AU2015100738A4 - Direct electrowinning of nickel - Google Patents

Direct electrowinning of nickel Download PDF

Info

Publication number
AU2015100738A4
AU2015100738A4 AU2015100738A AU2015100738A AU2015100738A4 AU 2015100738 A4 AU2015100738 A4 AU 2015100738A4 AU 2015100738 A AU2015100738 A AU 2015100738A AU 2015100738 A AU2015100738 A AU 2015100738A AU 2015100738 A4 AU2015100738 A4 AU 2015100738A4
Authority
AU
Australia
Prior art keywords
nickel
pls
direct electrowinning
recovered
during
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
AU2015100738A
Inventor
Ndinanwi Mulaudzi
Chrisoph Karl Pawlik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mintek
Original Assignee
Mintek
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mintek filed Critical Mintek
Application granted granted Critical
Publication of AU2015100738A4 publication Critical patent/AU2015100738A4/en
Anticipated expiration legal-status Critical
Expired legal-status Critical Current

Links

Landscapes

  • Manufacture And Refinement Of Metals (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

Abstract A nickel metal product which is recovered from a dilute process solution by direct electrowinning.

Description

Page 1 DIRECT ELECTROWINNING OF NICKEL BACKGROUND OF THE INVENTION [0001] This invention relates to the recovery of nickel from a dilute process leach solution. [0002] A pregnant leach solution (PLS), which results from high-pressure acid leaching (HPAL) of laterite ores, generally contains a mix of cobalt and nickel sulphide. [0003] There are two methods by which cobalt and nickel are generally recovered from the PLS, viz. mixed sulphide precipitation (MSP), and mixed hydroxide precipitation (MHP). [0004] During the MSP process, the PLS is purified by removing copper with NaHS before precipitating the mixed nickel sulphide with H 2 S. The process is conducted in an autoclave, at a high temperature and pressure. The mixed sulphide product typically contains about 55 to 60% nickel, which is refined by hydrogen reduction or electrowinning, to produce nickel metal. [0005] Disadvantages associated with the MSP process are that; e it requires the use of H 2 S, which is an expensive and hazardous reagent; and * the autoclave is associated with high maintenance costs and requires well trained personnel to operate. 17/0/385/foreign Page 2 [0006] During the MHP process, limestone is added to remove iron, aluminium and chromium from the PLS. Nickel is then precipitated with magnesium oxide. The MHP product contains about 35% to 40% nickel sulphide, which is refined to produce nickel metal. [0007] Disadvantages associated with this process are; * it requires large recycle streams to minimise nickel and cobalt losses; and * it requires the use of magnesium oxide, which is expensive and requires downstream purification. [0008] Neither the MSP nor the MHP process produces a particularly high quality nickel metal product. Consequently a relatively large quantity of a low grade product has to be transported to a refinery, leading to an overall increase in the cost of recovery. [0009] An object of the present invention is to address, at least to some extent, the aforementioned factors in order to produce a high grade nickel product, with an increased market value, at a reduced operating cost. SUMMARY OF INVENTION [0010] In accordance with the invention a nickel metal product is recovered from a dilute process leach solution (PLS) by direct electrowinning. [0011] The nickel metal product recovered by means of direct electrowinning is of a higher grade, compared to metal products recovered by means of the MSP process and the MRP process. 17/0/385/foreign Page 3 [0012] The leach solution from which the nickel is recovered may result from a high-pressure acid leach process of laterite ores. [0013] Prior to the direct electrowinning of the nickel, iron, aluminium, copper and chromium contained in a pregnant leach solution may be removed by means of any appropriate process. [0014] The invention extends to a method of recovering a nickel metal product from a pregnant leach solution by subjecting the leach solution to direct electrowinning step. [0015] The leach solution from which the nickel is recovered may result from a high-pressure acid leach process of laterite ores. [0016] Prior to the direct electrowinning of the nickel, iron, aluminium, copper and chromium contained in a pregnant leach solution may be removed by means of any appropriate process. [0017] The PLS may be obtained from high pressure leaching of a laterite ore. [0018] Following the direct electrowinning step, lime may be added to the solution to precipitate nickel which is recovered by a solid/liquid separation step. BRIEF DESCRIPTION OF THE DRAWING [0019] The invention is further described by way of example with reference to the accompanying drawings: Figure 1 is a flow sheet of a high pressure leach process of a laterite ore during which a pregnant leach solution is formed; and 17/0/385/foreign Page 4 Figure 2 is a flow sheet of a process for recovering nickel, from the pregnant leach solution of Figure 1, in accordance with the present invention. DESCRIPTION OF PREFERRED EMBODIMENT [0020] Figure 2 of the accompanying drawings illustrates a process 10 in which the method of the invention is utilised. [0021] The process 10 is preceded by a process 10A, illustrated in Figure 1, during which a laterite ore 12 is subjected to conventional ore preparation and preheating steps 14 and 16 respectively, prior to being subjected to a high pressure acid leaching step 18. [0022] During the step 18, sulphuric acid and steam 20 are added to the prepared ore. The ore is then leached in an autoclave at a temperature between 240 0 C to 270 0 C and at a high pressure. [0023] During a subsequent heat recovery step 22, jarosite and hematite are precipitated, resulting in flash steam 24 and a leach pulp 26. The steam 24 is recycled to the step 16. [0024] The pulp 26 is subjected to a counter current decantation (CCD) step 28. Tailings 30 are directed to waste. The pH of the resulting solution is adjusted (step 32), by the addition of limestone 34 to produce a PLS 36 suitable for processing in terms of the invention. [0025] Referring to Figure 2, lime is added to the PLS 36 during a step 38 to precipitate iron, prior to a solid/liquid separation step 40, during which the precipitated iron is removed from the PLS. 17/0/385/foreign Page 5 [0026] In a step 42 additional lime is added to the PLS to precipitate copper prior, to a solid/liquid separation step 44, during which the precipitated copper metal is removed from the PLS. [0027] The step 44 is followed by a direct electrowinning circuit 46, during which nickel 48 is recovered. Some of the solution from the circuit 46 is returned to the HPAL process 10A. The remainder of the solution passes to a step 50 during which lime is added to precipitate nickel, prior to a solid/liquid separation step 52, during which the precipitated nickel is removed from the PLS. A part of the resulting solution is recycled to step 38 and the rest is directed to an effluent treatment stage. [0028] The invention is based on the use of direct electrowinning of nickel as an alternative to nickel recovery by the MSP process and MHP process from a conventional refinery. This holds significant economic value in the production of nickel, particularly at a remote site which may have a high capital investment risk and where there is a need to maximise the nickel content in the final product and hence the value. The nickel which is recovered using the technique of the invention has increased nickel purity compared to the nickel hydroxide product, although it has a lower grade than LME or A grade nickel produced by a nickel refining process. [0029] It is envisaged that nickel recovery by direct electrowinning, as is contemplated by the present invention, would significantly reduce operating costs. [0030] The method of the invention is thus capable of achieving the following: 17/0/385/foreign Page 6 * A higher grade product resulting in corresponding increased revenue; * Reduced transport cost of the higher grade product; * Use of reagents, such as MgO and H 2 S, is eliminated, decreasing the operating costs; * Limiting the use of lime; * Eliminating the use of additives; and * A simplified process for the recovery of nickel metal, which eliminates the use of an autoclave and other operational risks. [0031] In the claims which follow and in the preceding description of the invention, except where the context requires otherwise due to express language or necessary implication, the word "comprise" or variations such as "comprises" or "comprising" is used in an inclusive sense, i.e. to specify the presence of the stated features but not to preclude the presence or addition of further features in various embodiments of the invention. [0032] It is to be understood that, if any prior art publication is referred to herein, such reference does not constitute an admission that the publication forms a part of the common general knowledge in the art, in Australia or any other country. 17/0/385/foreign
AU2015100738A 2014-06-02 2015-06-02 Direct electrowinning of nickel Expired AU2015100738A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA2014/03818 2014-06-02
ZA201403818 2014-06-02

