AU2021102475A4 - A drug harmless treatment device - Google Patents
A drug harmless treatment device Download PDFInfo
- Publication number
- AU2021102475A4 AU2021102475A4 AU2021102475A AU2021102475A AU2021102475A4 AU 2021102475 A4 AU2021102475 A4 AU 2021102475A4 AU 2021102475 A AU2021102475 A AU 2021102475A AU 2021102475 A AU2021102475 A AU 2021102475A AU 2021102475 A4 AU2021102475 A4 AU 2021102475A4
- Authority
- AU
- Australia
- Prior art keywords
- pipeline
- reaction
- zone
- temperature
- harmless treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229940079593 drug Drugs 0.000 title claims abstract description 48
- 239000003814 drug Substances 0.000 title claims abstract description 48
- 238000006243 chemical reaction Methods 0.000 claims abstract description 172
- 238000003756 stirring Methods 0.000 claims abstract description 21
- 239000000376 reactant Substances 0.000 claims abstract description 11
- 239000007789 gas Substances 0.000 claims description 83
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 80
- 239000007788 liquid Substances 0.000 claims description 61
- 238000004321 preservation Methods 0.000 claims description 49
- 238000010438 heat treatment Methods 0.000 claims description 46
- 239000000463 material Substances 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 12
- 238000000926 separation method Methods 0.000 claims description 10
- 230000002093 peripheral effect Effects 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 39
- 231100000614 poison Toxicity 0.000 abstract description 12
- 230000007096 poisonous effect Effects 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 11
- 230000008901 benefit Effects 0.000 abstract description 7
- 239000000599 controlled substance Substances 0.000 abstract description 4
- 238000007599 discharging Methods 0.000 abstract description 3
- 238000000746 purification Methods 0.000 abstract description 3
- 238000009284 supercritical water oxidation Methods 0.000 abstract description 3
- 238000012423 maintenance Methods 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 description 55
- 238000006731 degradation reaction Methods 0.000 description 55
- 239000007800 oxidant agent Substances 0.000 description 29
- 230000001590 oxidative effect Effects 0.000 description 26
- 239000000047 product Substances 0.000 description 25
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 24
- 238000002360 preparation method Methods 0.000 description 24
- 238000000034 method Methods 0.000 description 22
- 230000008859 change Effects 0.000 description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 238000009413 insulation Methods 0.000 description 13
- 231100000252 nontoxic Toxicity 0.000 description 13
- 230000003000 nontoxic effect Effects 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 230000008569 process Effects 0.000 description 13
- 244000025254 Cannabis sativa Species 0.000 description 12
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 12
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 12
- GVGLGOZIDCSQPN-PVHGPHFFSA-N Heroin Chemical compound O([C@H]1[C@H](C=C[C@H]23)OC(C)=O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4OC(C)=O GVGLGOZIDCSQPN-PVHGPHFFSA-N 0.000 description 12
- 239000007795 chemical reaction product Substances 0.000 description 12
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 12
- 239000002994 raw material Substances 0.000 description 12
- 150000003384 small molecules Chemical class 0.000 description 12
- 239000005416 organic matter Substances 0.000 description 10
- 229960002069 diamorphine Drugs 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 6
- VBGLYOIFKLUMQG-UHFFFAOYSA-N Cannabinol Chemical compound C1=C(C)C=C2C3=C(O)C=C(CCCCC)C=C3OC(C)(C)C2=C1 VBGLYOIFKLUMQG-UHFFFAOYSA-N 0.000 description 4
- CYQFCXCEBYINGO-UHFFFAOYSA-N THC Natural products C1=C(C)CCC2C(C)(C)OC3=CC(CCCCC)=CC(O)=C3C21 CYQFCXCEBYINGO-UHFFFAOYSA-N 0.000 description 4
- ZTGXAWYVTLUPDT-UHFFFAOYSA-N cannabidiol Natural products OC1=CC(CCCCC)=CC(O)=C1C1C(C(C)=C)CC=C(C)C1 ZTGXAWYVTLUPDT-UHFFFAOYSA-N 0.000 description 4
- 229960003453 cannabinol Drugs 0.000 description 4
- CYQFCXCEBYINGO-IAGOWNOFSA-N delta1-THC Chemical compound C1=C(C)CC[C@H]2C(C)(C)OC3=CC(CCCCC)=CC(O)=C3[C@@H]21 CYQFCXCEBYINGO-IAGOWNOFSA-N 0.000 description 4
- 229960004242 dronabinol Drugs 0.000 description 4
- 229960001252 methamphetamine Drugs 0.000 description 4
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
- B01J3/04—Pressure vessels, e.g. autoclaves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/343—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the pharmaceutical industry, e.g. containing antibiotics
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/003—Downstream control, i.e. outlet monitoring, e.g. to check the treating agents, such as halogens or ozone, leaving the process
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/06—Pressure conditions
- C02F2301/066—Overpressure, high pressure
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The invention discloses a drug harmless treatment device, which is composed by
reaction zone, feeding zone and a reactant treatment zone. The exhaust in feeding
zone is communicated with the upper portion of the reaction zone through a pipeline.
