AU2014363852B2 - Process for the fixed-bed pressure gasification of carbonaceous fuels - Google Patents
Process for the fixed-bed pressure gasification of carbonaceous fuels Download PDFInfo
- Publication number
- AU2014363852B2 AU2014363852B2 AU2014363852A AU2014363852A AU2014363852B2 AU 2014363852 B2 AU2014363852 B2 AU 2014363852B2 AU 2014363852 A AU2014363852 A AU 2014363852A AU 2014363852 A AU2014363852 A AU 2014363852A AU 2014363852 B2 AU2014363852 B2 AU 2014363852B2
- Authority
- AU
- Australia
- Prior art keywords
- reactor
- fixed
- gasification
- liquid
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002309 gasification Methods 0.000 title claims abstract description 105
- 238000000034 method Methods 0.000 title claims abstract description 34
- 239000000446 fuel Substances 0.000 title claims description 37
- 239000007789 gas Substances 0.000 claims abstract description 62
- 239000007788 liquid Substances 0.000 claims abstract description 52
- 239000006227 byproduct Substances 0.000 claims abstract description 49
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 30
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 30
- 239000011269 tar Substances 0.000 claims abstract description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001301 oxygen Substances 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000001257 hydrogen Substances 0.000 claims abstract description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 9
- 239000003921 oil Substances 0.000 claims abstract description 9
- 239000003245 coal Substances 0.000 claims abstract description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910002090 carbon oxide Inorganic materials 0.000 claims abstract description 6
- 239000000571 coke Substances 0.000 claims abstract description 6
- 150000002989 phenols Chemical class 0.000 claims abstract description 5
- 239000003380 propellant Substances 0.000 claims description 18
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- 238000005507 spraying Methods 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 5
- 239000001569 carbon dioxide Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 3
- 229910010293 ceramic material Inorganic materials 0.000 claims description 2
- 239000002826 coolant Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- -1 steam Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000000470 constituent Substances 0.000 description 12
- 238000006887 Ullmann reaction Methods 0.000 description 5
- 239000000428 dust Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000197 pyrolysis Methods 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004449 solid propellant Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000001141 propulsive effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/34—Grates; Mechanical ash-removing devices
- C10J3/40—Movable grates
- C10J3/42—Rotary grates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/152—Nozzles or lances for introducing gas, liquids or suspensions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
Abstract
A process for producing a synthesis gas containing hydrogen and carbon oxides by gasification of coke or coal with oxygen and steam in a fixed bed carried by a discharge grate and by producing an ash in a fixed-bed pressure gasification reactor, wherein liquid, hydrocarbonaceous by-products of the gasification, such as tars, oils, naphtha and phenols, are introduced into the fixed bed of the fixed- bed pressure gasification reactor.
Description
Process for the Fixed-Bed Pressure Gasification of Carbonaceous Fuels
Field of the Invention
This invention relates to a process for producing a synthesis gas containing hydrogen and carbon oxides by gasification of carbonaceous fuels, in particular of coke or coal, with oxygen and steam in a fixed bed carried by a discharge grate and by producing a solid ash in a fixed-bed pressure gasification reactor, wherein the carbonaceous by-products obtained during the further processing of the raw synthesis gas discharged from the fixed-bed pressure gasification reactor, such as tars, oils, naphtha or phenols, can be utilized advantageously.
Prior art
By means of fixed-bed pressure gasification reactors solid fuel, such as coal, coke or other carbonaceous fuel, is gasified with steam and oxygen as gasification medium at elevated temperature and, in most cases, at overpressure to obtain a synthesis gas containing carbon monoxide and hydrogen, wherein a solid ash is obtained, which is discharged from the reactor via an ash discharge grate which in many cases is formed as rotary grate. This type of reactor frequently also is referred to as FBDB (= Fixed Bed Dry Bottom) pressure gasifier.
In the fixed bed, the fuel passes through the following temperature zones from top to bottom with a temperature rising in this direction:
WO 2015/086353
PCT/EP2014/076040
- Drying zone: In the drying zone, moisture bound in or on the fuel is desorbed and discharged from the fixed-bed pressure gasification reactor with the raw synthesis gas stream.
- Pyrolysis zone: Here, highly volatile compounds are released from the fuel and expelled. There is effected a carbonization or coking of the fuel.
