AU2021103591A4 - Curing agent for titanium gypsum road, preparation method and application method thereof - Google Patents
Curing agent for titanium gypsum road, preparation method and application method thereof Download PDFInfo
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- AU2021103591A4 AU2021103591A4 AU2021103591A AU2021103591A AU2021103591A4 AU 2021103591 A4 AU2021103591 A4 AU 2021103591A4 AU 2021103591 A AU2021103591 A AU 2021103591A AU 2021103591 A AU2021103591 A AU 2021103591A AU 2021103591 A4 AU2021103591 A4 AU 2021103591A4
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- Prior art keywords
- titanium gypsum
- curing agent
- stabilizer
- regulator
- road
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- 239000010440 gypsum Substances 0.000 title claims abstract description 67
- 229910052602 gypsum Inorganic materials 0.000 title claims abstract description 67
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 239000010936 titanium Substances 0.000 title claims abstract description 65
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 65
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title abstract description 17
- 239000003381 stabilizer Substances 0.000 claims abstract description 27
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 17
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 17
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002893 slag Substances 0.000 claims abstract description 14
- 238000010276 construction Methods 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 9
- 238000006703 hydration reaction Methods 0.000 abstract description 5
- 238000011049 filling Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000036571 hydration Effects 0.000 abstract description 3
- 239000013543 active substance Substances 0.000 abstract description 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000002699 waste material Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 3
- JLDKGEDPBONMDR-UHFFFAOYSA-N calcium;dioxido(oxo)silane;hydrate Chemical compound O.[Ca+2].[O-][Si]([O-])=O JLDKGEDPBONMDR-UHFFFAOYSA-N 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 229910001653 ettringite Inorganic materials 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229910018516 Al—O Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000007514 bases Chemical group 0.000 description 1
- 239000000404 calcium aluminium silicate Substances 0.000 description 1
- 235000012215 calcium aluminium silicate Nutrition 0.000 description 1
- WNCYAPRTYDMSFP-UHFFFAOYSA-N calcium aluminosilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O WNCYAPRTYDMSFP-UHFFFAOYSA-N 0.000 description 1
- 229940078583 calcium aluminosilicate Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/14—Waste materials; Refuse from metallurgical processes
- C04B18/141—Slags
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/06—Oxides, Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/12—Nitrogen containing compounds organic derivatives of hydrazine
- C04B24/121—Amines, polyamines
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Road Paving Structures (AREA)
Abstract
OF THE DISCLOSURE
The invention discloses a curing agent for titanium gypsum road and a preparation
method and an application method thereof, and belongs to the field of road engineering.
The curing agent is prepared by mixing a stabilizer (industrial slag) and a regulator
(sodium silicate, triethanolamine, etc.) according to a certain proportion. By activating
the hydration activity and pozzolanic activity of the active substance in the stabilizer
with the regulator, the titanium gypsum can be solidified, so that the titanium gypsum
can be used in the filling project of highway pavement base. The curing agent is made
by the following raw materials in percentage by mass: 90-95% of the stabilizer and
5-10% of the regulator. The invention has the advantages of low cost, resource saving,
environmental protection, simple preparation and convenient application, and is suitable
for the construction of titanium gypsum subbase for general roads and high-grade
highways.
Description
[01] The invention relates to the field of road engineering, in particular to a curing agent for titanium gypsum road, a preparation method and an application method thereof.
[02] Titanium gypsum is mainly industrial waste produced by adding lime to neutralize acid wastewater when titanium dioxide production enterprises adopt sulfuric acid method to produce titanium dioxide. The main ingredient is calcium sulfate dihydrate. Titanium gypsum is grayish-brown when it comes out of the waste slag treatment plant. After being left in the air for a period of time, it turns red (the ferrous ions are gradually oxidized to ferric ions), so it is also called red gypsum. Titanium gypsum has high water content, many impurities, high viscosity, and weak acidity. Compared with natural gypsum, titanium gypsum has a higher iron content. Therefore, titanium gypsum has the characteristics of high viscosity and easy to turn red when placed in the air. This makes the treatment of titanium gypsum difficult. According to relevant statistics, each production of 1 ton of titanium dioxide output about 3-6 tons of waste titanium gypsum. At present, the annual emission of titanium gypsum has reached 22 million tons, but its comprehensive utilization rate is only about 10%. It can be seen that the output of titanium gypsum causes a large amount of stacking, takes up a lot of land, wastes resources, and is particularly easy to cause environmental damage. Therefore, it is urgent to reduce the stacking of titanium gypsum and realize the multi-directional, multi-channel, and large-scale research and utilization of titanium gypsum.
