AU2017200185B2 - Reducing refrigeration duty on a refrigeration unit in a gas processing system - Google Patents

Reducing refrigeration duty on a refrigeration unit in a gas processing system Download PDF

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AU2017200185B2
AU2017200185B2 AU2017200185A AU2017200185A AU2017200185B2 AU 2017200185 B2 AU2017200185 B2 AU 2017200185B2 AU 2017200185 A AU2017200185 A AU 2017200185A AU 2017200185 A AU2017200185 A AU 2017200185A AU 2017200185 B2 AU2017200185 B2 AU 2017200185B2
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stream
pressure
process stream
feedstock
heat exchanger
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AU2017200185A1 (en
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Eduardo Andrade
Negar Davani
David Allen Kennedy
John Raymond ZIGTEMA
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GE Oil and Gas Inc
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GE Oil and Gas Inc
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022Hydrocarbons, e.g. natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/007Primary atmospheric gases, mixtures thereof
    • F25J1/0072Nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/008Hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0204Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle as a single flow SCR cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0208Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0211Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
    • F25J1/0212Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a single flow MCR cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0211Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
    • F25J1/0219Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0229Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
    • F25J1/0231Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the working-up of the hydrocarbon feed, e.g. reinjection of heavier hydrocarbons into the liquefied gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257Construction and layout of liquefaction equipments, e.g. valves, machines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/08Separating gaseous impurities from gases or gaseous mixtures or from liquefied gases or liquefied gaseous mixtures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/02Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/64Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30Compression of the feed stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/60Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being hydrocarbons or a mixture of hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/40Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/66Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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Abstract

REDUCING REFRIGERATION DUTY ON A REFRIGERATION UNIT IN A GAS PROCESSING SYSTEM ABSTRACT A liquefaction process configured to facilitate thermal transfer in a heat exchanger during liquefaction of a natural gas feedstock. The liquefaction process can include compressing a process stream to a first pressure, the process stream comprising predominantly methane, cooling the process stream to a first temperature, expanding the process stream from the first pressure to a second pressure that is less than the first pressure, bleeding-off a first product from the process stream at the second pressure, and conditioning the first product for storage as liquid natural gas (LNG). 5/9 0 0 o4 0 (Ko N NC 0 co LOC

Description

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LOC REDUCING REFRIGERATION DUTY ON A REFRIGERATION UNIT IN A GAS PROCESSING SYSTEM
[0001] This application claims priority from US Patent Application No. 14/992,655 filed 11 January 2016, the contents of which are to be taken as incorporated herein by this reference.
BACKGROUND
[0002] Liquefying natural gas can facilitate transport and storage of hydrocarbons and related material. Generally, the processes greatly reduce the volume of gas. The resulting liquid is well-suited to transit long distances through pipelines and infrastructure. It is particularly economical for transport overseas and/or to areas that are not accessible by such pipeline infrastructure.
[0003] A reference herein to a patent document or other matter which is given as prior art is not to be taken as an admission that the document or matter was known or that the information it contains was part of the common general knowledge as at the priority date of any the claims.
SUMMARY
[0004] The subject matter of this disclosure relates generally to liquefaction processes. The embodiments address refrigeration requirements of a heat exchanger (or "cold box") necessary to liquefy an incoming hydrocarbon feed to a liquefied product. In one application, the embodiments incorporate a fluid circuit to liquefy a natural gas feed to liquid natural gas (LNG).
[0005] According to one aspect of the present invention, there is provided a liquefaction process, comprising: receiving a feedstock; forming a process stream from the feedstock by separating the feedstock into a first stream and a first bottom product, the process stream comprising a first stream and a second stream; distilling the first bottom product to form a second stream and a second bottom product, each of the first stream and the second stream comprising predominantly methane vapor; compressing the process stream to a first pressure; cooling the process stream to a first temperature; expanding the process stream from the first pressure to a second pressure that is less than thefirst pressure; bleeding-off a liquid product from the process stream at the second pressure; conditioning the liquid product for storage as liquid natural gas (LNG) and conditioning the second bottom product to form a liquid petroleum gas (LPG).
