AU2240800A

AU2240800A - Process for the mig welding of aluminium and its alloys in pulsed mode or unmodulated-spray mode

Info

Publication number: AU2240800A
Application number: AU22408/00A
Authority: AU
Inventors: Jean-Marie Fortain; Philippe Lefebvre; Gerard Plottier
Original assignee: Air Liquide SA; LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Current assignee: LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date: 1999-04-15
Filing date: 2000-03-20
Publication date: 2000-10-19
Also published as: JP2000317633A; FR2792236A1; DE60016077D1; EP1044752B1; ATE283139T1; EP1044752A1; DE60016077T2; US6392194B1; AR023516A1; FR2792236B1; ES2233300T3; CA2305026A1; BR0001608A

Description

AUSTRALIA

Patents Act COMPLETE SPECIFICATION

(ORIGINAL)

Class Int. Class Application Number: Lodged: Complete Specification Lodged: Accepted: Published:

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r Priority Related Art:

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Name of Applicant: L'Air Liquide, Societe Anonyme pour I'Etude et I'Exploitation des Procedes Georges Claude Actual Inventor(s): GERARD PLOTTIER, JEAN-MARIE FORTAIN, PHILIPPE LEFEBVRE Address for Service: PHILLIPS ORMONDE FITZPATRICK Patent and Trade Mark Attorneys 367 Collins Street Melbourne 3000 AUSTRALIA Invention Title: PROCESS FOR THE MIG WELDING OF ALUMINIUM AND ITS ALLOYS IN PULSED MODE OR UNMODULATED-SPRAY MODE Our Ref 611139 POF Code: 1290/43509 The following statement is a full description of this invention, including the best method of performing it known to applicant(s): -1- 11 i la The present invention relates to a MIG (Metal Inert Gas) process for the electric-arc welding of aluminium and aluminium alloys in pulsed mode or in spray mode, with the exception of a process in spray mode with modulated current.

The electric-arc welding process using a meltable wire as electrode and an inert gas for shielding the welded zone is well known and widely used in industry. Usually, it is called the MIG welding process.

When the meltable wire, that is to say the electrode, melts, the molten metal can be transferred according to several modes. Thus, mention may be made of the modes: called "short-circuiting" mode, in which a drop of molten metal forms, at a low arc energy, at the S end of the meltable wire, then grows and thereafter comes into contact with the weld puddle before detaching from the wire; "20 called "spray" mode, in which the transfer of metal from the wire to the puddle of molten metal takes place, at high energy and high current density, and at oeeo a high speed, in the form of fine droplets having a diameter of less than that of the wire and along the axis of the said wire. It is characterized by a very stable arc and no spatter of metal; called "pulsed" mode, in which current pulses are superimposed on a base current intended to maintain the arc, so as to send one drop of molten metal per current pulse. This mode is comparable to the spray mode (with axial spraying), but with the use of a lower mean current.

In order to follow the technological developments in industry, such as those of the transportation (railway, naval, automobile, aeronautic or space) sector or the energy and storage sector, the MIG process has had to be adapted.

First of all, there has been significant development in current sources (power electronics with microprocessor control) and this has been followed by a I) 2more rational choice of welding gases, which has allowed the expectations of industry to be more specifically met, particularly in terms of welding productivity and quality.

Thus, it has been shown that argon leads, both in automatic and manual welding, to good transfer of metal into the arc and a beautiful shiny appearance of the welds thus produced.

On the other hand, argon does not allow high welding rates and can give rise, in automatic welding, to arc instabilities above 500 A.

In addition, the narrow characteristic shape of the penetrations obtained under argon do not fit well with welding by interpenetration.

15 In mixtures of argon and helium (hereafter called Ar/He mixtures), the helium makes it possible to increase the depth of penetration and its root width, and therefore is able to allow expensive preparations to be dispensed with, this being all the more pronounced the higher the helium content.

In other words, for a constant thickness, it *therefore allows higher welding rates the higher its content.

general, the compactness of the beads is also improved, but to the detriment of the appearance of the beads, which are less shiny than under pure a argon.

The Ar/He mixtures are therefore of obvious advantage in terms of quality and productivity both in manual welding (Ar 20% He) and in automatic welding (Ar 50% to 70% He), but faced, however, with a not insignificant cost owing to the helium content.

For applications not necessarily requiring these two criteria to be met, it may be judicious to consider other types of mixtures.

Thus, document EP-A-639,423 proposes, for TIG and MIG processes, the use of a welding gas of the argon or argon/helium type containing, in addition, from 100 to 1000 ppmv of C0 2 and/or 02.