[03] In addition, in most road construction, the contradiction of the shortage of natural materials is becoming more and more intense, and all of them are facing the problem of financial shortage. Therefore, on the one hand, it can guarantee the quality of road construction; on the other hand, it can alleviate the shortage of natural materials and reduce construction costs, these two aspects are worthy of consideration for road construction companies. Coupled with the implementation of the development concept of "Clear waters and green mountains are as good as mountains of gold and silver", reducing the stacking amount of titanium gypsum, increasing the utilization rate of titanium gypsum, and protecting the environment are also urgent needs of relevant government departments. If the titanium gypsum can be recycled and used as the base material in the road pavement structure, it can reduce costs, save resources, and reduce local environmental pollution. Therefore, the use of titanium gypsum as a base material in road construction can not only alleviate the contradiction of the shortage of natural materials, but also help solve the problem of titanium gypsum disposal, which has far-reaching social and environmental protection significance.
[04] Shrinkage cracking is common in the existing traditional semi-rigid base layer.
The shrinkage and cracking of the base layer can be reflected to the surface layer, causing road cracks, inconvenience to driving, and waste of resources. Although many scholars and experts have added a small amount of titanium gypsum to the water-stable base layer to compensate for shrinkage and cracking, the small amount of titanium gypsum cannot effectively alleviate the current problem of large amounts of titanium gypsum, and if a large amount of titanium gypsum is added in the water-stable base layer, there is a problem that cannot be ignored is the problem of expansion. Therefore, providing a curing agent to cure titanium gypsum as a pavement subbase filling is a problem worth studying.
[05] Preferred embodiments of the present invention seek to provide a curing agent for titanium gypsum road, a preparation method and an application method thereof in view of the above-mentioned existing problems.
[06] Preferred embodiments of the present invention further seek to provide a preparation method of the above curing agent.
[07] Preferred embodiments of the present invention further seek to provide an application method of the above curing agent.
[08] One aspect of the present invention is provided in the following manner.
[09] A curing agent for titanium gypsum road is characterized by being made of the following raw materials in percentage by weight: 90-95% of stabilizer, and 5-10% of regulator; The stabilizer is industrial slag, and the mass fraction of the main components of the slag is: 39.4% of CaO, 13.5% of Al203, 26.4% of SiO 2 , 7.5% of MgO, 0.406% of Fe203, and 1.28% of SO3 ; the regulator is sodium silicate, triethanolamine or a mixture of the two; when the regulator is a mixed reagent of triethanolamine and sodium silicate, the mass ratio of triethanolamine to sodium silicate is 1:1-3.
[10] The best mass ratio of the raw material in the curing agent is: 94% of stabilizer, and 6% of regulator; The regulator is a basic compound in the prior art, but in order to achieve the best technical effect, it is preferably a mixed reagent of triethanolamine and sodium silicate, and the best mass ratio of triethanolamine to sodium silicate is 1:2.
[11] The preparation method includes the following steps: (1) Taking the stabilizer (industrial slag) according to the proportion, drying at -80°C, and grinding to make the specific area of 400-500kg/m 2; (2) Taking the regulator (sodium silicate, triethanolamine, etc.) according to the proportion, adding to the stabilizer in step (1), and mixing thoroughly to obtain the finished curing agent.
