AU602398B2 - Initiating system for firing a detanator - Google Patents

Initiating system for firing a detanator Download PDF

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Publication number
AU602398B2
AU602398B2 AU15199/88A AU1519988A AU602398B2 AU 602398 B2 AU602398 B2 AU 602398B2 AU 15199/88 A AU15199/88 A AU 15199/88A AU 1519988 A AU1519988 A AU 1519988A AU 602398 B2 AU602398 B2 AU 602398B2
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AU
Australia
Prior art keywords
energy
capacitor
light
detonator
light signal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU15199/88A
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AU1519988A (en
Inventor
Jacques Lafond
James Robert Simon
Donald Clinton True
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CXA Ltd
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CXA Ltd
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Filing date
Publication date
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Publication of AU1519988A publication Critical patent/AU1519988A/en
Application granted granted Critical
Publication of AU602398B2 publication Critical patent/AU602398B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42DBLASTING
    • F42D1/00Blasting methods or apparatus, e.g. loading or tamping
    • F42D1/04Arrangements for ignition
    • F42D1/045Arrangements for electric ignition
    • F42D1/05Electric circuits for blasting

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Air Bags (AREA)
  • Geophysics And Detection Of Objects (AREA)

Description

Ref: CIL.73O P/00/011 .4 AUSTRLI l Form PATENTS ACT 1952-1973 Class: Int. Cl, COMPLETE SPECIFICATION
(ORIGINAL)
FOR OFFICE USE 6 028 This document contains the amendments made under Section 49 and is correct for printing.
Application Number: Lodged., Complete Specification-Lodged: Accepted: Published: Priority: Related Art: it
I
Name of Applicant* Address of Applicant: Actual Inventor: TO BE COMPLETED BY APPLICANT CXA LTD/CXA LTEE 630 Dorchester Blvd. West, Montreal Quebec
CANADA
James Robert SIMON Donald Clinton TRUE Jacques LAFOND Industrial Property Section ICI Australia Operations Proprietary Limited 1 Nicholson Street GPO Box 4311 MELBOURNE 3001, Victoria Australia Address for Service; Co ecification for the invention entitled: "INITIATING SYSTEM lzbe f ing atemrent is a full description of this invention, including the best method of performing it known *Notl scription Is to be typed in double spacing, pica type face, In an area not exceeding 250 mm In depth and 160 mm In width, on tough white paper of good quality and It is to be Inserted inside this form, 117 10/76-L C. Tiio0isos. Commonweilth Government rinter, Canberrit '4 S eiboure I 'O:±The Commissioner of Patents FEE SrANP TO YAii; OF S MAIL OFFICER! I C-I-L 730 -1- BACKGROUND OF INVENTION 1. Field of the Invention The present invention relates to an initiating system for providing firing energy to a detonator used in blasting with explosives. More specifically, the invention relates to such a system wherein light energy is converted to electrical energy for the firing of a detonator.
2. Description of Prior Art The mining and construction industries are very aware of the hazards involved in the use of electric detonators for 00 blasting in conductive underground ore bodies where the o"o:o detonators are susceptible to accidental initiation by stray o currents created by high voltage electrical equipment. It is 0 0 o 9o 15 also known that electric detonators are prone to initiation o by electrostatic discharges generated by explosive loading 0 equipment or by lightening strikes in conductive ore deposits which produce high voltage transients at the working face.
o00 In surface blasting applications at construction sites, o *a 20 for example, hazards are likely to arise when blasting is S0 0o 0 a conducted with electric detonators in relatively close proximity to radio or radar transmitting antennas. The American National Standards Institute has established safe distances of blasting operations from fixed radio frequency 25 transmitting antennas, but there is little control over mobile transmitters which frequently transmit with power levels well in excess of the legal limit of 5 watts.
Although mobile transmitters per se are banned from blasting sites, there is little control over vehicles transmitting from nearby public roads.
The hazards arising from static discharges, electrical storms, ground currents, electric power generators, transmission lines, rf antennas or electromagnetic fields generated by other means are all additive. At some blasting locations, complex situations may arise which make it C-I-L 730 -2necessary to call in expert technical assistance to determine whether a hazard exists. This results in additional expense and delays for the mine operator or blasting contractor.
Over the past several years, many mines and quarries have converted to the use of non-electric blasting systems in order to avoid the hazards of electric initiated detonators previously described. Typically, a non-electric blasting system employs a shock wave conductor as the initiator means for a detonator. A shock wave conductor or shock tube comprises a hollow, non-conductive plastic tube with a thin layer of explosive dust deposited on its inner surface. When Sao* a o initiated at one end by detonating cord or similar shock o o producing device, a shock front propagates along and within o 15 the length of the tube to initiate a detonator attached at 0 o the opposite end.