- Gasification zone: In the gasification zone the actual conversion of the fuel with the gasification medium is effected, which mostly contains air or oxygen as well as steam and possibly carbon dioxide as moderator, to obtain the target products of the gasification, namely hydrogen and carbon monoxide.
- Combustion zone: Here, the thermal energy necessary for the gasification, pyrolysis and drying is produced by combustion of a part of the fuel.
For further process details reference is made to the relevant literature, of. Ullmanns Encyclopedia of Industrial Chemistry,Sixth Edition, Vol. 15, pages 367 ff. The gasification typically starts at temperatures of about 700 °C and proceeds with high speed at temperatures of 800 °C, of. Ullmanns Encyklopadie der Technischen Chemie, 4th Edition (1977), Vol. 14, p. 384. Fig. 10 of this reference shows a typical temperature profile of the gas temperature in a fixed-bed pressure gasification reactor, in particular in the temperature zones discussed above.
Beside the target products carbon monoxide and hydrogen, the raw synthesis gas after leaving the reactor however also contains by-products obtained during the gasification, such as tars, oils, naphtha as well as phenols, which all contain hydrocarbons or consist of hydrocarbons and at ambient conditions are present in liquid form or during processing of the raw synthesis gas are obtained in liquid form, in a form dissolved in liquid or in a form dispersed in liquid (for example as emulsion in water). All of these by-products subsequently are to be understood as liquid by-products.
In addition, the raw gas contains dust entrained from the fixed bed, consisting of fuel and ash particles, and also ammonia which likewise is separated in the course of the processing of the raw synthesis gas and is obtained as valuable
WO 2015/086353
PCT/EP2014/076040
-3substance, cf. Ullmanns Encyclopedia of Industrial Chemistry, Sixth Edition, Vol. 15, page 437, Fig. 75.
In particular in smaller gasification plants it is not always economic to process the liquid by-products into a saleable state, for example with increased purity and/or liberated from solid particles. In these cases, the by-products must be disposed of properly, whereby disposal costs are incurred.
DE-OS 2607745 presents a process in which the dust-containing tars separated from the gas condensate are disposed of by recirculating them into the fixed-bed pressure gasification reactor. In this process it is disadvantageous that the recirculated mass merely is charged onto the surface of the fixed bed of the reactor. The tars contained in the mass in this way are evaporated before they reach the gasification zone of the fixed bed. The evaporated tars are discharged from the fixed-bed pressure gasification reactor with the raw synthesis gas and again washed out from the gas condensate, so that they merely are circulated between reactor and gas scrubber.
The document DE 19509570 A1 teaches a process for the pyrolysis and fixed-bed pressure gasification of carbonaceous substances. Among other things, a tar-oilsolids-water mixture is applied there onto the surface of the fuel bed by means of lances. A part of the applied substances is pyrolyzed, but a significant amount in turn is discharged from the fixed-bed pressure gasification reactor with the raw synthesis gas.
The document DE 102013202356 A1 teaches a process and an apparatus for the fixed-bed pressure gasification of solid fuels with increased performance and a widened usage spectrum of solid fuels. It is disclosed there that powdery fuels as secondary fuels are formed to a fuel strand by means of a briquetting press and subsequently are pressed into the fixed-bed pressure gasification reactor. A taroil-solids mixture obtained during the fixed-bed pressure gasification serves as agglomeration aid. Since the addition of the formed secondary fuel is effected into
WO 2015/086353
PCT/EP2014/076040
-4the drying and pyrolysis zone of the fixed-bed pressure gasification reactor, the above-described disadvantages of the discharge of volatile constituents with the raw synthesis gas exist again.
Therefore, it is the object of the invention to provide a process which is capable of recirculating the by-products into the fixed-bed pressure gasification reactor such that they are converted there into synthesis gas.
Description of the Invention
The object is solved by a process for the gasification of solid carbonaceous fuels, in particular of coke or coal, with gasification media in a fixed-bed pressure gasification reactor, comprising a gasification medium inlet, a product gas outlet, a fuel bed of solid carbonaceous fuel arranged on an ash discharge grate, a fuel supply device, an ash discharge device; wherein a raw synthesis gas containing hydrogen and carbon oxides is obtained, discharged from the fixed-bed pressure gasification reactor through the product gas outlet and subsequently processed to a pure synthesis gas, characterized in that carbonaceous by-products (liquid byproducts) of the gasification, such as tars, oils, naphtha and phenols, which during processing of the raw synthesis gas are obtained in liquid form, in a form dissolved in liquid or in a form dispersed in liquid, are introduced into the gasification zone and/or the combustion zone of the fixed-bed pressure gasification reactor and likewise at least partly converted to hydrogen and/or carbon oxides.