3 Furthermore, document DE-A-4, 241, 982 proposes the use of argon or an argon/helium mixture to which, moreover, from 80 to 250 ppmv of nitrogen has been added.

However, none of these known processes is entirely satisfactory from the industrial standpoint.

What is more, in modulated spray MIG welding, that is to say with the welding current being modulated, it has already been recommended to use a shielding gas or gas mixture, formed from argon, helium or their mixtures, to which from 0.01% to 1.80% of carbon dioxide and/or oxygen has been added, as described in EP-A-909,604.

However, in this case, current modulations at a frequency of less than 60 Hz are applied to the current so as to be able to outgas the weld puddle in order to remove gaseous inclusions therefrom, particularly diffusible hydrogen, which are liable to be found S: therein.

Thus, MIG processes in spray mode with current modulations are employed when it is desired to obtain a .high quality of the welded joint, but without the real need to achieve a high welding speed.

Consequently, the problem that arises is to 25 improve the known MIG welding processes that do not involve modulating the welding current, particularly MIG processes in unmodulated spray mode, that is to say without modulating the welding current, as well as those in pulsed mode, in order to obtain high performance in terms of welding productivity and speed.

To do this, MIG processes in unmodulated spray mode and those in pulsed mode are much more suitable when it is desired to improve the productivity rather than the quality, that is to say the appearance, of the welds thus produced.

However, hitherto MIG processes in unmodulated mode or in pulsed mode have been used little, or not at all, for welding aluminium or its alloys when the gas shield contains oxygen.

4 This is because it is commonly recognized that the presence of oxygen in the gas shield may have a deleterious impact on the weld given that, when oxygen is incorporated into the gas shield, it can easily combine with aluminium atoms and result in solid inclusions of alumina (A1 2 0 3 in the weld, these having a negative impact on the mechanical properties of the said weld. This has, moreover, been confirmed in the case of high oxygen contents, that is to say oxygen contents greater than as well as in the case of high carbon. dioxide contents, that is to say, again, contents greater than 2%.

However, conversely, the presence of oxygen in the stream of shielding gas results in acceptable productivity levels.

It therefore follows that the problem which arises is to provide an MIG welding process for aluminium and its alloys which makes it possible to .i achieve both a high and industrially acceptable productivity and a low concentration of alumina inclusions in the weld without a major or appreciable impact on the mechanical properties of the welded joints.

The above discussion of documents, acts, materials, devices, articles S. and the like is included in this specification solely for the purpose of providing a context for the present invention. It is not suggested or represented that any or all of these matters formed part of the prior art base or were common general knowledge in the field relevant to the present invention as it existed in Australia before the priority date of each claim of this application.

4a The solution provided by the present invention therefore relies on a process for the MIG welding of aluminium and aluminium alloys in spray mode without current modulation or in pulsed mode, with the use of gas shielding of at least part of the welding zone, characterized in that the gas shield is a gas mixture consisting of 0.01% to 1.80% oxygen and of 98.20% to 99.99% argon.

Further features of the process of the invention are given below: the shielding gas mixture contains from to 1.8% oxygen; the balance being argon; the gas mixture or shield contains from 1 to 1.7% oxygen, the balance being argon;.

the gas mixture or shield contains from 1.2 to 1.65% oxygen, the balance being argon; 5 a solid meltable wire or a flux-cored wire is used; the welding speed is from 0.25 m/minute to 1.20 m/minute, preferably from 0.60 to 1 m/minute; the wire feed rate is from 2.5 m/minute to m/minute, preferably from 4 m/minute to 13 m/minute; the mean welding current is from 40 A to 450 A and/or the mean welding voltage is from 15 V to

V;

the process is in pulsed mode and/or the welding current is from 120 A to 350 A and/or the mean welding voltage is from 20 V to 28 V; the process is in spray mode and/or the welding current is from 180 A to 450 A and/or the mean welding voltage is from 20 V to 39 V.

The present invention therefore relies on precise control of the oxygen content in the argon, the oxygen content having not to exceed approximately 1.80% at most; the gas mixture thus formed constitutes the gas shield used during the use of the MIG process.

It should be emphasized that any MIG process in spray mode with modulation of the welding current is excluded from the invention.

The invention will now be more clearly 25 understood by virtue of the examples below, given by way of illustration that implies no limitation, the results of which are shown schematically in the figures appended hereto.

Examples In order to show the effectiveness of the MIG process according to the invention, several comparative trials were carried out.

