AU2015252065B2 - Low dust joint compound and method of making the same - Google Patents

Abstract

A joint compound or wall repair composition and the method of making the same is disclosed that reduces the amount of airborne dust emitted during traditional sanding 5 processes. Generally, such a reduction can be achieved by combining a first binder that has a high glass transition temperature and a second binder that has a low glass transition temperature with conventional joint compound compositions. 7078484_1 (GHMatters) P89909.AU.1 JOSHUAF

Description

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LOW DUST JOINT COMPOUND AND METHOD OF MAKING THE SAME

Field of ΙηΛ^ιιΙΙο^ [0001] This disclosure generally relates to joint compound compositions, wallboard repair compound coaipositions, spackling compositions, wood fillers, plasters, and the like used to repair imperfections in w'alls or fill joints between adjacent wallboard panels. More particularly, this disclosure relates to such compositions that reduce the quantity of airborne dust generated when tire hardened composition is sanded,

Backgroimd of Itiventiom [0002] Interior walls of commercial and residential buildings are often constructed using gypsum wallboard panels, generally refers'ed to as "wallboard" or "drywall". During construction of the walls, wallboard panels are affixed adjacent to one another on a support stmcture (e.g., a; wooden frame) using screws, nails or other fasteners. As the v/ali is constructed, gaps (typically referred to as "joints") are formed between the adjacent wallboard panels. In order to achieve a smooth, visually appealing surface, the joints between the board panels and any cracks, screw*^ holes, andfor nail holes must be concealed, [0003] A formulated adhesive composition, typically known as a "joint compound composition" or 'hvall repair compound", is commonly used to conceal and finish the joints and any other imperfections in the wall (e.g., cracks, screw holes, or nail holes). The procedure for concealing the joints involves applying soft wet joint compound within the joints formed by the abutting edges of adjacent wallboard panels using a trowel or other straiglrt edged tool. A fiberglass, cloth, or paper reinforcing tape material is then embedded within the wet joint compound, and the joint compound is allowed to harden.

[0004] .After the compound composition has hardened, a second layer of compound composition is applied over the joint find tape to completely fill the joint and provide a smooth surface. Multiple layers may be applied in order to obtain a smooth, attractive 1 - ο (Ν > Ο ο ιη Ο (Ν (Ν ίΤ) ο (Ν finished wall. Each layer is allowed to dry prior to application of the next layer. Upon hardening, the compound composition is sanded smooth to eliminate surface irregularities. Paint or a wall covering, such as wall paper, can then be applied over the joint compound composition and wallboard panels, so that the compound composition and the panels are imperceptible under the paint or wall covering. While such compound compositions are referred to as joint compound compositions throughout this disclosure, it will be appreciated that the terms "w'all repair composition", "joint compound composition", "compound composition" or "joint compound" are not limiting in nature and refer generally to any composition, including, but not limited to, wallboard repair compound compositions, spackling compositions, wood fillers, and plasters, that can be used to finish tlie joints and/'or conceal the joints in between wallboard panels or be used to conceal or repair any imperfections in a wall.

[Θ0Θ5] An array of joint compound compositions have been sold commercially, described in printed publications, and have been the subject of patents. Generally, such compound compositions are referred to as either "ready mixed" compounds or "setting type" compounds and arc made up of a filler (e.g,, calcium carbonate, calcium sulfate heroihydrate, or calcium sulfate dihydrate), thickener, preservative, and a binder, as well as various other additives. .Λ common example of such a joint compound is disclosed in U.S. Pat. No. 5,653,797, which is incorporated herein by reference.

[ΘΘ06] "Ready mixed" or "drying ty^pe" compositions, are pre-mixed with water during manufacturing and require little or no addition of water at the job site. Such compounds harden when the water evaporates and the compound dries. Ready mixed compounds substantially contain a filler component that can be either calcium carbonate (CaCOa; also referred to as limestone), calcium sulfate dihydrate (CaS04-2H20) and/or talc (Mg3Si40io(OH)2 or 3Mg04Si02H20). Prior to use (generally during manufacturing), the ο (N > Ο ο in Ό Ο (Ν in (Ν in ο (Ν filler, a binder and several other ingredients are mixed for a specific time with water to produce the ready mixed compound composition, Such a composition has a high ionic content and basic pH. Once the retidy mixed compound composition is applied to the wallboard panels, the composition dries (i.e., water evaporates) and a dry, relatively hard cementitious material remains. Many conventional ready mix compound compositions undergo shrinkage upon drying, which makes it difficult to achieve a smooth wall surface. Shrinkage can be paiticularly troubiesome when a second coat of compound is applied over a previous coat that is not completely dried.

[0007] To avoid such disadv£iniages of the ready mix compound compositions, "setting type" compound compositions have been developed. A setting type compound composition generally includes calcium sulfate hemihydrate (CaS04-yiH20; also referred to as calcined gypsum) as its filler and hardens upon being mixed wdtii water. Upon being mixed with water, the calcium sulfate hemihydrate is hydrated, which causes dihydrate crystals to form and interlock.