Reaction zone is a cylindrical container with high-temperature and high-pressure, the
stirring device was arranged. The reaction zone's upper portion is further
communicated with reactant treatment zone by a pipeline. The device was used for
treating poisonous substances and controlled drugs by adopting supercritical water
oxidation reaction. This device can degrade more than 99% of organic drug in 5
minutes, and could be used for directly discharging treated drug water. This system
has many advantages, such as simple structure, high efficiency, easy to operate,
maintenance and extension etc. Another important advantage was the secondary
pollution to the environment can be avoided, with no need for a complex tail gas
purification device.
Drawings
20
t 23
F1G.
.22
FIG.2I
411
Description
Drawings
20 t 23
F1G.
.22
FIG.2I
Technical Field The invention relates to the field of chemistry and environmental science and technology, in particular to a chemical drug harmless treatment device.
Background The poisonous substances and intermediate products were harmful to the environment. Prior conventional treatment methods were mainly incineration and direct landfill. Incineration can effectively destroy harmful components of poisonous substances and reduce waste volume and quality, which is the fastest and most effective method to achieve harmless treatment. But the incineration technology cannot be used to treat hazardous liquid wastes, and the safety is not enough in handling poisonous substances. The incomplete oxidation products will form tiny organic particles suspended in the atmosphere and become a component of air pollution. The landfill treatment not only requires a large amount of natural space, but also the biogeochemical process between the landfills has a huge potential risk to the ecological safety of soil and groundwater. In recent years, in order to solve the problem of harmless treatment of poisonous substances, research has been focused on chemical treatment methods. This method was only suitable for waste water with low toxic content, wherein the oxidant generally cannot be reused. And this technology was expensive. UV oxidation method, adsorption-catalytic ozone oxidation and ultrasonic catalytic removal methods developed subsequently, are all treatment methods for industrial wastewater in principle, which can only improve the degradation efficiency of the poisonous liquids with low poisonous content. The degradation rate was still not up to the standard on treating the poisonous substances, and the generated waste liquid will also form a secondary pollution.
Summary of the Invention In order to achieve above purpose, the invention provides a drug harmless treatment device to solve the problem of lacking a harmless drug treatment device in advanced technology. In order to achieve above purpose, the invention provides the following technical schemes:
According to the first aspect of the invention, a drug harmless treatment device, comprising a reaction zone, a feeding zone and a reactant treatment zone which are communicated with the reaction zone, the tail end of the feeding zone is communicated with the upper portion of the reaction zone through a pipeline, the reaction zone is of a cylindrical high-temperature and high-pressure container structure. The stirring device was arranged in the high-temperature and high-pressure container structure. The invention also composed a check valve and a counterbalance valve, the check valve is arranged on the pipeline between the feeding zone and the reaction zone. The reaction zone composed a material storage bottle, a hydrogen peroxide storage bottle, and a first high pressure constant flow pump and a second high pressure constant flow pump. The material storage bottle and the hydrogen peroxide storage bottle were respectively connected to the check valve through pipeline. The reaction zone composed a high temperature reaction kettle, a heating device, and a first heat preservation device. The high temperature reaction kettle was also connected to the counterbalance valve through a pipeline, the heating device was sleeved on the outer peripheral side of the high temperature reaction kettle. The stirring device in reaction zone composed a stirrer motor, a stirrer impeller and a stirrer protection sleeve. Further, the invention also composed a temperature measurer and a controller, the temperature measurer was inserted in the high temperature reaction kettle, the thermocouple of the temperature measurer was divided into three sections, an upper, a middle and a lower section, and the temperature measurer was electrically connected with the controller. The invention also composed a cooling device, the cooling device is arranged on the pipeline between the high temperature reaction kettle and the counterbalance valve, a filter screen is provided on the pipeline between high temperature reaction kettle and the cooling device. The reactant treatment zone composed a gas-liquid separation device. The maximum working pressure of the reaction zone is 35MPa, and the maximum working temperature of the reaction zone is 600°C.