Within the context of these trials, aluminium workpieces (aluminium grades 5000 and 6000 according to the NFEN 485, 487, 515 and 573 standards) were welded according to a MIG process in unmodulated spray mode and in pulsed mode, using a gas shield consisting of 6 argon to which from 1 to 3% 02 or, depending on the case, from 1 to 3% CO 2 was added.

The current generator is a 480 TRS generator sold by La Soudure Autogene Francaise.

The meltable wire, as filler metal used, is in all cases a wire 1.2 mm in diameter of the 5356 type (according to the AWS A5.10 and NF A50.403 standards).

Prior to welding, the aluminium workpieces are prepared by mechanical gouging.

The other welding parameters are given in Table I below, in which: Vwire represents the feed rate of the meltable wire; Ipeak represents the peak current; Ibase represents the base current; Imean represents the mean current; S Upeak represents the peak voltage; Umean represents the mean voltage; fp represents the current pulse frequency (in pulsed-mode MIG); tp represents the current pulse time (in pulsed-mode MIG).

Table I: Welding parameters 25 ^1 Mode Spray Pulsed Spray Pulsed Grade of the 5000 5000 6000 6000 aluminium workpiece Thickness 6 6 6 (mm) Vwie (m/min.) 12.5 9 12.5 10.1 Ipeak 330 330 Ibase 110 110 Imean 210-230 156-180 210-230 156-180 Upeak 28 29 Umean 22-25 20-25 22-25 20-25 fp (Hz) 155 155 tp (ms) 1.6 1.6 7 The results obtained are given below, after assessing the performance in terms of productivity (welding speed) and of joint quality (compactness and appearance of the bead) and the mechanical properties.

In Tables II and III, the speed increases given for the 3 grades of aluminium were determined with respect to the welding speeds conventionally obtained with argon (without the addition of 02 or C02).

The shaded areas correspond to additions to be proscribed, for which the mechanical properties of the joints (tensile and/or flexural strength) are unsatisfactory.

15 Table II: Argon 02 ND: not done because of the results obtained on the 5000 grade.

Table III: Argon CO 2 Mode Spray Pulsed Spray Pulsed Grade 5000 5000 6000 6000 1% C0 2 25% 28% ND ND 2% CO 2 46% 60% ND ND 3% CO 2 ND ND ND: not done because of the results obtained on the 5000 grade.

It is clearly apparent from Tables II and III that although the additions of C0 2 give a priori higher 8 performance in terms of welding speed, only the additions of 02 not exceeding 2% make it possible to guarantee the mechanical properties of the various grades of the aluminium workpieces.

Moreover, in order to evaluate the performance in terms of joint quality (compactness and appearance of the bead), radiographic examinations were made on the workpieces of 5000 grade, these giving no indications different from those usually found in MIG welding with argon or Ar/He mixtures. Nevertheless, for additions of CO 2 of 3% and more, the highly contorted surface appearance is likely to conceal any fine defects, in radiography.

Therefore, as a complement, macrographic 15 samples made it possible to reveal, by simple polishing, areas of small inclusions (about 0.01 mm in size), of different distribution and orientations.

However, for the same of addition, these areas are much greater in size and in density with CO 2 than with 02.

These areas were identified in the SEM as areas of alumina (A1 2 0 3 Furthermore, the appearance of the beads obtained with the Ar/0 2 and Ar/CO 2 mixtures ".*differs substantially from those produced with pure 25 argon. This is because, for both types of additions,

CO

2 or 02, the beads are dull, or even blackish, in appearance depending on the content used. Generally, the surface deposits obtained with the addition of CO 2 are more pronounced and more adherent than those produced with 02, which can be removed simply by brushing or with the aid of a cloth.

Next, the mechanical properties were measured using skived crosswise tensile test pieces and crosswise bending specimens taken from joints.

Tables IV and V below give the tensile results, which are expressed in terms of a joint coefficient (strength of the melted metal/strength of the base metal) 9 It should be noted that the differences in joint coefficients between the 5000 and 6000 grades are simply due to the use of a 6000 grade base metal delivered in the T6 state, while the joint underwent no postwelding heat treatment.

Table IV: Ar 02 Mode Spray Pulsed Spray Pulsed Grade 5000 5000 6000 6000 1% 02 0.87 0.85 0.70 0.66 2% 02 0.82 0.83 0.70 0.65 3% 02 ND ND 10 ND: not done because of the results obtained on the 5000 grade.

