AU2014203689B2

AU2014203689B2 - Combinations comprising a fungicidal strain and an active compound

Info

Publication number: AU2014203689B2
Application number: AU2014203689A
Authority: AU
Inventors: Egon Haden; Maria Scherer; Ulrich Schöfl
Original assignee: Bayer CropScience LP
Current assignee: Bayer CropScience LP
Priority date: 2007-09-20
Filing date: 2014-07-04
Publication date: 2016-02-04
Anticipated expiration: 2028-09-16
Also published as: AU2014203689A1

Abstract

Fungicidal mixtures, comprising 1) a fungicidal strain (1) selected from a) the Bacillus substilis strain with NRRL Accession No. B-21661, and b) the Bacillus pumilus strain with NRRL Accession No. B-30087, or a mutant of these strains having all the identifying characteristics of the respective strain, or a metabolite produced by the respective strain that exhibits activity against plant pathogenic fungi, and 2) at least one chemical compound (11), selected from the active compound groups A) to F): A) azoles; B) strobilurins; C) carboxamides; D) heterocyclic compounds; E) carbamates; F) other fungicides; in a synergistically effective amount, methods for controlling harmful fungi using compositions of components 1) and 2), the use of a component 1) with acomponent 2) for preparing such compositions, and also fungicidal agents and seed comprising such compositions.

Description

1 Combinations comprising a fungicidal strain and an active compound Description 5 The present invention relates to fungicidal compositions for controlling phytopathogenic harmful fungi comprising, as active components, 1) a fungicidal strain (I) selected from a) the Bacillus substilis strain with NRRL Accession No. B-21661, and b) the Bacillus pumilus strain with NRRL Accession No. B-30087, 10 or a mutant of these strains having all the identifying characteristics of the respective strain, or a metabolite produced by the respective strain that exhibits activity against plant pathogenic fungi; and 15 2) at least one chemical compound (II), selected from the active compound groups A) to F): A) azoles selected from the group consisting of azaconazole, diniconazole-M, oxpoconazol, paclobutrazol, uniconazol, 1-(4-chloro-phenyl)-2-([1,2,4]triazol- 1 -yl)-cycloheptanol and imazalil sulfphate; 20 B) strobilurins selected from the group consisting of 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5 fluoro-pyrimidin-4-yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide and 3-methoxy-2-(2-(N (4-methoxy-phenyl)-cyclo-propanecarboximidoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester; 25 C) carboxamides selected from the group consisting of benalaxyl, benalaxyl-M, 2-amino-4-methyl-thiazole-5-carboxamide, 2-chloro-N-(1,1,3-trimethyl-indan-4-yl)-nicotinamide, N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide, N-(4' chloro-3',5-difluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,

N

30 (4'-chloro-3',5-difluoro-biphenyl-2-yl)-3-trifluoromethyl-1-methyl-iH-pyrazole-4-carboxamide, N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N (trans-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1-methyl-iH-pyrazole-4-carboxamide, fluopyram, N-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formylamino-2-hydroxy-benzamide, oxytetracyclin, silthiofam, N-(6-methoxy-pyridin-3-yl) cyclopropanecarboxylic acid amide, 35 penthiopyrad, isopyrazam and a 1 -methyl-pyrazol-4-ylcarboxamide of the formula III 2 R O N NH| H3C R R5 R' in which the substituents are as defined below: X is hydrogen or fluorine;

R

1 is Ci-C4-alkyl or C-C 4 -haloalkyl; 5 R 2 is hydrogen or halogen;

R

3 , R 4 and R 5 independently of one another are hydrogen, cyano, nitro, halogen, CI-C 4 -alkyl, C-C4-haloalkyl, Cr1C4-alkoxy, CI-C4-haloalkoxy, Ct-C4-alkylthio or C-C 4 -haloalkyl; 10 D) heterocyclic compounds selected from the group consisting of 5-chloro-7-(4 methylpiperidin-1 -yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, 2,3,5,6-tetrachloro-4-methanesulfony-pyridine, 3,4,5-trichloro-pyridine-2,6-di carbonitrile, N-(1-(5-bromo-3-chloro-pyridin-2-yl)-ethyl)-2,4-dichloro nicotinamide, N-((5-bromo-3-chloro-pyridin-2-yI)-methyl)-2,4-dichloro 15 nicotinamide, diflumetorim, nitrapyrin, dodemorph-acetate, fluoroimid, blasti cidin-S, chinomethionat, debacarb, oxolinic acid, piperalin and an azolopyrimidin-7-ylamine of the formula IV

NH

2 N'N El E / IV, A' N E 2 in which the substituents have the following meanings: 20 El is C3-Cn-alkyl, Cr0C12-alkenyl, Cs-Ciz-alkoxyalkyl, C3-C6-cycloalkyl, phenyl or phenyl-CI-C4-alkyl;

E

2 is C1r-C2-alkyl, CrC12-alkenyl, Ci-C4-haloalkyl or Ci-C 4 -alkoxy-Ci-C 4 alkyl; 25 where the aliphatic chains in El and/or E 2 may be substituted by one to four identical or different groups Ra: Ra is halogen, cyano, hydroxyl, mercapto, C-Co-alkyl, C-CIo-haloalkyl, Ca-Ca-cycloalkyl, C2-Co-alkenyl, CrC1o-alkynyl, C1C6-alkoxy, Ci-C6 alkylthio, C-C6-alkoxy-C-CS-alkyl or NRARB; 3. RA, RB independently of one another are hydrogen or Cr1C6-alkyl; where the cyclic groups in E' and/or Ra may be substituted by one to four groups Rb: 3 Rb is halogen, cyano, hydroxyl, mercapto, nitro, NRA R B, Cl-C1o-alkyl, Ci-C 6 -haloalkyl, C 2

