AU612619B2

AU612619B2 - Water absorbing polymers

Info

Publication number: AU612619B2
Application number: AU11144/88A
Authority: AU
Inventors: David Farrar; Peter Flesher; Malcolm Skinner
Original assignee: Allied Colloids Ltd
Current assignee: Ciba Specialty Chemicals Water Treatments Ltd
Priority date: 1987-01-30
Filing date: 1988-02-01
Publication date: 1991-07-18
Anticipated expiration: 2008-02-01
Also published as: GB8801902D0; AU596055B2; EP0277018A2; EP0277018A3; GB8801903D0; GB2200440A; GB2200440B; EP0277017A3; GB2200133B; EP0277017A2; AU1114588A; GB2200133A; ES2030165T3; DE3869631D1; CA1293351C; EP0277018B1; AU1114488A

Description

COMMONWEALTH O UT~I 0 F A U S T R t L I A PATENT ACT 1952 COMPLETE SPECIFICATION

(ORIGINAL)

FOR OFFICE USE Application Number: Lodged: Complete Specification L~odged: Accepted: Published: Priority: 0~ Related Art-: CLASS INT. CLASS_ g.

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NAME OF APPLICANT: ALLIED COLLOIDS LIMITED ADDRESS OF APPLICANT: NAME(S) OF INVENTOR(S)

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P.O. Box. 38, Low Moor, Bradford, West Yorkshire, BD12 OJZ, England.

David FARRAR Peter FLESHER Malcolm SKINNER DAVIES COLLISON, Patent Attorneys 1 Little Collins Street, Melbourne, 3000.

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COMPLETE SPECIFICATION FOR THE INVENTION ENTITLED: "WATER ABSORBING POLYMERS" The following statement is a full description of this invention# including the best method of pierforming it known to us -1- I 1_ li~~ Allied Colloids Limited 60/2717/02 Water Absorbing Polymers It is well known to absorb aqueous fluids by means of water absorbent particulate polymeric material. In practice the material is always supplied for this purpose as a substantially dry powder that is sufficiently large as to avoid dusting problems. For instance its particle size is typically in the range 75gm up to 3mm.

The polymer can be semi-synthetic and it can be film forming, as in U.S. 3,935,099. Alternatively it can be wholly synthetic and non-film forming, as in EP 195550. In particular there is described in that specification a process in which a wet particulate mass which is not crumbly is converted to a crumbly state by 15 mixing into the mass polymer particles that are substantially non-sticky when swollen with water and ooo* which are non-film forming and which are based on cross linked po.yacrylic acid, optionally blended with acrylamide and other monomers. Although that specification mentioned the use of particles as small as L04m it recommended values above 504m so as to avoid dusting problems, as is conventional.

o We have also observed that, at any particular rate of addition, decreasing5 the particle size below the S 25 typical minimum of around 100gm tends to make the crumbly S• mass less friable. This is probably because the smaller particle size results in a greatly increased number of particles. Although the particles are substantially 0Oo 00 S• non-sticky when several of the swollen polymer particles S 30 contact one another there can be a tendency for them to aggregate. The use of particles as low as 504m or less is therefore generally undesirable, but a tendency with the use of larger particles, 200gm and above, is that their rate of absorption of liquid from the environment can be rather slow and, if such particles 0 0 .000.

so aggregate, then the aggregates are rather large and this can be undesirable.

According to the invention, a wet particulate sticky mass is converted to a crumbly or flowable solid by mixing into the mass water absorbent synthetic polymeor particles that are substantially non-sticky when swollen with water and that are non-film forming, and in this process the particles have an effective dry size within the mass of at least 90% by weight below 504im and the particles are mixed into the mass while the particles are in the form either of internally bonded friable aggregates having a dry size of at least 90% by weight above 50g±m or in the form of a dispersion in water immiscible liquid of particles having a dry size of at least 90% by weight below Thus in one aspect of the invention the polymer is introduced into the sticky mass in the form of a dispersion in water immiscible liquid (3f polymer particles having a dry size below 50ia. it mright have been thought that the incorporation of the water immiscible liquid would be undesirable but this does not seem to be the case and, instead, the liquid serves as a convenient vehicle for introducing the small particles in such a way as to avoid dusting and clustering of the individual particles within the mass. The particles can be mixed into the mass relatively easily so as to obtain uniform distribution of the particles, and they absorb water from the mass very rapidly.

In the second aspect of the invention the particles are introduced as dry powder having a particle size above 504m and which consists of internally bonded aggregates of finer particles having a size of below 504m and often below 304±m. For instance polymer gel fines, as obtained from the comminution of polymer gel or as fines from a reverse phase bead polymerisation process, can be 3> aggregated by swelling with sufficient water to form a comminutable gel, comiminuted to a coarse size and dried by a fluidised bed). These internally bonded aggregates appear to behave initially as coarse particles and then to behave as fines.

Any aqueous solution that permits swelling can be used. Water is usually best. An aqueous solution of a small amount of a soluble polymer or other binder could be used. The comminution can be to >90% by weight above 50gm and usually above l00gm, but generally below 1 or 2mm and often below 500gm. Comminution can be by conventional gel comnminution methods. Drying can be by conventional techniques followed if necessary by se:comminution in conventional manner. The resultant 15 aggregates have a size in the range generally of 50 to 096: 5004m. They can very satisfactorily be used in the invention. The fines within each aggregate typically 0 have a size mainly 5 to 304~m and often below 204m.