Further advantageous aspects of the process according to the invention can be found in sub-claims 2 to 13.
As carbonaceous fuels coke and coal are preferred due to their favorable combustion and gasification properties. The process according to the invention however also comprises the gasification of biomass with sufficiently high carbon content, when the same can form a mechanically and hydrodynamically stable fuel bed under gasification conditions. As during the conversion of the latter
WO 2015/086353
PCT/EP2014/076040
-5particularly high amounts of liquid by-products are obtained, the application of the process according to the invention here offers particular advantages.
As gasification medium oxygen or air, preferably in conjunction with steam or carbon dioxide, is used as moderator.
As ash discharge grate, a rotary grate can be used for example. The construction and use of this apparatus is known per se to the skilled person. With regard to the temperature control in the fixed-bed pressure gasification reactor, the thermal design limits for rotary grates are to be taken into account. Admissible maximum temperatures for rotary grates lie in the range from 300 to 400 °C. This also limits the inlet temperature of the gasification medium which is added via a gasification medium inlet arranged below the rotary grate, so that the gasification medium passes the rotary grate before it gets into the fuel bed.
The processing of the raw synthesis gas to a pure synthesis gas is known per se and described in the relevant literature, cf. Ullmanns Encyklopadie der Technischen Chemie, 4th Edition (1977), Vol. 14, p. 449 ff. Liquid by-products obtained thereby in particular include tar fractions, hydrocarbon fractions, e.g. naphtha, phenol-containing liquids and oil fractions. The oil fractions in part consist of tramp oils which are utilized as processing aids and for example serve for lowering the viscosity and improving the filterability of tar fractions.
As explained already in the discussion of the prior art, by-products obtained during the gasification, which contain hydrocarbons or consist of hydrocarbons and at ambient conditions are present in liquid form or during processing of the raw synthesis gas are obtained in liquid form, in a form dissolved in liquid or in a form dispersed in liquid (for example as emulsion in water), subsequently are to be understood as liquid by-products.
The transition between the above-discussed temperature zones of the fixed-bed pressure gasification reactor of course is fluent. These zones are not to be
WO 2015/086353
PCT/EP2014/076040
-6regarded as discrete regions with sharp transitions to the adjacent zones, but rather are defined idealized. For the definition of the gasification zone it is decisive that in this zone a significant conversion of the fuel to synthesis gas constituents is effected, or the gasification reaction proceeds with sufficient speed of reaction. The location of this zone inside the fixed-bed pressure gasification reactor therefore of course is dependent on its geometry and other construction as well as on its operating parameters, such as the mass flow rates and inlet temperatures of gasification medium and fuel, the composition of the gasification medium, the ash discharge mass flow rate and the operating pressure. According to experience, however, at temperatures above 700 °C a noticeable and at temperatures above 800 °C a significant conversion of the fuel with the gasification medium to synthesis gas constituents is effected.
Preferred Aspects of the Invention
The process according to the invention preferably is carried out such that at least a part of the liquid by-products introduced into the fixed-bed pressure gasification reactor gets into a region in which the gas temperature is at least 700 °C, preferably at least 800 °C. As explained above, at temperatures above 700 °C a noticeable and at temperatures above 800 °C a significant conversion of the fuel with the gasification medium to synthesis gas constituents is achieved. This is achieved in that the liquid by-products are introduced into the fixed-bed pressure gasification reactor in the region of the gasification and/or combustion zone by pumping, injecting or spraying, wherein in the case of injecting or spraying a propellant gas is used. The introduction into the fixed-bed pressure gasification reactor by injecting or spraying in particular is suitable for liquid by-products with low viscosity under the conditions of addition. For injecting or spraying the liquid by-products a propellant gas advantageously is used, which with respect to the by-products and the reactions taking place in the gasification reactor can show an either inert or reactive behavior. As inert propellant gas, nitrogen can be used for example. It is, however, particularly advantageous when in the case of injecting or spraying a reactive propellant gas is used, for example the gasification medium or one or more of its constituents. The separate provision of propellant gas thereby
WO 2015/086353
PCT/EP2014/076040
- 7 can be omitted, a further conversion to synthesis gas constituents is effected, and the product gas is not contaminated by extraneous propellant gas constituents.