The device was used for treating poisonous substances and controlled drugs by adopting supercritical water oxidation reaction. The device has the advantages of high degradation rate and high degradation speed, can degrade more than 99% of organic
matters. This device can be used for directly discharging treated waste water, were safe and environment-friendly. The device is compact in structure, small in occupied area, simple to operate, easy to adjust and manage and high efficiency. The secondary pollution to the environment was avoided, a complex tail gas purification device is not needed and reduce the burden on the environment. This method has an excellent development prospect and huge economic and social benefits.
Brief Description of Accompanying Drawings In order to explain the invention more clearly, the following will briefly introduce the drawings that need to be used in the description of the prior technology. Obviously, the drawings in the following description are only exemplary, and for those of ordinary skill in the art, without creative work, other implementation drawings can be derived from the provided drawings. FIG. 1 is a structural diagram of a drug harmless treatment device provided in some embodiments of the invention. FIG. 2 is a degradation curve of ice solution under different temperature in a drug harmless treatment device provided in some embodiments of the invention. FIG. 3 is a degradation curve of ice solution under different pressure in a drug harmless treatment device provided in some embodiments of the invention. FIG. 4 is a degradation curve of ice solution under different residence time in a drug harmless treatment device provided in some embodiments of the invention. FIG. 5 is a degradation curve of ice solution under different oxidizing agent solubility in a drug harmless treatment device provided in some embodiments of the invention. FIG. 6 is a degradation curve of heroin solution under different temperature in a drug harmless treatment device provided in some embodiments of the invention. FIG. 7 is a degradation curve of heroin solution under different pressure in a drug harmless treatment device provided in some embodiments of the invention. FIG. 8 is a degradation curve of heroin solution under different residence time in a drug harmless treatment device provided in some embodiments of the invention. FIG. 9 is a degradation curve of heroin solution under different oxidizing agent solubility in a drug harmless treatment device provided in some embodiments of the invention. FIG. 10 is a degradation curve of marijuana solution under different temperature
in a drug harmless treatment device provided in some embodiments of the invention. FIG. 11 is a degradation curve of marijuana solution under different pressure in a drug harmless treatment device provided in some embodiments of the invention. FIG. 12 is a degradation curve of marijuana solution under different residence time in a drug harmless treatment device provided in some embodiments of the invention. FIG. 13 is a degradation curve of marijuana solution under different oxidizing agent solubility in a drug harmless treatment device provided in some embodiments of the invention. In the accompanying drawings: 1 material storage bottle, 2 hydrogen peroxide storage bottle, 3 first high pressure constant flow pump, 4 second high pressure constant flow pump, 5 check valve, 6 explosion-proof gasket, 7 buffer pipeline, 8 pressure indicator, 9 controller, 10 stirrer motor, 11 first heat preservation cover, 12 second heat preservation cover, 13 heating device, 14 high temperature reaction kettle, temperature measurer, 16 first heat preservation device, 17 stirrer impeller, 18 second heat preservation device, 19 stirrer protection sleeve, 20 heat preservation outlet, 21 cooling device, 22 circulating cooling water inlet, 23 counterbalance valve, 24 gas-liquid separation device, 25 a first control valve, 26 a second control valve, 27 a liquid sample collection bottle, 28 a gas collection bottle.