-C

6 -alkenyl, C 2

-C

6 -alkynyl or C 1

-C

6 -alkoxy; E 3 is hydrogen, halogen, cyano, NRARB, hydroxyl, mercapto, C 1

-C

6 alkyl, Ci-C 6 -haloalkyl, C 3

-C

8 -cycloalkyl, C 1

-C

6 -alkoxy, Ci-C 6 -alkylthio,

C

3

-C

8 -cycloalkoxy, C 3

-C

8 -cycloalkylthio, carboxyl, formyl, Ci-Cio-alkyl carbonyl, C 1 -Ci-alkoxycarbonyl, C 2 -Cio-alkenyloxycarbonyl, C 2 -Cio alkynyloxycarbonyl, phenyl, phenoxy, phenylthio, benzyloxy, benzylthio or Ci-C 6 -alkyl-S(O)m-; 10 m is 0, 1 or 2; A is CH or N; 15 E) carbamates selected from the group consisting of methasulphocarb and p propamocarb hydrochlorid; F) other fungicides selected from the group consisting of metrafenone, dodine free base, guazatine-acetate, iminoctadine-triacetate, iminoctadine 20 tris(albesilate), kasugamycin-hydrochlorid-hydrat, dichlorophen, pentachlorophenol and its salts, N-(4-chloro-2-nitro-phenyl)-N-ethyl-4 methyl-benzenesulfon-amide, dicloran, nitrothal-isopropyl, tecnazen, biphenyl, bronopol, diphenylamine, mildiomycin, oxin-copper, prohexadione calcium, N-(cyclopropylmethoxyimino-(6-difluoromethoxy 25 2,3-difluoro-phenyl)-methyl)-2-phenyl acetamide, N'-(4-(4-chloro-3 trifluoromethyl-phenoxy)-2,5-dimethyl-phenyl)-N-ethyl-N-methyl formamidine, N'-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5-dimethyl phenyl)-N-ethyl-N-methyl formamidine, N'-(2-methyl-5-trifluormethyl-4 (3-trimethylsilanyl-propoxy)-phenyl)-N-ethyl-N-methy formamidine and 30 N'-(5-difluormethyl-2-methyl-4-(3-trimethylsilanyl-propoxy)-phenyl)-N ethyl-N-methyl formamidine; in a synergistically effective amount.

