AU4763193A - Powder coating composition with hydroxyalkylamide crosslinker - Google Patents
Powder coating composition with hydroxyalkylamide crosslinkerInfo
- Publication number
- AU4763193A AU4763193A AU47631/93A AU4763193A AU4763193A AU 4763193 A AU4763193 A AU 4763193A AU 47631/93 A AU47631/93 A AU 47631/93A AU 4763193 A AU4763193 A AU 4763193A AU 4763193 A AU4763193 A AU 4763193A
- Authority
- AU
- Australia
- Prior art keywords
- compound
- functionality
- hydroxyalkylamide
- powder coating
- crosslinker
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Description
POWDER COATING COMPOSITION WITH HYDROXYALKYLAMIDE CROSSLINKER
The invention relates to a powder coating compostion comprising as a binder a polymer with free carboxylic acid groups and as a crosslinker a compound containing β-hydroxyalkylamide groups. A powder coating comprising a co-reactable mixture of an amorphous carboxylic acid group containing polyester and a β-hydroxyalkylamide is known from EP-A- 322834. The composition described in this application is cured - after application to a substrate - by heating the powder to 160-200°C so that the powder melts, forming a smooth layer. At that temperature the coating is chemically crosslinked due to an esterification reaction between the acid groups of the polymer and the hydroxy groups of the compound containing β-hydroxyalkylamide groups. According to EP-A-322834, a de-gasifying agent, benzoin (0.5 to 3% by wt. of the powder composition), may be added to the composition. A de-gasifying agent is needed to ensure that the air and/or water entrapped due to melting of the powder (during a curing cycle) are removed from the paint layer as a result of the reaction. Any gas bubbles that remain in the coating reduce the adhesion of the coating to the substrate and markedly adversely affect the protection obtainable with the coating. Although coatings of this composition are characterized in EP-A-322834 as having good physical properties, such compositions are unsuitable for preparing a white or crystal-clear coating because the powder coating exhibits some degree of browning after curing, as indicated in Mercurio, New Perspective on Hydroxyamide Crosslinkers, 16th International Conf. in Org. Sci. and Tech. 235-49 (Athens, Greece 1990).
Also, browning appears to intensify upon heating
the cured powder coating at a temperature of 200°C for a prolonged period of time (for example between 30 and 60 minutes). This discolouration upon excessive curing (yellowing on overbake) increases with the amount of benzoin. A lower amount of benzoin, on the other hand, results in a lower blister limit, such as lower than 60 μm, which results in surface defects.
The object of the invention is to provide a powder coating composition in which it is possible to use a small amount of benzoin, for example between 0.05 and 0.8 wt.%, to obtain the highest possible blister limit, for example higher than 120 μm. Of course, the powder coatings must also retain good mechanical properties, such as, for example, good gloss, toughness and impact resistance and chemical properties such as for example a good chemical resistance.
The invention is characterized in that the crosslinker comprises a combination of at least two compounds containing β-hydroxyalkylamide groups and each compound having different β-hydroxylalkylamide functionalities, the first compound having a β-hydroxy¬ alkylamide functionality of . 3 and the second compound having a β-hydroxyalkylamide functionality of . 3.
The functionality stands for the average number of β-hydroxyalkylamide groups per molecule.
As a result, powder coatings are obtained in which the blister limit has been raised considerably while the desired mechanical and chemical properties are retained. Suitable compounds containing β- hydroxyalkylamide groups and having a functionality of ≥ 3 can be depicted structurally according to formula (I):
where:
- A represents a mono- or polyvalent organic group derived from a saturated or unsaturated alkyl group with 1-60 carbon atoms (for example ethyl, methyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, eicosyl, triacontyl, tetracontyl, pentacontyl and hexacontyl); an aryl group, such as for example phenyl, naphthyl; a trialkylene amino group with 1-4 carbon atoms per alkylene group, for example trimethylene amino and triethylene amino; or an unsaturated residue with one or more alkenic groups ( -C=C- ) with 1-4 carbon atoms, such as, for example, ethenyl, 1-methyl ethenyl, 3-butenyl-l,3- diyl and 2-propenyl-l,2-diyl , carboxy-alkenyl group, for example 3-carboxy-2-propenyl group, an alkoxy carbonyl- alkenyl group with 1-4 carbon atoms, such as, for example, 3-methoxy carbonyl-2-propenyl group;
- R1 represents hydrogen, an alkyl group with 1- 5 carbon atoms (for example methyl, ethyl, n-propyl, n-butyl, sec. butyl, tert. butyl and pentyl) or a hydroxy- alkyl group with 1-5 carbon atoms (for example 2-hydroxy- ethyl, 3-hydroxypropyl, 2-hydroxypropyl, 4-hydroxybutyl, 3-hydroxybutyl, 2-hydroxy-2-methylpropyl, or the hydroxy derivatives of the pentyl isomers);
- R2 and R3 are the same or different and each independently represents hydrogen or a straight or branched alkyl group with 1-5 carbon atoms, while one of the groups R2 and one of the groups R3 may also form, together with the adjacent carbon atoms, a cycloalkyl group, such as, for example, cyclopentyl and cyclohexyl; R2 and R3 may also be hydroxyalkyl groups, such as, for example, hydroxy (C1-C5)-alkyl groups, hydroxymethyl and 1-hydroxyethyl, being preferred among the latter and
- the β-hydroxyalkylamide functionality is ≥ 3. Preferably, the functionality is 4. According to a further preferred embodiment of the invention in formula (I):
A is an alkyl group with (1-10) carbon atoms, R1 represents 2-hydroxyethyl or hydrogen, and R2 and R3 are independent of one another hydrogen
or hydroxy ( Ci-Cj J-alkyl .