Table V: Ar C02 n1 a Mode Spray Pulsed Spray Pulsed Grade 5000 5000 6000 6000 1% C02 0.82 0.83 ND ND 2% CO 2 0.80 0.83 ND ND 3% CO 2 0.79 ND ND ND: not done because of the results obtained on the 5000 grade.

The results obtained reveal, on the fracture surfaces of these test pieces, areas of fine dispersed black inclusions. These observations confirm the results of the macrographic examinations. As the percentage of 02 or CO 2 is increased, these inclusions become greater in size and in density, and cause a greater reduction in deformability in the bending tests, as well as a substantial reduction in mechanical properties.

The results of the latter are rated as being acceptable (1800 bending angle without any defect or 10 with only slight defects) and as unacceptable (bending angle 1800 with cracking) However, it should be emphasized that the areas of inclusion (alumina) are much denser and more numerous with Ar+C0 2 mixtures than with Ar+0 2 mixtures.

The results are shown diagrammatically in the appended Figures 1 to 4.

Figure 1 (5000 alloy grade) and Figure 3 (6000 alloy grade) show the influence of adding increasing amounts of 02 or COz to the argon in MIG welding in unmodulated spray mode on the bending resistance behaviour and the tensile strength on tensile test pieces, whereas Figure 2 (5000 alloy grade) and Figure 4 (6000 alloy grade) show the influence of adding increasing amounts of 02 or CO 2 to the argon in MIG ***welding in pulsed mode on the bending resistance behaviour and the tensile strength on tensile test o ~.pieces.

In Figures 1 to 4, the x-axis represents the 20 contents (in of 02 or CO 2 in the argon and the y-axis represents the values (in MPa) of the tensile strength (Rm) of the 5000 grade joints (Figs. 1 and 2) and 6000 grade joints (Figs. 3 and 4).

results are regarded as being acceptable when the 1800 bending produces "no defect" or "slight defects, but without cracking" (see the legend in Figures 1 to 4) Figures 3 and 4 show that there is no degradation in the mechanical properties of the melted zone as a function of the 02 content in so far as the tensile test pieces systematically break in the connection zone corresponding to a T4 state of the material, inferior to the unaffected delivery state T6.

This also explains the differences in the joint efficient between the 5000 and 6000 series.

Finally, the best results are obtained by using argon/oxygen mixtures containing less than 2% oxygen.

11 Further trials have shown that the best results are obtained for oxygen contents of 1.20% to 1.70%, preferably about 1.50%.

Throughout the description and claims of the specification the word "comprise" and variations of the word, such as "comprising" and "comprises", is not intended to exclude other additives, components, integers or steps.

9* 9 a

Claims

1. A process for the MIG welding of aluminium and aluminium alloys in spray mode without current modulation or in pulsed mode, with the use of gas shielding of at least part -of the welding zone, wherein the gas shield is a gas mixture consisting of 0.01% to 1.80% oxygen and of 98.20% to

99.99% argon. 2. A process according to Claim 1, wherein the shielding gas mixture contains from 0.5 to 1.8% oxygen, the balance being argon. 3. A process according to Claim 1 or 2, wherein the gas mixture or shield 15 contains from 1 to 1.7% oxygen, the balance being argon. 4. A process according to Claims 1 to 3, wherein the gas mixture or shield contains from 1.2 to 1.65% oxygen, the balance 'being 20 argon. A process according to Claims 1 to 4, wherein a solid meltable wire or a flux- cored wire is used. 6. A process according to Claims 1 to wherein the welding speed is from 0.25 m/minute to 1.20 m/minute, preferably from Q;.60 to 1 m/minute. 7. A process according. to Claims 1 to 6, wherein the wire feed rate is from 2.5 m/minute to 20 m/minute, preferably from 4 m/minute to 13 m/minute. 8. A process according to Claims 1 to 7, wherein the mean welding current is from A to 450 A and/or in that the mean welding voltage is from 15 V to 40 V. 9. A process according to Claims 1 to 8, wherein the process is in pulsed mode and/or in that the welding current is from 120 A to 13 350 A and/or in that the mean welding voltage is from V to 28 V. A process according to Claims 1 to .8, wherein the process is in spray mode and/or in that the welding current is from 180 A to 450 A and/or in that the mean welding voltage is from V to 39 V. 11. A process according to any one of the claims substantially as hereinbefore described with reference to any one of the examples. DATED: 16 March, 2000 PHILLIPS ORMONDE FITZPATRICK Attorneys for: AIR LIQUIDE S. S S *055 55 5 p5 S 0*55 S. S