By swelling the fines into a conuninutable gel, the resultant dried commxinuted particles appear to be internally bonded. This is in contr-ast to the skin bonding effect that is obtained if fines are merely sprayed with water and immediately dried in a fluid bed.

Skin bonded aggregates can be used in the invention but 25 internally bonded aggregates give better results. They are novel materials. By this means it is possible to achieve the rapid uptake of water and good friability at low doses that is obtained with the use of fine particles V0 00 0 while avoiding the dusting problems and the risk of reduced friability at excess dosages that occurs with fine particles. Particularly good friability can be obtained, without risk of overdosing, using these aggregates. Preferably at least 90% by weight of the aggregates are above 125.im.

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4 The wet particulate sticky mass may be organic, for instance food waste or sewage, but is generally inorganic. It may be, for instance, sand, china clay, crushed mineral, red mud deposits, phosphate slime or coal. The process is of particular value when the particulate sticky mass is environmentally important, toxic or semi-liquid industrial waste, when it is economically important, carbon black or metallurgical suspension such as red mud or copper concentrates. The particulate material can be hydrophilic but is preferably hydrophobic.

The invention is of particular value when the sticky mass is a coal fines filter cake, for instance the sticky mass that results from vacuum filtration by a disc, drum 15 or other vacuum filter of a slurry or froth flotation see: concentrate of coal fines, typically having a particle 0S*@S@ size below 0.5mm. Often the particle size is mainly in range 50 to 3004m, often at least 80% by weight below iOOjim. The ash content of the cake is usually below often below 15%. The cake can be taken direct from the filter or it can be stored for prolonged periods, e.g., as a wet coal fine dump, before treatment in the invention.

The resultant mass is crumbly, as opposed to the S 25 sticky and pasty texture before treatment, and can easily be mixed with coal smalls to form a useful fuel, or used in some other way. Whereas 10% coal fines is often the maximum that can be incorporated by traditional techniques, in the invention the amount of coal fines can 0 30 be increased considerably, to 20% or more.

Typically the crumbly dry coal fines are used as an industrial fuel, in an electricity generating station. Often they are subjected to various treatments, such as blending, pelleting and/or grinding, before being burnt.

The coal fines filter cake or other wet particulate mass generally has a water content in the range 15 to often 20 to 40% and usually around 25 to It is necessary to ensure uniform mixing of the polymer particles into the sticky mass. The mixing generally comprises some degree of back mixing and, in particular, plug mixing should be avoided since it will result in parts of the sticky mass remaining sticky, due to inadequate contact with polymer particles. The mixing can be achieved by tumbling the mass but preferably it is by means of a rotating mixing blade or other mixer that provides adequate shear. Preferably 0:8. the mixing is by a Simon or other double scroll mixer or, preferably a plough share mixer, for instance a Lodige or 15 Morton mixer. A plough share mixer has a substantially foe: horizontal cylindrical container provided with a coaxial rotating shaft that carries a plurality of mixing shovels each generally having the shape of a plough share and mounted to rotate close to the wall of the cylinder.

The peripheral speed and shape of the shovels causes the product to be whirled from the particulate mass in the lower part of the cylinder into the free mixing zone above the mass, so as to obtain high turbulence and both Soforward and back mixing.

S 25 The polymer must not become sufficiently sticky S. during the process to cause permanent aggregation of the particles that are being treated. The polymer preferably is wholly insoluble. If, as is preferred, the polymer is a synthetic polymer then the S: 30 polymerisation conditions and the monomers are preferably such that the content of high molecular weight linear, or soluble, polymer is sufficiently low that during the process the particles do not become sticky.

The polymer may be natural or modified natural polymer such as a starch acrylonitrile graft copolymer or I _1 _1 .I 0

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other modified starch, but preferably it is a synthetic polymer. It may be formed from a monomer blend such that the polymer, in linear form, is swellable but insoluble, for instance as a result of including hydrophobic monomer in the monomer blend. Such polymers can, for instance, be made by oil-in-water emulsion polymerisation. For instance they may be made at a pH at which they are relatively non-swellable and insoluble and the pH may then be adjusted, for use, to a value at which the particles are swellable and absorbent and that is the pH of the wet particulate mass.

Generally however the polymer is made from water soluble monomer or monomer blend. Suitable monomers are generally monoethylenically unsaturated monomers but 15 cross linking agent is preferably included in order to convert the resultant polymer to water insoluble but water swellable form. The cross linking agent can be reacted into the polymer after polymerisation but preferably is present during polymerisation. Generally it is a di-. or other poly- ethylenically unsaturated monomer such as methylene bis acrylamide or any of the other ethylenically unsaturated cross linking agents that are suitable for cross linking absorbent polymer particles. Instead of or in addition to relying on a covalent cross linking agent of this type, cross linking can also be through pendant groups in known manner. For instance it can be by polyvalent metal ions.

When the polymer particles are of cross linked, water swellable but insoluble, synthetic polymer, it is sometimes possible to achieve adequate results using a non-ionic polymer but best results are obtained more reliably using a cationic or anionic polymer. The polymer is made from the appropriate monomer or monomer blend. The monomers are generally acrylic. Preferably 5 to 100%, often 10 to 100% is ionic.

Suitable anionic monomers are ethylenically unsaturated carboxylic or sulphonic monomers such as (meth) acrylic acid, allyl sulphonate or 2-acrylamido methyl propane sulphonic acid. Anionic monomers are generally present as a water soluble salt, usually a sodium salt.