[0008] To produce calcined gypsum, calcium sulfate dihydrate is converted irom raw gypsum to the hemihydrate state via a suitable calcination process. A gypsum calcination process removes one and one-half molecules of water fiom each calcium sulfate dihydrate gypsum molecule. The hemihydrate form of calcium sulfate is substantially more soluble in w'ater than the dihydrate form of calcium sulfate. During use of a setting type compound composition, the calcium sulfate hemihydrate is rehydrated to the dihydrate state via the addition of water. This rehydration process normally takes place over a fairly short period of time. Once completed, a dry, relatively hard cementitious material remains. It has been extremely difficult to produce a setting compound composition comprising hemihydrate gypsum pro-mixed with water, because such a pre-mixed product would set in its storage container. For this reason, setting type compound compositions are typically supplied to the -3- ο (Ν > Ο 2; ο ΙΟ Ό Ο (Ν ΙΟ (Ν ΙΟ Ο (Ν ΙΟ job site in the form of a dry powder to which the user then adds a sufficient amount of water to give the compound a suitable consistency to be applied to the wall, [0009] Setting type compounds have the advantage of having generally quicker finishing times (setiing time) than ready mix compounds. This is advantageous because it prevents the shiinkage problems associated with ready mix compounds. Further, because setting type compounds form a crystalline network upon setting (as opposed to merely drying), these compounds typically provide a stronger, more durable bond between adjacent wallboard sheets than the bond formed by ready mix compounds. However, because these compounds provide a strong crystalline network upon setting, the setting type compound is often harder to sand to a smooth finish, [0010] Ready mixed, setting type joint compounds are also known. For example, U.S. Patent No. 4^661,161 suggests a joint compound comprising an aqueous slurry of calcium sulfate hemihydrate and a set retarding agent formed of two ingredients: an organic, proteinaceous retarder and a chelating agent (e.g,, selected irom diethylene triamine pentaacetic acid, ethylene diamine tetraacetic acid, and salts thereof. This patent indicates that the compound has an adequately long shelf life for Gommercialization, and that when mixed with an accelerator that the joint compound hydrates after a period of time to form a set material having acceptable joint compound properties. Hov«ever, it is believed that joint compounds of the setting, ready mix type have not been successfully commercially employed due to the difficulty in finding a suitable retarding agent and a suitable accelerator to overcome the retarding agent.

[0011] Regardless of the type of joint compound used, a user will, after the compound hardens, sand the compound to create a smooth finish before painting or applying a wall covering to the w^ll. Sanding hardened joint compound can be accomplished using conventional techniques including power sanders, abrasive screens, or manual sandei-s. _ a _ Ο (N > Ο ο

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During the sanding process, a portion of the joint compound is sanded away, Unfortunately, a lai'ge portion of the removed joint compound typically is in the form of a fine powder and/or dust that tends to become suspended in air for a long period of time. Eventually, this joint compound dust settles on eveiything in the vicinity of die sanding site. A lengthy and tedious clean up process must then take place to τβηιοΛ'ε the dust from the site. Due to the dust settling over time, multiple cleanings must occur to remove all of the joint compound. Not only is this a time consuming process but the dust could present a health hazard to workers. Studie,s have shown that dust levels at the job site normally exceed the limits set by the Occupational Safety and Health Agency ('*OSHA**) and even when the dust levels fall below the limitations set by OSHA, it is not known whether the dust still poses a health risk, [0012] To limit exposure and avoid potential health complications, an exhaust ventilation system, personal protective equipment (e.g., masks), or "low dust" removal teclmiques can be used. For example, U.S. Patent No. 4,782,6.32 discloses a sander with a sanding head designed to reduce the dust created aiid discloses attaching a vacuum to the sander to immediately capture the dust. U.S, Patent No. 4,955,748 discloses a drywall finishing system that utilizes a wet sponge to prevent the formation of dust. While these methods are available, it is still preferred to use conventional sanding techniques because they are less expensive and perceived to be easier, 'fhus, it would be preferred if dust could be reduced tlirough the formulation of the joint compound composition, so conventional sanding techniques could be used.

[0013] To address this need, manufacturers are beginning to offer "low-dust" joint compound compositions that reduce the amount of dust that is created when conventional sanding techniques are used. For example, U.S. Patent No. 6,358,309 discloses a joint compoimd that is mixed with an additive that produces a lower amount of dust during the sanding process than the joint compound does without such an additive. As discussed in the ο (Ν > Ο Ο Ό Ο (Ν •Ο (Ν ο (Ν ΙΟ patent, such additives can be used ν,ήίΐι either ready mix or setting type joint compounds and suitable additives include oils (such as mineral oils, vegetable oils and-aiiimai oils), surfactants, oleoresinous mixtures, pitch, solvents, paraffins, waxes, including aatural and synthetic wax, glycols, and other petroleim derivatives. It is theorized in U.S. Patent No. 6,358,309 that such additives cause the dust particles to agglomerate or stick together, thereby forming larger and heavier particles wliich tend not to become or remain airborne.

[0014] While the inclusion of such dust reducing additives do decrease the amount of dust produced during conventional sanding processes, it has been observed that such additives lead to other problems during the wall finishing process. For example, when users sand a hardened joint compound containing such oil or wax additives, the joint compound sticks to the sand paper causing the sand paper to quickly become clogged and unusable. As a result, users of joint compound with such additives are required to ckinge to new sand paper more frequently during the sanding process and as a result, use more sand paper than required with conventional joint compounds.

[0015] Moreover, it has also been suggested by users that such additives cause an increase in "flashing" problems when a finished wail is painted. Tire term "flashing" refers to when the joints and/or other areas covered by the joint compound can still be seen when the v/all is painted. Here, joint compounds with the oil or wax additives disclosed in U.S. Patent No, 6,358,309 have different absorption chafacteristios than the wallboard panels. When the walls using such low dust joint compound compositions are painted, the areas that correspond to the joints are likely to be more severely discolored than walls using conventional joint compound compositions because of the difference absorption characteristics between the board and joint compound. As a result, such joints may be noticed once the wall is painted, which causes dissatisfaction with the appearance of the painted wail. Ο (N > Ο 2; ο ο (Ν (Ν Ο (Ν [0016] Thus, a joint compound composition is still needed that reduces the amount of dust produced during conventional sanding processes that has the same general characteristics of conventional joint compound compositions. For example, it is desirable to obtain a low dust joint compound that sajids easily without increased clogging problems during sanding of the hardened joint compound and allows for the joints to have similar absorption characteristics as the wallboard panels, so that the joints are not easily noticed when the wall is painted.