[0006] According to a second aspect of the present invention, there is provided a gas processing system, comprising: a pre-processing unit configured to receive a feedstock and form a process stream from the received feedstock by separating the feedstock into a first stream and a first bottom product, the process stream comprising a first stream and a second stream; distilling the first bottom product to form a second stream and a second bottom product, each of the first streamandthesecondstream comprising predominantly methane vapor; a heat exchanger; a fluid circuit coupled with the heat exchanger, the fluid circuit directing the process stream through the heat exchanger, wherein the fluid circuit is configured to: compress the process stream to a first pressure; pass the process stream through the heat exchanger at the first pressure; expand the process stream from the first pressure to a second pressure that is less than the first pressure; bleed-off a liquid product from the process stream at the second pressure; condition the liquid product for storage as liquid natural gas (LNG); and condition the second bottom product to form a liquid petroleum gas (LPG).
[00071 There is also disclosed herein a gas processing system, comprising: a heat exchanger; and a fluid circuit coupled with the heat exchanger, the fluid circuit configured to circulate a process stream through the heat exchanger, the fluid circuit comprising: a methane compressor coupled to the heat exchanger; a turbo-compressor interposed between the methane compressor and the heat exchanger; a turbo-expander coupled to the compressor and to the heat exchanger; and a first separator unit interposed between the turbo-expander and the heat exchanger.
[0008] As noted more below, the improvements afford the embodiments herein with many capabilities and/or advantages. The fluid circuit can take on some of the duty cycle of a primary refrigeration unit that cool the heat exchanger. This feature can permit the embodiments to expand or increase production of LNG product to levels that would normally outstrip operation of certain equipment (e.g., compressors) in the liquefaction system. Use of the embodiments can allow the liquefaction system to increase production levels by approximately 80 % using the default or initial configuration or, for purposes of example, to increase production from 450,000 gpd to approximately 800,000 gpd. Moreover, liquefaction systems that supplement cooling of the heat exchanger with the embodiments can operate at or above efficiencies as compared to other auxiliary refrigeration systems (e.g., propane pre cooling), particularly at production levels at less than 700,000 gpd.
[0009] These production improvements come at limited, if any, capital and/or operating expenses. Liquefaction systems that incorporate the fluid circuit of the embodiments herein require little design changes to the primary refrigeration system. This
2a feature can forgo the need to modify refrigerants and/or equipment, lines, controls, and/or other components of the primary refrigeration system.
[0010] The embodiments may find use in many different types of processing facilities. These facilities may be found onshore and/or offshore. In one application, the embodiments can incorporate into and/or as part of processing facilities that reside on land, typically on (or near) shore. These processing facilities can process natural gas feedstock from production facilitates found both onshore and offshore. Offshore production facilitates use pipelines to transport feedstock extracted from gas fields and/or gas-laden oil-rich fields, often from deep sea wells, to the processing facilitates. For LNG processing, the processing facility can turn the feedstock to liquid using suitably configured refrigeration equipment or "trains." In other applications, the embodiments can incorporate into production facilities on board a ship (or like floating vessel), also known as a floating liquefied natural gas (FLNG) facility.
BRIEF DESCRIPTION OF THE DRAWINGS
[0011] Reference is now made briefly to the accompanying drawings, in which:
[0012] FIG. 1 depicts a flow diagram of an exemplary embodiment of a process to liquefy a hydrocarbon feedstock to liquid natural gas (LNG) for storage;
[0013] FIG. 2 depicts a flow diagram of an example of the process of FIG. 1;
[0014] FIG. 3 depicts a schematic diagram of an exemplary embodiment of a system that can liquefy an incoming hydrocarbon feedstock to a product that meets specifications for liquefaction to liquid natural gas (LNG) ;
[0015] FIG. 4 depicts a schematic diagram of an example of the system of FIG. 3 that can accommodate an incoming hydrocarbon feedstock with a high level of impurities;
[0016] FIG. 5 depicts a schematic diagram of a first configuration of components to form a fluid circuit in an example of the system of FIG. 3;
[0017] FIG. 6 depicts a schematic diagram of a second configuration of components to form a fluid circuit in an example of the system of FIG. 3;
[0018] FIG. 7 depicts a schematic diagram of an example of the system of FIG. 3 that can accommodate an incoming hydrocarbon feedstock with a high level of impurities;
[0019] FIG. 8 depicts a schematic diagram of an example of the system of FIG. 7; and
[0020] FIG. 9 a schematic diagram of an example of the system of FIG. 7.