Suitable non-ionic monomers are (meth) acrylamide and (meth) acrylic esters.

Suitable cationic monomers are dialkyl amino alkyl (meth) -acrylate or -acrylamide as free base, acid salt or, preferably, quaternary salt and diallyl dimethyl ammonium chloride. Cationic monomers are generally used as a blend with acrylamide. Anionic monomers may be present as homopolymer or as copolymers of anionic 15 monomer with, preferably, acrylamide.

The polymers can be as described in EP 213799, or cationic versions thereof.

In some instances best results are achieved using S cationic polymer or blends of cationic polymer with anionic polymer, but it is often preferred to use anionic polymer alone. The preferred anionic polymers are cross linked polymers of 5 to 100 mole acrylic acid (as free acid or salt) with 0 to 95 mole acrylamide and optionally 0 to 50 mole other non-ionic or anionic 25 monomer. The acrylic acid is preferably present wholly or mainly, at least 70 or 80% by weight, as sodium acrylate. Suitable polymers are copolymers in which the amount of acrylic acid (as free acid or salt) is S* typically from 20 to 75% by weight, with the balance 30 being acrylamide. It is generally preferred for least by weight of the monomers for the anionic polymer to be sodium acrylate. Typical polymers c this general type are cross linked polymers of 40 to 60% by weight sodium acrylate with 60 to 40% by weight acrylamide when used as dispersions in water immiscible liquid.

8 Particularly preferred swellable polymers for use in the invention are sodium polyacrylate homopolymers, although up to 20% of the sodium acrylate can be replaced by acrylamide. Also some or all of the sodium acrylate groups can be replaced by acrylic acid or by other water soluble salts, generally alkali metal salts.

The degree of swellability and absorption is controlled, in part, by the extent of cross linking and the amount of cross linking agent is usually below 500ppm, often below 300ppm. It is usually at least lOppm or 20ppm and preferably at least 50ppm. Best results are often achieved at around 100 or 200ppm.

These amounts are the amounts by weight of monomer of methylene bis acrylamide and equivalent amounts of other 15 cross linking agents may be used.

The degree of cross linking, and the polymer type, 0* should be such that the gel capacity of the polymer S*(grams deionised water absorbed per gram polymer) is at least 25, generally at least 100 and preferably at least 200 typically up to 500 or even 700 or higher.

In some instances it is desirable for the polymer particles to have a surface layer that is less swellable than the inner parts of the particles. The desired reduced swellability of the surface layer is preferably 25 obtained by cross linking the surface layer. This S* reduces the content of linear polymer at any position where it might cause stickiness and has the advantage of promoting uptake of water and of preventing aggregation *i of the polymer particles. The desired cross linking can 30 be achieved by methods such as those described in U.S.

3,114,651, 3,251,814, 4,043,952, 4,093,013 and 4,090,013, JP 1983/42602 and EP 227305. Other ways of treating the surface are by applying a coating of a counter ionic polymer poly diallyl dimethyl ammonium chloride or other cationic polymer when the swellable polymer is s T- I- I I ;C anionic) or by applying sodium aluminate or other aluminate.

The polymer particles may be introduced as individual particles having the size that is required during the mixing step or they may be introduced as aggregates that we assume break down during the mixing step into smaller particles.

When the particles are introduced into the mixing step in the form of a dispersion in water immiscible liquid, preferably at least 90% of the particles are below about 204m or 304m, and most preferably below 104m.

Fastest results are generally achieved with at least 90 preferably 99%, by weight being below 3gm, in the range 0.03 to 2±m. Often however adequate results are 15 obtained in a cost effective manner, albeit more slowly, *6SS if the particle are 90% between 5 and 504m, about to SWhereas most industrial processes that use dispersions of polymer in water-immiscible liquid require that the amount of polymer should be as high as possible, in the invention we find that best results are achieved when the amount of polymer is relatively low. Thus although the dry weight of polymer can be up to, for instance, 50 or 60% by weight of the dispersion, the dry I.6 S 25 weight of polymer in the dispersion is preferably below S" 45% by weight and preferably below 40%. Generally it is at least 15%, preferably at least 20%. Concentrations of 30 to 40% polymer dry weight based on total dispersion S. SC are often best when the polymer particles are wet and 30 to 30% when the polymer particles are dry.

The water-immiscible liquid may be any organic liquid in which the polymer particles can be adequately dispersed and that will not interfere with the process and so in practice needs to be substantially water immiscible. It can be, for instance, a vegetable oil but is preferably a hydrocarbon or halogenated hydrocarbon liquid. It may be selected from any of the liquids conventionally used in reverse phase dispersions.

For instance it can be kerosene or diesel oil or other mineral oil.

The dispersion can be formed at the point of use, with the polymer particles being dispersed into the water-immiscible liquid and the mixture then being applied substantially immediately to the wet particulate mass. Preferably however the dispersion is preformed, in which event it needs to be substantially stable against settlement.

One form of dispersion is a suspension obtained by *6 dispersing preformed dry polymer particles into 15 water-immiscible liquid in the presence of a dispersion 9*O* e stabiliser. The preformed dry polymer particles can be reverse phase microbeads but preferably they are fines separated from polymer gel, obtained during the comminution of bulk or bead gel or separated from beads J *Sd O obtained by reverse phase polymerisation.