Specific Embodiments of the Invention The following specific embodiments illustrate the implementation of the invention, those familiar with the technology can easily understand the other advantages and effects of the invention from the content disclosed in the specification, obviously, the described embodiments are part of the embodiments of the invention, not all embodiments. Based on the embodiments of the invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of the invention. Embodiment 1 As shown in FIG.1, a drug harmless treatment device in the embodiment, comprising a reaction zone, and a feeding zone and a reactant treatment zone which are communicated with the reaction zone, the tail end of the feeding zone is communicated with the upper portion of the reaction zone through a pipeline, the reaction zone is of a cylindrical high-temperature and high-pressure container
structure, a stirring device is arranged in the high-temperature and high-pressure container structure, and the upper portion of the reaction zone is further communicated with the reactant treatment zone through the pipeline. The technical effects achieved by the embodiment is as follows: a harmless drug treatment device in the embodiment is used to treat poisonous substances and controlled drugs by supercritical water oxidation reaction, which has the advantages of high degradation rate and fast degradation speed, can degrade more than 99% of organic matters, can be used for directly discharging treated waste water, and is safe and environment-friendly; the device is compact in structure, small in occupied area, simple to operate, easy to adjust and manage and high in treatment efficiency; secondary pollution to the environment is avoided, a complex tail gas purification device is not needed, can achieve the purpose of efficiently degrading poisonous substances and controlled drugs, improve the degradation efficiency and reduce the burden on the environment, and the method has an excellent development prospect and huge economic and social benefits. Embodiment 2 As shown in FIG.1, the drug harmless treatment device in the embodiment comprises all technical features in embodiment 1, also comprises a check valve 5 and a counterbalance valve 23, the check valve 5 is arranged on the pipeline between the feeding zone and the reaction zone, the counterbalance valve 23 is arranged on the pipeline between the reaction zone and the reactant treatment zone; the check valve 5 and the counterbalance valve 23 are used to prevent the backflow of sample and to control the pressure of the reactor; the check valve 5 is used to prevent the backflow of the fluid after the reaction, restricting only one-way flow; when the fluid enters the counterbalance valve 23 of the cooling device 21, there is still a high pressure in the kettle, because the pressure in the kettle is to be controlled, which is far greater than atmospheric pressure, it is necessary to ensure that the back pressure valve 23 cannot be opened too much. In some optional embodiments, the reaction zone comprises a material storage bottle 1, a hydrogen peroxide storage bottle 2, a first high pressure constant flow pump 3 and a second high pressure constant flow pump 4, the material storage bottle 1 and the hydrogen peroxide storage bottle 2 are respectively connected to the check valve 5 through pipelines, and the first high pressure constant flow pump 3 is provided on the pipeline between the material storage bottle 1 and the check valve 5,
the second high pressure constant flow pump 4 is provided on the pipeline between the hydrogen peroxide storage bottle 2 and the check valve 5; wherein, the material storage bottle 1 may specifically be a material storage box for storing liquid poisons to be treated; the hydrogen peroxide storage bottle 2 is specifically used for storing hydrogen peroxide; the first high pressure constant flow pump 3 is used to control the flow rate of the liquid sample in the material storage bottle 1, and the second high pressure constant flow pump 4is used to control the flow rate of the liquid sample in the hydrogen peroxide storage bottle 2. In some optional embodiments, the reaction zone comprises a high temperature reaction kettle 14, a heating device 13, a first heat preservation device 16, and a second heat preservation device 18, the high temperature reaction kettle 14 is connected to the check valve 5 through a pipeline, the high temperature reaction kettle 14 is also connected to the counterbalance valve 23 through a pipeline, the heating device 13 is sleeved on the outer peripheral side of the high temperature reaction kettle 14, and the outer peripheral side of the heating device 13 is provided with the first heat preservation device 16 and the second heat preservation device 18, an upper end of the first heat preservation device 16 is provided with a first heat preservation cover 11, and an upper end of the second heat preservation device 18 is provided with a second heat preservation cover 12, the first heat preservation device 16 and the second heat preservation device 18 are an integrated structure or a split structure; in the embodiment, the high temperature reaction kettle 14 is the core equipment of the high-temperature and high-pressure vessel, the high temperature reaction kettle 14 is provided with a liquid-containing liner, wherein the liquid-containing liner is embedded on the high temperature reaction kettle 14 and makes the liquid-containing liner can be stably placed in the internal space of the high temperature reaction kettle 14; first heat preservation device 16 and the second heat preservation device 18 ensure that the temperature of the high temperature reaction kettle 14 will not change seriously, and the temperature of the high temperature reaction kettle 14 during operation is much higher than ambient temperature, the heat preservation device can not only keep heat effectively, but also play a good role in heat insulation and maintain stability. In some optional embodiments, the stirring device in the reaction zone comprises a stirrer motor 10, a stirrer impeller 17 and a stirrer protection sleeve 19, and the stirrer motor 10 is arranged outside the high temperature reaction kettle 14, the stirrer