When using a propellant gas, the liquid by-products can be delivered according to the principle of the propulsive jet pump, so that a further pump for delivering the liquid by-products possibly can be omitted.
When the viscosity allows, injecting or spraying of the liquid by-products advantageously is carried out such that they are atomized to a fine aerosol. In this way, a high penetration depth into the fixed bed of fuel and a high conversion to synthesis gas constituents are ensured.
Liquid by-products with a viscosity still high under the conditions of addition preferably are introduced into the fixed-bed pressure gasification reactor by pumping, wherein here as well the addition according to the invention is effected into the region of the gasification and/or combustion zone.
In a preferred aspect of the invention, injecting or spraying of the liquid byproducts into the fixed-bed pressure gasification reactor is effected via at least one nozzle installed in the wall of the reactor and directed radially into the reactor space, wherein when several nozzles are used, the same preferably are distributed on the circumference of the reactor at equal distances from each other and preferably at the same height. Due to this symmetric arrangement of the nozzles a homogeneous distribution of the liquid by-products on the individual nozzles can be ensured. In terms of construction, the nozzles can correspond to the tuyeres known from the blast-furnace process for pig iron production, of. Ullmanns Encyclopedia of Industrial Chemistry, Sixth Edition, Vol. 18, page 493.
Another particular aspect of the invention consists in that the nozzle orifices terminate with the lining of the inner reactor wall, so that they do not protrude into the inner reactor space. In this way, the mechanical load of the nozzle orifice by the material of the fixed bed sinking down is reduced.
WO 2015/086353
PCT/EP2014/076040
-8Another particular aspect of the invention consists in that carbon dioxide, steam, air or oxygen or arbitrary mixtures of these components are used as propellant gases. In the case of the addition of carbon dioxide or steam the gas rather serves as propellant, in the case of the addition of air or oxygen the propellant gas supports the oxidation and hence the gasification of the injected liquid by-products due to its oxygen content. It is advantageous that in all cases mentioned a further conversion of the propellant gas constituents can be effected in the gasification reactor or the propellant gas constituents anyway are present as components in the raw synthesis gas. The introduction of extraneous components into the process thus is avoided.
In a particularly preferred aspect of the invention, the nozzles are installed in the reactor wall at a vertical distance of 1.0 to 2.0 m, preferably 1.5 m above the highest point of the discharge grate at the same distance from each other on the circumference of the reactor. With a suitable setting and adjustment of the flow rates of fuel, oxygen and steam, the gasification zone of the fixed bed is located at this distance. The injected material thus gets into the gasification zone and together with the material of the fixed bed is converted to synthesis gas constituents. It was found to be particularly favorable when the jet direction of the nozzles is directed downwards at an angle deviating from the horizontal between 0 to 30°, preferably 0 to 20°, most preferably 0 to 10°. The residence time of the liquid by-products introduced into the fixed-bed pressure gasification reactor thereby is increased in the hot regions and their total path through the reactor is extended, which leads to an improved conversion of the liquid by-products to synthesis gas constituents. On the other hand, it thereby is avoided that the part of the fixed bed located above the nozzles is loosened up too much and that the nozzle jets possibly reach the ash layer and the grate.
Another particular aspect of the invention consists in that the nozzle exit velocity based on the amount of propellant gas exiting from the nozzle is between 50 and 150 m/s, preferably between 80 and 120 m/s. The volume of the injected liquid byproducts is neglected in the calculation. In this velocity range a sufficient
WO 2015/086353
PCT/EP2014/076040
-9penetration depth of the nozzle jet into the fixed bed is given, so that high residence times and conversions of the liquid by-products are achieved.
Another particularly preferred aspect of the invention consists in that the local temperature of the fixed bed on the inside of the reactor wall is determined by means of two rows of temperature sensors installed on the circumference of the reactor, wherein the temperature sensors within one row are spaced from each other at equal distances, wherein the vertical distance to the highest point of the discharge grate is 0.5 to 2.5 m, preferably 1.0 to 2.0 m, for the upper row, and the vertical distance to the highest point of the discharge grate is 0 to 0.5 m, preferably 0.25 m for the lower row, and wherein the quantity of the ash discharged via the discharge grate per unit time is adjusted such that a temperature between 700 and 1300 °C is measured by the upper row of temperature sensors, and a temperature between 300 and 400 °C is measured by the lower row. In this way, the vertical location of the gasification zone of the fixed bed is adjusted such that the nozzle jets reach the gasification zone and the result is a sufficient residence time of the introduced liquid by-products in the gasification zone. The large temperature ranges in both cases are due to the different properties of the possible fuels used. When the temperature of the upper sensor row lies in the stated range of 700 to 1300 °C, this shows that the gasification zone, as required, lies at the height of the nozzles.