3a According to one embodiment, there is provided, a fungicidal composition for controlling phytopathogenic harmful fungi, comprising 1) Bacillus subtilis strain with NRRL Accession No. B-21661 or a mutant 5 thereof having all the identifying characteristics of the strain, and 2) an active carboxamide compound selected from the group consisting of N (3',4'-dichloro-5-fluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4 carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H pyrazole-4-carboxamide, N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5-fluoro-1H 10 pyrazole-4-carboxamide and fluopyram. Moreover, the invention relates to a method for controlling harmful fungi using a composition of components 1) and 2), to the use of a component 1) with a component 2) 15 3b for preparing such compositions, and also to agents and seed comprising such compositions. The strains (I), their mutants and the metabolites produced by the strains that exhibit 5 activity against plant pathogenic fungi, referred to above as component 1), their preparation and their action against harmful fungi are known from WO 98/50422, 4 WO 00/29426 and WO 00158442, therein also referred to as AQ713 (QST713) and QST2808. Isolates of bacteria of species Bacillus subtilis and Bacillus pumilus which are effective 5 in inhibiting the growth of fungi of species botrytis cinerea and/or Alternaria brassicicola and a method of obtaining those isolates are also known from WO 93/18654. Example 13 of WO 98/50422 already discloses that synergistic activity is obtained by the combined treatment of component 1) a) and azoxystrobin. 10 NRRL is the abbreviation for the Agricultural Research Service Culture Collection, an international depositary authority for the purposes of deposing microorganism strains under the BUDAPEST TREATY ON THE INTERNATIONAL RECOGNITION OF THE DEPOSIT OF MICROORGANISMS FOR THE PURPOSES OF PATENT PROCE 15 DURE, having the address National Center for Agricultural Utilization Research, Agri cultural Research Service, U.S. Department of Agriculture, 1815 North University Street, Peoria, Illinois 61604, USA. Suitable formulations of the Bacillus subtilis strain 1) a) are commercially available un 20 der the tradenames RHAPSODY*, SERENADE* MAX and SERENADE* ASO from AgraQuest, Inc., USA. Suitable formulations of the Bacillus pumilus strain 1) b) are commercially available under the tradenames SONATA* and BALLAD* Plus from AgraQuest, Inc., USA. 25 However, the known strains (I), their mutants and the metabolites produced by the strains are, in particular at low application rates, not entirely satisfactory. The active compounds (II) mentioned above as component 2), their preparation and 30 their action against harmful fungi are generally known (cf., for example, http://www.hclrss.demon.co.uk/index.htmi); they are commercially available. N-(2-bicycloprop-2-yl-phenyl)-3-difluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide is known from WO 03/074491 and can be prepared in the manner described therein. 35 The fungicidal activity of said compound against various harmful fungi is known from WO 2006/015866. Isopyrazam is known from WO 04/035589 and can be prepared in the manner described therein or as described in WO 2007/068417. 40 The 1-methyl-pyrazol-4-ylcarboxanilides of formula (Ill) are known from the literature 5 (cf., for example, EP-A 545 099, EP-A 589 301, WO 99/09013, WO 2003/70705 and WO 2006/087343), or they can be prepared in the manner described therein. The azolopyrimidin-7-ylamines IV, their preparation and their action against harmful 5 fungi are known from the literature (EP-A 71 792; EP-A 141 317; WO 03/009687; WO 05/087771; WO 05/087772; WO 05/087773; WO 2005/087772; WO 2006/087325; WO 2006/092428). Metrafenone, 3'-bromo-2,3,4,6'-tetramethoxy-2',6-dimethylbenzophenone, is known 10 from US 5,945,567. It was an object of the present invention, with a view to reducing the application rates and broadening the activity spectrum of the strains (1) and compounds (II), to provide compositions which, at a reduced total amount of active compounds applied, have 15 improved activity against harmful fungi, in particular for certain indications. We have accordingly found that this object is achieved by the compositions, of components 1) and 2), defined at the outset. Moreover, we have found that simultaneous, that is joint or separate, application of componentws 1) and 2) or 20 successive application of the components 1) and 2) allows better control of harmful fungi than is possible with the strains, their mutants and the metabolites produced by the strains on the one hand and with the individual compounds (11) on the other hand, alone (synergistic mixtures). 25 By simultaneous, that is joint or separate, application of components 1) and 2), the fungicidal activity is increased in a superadditive manner. Component 1) embraces not only the isolated, pure cultures of the Bacillus substilis strain and the Bacillus pumilus strain, but also their suspensions in a whole broth 30 culture or as a metabolite-containing supernatant or a purified metabolite obtained from a whole broth culture of the strain. Whole broth culture" refers to a liquid culture containing both cells and media. Supernatant" refers to the liquid broth remaining when cells grown in broth are removed by centrifugation, filtration, sedimentation, or other means well known in the 35 art. The term " metabolite" refers to any compound, substance or byproduct of a fermentation or a microorganism that has fungicidal activity. 40 Preferred component 1) is a fungicidal strain 1) a), the Bacillus substilis strain with NRRL Accession No. B-21661, a mutant thereof having all the identifying characteris- 6 tics of the strain, or a metabolite produced by the strain that exhibits activity against plant pathogenic fungi. Many of the active compounds 11 can be present in different crystal modifications, which 5 may differ in biological activity. They also form part of component 2). Preference is given to compositions of a component 1) with a component 2) consisting of at least one active compound (II) selected from the group of A) azoles. 10 Preference is also given to compositions of a component 1) with a component 2) con sisting of at least one active compound (II) selected from the group of B) strobilurins. Preference is given to compositions of a component 1) with a component 2) consisting of at least one active compound (II) selected from the group of C) carboxamides. 15 Among the group of C) carboxamides, penthiopyrad, N-(2-(1,3-dimethylbutyl)-phenyl) 1,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxamide, N-(cis-2-bicyclopropyl-2-yl-phenyl) 3-difluoromethyl-1-methyi-1H-pyrazole-4-carboxamide, N-(trans-2-bicyclopropyl-2-y phenyl)-3-difluoromethy-1 -methyl-1 H-pyrazole-4-carboxamide and the 1-methyl 20 pyrazol-4-ylcarboxanilides of the formula III are preferred. In the formula Ill, halogen is fluorine, chlorine, bromine or iodine, preferably fluorine or chlorine; 25 CI-C4-alkyl is methyl, ethyl, n-propyl, 1-methylethyl, n-butyl, 1-methylpropyl, 2 methylpropyl or 1,1-dimethylethyl, preferably methyl or ethyl;

C

1

-C

4 -haloalky is a partially or fully halogenated C 1

-C

4 -alkyl radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, 30 chloromethyl, bromomethyl, dichioromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2 difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2 dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, heptafluoropropyl or 35 nonafluorobutyl, in particular halomethyl, with particular preference CH-Cl, CH(CI) 2 , CH2-F, CHF 2 , CF 3 , CHFCI, CF 2 CI or CF(C) 2 , in particular CHF 2 or CF 3 ; Cl-C 4 -alkoxy is OCH 3 , OC2-s, OCH 2

-C

2

H

5 , OCH(CH3) 2 , n-butoxy, OCH(CH 3

)-C

2

H

5 ,

OCH

2 -CH(CH3) 2 or OC(CH3) 3 , preferably OCH3 or OC2H; 40 Cl-C 4 -haloalkoxy is a partially or fully halogenated C1C4-alkoxy radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, 7 chloromethoxy, bromomethoxy, dichloromethoxy, trichloromethoxy, fluoromethoxy, difluoromethoxy, trifluoromethoxy, chlorofluoromethoxy, dichlorofluoromethoxy, chloro difluoromethoxy, 1-chloroethoxy, 1-bromoethoxy, 1-fluoroethoxy, 2-fluoroethoxy, 2,2 difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-2,2 5 difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy, heptafluoropropoxy or nonafluorobutoxy, in particular halomethoxy, particularly pref erably OCH 2 -CI, OCH(CI) 2 , OCH 2 -F, OCH(F) 2 , OCF 3 , OCHFCI, OCF 2 CI or OCF(CI) 2 ; C-C4-alkylthio is SCH 3 , SC2H-, SCH 2

-C

2

H

5 , SCH(CH 3

)

2 , n-butylthio, SCH(CH3)-C 2

H

5 , 10 SCH 2 -CH(CH3) 2 or SC(CH3)3, preferably SCH 3 or SC2H 5 .