impeller 17 is arranged in the high temperature reaction kettle 14, an output shaft of the stirrer motor 10 is connected to the stirrer impeller 17, and the connecting shaft between the output shaft of the stirrer motor 10 and the stirrer impeller 17 is sleeved with the stirrer protection sleeve 19; the stirring device stirs the liquid in the high temperature reaction kettle 14, in addition, the sample outlet end of the high temperature reaction kettle 14 is equipped with a pressure indicator to observe the pressure in the reaction kettle. In some optional embodiments, the invention also comprises a temperature measurer 15 and a controller 9, the temperature measurer 15 is inserted in the high temperature reaction kettle 14, the thermocouple of the temperature measurer 15 is divided into three sections according to different height, an upper, a middle and a lower section, which can effectively observe the temperature change at different heights in the kettle, wherein the temperature at middle section controls the heating temperature of the electric heating coil, the temperature measurer 15 is electrically connected with the controller 9, the temperature measurer 15 is adjusted and displayed by the temperature control box in the controller 9; in addition, the controller 9 also controls the heater, temperature sensor, pressure sensor and motor tachometer respectively; the controller 9 can be integrated into a control panel. In some optional embodiments, the invention also comprises a pressure indicator 8, an explosion-proof gasket 6 and a buffer pipeline 7, the buffer pipeline 7 is vertically arranged on the pipeline between the check valve 5 and the high temperature reaction kettle 14, a lower end of the buffer pipeline 7 is connected to the explosion-proof gasket 6, an upper end of the buffer pipeline 7 is connected to the pressure indicator 8, the pressure indicator 8 is electrically connected with the controller 9; the arrangement of the explosion-proof gasket 6 can prevent sudden rapid air leakage due to high pressure; the pressure indicator 8 is easy to observe the pressure in the kettle of high temperature reaction kettle 14. In some optional embodiments, the invention also comprise a cooling device 21, the cooling device 21 is arranged on the pipeline between the high temperature reaction kettle 14 and the counterbalance valve 23, a filter screen is provided on the pipeline between high temperature reaction kettle 14 and the cooling device 21, a heat preservation outlet 20 is provided on the side of the second heat preservation cover 12, and the heat preservation outlet 20 is sleeved on the pipeline between the high temperature reaction kettle 14 and the cooling device 21, a circulating cooling water
inlet 22 is provided at an lower end of the cooling device 21. In some optional embodiments, the reactant treatment zone comprises a gas liquid separation device 24, a first control valve 25, a second control valve 26, a liquid sample collection bottle 27, and a gas collection bottle 28, the gas-liquid separation device 24 is connected to the counterbalance valve 23 through a pipeline, and the gas liquid separation device 24 is also connected to a liquid collection bottle 27 and a gas collection bottle 28 respectively through pipelines, the first control valve 25 is provided on the pipeline between the gas-liquid separation device 24 and the gas collection bottle 28, the second control valve 26 is provided on the pipeline between the gas-liquid separation device 24 and the liquid collection bottle 27, an online measuring system is arranged on the second control valve 26; during the use of the gas-liquid separation device 24, it is usually selected to open the first control valve 25 first to separate the gas phase of the reaction system, and then open the second control valve 26 to take out the remaining liquid and perform component analysis. In some optional embodiments, the maximum working pressure of the reaction zone is 35MPa, and the maximum working temperature of the reaction zone is 600°C.
The drug harmless treatment device in the above embodiment uses organic components in supercritical water to form a homogeneous phase with water, which can be quickly oxidized to form a non-toxic and harmless solution and gas, the device can make the solution reach supercritical state (>374°C, >22.1MPa), where the internal pressure of the high temperature reaction kettle 14 can be stabilized at the required setting according to actual conditions. In the above embodiment, the hydrogen peroxide and the second high pressure constant flow pump 4 can be replaced with an air compressor, the purpose of which is to provide oxygen in the air as an oxidant to the reaction system to ensure that the reaction can proceed quickly; the pressure in the kettle can be appropriately reduced according to the switch of the control of counterbalance valve 23, thereby the pressure in the kettle can be controlled within a certain range; each interface and valve in the reaction system must be made of temperature and pressure resistant materials. Embodiment 3 In the drug harmless treatment device in the embodiment, the degradation of the ice solution at different temperatures is shown in FIG.2, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and ice (methamphetamine) is
used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C-600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; After preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the reaction temperature was controlled to 375C, 400°C, 450°C, 500°C, 550°C and 600°C, respectively, and other conditions were unchanged (pressure MPa, residence time 2min, hydrogen peroxide 18ml). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02, H20, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized toC0 2 ,
H 20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 4 In the drug harmless treatment device in the embodiment, the degradation of the ice solution at different pressures is shown in FIG.3, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and ice (methamphetamine) is used as the raw material for degradation, and many devices such as gas chromatograph mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and
headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by °C/min, and the heating temperature is 375°C-600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the reaction pressure was controlled to 17MPa, 21MPa, 23MPa, 25MPa and 30MPa, respectively, and other conditions were unchanged (temperature 450°C, residence