[12] In the curing agent for titanium gypsum road of the present invention, the main mechanism is that under the action of the regulator, it can provide an alkaline environment for the stabilizer, and stimulate the hydration activity and pozzolan activity of the active material, the Si-O bond and the Al-O bond in the stabilizer are immediately broken, quickly participate in the hydration reaction, and mix with some oxides in the titanium gypsum to produce hydration products such as calcium silicate hydrate (C-S-H), calcium aluminate hydrate (C-A-H), calcium aluminate ferrite hydrate (C-A-F-H), calcium aluminosilicate hydrate (C-A-S-H), calcium hydroxide (Ca(OH)2), ettringite, etc., with the formation of these gelling substances such as C-S-H, C-A-S-H, C-A-F-H, etc., they can produce coating and adsorption effects on titanium gypsum, thereby achieving solidification of titanium gypsum and improving the strength of the base layer of titanium gypsum. In addition, when selecting the mixed reagent of sodium silicate and triethanolamine as the optimal regulator, on the one hand, triethanolamine can accelerate the early hydration reaction and improve the early strength; on the other hand, sodium silicate can effectively prevent the swelling caused by the formation of Ca(OH)2 from CaO and the swelling caused by the formation of ettringite, due to the reaction between sodium silicate and calcium sulfate, Ca(OH)2 can both generate calcium silicate (C-S-H) gel, which not only inhibits the expansion of CaO and the formation of ettringite, but also the gel material produced can play the role of curing titanium gypsum. It can be seen from the above that the invention of the curing agent for titanium gypsum road provides a good method for titanium gypsum as a subbase filling material, which can ensure the long-term performance of the road base and solve the problem of environmental pollution.
[13] During the laying of the titanium gypsum base layer, the curing agent in present invention can be mixed into the titanium gypsum according to a certain mass ratio, and the base layer can be laid after the titanium gypsum is evenly mixed. The laying process of the titanium gypsum base layer is the same as the laying process of the base layer in the prior art.
[14] During construction, the mixing ratio of curing agent and titanium gypsum is %~15% (mass percentage).
[15] The moisture content of the titanium gypsum base layer is preferably 2% below the optimum moisture content of the titanium gypsum.
[16] According to "Highway Geotechnical Test Regulations" (JTG E40-2007) compaction test T0131-2007, the optimal moisture content of titanium gypsum is determined.
[17] Compared with the prior art, the curing agent for titanium gypsum road, its preparation method and application method of the present invention have the following advantages: (1) The raw material used in the curing agent for titanium gypsum road of the present invention is industrial residue. The active substance in the stabilizer is mainly activated by the regulator to realize the curing of the titanium gypsum, and the titanium gypsum is used in the filling of the highway pavement subbase, the waste is turned into treasure and the utilization value of the titanium gypsum is improved; (2) The preparation method of the curing agent is simple, and the construction operation is easy; (3) The application method of the curing agent can be widely used in areas lacking landfills and areas with high yield of titanium gypsum solid waste, which can reduce the large amount of titanium gypsum stacking, reduce the damage of titanium gypsum to the environment, and reduce the cost of construction.
[18] The curing agent for titanium gypsum of the present invention, its preparation method and application method are described in detail below with specific examples.
[19] Example 1
[20] [Formula] Stabilizer 95% Regulator 5% The stabilizer is industrial slag; the regulator is sodium silicate.
[21] [Preparation] The preparation method of the curing agent for titanium gypsum road is characterized by comprising the following steps: (1) The stabilizer (industrial slag) according to the proportion was taken, dried at 60-80°C, and grinded to make the specific area of 400-500kg/m 2, and waited for use; (2) The regulator (sodium silicate) according to the proportion was taken, added to the stabilizer in step (1), and mixed thoroughly to obtain the finished curing agent.
[22] [Application and effect] The curing agent prepared above was uniformly mixed with titanium gypsum with moisture content of 2% below the optimum moisture content in a ratio of 10%, molded and maintained for 7 days. The 7-day unconfined compressive strength of the test specimen was measured as 2.2MPa.