[0021] Where applicable like reference characters designate identical or corresponding components and units throughout the several views, which are not to scale unless otherwise indicated. The embodiments disclosed herein may include elements that appear in one or more of the several views or in combinations of the several views. Moreover, methods are exemplary only and may be modified by, for example, reordering, adding, removing, and/or altering the individual stages.
DETAILED DESCRIPTION
[0022] FIGS. 1 and 2 illustrate flow diagrams of an exemplary embodiment of a process 10 to liquefy an incoming hydrocarbon feedstock. As shown in FIG. 1, the embodiments may include, at stage 12, receiving a feedstock and, at stage 14, forming a process stream from the feedstock, the process stream comprising predominantly methane in a concentration of 92 % or greater. The process 10 can also include, at stage 16, compressing the process stream to a first pressure and, at stage, 18, cooling the process stream to a first temperature. The process 10 can further include, at stage 20, expanding the process stream from the first pressure to a second pressure that is less than the first pressure. The process 10 can include, at stage 22, bleeding-off a first stream from the process stream at the second pressure and, at stage 24, conditioning the first stream for storage as liquid natural gas (LNG). In one implementation, the process 10 can include, at stage 26, compressing the process stream from the second pressure to an intermediate pressure that is between the first pressure and the second pressure. The process 10 can then continue to further compress the process stream at stage 16.
[0023] In the example of FIG. 2, the process 10 can include, at stage 14, various stages to accommodate an incoming hydrocarbon feedstock with a high level of impurities. The process 10 can include, at stage 28, separating the feedstock into a first stream and a first bottom product. The process 10 can also include, at stage 30, introducing the first stream into the process stream at the intermediate pressure. In one implementation, the process 10 can include, at stage 32, distilling the first bottom product to form a second stream and a second bottom product and, at stage 34, introducing the second stream into the process stream at the second pressure. The process 10 can further include, at stage 36, conditioning the second bottom product to form a liquid petroleum gas (LPG).
[0024] FIG. 3 illustrates a schematic diagram of an exemplary embodiment of a gas processing system 100 (also, "system 100") for use to process natural gas and like hydrocarbon materials. The system 100 may include an expansion unit 102 and a refrigeration unit 104, each coupled with a heat exchanger 106. Examples of the heat exchanger 106 or "cold box" can feature brazed aluminum fins ("plate-fin exchanger") and/or coils ("coil wound exchanger). These devices can facilitate thermal transfer by indirect contact between fluids. The fluids may include a refrigerant 108 that the refrigeration unit 104 circulates through the heat exchanger 106. Examples of the refrigerant 108 can have a composition comprising one or more constituent components including light hydrocarbons (e.g., methane, ethane, propane, etc.) and/or nitrogen. In one implementation, the composition is consistent with a "mixed" refrigerant cycle.
[0025] The expansion unit 102 can be configured to reduce the duty cycle on the refrigeration unit 104 necessary to cool the heat exchanger 106. These configurations can be used in lieu of auxiliary or supplementary refrigeration units (e.g., propane coolers) that may provide supplemental cooling and/or pre-cooling of fluids in the heat exchanger 106. The expansion unit 102 can include a fluid circuit 110 that circulates fluid through the heat exchanger 106. For clarity, the fluid that circulates in the fluid circuit 110 is identified as a process stream 112. Examples of the process stream 112 can have a composition that is predominantly methane in liquid and/or vapor forms. In one implementation, the fluid circuit 110 can be configured to bleed-off a first product 114 from the process stream 112. The first product 114 may meet specifications for liquid natural gas (LNG). The system 100 can direct the first product 114 from the heat exchanger 106 to a storage facility 116 or other post liquefaction facility, as desired. Notably, use of the expansion unit 102 can expand the range of production levels of LNG product (e.g., the first product 114) on the system 100. It is reasonable that the system 100 can expand production levels of LNG product from approximately 450,000 gpd to approximately 800,000 gpd.