time 2min, hydrogen peroxide 18ml). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C0 2 , H 20, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C0 2 , H 20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 5 In the drug harmless treatment device in the embodiment, the degradation of the ice solution for different residence time is shown in FIG.4, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and ice (methamphetamine) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high
in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C-600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the residence time was controlled to 30s, 60s, 90s, 120s and 180s, respectively, and other conditions were unchanged (temperature 450°C, pressure
MPa, hydrogen peroxide 18ml). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02, H20, and the presence of a small amount of small organic molecules and N2, the small molecules can continue to be oxidized to C0 2 , H 20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 6 In the drug harmless treatment device in the embodiment, the degradation of the ice solution at different amount of the hydrogen peroxide is shown in FIG.5, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and ice (methamphetamine) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the
temperature must not change by 10°C/min, and the heating temperature is 375°C 600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the amount of hydrogen peroxide was controlled to 9ml, 18ml, 27ml and 36ml, respectively, and other conditions were unchanged (temperature 450°C, pressure 25MPa, residence time 2min). Since the
organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02 , H2 0, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C02, H20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 7 In the drug harmless treatment device in the embodiment, the degradation of the heroin solution at different temperatures is shown in FIG.6, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and heroin (diacetylmorphine) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C-600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the
pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the reaction temperature was controlled to 375C, 400°C, 450°C, 500°C,
550°C, 600°C, and other conditions were unchanged (pressure 25MPa, residence time
2min, hydrogen peroxide 18ml). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C0 2
, H20, and the presence of a small amount of small organic molecules and N2, the small molecules can continue to be oxidized to C02 , H 20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 8 In the drug harmless treatment device in the embodiment, the degradation of the heroin solution at different pressures is shown in FIG.7, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and heroin (diacetylmorphine) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C-600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and
then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the reaction pressure was controlled to 17MPa, 21MPa, 23MPa, 25MPa, MPa respectively, and other conditions were unchanged (temperature 450°C,
residence time 2min, hydrogen peroxide 18ml). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02 , H 20, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C0 2 , H20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 9 In the drug harmless treatment device in the embodiment, the degradation of the heroin solution for different residence time is shown in FIG.8, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and heroin (diacetylmorphine) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C 600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and
configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the residence time was controlled for s, 60s, 90s, 120s and 180s, respectively, and other conditions were unchanged (temperature 450°C, pressure 25MPa, hydrogen peroxide 18ml). Since the organic
matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02, H20, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C0 2
, H 20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 10 In the drug harmless treatment device in the embodiment, the degradation of the heroin solution at different amount of the hydrogen peroxide is shown in FIG.9, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and heroin (diacetylmorphine) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C 600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process
of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the amount of hydrogen peroxide was controlled to 9ml, 18ml, 27ml and 36ml, respectively, and other conditions were unchanged (temperature 450°C, pressure 25MPa, residence time 2min). Since the
organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02 , H2 0, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C02, H20, and the liquid and gas will not pollute the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 11 In the drug harmless treatment device in the embodiment, the degradation of the marijuana solution at different temperatures is shown in FIG.10, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and marijuana (tetrahydrocannabinol, cannabinol) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C 600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and
pressure, and analyzing the composition thereof, the reaction temperature was controlled to 375°C, 400°C, 450°C, 500°C, 550°C, 600°C, and other conditions were
unchanged (pressure 25MPa, residence time 2min, hydrogen peroxide 18ml). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02, H20, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C0 2 , H 20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 12 In the drug harmless treatment device in the embodiment, the degradation of the marijuana solution at different pressures is shown in FIG.11, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and marijuana (tetrahydrocannabinol, cannabinol) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C 600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; After preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the reaction pressure was controlled to 17MPa, 21MPa, 23MPa, 25MPa and 30MPa, respectively,