oIn a typical shock tube blast, the boreholes to be o o loaded with explosives are each primed with a delay detonator having a specified delay time and to which a length of shock S20 tube is attached. The ends of the tubing extending from each 0o0 Soo borehole are connected to a common detonating cord trunkline 00 0 by means of connectors. A blasting round hooked up in this manner is completely non-electric and non-conductive and is 00Ie therefore safe from any inadvertent electrical initiation.
To initiate a blast which uses shock tube and non-electric detonators and a detonating cord trunkline, it has been common practice to set off the detonating cord by means of an attached electric detonator. As a safe practice, some larger mines are evacuated, and the blasting of multiple faces located throughout the mine is controlled electrically by a central blasting station on surface. The introduction of an electric detonator to initiate the trunkline however, defeats the safety advantages gained through the use of the shock tube system. For this reason, many mining managers have elected not to use fully electric central blasting systems and have been searching for alternate methods to I lsx~ C-I-L 730 -3improve the safety of their operation.
In some operations the shock tube and associated trunkline is initiated by tying a safety fuse assembly to the detonating cord. The safety fuse assembly comprises a factory-assembled length of safety fuse with a detonator crimped to one end and an igniter cord connector as a means of lighting the fuse at the opposite end. To this fuse assembly, a short length of igniter cord is attached which is, in turn, connected to an HFE electric starter. The HFE electric starter requires an ignition current of 3 amps and is ten times less sensitive than conventional electric S: detonators. Although this make-shift system improves the o safety somewhat, it tends to be cumbersome, is sometimes on: prone to failure by virtue of the various manual connections oo 15 required and can still be readily initiated by simple electrical means. The use of safety fuse is also declining for safety reasons. As a result of a number of recent mining fatalities involving the misuse of safety fuse, several S9 jurisdictions are considering legislation banning its use.
Other blasting operations make use of exploding bridge wire (EBW) detonators in extremely hazardous locations.
These specialized detonators are safe by virtue of the fact that they do not contain a sensitive primary explosive and require in excess of 2000 volts from a specially designed power supply to achieve initiation. Apart from being g expensive, they are limited to relatively short lead-in wires and are not suitable for multipoint initiation from a centralized blasting location.
Most recently some blasting operations are employing a transformer coupled system in conjunction with centralized blasting. Transformer coupled systems are electric detonators with sliding, insulated toroidal transformers attached to the end of the detonator lead wires. This provides protection from stray currents and most electrical interference. They are however limited to the use of !1 C-I-L 730 -4relatively short firing circuit wires.
There is, therefore, a continuing need for an initiatiog system for blasting which retains the reliability of conventional electric systems but which reduces or substantially eliminates the hazards associated therewith.
SUMMARY OF INVENTION It is an object of the invention to provide an initiating system which overcomes substantially all of the disadvantages of the prior art.
It is a more specific object of the invention to provide an initiating system for providing firing energy and an activating signal to a detonator, comprising: means for generating light energy; means for receiving said light energy and converting tO said light energy to electrical energy; means isolated from said light energy generating o means for generating, receiving and identifying a coded light signal; means to store said electrical energy when a correct coded light signal is identified; and 4 means to transfer the said stored energy to a resistor element of a detonator; whereby said generated, light energy is converted to electrical energy and transferred to said detonator resistor element, said transferred electrical energy comprising said firing energy. Thus, a generated, coded light signal is converted to electrical energy, stored until a sufficient firing energy level is reached and then transferred to a detonator, then transferred electrical energy comprising energy required to initiate the detonator.
A particular feature of the system of the invention is its ability to recognize only a specific or coded light signal for utilisation as the primary energy source for the ultimate firing of the detonator. This is accomplished by providing a C-I-L 730 4(a) pulsed on/off electrical signal simultaneously to a first light source, for example, a lightbulb, and a second light source, for example, a light emitting diode (LED) causing both the lightbulb and the LED to be illuminated. The light from the lightbulb is converted to electrical energy by a photovoltaic cell and the light signal from the LED is transmitted to a photodetector. When the LED is ON, the photodetector is also ON. This provides a trigger
CO