[0026] The system 100 can operate on incoming natural gas and like hydrocarbon streams. As shown in FIG. 1, the fluid circuit 110 may receive these streams as a feedstock 118 from a source 120. The source 120 may include pre-treatment equipment that process natural gas from production facilities (e.g., well-head, pipeline, etc.). These processes can result in "dry sweet gas" with a composition that is predominantly methane (e.g., in a concentration of 84 % (840,000 ppmV) or greater) and with a concentration of water that is less than 0.0001 % (1 ppmV). For compositions that lack significant levels of impurities, the fluid circuit 110 can be configured to directly circulate the feedstock 118 as the process stream 112. These compositions may, for example, have concentrations of methane that are 98 % (980,000 ppmV) or greater. However, at least one benefit of the expansion unit 102 is that it can be configured in manner that can remove impurities from the feedstock 118 prior to, or upstream of, the fluid circuit 110.
[0027] FIG. 4 illustrates an example of the system 100 that can handle compositions of the feedstock 118 with higher levels of impurities. At a high level, the expansion unit 102 may include a pre-processing unit 122 upstream of the fluid circuit 110. The pre-processing unit 122 can receive the feedstock 118 via pipeline and/or other modality from the source 120. In one implementation, the pre-processing unit 122 can form a feedstream 124 and a second product 126. The system 100 can direct the feedstream 124 into fluid circuit 110 for use as the process stream 112. The second product 126 can be a derivative product that is useful for fuel. Such derivative products may have a composition of hydrocarbon gases (e.g., propane, butane, etc.) and/or like constituent components. The composition may be consistent with a liquid petroleum gas (LPG) product. The system 100 may be configured to direct this LPG product to a collateral system 128 for further processing and/or storage, e.g., in a tank.
[0028] FIG. 5 depicts a first configuration of components to implement the fluid circuit 110. This first configuration forms an open loop to circulate the process stream 112 through the heat exchanger 106. The open loop includes a turbo-machine 130, preferably with a turbo-compressor 132 that is configured to operate in response to work from a turbo expander 134. The turbo-compressor 132 can have an inlet 136 and an outlet 138 that couple with the heat exchanger 106 and with a methane compressor 140, respectively. As also shown in FIG. 6, the turbo-expander 134 can have an inlet 142 and an outlet 144. The inlet 142 can couple with the heat exchanger 106. The outlet 144 can couple with a first separator unit 146, which itself couples with the heat exchanger 106.
[0029] Starting at the methane compressor 140, the fluid circuit 110 can use the feedstock 118 from the source 120 without any upstream processing. This first configuration may be useful with incoming natural gas with low levels of impurities. In one implementation, incoming feedstock 118 is introduced into the methane compressor 140, typically at a temperature of from approximately 80 °F to approximately 120 °F. The methane compressor 140 can be configured to accommodate in-flow pressures for the feedstock 118 of approximately 450 psig and larger. However, this disclosure does consider that the methane compressor 140 and the fluid circuit 110, generally, can be configured for use of the system 100 across a wide range of applications to accommodate in-flow pressures that vary in accordance with the source 120, as necessary. Such configurations may vary the location(s) at which the incoming feedstock 118 is introduced to the process stream 112 in the methane compressor 140.
[0030] The methane compressor 140 can be configured to modify temperature and pressure of the process stream 112. These configurations may flow the process stream 112 through one or more cooling devices (e.g., air coolers). In this way, the process stream 112 can exit the methane compressor 140 (at 148) at a temperature of approximately 20 °F above ambient temperature that prevails at the location of the system 100. In one implementation, the methane compressor 140 may also pressurize the process stream 112 so that the process stream 112 (at 148) is at a pressure of 1200 psig. The pressure may be selected based on construction considerations (e.g., flange ratings) for the fluid circuit 110; for example, operating the system 100 at pressures not in excess of 1200 psig will require flanges rated at class 600 lbs. or less, thus potentially providing a considerable cost savings. Other temperatures and pressures for the process stream 112 (at 148) may be useful, as well.