Summary [0017] As discussed herein, a joint compound composition and method of making the same is disclosed that reduces the amount of airborne dust that is emitted during the sanding of the hardened joint compound composition. Such a joint compound composition comprises a filler material and at least a first binder and a second binder. The first binder has a glass transitiori iempcratm'e that is equal to or greater than about -10 degrees Celsius and the second binder has a glass ti'ansition temperature between the range of about -80 degrees Celsius to about 10 degrees Celsius, It is preferred that the first binder has a glass transition temperature between the range of about 0 degrees Celsius to about 40 degrees Celsius. The first binder and second binders are selected so that the glass transition temperature of the first, binder is at least about 5 degrees Celsius greater than the glass transition temperature of the second binder.

[0018] Such a joint compound composition typically has a filler material that comprises between about 25% to about 95% of the total wet weight of the joint compound composition, a first binder that is equal to or greater than about .5% of the total wet v/eight of the joint compound composition, and a second binder that is equal to or greater than at least about .05% of the total wet weight of the joint compound composition. The first binder and second binder can be added to any conventional joint compound composition, including ο (N o

Ό O (N (N o (N ready mix joint compounds, setting type joint compounds, and ready mix, setting type joint compounds. Thus, the filler material can include at least one material selected from the group consisting of calcium carbonate, calcium sulfate dihydrate, talc, and calcium sulfate hemihydrate. 5 [0019] The first binder and second binder can be any number of latex or non-latex polymers. For example, the first binder and second binder can be selected from a group consisting of polymers of ethylene vinyl acetate, vinyl acetate, acrylics, styrene acrylics, polyvinyl alcohol, and cellulose ether. In a preferred embodiment, the first binder comprises a functionalized styrene-butadiene polymer and the second binder comprises an 10 emulsion comprising water, a latex polymer (e.g., ethylene-vinyl-acetate), and a plasticizer, wherein the plasticizer depresses the glass transition temperature of the latex polymer. In another embodiment, the first and second binders comprise the same molecule with differing glass transition temperatures.

[0020] Such a joint compound composition can be made by adding a first binder 15 having a glass transition temperature that exceeds about -10 degrees Celsius and adding second binder having a glass transition temperature between the range of about -80 degrees Celsius to 10 degrees Celsius to a joint compound composition comprising at a least one filler material. The first binder and second binders are selected so that the glass transition temperature of the first binder is at least about 5 degrees Celsius greater than the glass 2 0 transition temperature of the second binder. One or both of the first and second binders can be added to the joint compound composition during mixing or one or both of the first and second binders can be added after the joint compound composition has been made.

[0020a] The invention as claimed herein is described in the following items 1 to 13: 1. A j oint compound composition, comprising: 25 a filler material selected from the group consisting of: calcium carbonate, calcium sulfate dehydrate, and calcium sulfate hemihydrate; a first binder comprising a first polymer, the first binder having a glass transition temperature that is equal to or greater than about -10 degrees Celsius; and a second binder comprising a second polymer, the second binder having a glass 30 transition temperature in the range of about -80 degrees Celsius to about 10 degrees Celsius, wherein the glass transition temperature of the first binder is at least about 5 degrees Celsius greater than the glass transition temperature of the second binder; and wherein the first and second polymers have the same chemistry. -8- 9141723_1 (GHMatters) P89909.AU.1 r- ο (N α ο ΙΟ Ο (Ν ΙΟ (Ν ΙΟ Ο (Ν 2. The joint compound of item 1, wherein the second binder further comprises a plasticizer. 3. The joint compound of item 2, wherein the first and second polymers are polymers of ethylene vinyl acetate. 5 4. The joint compound of item 3, wherein the plasticizer is selected from the group consisting of: a diethylene dibenzoate ester and a dipropylene dibenzoate ester. 5. The joint compound of item 1, wherein the first and second polymers comprise copolymers of a first monomer and a second monomer, the first and second polymers having different ratios of first and second monomers. 10 6. The joint compound of item 5, wherein the first and second polymers are block copolymers. 7. The joint compound of item 1, wherein the first and second polymer are selected from the group consisting of polymers of: ethylene vinyl acetate, vinyl acetate, acrylics, styrene acrylics and polyvinyl alcohol. 15 8. The joint compound of item 1, wherein the first binder has a glass transition temperature that is equal to or greater than 0 degrees Celsius. 9. The joint compound of item 1, wherein the first binder has a glass transition temperature that is in a range of about 0 degrees Celsius to about 40 degrees Celsius. 10. The joint compound of item 1, wherein the first binder has a glass transition 2 0 temperature of about 5 degrees Celsius. 11. The joint compound of item 1, wherein the second binder has a glass transition temperature of about -40 degrees Celsius. 12. A joint compound composition, comprising: a filler material selected from the group consisting of: calcium carbonate, calcium 2 5 sulfate dehydrate, and calcium sulfate hemihydrate; a first binder comprising a cellulose ether, the first binder having a glass transition temperature that is equal to or greater than about -10 degrees Celsius; and a second binder having a glass transition temperature in the range of about -80 degrees Celsius to about 10 degrees Celsius, wherein the glass transition temperature of 30 the first binder is at least about 5 degrees Celsius greater than the glass transition temperature of the second binder. 13. The joint compound of item 12, wherein the second binder comprises a polymer selected from the group consisting of: ethylene vinyl acetate, vinyl acetate, acrylics, styrene acrylics and polyvinyl alcohol. 8a 9141723_1 (GHMatters) P89909.AU.1 r- ο (N Ό Ο

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Detailed Description [0021] Research was undertaken to discover binders that could be added to any type of joint compound composition (ready mix joint compounds, setting type compounds, or 8b 9141723_1 (GHMatters) P89909.AU.1 ο (Ν > Ο Ζ ο ΙΟ Ό Ο (Ν ΙΟ (Ν Ο (Ν ΙΟ ready mix, setting type compounds) to significantly reduce the amount of dust produced during conventional sanding processes without detrimentally impacting the other desired characteristics of the joint compound composition. Generally, such a reduction can be achieved by combining a first binder that has a high glass transition temperature (a "high Tg binder") and a second binder that has a low giaSvS transition temperature (a "low' Tg binder") with traditional joint compound ingredients, As generally known in the ail, die glass transition temperature ("Tg") marks the temperature that the polymer transitions from a glassy state to a viscoelastic state.