C-C

4 -haloalkylthio is a partially or fully halogenated Cr-C 4 -alkylthio radical, where the halogen atom(s) is/are in particular fluorine, chlorine and/or bromine, i.e., for example, chloromethylthio, bromomethylthio, dichloromethylthio, trichloromethylthio, fluoro 15 methylthio, difluoromethylthio, trifluoromethylthio, chlorofluoromethylthio, dichloro fluoromethylthio, chlorodifluoromethylthio, 1-chloroethylthio, 1-bromoethylthio, 1 fluoroethylthio, 2-fluoroethylthio, 2,2-difluoroethylthio, 2,2,2-trifluoroethylthio, 2-chloro 2-fluoroethylthio, 2-chloro-2,2-difluoroethylthio, 2,2-dichloro-2-fluoroethylthio, 2,2,2-tri chloroethylthio, pentafluoroethylthio, heptafluoropropylthio or nonafluorobutylthio, in 20 particular halomethylthio, particularly preferably SCF 3 ; Preferred 1-methylpyrazol-4-ylcarboxanilides Ill are, on the one hand, those in which X is hydrogen. 25 On the other hand, preferred compounds Ill are those in which X is fluorine. For the mixtures according to the invention, preference is given to compounds of the formula Ill in which R' is methyl or halomethyl, in particular CH 3 , CHF 2 , CH 2 F, CF 3 , CHFCI or CF 2 CI. 30 Preference is furthermore given to compounds Ill in which R 2 is hydrogen, fluorine or chlorine, in particular hydrogen. Preference is furthermore given to those compounds Ill in which R 3 is halogen, Cr1C4 35 alkyl, C-C 4 -haloalkyl, C-C 4 -alkoxy, C-C 4 -haloalkoxy or C-C 4 -alkylthio, preferably halogen, methyl, halomethyl, methoxy, halomethoxy or methylthio, in particular F, Cl,

CH

3 , CF 3 , OCH 3 , OCHF 2 , OCF 3 or SCH 3 , particularly preferably fluorine. Moreover, preference is given to those compounds Ill in which R 4 is halogen, in par 40 ticular fluorine.

