetoacetamide groups |
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