Preferably, the first compound having a β- hydroxyalkylamide functionality of ≥ 3 is a compound according to formula (II):
HO-H2C-H2C 0 0 CH2-CH2-OH \ II )i / N-C-(CH2)4-C-N (II)
HO-H2C-H2C CH2-CH2-OH
Very suitable compounds having a β-hydroxyalkyl¬ amide functionality of ≤ 3 are compounds according to formula (I) having a β-hydroxyalkylamide functionality of . 3 or compounds according to formula (III):
wherein formula (III) A represents a monovalent group as defined for formula (I), where R1, R2 and R3 also have the same meaning as in formula (I), and where m = 1 or 2.
According to a further preferred embodiment of the invention in formula (I):
A is an alkyl group with (1-10) carbon atoms, R1 represents 2-hydroxyethyl or hydrogen, and
R2 and R3 are independent of one another hydrogen or hydroxy (C1_C2)-alkyl.
Preferably, the second compound having a β- hydroxyalkylamide functionality of r. 3 is a compound according to formula (IV):
(IV)
Preferably, the functionality of the second compound having a functionality of ≤ 3 according to formula (I) is 2.
Compounds according to formula (V) are also very suitable as compounds having a functionality of _ 3:
0 CH2 - CH2 - OH H - C - N (V)
CH2 - CH2 - OH
The weight ratio in the crosslinker between is preferably between 90:10 and 10:90 and more preferably between 80:20 and 20:80. This ratio depends on the functionality of the polymer with free carboxylic groups.
Usually the average functionality of the polymer is between 1.7 and 4.5 and preferably between 2.3 and 3.5.
The weight ratio of the crosslinker to the polymer is usually between 10:90 and 3:97, more preferably between 20:80 and 3:97.
The acid number of the polymer containing carboxyl groups is preferably between about 15 and about 150 mg KOH/gram resin, in particular is between about 20 and about 70 mg KOH/gram resin.
The glass transition temperature, Tg, is preferably between about 30°C and about 80°C and in particular ranges between about 35°C and about 65°C.
The viscosity at 165°C (Emila, D = 17.6 s-1) is preferably between about 100 and about 1000 dPas and in particular ranges between about 100 and about 800 dPas.
Said parameters influencing powder coating properties and the determination of these parameters is decribed at pages 175-199 and 284-300 of Powder Coatings, Chemistry and Technology by Misev (Wiley and Sons, 1991).
Preferably, the polymer that contains carboxyl groups is a polyester and/or a polyacrylate.
Examples of preferred monomers for polyacrylates that can be incorporated in the main chain of the polymer are unsaturated monocarboxylic acids, such as, for example, acrylic acid, methacrylic acid and crotonic acid, unsaturated dicarboxylic acids, such as, for example, maleic acid, 2-methyl maleic acid, itaconic acid, and
α-β-methylene glutaric acid, unsaturated anhydrides, such as, for example, maleic anhydride, itaconic anhydride, acrylic anhydride and methacrylic anhydride. The polymer usually also consists of copolymerized esters of (meth)acrylic acid, such as, for example, methyl methacrylate, butyl acrylate, 2-ethyl hexyl acrylate or acrylonitrile, styrene and other ethylenically unsaturated compounds.
Suitable polyesters can be obtained via standard preparation methods from essentially aromatic poly- carboxylic acids, such as, for example, phthalic acid, isophthalic acid, terephthalic acid, pyromellitic acid, trimellitic acid, 3,6-dichloro phthalic acid, tetrachloro phthalic acid, or, if obtainable, the anhydrides, acid chlorides or lower alkyl esters thereof. Usually the carboxylic acid component is composed at least of 50% by weight, preferably at least 70 mol %, of isophthalic acid and/or terephthalic acid. Exemplary procedures are described in said reference of Misev at pages 144-162. The polycarboxylic acids used can also be cyclo- aliphatic and/or acyclic polycarboxylic acids such as, for example, tetrahydro phthalic acid, hexahydro-endomethylene terephthalic acid, hexachloro tetrahydrophthalic acid, azelaic acid, sebacic acid, decane dicarboxylic acid, dimer fatty acid, adipic acid, succinic acid and maleic acid, in amounts of up to not more than 30 mol%, preferably up to not more than 20 mol%, of the total of carboxylic acids. Hydroxy-carboxylic acids and/or, optionally, lactones such as, for example, 12-hydroxy- stearic acid, ε-caprolactone and the hydroxypivalic acid ester of neopentyl glycol can also be used. In minor amounts, monocarboxylic acids such as, for example, benzoic acid, tert-butylbenzoic acid, hexahydro benzoic acid and saturated aliphatic monocarboxylic acids can also be added during the polyester preparation.
Furthermore, especially suitable in the polyester preparation are aliphatic diols such as, for example, ethylene glycol, 1,2-propanediol, 1,3-propane-
diol, 1,2-butanediol, 1,4-butanediol, 1,3-butanediol, 2,2- dimethyl-l,3-propanediol (= neopentyl glycol), 2,5- hexanediol, 1,6-hexanediol, 2,2-[bis(4-hydroxycyclo- hexyl)]propane, 1,4-dimethylol cyclohexane, diethylene glycol, dipropylene glycol and 2,2-bis[4-(2-hydroxy- ethoxy) ]phenylpropane and smaller amounts of polyols such as glycerol, hexanetriol, pentaerythritol, sorbitol, trimethylol ethane, trimethylol propane and tris(2- hydroxyethyl)isocyanurate can be used. Preferably, the alcohol component contains at least 50 mol% of neopentyl glycol and/or propylene glycol.
Additional suitable compounds for reacting with polycarboxylic acids include monoepoxides such as, for example, ethylene oxide, propylene oxide, monocarboxylic acid glycidyl ester (for example Cardura E10™; Shell) or phenyl glycidyl ether.
The polyesters are prepared, using methods known per se, by esterification or transesterification, optionally in the presence of customary catalysts such as, for example, dibutyl tin oxide or tetrabutyl titanate, a suitable choice of the preparation conditions and of the COOH/OH ratio yielding end products with an acid number between 15 and 150.
Compounds according to formula (I), (II), (III) and (IV) and methods for making them, are described in, amongst others: US-A-4727111, US-A-4788255 and EP-A- 322834. The complete disclosures are incorporated herein by reference.
The preparation and testing of the powder coating can take place in a customary manner, for example as described in Misev, Powder Coatings; Chemistry and Technology (Wiley and Sons, 1991) pp. 225-226.
If desired, the powder coating can also contain mixtures of polyesters and polyacrylates. Furthermore, other resins, such as, for example, an epoxy resin, can also be included in the powder coating composition.
Of course, all the standard additives such as, for example, pigments, fillers, flow-promoting agents,
stabilizers and catalysts can be added to the coating systems.
Suitable pigments include, for example, inorganic pigments such as titanium dioxide, zinc sulphide, iron oxide and chromium oxide, and organic pigments such as azo compounds.
Suitable fillers include, for example, metal oxides, silicates, carbonates and sulphates.
Compositions according to the invention can be used as coating agents for metal, wood and plastic substrates. Examples are general-purpose industrial top coats, top coats on machinery and equipment, in particular top coats on metal, for example for tins, domestic and other small equipment, cars and the like. The invention will be elucidated with the following, non-restrictive examples and comparative example.
Example I
The preparation of a powder coating based on a combination of a two- and a four-functional β-hvdroxy- alkylamide
In an extruder (Werner & Pfleider, ZSK 30) 570.5 parts by weight of a carboxyl-functional polyester resin (Uralac P845PM; DSM Resins B.V. ) with an acid number of 35 mg KOH/g were mixed at 130°C with 20.5 parts by weight of Primid XL 552™ (compound according to formula (II); Rohm & Haas), with 9 parts by weight of n-acetyl diethanol amine (compound according to formula (IV)), with 300 parts by weight of titanium dioxide (Kronos CL 310™), with 9 parts by weight of flow-promoting agent (Resiflow PV-5™, Worlee), and with 2.5 parts by weight of benzoin.
After cooling, the extrudate was subjected to granulation and fine grinding to a particle size of 90 μm.
Example II
The preparation of a powder coating based on a two- and a four-functional β-hvdroxyalkylamide
Example I was repeated, use being made of the listed ingredients in the following amounts by weight (Table I).
TABLE I
parts by weight
Uralac P845™ 571
Primid XL 552™ 15 n-acetyl diethanol amine 14
Ti02 300
Resiflow PV-5™ 9
Benzoin 2.5
Comparative example A
The preparation of a powder coating based on a four-functional β-hvdroxyalkylamide
The procedure of Example 1 was repeated, to make powder coatings from the ingredients listed in the following table A in the indicated amounts by weight. No acetyl diethanol amine was added.
TABLE A
parts by weight
Uralac P845™ 570
Primid XL 552™ 30
Ti02 300
Resiflow PV-5™ 9
Benzoin 2.5
The powder coatings according to Examples I, II and Comparative Example A were electrostatically applied to steel panels and cured, during 15 minutes, at 180°C.
The blister limit was determined via electromagnetic induction (see the already cited Misev, Powder Coatings, pp. 295-296).
TABLE II
Example blister limit in μm
I 120
II 140 A 105
In I, II and A the reverse impact strength (160 inchpound), the acetone resistance (more than 100 rubs full curing), the flow (good, visually determined) and the gloss were good.
The powder coating compositions according to the present invention having the specified combinations of β- hydroxyalkylamides at a constant amount of benzoin yielded coatings having a desirable higher blister limit. The coatings obtained using the powder coating compositions according to the present invention also retained the desired mechanical properties.
Claims (12)
1. Powder coating composition comprising as a binder a polymer with free carboxylic acid groups and as a crosslinker a compound containing β-hydroxyalkylamide groups, characterized in that the crosslinker comprises a combination of at least two compounds containing β-hydroxyalkylamide groups and each compound having different β-hydroxyalkylamide functionalities, the first compound having a β- hydroxyalkylamide functionality of ≥ 3 and the second compound having β-hydroxyalkylamide a functionality of _ 3.
2. Powder coating composition according to claim 2 , characterized in that the first compound has a functionality of 4 and the second compound has a functionality of 2.
3. Powder coating composition according to any one of claims 1-2, characterized in that the weight ratio between the first compound to the second compound is from 90:10 and 10:90.
4. Powder coating composition according to any one of claims 1-3, characterized in that the polymer is a polyester and/or polyacrylate.
5. Crosslinker for the preparation of a powder coating, characterized in that the crosslinker comprises a combination of at least two compounds containing β-hydroxyalkylamide groups and each compound having different β-hydroxyalkylamide functionalities, the first compound having a β-hydroxyalkylamide functionality of ≥ 3 and the second compound having a β-hydroxyalkylamide functionality of ≤ 3.
6. Crosslinker according to claim 5, characterized in that the first compound has a functionality of 4 and the second compound has a functionality of 2.
7. Use of a combination of at least two compounds containing β-hydroxyalkylamide groups and each compound having different β-hydroxyalkylamide functionalities, the first compound having a β- hydroxyalkylamide functionality of ≥ 3 and the second compound having a β-hydroxy-alkylamide functionality of -. 3, as a crosslinker in the preparation of powder coatings.
8. Use according to claim 7, characterized in that the first compound has a functionality of 4 and the second compound has a functionality of 2.
9. Powder coating composition, crosslinker and use according to any one of claims 1-8, characterized in that the first compound having a β-hydroxyalkylamide functionality of ≥ 3 is a compound according to formula (II) :
HO-H2C-H,C 0 0 CH2-CH2-OH
\ N N-C "- (CH2 ) 4-C "-N / y ( II )
HO-H2C-H2C y \ CT2-CH2-OH
10. -Powder coating composition, crosslinker and use according to any one of claims 1-9, characterized in that the second compound having a β-hydroxyalkyamide functionality of ≤ 3 is a compound according to formula (IV) :
0 CH2 - CH2 - OH
CH3 - C - N (IV)