8 Preference is furthermore given to those compounds Ill in which R 5 is halogen, in par ticular fluorine. Among those 1-methylpyrazol-4-ylcarboxanilides liI where X is hydrogen, particular 5 preference is given to N-(2'-fluoro-4'-chloro-5'-methoxybiphenyl-2-yl)-3-trifluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide, N-(2'-fluoro-4'-chloro-5'-methylbiphenyl-2-yl) 3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl) 3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N-(2',4',5'-trifluorobiphenyl-2-yl) 3-trifluoromethyl-1-methyl-IH-pyrazole-4-carboxamide, N-(2'-fluoro-4'-chloro-5' 10 methoxybiphenyl-2-y)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N (2',3',4'-trifluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide, N (2'-fluoro-4'-chloro-5'-methyl biphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole 4-carboxamide, N-(3',4',5'-trifluorobiphenyl-2-y)-3-difluoromethyl-1 -methyl-1 H-pyrazole 4-carboxamide, N-(2',4' ,5'-trifluorobiphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole 15 4-carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl)-3-fluoromethyl-1-methyl-1H-pyrazole-4 carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorodifluoromethyl-1-methyl-iH pyrazole-4-carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide, N-(2',3',4'-trifiuorobipheny-2-yl)-3-fluoromethyl 1-methyl-1 H-pyrazole-4-carboxamide, N-(2',4',5'-trifluorobiphenyl-2-yl)-3-fluoro-methyl 20 1-methyl-1H-pyrazole-4-carboxamide, N-(4'-trifluoromethylthio-biphenyl-2-yl)-3-difluoro methyl-1-methyl-1 H-pyrazole-4-carboxamide and N-(4'-trifluoromethylthio-biphenyl-2-yl) 1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide. Among those 1-methylpyrazol-4-ylcarboxanilides I where X is fluorine, particular 25 preference is given to N-(3',4'-dichloro-3-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl 1H-pyrazole-4-carboxamide, N-(3',4'-dichloro-3-fluorobiphenyl-2-yl)-1-methyl-3 difluoromethyl-1H-pyrazole-4-carboxamide, N-(3',4'-difluoro-3-fluorobiphenyl-2-yl)-1 methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',4'-difluoro-3-fluorobiphenyl 2-yl)-1 -methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, N-(3'-chloro-4'-fluoro-3 30 fluorobiphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxa mid e, N-(3',4' dichloro-4-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(3',4'-difluoro-4-fluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide, N-(3',4'-dichloro-4-fluorobiphenyl-2-yl)-1 -methyl-3-difluoromethyl-1 H pyrazole-4-carboxamide, N-(3',4'-difluoro-4-fluorobiphenyl-2-yl)-1-methyl-3 35 difluoromethyl-1 H-pyrazole-4-carboxamide, N-(3'-chloro-4'-fluoro-4-fluorobiphenyl-2-yl) 1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide, N-(3',4'-dichloro-5 fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',4'-difluoro-5-fluorobipheny-2-y)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide, N-(3',4'-dichloro-5-fluorobiphenyl-2-y)-1-methyl-3-difluoromethyl-1H 40 pyrazole-4-carboxamide, N-(3',4'-difluoro-5-fluorobiphenyl-2-yl)-1-methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide, N-(3',4'-dichloro-5-fluorobiphenyl-2-y)-1,3- 9 dimethyl-1H-pyrazole-4-carboxamide, N-(3'-chloro-4'-fluoro-5-fluorobiphenyl-2-yl)-1 methyl-3-difluoromethyl-1 H-pyrazole-4-carboxamide, N-(4'-fluoro-4-fluorobiphenyl-2-yl) 1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(4'-fluoro-5-fluorobiphenyl-2 yI)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide, N-(4'-chloro-5 5 fluorobiphenyl-2-yl)-1 -methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(4'-methyl-5-fluorobiphenyl-2-yl)-1-methyl-3-trifluoromethyl-1 H-pyrazole-4 carboxamide, N-(4'-fluoro-5-fluorobiphenyl-2-yl)-1,3-dimethyl-1 H-pyrazole-4 carboxamide, N-(4'-chloro-5-fluorobiphenyl-2-yl)-1,3-dimethyl-1 H-pyrazole-4 carboxamide, N-(4'-methyl-5-fluorobiphenyl-2-yl)-1,3-dimethyl-1H-pyrazole-4 10 carboxamide, N-(4'-fluoro-6-fluorobiphenyl-2-y)-1 -methyl-3-trifluoromethyl-1 H pyrazole-4-carboxamide and N-(4'-chloro-6-fluorobiphenyl-2-yl)-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide. Preference is furthermore also given to compositions of a component 1) with a compo 15 nent 2) consisting of at least one active compound (II) selected from the group of D) heterocyclic compounds. Among the D) heterocyclic compounds, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6 trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine and the azolopyrimidin-7-ylamines of the 20 formula IV are preferred. In the formula IV, halogen is fluorine, chlorine, bromine or iodine. alkyl: saturated, straight-chain or branched hydrocarbon radicals having 1 to 4, 1 to 6, 1 25 to 10, 1 to 12 or 3 to 12 carbon atoms, for example CI-C-alkyl, such as methyl, ethyl, propyl, 1 -methylethyl, butyl, 1 -methylpropyl, 2-methylpropyl, 1,1 -dimethylethyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2 30 dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2 trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2 methylpropyl; haloalkyl: straight-chain or branched alkyl radicals having 1 to 4, 1 to 6 or 1 to 10 car 35 bon atoms (as mentioned above), where some or all of the hydrogen atoms in these radicals may be replaced by halogen atoms as mentioned above: in particular CrC2 haloalkyl such as chloromethyi, bromomethyl, dichloromethyl, trichloromethyl, fluoro methyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chloro difluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl, 2-fluoroethyl, 40 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 10 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl or 1,1,1-trifluoroprop-2 yl; alkenyl: unsaturated straight-chain or branched hydrocarbon radicals having 2 to 6, 2 to 5 10 or 2 to 12 carbon atoms and one or two double bonds in any position, for example CrCs-alkenyl, such as ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2 butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl- -propenyl, 1-methyl-2-propeny, 2 methyl-2-propenyl, 1 -pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-methyl-1 -butenyl, 2-methyl-1-butenyl, 3-methyl-1-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3 10 methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1 dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-1 propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1 methyl-1 -pentenyl, 2-methyl-1 -pentenyl, 3-methyl-1 -pentenyl, 4-methyl-1 -pentenyl, 1 methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1 15 methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1 methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-1-butenyl, 1,2-dimethyl 2-butenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl-1-butenyl, 1,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl 20 2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2-butenyl, 1-ethyl-1 -butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyi, 2-ethyl-1-butenyl, 2-ethyl 2-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl, 1-ethyl-2-methyl-1-propenyl or 1-ethyl-2-methyl-2-propenyl; 25 alkynyl: straight-chain or branched hydrocarbon radicals having 2 to 6 or 2 to 10 carbon atoms and one or two triple bonds in any position, for example C 2

-C

6 -alkynyl, such as ethynyl, 1-propynyl, 2-propyny, 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-2-butynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 3-methyl-1-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 30 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 1-methyl-2-pentynyl, 1-methyl 3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-methyl 1-pentynyl, 3-methyl-4-pentynyl, 4-methyl-1-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl 3-butynyl, 3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl 35 or i-ethyl-i-methyl-2-propynyl: cycloalkyl: mono- or bicyclic saturated hydrocarbon radicals having 3 to 6 or 3 to 8 car bon ring members, for example C-Cs-cycloalkyl, such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl or cyclooctyl; 40 11 cycloalkoxy: mono- or bicyclic saturated hydrocarbon radicals which are attached via an oxygen atom (-0-); cycloalkylthio: mono- or bicyclic, saturated hydrocarbon radicals which are attached via 5 a sulfur atom (-S-); alkylthio: saturated, straight-chain or branched hydrocarbon radicals which are at tached via a sulfur atom (-S-); 10 alkylcarbonyl: straight-chain or branched alkyl radicals which have 1 to 10 carbon at oms and are attached via a carbonyl group (-CO-); alkoxy: straight-chain or branched alkyl radicals which are attached via an oxygen atom (-0-); 15 alkoxyalkyl: straight-chain or branched alkoxy radicals which are attached to an alkyl radical; haloalkoxy: straight-chain or branched alkoxy radicals, where some or all of the hydro 20 gen atoms in these radicals may be replaced by halogen; alkoxycarbonyl: alkoxy radicals which have 1 to 10 carbon atoms and are attached via a carbonyl group (-CO-); 25 alkenyloxycarbonyl: alkenyl radicals which are attached via an oxygen atom (-0-) to a carbonyl group (-CO-); alkynyloxycarbonyl: alkynyl radicals which are attached via an oxygen atom (-0-) to a carbonyl group (-CO-); 30 phenylalkyl: a phenyl group which is attached via saturated, straight-chain or branched alkyl radicals. Preferred azolopyrimidin-7-ylamines IV are those compounds in which El is straight 35 chain or branched C3-C12-alkyl or phenyl which may be substituted by one to three halogen or CrC-4-alkyl groups. In one embodiment of the compounds IV, the aliphatic chains in El and E 2 or in E 1 or

