AU5674594A - Alpha crystalline modification of 2,2',2"-nitrilo(triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1, 1'-biphenyl-2,2'-diyl)phosphite) - Google Patents
Alpha crystalline modification of 2,2',2"-nitrilo(triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1, 1'-biphenyl-2,2'-diyl)phosphite)Info
- Publication number
- AU5674594A AU5674594A AU56745/94A AU5674594A AU5674594A AU 5674594 A AU5674594 A AU 5674594A AU 56745/94 A AU56745/94 A AU 56745/94A AU 5674594 A AU5674594 A AU 5674594A AU 5674594 A AU5674594 A AU 5674594A
- Authority
- AU
- Australia
- Prior art keywords
- nitrilo
- diyl
- phosphite
- triethyl
- biphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000004048 modification Effects 0.000 title abstract 2
- 238000012986 modification Methods 0.000 title abstract 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 title 1
- 239000002904 solvent Substances 0.000 abstract 2
- YAGPRJYCDKGWJR-UHFFFAOYSA-N 2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxy-n,n-bis[2-(2,4,8,10-tetratert-butylbenzo[d][1,3,2]benzodioxaphosphepin-6-yl)oxyethyl]ethanamine Chemical compound O1C2=C(C(C)(C)C)C=C(C(C)(C)C)C=C2C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP1OCCN(CCOP1OC2=C(C=C(C=C2C=2C=C(C=C(C=2O1)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C)CCOP(OC1=C(C=C(C=C11)C(C)(C)C)C(C)(C)C)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C YAGPRJYCDKGWJR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- -1 polypropylene Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
The alpha crystalline modification of 2,2',2''-nitrilo[triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl)phosphite] is obtained by crystallizing said compound from selected solvents, preferably from a mixture of an aromatic hydrocarbon solvent and a lower alkanol. The alpha crystalline form is an effective process stabilizer for polyolefins, particularly polypropylene.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/983,180 US5334739A (en) | 1992-11-30 | 1992-11-30 | Process an alpha monoclinic crystalline modification of 2,2',2"-nitrilo[triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl)phosphite] |
US983180 | 1992-11-30 | ||
PCT/US1993/011327 WO1994012509A1 (en) | 1992-11-30 | 1993-11-22 | Alpha crystalline modification of 2,2',2'-nitrilo[triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl)phosphite] |
Publications (2)
Publication Number | Publication Date |
---|---|
AU5674594A true AU5674594A (en) | 1994-06-22 |
AU686124B2 AU686124B2 (en) | 1998-02-05 |
Family
ID=25529826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU56745/94A Ceased AU686124B2 (en) | 1992-11-30 | 1993-11-22 | Alpha crystalline modification of 2,2',2"-nitrilo(triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1, 1'-biphenyl-2,2'-diyl)phosphite) |
Country Status (16)
Country | Link |
---|---|
US (2) | US5334739A (en) |
EP (1) | EP0670843B1 (en) |
JP (1) | JPH08503948A (en) |
AT (1) | ATE149173T1 (en) |
AU (1) | AU686124B2 (en) |
BR (1) | BR9307546A (en) |
CA (1) | CA2148926A1 (en) |
CZ (1) | CZ137595A3 (en) |
DE (1) | DE69308319T2 (en) |
ES (1) | ES2100672T3 (en) |
MX (1) | MX9307467A (en) |
RU (1) | RU2114856C1 (en) |
SK (1) | SK280212B6 (en) |
TW (1) | TW294670B (en) |
WO (1) | WO1994012509A1 (en) |
ZA (1) | ZA938893B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU687839B2 (en) * | 1993-08-18 | 1998-03-05 | Ciba Specialty Chemicals Holding Inc. | Gamma crystalline modification of 2,2',2"-nitrilo(triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1, 1'-biphenyl-2,2'-diyl)phosphite) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0710677A3 (en) * | 1994-11-03 | 1998-02-04 | Ciba SC Holding AG | Process for producing stabilized olefin polymers |
US5486641A (en) * | 1995-02-28 | 1996-01-23 | Ciba-Geigy Corporation | Solvent-free process for the preparation of the beta crystalline modification of 2,2',2"-nitrilo[triethyl-tris-(3,3',5,5',-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphite] |
US5489636A (en) * | 1995-05-03 | 1996-02-06 | Ciba-Geigy Corporation | Amorphous modification of 1,1',1"-nitrilo(tri-2-propyl-tris-[2,2'-ethylidene-bis(4,6-di-tert-butylphenyl] phosphite) |
IT1277583B1 (en) * | 1995-09-14 | 1997-11-11 | Great Lakes Chemical Italia | CRYSTALLINE FORM OF TETRAKIS-(2,4-DI-T-BUTYLPHENYL)-4,4'- BIFENYLENE DIPHOSPHONITE |
EP0771814A1 (en) * | 1995-11-02 | 1997-05-07 | Ciba SC Holding AG | Amorphous and crystalline modifications of 1,1',1"-nitrilo triethyl-tris[2,2'-methylene-bis(4,6-di-tert-butyl-phenyl)]phosphite |
