AU5179401A - Method of reducing syneresis in aqueous compositions - Google Patents

Description

AUSTRALIA

PATENTS ACT 1990 COMPLETE SPECIFICATION NAME OF APPLICANT(S): Rohm and Haas Company ADDRESS FOR SERVICE: DAVIES COLLISON CAVE Patent Attorneys 1 Little Collins Street, Melbourne, 3000.

INVENTION TITLE: Method of reducing syneresis in aqueous compositions The following statement is a full description of performing it known to me/us:of this invention, including the best method Document received on: 0 7 JUN 2001 Batch No: The present invention relates to a method of reducing syneresis in certain aqueous compositions while, at the same time, increasing the viscosity efficiency of the aqueous system. The method of this invention is particularly applicable to aqueous compositions which contain latex polymers and thickening agents.

Since aqueous based compositions were first introduced, additives have been sought to increase the viscosity and to maintain the viscosity at desired levels under various processing conditions and end use situations. These additives are commonly referred to as "thickening agents" or "thickeners". Thickeners are used in latex paints for viscosity improvement and control as well as for protective colloidal action and for the improvement of pigment suspension, leveling and flow.

In addition, the additives often emulsify, disperse and stabilize latex ingredients. In latex paints and textile treating compositions, thickeners often improve the "sticking" or binding properties of the overall composition. Thickeners are commonly used in the cosmetic industry as thixotropic agents and to improve softening, sizing and handling properties. As additives to paper coating compositions, thickeners improve thickening under high shear conditions.

Thickeners are likewise useful for the foregoing and other properties in oil well drilling and flooding fluids, fire-fighting foams and fluids, detergents, leather pastes and finishes, adhesives, pharmaceuticals, agricultural formulations and emulsions of all types.

:Among the many well-known thickeners are natural products such as the alginates, casein, gum karaya, locust bean gum and gum tragacanth, and modified 000003 natural products such as the cellulosics, including methyl cellulose, hydroxyethyl °•oo cellulose and hydroxypropyl cellulose.

Many synthetic thickeners are also available, such as carboxy vinyl ether copolymers, acrylic polymers and maleic anhydride styrene copolymers. One of the most significant classes of synthetic thickeners available today are comprised of urethane polymers. More specifically, these polymers contain hydrophobic moieties attached to a poly-ethylene oxide backbone. The various polymeric chains are linked together via urethane linkages. This class of thickeners is often referred to as HEUR modifiers, which stands for "hydrophobically modified ethylene oxide urethane". The hydrophobic groups are positioned on the ends of the polymeric chain and together contain at least 20 carbon atoms. Since each end of the polymer chain contains a hydrophobic group, these modifiers are referred to as "diphobes".

The polymeric backbone is comprised of hydrophilic polyether segments. Such HEUR modifiers are described in detail in U.S. Patent Nos. 4,079,028 and 4,426,485.

The HEUR thickeners are referred to as "associative thickeners" because the mechanism by which they thicken involves forming hydrophobic associations between the hydrophobic moieties in the thickener molecules and other hydrophobic surfaces, including other thickener molecules, pigments or latex particles. It is this interaction with latex particles that is the focus of this invention.

Certain formulations containing HEUR modifiers may cause bridging between the latex particles, which, in turn, leads to flocculation or "syneresis" of the aqueous latex system. Syneresis is the separation of a liquid from a gel, and manifests itself as an exudation or "squeezing out" of diluent from a separate phase.

Obviously, such separation is unacceptable when found in aqueous latex paint formulations. However, attempting to solve this problem by removing or reducing the amount of HEUR modifiers results in an unacceptable drop in the viscosity of the formulation. Specifically, an unacceptable drop in mid-shear (Krebs-Stormer) S: 20 viscosity results, measured as a drop in KU, or "Krebs Units".

0 The present invention solves the problem of syneresis in aqueous latex 0V0 00 formulations. Surprisingly, the method of the present invention also results in an increase in the KU efficiency. KU efficiency is defined herein as a measure of the "0"0 amount of thickener required to achieve a target viscosity. That is, the greater the amount of thickener required to reach a specified viscosity, the lower the KU efficiency. Achieving greater KU efficiency while, at the same time, reducing or 000.0 eliminating syneresis often involves employing solutions from two diametrically opposed process parameters. To achieve both objectives through a single process s biab 0000 .step is both surprising and contra-indicated based on the known art.

0.00 STATEMENT OF THE INVENTION The invention is directed toward a method of reducing syneresis and increasing the viscosity efficiency in aqueous compositions which contains urethane based, or "HEUR", thickeners by adding to the composition a high molecular weight monophobe or a monophobe in combination with a multiphobe. The monophobe contains at least one hydrophilic segment and only one hydrophobic segment. The hydrophobe segment will ideally have a carbon content of more than 12, and preferably in the range of 12 to 18. The monophobes of the invention may be nonionic, anionic, cationic or amphoteric. The Mn (number average molecular weight) of the monophobe hydrophilic segment is at least 2,000, and preferably greater than 5,000, up to 10,000.

The monophobe may optionally contain multiphobe molecules of various chain lengths or molecular weights. A multiphobe is a molecule containing at least one hydrophilic segment and at least two hydrophobic segments. The multiphobe is preferably a diphobe (2 hydrophobic segments). The Mn of the diphobe hydrophilic segment is less than twice the Mn of the monophobe. The hydrophobicity of the diphobe hydrophobic segment is sufficient to form non-specific hydrophobic associations. Preferably, the diphobe hydrophobic segments each contain a hydrocarbon moiety having at least 8 carbon atoms or its equivalent.