E

2 are not substituted by Ra. 40 12 A preferred embodiment relates to compounds IV in which El is straight-chain or branched C5-C1o-alkyl, in particular ethyl, 3,5,5-trimethylhexyl, n-heptyl, n-octyl, n-nonyl or n-decyl. 5 A further embodiment relates to compounds IV in which Ei is phenyl which is unsubsti tuted or substituted by one to four radicals Rb. Preferred compounds IV are those in which El is a substituted phenyl group which cor responds to a group Ar

(L

3 )r L 10 #q(L 2 in which

L

1 to L 3 are halogen, cyano, hydroxyl, mercapto, nitro, NRARB, C 1 -C1o-alkyl, CrCs haloalkyl, C2-CS-alkenyl, C2-CO-alkynyl or CrC6-alkoxy; r and q independently of one 15 another may be 0 or 1 sein, where NRARB is as defined in formula IV and # denotes the bond to the azolopyrimidine skeleton. In a further embodiment of the compounds IV, L 1 is halogen, cyano, hydroxyl, mer capto, nitro, NRARB, C-Ce-alkyl, halomethyl and C-Cralkoxy, preferably halogen, 20 cyano, C-Co-alkyl, halomethyl or CI-C2-alkoxy. In a further embodiment of the compounds IV, q is 0 or L 2 is one of the groups men tioned above and q is 1. 25 In a further embodiment of the compounds IV, r is 0 or L 3 is halogen, cyano, hydroxyl, mercapto, nitro, NRARB, C 1

-C

6 -alkyl, halomethyl or C-C 2 -alkoxy and r is 1. Preferably, r is zero. Preference is given to compounds IV in which E 2 is straight-chain or branched C-C1 30 alkyl, C-C4-alkoxy-C 1

-C

4 -aIkyl or C-C 4 -haloalkyl. In a particularly preferred embodiment of the compounds IV, E 2 is methyl, ethyl, n propyl, n-octyl, trifluoromethyl or methoxymethyl, in particular methyl, ethyl, trifluoro methyl or methoxymethyl. 35 Preference is furthermore given to compounds IV in which E 3 is hydrogen. In a further embodiment of the compounds IV, E 3 is amino.

13 One embodiment of the compounds IV relates to those in which A is N. These com pounds correspond to formula IVa in which the variables are as defined for formula IV:

NH

2 E3 IVa 5 Another embodiment of the compounds of the formula IV relates to those in which A is CH. These compounds correspond to formula lVb in which the variables are as defined for formula IV:

