AU2161899A - Use of transitional metal complexes for dying keratin fibers - Google Patents
Use of transitional metal complexes for dying keratin fibersInfo
- Publication number
- AU2161899A AU2161899A AU21618/99A AU2161899A AU2161899A AU 2161899 A AU2161899 A AU 2161899A AU 21618/99 A AU21618/99 A AU 21618/99A AU 2161899 A AU2161899 A AU 2161899A AU 2161899 A AU2161899 A AU 2161899A
- Authority
- AU
- Australia
- Prior art keywords
- atoms
- independently
- represent hydrogen
- transitional metal
- substituent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 102000011782 Keratins Human genes 0.000 title 1
- 108010076876 Keratins Proteins 0.000 title 1
- 239000000835 fiber Substances 0.000 title 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000000975 dye Substances 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000004450 alkenylene group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 230000000536 complexating effect Effects 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/58—Metal complex; Coordination compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Coloring (AREA)
Abstract
The invention relates to the use of transitional metal (III) complexes of the formula (I), in which UM represents manganese, iron, cobalt, ruthenium, molybdenum or vanadium; R represents an alkylene-, alkenylene-, phenylene- or cycloalkylen- rest which in addition to the substituent X can possibly be substituted with alkyl- and/or aryl-, with a total of between 1 and 12 C atoms, whereby within R the shortest distance between the N-atoms complexing with UM is between 1 and 5 C atoms; X represents -H, -OR<3>, -NO2, -F, -Cl, -Br or -J; R<1>, R<2 >and R<3> independently of each other represent hydrogen or an alkyl rest with between 1 and 4 C atoms; Y<1> and Y<2> independently of each other represent hydrogen or an electron displacing substituent; Z<1> and Z<2> independently of each other represent hydrogen, -CO2M, -SO3M, -NO2, -CH3, -C2H5, -C3H7, -CH2OH or -CHO; M represents hydrogen or an alkali metal such as lithium, sodium or potassium; and A represents a charge-balancing anion ligand. According to the invention, use of the above complexes allows for a marked reduction in the quantity of oxidizing agent in oxidation dyes. In addition, oxidation dyes can be formulated as oxidizing agents using atmospheric oxygen.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19757510 | 1997-12-23 | ||
DE19757510A DE19757510A1 (en) | 1997-12-23 | 1997-12-23 | Coloring keratinous fibers, especially hair |
PCT/EP1998/008192 WO1999033435A1 (en) | 1997-12-23 | 1998-12-14 | Use of transitional metal complexes for dying keratin fibers |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2161899A true AU2161899A (en) | 1999-07-19 |
Family
ID=7853165
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU21618/99A Abandoned AU2161899A (en) | 1997-12-23 | 1998-12-14 | Use of transitional metal complexes for dying keratin fibers |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1041955B1 (en) |
JP (1) | JP2001527031A (en) |
AT (1) | ATE248577T1 (en) |
AU (1) | AU2161899A (en) |
DE (2) | DE19757510A1 (en) |
WO (1) | WO1999033435A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19859681A1 (en) * | 1998-12-23 | 2000-06-29 | Henkel Kgaa | Colorants with transition metals |
DE10000460B4 (en) * | 2000-01-07 | 2004-05-06 | Wella Aktiengesellschaft | Means and processes for coloring hair |
US6695888B2 (en) * | 2001-07-30 | 2004-02-24 | Unilever Home & Personal Care, Usa, Division Of Conopco, Inc. | Transition metal complexes as dye forming catalysts in hair coloring compositions |
WO2003047542A1 (en) * | 2001-12-05 | 2003-06-12 | Unilever Plc | Hair bleaching and colouring composition which comprise trasition metal catalysts |
JP5294397B2 (en) * | 2008-09-04 | 2013-09-18 | 国立大学法人 東京大学 | Metal complex compound |
MD4279C1 (en) * | 2013-01-17 | 2014-10-31 | Институт Химии Академии Наук Молдовы | Dye for thermoplastic polymers |
US9237993B2 (en) | 2014-01-24 | 2016-01-19 | Combe Incorporated | Gradual haircolor compositions and methods of using the same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2123453A1 (en) * | 1971-05-12 | 1972-11-23 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Metal complex dyes |
DE2327987A1 (en) * | 1973-06-01 | 1975-01-02 | Henkel & Cie Gmbh | Dyeing keratin fibres pref. hair - with nickel complex cpds. opt formed in situ |
EP0150676B1 (en) * | 1984-01-06 | 1988-10-12 | Ciba-Geigy Ag | 1:2 chromium complex dyes |
DE3545245A1 (en) * | 1985-12-20 | 1987-06-25 | Henkel Kgaa | HAIR DYE WITH DIRECT DRAWING AZOMETHINE DYES |
EP0630964B1 (en) * | 1993-06-19 | 1998-08-05 | Ciba SC Holding AG | Inhibition of re-absorption of migrating dyes in the wash liquor |
FR2735976B1 (en) * | 1995-06-30 | 1997-08-14 | Oreal | TWO-STAGE OXIDATION DYEING PROCESS FOR KERATINIC FIBERS WITH MANGANESE SALT AND OXIDATION DYE AND DYEING KIT |
DE19529905A1 (en) * | 1995-08-15 | 1997-02-20 | Henkel Kgaa | Activator complexes for peroxygen compounds |
-
1997
- 1997-12-23 DE DE19757510A patent/DE19757510A1/en not_active Withdrawn
-
1998
- 1998-12-14 AU AU21618/99A patent/AU2161899A/en not_active Abandoned
- 1998-12-14 AT AT98965832T patent/ATE248577T1/en not_active IP Right Cessation
- 1998-12-14 WO PCT/EP1998/008192 patent/WO1999033435A1/en active IP Right Grant
- 1998-12-14 DE DE59809515T patent/DE59809515D1/en not_active Expired - Fee Related
- 1998-12-14 JP JP2000526195A patent/JP2001527031A/en active Pending
- 1998-12-14 EP EP98965832A patent/EP1041955B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1041955B1 (en) | 2003-09-03 |
DE19757510A1 (en) | 1999-06-24 |
EP1041955A1 (en) | 2000-10-11 |
JP2001527031A (en) | 2001-12-25 |
WO1999033435A1 (en) | 1999-07-08 |
DE59809515D1 (en) | 2003-10-09 |
ATE248577T1 (en) | 2003-09-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK5 | Application lapsed section 142(2)(e) - patent request and compl. specification not accepted |