[0022] The use of a high Tg binder and low' Tg binder can be used with any joint compound composition, including ready mix joint compound compositions, setting type joint compound compositions, or ready mix, setting ts^pe joint compound compositions. Conventional joint compound compositions include at least a filler and a binder. Any conventional filler material can be used, including calcium carbonate, calcium sulfate dihydrate, and/or talc for ready mixed joint compound compositions and calcium sulfate hemihydrate for setting type joint compound compositions. Generaily, the concentration of the filler is between about 25 weight percent to about 95 weight percent based on the total wet w'eight (i.e., including water) of the compound composition.

[0023] In addition to die filler and binder, conventional joint compound compositions contain any number of other ingredients, such as, thickeners, non-leveling agents, surfactants, stabilizers, preservatives, fungicides, anti-freeze agents, wetting agents, and colorings. Secondary fillers can also be added, including, but not limited to, glass micro bubbles, mica, perlite, limestone, pyrophyllite, silica, and diatoinaceous eaith. The glass micro bubbles or a treated expanded perlite are added to the compound composition to provide a lighter weight joint compound, as described in U.S. Patent No. 4,454,267. The selectioa and concentration of the various components can be any concentration that will afford a joint compound ο (Ν > Ο Ο ΙΟ Ό ο (Ν ΙΟ (Ν ΙΟ Ο (Ν ΙΟ suitable characteristics for home and industrial use. Such characteristics, typically, include having good plasticity, water retention, eohesiveness, viscosity stability, resistance to cracking, sandability, minimal shrinkage, good paint adherence, good hardening properties, low weight and low cost.

[0024] ^Tiile any number of binders can be used in conventional joint compound compositions, it has been found that the combination of a high Tg binder with a low Tg binder reduces the amount of the airborne dust that results from the sanding processes without detrimentally impacting the desired characteristics of the joint compound composition. The high Tg binder and low Tg binder can be added to the joint compound composition during the mixing of the joint compound composition. Alternatively, either the high Tg binder or low Tg binder can be added to the joint compound composition during the mixing of the joint compound composition and the other binder can be added at a later time after the joint compound composition is made and before application of the joint compound. Further, the joint compound composition can be mixed without either of the high Tg binder or low Tg binder and both tlie high Tg and lov/ Tg binders can be added at a later time after the joint compound composition is made. For example, for a setting type compound, either one or both of the high Tg binder and low' Tg binder could be added w'hen the user mixes the setting type joint compound powder wdtli water at the job site. Further, the iow' Tg binder could be applied as a coating after the joint compound composition is applied to the w'all and prior to sanding taking place.

[0025] Generally, the glass transition temperature of the low' Tg binder can be anything in the range of about -80 degrees Celsius to 10 degrees Celsiu.s. Specific examples of the glass transition temperature of the low Tg binder include about 10 degrees Celsius, 0 degrees Celsius, about -40 degrees Celsius, about -80 degi'ees Celsius, and ranges betw'een any two of these values. Such a low' Tg binder cfoi be used in any type of joint compound 10- Ο (N > Ο Ο IT) Ό Ο (Ν in (Ν »η ο (Ν composition that also comprises another binder that provides the required bond strength to waliboard panels and/or joint tape for the joint compound composition.

[0026] Generally, the glass trrmsition temperature of the high Tg binder can be equal to or anvdhing above -10 degrees Celsius. It is presently preferred that the high Tg binder have a glass transition temperature above abou t 0 degrees Celsius. It is presently more preferred that the high Tg binder have a glass transition temperature that falls within the range of about 0 degrees Celsius to about 40 degrees Celsius. Specific examples of the glass transition temperature of the high Tg binder include about -10 degi-ees Celsius, about 0 degrees Celsius, about 5 degrees Celsius, about 40 degrees Celsius, and ranges between any two of these values. While there is some overlap between the disclosed glass tran-sition temperatures for tire low and high Tg binders, the high Tg binder and low Tg binder are selected such that the glass transition temperature of tlie high Tg binder exceeds the glass transition temperature of the low Tg binder by at least 5 degrees Celsius.

[0027] Any number of binders can be used as the high Tg binder, including, but not limited to, polymers of ethylene vinyl acetate, vinyl acetate, acrylics, styrene acrylics, and polyvinyl alcohol amongst a wide variety of others. It will also be appreciated that non-latex binders, such as, cellulose ethers, can also be used as the high Tg binder. An example of a latex, high fg binder that can be used is a functionalized styrene-butadiene polymer, such as Rhoximat PSB 150 (commercially available from Hexion Chemical Company), that has a Tg of about 5 degrees Celsius.

[0028] Any number of polymeric binders can be used as the low' Tg binder, including, but not limited to, polymers of ethylene vinyl acetate, vinyl acetate, acrylics, styrene acrylics, and polyvinyl alcohol amongst a wide variety of others. An example of a low Tg binder that can be used is an ethylene-vinyl-acetate polymer with a Tg of about -40 degrees Celsius. Such a iow'^ Tg binder was created by depressing the Tg of Forbo Chemical 11 Ο (Ν > Ο ο ΙΟ Ο (Ν ΙΟ (Ν ΙΟ Ο (Ν ΙΟ

Company's commercially available Elvace CPS 716 latex with a plasticizer (s.g., a diethylene or dipropylene dibenzoate ester plasticizer).