The amount of stabiliser is generally from 1 to often 3 to 10%, by weight based on the dry weight of polymer. Conventional stabilisers for oil based o. dispersions may be used, Bentone clays but S 25 preferably the dispersion is stabilised by stirring into it an aqueous emulsion of an oil soluble or oil swellable polymeric thickener, generally a thickener that is Sinsoluble and non-swellable in water. Suitable S thickeners are described in EP-A-0161926, for instance in 30 Example 7 and at page 11 line 22 to page 12 line Instead of using polymer fines, typically having a size of 10 to 30 or 10 to 40Im, the dispersion can be a reverse phase dispersion made by reverse phase polymerisation of aqueous monomer or monomer blend in water-immiscible liquid. See for instance U.S.

11 4,059,552. The reverse phase polymerisation is preferably conducted as a reverse phase suspension polymerisation. Formation of an initial dispersion of monomer particles can be facilitated by the incorporation of a small amount of water-in-oil emulsifying agent.

Often amphipathic stabiliser is included, in known manner, especially when the dispersion is subsequently azeotroped. Depending upon the degree of agitation when forming the initial dispersion of aqueous monomer in the non-aqueous liquid, and depending upon the amount and type of stabiliser and emulsifier, if present, the dry particle size of the final dispersion can be controlled J and typically has a maximum size of l4m or up to 2 or 34m or lOm at the most. The product of the reverse phase 15 polymerisation can be described as an emulsion. It may be dried, by azectroping to reduce the water content, typically to below 15% by weight of the polymer.

The product is then a substantially dry dispersion.

The amount of amphipathic stabiliser (if present) is generally in the range 0.2 or 0.5 to 10%, and generally below based on the weight of polymer. The amount of water-in-oil emulsifier is preferably from 0.2 to 3%, .a based on weight of monomer.

i In normal processes in which a reverse phase dispersion in oil of water soluble or swellable polymer is mixed into water, it is conventional to conduct the mixing in the presence of an oil-in-water emulsifier so S as to promote distribution of the dispersion and the dispersed polymer into the water. For instance, it is 30 common to add the emulsifier to the polymer dispersion before blending with the water. Because of the apparent need to achieve rapid distribution of the polymer throughout the wet particulate mass, we therefore expected it to be necessary to use such an emulsifier.

We have surprisingly found, in the invention, that better 12 results are achieved in the absence of this emulsifier than when the conventional addition is made. This suggests, surprisingly, that it is desirable to retard the rate at which the polymer particles are made available to, and can take up water from, the wet particulate mass.

Since one purpose of the polymer particles is to absorb water from the wet particulate mass it would be expected that the particles should be as dry as possible at the start of the process. However we have surprisingly found that improved results are achieved when, at the time of addition to the wet particulate mass, the polymer particles in the dispersion contain a substantial amount of water, usually at least 30% based 15 on the dry weight of polymer. Usually the amount is below 150% and typically is in the range 60 to 120%, preferably 80 to 100%, based on the dry weight of polymer.

Preferred compositions comprise 20 to 50% by weight of each of the polymer (dry. weight), water-irmniscible liquid and water. The amount of each of the polymer and the water immiscible liquid is preferably 25 to 45%, ILIGSt **preferably 30 to 40% by weight. The amount of the water is preferably from 20 to 40%, most preferably 25 to 25 Particularly preferred compositions comprise 30 to 40% by weight polymer, 30 to 40% by weight water immiscible liquid and 25 to 35% by weight water, with the amount of .water generally being less than the weight of polymer.

Compositions containing such amounts of water tend :30 to be unstable if the dry particle size is significantly above 10p-m and so the preferred compositions that contain water have a particle size lower than this, preferably below 3gm. They can be made by reverse phase polymerisation (usually by reverse phase suspension polymerisation) to form an emulsion of aqueous polymer 13 gel particles dispersed in the water immiscible liquid, and then the emulsion can be used as such without further drying and without the addition of oil-in-water activator. However for some purposes it appears best to dry the emulsion by azeotroping in conventional manner and then to add water back into the dispersion.

It is very surprising that better results can be achieved using wet polymer particles than dry, both because it would be expected that dry particles would be more effective absorbents and because it has occasionally been suggested in the literature that wet particles initiate absorption quicker than dry particles. However the improved results obtainable in the absence of oil-in-water emulsifier indicate that accelerated 15 absorption is not desirable.

When the polymer particles are large, such that the i swollen polymer particles have a size greater than the size of most or all of the particles being treated, the i swollen polymer particles can subsequently be separated from the dry treated particles. For instance in one process according to the invention at least 50% (dry weight) of the swollen polymer particles have a size greater than the size of at least 95% of the substantially dry treated particles, and these oversize S 25 swollen particles are separated from the dry treated S. particles. Preferably the polymer particles swell to at least twice their dry diameter and substantially all the said swollen polymer particles have a size greater than the size of substantially all the dry treated particles S: 30 and the polymer particles are separated from the dry treated particles. The separation may be by conventional size classification or weight classification techniques, preferably by seiving using a vibrating seive.

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A 2 0 0* When the particles being treated are coal fines, the resultant friable mass is subsequently uised as fuel and as a result of having separated the polymer from the fines the water content of the polymer is not carried in to the fuel and the separated swollen particles can, if desired, be dried by heat exchange from the fuel burner) and can be recycled for further use.