and other conditions were unchanged (temperature 450°C, residence time 2min,
hydrogen peroxide 18ml). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C0 2 , H2 0, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C02, H20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 13 In the drug harmless treatment device in the embodiment, the degradation of the marijuana solution for different residence time is shown in FIG.12, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and marijuana (tetrahydrocannabinol, cannabinol) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C 600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the residence time was controlled for s, 60s, 90s, 120s and 180s, respectively, and other conditions were unchanged (temperature 450°C, pressure 25MPa, hydrogen peroxide 18ml). Since the organic
matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C02, H20, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C0 2
, H 20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Embodiment 14 In the drug harmless treatment device in the embodiment, the degradation of the marijuana solution at different amount of the hydrogen peroxide is shown in FIG.13, hydrogen peroxide is used as the oxidant of the reaction to accelerate the reaction, and marijuana (tetrahydrocannabinol, cannabinol) is used as the raw material for degradation, and many devices such as gas chromatograph-mass spectrometer (GC/MS), fourier transform infrared spectrometer (FTIR) and headspace gas chromatograph are used to analyze the organic components of the sample; because the temperature and pressure requirements are extremely high in the state of supercritical water, the heating device 13 requires good heat preservation and heat insulation, during heat preservation, the temperature must not change by 10°C/min, and the heating temperature is 375°C-600°C. In the preparation process, first opening all the valves of the device to discharge the liquid and gas in the pipeline, and then closing the valve after the reaction kettle, after checking that the device does not leak, opening the counterbalance valve 23 to discharge the gas, and then closing the counterbalance valve 23, and finally adding samples through a high pressure constant flow pump, and configuring the samples according to the oxidant solubility; after preparation, opening the heater and the stirrer motor 10 to select the rotating speed to perform the process of heating and stirring the solution, controlling the reaction temperature and pressure, obtaining the liquid and gas of the reaction product at the required temperature and pressure, and analyzing the composition thereof, the amount of hydrogen peroxide was controlled to 9ml, 18ml, 27ml and 36ml, respectively, and other conditions were unchanged (temperature 450°C, pressure 25MPa, residence
time 2min). Since the organic matter remains homogeneous with water in the supercritical water, the two can be dissolved together indefinitely, and oxygen can
also fully participate in the reaction, which greatly speeds up the reaction and shortens the degradation time. The products after the reaction are mainly C0 2 , H2 0, and the presence of a small amount of small organic molecules and N 2 , the small molecules can continue to be oxidized to C02, H20, and the liquid and gas will not contaminate the environment. These products can be used as indicators for determining whether the sample is completely degraded, harmless and non-toxic, and can be safely discharged. Although the invention has been described in detail above with general descriptions and specific embodiments, some modifications or improvements can be made on the basis of the invention, which is obvious to those skilled in the art. Therefore, all these modifications or improvements made without departing from the spirit of the invention shall be included in the scope of the invention. The terms such as "upper", "lower", "left", "right", "middle", etc. quoted in the specification are only for ease of description and are not used to limit the scope of embodiments of the invention, the change or adjustment of the relative relationship shall also be regarded as the applicable scope of the invention without substantial change in the technical content.
Claims (10)
1. The drug harmless treatment device, composed a reaction zone, feeding zone and a reactant treatment zone which are communicated with the reaction zone. The feeding zone was communicated with the upper portion of the reaction zone through a pipeline, the reaction zone was a container with high-temperature and high-pressure, a stirring device was arranged.
2. The drug harmless treatment device of claim 1, also composed a check valve (5) and a counterbalance valve (23), the check valve (5) is arranged on the pipeline between the feeding zone and the reaction zone, the counterbalance valve (23) was arranged on the pipeline between the reaction zone and the reactant treatment zone.
3. The drug harmless treatment device of claim 2, the reaction zone composed a material storage bottle (1), a hydrogen peroxide storage bottle (2), a first high pressure constant flow pump (3) and a second high pressure constant flow pump (4), the material storage bottle (1) and the hydrogen peroxide storage bottle (2) are respectively connected to the check valve (5) through pipelines, and the first high pressure constant flow pump (3) is provided on the pipeline between the material storage bottle (1) and the check valve (5), the second high pressure constant flow pump (4) is provided on the pipeline between the hydrogen peroxide storage bottle (2) and the check valve (5).
4. The drug harmless treatment device of claim 3, the reaction zone composed a high temperature reaction kettle (14), a heating device (13), a first heat preservation device (16), and a second heat preservation device (18). The high temperature reaction kettle (14) was connected to the check valve (5) through a pipeline, the high temperature reaction kettle (14) was also connected to the counterbalance valve (23) through a pipeline, the heating device (13) was sleeved on the outer peripheral side of the high temperature reaction kettle (14), and the outer peripheral side of the heating device (13) was provided with the first heat preservation device (16).