[0029] A preferred low Tg binder with a Tg of -40 degrees Celsius can be created by adding water at a concentration of at least about 20.7 weight percent based on the weight of the composition, the Elvace CPS 716 latex at a concentration of 47.6 weight percent based on the weight of the composition, and K-Flex 500 (a plasticizer commercially available from Emerald Kalama Chemicals, LLC) at a concentration of 31.7 w'eiglit percent based on tlie weight of the composition. Forbo Chemical Company currently makes such a low Tg binder available under the product name Elvace EP 1026. Another preferred low Tg binder with a Tg of -40 degrees Celsius can be created by adding water at a concentration of at least about 40.1 weight percent based on the weight of the composition, Elvace CPS 741 latex with a Tg of-10 degrees Celsius at a concentration of 53.6 weight percent based on the weight of the composition, and K-Flex 500 plasticizer at a concentration of 5.4 weight percent based on the weight of the composition. Forbo Cbemicai Company currently makes such a low Tg binder available under the product name Elvace EP 1028, [ΘΘ3Θ] virile examples of low' and high Tg binders are disclosed, it will be appreciated by one of ordinary skill in the art that any number of binders can be used as the high Tg binder and/or low Tg binder. Moreover, it should be noted that the high and low Tg binders do not necessarily have to be of different chemistries. In some embodiments, the high and low Tg binders cair be the same molecules with different Tgs. In such embodiments, a plasticizer may be used to depress the Tg of one of the molecules to create the low Tg binder. One of ordinary skill in the art will also appreciate that the low Tg binder does not have to be created by using a plasticizer. With respect to either random and'or block copolymers for instance, a low' or high Tg can be created by manipulating monomer ratios, even though the general chemistry in terms of functional groups of the copolymers are the same. 12 ο (Ν > Ο Ο ο (Ν ΙΟ (Ν ΙΟ Ο (Ν ΙΟ

Consequently, there are a nimiber of binders tlrat can be used that fell within the glass temperature range of about -80 dep'ees Celsius to about 10 degrees Celsius.

[0031] The high Tg binder provides bond strength and adhesion of the joint compound to the substrate (e.g., wallboard and/or joint tape), it is theorized that the low Tg only mildly augments the adhesive force of the high Tg binder and that the low Tg binder's primary function Is to sen^ as a weak inter-particle binder within the joint compound composition, so that the eli^ticity of the low Tg binder causes dislodged particles from the joint compound composition to aggregate during tlie sanding process. In contrast to the high Tg binder, the low Tg binder is sufficiently malleable at the temperatures that the joint compound is expected to be sanded (ambient conditions of 0 degrees Celsius and liigher). At such temperatures, the low Tg binder is able to adhere to the smaller particles being dislodged from the joint compound during the sanding process, because of its elasticity. .As a result, the low' Tg binder prevents small, dust forming particles (e.g., particles less than 10 microns in size) from leaving the bulk compound and becoming airborne. As more small particles are dislodged, the low Tg binder holds onto such small particles and aggregates them together. Once the aggregated particles grow large and heavy enough, they siniply fall to the ground because they are too large to float in air.

[0032] ySn exemplary embodiment of a low dust joint compound composition in accordance wdth this disclosure is directed towards a ready mix joint compound composition comprising at least calcium carbonate, water, a polyeiher siloxane copolymer, a high Tg binder and a lov/ Tg binder. Generally, the concentration of calcium carbonate can be between about 25 weight percent to 95 weight percent based on the total wet weight of the compound composition (i.e., including w^ter). It is presently preferred that die concentration of calcium carbonate be about 25 weight percent to about 60 weight percent based on the wet w'eight of the compound composition. Specific examples of the concentration of calcium 13 Ο (Ν > Ο ο ΙΟ Ό Ο (Ν ΙΟ <Ν ΙΟ Ο <Ν ΙΟ carbonate include about 25 weight percent, about 30 weight percent, about 35 weight percent, about 40 weight percent, about 45 weight percent, about 50 weight percent, about 55 weight percent, about 60 weight percent, and ranges between any two of these values.

[0033] Generally, the concentration of water can be at least about 30 weight percent based on the wet weight of the compound composition, it is presently preferred that the concentration of w'ater be about 30 weight percent to about 50 weight percent based on the wet weight of the compound composition. Specific examples of the concentration of water include about 30 weight percent, about 35 weight percent, about 40 w^eight percent, about 45 weight percent, about 50 weight percent, and ranges between any two of these values.

[0034] Generally, the concentration of polyether siloxane copolymer can be equal to or greater than about 0.01 weight percent based on the wet weight of the compound composition. It is presently preferred that the concentetion of polyether siloxane copolymer be about 0.01 weight percent to about 0.50 weight percent based on the wet weight of the compound composition. Specific examples of the concentration of polyether siloxane copolymer include about 0.01 weight percent, about 0.10 weight percent, about 0.20 weight percent, about 0,30 weight percent, about 0.40 weight percent, about 0.50 weight percent, and ranges between any two of these values. While polyether siloxane copolymer is included in this embodiment as a wetting agent to improve wetting and reduce the formation of poclcmarks or craters in the joint compound, it is appreciated by one skilled in the art that polyether siloxane copolymer does not need to be included in tlie joint compound composition, [0035] In this ready mix embodiment, the high Tg binder comprises a functionalized slyrene-butadicne polymer. Generally, the styrene-butadiene polymer is added to the joint compound composition as a powder and the concentration of styrene-butadiene polymer can be equal to or greater than about 0.5 weight percent based on the wet weight of the compound -14- ο (N > Ο Ο in Ό Ο (Ν ιη (Ν ιη Ο (Ν composition. It is presently preferred that the concentration of styrene-butadiene polymer be about 0.5 weight percent to about 5 weight percent based on the %'et weight of the compound composition. Specific examples of the concentration of styrene-butadiene polymer include about 0.5 weight percent, about 1 weight percent, about 1.3 weight percent, about 1.5 weight percent, about 2 weight percent, about 2.5 weight percent, about 3 weight percent, about 3.5 weight percent, about 4 weight percent, about 4.5 weight percent, about 5 weight percent, and ranges between any two of these values.