0 0 F4004 0o 4410 C-I-L 730 mechanism which allows energy from the photovoltaic cell to be charged into a storage condenser. Unless both the lightbulb and LED are tuned to the frequency of the ON/OFF pulsed electric signal, charging of the condenser is prevented and hence no electrical energy is available to initiate the detonator. Thus, the energy for initiation of the detonator is initially supplied by a light source such as a filament bulb, laser, laser diode, LED diode or via an optical fibre. This light energy is converted into electrical energy by means of a photovoltaic cell or photo diode. The low voltage from the photovoltaic cell is amplified and charged in an electronic circuit and delivered Sa to a capacitor for storage. The amplifying and charging circuit is adapted to function only if a suitably encoded I 0 0 15 enabling light signal is received.
BRIEF DESCRIPTION OF THE DRAWINGS 9 B Figure 1 is a block diagram of the initiating system of the invention; O* Figure 2 is a circuit schematic of the photo-coupled o o 20 firing unit of Figure 1; and SFigure 3 is a circuit schematic of the firing control 0000 S° unit of Figure 1.
DECRIPTION OF PREFERRED EMBODIMENTS Referring to Figure 1 where the initiating system is S\ 25 generally depicted, three separate components designated 1, 2 S and 3 are shown. Component 1, labelled the "Firing Control Unit", comprises a power supply 5 with associated oscillator 6 and power output 7. A pulsed electrical signal is delivered from the control unit 1 through switch 101 via conductors 4 and rectifier bridge 8 to component 2 which is the "Photo-Coupled Firing Circuit". Conductors 4 provide power for a first light source 9 and a second light source The first light source 9 can comprise a lightbulb for generating light energy. The -;econd light source 15 may comprise, for example, a light emitting diode (LED) for C-I-L 730 -6optical coupling and control purposes as will be discussed below.
Component 2 comprises a firing arrangement including a means 11 for processing the electrical energy, a means 12 for stoLing the electrical energy, and a firing circuit 13.
Attached to the input of the means for processing electrical energy is a means for receiving light energy and converting it to electrical energy, comprising, for example, a photovoltaic cell 10 and a light detector 16 which may comprise a photodiode. Photovoltaic cell 10 is positioned to receive pulsating light energy from the lightbulb 9 and the light detector 16 is positioned to receive a pulsating light signal from the light source Component 3, labelled "Disposable Device" comprises the initiation unit itself and consists of a squib 17, a shock wave conductor lead-in line 18 and a detonator 19. The squib 17, which provides firing energy for the detonator 19, is adapted for plug-in connection with firing circuit 13 of component 2.
Referring to Figure 2, pulsed electrical signal carried by conductors 4 is delivered to light bulb 9 and LED 15. The light energy generated by lightbulb 9 is received by the means for receiving the light energy and converting it to electrical energy. In the illustrated embodiment, this comprises the solar cell 10. The light energy from LED 15 is received by photodiode 16. Thus, solar cell 10 is disposed to receive light from lamp 9, and photodiode 16 is disposed to receive light from LED The switching power supply generally designed 11 for processing the converted electrical energy comprises an inductor 24 and transistor 30 in conjunction with photovoltaic cell 10 and light detector 16. Means 11 also includes a security circuit which rejects low frequencies and discharges capacitor 12 in the event of interruption or absence of the correct coded signal. The security circuit C-I-L 730 -7includes diodes 65 and 66, capacitor 31, resistors 32, 33 and 34 and inverters 28 and 29. The means for storing the process electrical energy comprises a capacitor 12. A diode is shown between inductor 24 and capacitor 12.
The firing or triggering circuit generally designated 13 comprises zener diode 37 connected to a high current solid state switch such as a power mos field effect transistor Connected between the zener diode 37 and the field effect transistor 45 are transistors 40 and 39. Resistors are shown at 38, 41, 42, 43 and 44.
In operation, when the positive going portion of the so 0 pulse train is applied to the lightbulb 9 and the LED 0,o 0 11 both the lightbulb and the LED will be illuminated. Light 4o00 energy, generated by the lightbulb 9, will be transmitted to a a o o: 15 the solar cell 10, and the light signal, generated by the LED o4 o 0 a 15, will be transmitted to the photodector 16. The light energy, received by the solar cell 10, is converted to electrical energy by solar cell 10. When LED 15 is ON, and a oas photodetector 16 is also ON, transistor 30 is turned ON.
Accordingly there is a low impedance discharge path for the solar cell 10 through the inductor, so that the electrical
S
c energy is stored in the inductor when LED 15 is turned ON.
When the zero level or negative going portion of the pulse train is applied to the lightbulb 9 and LED 15, both of these light sources are turned OFF. Accordingly, no further light energy is transmitted to the solar cell 10, and photodetector 16 is turned OFF. With photodetector 16 turned OFF, transistor 30 is turned OFF. The energy stored in the inductor is released as a voltage spike in the order of 10 to 15 volts which charges the capacitor 12 through the diode A portion of the chargiog energy will also be applied to the capacitor 31 through diodes 65 and 66.