US5624983A (en) * | 1995-11-02 | 1997-04-29 | Ciba-Geigy Corporation | Amorphous modification of 1,1',1"-nitrilo(triethyl-tris-[2,2'-methylene-bis(4,6-di-tert-butylphenyl)] phosphite) |
GB2311526A (en) * | 1996-03-28 | 1997-10-01 | Ciba Geigy Ag | Polyolefins containing catalyst residues and stabilised with trialkanolamine triphosphites |
US5763512A (en) * | 1996-03-29 | 1998-06-09 | Ciba Specialty Chemicals Corporation | Stabilization of polyamide, polyester and polyketone |
DE19624425A1 (en) * | 1996-06-19 | 1998-01-08 | Hoechst Ag | Process for the preparation of 2,2 ', 2 "-Nitrilo (triethyl-tris (3,3', 5,5'-tetra-tert-butyl-1,1'-biphenyl-2,2'-diyl) phosphite " |
DE19624424A1 (en) * | 1996-06-19 | 1998-01-08 | Hoechst Ag | Process for the preparation of the alpha-kirstall modification of the 2,2 ', 2 "-nitrilo (triethyl-tris (3,3', 5,5'-tetra-tert-butyl-1,1'-biphenyl-2, 2'-diyl) phosphite) " |
CN1147717C (en) | 1998-09-16 | 2004-04-28 | 布劳恩有限公司 | Method for determining tmep. radiation thermometer with several infrared sensor elements |
DE10115222A1 (en) * | 2001-03-28 | 2002-10-10 | Clariant Gmbh | High molecular weight polyvinylbutyral, for production of laminated safety glass, comprises use of benzofuran and/or at least one derivative as crosslinking agent |
JP6170059B2 (en) * | 2011-10-31 | 2017-07-26 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | Prevention of crystallization solvents in the production of polyphosphite ligands |
WO2018012573A1 (en) * | 2016-07-15 | 2018-01-18 | 住友化学株式会社 | Method for producing crystal of uracil compound |
JP2018100254A (en) | 2016-07-15 | 2018-06-28 | 住友化学株式会社 | Method for producing crystal of uracil compound |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2940548A1 (en) * | 1979-10-06 | 1981-04-16 | Hoechst Ag, 6000 Frankfurt | CRYSTALLIZED TRIS (2-TERT.-BUTYLPHENYL) PHOSPHITE AND METHOD FOR THE PRODUCTION THEREOF |
US4318845A (en) * | 1980-11-24 | 1982-03-09 | Ciba-Geigy Corporation | Alkanolamine esters of 1,1'-biphenyl-2,2'-diyl-and alkylidene-1,1'-biphenyl-2,2'-diyl-cyclic phosphites |
US4374219A (en) * | 1980-11-24 | 1983-02-15 | Ciba-Geigy Corporation | Alkanolamine ester of 1,1-biphenyl-2,2-diyl-and alkylidene-1,1-biphenyl-2,2-diyl-cyclic phosphites |
-
1992
- 1992-11-30 US US07/983,180 patent/US5334739A/en not_active Expired - Lifetime
-
1993
- 1993-11-12 US US08/152,106 patent/US5512621A/en not_active Expired - Lifetime
- 1993-11-22 CA CA002148926A patent/CA2148926A1/en not_active Abandoned
- 1993-11-22 SK SK717-95A patent/SK280212B6/en unknown
- 1993-11-22 AU AU56745/94A patent/AU686124B2/en not_active Ceased
- 1993-11-22 EP EP94902345A patent/EP0670843B1/en not_active Expired - Lifetime
- 1993-11-22 RU RU95113872A patent/RU2114856C1/en active
- 1993-11-22 WO PCT/US1993/011327 patent/WO1994012509A1/en not_active Application Discontinuation
- 1993-11-22 DE DE69308319T patent/DE69308319T2/en not_active Expired - Fee Related
- 1993-11-22 AT AT94902345T patent/ATE149173T1/en not_active IP Right Cessation
- 1993-11-22 ES ES94902345T patent/ES2100672T3/en not_active Expired - Lifetime
- 1993-11-22 CZ CZ951375A patent/CZ137595A3/en unknown
- 1993-11-22 JP JP6513309A patent/JPH08503948A/en active Pending
- 1993-11-22 BR BR9307546-4A patent/BR9307546A/en not_active Application Discontinuation
- 1993-11-27 TW TW082110009A patent/TW294670B/zh active
- 1993-11-29 ZA ZA938893A patent/ZA938893B/en unknown
- 1993-11-29 MX MX9307467A patent/MX9307467A/en not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU687839B2 (en) * | 1993-08-18 | 1998-03-05 | Ciba Specialty Chemicals Holding Inc. | Gamma crystalline modification of 2,2',2"-nitrilo(triethyl-tris-(3,3',5,5'-tetra-tert-butyl-1, 1'-biphenyl-2,2'-diyl)phosphite) |
Also Published As
Publication number | Publication date |
---|---|
WO1994012509A1 (en) | 1994-06-09 |
EP0670843B1 (en) | 1997-02-26 |
CA2148926A1 (en) | 1994-06-09 |
ZA938893B (en) | 1994-06-01 |
SK280212B6 (en) | 1999-10-08 |
RU2114856C1 (en) | 1998-07-10 |
BR9307546A (en) | 1999-08-31 |
SK71795A3 (en) | 1995-09-13 |
MX9307467A (en) | 1994-05-31 |
DE69308319D1 (en) | 1997-04-03 |
TW294670B (en) | 1997-01-01 |
CZ137595A3 (en) | 1995-10-18 |
DE69308319T2 (en) | 1997-10-09 |
US5512621A (en) | 1996-04-30 |
ATE149173T1 (en) | 1997-03-15 |
JPH08503948A (en) | 1996-04-30 |
US5334739A (en) | 1994-08-02 |
EP0670843A1 (en) | 1995-09-13 |
ES2100672T3 (en) | 1997-06-16 |
RU95113872A (en) | 1997-06-20 |
AU686124B2 (en) | 1998-02-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |