AU2423688A - Air meltable castable corrosion-resistant (NI+CR+MO+CO+FE) base alloy - Google Patents
Air meltable castable corrosion-resistant (NI+CR+MO+CO+FE) base alloyInfo
- Publication number
- AU2423688A AU2423688A AU24236/88A AU2423688A AU2423688A AU 2423688 A AU2423688 A AU 2423688A AU 24236/88 A AU24236/88 A AU 24236/88A AU 2423688 A AU2423688 A AU 2423688A AU 2423688 A AU2423688 A AU 2423688A
- Authority
- AU
- Australia
- Prior art keywords
- alloy
- carbon
- castable
- phosphoric acid
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims description 126
- 239000000956 alloy Substances 0.000 title claims description 126
- 238000005260 corrosion Methods 0.000 title claims description 41
- 230000007797 corrosion Effects 0.000 title claims description 41
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 44
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 30
- 239000010949 copper Substances 0.000 claims description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 28
- 229910052802 copper Inorganic materials 0.000 claims description 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 26
- 229910052799 carbon Inorganic materials 0.000 claims description 23
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 21
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 21
- 229910052710 silicon Inorganic materials 0.000 claims description 21
- 239000010703 silicon Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 18
- 229910052742 iron Inorganic materials 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 14
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 13
- 229910052804 chromium Inorganic materials 0.000 claims description 13
- 239000011651 chromium Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 8
- 238000005266 casting Methods 0.000 claims description 8
- -1 halogen ions Chemical class 0.000 claims description 8
- 239000002367 phosphate rock Substances 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 229910000640 Fe alloy Inorganic materials 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 16
- 229910001339 C alloy Inorganic materials 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 229910021386 carbon form Inorganic materials 0.000 description 3
- 239000002686 phosphate fertilizer Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 229910002065 alloy metal Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000007514 turning Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/055—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 20% but less than 30%
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Coating By Spraying Or Casting (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Description
Air Meltable Castable Corrosion Resistant Alloy
Technical Field
Equipment used in highly corrosive environments typically is constructed of metal alloys such as stainless steel or other high alloys. These alloys are necessary to withstand the extremely corrosive effects of environments in which the equipment encounters chemicals such as concentrated sulfuric acid or concentrated phosphoric acid. A particularly difficult environment is encountered in making phosphate fertilizer. In the digestion of phosphate rock with hot, concentrated sulfuric acid, equipment must resist the environment at temperatures up to about 100°C. The impure phosphoric acid which is produced can be extremely corrosive and contains some residual sulfuric acid. The corrosive effect is often increased by other impurities in the phosphoric acid, particularly by halogen ions such as chloride and fluoride, which are normally present in the phosphate rock feedstock used in the process. An extremely corrosive environment is encountered in the concentration of the crude phosphoric acid . Background Art
Typically, the art has used high alloys, such as Hasteloy C276, for the extremely corrosive environments. The high alloys require expensive special processing, such as vacuum or electroslag
processing. High alloys requiring such low carbon and silicon residuals must be melted using specialized melting techniques and are generally available only in wrought form. They cannot be produced by casting in commercial foundries using air melting techniques.
The very low carbon and silicon contents which are specified for the commercial high alloys are produced by these expensive melting techniques. It is known that a relatively high silicon content promotes fluidity of the molten metal and renders the melt castable. At the extremely low silicon content specified for the high alloys, the molten metal lacks fluidity and cannot be cast by conventional sand, investment or centrifugal foundry methods. Disclosure of Invention
Applicants have produced a new alloy which has particular corrosion resistance in the environment encountered in producing phosphate fertilizer. In addition to superior corrosion resistance, the new alloy is relatively inexpensive and is highly castable to form complex parts and shapes. The alloy may be prepared by conventional and inexpensive air melt techniques, which is a particular advantage. Applicants' alloy typically contains betwen about 20-25% chromium, 6-9% molybdenum, 0.5-1% silicon, 2-4% manganese, 15-20% iron, 4-8% cobalt, up to 0.2% nitrogen, up to 0.2% carbon and less than about 0.15% copper; a low copper content is preferred. The balance (about 33-53%) is nickel.
Applicants' alloy is an air melted, substantially
copper free, nickel base corrosion resistant alloy. Applicant has discovered, contrary to conventional wisdom, that an essentially copper free alloy exhibits corrosion resistance equal to and in most instances significantly better than similar alloys containing copper, particularly in the severe environment encountered in the concentration of phosphoric acid for fertilizers. This is particular true where quantities of halogen ions, as chloride and fluoride, are present.
Applicants have discovered that their particular substantially copper free alloys are significantly superior to commercial alloys normally used in this service, such as Hasteloy C276. Applicants' alloys have the significant advantage that they may be formed by standard air smelting techniques and do not required the special techniques required by conventional high alloys used in this service. It is generally known that copper content in corrosion resistant alloys, such as the austentic stainless steels and certain other high nickel alloys, enhances the corrosion resistance of these alloys in environments where the alloys are exposed to acids of sullfur and phosphorus. Typical corrosion resistant alloys make use of a significant copper content to achieve better corrosion resistance. It is known that if the copper content is too high, it can cause a condition known as hot shortness in the alloys which makes them difficult to cast or hot work. Copper also may reduce the weldability of these alloys, but conventionally, significant copper content is desirable. Applicant's have found, however, that they can
product a highly corrosion resistant alloy which is essentially copper free. In doing so, applicants also have produced an alloy which is weldable, which can result in high process yields and in a reduction of scrap and waste metal. These factors all contribute to a much lower product cost in applicants' alloy.
Phosphate rock deposits at various locations in the world vary greatly in chemical composition. The most severe corrosion environments are typically encountered in processing deposits of phosphate rock which contain a high content of halogens, such as chloride or fluoride. It is an object of applicants' invention to produce a material of construction suitable for use in processing such phosphate rock which presents severely corrosive environment.
It is also an object of applicants' invention to produce a corrosion resistant which is low in copper and which has an enchanced corrosion resistance.
It is a further object of applicants' invention to produce a highly corrosion resistant alloy which contains silicon in sufficient quantity to render the alloy castable by conventional methods. It is an object of applicants' invention to produce a highly corrosion resistant alloy which contains silicon.
It is an object of applicants' invention to produce a corrosion resistant alloy that is essentially copper free.
It is an object of applicants' invention to produce a corrosion resistant alloy which has high strength and hardness properties.
Applicants' substantially copper free alloy may be made in two forms, depending upon the level of carbon in each form. The ultra low carbon alloys of applicants' invention have a carbon content of less than about 0.08% and have an austenitic solid solution structure when solution treated. The low carbon alloys, with a carbon content of between about 0.10 and 0.20%, exhibit a precipitation of a Chinese script configuration. It will be understood that, as used herein, the terms "low carbon" and "ultra low carbon" are meant to describe alloys having the above carbon contents. The precipitates have been identified as heavy metal carbides. the micro hardness test, converted to Rockwell C scale, shows a matrix hardness in the low carbon alloy matrix of about 26.7 and about 52.3 hardness in the carbide. The low carbon alloys do not have the exceptionally high corrosion resistance exhibited by the ultra low carbon alloy. However, the low carbon alloys have a structure which may be highly useful in corrosive services hwere physical abrasion, erosion or galling is encountered.
The invention may be further understood by reference to the following Best Mode for Carrying out the Invention.
Best Mode for . Carrying out the Invention
The alloys of the invention are nickel base alloys with high iron and moderate to high chromium content. The alloys contain between about 33 to 53 percent nickel, preferrably about 42 percent (to balance to 100 percent), about 20 to 25 percent chromium, about 6 to 9 percent molybdnum, about 4 to 8 percent cobalt, about 15 to 20 percent iron, about
2 to 4 percent manganese and about 0.5 to 1.0 percent silicon. the alloy is substantially copper free, having less than about 0.15 percent copper and preferably having substantially less than 0.15%. The alloy may contain up to about 0.2 percent carbon, preferrably up to about 0.08% carbon and having an austenitic composition or containing about 0.10 and 0.20 percent carbon and having an extremely hard Chinese script precipitated structure in an austenitic matrix. The alloy may also contain minor amounts of tramp or extraneous elements, as is typical in alloy compositions, for example, sulfur and phosphorous. It is prefered that these elements be kept to as low a level as conveniently possible. Preferrably sulfur is maintained below about 0.025 percent by weight and phosphorous below about 0.025 percent by weight. Nitrogen, up to about 0.20% by weight, may be used as an alloy ingredient to promote formation of an austenitic structure and to increase strength.
Nickel is present in the alloy as the base metal and at a relatively high percent. Nickel adds greatly to the corrosion resistance of the alloy. The chromium level is at a moderate/high level of between, about 20 and 25 percent by weight. It is preferred that the chromium present be added, within these limits, at a high level to add corrosion resistance and strength to the alloy. The addition of cobalt and managese to the alloy also adds additional strength and contributes to the corrosion resistance.
Applicants have found that the elimination of copper from the alloy, to the greatest extent
possible, greatly improves the castability of the alloy and unexpectedly provides an alloy having as high or higher corrosion resistance than conventional alloys containing copper. In addition, the weldability of the alloy is greatly improved by the omission of copper from the alloy. It is preferred that the copper content be kept as low as possible and preferably substantially below 0.15 percent by weight. The silicon content in this alloy should be as low as possible to provide increased corrosion resistance in the severe halogen containing phosphoric acid environments. However, reducing silicon in alloys is known to reduce the fluidity of the melt and inhibit the castability of the alloys, particular using conventional air melt, gravity casting techniques. Applicants have found however, that they can reduce the silicon content substantially below 1.0 percent by weight, in this alloy, and still provide an alloy which is highly fluid in the molten state. Applicants' alloys produce superior cast articles, even when casting complex shapes. In addition, applicants have found that, at this low silicon content, the corrosion resistance of their alloy against halide contianing phosphoric acid is greatly improved. Preferably the silicon content is between about 0.5 and 1.0 percent by weight.
It is desirable that, within the limits set, iron also be included at as high a level as conveniently possible. Having a high iron content reduces the cost of the alloy, since iron is a much less expensive constituent then nickel, chromium and the
other high alloy metals. Moreover, having the high iron content permits the inclusion of alloy constituents in their alloyed form with iron, rather than requiring the use of pure alloying metals. This reduces the cost of preparation of the alloy. Moreover, applicants have found that within the limits of their alloy, the presence of iron does not detract from the overall corrosion resistance, weldability, and castability of their alloy product. While applicants' alloy is described as a castable alloy, it will be understood that it may be readily machined by conventional processes, such as turning, milling or drilling, as required to produce a finished product. Applicants' alloy may take two finished forms.
In the first form, applicants' alloy has a carboncomposition of up to about 0.08 percent, preferably between about 0.02-0.08%. this form, designated the ultra low carbon form, exhibits an austenitic structure and has very high corrosion resistance in the target environment, particularly where the environment contains halide ion, such as chloride and fluoride. The second type of applicants' alloy is designated the low carbon form. This form typically has the carbon content between about 0.1 and 0.2 percent by weight. The low carbon form has a two phase structure having an austenitic matrix containing Chinese script carbon precipitates. The precipitates have exceptional hardness. While the low carbon alloys do not have the very high corrosion resistance in the target environment exhibited by the ultra low carbon alloys, they may be used for service exhibiting corrosion, abrasion,
erosion and galling. The low carbon alloys can find exceptional utility in an environment having both high corrosion and abrasive factors, such as pumping of slurries of acidified phosphate rock, as might be eήcountereed in phosphoric acid production.
The preferred composition of applicants' ultra low carbon alloy is nickel about 41.7%, chromium about 22.5%, molybdenum about 8.0%, cobalt about 6-8%, iron about 16%, manganese about 2.5-3.0%, carbon up to about 0.08%, silicon about 0.6-0.75% and copper below about 0.15%.
The following tables show examples of alloys made within the concepts of the invention compared with conventional alloys. LEWMET 25 (TM) is a commercial version of alloys disclosed in U.S.. Patent No.3,758,296. All of the examples, as summarized in Tables I through IV, are alloys made by conventional air melt techniques with the exception o the commercial alloys Hasteloy (TM) C276 and Carpenter (TM) 20Cb3. Hasteloy (TM) C276 is an example of a super low carbon and silicon wrought alloy requiring a specialized melting process. Carpenter 20Cb3 is a commercial wrought material. Also compared in the Tables are two versions of conventional type 316 stainless steel (CF8M and CFBMX). Table I shows a comparison of the compositions of these alloys. The experimental material shown in the tables was made in a conventional electric furnace by melting the ingredients together in the proper proportions, deoxidizing and casting test bars using convetional gravity casting techniques. The cast bars were heat treated and subjected to the tests shown in Tables I through IV. A solution heat treatment, such as a
solution heat treating in excess of 2000°F
(1050°C) and water quench, is satisfactory.
Table II summarizes the comparison of corrosion testing of these alloys in the environment noted in Table II. the alloys were prepared as conventional test blanks and subjected to a series of corrosion tests. A series was tested in phosphoric acid at 90°C. The test were run for 96 hours. Where noted, the test samples were subjected to temperatures of 115°C for twelve hours. This extremely severe test occurred as a result of the malfunction of the test equipment. The composition of phosphoric acid was adjusted to have the chloride ion content as noted. The phosphoric acid was a crude phosphoric acid typical of acids used in producing phosphate fertilizer using Florida phosphate rock. Two standard grades, 32% P2O5 and 54% P2O5, were tested. A third grade tested, 42% P2O5, was manufactured by a different commercial process also using Florida rock. These acids contained approximately 2.2 percent fluoride ion, in the 54 percent P2O5 acid, and 1.25 percent fluoride ion the 32 percent P2O5. These acid compositions are typical of those which would be encountered in severe phosphoric acid environments with high halide ion content.
As can be seen from Table II, applicants' new ultra low carbon alloys in particular tested as being superior to conventional wrought and cast materials. The resistance of applicants' new alloys to 32% P2O5 solutions containing halide ion tested as being highly superior to the best conventional material tested, LEWMET 25. The 32% P2O5 solutions are typical of environments encountered in phosphoric acid concentration.
TABLE II A,
Static Corrosion Laboratory Tests in H3PO4 Rates - mils per year (0.001 inch per year) (Test run for 96 hours in non-aerated acid at 90°C, except where noted)
TABLE II B
Static Corrosion Laboratory Tests in H3PO4 Rates - mils per year (0.001 inch per year) (Test run for 96 hours in non-aerated acid at 90°C, except where noted)
In Table III a number of applicants' alloys were subjected to comparative tests in aerated 98 percent sulfuric acid. The tests were conducted at 100°C, 110°C and 120°C. As can be seen, the alloy exhibits a high degree of corrosion resistance in concentrated sulfuric acid, particularly at temperatures of 100°C and below, as would normally be encountered in handling sulfuric acid in a phosphoric acid plant.
TABLE III
Average corrosion rates - Ultra Low C - Low Cu experimental heats in 98% Sulfuric acid - Rates inches per year
Table IV shows the hardness and strength data for applicants' alloys. It can be seen that applicants' alloys have a high degree of mechanical strength and hardness, which makes them particularly suited for structural and mechanical components in contact with corrosive environments.
TABLE IV A Mechanical Test Data (solution heat treated at 2150°F - 2235°F for one hour per inch of metal section and water quenched)
A leg of standard cast keel bar as described in ASTM Standard A370 was sectioned from a bar cast from experimental heat No. N318. A section was removed from the cut surface of the bar and weld filler metal applied. The bar was then solution heat treated and submitted to an independent commercial laboratory for evaluation. No fracture was observed in bending the bar 180 degrees on a 1 1/2 inch radius. This test indicated excellent weldability.
Evaluation of the castability of the experimental alloys was made by making experimental castings of the general type used in this service. These included pump propellers an pump casings. The molten metal exhibited adequate fluidity filling all voids in the molds. No hot shortness or cracking was evident even when castings were water quenched from high temperature in the heat treating process. Various changes and modifications may be made within the purview of this invention, as will be readily apparent to those skilled in the art. Such changes and modifications are within the scope and techings of this invention as defined by the claims appended hereto. The invention is not to be limited by the examples given herein for purposes of illustration, but only by the scope of the appended claims and their equivalents.
Claims (19)
1. An air meltable, castable, nickel base alloy having high corrosion resistance to severe phosphoric acid environments, the alloy having a copper content of less than about 0.15 percent by weight and having a silicon content of between about 0.5 and 1.0 percent by weight, the alloy melt being highly fluid and castable, the alloy having a high resistance to concentrated phosphoric acid environments and the like.
2. The alloy of claim 1 wherein the alloy has an austenitic matrix.
3. The alloy of claim 1 wherein the alloy is a high iron containing alloy and contains a moderate to high amount of chromium.
4. The alloy of claim 1 wherein the alloy contains up to about 0.08 percent by weight carbon.
5. The alloy of claim 1 wherein the alloy is highly corrosion resistant in phosphoic acid environments containing halogen ions.
6. The alloy of claim 1 wherein the alloy has the following approximate composition by weight: Nickel 33-53% (to balance) Chromium 20-25 Molybdenum 6-9 Cobalt 4-8
Iron 15-20
Manganese 2-4 Silicon 0.5-1.0 Copper 0-0.15 Carbon up to 0.2 Nitrogen up to 0.2
7. The alloy of claim 6 wherein the alloy contains up to about 0.08% carbon.
8. The alloy of claim 6 wherein the alloy contains between about 0.1 to 0.2% carbon.
9. The alloy of claim 8 wherein the alloy has an austenitic base matrix containing a hard carbide precipitate phase.
10. The alloy of Claim 9 wherein the precipitate phase has a Chinese script configuration.
11. An air meltable, castable, weldable, nickel base alloy having a high corrosion resistance to severe phosphoric acid environments contianing halide ions, the alloy containing an effective amount of silicon to produce a highly fluid, castable melt, the alloy being essentially copper free, the alloy having high corrosion resistance to severe phosphoric acid environments such as those encountered in producing phosphoric acid from phosphate rock containing chlorine and fluorine.
12. The alloy of claim 11 wherein the alloy is a high iron alloy containing moderate to high chromium, the alloy containing between about 12-20% iron, between about 20-25% chromium, between about 33-53% nickel, between about 6-9% molybdenum, between about 4-8% cobalt, between about 2-4% manganese and between about 0.5-1.0% silicon.
13. The alloy of claim 11 wherein the alloy contains up to about 0.08% carbon.
14. The alloy of claim 13 wherein the alloy is austenitic.
15. The alloy of claim 11 wherein the alloy contains up to about 0.2% nitrogen.
16. A method of producing a castable alloy having high corrosion resistance to severe phosphoric acid environments comprising air melting a nickel base contining a high iron content and moderate to high chromium content, adding an amount of silicon effective to produce a highly fluid castable melt, and maintaining the copper content at less than about 0.15% by weight, casting the alloy to form structural elements and heat treating the formed structural elements.
17. The method of claim 16 wherein the structural elements are solution heat treated.
18. The method of claim 16 wherein the alloy is essentially copper free and the carbon content is less than about 0.08%.
19. The method of claim 16 wherein the alloy has the following approximate composition be weight: Nickel 33-53% (to balance)
Chromium 20-25
Molybdenum 6-9
Cobalt 4-8
Iron 15-20
Manganese 2-4
Silicon 0.5-1.0
Copper 0.15
Carbon up to 0.2
Nitrogen up to 0.2
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US090657 | 1987-08-28 | ||
| US07/090,657 US4853183A (en) | 1987-08-28 | 1987-08-28 | Air meltable castable corrosion resistant alloy and its process thereof |
| PCT/US1988/002977 WO1989001985A1 (en) | 1987-08-28 | 1988-08-26 | Air meltable castable corrosion resistant alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2423688A true AU2423688A (en) | 1989-03-31 |
| AU621565B2 AU621565B2 (en) | 1992-03-19 |
Family
ID=26777756
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU24236/88A Ceased AU621565B2 (en) | 1987-08-28 | 1988-08-26 | Air meltable castable corrosion-resistant (ni+cr+mo+co+fe) base alloy |
Country Status (1)
| Country | Link |
|---|---|
| AU (1) | AU621565B2 (en) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA717614B (en) * | 1970-12-21 | 1972-08-30 | Cabot Corp | Weldable nickel base alloy |
-
1988
- 1988-08-26 AU AU24236/88A patent/AU621565B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU621565B2 (en) | 1992-03-19 |
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