AU648559B2 - Cross-linked polymers of ethylenically unsaturated acids and their use in the production of hygiene articles - Google Patents

Cross-linked polymers of ethylenically unsaturated acids and their use in the production of hygiene articles

Info

Publication number
AU648559B2
AU648559B2 AU77897/91A AU7789791A AU648559B2 AU 648559 B2 AU648559 B2 AU 648559B2 AU 77897/91 A AU77897/91 A AU 77897/91A AU 7789791 A AU7789791 A AU 7789791A AU 648559 B2 AU648559 B2 AU 648559B2
Authority
AU
Australia
Prior art keywords
polymer
cross
production
ethylenically unsaturated
unsaturated acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU77897/91A
Other versions
AU7789791A (en
Inventor
Helmut Brehm
Kurt Dahmen
Richard Mertens
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stockhausen GmbH and Co KG
Original Assignee
Chemische Fabrik Stockhausen GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Fabrik Stockhausen GmbH filed Critical Chemische Fabrik Stockhausen GmbH
Publication of AU7789791A publication Critical patent/AU7789791A/en
Application granted granted Critical
Publication of AU648559B2 publication Critical patent/AU648559B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Hematology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

The invention relates to a cross-linked, water-absorbent polymer obtainable by the polymerisation of a mixture consisting of a) 60 - 99 % wt. unsaturated, polymerisable monomers with acid groups which are neutralised to the extent of at least 30 mol %, b) 0 - 37 % wt. monomers copolymerisable with a), c), 0.1 - 3.0 % wt. of a cross-linking agent and d) 0 - 10 % wt. of a water-soluble polymer, in which polymerisation is brought about with a redox catalyst system containing formamidine sulphinic acid. The polymer is distinguished by a retention of over 28 g 0.9 % aqueous NaCl solution per 1 g of polymer, an absorption of more than 26 g 0.9 % aqueous NaCl solution per 1 g of polymer at a load of 20 g/cm?2 and a residual monomer content of less than 700 ppm and preferably less than 500 ppm. The invention also relates to the use of this polymer in the production of hygiene items.
AU77897/91A 1990-05-11 1991-05-10 Cross-linked polymers of ethylenically unsaturated acids and their use in the production of hygiene articles Ceased AU648559B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4015085 1990-05-11
DE4015085A DE4015085C2 (en) 1990-05-11 1990-05-11 Crosslinked, water-absorbent polymer and use for the manufacture of hygiene articles, for soil improvement and in cable sheathing
PCT/EP1991/000878 WO1991018031A1 (en) 1990-05-11 1991-05-10 Cross-linked, water-absorbent polymer and its use in the production of hygiene items

Publications (2)

Publication Number Publication Date
AU7789791A AU7789791A (en) 1991-12-10
AU648559B2 true AU648559B2 (en) 1994-04-28

Family

ID=6406153

Family Applications (1)

Application Number Title Priority Date Filing Date
AU77897/91A Ceased AU648559B2 (en) 1990-05-11 1991-05-10 Cross-linked polymers of ethylenically unsaturated acids and their use in the production of hygiene articles

Country Status (9)

Country Link
EP (1) EP0527867B1 (en)
JP (1) JP3076853B2 (en)
AT (1) ATE111924T1 (en)
AU (1) AU648559B2 (en)
CA (1) CA2082506A1 (en)
DE (2) DE4015085C2 (en)
ES (1) ES2037637T3 (en)
GR (1) GR930300039T1 (en)
WO (1) WO1991018031A1 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4206850C2 (en) * 1992-03-05 1996-08-29 Stockhausen Chem Fab Gmbh Polymer compositions, preparation of polymer compositions, in particular absorption materials and their use
US5416160A (en) * 1992-06-19 1995-05-16 The Dow Chemical Company Water-swellable polymers having improved color
DE4435422A1 (en) * 1994-10-04 1996-04-18 Basf Ag Process for the preparation of an aqueous polymer dispersion
DE19529348C2 (en) * 1995-08-09 1997-11-20 Stockhausen Chem Fab Gmbh Absorbent for water and aqueous liquids based on polyacrylate and process for their production and use
CN1279097C (en) * 1996-12-13 2006-10-11 株式会社日本吸收体技术研究所 Highly absorbent composite compositions, absorbent sheets provided with the compositions, and process for producing the same
DE19854573A1 (en) 1998-11-26 2000-05-31 Basf Ag Process for post-crosslinking hydrogels with 2-oxo-tetrahydro-1,3-oxazines
AU2001246902B2 (en) 2000-04-13 2005-02-17 Sanyo Chemical Industries, Ltd. Crosslinked polymer, process for producing the same, absorbent structure, and absorbent article
WO2002032975A1 (en) * 2000-10-18 2002-04-25 Basf Aktiengesellschaft Hydrogel-forming polymers
DE10225943A1 (en) 2002-06-11 2004-01-08 Basf Ag Process for the preparation of esters of polyalcohols
AU2003296558A1 (en) * 2002-10-25 2004-05-13 Stockhausen Gmbh Absorbent polymer structure provided with an improved retention capacity and permeability
EP1736508A1 (en) 2005-06-22 2006-12-27 Basf Aktiengesellschaft Hydrogel-forming polymers with increased permeability and high absorption capacity
JP2019094444A (en) * 2017-11-24 2019-06-20 Ｓｄｐグローバル株式会社 Water-absorbable resin particle and production method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076663A (en) * 1975-03-27 1978-02-28 Sanyo Chemical Industries, Ltd. Water absorbing starch resins
US4286082A (en) * 1979-04-06 1981-08-25 Nippon Shokubai Kagaku Kogyo & Co., Ltd. Absorbent resin composition and process for producing same
EP0205674A1 (en) * 1985-06-18 1986-12-30 The Procter & Gamble Company Hydrogel-forming polymer compositions for use in absorbent structures