[0036] In this embodiment, the low Tg binder comprises an ethyiens-viny 1-acetate polymer. Generally, the ethylene-vinyl-acetate polymer is added to the joint compound as an emulsion and the concentration of the ethylene-vinyl-acetate polymer can be equal to or greater than about ,05 weight percent based on the wet weight of the compound composition. It is presently preferred that the concentration of ethyleae-vinyl-acetate polymer be about 3.00 weight percent to about 7.00 w^eight percent based on the wet weight of the compound composition. Specific examples of the concentration of ethyiene-vin5d-aoetaie polymer include about 3.10 weight percent, about 3.90 weight percent, about 4.90 weight percent, about 6.95 weight percent and ranges between any two of these values.

[0037] Although not required, such a ready mix joint compovsnd composition can further comprise various other additives, such as other fillem, thickeners, non-leveling agents, surfactants, stabilizers, presei-vatives, fungicides, anti-ifeeze agents, wetting agente, and colorings. To provide a lighter weight joint compound, glass bubbles or a treated expanded perlite can be added to the compositions as well Examples of such lightweight ready mix joint compound compositions are now provided,

Exantnles [0038] The following examples are included to demonstrate preferred embodimeiits of the invention, it should be appreciated by those of ordinary skill in the art tliat the 15 in ο (N > Ο Ο in Ο (Ν ιη (Ν ιη ο (Ν techniques disclosed in the examples which follow represent techniques discovered by the inventors to function well and thus, can be considered to constitute preferred inodes. However, those of ordinary skill in the art, in light of the present disclosure, will appreciate that many changes can be made in the specific embodiments which are disclosed and still obtain a like or similar result without departing from the scope of this disclosure.

Example 1 - Lightweight, Imw-Dust Joint Treatment Formulation and Measurement of

Average and Peak Number of Particles [0039] The control composition shown in Table 1 was prepared by blending all components together in a mixer until a smooth composition was obtained. The weight percentages show'n in Table 1 are based on the total wet weight of the compound composition.

[0040] Table 1 - Control Ready Mix, Lightweight Joint Compound Composition for Example 1.

Component Weieht Percent Water 42.3 Preservatives 0.2 Limestone 34.7 Mica 4.7 Talc 5.2 Perlite 8.1 Polyether siloxane copolymer 0.1 Latex (EVA Emulsion, Elvace CPS 716) 3.0 Latex (Powder, Rhoximat PSB ISO) (-i-5°C Tg) 1.2 Cellulose Ether 0.5 [0041] To create the low-dust joint compound formulations, the control composition described in Table 1 was modified by replacing Elvace CPS 716 with Elvace EP 1026. Three different loading levels were used for Elvace EP 1026 to create samples of the low dust joint formulation. First, Elvace CPS 716 was replaced by Elvace EP 1026 at a 1:1 load level, where an equivalent amount of Elvace EP 1026 was used to replace the Elvace CPS 716. Second, Elvace CPS 716 was replaced by Elvace EP 1026 at a 1:1.25 load level, where a 25% -16 ο (Ν > Ο 2; ο ΙΟ νο ο (Ν ΙΟ (Ν ΙΟ Ο (Ν ΙΟ excess of Elvace ΕΡ 1026 was used to replace the Elvaoe CPS 716. Finally, Elvace CPS 716 was replaced by Elvace EP 1026 at a 1:1.50 load level, where a 50% excess of Elvace EP 1026 was used to replace the Elvace CPS 716.

[0042] To assess the reduction of dust formation during the sanding process by samples created with joint compound compositions v/ith a low Tg binder and a high Tg binder, the samples were compared with three other commercially available products, The commercially availabie products are National Gypsum Company's commercially available Blue lite product (which is the control sample set forth above). United States Gypsum Company's ("USG") Sheetrock Lightweight All Purpose Pius 3 with Dust Control commercially available low dust joint compound, and LaFarge North America, Inc.'s ("T.aFarge") commercially available Rapid Coat Low Dust All Purpose Joint Compound. Testing was performed on ail products upon thorough mixing.

[0043] The test procedure for measuring the quantity of airborne particles generated when .sanding the hardened joint compound is largely the same as described in U.S. Patent No. 6,358,309, which is incorporated herein by reference. In essence, a test specimen was prepared using each of the commercial products and formulations described above. The test specimens were approximately five inches long, one and one-half inches wide, and one quarter of an inch thick (5" by PA" by A"), Before sanding, each test specimen was allowed to completely harden for a minimum of forty eight hours at room temperature (at least about 70 degrees Fahrenheit) in an enviromnent where the relative humidity generally ranged from about 25% to about 75%.

[0044] A model B04552 power palm sander available from Makita Corporation of America was used to .sand the .specimens. The sander included a 4½ X 4 inch pad equipped v/ith a 120 grit mesh sanding screen mounted over a 5 X 3½ X % inch open, semi-rigid, non-woven, heavy duty, stripping, backing pad available from Minnesota Mining and -17 ο (Ν > Ο ;ζ; ο ΙΟ ο (Ν (Ν ^Ο Η Ο (Ν ΙΟ

Marjufactui’ing Coinpany. Sanding was performed at a sanding speed of approximately 14,000 orbits per minute using pressure normally applied by an ordinary person when sanding a joint compound. It will be recognized that the sanding pressure can vary depending on the hardness oi the joint compound. Sanding was continued until a generally smooth wall surface was produced. Care was taken to ensure that sanding was discontinued before the di'ywall itself was sanded. The amount of time required to sand eacli specimen varied depending on the hardness of the joint compound and the sanding pressure.

[0045] Each test was performed in a test enclosure that is fully described in U.S. Patent No. 6,358,309. Essentially, the test enclosure is a wood rectangular box six feet high, four feet wide, and two feet wide with a transparent front wall made of Plexiglas. An access opening is provided in the front wall about one foot above the bottom wall to allow the tester to insert his/her hand into the enclosure and sand the specimen. The access opening has a cover that can. be closed when sanding is complete to seal the opening off, [0046] As described in more detail in U.S. Patent No. 6,358,309, each specimen was tested individually by clamping the specimen on a mounting block about 12 inches off of the ground within the testing enclosure. After each test, the enclosure was cleaned so that the quantity of airborne dust piartides measured less than 0.5 mg/m", A DIJSTTRAK™ aerosol monitor (model 8520, commercially avaiiabie from TSI Incorporated) was used to measure the quantity of airborne dust particles from when sanding started until the level of airborne paiiicles decreased to less than 50% of its peak level. The DUSTTRAK ™ aerosol monitor measures the number of particles having a size of less than or equal to 10 microns and was positioned about 48 inches above the samples.

[0047} As shown in Table 2, the peak or highest level of airborne particles measured during the test is presented, as well as, tire average number of particles measured for the -18 Ο (N > Ο :z; o

o (N in (N in O <N duration of the test. Three different specimens were prepared and tested for each of the sample formulations.

[0048] Table 2 -- Compariso s! of Average and Maxiinnoi Level of Airborne Particles

Desc. of Sample Sample ID No. Average (mg/n?) Maximum (mg./m^) Elapsed Time (min.) 2936-41-1 61.30 91.90 3:10 Control 2936-41-1 83.10 132.00 2:11 Blue Lite 2936-41-1 87.60 134.00 2:38 Average 77.33 119.30 2936-41-2 33.10 57.00 1:18 Low Tg 2936-41-2 31.00 56.20 1:55 (1:1) 2936-41-2 24,70 40.60 1:41 Average 29,60 51.27 2936-41-3 21.50 41.10 1:31 LowTg 2936-41-3 20.40 33.50 2:03 (1:1.25) 2936-41-3 20.00 34.30 1:54 Average 20.63 36.30 2936-41-4 12.80 25.50 1:04 Low Tg 2936-41-4 13.20 22.00 0:58 (1:1.50) 2936-41-4 13.40 24.80 1:50 Average 13.13 24.10 USG 2936-41-5 15.30 28.40 2:00 Low 2936-41-5 11.70 22.90 2:11 Dust 2936-41-5 25.30 39.60 2:29 Average 17.43 30.30 LaFarge 2936-41-6 55.10 78.90 2:13 Low 2936-41-6 62.20 95.30 1:22 Dust 2936-41-6 89.60 134.00 2:05 Average 68.97 102.73 [0049] As demonstrated by the above results, all of the joint compound formulations comprising a low Tg binder with a high Tg binder produced less airborne dust than tire control specimens and the LaFargc low dust joint compound specimens. The performance of these formulations against the USG low dust joint compound depended on the level of low Tg pohincr in the formulation. The low dust formulation with a low Tg binder load level of 1:1,5 produced better results than the USG low dust joint compound specimens. Moreover, it -19- ο (N > Ο Ο ΙΟ Ό Ο (Ν (Ν ιη Ο (Ν has been noticed that the USG low dust joint compound composition causes an increase in the frequency of clogging of the sand paper during sanding. The low Tg/'high Tg binder joint compound compositions of Example 1 do not lead to such an increase in clogging. Such low Tg.diigh Tg binder joint compound compositions also do not cause an increase in flashing problems.

Example 2 - Lightweight, Low-Dust Joint Treatment Formulation and TWA Test [0050] In another example, a joint compound composition was prepared by blending all the components shown in Table 3 together in a mixer until a smooth composition was obtained, The Aveight percentages shown in Table 3 are based on the total wet weight of the compormd composition.

[0051] Table 3 - Joint Compound Composition for TWA Test

Component Weight Percent Water 41.71 Limestone 34.12 Latex Elvace 1028 (EVA Emulsion) (-40°C Tg) n ΊΚ Rhoximat PSB 150 (Powder) (+5°C fg) 1.38 Cellulose Ether .50 Perlite 7.76 Preservations .24 Polycther siloxane copolymer .05 Clay 1.67 Mica 4.69 Talc 5.14 [0052] Airborne dust from sanding joint compound compositions falls under OSHA standards for exposure to nuisance dust. OSHA recommends that the exposure level for nuisance dust be no more than a time-weighted-average quantity of 15 mg/m^ over an 8 hour period. In view of OSHA's recommendation, saniples were prepared using the joint compound set forth in Table 3 and subjected to a test to determine the time it took for its time-weighted-avcrage ("TV/A") to fall below the 15 mg/m'’ level. Largely, the same testing method was used as described in association with Example 1 to determine how long the time- ο (Ν > Ο Ο ΙΟ Ό Ο (Ν ΙΟ (Ν ΙΟ Ο (Ν ΙΟ weighted-average of each of the samples took to fall below the 15 mg/ m^. While the same sanding technique and test enclosure were used, the DUSTRAK'*'^ aerosol monitor was replaced with Thermo Electron Corporation's commercially available MIE DataRAM 4 (for Data-logging Real-time Aersol Monitor 4), model DR-4000. The DR-4000 instrument was placed about forty-eight inches above where the sample was sanded and the air was sucked into the DR-4000 instrument at a rate of 1 liter per minute with a dust reading being recorded every three seconds.

[0053] Samples prepared with the joint compound composition of Example 2 were compared to samples prepmed with DSG's Sheetrock Lightweight All Purpose Plus 3 with Dust Control commercially available low dust joint compound, and LaFarge's commercially available Rapid Coat Low Dast All Purpose Joint Compound. As showm in Table 4, the peak or maximum level of airborne particles (Maximum (mg/nr')), the duration, in minutes and second, in which the dust level reading exceeded the 15 mg,tin' level (Time), and the duration, in minutes and seconds, the time-'weighted-average of the dust level exceeded 15 mg/m^ (TWA Time) were all measured.

[0054] Table 4 ~ Comparison of TWA Time

Sample ID No. Product Maximum (mg/m^ TWA Time 42-1 LaFarge Low Dust 48.51 56 min 21 sec 42-3-1 USG 53.92 40 min 57 sec 42-3-2 Low Dust 32.57 3 min 15 sec 46-5-1 Example 15.95 0 46-5-2 2 56 12 min 48 sec 46-5-3 34.38 2 min 32 sec '21 - ο (N > Ο ο in Ό Ο (Ν ιη (Ν ιη Η Ο (Ν (0055] 1η comparing the samples with similar peak levels of airborne particles, the Example 2 sample 46-5-2 with a peak level of 56 mg,''m‘^, as compared to the USG sample 42-3-1 Vvdth a peak value of 53.92 mg/m'’ and LaFarge sainple 42-1, has a lower amount of time -where the time-weighted average exceeded 15 mg/m.l Similarly, the Example 2 sample 46-5-3 with a peak level of 34.38 mg/m·*, as compared to the USG sample 42-3-2 with a peak value of 32,57 mg/m^, has a lower amount of time where the time-weighted average exceeded 15 mg/nr. Thus, the low Tgdiigh Tg binder joint compound compositions of Example 2 prodticed better results than the USG and LaFarge samples. Moreover, similar to Example 1 and in contrast to the USG samples, the low Tg.'liigh Tg binder joint compound compositions of Example 2 do not lead to an increase in clogging of sand paper. Such low' Tg/high Tg binder joint compound compositions also do not cause an increase in flashing problems.

[0056] All of the compositions and/or methods disclosed and claimed herein can be made and executed wdthout undue experimentation in light of the present disclosure. ·ννΐιϋ6 the compositions disclosed herein have been described in terms of embodiments, preferred embodiments and examples, it will be apparent to those of ordinary skill in the art that variations and modifications may be made to the compositions herein without departing from the concept and scope of the invention. More specifically, it will be apparent that certain agents which are chemically related may be substituted for the agents described herein while the same or similar results w'ould be achieved. All such similar substitutes, variations and modifications apparent to those skilled in the art are deemed to be within the scope and concept of this di sclosure.

[Θ057] Further, in describing representative embodiments, the disclosure m,ay have presented a method and/or process as a paidicular sequence of steps. However, to the extent that the method or process does not rely on the particular order of steps set forth herein, tlie method or process should not be limited to the particular sequence of steps described. Other -22- ο ο <Ν α ο ο (Ν ιη (Ν ιη Ο (Ν 10 sequences of steps may be possible. Therefore, the particular order of the steps disclosed herein should not be construed as limitations of the present disclosure. Such sequences may be varied and still remain within the scope of the present disclosure. [0058] It is to be understood that, if any prior art publication is referred to herein, such reference does not constitute an admission that the publication forms a part of the common general knowledge in the art. [0059] In the claims which follow and in the preceding description of the invention, except where the context requires otherwise due to express language or necessary implication, the word “comprise” or variations such as “comprises” or “comprising” is used in an inclusive sense, i.e. to specify the presence of the stated features but not to preclude the presence or addition of further features in various embodiments of the invention. -23 - 9141723_1 (GHMatters) P89909.AU.1

Claims (13)

1. Claims

   1. A joint compound composition, comprising: a filler material selected from the group consisting of: calcium carbonate, calcium sulfate dehydrate, and calcium sulfate hemihydrate; a first binder comprising a first polymer, the first binder having a glass transition temperature that is equal to or greater than about -10 degrees Celsius; and a second binder comprising a second polymer, the second binder having a glass transition temperature in the range of about -80 degrees Celsius to about 10 degrees Celsius, wherein the glass transition temperature of the first binder is at least about 5 degrees Celsius greater than the glass transition temperature of the second binder; and wherein the first and second polymers have the same chemistry.
2. 2. The joint compound of claim 1, wherein the second binder further comprises a plasticizer.
3. 3. The joint compound of claim 2, wherein the first and second polymers are polymers of ethylene vinyl acetate.
4. 4. The joint compound of claim 3, wherein the plasticizer is selected from the group consisting of: a diethylene dibenzoate ester and a dipropylene dibenzoate ester.
5. 5. The joint compound of claim 1, wherein the first and second polymers comprise copolymers of a first monomer and a second monomer, the first and second polymers having different ratios of first and second monomers.
6. 6. The j oint compound of claim 5, wherein the first and second polymers are block copolymers.
7. 7. The j oint compound of claim 1, wherein the first and second polymer are selected from the group consisting of polymers of: ethylene vinyl acetate, vinyl acetate, acrylics, styrene acrylics and polyvinyl alcohol.
8. 8. The joint compound of claim 1, wherein the first binder has a glass transition temperature that is equal to or greater than 0 degrees Celsius.
9. 9. The joint compound of claim 1, wherein the first binder has a glass transition temperature that is in a range of about 0 degrees Celsius to about 40 degrees Celsius.
10. 10. The joint compound of claim 1, wherein the first binder has a glass transition temperature of about 5 degrees Celsius.
11. 11. The j oint compound of claim 1, wherein the second binder has a glass transition temperature of about -40 degrees Celsius.
12. 12. A joint compound composition, comprising: a filler material selected from the group consisting of: calcium carbonate, calcium sulfate dehydrate, and calcium sulfate hemihydrate; a first binder comprising a cellulose ether, the first binder having a glass transition temperature that is equal to or greater than about -10 degrees Celsius; and a second binder having a glass transition temperature in the range of about -80 degrees Celsius to about 10 degrees Celsius, wherein the glass transition temperature of the first binder is at least about 5 degrees Celsius greater than the glass transition temperature of the second binder.
13. 13. The joint compound of claim 12, wherein the second binder comprises a polymer selected from the group consisting of: ethylene vinyl acetate, vinyl acetate, acrylics, styrene acrylics and polyvinyl alcohol.