Publications (1)

Publication Number Publication Date
AU2015100738A4 true AU2015100738A4 (en) 2015-07-09

Family

ID=53547757

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2015100738A Expired AU2015100738A4 (en) 2014-06-02 2015-06-02 Direct electrowinning of nickel

Country Status (3)

Country Link
AP (1) AP2015008649A0 (en)
AU (1) AU2015100738A4 (en)
ZA (1) ZA201503920B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104724864A (en) * 2015-03-31 2015-06-24 江苏地一环保科技有限公司 Cyclone treatment technique of nickel-containing electroplating wastewater

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104724864A (en) * 2015-03-31 2015-06-24 江苏地一环保科技有限公司 Cyclone treatment technique of nickel-containing electroplating wastewater

Also Published As

Publication number Publication date
ZA201503920B (en) 2016-03-30
AP2015008649A0 (en) 2015-08-31

Similar Documents

Publication Publication Date Title
CA2590927C (en) A process for the treatment of electric and other furnace dusts and residues containing zinc oxides and zinc ferrites
Kongolo et al. Cobalt and zinc recovery from copper sulphate solution by solvent extraction
US9677155B2 (en) Method for recovering scandium from intermediate products formed in the hydrometallurgical processing of laterite ores
US20090148365A1 (en) Recovery of Solid Magnesium Sulfate Hydrate
WO2007070973A1 (en) Magnesium oxide recovery
EP2389457B1 (en) An improved process of leaching lateritic ore with sulphuric acid
AP1072A (en) Selective precipitation of nickel and cobalt.
CN105803197B (en) A kind of method of method using synergic solvent extraction removing calcium and magnesium from nickel cobalt biochemical lixivium
CA2887675A1 (en) Gold recovery from refractory ores and concentrates
NO330197B1 (en) Process for leaching zinc concentrate under atmospheric conditions
EP2703503B1 (en) Method of precipitation of iron from leach solutions
AU2015100738A4 (en) Direct electrowinning of nickel
EP3048083B1 (en) Production method for hematite for iron production
KR101510532B1 (en) The method for recovering Fe from Iron chloride solution acquired during hydrometallurgical process
JP6953765B2 (en) Iron removal method for crude nickel sulfate solution
AU2015276799B2 (en) A method of recovering base metals from low grade ores and residues
US10190189B2 (en) Scandium recovery process
AU2014209919B2 (en) Method of precipitation of iron from leach solutions
NO20130823A1 (en) Method of separating nickel from low nickel material
WO2002048042A1 (en) Hydroxide solids enrichment by precipitate contact
AU2002221333B2 (en) Hydroxide solids enrichment by precipitate contact
PH12015000134A1 (en) Nickel laterite treatment process
PH12014000329A1 (en) Low pressure nickel laterite treatment process
PH22014000781U1 (en) Nickel laterite treatment process for the production of nhp
AU5401801A (en) Processing gold containing copper sulphide feeds

Legal Events

Date Code Title Description
FGI Letters patent sealed or granted (innovation patent)
MK22 Patent ceased section 143a(d), or expired - non payment of renewal fee or expiry