The swellable polymer particles ;ay be mixed with the wet particulate mass without any prior addition of any material to the particulate mass. However improved results can be achieved if the particulate mass that is mixed with the swellable polymer particles has previously been treated with a co-ionic dispersing agent, a counter-ionic coagulant, or a co-ionic, counter-ionic or 15 non-ionic flocculant. For instance the mass may be blended with a solution of the dispersing agent, coagulant or flocculant so as to promote liberation of bound water from the cake, before adding the absorbent polymer particles, In some instances it can be 20 desirable to include the dissolvedagent with the mass at the time of a filtration stage, for producing the mass as a wet filter cake. For instance a slurry or froth concentrate of coal fines can be treated by a coagulant or a flocculant or a combination (usually a coagulant followed by a flocculant) prior to filtration to provide the wet filter cake.

Co-ionic dispersing agent is generally a polymer of low molecular weight, usually below 500,000, generally below 200,000 and often below 50,000. For many 30 processes molecular weights of below 10,000, 2,000 to 5,000, are satisfactory. The dispersing agent is usually anionic. The counter-ionic coagulant generally has a molecular weight of above 50,000, often in the range 100,000 to 1 million, typically about 500,000.

However it can have a higher molecular weight. The flocculant can have molecular weight below 1 million but generally it is above. It can be of several million, and can be of typical flocculant molecular weight.

Although these polymeric agents are usually substantially linear and in true solution, it can be particularly advantageous, when the agent is a higher molecular weight agent such as a flocculant, for it to be in the form of very small particles at the time it is mixed with the wet mass, preferably being a slightly cross linked polymer, as describes in EP 0202780.

The added agents are usually synthetic polymers formed from water soluble ethylenically unsaturated monomers, and these monomers will be chosen to give the polymer the desired ionic characteristic. Generally the 15 agents are formed wholly from ionic monomers or from I blends of ionic monomers with acrylamide or other non-ionic monomers, such as (meth) acrylic esters.

The anionic monomer is preferably acrylic acid but can be any other suitable ethylenically unsaturated monocarboxylic acid or sulphonic acid. It can include or consist of 2-acrylamido-2-methyl propane sulphonic acid, The anionic monomer is generally present as a "f water soluble salt, generally the sodium salt.

Suitable cationic monomers include diallyl dimethyl 25 ammonium chloride and dialkyl amino alkyl (meth) -acrylates or -acrylamides, generally as acid addition or quaternary ammonium salts. For instance the cationic dispersing agent is preferably a low molecular weight polymer of diallyl dimethyl ammonium chloride or dimethyl 30 amino ethyl (meth) acrylate, or a blend of either of these with acrylamide.

When a dispersant or coagulant or other material is being incorporated before the absorbent polymer, it is generally applied as a solution but can be applied in C~c.

solid form if its solubility is such as to permit it to dissolve relatively rapidly within the wet filter cake.

It is often preferred that the particle sizes and the amounts of the absorbent polymer and of the filter cake are such that the number ratio of polymer particles:filter cake particles is approximately 1, e.g., from 3:1 to 1:3. For instance this is achieved by adding about 0.2% (dry on dry) of polymer particles having a particle size of about 20 to 304m to filter cake having a particle size of about 1000m. Larger amounts of these polymer particles are appropriate when the filter cake has a significant electrolyte content.

The amount of polymer that is applied is generally at least 0.005% and is preferably at least 0.05%. It is o 15 usually below preferably below 1% and most preferably 0:000: is around 0.05 to It is a particular advantage of the invention that, despite the unpleasant character of 00480: S* the wet mass, good results can be obtained with very low amounts of polymer, often below 0.3% or 0.4% and often below 0.15% or These amounts are of dry polymer based on dry particles by weight.

The following are some examples. The coal filter cakes used in these examples have a maximum particle size 0 0•0 below 0.5mm and contain generally 20 to 30% water and 0 25 to 15% ash. In the examples values are named as the 0°•°0 S "shear dissociation time" and the "dissociation time".

The "dissociation time" is recorded by putting 600g Sof the coal filter cake in a Hobart mixer bowl, adding S the water absorbent polymer, and stirring at speed 2 .0 0 30 until the product became sufficiently friable that aggregates start being thrown out of the bowl. The time take for this stage to be reached is the dissociation time and should be as low as possible.

After stirring for a further 2 minutes at speed i, the resultant mix is left for 30 minutes in a sealed bag.

17 100 grrams of the mix is put into a cylinder 65mm in diameter and pressed into this cylinder to a disc under a cake-forming pressure of 0.38kg/cm 2 (5.5psi) to give a cake. The cake is placed on a rectangular plate so that the entire cake is within the profile of the plate, but a substantially semicircular portion is cut away from one side of the plate so that about one third of the cake is unsupported. A solid plate is lowered at 12mm/sec on to the top of the cake by a piston and is pressed down on to it with a pressure of 5psi (0.35kg/cm2). The time is measured between the plate touching the top of the cake and the cake shattering over the cut away part of the test plate. This is the shear dissociation time (SDT If the cake shatters immediately upon contact with 15 the lowering plate, the shear dissociation time is recorded as zero. Again, low values are preferred.

The test can be repeated at higher cake-forming pressures of 20 and 50 psi to give SDT 20 and SDT 50 values.