When the temperature of the lower sensor row lies in the required range of 300 to 400 °C, it hence is ensured that a sufficiently thick ash zone lies above the discharge grate and the discharge grate thus is protected from too high temperatures.
When using a rotary grate, for example, the quantity of the ash discharged via the discharge grate per unit time can be controlled by the speed of revolution.
Another particular aspect of the invention provides that the intermixed liquid byproducts are introduced into the fixed-bed pressure gasification reactor. In this
WO 2015/086353
PCT/EP2014/076040
- 10way, the viscosity of e.g. viscous, dust-laden tars is lowered by addition of oils, so that they become more flowable, whereby the wear of the nozzle orifices is reduced. It is, however, also possible to separately introduce different liquid byproducts into the fixed-bed pressure gasification reactor via separate nozzles each. In this way, the wear can be limited to certain nozzles or the nozzles can optimally be designed corresponding to the liquid by-product to be introduced, for example by using particularly abrasion-resistant materials.
The by-products recirculated into the reactor according to the invention are liquid, although in part loaded with dust, so that they can be pumped to the nozzles by using displacement pumps, e.g. multi-head plunger or membrane pumps. Depending on the quality of the dust contained in the tar, it may be required to separate or comminute larger dust particles before introducing the tar. This can be done by using mechanical separation methods known per se from the fixed-bed gasification of coal in connection with the processing of tar products, e.g. the filtration, or by using comminution or homogenization methods.
Another particular aspect of the invention consists in that the inner wall of the reactor in the surroundings of the nozzle orifices is protected by panels, wherein the panels are made of ceramic material in which cooling elements made of metal, such as tubes, are contained, which are traversed by a cooling medium such as water. In this way, the inner wall of the reactor in the surroundings of the nozzle orifices is protected from too much exposure to heat. As a result of operating failures, such as a damage of the nozzle orifice, the nozzle jet can be deflected and come close to the reactor wall.
Exemplary Embodiments
Further developments, advantages and possible applications of the invention can also be taken from the following description of non-limiting exemplary embodiments and numerical examples as well as the drawings. All features described and/or illustrated form the invention per se or in any combination, independent of their inclusion in the claims or their back-reference.
WO 2015/086353
PCT/EP2014/076040
- 11 In the drawings:
Fig. 1 shows a longitudinal section through a fixed-bed pressure gasification reactor with inlets for liquid by-products according to the invention,
Fig. 2 shows a cross-section through the fixed-bed pressure gasification reactor at the height of the inlets for the liquid by-products.
Fig. 1 by way of example shows how the inlets for liquid by-products are distributed on the circumference of the fixed-bed pressure gasification reactor 1 at the same height. Fuel, in the present example lump coal, is supplied to the fixedbed pressure gasification reactor via the fuel addition 3. The ash obtained as byproduct of the gasification is discharged from the fixed-bed pressure gasification reactor via the ash discharge device 6. The gasification medium, in the present example steam and air or oxygen, is introduced into the fixed-bed pressure gasification reactor below the ash discharge grate 2, which in the present example is designed as rotary grate, via the gasification medium inlet 5 after completion of the heating method. The raw synthesis gas produced thereby is discharged from the fixed-bed pressure gasification reactor via the product gas outlet 6 and supplied to the further processing.
Via the inlets 7 liquid by-products, in the present case a tar-oil-naphtha mixture, are introduced into the fixed bed of the fixed-bed pressure gasification reactor. The inlets are designed as nozzles and directed downwards at an angle deviating from the horizontal by 10°. The nozzles are installed in the reactor wall at a vertical distance of 1.5 m above the highest point of the rotary grate at the same distance from each other on the circumference of the reactor. The nozzle orifices terminate with the lining of the inner reactor wall and hence do not protrude into the inner reactor space.
As propellant gas, superheated high-pressure steam is used, to which technical oxygen can be admixed. The amount of propellant gas exiting from the nozzle, based on the nozzle exit velocity, roughly is 100 m/s.
WO 2015/086353
PCT/EP2014/076040
- 12 On the inside of the reactor wall, the fixed-bed pressure gasification reactor is equipped with two rows of temperature sensors installed on the circumference of the reactor (not shown in the Figure), wherein the temperature sensors within one row are spaced from each other at equal distances. The vertical distance to the 5 highest point of the rotary grate is 1.8 m for the upper row of temperature sensors, and 0.25 m for the lower row. By adjusting a corresponding speed of revolution, the amount of ash discharged via the rotary grate per unit time is adjusted such that a temperature between 700 and 1300 °C is measured by the upper row temperature sensors and a temperature between 300 and 400 °C by the lower 10 row.
Industrial Applicability
The invention provides an economic process for disposing of the by-products obtained during the gasification. The process according to the invention is 15 particularly suitable for application in smaller gasification plants. The processing of the liquid by-products into a saleable state thereby can be omitted and the disposal costs for these by-products are reduced.
WO 2015/086353
PCT/EP2014/076040
- 13List of Reference Numerals [1] fixed-bed pressure gasification reactor [2] ash discharge grate [3] fuel supply device [4] ash discharge device [5] gasification medium inlet [6] product gas outlet [7] inlets for liquid by-products
Claims (12)
- 2014363852 31 Oct 2018Claims:1. A process for the gasification of solid carbonaceous fuels, in particular of coke or coal, with gasification media in a fixed-bed pressure gasification reactor, comprising a gasification medium inlet, a product gas outlet, a fuel bed of solid carbonaceous fuel arranged on an ash discharge grate, a fuel supply device, an ash discharge device; wherein a raw synthesis gas containing hydrogen and carbon oxides is obtained, discharged from the fixed-bed pressure gasification reactor through the product gas outlet and subsequently processed to a pure synthesis gas, wherein carbonaceous byproducts (liquid by-products) of the gasification, such as tars, oils, naphtha and phenols, which during the processing of the raw synthesis gas are obtained in liquid form, in a form dissolved in liquid or in a form dispersed in liquid, are introduced by pumping, injecting or spraying through at least one nozzle installed in a reactor wall into the gasification zone and/or the combustion zone of the fixed-bed pressure gasification reactor and likewise at least partly converted to hydrogen and/or carbon oxides; and wherein the jet direction of the at least one nozzle is directed downwards at an angle deviating from the horizontal between 0 to 30°, preferably 0 to 20°, most preferably 0 to 10°.
- 2. The process according to claim 1, wherein at least a part of the liquid by-products introduced into the fixed-bed pressure gasification reactor gets into a region in which the gas temperature is at least 700 °C, preferably at least 800 °C.
- 3. The process according to claim 1 or 2, wherein, in the case of injecting or spraying, a propellant gas is used.
- 4. The process according to claim 3, wherein the at least one nozzle installed in the wall of the reactor is directed radially into the reactor space, and wherein when a plurality of nozzles are used, the same preferably are distributed on the circumference of the reactor at equal distances from each other and preferably at the same height.
- 5. The process according to claim 4, wherein the nozzle orifices terminate with the lining of the inner reactor wall, so that they do not protrude into the inner reactor space.
- 6. The process according to any one of claims 3 to 5, wherein carbon dioxide, steam, air or oxygen or arbitrary mixtures of these components are used as propellant gases.
- 7. The process according to any one of claims 3 to 6, wherein each nozzle of a plurality of nozzles is installed in the reactor wall at a vertical distance of 1.0 to 2.0 m, preferably2014363852 31 Oct 20181.5 m above the highest point of the discharge grate at the same distance from each other on the circumference of the reactor wall.
- 8. The process according to any one of claims 3 to 7, wherein the nozzle exit velocity based on the amount of propellant gas exiting from the nozzle is between 50 and 150 m/s, preferably between 80 and 120 m/s.
- 9. The process according to any one of claims 3 to 8, wherein the local temperature of the fixed bed on the inside of the reactor wall is determined by means of two rows of temperature sensors installed on the circumference of the reactor, wherein the temperature sensors within one row are spaced from each other at equal distances, wherein the vertical distance to the highest point of the discharge grate is 0.5 to 2.5 m, preferably 1.0 to 2.0 m, for the upper row, and the vertical distance to the highest point of the discharge grate is 0 to 0.5 m, preferably 0.25 m for the lower row, and wherein the quantity of the ash discharged via the discharge grate per unit time is adjusted such that a temperature between 700 and 1300 °C is measured by the upper row of temperature sensors, and a temperature between 300 and 400 °C is measured by the lower row.