Family Cites Families (20)

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Publication number Priority date Publication date Assignee Title
DE861155C (en) * 1941-02-22 1952-12-29 Hoechst Ag Process for emulsion polymerization in the simultaneous presence of oxidizing agents and reducing agents
DE926091C (en) * 1942-07-21 1955-04-07 Hoechst Ag Process for the production of polymers or copolymers of simply unsaturated compounds
US4115339A (en) * 1971-11-18 1978-09-19 Hercules Incorporated High molecular-weight, water-soluble vinyl polymers
CA1178744A (en) * 1979-07-11 1984-11-27 Daniel F. Herman Polymeric electrolytes
DE3124008A1 (en) * 1981-06-19 1983-01-27 Chemische Fabrik Stockhausen & Cie, 4150 Krefeld CROSSLINKED, WATER-SWELLABLE COPOLYMERS AND THEIR USE AS AN ABSORBENT FOR AQUEOUS BODY LIQUIDS LIKE URINE
US4677174A (en) * 1986-04-21 1987-06-30 American Colloid Company Water absorbent styrene-acrylic acid copolymers
DE3312424A1 (en) * 1983-04-07 1984-10-11 Basf Ag, 6700 Ludwigshafen Process for the preparation of bead-form polymers
CA1256640A (en) * 1984-03-05 1989-06-27 Harumasa Yamasaki Absorptive material
FR2575479B1 (en) * 1984-12-27 1987-02-27 Charbonnages Ste Chimique AMPHOTERIC COPOLYMERS, THEIR MANUFACTURING PROCESS AND THEIR APPLICATION TO WATER RETENTION
DE3505920A1 (en) * 1985-02-21 1986-08-21 Röhm GmbH, 6100 Darmstadt SLOWLY CROSSLINKED, PARTICULAR, SOLID POLYMERISATES OR MIXED POLYMERS, QUICKLY SWELLING IN WATER, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN HYGIENE ITEMS
US4616063A (en) * 1985-03-06 1986-10-07 Atlantic Richfield Company Water absorbent polymer composition
JPS61271303A (en) * 1985-05-24 1986-12-01 Lion Corp Production of water-absorptive resin
EP0208945B1 (en) * 1985-06-22 1990-01-31 Taiyo Fishery Co., Ltd. An aqueous composition, method of producing a water absorbent polymer, water absorbent polymer-coated article and method of producing the same
DE3605332A1 (en) * 1986-02-19 1987-08-20 Bayer Ag CHLOROPRENE POLYMERISATION
CS263644B1 (en) * 1986-10-16 1989-04-14 Hudecek Slavko Copolymers of acrylic or methacrylic acid or alkalic metal salts thereof
DE3713601A1 (en) * 1987-04-23 1988-11-10 Stockhausen Chem Fab Gmbh METHOD FOR PRODUCING A STRONG WATER-ABSORBENT POLYMER
KR0130652B1 (en) * 1987-08-14 1998-04-07 존 휴즈 Improved process for preparing water-absorbing resins
US4833222A (en) * 1987-10-22 1989-05-23 The Dow Chemical Company Crosslinker stabilizer for preparing absorbent polymers
DE3741158A1 (en) * 1987-12-04 1989-06-15 Stockhausen Chem Fab Gmbh POLYMERISATES WITH HIGH ABSORPTION SPEED FOR WATER AND AQUEOUS LIQUIDS, METHOD FOR THE PRODUCTION THEREOF AND USE AS ABSORBENTS
KR970009239B1 (en) * 1988-06-16 1997-06-09 미츠비시유카 가부시키가이샤 Process for producing highly water absorptive polymer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4076663A (en) * 1975-03-27 1978-02-28 Sanyo Chemical Industries, Ltd. Water absorbing starch resins
US4286082A (en) * 1979-04-06 1981-08-25 Nippon Shokubai Kagaku Kogyo & Co., Ltd. Absorbent resin composition and process for producing same
EP0205674A1 (en) * 1985-06-18 1986-12-30 The Procter & Gamble Company Hydrogel-forming polymer compositions for use in absorbent structures

Also Published As

Publication number Publication date
WO1991018031A1 (en) 1991-11-28
EP0527867A1 (en) 1993-02-24
ES2037637T1 (en) 1993-07-01
EP0527867B1 (en) 1994-09-21
CA2082506A1 (en) 1991-11-12
AU7789791A (en) 1991-12-10
JP3076853B2 (en) 2000-08-14
DE4015085A1 (en) 1991-12-12
DE59103054D1 (en) 1994-10-27
DE4015085C2 (en) 1995-06-08
ATE111924T1 (en) 1994-10-15
ES2037637T3 (en) 1994-12-01
GR930300039T1 (en) 1993-06-07
JPH05507508A (en) 1993-10-28

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