SDT 5 needs to be below 30 seconds for generally satisfactory results and, in particular, if SDT 5 is below about 20 seconds, preferably below about 10 seconds and most preferably below about 7 seconds (especially 'substantially zero) and if the dissociation time is satisfactory, then the polymer cake combination is such S 25 that, with appropriate mixing, homogeneous blendability with coal smalls can be expected. For instance Examples 1 and 2 below show that good results are obtained when SDT 5 is not above 7 and dissociation is not above 18.

For the friable cake to resist caking or clogging 30 during transport, a more friable texture is needed. For this, the SDT test is repeated under a cake-forming pressure of about 20psi (1.4kg/cm 2 to determine SDT or even at about 50psi (3.5kg/cm 2 to determine SDT These values also should be below about 20, preferably i 2 t* o f f *t t ft ft ft.

below about 10, most preferably below about 7 seconds, especially substantially zero.

Example 1 Sodium polyacrylate cross linked with 0.025% methylene bis acrylamide is formed by conventional bulk gel polymerisation and is dried and comminuted in conventional manner. The resultant particles are classified according to size and the fines are retained for use in the invention. They have a dry particle size below 50Mm, mainly in the range 10 to 304m.

The fines are dispersed into an equal weight of a hydrocarbon oil that is thickened with a dispersion stabiliser as described at page 18 lines 25 to 35 of EP 0161926A. 1% oil-in-water emulsifier is included.

15 The dispersion is sprayed on to a wet filter cake of coal fines, this filter cake having been taken from a vacuum filter following froth flotation. The amount of dispersion is 0.1% dry polymer on dry particulate mass.

The product is mixed thoroughly and rapidly became a friable, crumbly solid. This can easily be blended with coal smalls to form a fuel. Without the addition of the dispersion, the filter cake is a wet sticky mass that could not easily be used.

In a comparison, when a similar amount of dry 25 polymer particles of the same polymer but having a size of around l00m, and that are not dispersed in oil, was added to the cake, the cake does not become so crumbly so quickly. With prolonged mixing and larger amounts of polymer 0.2% or even the product is 30 adequately crumbly but swollen polymer particles and aggregates are apparent.

Example 2 Three types of dispersion, each containing equal amounts of polymer and hydrocarbon oil (kerosene or -4, 19 diesel), and oil-in-water emulsifier, are made as follows.

Suspensions by the general technique of Example 1 using particles of the size shown, with >90% by weight <504m when the suspension is shown as <654m RP Emulsions by the reverse phase polymerisation to give a product of about 35% oil, 35% polymer, 30% water RP Dispersions by azeotroping RP Emulsions to about polymer 50% oil The compositions are tested at 0.5% product on wet coal filter cake as above. The monomers used and the results are in the following table, where NaAc sodium acrylate, ACM acrylamide and MBA methylene bis acrylamide (ppm).

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i Ccnposition NaAc CM MBA Dissociation Ex 1 100 0 200 18 7 355-500pm Suspension 50 50 200 82 0 65-180m Suspension 50 50 200 28 0 Suspension 50 50 200 14 O RP Dispersion 50 50 100 50 0 do. 50 50 200 37 O do. 50 50 300 75 0 do. 25 75 25 30 do. 25 75 50 42 11 do. 25 75 100 32 O do. 25 75 200 40 0 RP Emulsion 100 0 100 31 4.2 RP Dispersion 100 0 100 25 14 a..

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It is apparent from this that the overall trend is e that better results are obtained when the size is below 501pm. The disadvantage of too little cross-linking S 25 agent, for the particular mass, is apparent. This is probably due to the polymer containing too much soluble polymer.

Example 3 Tests similar to Example 2 are conducted on RP 30 dispersions of 50% oil and 50% of a copolymer of 50% NaAc ACM 200 ppm MBA with or without added oil-in-water emulsifier, at different amounts of polymer.

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Dispersion Amount Emulsifier Dissociation SDT 0.5% 0 16 O 0.2% 0 25 1.8 3% 23 0 0.2% 3% 37 2.2 The disadvantage of incorporating emulsifier is apparent.

Example 4 Tests similar to Example 2 are conducted on a 50% RP dispersion of a copolymer of 50% NaAc 50% ACM 200 ppm MBA 15 (product A) and the same product after dilution to polymer by red diesel oil Dispersion Polymer Amount Concentration Dissociation SDT 0.5% A 50% 19.4 2.6 0.3% A 50% 30.1 11.0 B 25% 14.8 2.3 0.6% B 25% 22.3 7.9 The benefit of reducing the polymer concentration is apparent.

Example A RP dispersion is formed of 50% oil 50% copolymer of 50% NaAc 50% ACM 200 ppm MBA. This is diluted with various amounts of water and the products are tested on wet coal filter cake as in Example 2 at different dosages of product.

I

S

S.e

S

So 0 0 *0 0 Product Amount Polymer Water Oil Dissociation SDT 0.5% 50 0 50 19 3.4 0.2% 50 0 50 31 0.56% 45 10 45 31 4.8 0.22% 45 10 45 34.6 10.6 0.63% 40 20 40 24.9 3.8 0.25% 40 20 40 31.8 8.9 0.71% 35 30 35 24.1 2.4 0.29% 35 30 35 29.9 14.4 0.83% 30 40 30 22.5 2.9 0.33% 30 40 30 26.8 15 1.0% 25 50 25 22.6 3.9 0.4% 25 50 25 29.7 This clearly shows that the addition of a controlled amount of water gives improved results at low dosages and 20 thus provides a particularly cost effective system.