Although a voltage spike of 10 to 15 volts is produced, the capacitor will not charge up to that voltage level.
Instead, several cycles will be required for the capacitor 12 r l
.L
I axas.rr~ a; arra~~ *V 0 0 00 00 0 A 0b 00 0Jb 0 0 *0 ot t 0 0 0
I
C-I-L 730 -8to charge up to the level of 9 volts. In one specific example, approximately seven seconds were needed to charge a 260 microfarad capacitor at a frequency of 3 KHz and a duty cycle of 90% on time and 10% off time.
When capacitor 12 is charged to a level of 9 volts, zener diode 37 is turned ON so that current can flow through the resistor 41. The resulting voltage drop across resistor 41 will provide a signal to the transistor 40 which in conjuntion with transistor 39, provides an amplified signal to turn on the high current solid state switch 45. The current from capacitor 12 is then allowed to flow through the ignition resistor 68. A small portion of this current will also flow through shunt resistor 67.
It can be seen that the zener diode 37 senses when the 15 capacitor 12 has reached the firing voltage, whereupon it provides a path for current from the capacitor 12 to ignite the squib 17 (Fig. Detonator 19 is ignited by energy carried from electrically-ignited squib 17 by means of a shock wave conductor 18.
The system as above described operates only within a given range of frequencies and duty cycles. If the frequency is too low, then capacitor 31 will not charge up.
Accordingly, inverter 29 will provide a low impedance discharge path for capacitor 12. The upper frequency of operation is limited by both the frequency response of the photodetector 16 and the time constant of the inductor circuit.
The pulsating light source must have the correct duty cycle at the correct frequency in order to activate the charging circuit for capacitor 12. The duty cycle is defined as the percentage of time in each cycle during which the light remains ON. A minimum on time and a minimum off time is required to store the energy in the inductor and rTelease it.
Thus, the system is "coded". Specifically, unless the 4__ ~Uur~~irrra~~~^-i C C-I-L 730 -9right type of signal is provided to the lightbulb 9 and the LED 15, firing energy will not be provided to the ignition resistor.
The requirement that several cycles are needed to drive the voltage on capacitor 12 up to the firing voltge is an advantage in safety in that a waiting period is provided during which time the circuit can be deactivated by removal of the "coded" signal.
Transistors 40 and 39 are provided for speeding up the firing of the field effect transistor The system will not be set off by stray fields or by o randomly transmitted radio waves. The energy from the light o o generator is coupled optically to the firing circuit so that e it will not be affected by such stray fields or randomly o o 15 transmitted radio waves.
Referring to Figure 3, the firing control unit comprises a means for generating a pulse train. In the embodiment shown, the means for generating a pulse train comprises an astable multivibrator 6 whose output is fed to the base of a 20 transistor 48. The output of the transistor 48 is fed to rectifier bridge 8 (Fig. 2) whose output drives both the o lightbulb 9 and the light source 15. The frequency and duty cycle of the pulse generator are determined by the selected values of capacitor 50, resistor 54 and resistor 61.
Although not specifically depicted, a further useful feature of the invention is the addition of current regulation to the photo-coupled firing unit identified as 2 in Figure i. This feature improves power distribution in large centralized blasting operations by permitting initiation of explosive charges at many blasting locations which are separated from each other by long lengths of initiating wire. The device typically draws 100 milliamps and can operate on standard wire sizes up to distances of five miles.
Although not specifically depicted, a still further C-I-L 730 useful feature of the invention is the addition of a "firing signal" to the said coded signal. This feature provides the advantage of accurate timing of multiple blast holes and can be used to initiate a large number of detonators simultaneously or provide synchronization for electronic timing counters which counters can introduce discrete time delays between blast holes. The means for coding the optical signal need not be limited to electrical means but may include, for example, the use of different wave lengths which can be decoded through difraction or other electronic means.
It is envisioned that miniaturization techniques may allow the Photo-Coupled Firing Circuit and the Disposable o9~g Device to be combined into a single integrated device. Such 0 a device might be enclosed for example, within the confines o:0 15 of a specially adapted detonator.
Although a particular embodiment has been described, 0 0~a this was for the purpose of illustrating, but not limiting, the invention. The two light sources and two light receivers described in the preferred embodiment can be replaced with oo 20 one light source and one receiver if, for example, the energy requir ments of the system are low or if higher efficiency 0:00 light emitters and receivers are employed.
Various modifications or component substitutions such as LASER diodes or commercially available opto-isolators, which i 25 will come readily to the mind of one skilled in the art, are i within the scope of the invention as defined in the appended claims.