[0031] The system 100 may direct the process stream 112 across a first pass of the heat exchanger 106 to further reduce the temperature. The heat exchanger 106 can be configured so that the process stream 112 enters the inlet 142 of the turbo-expander 134 at approximately - 90 °F and/or otherwise in a range of from approximately -70 °F to approximately -110 °F. In turn, the turbo-expander 134 can reduce the pressure of the process stream 112. For example, the process stream 112 can exit the turbo-expander 134 (at 150) as a mixed phase effluent (e.g., liquid and vapor). The process stream 112 (at 150) can have an outlet pressure that ensures efficient operation of the system 100. Examples of the turbo expander 134 can operate so that outlet pressure maintains an expansion ratio with the pressure of the process steam 112 (at 148) of from three and four; however, this disclosure contemplates that the outlet pressure may maintain the expansion ratio in range of from three and ten, as desired. In one example, the outlet pressure can be in a range of from approximately 285 psig to approximately 385 psig to accommodate operation of the methane compressor 140 to pressurize the process stream 112 to 1200 psig.
[0032] The fluid circuit 110 directs the process stream 112 from the turbo-expander 134 to the first separator unit 146. Processing of the process stream 112 in the first separator unit 146 may result in a bottom product 152 and a top product 154. The products 152, 154 exit the bottom and top of the first separator unit 146 in liquid and vapor form, respectively. The liquid bottom product 152 transits a second pass of the heat exchanger 106. This second pass conditions the liquid bottom product 152, typically reducing the temperature to form the first product 114 at and/or near temperatures for storage at the storage facility 116. The storage temperatures may be in a range of from approximately -250 °F to approximately -270 °F.
[0033] The vapor top product 154 forms the process stream 112 that continues to circulate through the fluid circuit 110. In one implementation, the fluid circuit 110 directs the process stream 112 through a third pass of the heat exchanger 106. This third pass can decrease the temperature of the process stream 112, typically by expelling thermal energy to fluid in one of the other passes in the heat exchanger 106. The system 100 can be configured so that the temperature of the process stream 112 at the inlet 136 of the turbo-compressor 132 is in a range of from approximately 80 °F to approximately 120 °F.
[0034] The turbo-compressor 132 can pressurize the process stream 112. In one implementation, the turbo-compressor 132 discharges the process stream 112 (at 156) at an intermediate pressure, preferably between the discharge (or first) pressure (at 148) of the methane compressor 140 and the discharge (or second) pressure (at 150) of the turbo expander 134. This intermediate pressure may be a range from approximately 400 psig to approximately 600 psig. The fluid circuit 110 can direct the process stream 112 at the intermediate pressure back to the methane compressor 140. As noted above, the fluid circuit 110 can introduce the feedstock 118 into the process stream 112 so that the resulting mixed stream exits the methane compressor 140 (at 148).
[0035] FIG. 6 depicts a second configuration of components to implement the fluid circuit 110. The methane compressor 140 has a compression circuit 158 with a first end 160 and a second end 162, one each coupled with the turbo-compressor 132 and the heat exchanger 106, respectively. At a high level, the compression circuit 158 may be configured to increase the pressure and without increasing the temperature of the process stream 112 from the first end 160 to the second end 162. Such function may utilize various components (e.g., coolers, compressors, etc.). In one implementation, the compression circuit 158 may include one or more coolers (e.g., a first cooler 164, a second cooler 166, and a third cooler 168). The coolers 164, 166, 168 may be air-cooled, although this disclosure does not limit selection to any particular type or variation for these devices. The compression circuit 158 may also include one or more compressors (e.g., a first compressor 170 and a second compressor 172). The compressors 170, 172 may be disposed between adjacent coolers 164, 166, 168 to maintain and/or raise the pressure of process stream 112 (at 148) at the temperature and pressure noted herein.
[0036] FIG. 7 depicts an example of the pre-processing unit 122 for use with the system 100. In one implementation, the pre-processing unit 122 may include a second separator unit 174 that couples with a demethanizer unit 176. The second separator unit 174 can remove heavy hydrocarbons from the feedstock 118. This feature is useful to avoid problems in the system 100 due to freeze out of impurities downstream and/or in storage, e.g., in the storage facility 116. The demethanizer unit 176 can recover light hydrocarbons (e.g., methane). Each of the units 174, 176 may couple separately with the fluid circuit 110 at one or more locations (e.g., a first location 178 and a second location 180). At the first location 178, the second separator unit 174 couples with the compression circuit 158 of the methane compressor 140. At the second location 180, the demethanizer unit 176 couples between the turbo-expander 134 and the first separator unit 146.