Example 6 Example 2 is repeated using similar amounts of three different polymer suspensions. ACN is acrylonitrile.

Tests 5, 6 and 7 were conducted with different starch acrylonitrile copolymers dispersions. Tests 8-10 are with 60% dispersions in oil and tests 11 to 13 are with 50% dispersions in oil. Test 14 is with 1% of a emulsion of aqueous polymer particles in oil and test with a 50% dry dispersion of similar, but dry, polymer particles.

7 Test Polymer ppmn MBA Amouic Dissociation

S

)OS

S

e.g.

S

0

*SSOS

C

~0S@e* 4 4.

C S *5 0C 1 100 NaAc 200 2 Superabsorbent Starch 3 30 Starch 70 ACN 4 30 Starch 70 ACN 15 Starch 85 ACN 6 15 Starch 85 ACN 7 15 Starch 85 ACN 8 25 NaAc 75 ACM 100 9 20 NaAc 80 ACM 100 10 NaAc 90 AfCM4 100 11 50 NaAc 50 ACM 200 12 25 NaAc 75 ACM 200 13 100 ACM 200 15 14 50 NaAc 50 ACM 100 15 50 NaAc 50 ACM 100 Example 8 The process of example 2 is by weight RP emulsion in oil polymer formed from 60% ACM acrylate (MeCl quaternary sa Dissociation is 11.7 seconds an using a 1% polymer dosage of a swellable polymer of 50% ACM 5( 0.5% 0.25% 0.25% 0.75% 0.4% 0.4% 0.4% 0.4% 0.4% 0.4% 0.5% 0.5% 0.5% 1% 0.5% 18 22.3 120 33.5 20.9 83.7 23.3 20.3 25.6 29.8 37.6 40.5 39.4 23.0 22.4 SDT 4.6 8.3 3 4.2 0.0 3.4 2.6 2.4 0 0 3.9 2.9 repeated but using a of cationic swellable 40% dimethylaminoethyl it). At 1% dosage, .d SDT 5 is 0.9. When 50% RP dispersion of a D% NaAc (instead of the 25 cationic polymer) Dissociation is 11 and SDT 5 is S 1.2.

Example 9 An aqueous solution of cationic soluble polymer A. B or C is stirred into a wet filter cake of coal fines.

30 After stirring for one minute, a 50% dispersion in oil of cross linked gel polymer particles of acrylamide and sodium acrylate polymer is blended into the filter cake.

The results are as follows, in which polymer A is a low molecular weight diallyl dimethyl ammonium chloride coagulant, polymer B is a high molecular weight, slightly i 24 cross linked, copolymer of 58 mole percent acrylamide and 42 mole percent cationic dialkylaminoalkyl acrylate quaternary monomer, and polymer C is a homopolymer of a cationic dialkylaminoalkyl methacrylate quaternary monomer. In addition to the results shown in the table below, the product was assessed visually and it was significant that increasing amounts of product B, and especially the tests with product C, gave the best visual appearance.

Cationic Dispersion Dissociation SDT Polymer 0.5 18.4 6.7 0.05 A 0.5 19.6 3.1 0.15 A 0.5 17.5 3.6 0 15 1.0 17.5 2.6 0.15 A 1.0 16.9 0 0.3 A 1.0 15.2 1.9 17.5 2.6 B 1.0 12.1 0.16 B 1.0 10.9 0 1.0 17.5 2.6 0.4 C 1.0 8.7 0 *0.8 C 1.0 8.6 0 Example S. 25 Fines having a size mainly 10-304m are separated from comminuted cross linked polyacrylic acid (75% as sodium salt) gel having a gel capacity well in excess of 25g/g. They are labelled A. Part of them are mixed with sufficient water to make a comminutable gel which is 30 then comminuted and dried on a fluid bed drier, in conventional manner, to a particle size >1254m but below 500gm. This is labelled B. Each product is mixed with coal filter cake as in Example 1 at various doses.

T- il- Product Product Dissociation SDT 5 SDT 20 SDT Dose Time (sec) A 0.25 13.1 2.7 30+ 9.9 1.3 4.7 0.75 8.3 0.7 2.9 7.9 0.9 2,9

B

0.25 0.75 23.2 14.8 13.1 12.5 1.5 0 0 0 2.0 0 0 3.6 2.1 0 5 5S Sr S r 45 a S This demonstrates that the agglomerates give improved results at higher dosages but give similar results at lower dosages.

As a comparison products A, B and C are formed from ACM 50% NaAc cross linked swellable polymer having gel capacity above 25g/g. A is a dispersion in oil of particles <40nm. B is powder <634m and C >125pm.

Different amounts are blended as in Example 1. The results are as follows.

.5 Si S

S

*5 0 S S *5 -2 1; I

F

i Product Active Dissociation SDT 5 SDT 20 SDT Dose Tine (sec) 5 A <40pm 0.15 0.25 0.5 0.75 15.6 12.5 9.8 8.1 7.4 5.9 6 B <63pu 0.15 20.8 0.25 12.2 2.7 0.5 8.9 1.2 3.1 0.75 8.2 0 3.5 1.0 7.2 0 3.8 6.6 0 3.9 C >125mn 0.15 25.4 0.25 15.7 1.0 5.6 10.9 0 0 0.75 9.5 0 0 0.8 1.0 9.3 0 0 0.8 7.5 0 O O Iu Example 11

IS

S I

IS

6 Polyacrylic acid (about 75% in sodium form) gel cross linked with about 200ppm MBA is formed, comminuted and dried in conventional manner. Fines having a size 30 mainly in the range 10 to 404m are separated and dispersed at 50% solids in kerosene or diesel using an emulsion of stabilising polymer (as in EP-A-0161926, Example 7) as stabiliser.