- 10. The process according to any one of the preceding claims, wherein intermixed liquid by-products are introduced into the fixed-bed pressure gasification reactor.
- 11. The process according to any one of the preceding claims, wherein different liquid byproducts are separately introduced into the fixed-bed pressure gasification reactor via separate nozzles.
- 12. The process according to any one of the preceding claims, wherein the inner wall of the fixed-bed pressure gasification reactor in the surroundings of the nozzle orifices is protected by panels, and wherein the panels are made of ceramic material in which cooling elements made of metal, such as tubes, are contained, which can be traversed by a cooling medium such as water.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102013113769.5A DE102013113769B4 (en) | 2013-12-10 | 2013-12-10 | Process for the fixed bed pressure gasification of carbonaceous fuels |
| DE102013113769.5 | 2013-12-10 | ||
| PCT/EP2014/076040 WO2015086353A1 (en) | 2013-12-10 | 2014-12-01 | Process for the fixed-bed pressure gasification of carbonaceous fuels |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2014363852A1 AU2014363852A1 (en) | 2016-07-07 |
| AU2014363852B2 true AU2014363852B2 (en) | 2018-12-06 |
Family
ID=52002953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2014363852A Active AU2014363852B2 (en) | 2013-12-10 | 2014-12-01 | Process for the fixed-bed pressure gasification of carbonaceous fuels |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN105940088B (en) |
| AU (1) | AU2014363852B2 (en) |
| DE (1) | DE102013113769B4 (en) |
| WO (1) | WO2015086353A1 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2146039A (en) * | 1983-08-25 | 1985-04-11 | British Gas Corp | Gasification of carbonaceous materials |
| DE3807387A1 (en) * | 1987-07-31 | 1989-02-09 | Schwarze Pumpe Gas Veb | Process for utilising tar/oil/solids/water mixtures |
| EP0953627A1 (en) * | 1998-04-28 | 1999-11-03 | Ansaldo Volund A/S | Method and apparatus for, in a fixed-bed gasifier, converting tar and possibly particles into combustible gas components |
| DE102012202129A1 (en) * | 2012-02-13 | 2013-08-14 | Technische Universität Bergakademie Freiberg | Fixed-bed gasification of solid, mechanically compacted, fine-grained and/or pulverized fuels e.g. tar with oxygen and water vapor-containing gasification agents using fixed-bed gasifier with head-side supply of coarse-grained fuel |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2607745C2 (en) | 1976-02-26 | 1984-03-15 | Metallgesellschaft Ag, 6000 Frankfurt | Process for treating condensate from the cooling of raw gas from the pressurized gasification of solid fuels |
| DD224611A5 (en) * | 1984-09-06 | 1985-07-10 | British Gas Corp | COAL GASIFICATION PROCESS |
| US5145490A (en) * | 1990-08-09 | 1992-09-08 | Crs Sirrine Engineers, Inc. | Process for fixed bed coal gasification |
| DE19509570C2 (en) | 1995-03-16 | 1997-01-16 | Schwarze Pumpe Energiewerke Ag | Process for pyrolysis and fixed-bed pressure gasification of carbonaceous substances |
| DE102007035301B4 (en) * | 2007-07-27 | 2009-04-30 | Lurgi Gmbh | Process and device for the utilization of brine obtained in the biological treatment of gas condensate |
| TWI558807B (en) * | 2008-12-17 | 2016-11-21 | 祿幕斯科技公司 | Gasification system and process with staged slurry addition |
| CN101580739B (en) * | 2009-03-12 | 2013-01-09 | 徐州燃控科技股份有限公司 | Fixed bed straw gasification process with tar backflash |
| CN101982529A (en) * | 2010-11-20 | 2011-03-02 | 山东百川同创能源有限公司 | High-temperature cracking system for tar in biomass fuel gas |
| KR102054353B1 (en) | 2012-02-13 | 2019-12-10 | 레르 리뀌드 소시에떼 아노님 뿌르 레뛰드 에 렉스쁠로아따시옹 데 프로세데 죠르쥬 끌로드 | Process and device for fixed-bed pressure gasification of solid fuels |
| EP2666845A1 (en) * | 2012-05-24 | 2013-11-27 | Murat Dogru | Gas producing apparatus |
| CN103289748B (en) * | 2013-03-25 | 2014-11-26 | 赵广健 | A self-tar removing biomass fixed bed gasifier system |
-