[0037] The pre-processing unit 122 can remove impurities from the feedstock 118 upstream the fluid circuit 110. In use, the feedstock 118 can transit a fourth pass of the heat exchanger 106. This fourth pass can lower the temperature of the feedstock 118 to a range of from approximately -80 °F to approximately -110 °F. The cooled feedstock 118 enters the second separator unit 174 to remove impurities (e.g., heavy hydrocarbons). In one implementation, the second separator unit 174 is configured to form a first stream 182 and a first bottom product 184, one each that exits the bottom and top of the second separator unit 174 in vapor and liquid form, respectively. The vapor first stream 182 comprises predominantly methane vapor, typically in a concentration of from approximately 92
% (920,000 ppmV) to approximately 97 % (970,000 ppmV). The system 100 directs the vapor first stream 182 through a fifth pass of the heat exchanger 106 and into the compression circuit 158 at the first location 178. This fifth pass can raise the temperature of the vapor first stream 182 to a range of from approximately 80 °F to approximately 120 °F.
[0038] The system 100 directs the first bottom product 184 to the demethanizer unit 176. In one implementation, the demethanizer unit 176 is configured to form a second stream 186 and a second bottom product 188, each exiting the bottom and top of the demethanizer unit 176 in liquid and vapor form, respectively. The vapor second stream 186 comprises predominantly methane vapor, typically in a concentration of from approximately 92 %
(920,000 ppmV) to approximately 97 % (970,000 ppmV). The system 100 can direct vapor second stream 186 to enter the fluid circuit 110 at the second location 180, effectively by passing the heat exchanger 106. The second bottom product 188 can form the second product 126 that is directed to the collateral system 128 and/or processing found further downstream of the system 100 at the facility.
[0039] FIG. 8 depicts an example of the system 100 with additional components that may be useful to modulate pressure (and/or temperature) of fluid. The system 100 may include one or more expansion valves (e.g., a first expansion valve 190, a second expansion valve 192, and a third expansion valve 194). J-T valves and like devices may be suitable for use as the valves 190, 192, 194. The pre-processing unit 122 may incorporate a reboiler 196 to boil the second bottom product 188 from the demethanizer unit 176. Boiling results in vapor that is directed back into the demethanizer unit 176.
[0040] FIG. 9 illustrates an example of the system 100 also with additional components to accommodate certain production levels and/or other process changes as necessary. The system 100 may include a third separator unit 198 upstream of the turbo expander 134 and interposed between the heat exchanger 106. Vapor from the third separator unit 198 enters the turbo-expander 134. Liquids from the third separator unit 198 are mixed with the effluent (at 150) from the turbo-expander 134, preferably upstream to the first separator unit 146.
[0041] The third separator unit 198 may be useful to prevent mixed phase feed that may occur at certain production levels at which temperatures of influent into the turbo expander 134 may drop below the bubble point. This embodiment modifies the process so that a portion of vapor from the effluent (at 150) may be added to the influent generated from expansion to feed the heat exchanger 106. Other embodiments may use an expander recycle loop with a maximum pressure of approximately 700 psig and an expanded pressure of approximately 285 psig. At these pressures, vapor from the second separator unit 174 can be fed directly into the turbo-expander 134, by-passing the heat exchanger 106 to avoid any warming. This configuration may also forgo any compression of the vapor, as well.
[0042] In light of the foregoing, the embodiments compare favorably to other refrigeration techniques that might supplement any primary refrigeration as provided, for example, by mixed-refrigerant cycles discussed herein.
[0043] As used herein, an element or function recited in the singular and proceeded with the word "a" or "an" should be understood as not excluding plural said elements or functions, unless such exclusion is explicitly recited. Furthermore, references to "one embodiment" should not be interpreted as excluding the existence of additional embodiments that also incorporate the recited features.
[0044] This written description uses examples to disclose the embodiments, including the best mode, and also to enable any person skilled in the art to practice the embodiments, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the embodiments is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal language of the claims.
[0045] Where the terms "comprise", "comprises", "comprised" or "comprising" are used in this specification (including the claims) they are to be interpreted as specifying the presence of the stated features, integers, steps or components, but not precluding the presence of one or more other features, integers, steps or components, or group thereof.