The resultant dispersion is diluted to about solids with further kerosene or diesel and sprayed at 27 about 0.2% polymer on to coal filter cake having a coal size mainly 50 to 1504m and a moisture content around and an ash content of around 10% as the cake is fed into a continuously moving Lodige Plough Share mixer.

The mix passes through the mixer in not more than about 2 minutes and emerges as a friable product that can easily be crumbled between the fingers (the SDT 5 for the wet filter cake-polymer combination is below The friable product is blended with about 5 times its own weight of coal smalls having a size of 1 to and the mix is pulverised and carried, entrained in air from the pulverisers, as a fuel into the coibustion chamber of a power station boiler. There is no evidence of clogging of the pulverisers or other parts of the 15 apparatus through which the product travels from the mixer to the boiler.

The blend, before pulverisation, may flow evenly ovt e of a Durham Cone at that is uniform and is about 1.4kg/sec, whereas the untreated cake clogs or flows unevenly at about half that rate.

Example 12 S.A wet cake of particulate magnetite having 14.6% moisture content is blended with a dispersion in oil of swellable, cross-linked polymer fines having a particle 25 size below 40pm. The amount of dispersion is 0.25% by B* A weight polymer based on wet magnetite. When the polymer is formed from 50% ACM 50% NaAc, dissociation time 7 seconds, SDT 5 0 and SDT 20 30. When Lhe polymer is formed of neutralised polyacrylic acid, dissociation time 30 8.2 seconds, SDT 5 5.7 and SDT 20 I

Claims

1. A process in which a wet pariculate sticky mass is converted to a crumbly or flowable solid by mixing into the mass water absorbent synthetic polymer particles that are substantially non-Sticky when swollen with water and that are non-film forming, characterised in that the particles have an effective dry size within the mixture of at least 90% below 504m and are mixed into the mass while the particles are in the form either of internally bonded friable aggregates of above 50g.m in size formed of particles below 504±m in size, or of a dispersion in water immiscible liquid of particles below 5O04m in size.

2. A process according to claim 1 in which the polymer is a cross linked polymer formed from anionic or cationic ethylenically unsaturated monomer optionaly mixed with non-ionic monomer and has gel capacity of at least

3. A process according to claim 1 or claim 2 in which the polymer is a cross linked polymer of 80 to 100% acrylic acid sodium salt and 0 to 20% acrylamide.

4. A process according to any preceding claim in which the surface of the polymer particles is preferentially cross linked.

A process according to any preceding claim in which the polymer particles have at least 90% by weight below 504im and are added to the sticky mass in the form of a dispersion in water immiscible liquid.

6. A process according to any preceding claim in which the particles have at least 90% by weight below 504.m and are added to the mass while present as a dispersion in water immiscible liquid of particles below 504m in size.

7. A process according to claim 6 in which the dispersion is a dispersion of fines obtained from polymer gel.

8. A process according to claim 7 in which the dispersion is stabilised against settlement as a result 9 0**9 *900 0 00000

9. 0 0 *0 00 0 S OS S t a 25 b 1 h t 30 s I t s m 29 of the incorporation into the dispersion of an oil swellable or oil soluble polymeric thickener. 9. A process according to claim 6 in which at least by weight of the polymer particles have a dry size below 10m and the dispersion has been obtained by reverse phase polymerisation.

A process according to any of claims 6 to 9 in which at least 90% by weight of the particles have a dry size below 10m and a dispersion contains at least 30% by weight water.

11. A process according to claim 10 in which the dispersion is made by reverse phase polymerisation and comprises 25 to 45% by weight of the polymer particles, 25 to 45% by weight water and 25 to 45% by weight water ooo 15 immiscible liquid. o.

12. A process according to any of claims 6 to 11 in which the dispersion is substantially free of oil-in-water emulsifier.

13. A process according to any of claims 5 to 11 in 0 20 which the mixing is by a double scroll or plough share mixer.

14. A process according to any of claims 1 to 4 in which the particles are introduced as internally bonded •o aggregates having 90% by weight above 1254m of particles t 25 below 40gm in size. o .0

15. A process according to claim 14 in which SDT 20, as herein defined, is below

16. A process according to any preceding claim in which the mixing is conducted by a double scroll or plough share mixer.

"17. A process according to any preceding claim in which the wet particulate mass is selected from toxic wastes, semi-liquid industrial wastes, carbon black, metallurgical suspensions and coal filter cakes.

18. A process according to any preceding claim in which the particulate polymeric material, its amount and the particulate mass are such that SDT 5, as defined herein, is below 20 and dissociation, as defined herein is below

19. A process according to claim 18 in which the polymer particles have at least 90% by weight below 50gm and are added in the form of a dispersion in water-immiscible liquid.

20. A process according to claim 1 substantially as herein described with reference to the Examples.

21. The steps, features, compositions and compounds referred to or indicated in the specification and/or claims of this application, individually or collectively, and any and all combinations of any two or more of said steps or features. Dated this 23rd day of March 1988 20 ALLIED COLLOIDS LIMITED By its Patent Attorneys DAVIES COLLISON