5. The drug harmless treatment device of claim 4, the stirring device in the reaction zone composed a stirrer motor (10), a stirrer impeller (17) and a stirrer protection sleeve (19).
6. The drug harmless treatment device of claim 5, also composed a temperature measurer (15) and a controller (9), the temperature measurer (15) was inserted in the high temperature reaction kettle (14).
7. The drug harmless treatment device of claim 6, also composed a pressure indicator (8), an explosion-proof gasket (6) and a buffer pipeline (7). The buffer
pipeline (7) was vertically arranged on the pipeline between the check valve (5) and the high temperature reaction kettle (14), a lower end of the buffer pipeline (7) was connected to the explosion-proof gasket (6).
8. The drug harmless treatment device of claim 7, also composed a cooling device (21), the cooling device (21) was arranged on the pipeline between the high temperature reaction kettle (14) and the counterbalance valve (23), a filter screen is provided on the pipeline between high temperature reaction kettle (14).
9. The drug harmless treatment device of claim 8, the reactant treatment zone composed a gas-liquid separation device (24). This gas-liquid separation device (24) was also connected to a liquid collection bottle (27) and a gas collection bottle (28) respectively through pipelines.
10. The drug harmless treatment device of claim 1, the maximum working pressure of the reaction zone is 35MPa, and the maximum working temperature of the reaction zone is 600°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2021102475A AU2021102475A4 (en) | 2021-05-11 | 2021-05-11 | A drug harmless treatment device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2021102475A AU2021102475A4 (en) | 2021-05-11 | 2021-05-11 | A drug harmless treatment device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2021102475A4 true AU2021102475A4 (en) | 2021-07-01 |
Family
ID=76584575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2021102475A Ceased AU2021102475A4 (en) | 2021-05-11 | 2021-05-11 | A drug harmless treatment device |
Country Status (1)
| Country | Link |
|---|---|
| AU (1) | AU2021102475A4 (en) |
-
2021
- 2021-05-11 AU AU2021102475A patent/AU2021102475A4/en not_active Ceased
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2577958C (en) | Device and installation for injecting particulate matter into an enclosure and associated method | |
| CN102107928A (en) | Pretreatment technique and equipment for degrading high-concentration organic waste water by power ultrasonic cavitation | |
| MX2008008590A (en) | Method for degassing a liquid. | |
| CN101868426A (en) | Hyperoxidation advanced oxidative treatment of water | |
| AU711513B2 (en) | Treatment of liquors | |
| CN104496004A (en) | High-concentration organic pesticide wastewater supercritical water oxidation treatment system and method | |
| AU2021102475A4 (en) | A drug harmless treatment device | |
| CN111517446A (en) | Drug innocent treatment device | |
| US11110390B1 (en) | Systems and methods for treating sterilization exhaust gas containing ethylene oxide | |
| CN107731336B (en) | The method of combination of ultrasound wet oxidation Fenton method processing radioactive wastewater | |
| CN212246370U (en) | Drug innocent treatment device | |
| CN101502842B (en) | Emergency quick processing device and processing method for toxic organic chemical polluted soil | |
| CN203639220U (en) | High-concentration critical sewage treatment system | |
| CN217838478U (en) | Ozone oxidation lab scale experimental apparatus for sewage treatment | |
| CN105300749B (en) | A kind of chemical oxygen demand of waste water detection pretreatment unit and method | |
| CN210237220U (en) | Device for treating wastewater by catalytic oxidation of ozone | |
| CN210855432U (en) | Novel landfill leachate wet oxidation device | |
| CN219084866U (en) | Dangerous waste compatibility test device | |
| CN208843913U (en) | SBR partial nitrification-UASB Anammox combination test apparatus | |
| Xu et al. | Ultrasonic decomposition of ammonia‐nitrogen and organic compounds in coke plant wastewater | |
| CN216337102U (en) | Isopropyl alcohol effluent disposal system | |
| WO2021184597A1 (en) | Systems and methods for treating sterilization exhaust gas containing ethylene oxide | |
| CN109264847A (en) | A kind of ozone pressurization mixed dissolution system | |
| CN216964621U (en) | Portable hazardous chemicals processing apparatus | |
| JP4250778B2 (en) | High temperature high pressure fluid cooling method and apparatus |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGI | Letters patent sealed or granted (innovation patent) | ||
| MK22 | Patent ceased section 143a(d), or expired - non payment of renewal fee or expiry |