NH

2

E

3 >N N IVb N E 2 10 In a further embodiment of preferred compounds IV, the sum of the carbon atoms in the carbon radicals of El and E 2 is not more than 12. Very particularly preferred azolopyrimidin-7-ylamines IV are those listed in Table 1: 15 Table I No. Compound IV. 1 6-(3,4-dichloroph enyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimid in-7-yla mine IV.2 6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine IV.3 5-methyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[ 1,5-alpyrimid in-7-ylamine IV.4 5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine IV.5 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-2,7-diamine IV.6 6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine IV.7 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine IV.8 5-ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine IV.9 6-octyl-5-propyl-[1,2,4]triazolof1,5-a]pyrimidin-7-ylamine IV.10 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine IV.11 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine V.12 5-trifluoromethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine Preference is furthermore also given to compositions of a component 1) with a compo nent 2) consisting of at least one active compound (II) selected from the group of E) carbamates. 20 Preference is furthermore also given to compositions of a component 1) with a compo nent 2) consisting of at least one active compound (11) selected from the group of F) 14 other fungicides. Preference is also given to compositions of a component 1) with a component 2) con sisting of at least one active compound (II) selected from the group of F) other fungi 5 cides selected from the group consisting of metrafenone, dodine free base, guazatine acetate, iminoctadine-triacetate, iminoctad ine-tris(albesilate), kasugamycin hydrochlorid-hydrat, dichlorophen, pentachlorophenol and its salts, N-(4-chloro-2-nitro phenyl)-N-ethyl-4-methyl-benzenesulfon-amide, dicloran, nitrothal-isopropyl, tecnazen, biphenyl, bronopol, diphenylamine, mildiomycin, oxin-copper and prohexadione cal 10 cium, in particular metrafenone, dodine free base, guazatine-acetate, iminoctadine triacetate, iminoctadine-tris(albesilate), nitrothal-isopropyl, mildiomycin, oxin-copper and prohexadione calcium. Very particularly preferred is metrafenone. Particular preference is given to compositions of a compound 1) with a component 2) 15 consisting of at least one active compound (il) selected from groups C), D) and F), whereas each of C), D) and F) may consist of all members or the preferred embodi ments. Preference is also given to three-component compositions comprising a component 1), 20 wherein component 2) consists of two of the active compounds (II) mentioned above. Preference is also given to three-component compositions comprising, in addition to component 1) and component 2) consisting of one active compound (11) mentioned above, a further fungicidally active compound V selected from active compound groups 25 G) to M): G) azoles selected from the group consisting of bitertanol, bromuconazole, cypro conazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquin conazole, fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, 30 ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothiocon azole, simeconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triti conazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole and hymexa zole; 35 H) strobilurins selected from the group consisting of azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, enestroburin, methyl (2-chloro-5-[1-(3 methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1-(6-methyl 40 pyridin-2-ylmethoxyimino)ethyl]benzyl)carbamate and methyl 2-(ortho-(2,5-di methylphenyloxymethylene)phenyl)-3-methoxyacrylate; 15 J) carboxamides selected from the group consisting of carboxin, boscalid, fen hexamid, flutolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, thifluzamide, tiadinil, 3,4-dichloro-N-(2-cyanophenyl)iso-thiazole-5 carboxamide, penthiopyrad, dimethomorph, flumorph, flumetover, 5 fluopicolide (picobenzamid), zoxamide, carpropamid, diclocymet, mandipropamid, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-ethoxyphenyl)ethyl)-2-methane sulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3 methoxyphenyl)ethyl)-2-ethanesulfonylamino-3-methylbutyramide, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methylbutyrylamino) 10 propionate, N-(4' -bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5 carbox-amide, N-(4' -trifluoromethylbiphenyl-2-yl)-4-difluoromethyl-2 methylthiazole-5-carboxamide, N-(4' -chloro-3' -fluorobiphenyl-2-yl)-4 d ifluoromethyl-2-methyl-thiazole-5-carboxa mide, N-(3' ,4' -dichloro-4 fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole-4-carboxamide and N-(2 15 cyanophenyl)-3,4-dichloroisothiazole-5-carboxamide; K) heterocyclic compounds selected from the group consisting of fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropi 20 morph, tridemorph, fenpropidin, iprodione, procymidone, vinclozolin, famoxadone, fenamidone, octhilinone, probenazole, 5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6 trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine, anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole, 2-butoxy-6-iodo-3-propylchromen-4-one, acibenzolar-S methyl, captafol, captan, dazomet, folpet, fenoxanil, quinoxyfen and N,N-dimethyl 25 3-(3-bromo-6-fluoro-2-methylindole-1-sulfonyl)-[1,2,4]triazole-1-sulfonamide; L) carbamates selected from the group consisting of mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram, diethofencarb, iprovalicarb, flub enthiavalicarb, propamocarb, 4-fluorophenyl N-(1-(1-(4-cyanophenyl)ethane 30 sulfonyl)but-2-yl)carbamate, methyl 3-(4-chlorophenyl)-3-(2-isopropoxycarbonyl amino-3-methylbutyrylamino)propanoate and carbamate oxime ethers of the for mula VI Cl H

H

3 00 ND:N - N. z H VI, 0 C 3 in which Z is N or CH; 35 M) other fungicides selected from the group consisting of guanidine, dodine, iminoctadine, guazatine, antibiotics: kasugamycin, streptomycin, polyoxin, validamycin A, 16 nitrophenyl derivatives: binapacryl, dinocap, dinobuton, sulfur-containing heterocyclyl compounds: dithianon, isoprothiolane, organometallic compounds: fentin salts such as fentin acetate, organophosphorus compounds: edifenphos, iprobenfos, fosetyl, 5 fosetyl-aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl, organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, hexachlor benzene, phthalide, pencycuron, quintozene, thiophanate-methyl, tolylfluanid, inorganic active compounds: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur, 10 others: cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl and spiroxamine. The active compounds V mentioned above, their preparation and their action against harmful fungi are generally known (cf., for example, 15 httI/www.hclrss.demon.co.uk/index.htrmk they are commercially available. Preference is given to three-component compositions of components 1) and 2) with an active compound V selected from the group of the azoles G). 20 Preference is also given to three-component compositions of components 1) and 2) with an active compound V selected from the group of the strobilurins H). Preference is given to three-component compositions of components 1) and 2) with an active compound V selected from the group of the carboxamides J). 25 Preference is furthermore also given to three-component compositions of components 1) and 2) with an active compound V selected from the group of the heterocyclic compounds K). 30 Preference is furthermore also given to three-component compositions of components 1) and 2) with an active compound V selected from the group of the carbamates L). Preference is furthermore also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the other fungicides M). 35 Preference is furthermore also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the azoles G) selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, penconazole, 40 propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl, carbendazim and ethaboxam.