Claims (6)

1. An initiating system for providing firing energy and an a' tivating signal to a detonator, comprising: means for generating light energy; means for receiving said light energy and converting said light energy to electrical energy; means isolated from said light energy generating means for generating, receiving and identifying a coded light signal; means to store said electrical energy when a correct coded light signal is identified; and means to transfer the said stored energy to a resistor element of a detonator; whereby said generated light energy is converted to electrical energy and transferred to said detonator resistor element, said Stransferred electrical energy comprising said firing energy.
2. A system as claimed in claim 1 wherein said means for generating light energy comprises a lightbulb and wherein said means for receiving said light energy and converting it to electrical energy comprises a solar cell. aa4 3. A system as claimed in claim I wherein said means for o generating, receiving and identifying a coded light signal comprises a light emitting diode (LED) and a photodiode. S A system as claimed in Claim 1I wherein said coded light signal is provided by a pulse generator which operates said light signal ON and OFF periodically at a predetermined frequency and duty cycle. A system as claimed in Claim 1 further including a means comprising, in circuit arrangement, an inouctor connected in series with said means for converting light energy to Selectrical energy; and -n~ CI, i; i C-I-L 730 12 said means to store electrical energy comprising a capacitor connected in series with said inductor; whereby when the said coded light signal generating means is ON, energy is stored in said inductor, and, when said coded light signal generating means is OFF, said energy stored in said inductor is transferred to said capacitor.
6. A system as claimed in Claim 5 further including means for sensing the level of said stored energy in the said capacitor which means comprises a zener diode connected across said capacitor whereby, when the voltage across said capacitor reaches a predetermined level, said zener diode is turned ON.
7. A system as claimed in. Claim 6 further including means for transferring said energy stored in said capacitor to said detonator resistor element, said means for transferring comprising a high current solid state switch connected in circuit to be triggered by said zener diode when said zener diode is turned ON.
8. A system as claimed in Claim 5 further including a security circuit adapted to reject low frequencies and to discharge the said storage capacitor in the event of interrupted or improperly coded light signals, the said security circuit comprising a second capacitor and an inverter, adapted to receive a charge from said inductor, and to discharge said storage capacitor through a resistor.
9. A system as claimed in Claim 5 further including means to regulate the current delivered to the said coded light signal generating means. C-I-L 730 -13- An initiating system according to any one of claims 1 to 9 substantially as herein described with reference to the drawings. Dated this 7' day of 8 8988. CXA LTD/CXA LTEE By Its Patent Attorney John 7 Davy Jo
AU15199/88A 1988-02-25 1988-04-27 Initiating system for firing a detanator Ceased AU602398B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA000559861A CA1326068C (en) 1988-02-25 1988-02-25 Detonator firing system
CA559861 1988-02-25