CH2 - CH2 - OH
11. Use of a powder coating composition according to any one of claims 1-4 or 9-10.
12. A coated substrate, characterized in that the coating material is a powder coating according to any one of claims 1-4 or 9-10.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9200687 | 1992-07-29 | ||
BE9200687A BE1006097A3 (en) | 1992-07-29 | 1992-07-29 | POWDER PAINT BASED ON WITH POLYMER free carboxylic acid groups AS A BINDER AND A BETA-hydroxyalkylamide containing compound as CROSSLINKER. |
PCT/NL1993/000155 WO1994003545A1 (en) | 1992-07-29 | 1993-07-21 | Powder coating composition with hydroxyalkylamide crosslinker |
Publications (2)
Publication Number | Publication Date |
---|---|
AU4763193A true AU4763193A (en) | 1994-03-03 |
AU664482B2 AU664482B2 (en) | 1995-11-16 |
Family
ID=3886379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU47631/93A Ceased AU664482B2 (en) | 1992-07-29 | 1993-07-21 | Powder coating composition with hydroxyalkylamide crosslinker |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0652911A1 (en) |
CN (1) | CN1086836A (en) |
AU (1) | AU664482B2 (en) |
BE (1) | BE1006097A3 (en) |
TW (1) | TW248568B (en) |
WO (1) | WO1994003545A1 (en) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5401790A (en) * | 1994-03-31 | 1995-03-28 | Ppg Industries, Inc. | Waterborne coating compositions having improved smoothness |
DE4430400A1 (en) * | 1994-08-26 | 1996-02-29 | Inventa Ag | Thermosetting coating system made of several binder resins |
TW385328B (en) * | 1995-06-14 | 2000-03-21 | Ciba Sc Holding Ag | Corrosion inhibitors in powder coatings |
US5744531A (en) * | 1996-06-24 | 1998-04-28 | Ppg Industries, Inc. | Anionic electrocoating compositions containing hydroxyalkylamide curing agents |
DK0839884T3 (en) * | 1996-10-30 | 2000-08-28 | Inventa Ag | Thermosetting coating compositions |
US5858549A (en) * | 1997-01-07 | 1999-01-12 | National Starch And Chemical Investment Holding Corporation | (Hydroxyalkyl)urea crosslinking agents |
US5840822A (en) * | 1997-09-02 | 1998-11-24 | National Starch And Chemical Investment Holding Corporation | Mono(hydroxyalkyl)urea and oxazolidone crosslinking agents |
NL1007186C2 (en) * | 1997-10-01 | 1999-04-07 | Dsm Nv | ß-hydroxyalkylamide group-containing condensation polymer. |
IT1311895B1 (en) | 1999-03-12 | 2002-03-20 | Sir Ind Spa | MIXTURES OF B-HYDROXIALKYLAMIDS AND THEIR USE AS RETICULATING AGENTS FOR THE PREPARATION OF POWDER PAINTS. |
DE10004136C2 (en) * | 2000-01-31 | 2001-11-29 | Ems Chemie Ag | Thermosetting coating compositions |
CA2466611C (en) * | 2001-12-06 | 2011-09-27 | Vantico Ag | Heat-curable resin composition |
MX2007011459A (en) * | 2005-03-18 | 2008-03-11 | Battelle Memorial Institute | Toner. |
EP1743924A1 (en) | 2005-07-11 | 2007-01-17 | DSM IP Assets B.V. | Powder paint composition |
WO2009090234A1 (en) * | 2008-01-17 | 2009-07-23 | Dsm Ip Assets B.V. | Heat curable powder coating composition |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4801680A (en) * | 1987-12-30 | 1989-01-31 | Ppg Industries, Inc. | Hydroxyalkylamide powder coating curing system |
US5101073A (en) * | 1990-08-27 | 1992-03-31 | Rohm And Haas Company | Production of β-hydroxyalkylamides |
-
1992
- 1992-07-29 BE BE9200687A patent/BE1006097A3/en not_active IP Right Cessation
-
1993
- 1993-07-21 EP EP93918083A patent/EP0652911A1/en not_active Withdrawn
- 1993-07-21 AU AU47631/93A patent/AU664482B2/en not_active Ceased
- 1993-07-21 WO PCT/NL1993/000155 patent/WO1994003545A1/en not_active Application Discontinuation
- 1993-07-27 TW TW82105974A patent/TW248568B/zh active
- 1993-07-28 CN CN 93116866 patent/CN1086836A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
AU664482B2 (en) | 1995-11-16 |
WO1994003545A1 (en) | 1994-02-17 |
TW248568B (en) | 1995-06-01 |
EP0652911A1 (en) | 1995-05-17 |
BE1006097A3 (en) | 1994-05-10 |
CN1086836A (en) | 1994-05-18 |
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