2013
- 2013-12-10 DE DE102013113769.5A patent/DE102013113769B4/en not_active Expired - Fee Related
-
2014
- 2014-12-01 WO PCT/EP2014/076040 patent/WO2015086353A1/en active Application Filing
- 2014-12-01 AU AU2014363852A patent/AU2014363852B2/en active Active
- 2014-12-01 CN CN201480066136.0A patent/CN105940088B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2146039A (en) * | 1983-08-25 | 1985-04-11 | British Gas Corp | Gasification of carbonaceous materials |
| DE3807387A1 (en) * | 1987-07-31 | 1989-02-09 | Schwarze Pumpe Gas Veb | Process for utilising tar/oil/solids/water mixtures |
| EP0953627A1 (en) * | 1998-04-28 | 1999-11-03 | Ansaldo Volund A/S | Method and apparatus for, in a fixed-bed gasifier, converting tar and possibly particles into combustible gas components |
| DE102012202129A1 (en) * | 2012-02-13 | 2013-08-14 | Technische Universität Bergakademie Freiberg | Fixed-bed gasification of solid, mechanically compacted, fine-grained and/or pulverized fuels e.g. tar with oxygen and water vapor-containing gasification agents using fixed-bed gasifier with head-side supply of coarse-grained fuel |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105940088B (en) | 2021-07-30 |
| AU2014363852A1 (en) | 2016-07-07 |
| WO2015086353A1 (en) | 2015-06-18 |
| DE102013113769B4 (en) | 2020-07-16 |
| DE102013113769A1 (en) | 2015-06-11 |
| CN105940088A (en) | 2016-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9234148B2 (en) | Process and apparatus for the utilization of the enthalpy of a syngas by additional and post-gasification of renewable fuels | |
| JP4112173B2 (en) | Method and apparatus for producing combustion gas, synthesis gas and reducing gas from solid fuel | |
| CA2699714C (en) | Gasification reactor and process for entrained-flow gasification | |
| EP2321387B1 (en) | Two stage entrained gasification system and process | |
| KR101874152B1 (en) | Process for the gasification of heavy residual oil with particulate coke from a delayed coking unit | |
| EP2430127B1 (en) | Two stage dry feed gasification system and process | |
| KR101966578B1 (en) | Chemical Roofing Combustion Process with Gravity Feed of Oxidized Particles and Various Fuel Reaction Zones | |
| US20150090938A1 (en) | Method and Device for the Entrained Flow Gasification of Solid Fuels under Pressure | |
| RU2607662C2 (en) | Method and device for gasification of solid combustible materials under pressure in stationary layer | |
| CN104342212B (en) | PC-FB hydropyrolysis and gasification coupling method | |
| CN103974898A (en) | Gasification of heavy residue with solid catalyst from slurry hydrocracking process | |
| CN102453550B (en) | Multi-nozzle multi-stage oxygen supplying entrained-flow gasifier and gasification method thereof | |
| CN104611063B (en) | A kind of airflow bed gasification furnace | |
| US9464248B2 (en) | Combined quenching and scrubbing system with guide tube for an entrained flow gasifying reactor | |
| US2689786A (en) | Process for the gasification of solid fuels | |
| AU2014363852B2 (en) | Process for the fixed-bed pressure gasification of carbonaceous fuels | |
| CN109054901A (en) | A kind of down-flow fluidized bed using ECT-fluidized bed tandem gasification process and device | |
| CN109072103A (en) | Two-stage gasifier and gasification process with feed flexibility | |
| US20150014594A1 (en) | Process and apparatus for molten slag gasification of solid fuels | |
| CN110938472A (en) | Gasification furnace and coal gasification method | |
| AU2014352152A1 (en) | Method for heating a fuel bed in a fixed-bed pressure gasification reactor | |
| EP3050941B1 (en) | Process and reactor for gasification or organic solid materials | |
| CN102888249A (en) | Coal gasification method | |
| JP4357484B2 (en) | A method for predicting the amount of gas produced during coal gasification. | |
| KR20130070774A (en) | Method for manufacturing fuel gas from wasted plastics in finex process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) |