Publications (2)

Publication Number Publication Date
AU1519988A AU1519988A (en) 1989-09-21
AU602398B2 true AU602398B2 (en) 1990-10-11

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AU15199/88A Ceased AU602398B2 (en) 1988-02-25 1988-04-27 Initiating system for firing a detanator

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AU (1) AU602398B2 (en)
BR (1) BR8900823A (en)
CA (1) CA1326068C (en)
GB (1) GB2216349A (en)
SE (1) SE8900515L (en)
ZA (1) ZA889661B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AUPO906897A0 (en) 1997-09-09 1997-10-02 F F Seeley Nominees Pty Ltd Improvements in actuators
PE20060926A1 (en) 2004-11-02 2006-09-04 Orica Explosives Tech Pty Ltd ASSEMBLIES OF WIRELESS DETONATORS, CORRESPONDING BLASTING APPLIANCES AND BLASTING METHODS
US9476685B2 (en) 2012-01-13 2016-10-25 Los Alamos National Security, Llc Detonation control
US10246982B2 (en) 2013-07-15 2019-04-02 Triad National Security, Llc Casings for use in a system for fracturing rock within a bore
US10294767B2 (en) 2013-07-15 2019-05-21 Triad National Security, Llc Fluid transport systems for use in a downhole explosive fracturing system
WO2015009753A1 (en) 2013-07-15 2015-01-22 Los Alamos National Security, Llc Multi-stage geologic fracturing
CN110375599B (en) * 2019-07-16 2024-07-02 广西中爆电子科技有限公司 Anti-radio-frequency interference circuit for electronic detonator
PL244611B1 (en) * 2022-04-15 2024-02-12 Wojskowy Inst Techniki Inzynieryjnej Im Profesora Jozefa Kosackiego Electronic circuit for the solar igniter

Citations (3)

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EP0003396A1 (en) * 1978-02-01 1979-08-08 Imperial Chemical Industries Plc Control circuit for energizing an electrically ignited load
EP0123593A1 (en) * 1983-04-07 1984-10-31 SEAT BOURGES Société Anonyme Projectile with electrical ignition and weapon for launching it
EP0174115A2 (en) * 1984-09-04 1986-03-12 Imperial Chemical Industries Plc Method and apparatus for safer remotely controlled firing of ignition elements

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4091734A (en) * 1977-02-22 1978-05-30 The United States Of America As Represented By The Secretary Of The Navy Aircraft to weapon fuze communication link
US4089268A (en) * 1977-03-30 1978-05-16 The United States Of America As Represented By The United States Department Of Energy Safe arming system for two-explosive munitions
DE3138073A1 (en) * 1981-09-24 1983-04-14 Siemens AG, 1000 Berlin und 8000 München ARRANGEMENT FOR TRANSMITTING MEASURED VALUES TO A REMOTE SITE

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0003396A1 (en) * 1978-02-01 1979-08-08 Imperial Chemical Industries Plc Control circuit for energizing an electrically ignited load
EP0123593A1 (en) * 1983-04-07 1984-10-31 SEAT BOURGES Société Anonyme Projectile with electrical ignition and weapon for launching it
EP0174115A2 (en) * 1984-09-04 1986-03-12 Imperial Chemical Industries Plc Method and apparatus for safer remotely controlled firing of ignition elements

Also Published As

Publication number Publication date
ZA889661B (en) 1989-10-25
GB8904269D0 (en) 1989-04-12
BR8900823A (en) 1989-10-17
AU1519988A (en) 1989-09-21
GB2216349A (en) 1989-10-04
SE8900515L (en) 1989-08-26
SE8900515D0 (en) 1989-02-15
CA1326068C (en) 1994-01-11

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