PARTS LIST
[0046] 100 Gas processing system 102 Expansion unit 104 Refrigeration unit 106 Heat Exchanger 108 Refrigerant 110 Fluid circuit 112 Process stream 114 First product 116 Storage facility 118 Feedstock 120 Source 122 Pre-processing unit 124 Feedstream 126 Second product 128 Collateral system 130 Turbo-machine 132 Turbo-Compressor 134 Turbo-expander 136 Inlet (compressor) 138 Outlet (compressor) 140 Methane compressor 142 Inlet (turbo-expander) 144 Outlet (turbo-expander) 146 First separator unit 148 Arrow 150 Arrow 152 Bottom product 154 Top product 156 Arrow 158 Compression circuit
160 First end 162 Second end 164 First cooler 166 Second cooler 168 Third cooler 170 First compressor 172 Second compressor 174 Second separator unit 176 Demethanizer unit 178 First location 180 Second location 182 First stream 184 First bottom product 186 Second stream 188 Second bottom product 190 First expansion valve 192 Second expansion valve 194 Third expansion valve 196 Reboiler 198 Third separator unit

Claims (12)

The claims defining the invention are as follows:
1. A liquefaction process, comprising:
receiving a feedstock;
forming a process stream from the feedstock by separating the feedstock into a first stream and a first bottom product, the process stream comprising a first stream and a second stream;
distilling the first bottom product to form a second stream and a second bottom product, each of the first streamandthesecondstream comprising predominantly methane vapor;
compressing the process stream to a first pressure;
cooling the process stream to a first temperature;
expanding the process stream from the first pressure to a second pressure that is less than the first pressure;
bleeding-off a liquid product from the process stream at the second pressure;
conditioning the liquid product for storage as liquid natural gas (LNG); and
conditioning the second bottom product to form a liquid petroleum gas (LPG).
2. The liquefaction process of claim 1, further comprising:
compressing the process stream from the second pressure to an intermediate pressure that is between the first pressure and the second pressure.
3. The liquefaction process of claim 1 or 2, wherein the process stream comprises liquid at the first pressure.
4. The liquefaction process of claim 3, wherein the process stream comprises both vapor and liquid at the second pressure.
5. The liquefaction process of any one of claims 1 to 4, wherein the first pressure and the second pressure form a ratio of from 3 to 10.
6. The liquefaction process of any one of claims I to 5, further comprising:
forming the process stream from a feedstock having a concentration of methane of 84 % or greater.
7. The liquefaction process of claim 6, further comprising:
introducing the first stream into the process stream at the intermediate pressure.
8. The liquefaction process of claim 6 or 7, further comprising:
introducing the second stream into the process stream at the second pressure.
9. A gas processing system, comprising:
a pre-processing unit configured to receive a feedstock and form a process stream from the received feedstock by separating the feedstock into a first stream and a first bottom product, the process stream comprising a first stream and a second stream;
distilling the first bottom product to form a second stream and a second bottom product, each of the first streamandthesecondstream comprising predominantly methane vapor;
a heat exchanger;
a fluid circuit coupled with the heat exchanger, the fluid circuit directing the process stream through the heat exchanger,
wherein the fluid circuit is configured to:
compress the process stream to a first pressure; pass the process stream through the heat exchanger at the first pressure; expand the process stream from the first pressure to a second pressure that is less than the first pressure; bleed-off a liquid product from the process stream at the second pressure; condition the liquid product for storage as liquid natural gas (LNG); and condition the second bottom product to form a liquid petroleum gas (LPG).
10. The gas processing system of claim 9, further comprising:
a refrigeration unit coupled with the heat exchanger,
wherein the refrigeration unit is configured to circulate a refrigerant through the heat exchanger.
11. The gas processing system of claim 9 or 10, wherein the fluid circuit is configured to receive a feedstock and to circulate the feedstock as the process stream.
12. The gas processing system of claim 11, further comprising:
a pre-processing unit coupled with the fluid circuit and with the heat exchanger, the pre-processing unit having:
a separator unit configured to receive the feedstock downstream of the heat exchanger;and
a demethanizer coupled downstream of the separator unit,
wherein the separator unit and the demethanizer are configured to form the first stream and the second stream, respectively, each comprising methane vapor, and
wherein the process stream comprises the first stream and the second stream.
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