20 In order to achieve the dual objectives of increasing the viscosity efficiency and reducing syneresis, it has been discovered that the multiphobe may be combined with the monophobe. Up to 66% of the total weight of the monophobe plus multiphobe may be multiphobe. If multiphobe is added in excess of this amount, the KU efficiency increases but syneresis is very likely to result.

The monophobe or monophobe-multiphobe mixtures of the invention are added to the aqueous composition as a function of the amount of HEUR thickener present therein. The mixtures of the invention are added in an amount of at least 1% by weight of the HEUR thickener. Preferably, this amount is 2-50% and most preferably, 10-30%.

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EXAMPLES

Various formulations of paint were prepared to verify the beneficial effects provided by the present invention. A standard pigmentless paint was prepared as follows.

MATERIAL AMOUNT by volume) Tamol 681 4.13 Nuosept 95 (Creanova, Inc.) 0.22 Foamaster AP (Henkel Corp.) 0.55 Propylene Glycol 4.34 Aqueous Ammonia 0.14 Texanol (Texaco Corp.) 5.54 Triton GR-7M 0.25 Rhoplex HG -74P (Rohm and Haas) 82.67 Water 2.17 100% The HEUR rheology modifier, RM2020NPR, available from the Rohm and 20 Haas Company, Philadelphia, PA, was also used.

SPreparation of diphobe: hydrophilic segment pEO (average Mn 8,600) hydrophobic segment C18 moiety Four hundred fifty grams of toluene and 258g (0.03 moles) of poly(ethylene glycol) (average Mn of -8,600) were charged to a flask, then stirred and heated to azeotropically remove residual water via a Dean Stark trap. The kettle temperature was reduced to 900 C, and 17.73 g (0.06 moles) of octadecyl isocyanate was added, followed by 0.2 g of dibutyltin dilaurate catalyst. After stirring at 900 C for 1 hour, the reaction was complete.

the reaction was complete.

Preparation of monophobe: hydrophilic segment pEO (average Mn 10,000) Three hundred grams of toluene and 300 g (0.03 moles) of poly(ethylene glycol) monomethyl ether (average Mn -10,000) were charged to a flask, then stirred and heated to azeotropically remove water via a Dean Stark trap. The kettle temperature was reduced to 900 C, and 8.02 g (0.03 moles) of hexadecyl isocyanate was added, followed by 0.2 g of dibutyltin dilaurate catalyst. After stirring at 900 C for 1 hour, the reaction was complete.

The results of adding 20% aqueous solutions of the monophobe and/or diphobe to 150 grams of the pigmentless paint are shown in Table 1.

TABLE 1 Experiment Syneresis Number RM2020 monophobe diphobe KU Inhibited? Standard 5g Og Og 93 No Control 6.5g Og Og 100 No 1 5g 1.5g Og 102 Yes 20 2 5g Og 1.5g >144 No* .o.o S 3 5g 1.2g 0.3g 114 Yes 4 5g 1.Og 0.5g 120 Yes 5g 0.75g 0.

7 5 g 135 Yes 6 5g 0.5g 1.0g >144 Yes 7 5g 0.3g 1.2g >144 No Comparative 5g 1.5g@ Og 82 No Syneresis was worse than expected commercial surfactant Triton X-405 (octyl phenol hydrophobe and @1800 Mw polyethylene oxide polymer backbone) The use of a common surfactant in the Comparative Example reflects the well recognized practice of using such materials to counteract the undesired effects of syneresis. It is apparent from the above results that the use of the surfactant, in the same amount as the monophobe, significantly lowered thickener efficiency (lower KU) and also failed to inhibit syneresis. However, since the monophobe and Triton X-405 are regarded as nonionic surfactants, it is surprising, in view of the failure of the commercial surfactant, that the monophobe would both increase thickener efficiency and inhibit syneresis.

The reference to any prior art in this specification is not, and should not be taken as, an acknowledgement or any form of suggestion that that prior art forms part of the common general knowledge in Australia.

Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" and "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.

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Claims (11)

1. In an aqueous composition containing thickeners, a method of reducing syneresis and increasing the viscosity efficiency in said composition comprising adding to said composition a high molecular weight monophobe, said monophobe comprising at least one hydrophilic segment and only one hydrophobic segment.

2. The method of claim 1 wherein the thickeners are hydrophobically modified ethylene oxide based urethane rheology modifiers.

3. The method of claim 1 wherein the number average molecular weight (Mn) of the monophobe hydrophilic segment is at least 2,000.

4. The method of claim 3 wherein the Mn of the monophobe hydrophilic segment is 5,000 to 10,000. The method of claim 1 further comprising a multiphobe.

6. The method of claim 5 wherein the multiphobe is a diphobe.

7. The method of claim 6 wherein up to 66% of the weight of the monophobe and diphobe comprises the diphobe.

8. The method of claim 7 wherein the Mw of the diphobe hydrophilic segment is less than twice the Mn of the monophobe hydrophilic segment.

9. The method of claim 1 wherein the viscosity efficiency is defined by an increase in KU units. 20 10. The method of claim 1 wherein the composition contains a latex polymer. *.25 8

11. A method of reducing syneresis substantially as hereinbefore described with reference to the Examples.

12. An aqueous composition containing thickener which has been treated by the method of any one of the preceding claims.

13. The steps, features, compositions and compounds disclosed herein or referred to or indicated in the specification and/or claims of this application, individually or collectively, and any and all combinations of any two or more of said steps or features. DATED this SEVENTH day of JUNE 2001 *fl. Rohm and Haas Company by DAVIES COLLISON CAVE ":Patent Attorneys for the applicant(s)