[23] Example 2
[24] [Formula] Stabilizer 94% Regulator 6% The stabilizer is industrial slag; the regulator is triethanolamine.
[25] [Preparation] The preparation method of the curing agent for titanium gypsum road is characterized by comprising the following steps: (1) The stabilizer (industrial slag) according to the proportion was taken, dried at 60-80°C, and grinded to make the specific area of 400500kg/m 2, and waited for use; (2) The regulator (triethanolamine) according to the proportion was taken, added to the stabilizer in step (1), and mixed thoroughly to obtain the finished curing agent.
[26] [Application and effect] The curing agent prepared above was uniformly mixed with titanium gypsum with moisture content of 2% below the optimum moisture content in a ratio of 8%, molded and maintained for 7 days. The 7-day unconfined compressive strength of the test specimen was measured as 1.6MPa.
[27] Example 3
[28] [Formula] Stabilizer 90%
Regulator 10% Triethanolamine 5% Sodium silicate 5% The stabilizer is industrial slag; the regulator is a mixture of triethanolamine and sodium silicate, and the mass ratio of the mixing amount is 1:1.
[29] [Preparation] The preparation method of the curing agent for titanium gypsum road is characterized by comprising the following steps: (1) The stabilizer (industrial slag) according to the proportion was taken, dried at 60-80°C, and grinded to make the specific area of 400500kg/m 2, and waited for use; (2) The regulator (mixture of triethanolamine and sodium silicate) according to the proportion was taken, added to the stabilizer in step (1), and mixed thoroughly to obtain the finished curing agent.
[30] [Application and effect] The curing agent prepared above was uniformly mixed with titanium gypsum with moisture content of 2% below the optimum moisture content in a ratio of 12%, molded and maintained for 7 days. The 7-day unconfined compressive strength of the test specimen was measured as 3.1MPa.
[31] Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" and "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
[32] The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.
Claims (3)
1. A curing agent for titanium gypsum road, made of the following raw materials in percentage by weight: 90-95% of stabilizer, and 5-10% of regulator; The stabilizer is industrial slag, and the mass fraction of the main components of the slag is: 39.4% of CaO, 13.5% of Al203, 26.4% of SiO 2 , 7.5% of MgO, 0.406% of Fe203, and 1.28% of SO3 ; the regulator is sodium silicate, triethanolamine or a mixture of the two.
2. A method for preparing a curing agent for titanium gypsum road, comprising the following steps: (1) Taking a stabilizer (industrial slag) according to the proportion, drying at -80°C, and grinding to make a specific area of 400-500kg/m 2; (2) Taking a regulator (sodium silicate, triethanolamine, etc.) according to the proportion, adding to the stabilizer in step (1), and mixing thoroughly to obtain the finished curing agent.
3. A method for applying the curing agent for titanium gypsum road according to claim 1, comprising: in terms of mass fraction, a mixing ratio of curing agent and titanium gypsum during construction is 5-15%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2021103591A AU2021103591A4 (en) | 2021-06-24 | 2021-06-24 | Curing agent for titanium gypsum road, preparation method and application method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2021103591A AU2021103591A4 (en) | 2021-06-24 | 2021-06-24 | Curing agent for titanium gypsum road, preparation method and application method thereof |
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| Publication Number | Publication Date |
|---|---|
| AU2021103591A4 true AU2021103591A4 (en) | 2021-08-19 |
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| AU2021103591A Ceased AU2021103591A4 (en) | 2021-06-24 | 2021-06-24 | Curing agent for titanium gypsum road, preparation method and application method thereof |
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| Country | Link |
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| AU (1) | AU2021103591A4 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115044382A (en) * | 2022-08-12 | 2022-09-13 | 中鼎长信(山东)工程科技有限公司 | Soil curing agent, cured soil and application of soil curing agent |
-
2021
- 2021-06-24 AU AU2021103591A patent/AU2021103591A4/en not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115044382A (en) * | 2022-08-12 | 2022-09-13 | 中鼎长信(山东)工程科技有限公司 | Soil curing agent, cured soil and application of soil curing agent |
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