17 Particular preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the azoles G) selected from the group consisting of cyproconazole, difenoconazole, epoxiconazole, fluquinconazole, flusilazole, flutriafol, metconazole, myclobutanil, propiconazole, 5 prothioconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl and carbendazim. Very particular preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the azoles 10 G) selected from the group consisting of epoxiconazole, fluquinconazole, flutriafol, metconazole, tebuconazole, triticonazole, prochloraz and carbendazim. Preference is also given to three-component compositions of components 1) and 2) with at least one active compound selected from the group of the strobilurins H) 15 selected from the group consisting of azoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl, orysastrobin, picoxystrobin, pyraclostrobin and trifloxystrobin. Particular preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the strobilurins H) selected 20 from the group consisting of kresoxim-methyl, orysastrobin and pyraclostrobin. Very particular preference is also given to three-component compositions of components 1) and 2) with pyraclostrobin. 25 Preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the carboxamides J) selected from the group consisting of fenhexamid, mefenoxam, ofurace, dimethomorph, flumorph, fluopicolide (picobenzamid), zoxamide, carpropamid and mandipropamid. 30 Particular preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the carboxamides J) selected from the group consisting of fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, zoxamide and carpropamid. 35 Preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the heterocyclic compounds J) selected from the group consisting of fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, proquinazid, 40 acibenzolar-S-methyl, captafol, folpet, fenoxanil and quinoxyfen, in particular fluazinam, cyprodinil, fenarimol, mepanipyrim, pyrimethanil, triforine, fludioxonil, dodemorph, 18 fenpropimorph, tridemorph, fenpropidin, iprodione, vinclozolin, famoxadone, fenamidone, probenazole, proquinazid, acibenzolar-S-methyl, captafol, folpet, fenoxanil and quinoxyfen. 5 Particular preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the heterocyclic compounds K) selected from the group consisting of pyrimethanil, dodemorph, fenpropimorph, tridemorph, iprodione, vinclozolin and quinoxyfen, in particular pyrimethanil, dodemorph, fenpropimorph, tridemorph, iprodione, vinclozolin and 10 quinoxyfen. Preference is also given to three-component compositions of components 1) and 2) with at least one active compound selected from the group of the carbamates L) selected from the group consisting of mancozeb, metiram, propineb, thiram, 15 iprovalicarb, flubenthiavalicarb and propamocarb. Particular preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the carbamates L) selected from the group consisting of mancozeb and metiram. 20 Preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the other fungicides M) selected from the group consisting of dithianon, fentin salts, such as fentin acetate, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, chlorothalonil, dichlofluanid, 25 thiophanate-methyl, copper acetate, copper hydroxide, copper oxychioride, basic copper sulfate, sulfur, cymoxanil and spiroxamine. Particular preference is also given to three-component compositions of components 1) and 2) with an active compound selected from the group of the other fungicides M) 30 selected from the group consisting of phosphorous acid and its salts and chlorothalonil. Preference is also given to four-component compositions of components 1) and 2) with two futher active compounds selected from compounds il and V mentioned above. 35 Preferred active compound combinations are listed in tables 2 to 7 below: Table 2 Active compound combinations of a component 1) and a component 2), conprising a compound 11 selected from group A): Mixture Component 1) Component 2) No. A.1 RHAPSODY* azaconazole 19 Mixture Component 1) Component 2) No. A.2 SERENADE* MAX azaconazole No. A.3 SERENADE* ASO azaconazole No. A.4 SONATA' azaconazole No. A.5 BALLAD' Plus azaconazole No. A.6 RHAPSODY 0 diniconazole-M No. A.7 SERENADE' MAX diniconazole-M No. A.8 SERENADE' ASO diniconazole-M No. A.9 SONATAS diniconazole-M No. A.10 BALLAD' Plus diniconazole-M No. A.11 RHAPSODY' oxpoconazol No. A.12 SERENADE' MAX oxpoconazol No. A.13 SERENADE' ASO oxpoconazol No. A.14 SONATA' oxpoconazol No. A. 15 BALLAD' Plus oxpoconazol No. A.16 RHAPSODY' paclobutrazol No. A.17 SERENADE' MAX paclobutrazol No. A.18 SERENADE' ASO paclobutrazol No. A.19 SONATA' paclobutrazol No. A.20 BALLAD' Plus paclobutrazol No. A.21 RHAPSODY' uniconazol No. A.22 SERENADE' MAX uniconazol No. A.23 SERENADE' ASO uniconazol No. A.24 SONATA' uniconazol No. A.25 BALLAD' Plus uniconazol No. A.26 RHAPSODY' 1-(4-chloro-phenyl)-2-([1,2,4]triazol-1 -yl) cycloheptanol No. A.27 SERENADE' MAX 1-(4-chloro-phenyl)-2-([1,2,4]triazol-1 -yl) cycloheptanol No. A.28 SERENADE' ASO 1-(4-chloro-phenyl)-2-([1,2,4]triazol-1 -yl) cycloheptanol No. A.29 SONATA' 1-(4-chloro-phenyl)-2-([1,2,4]triazol-1 -yl) cycloheptanol No. A.30 BALLAD' Plus 1-(4-chloro-phenyl)-2-([1,2,4]triazol-1 -yl) cycloheptanol No. A.31 RHAPSODY' imazalil-sulfphate No. A.32 SERENADE' MAX imazalil-sulfphate No. A.33 SERENADE' ASO imazalil-sulfphate No. A.34 SONATA' imazalil-sulfphate 20 Mixture Component 1) Component 2) No. A.35 BALLAD® Plus imazalil-sulfphate Table 3 Active compound combinations of a component 1) and a component 2), conprising a compound Il selected from group B): Mixture Component 1) Component 2) No. B.1 RHAPSODY® 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5-fluoro-pyrimidin-4 yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide No. B.2 SERENADE 6 MAX 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5-fluoro-pyrimidin-4 yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide No. B.2 SERENADE 6 ASO 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5-fluoro-pyrimidin-4 yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide No. B.1 SONATA® 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5-fluoro-pyrimidin-4 yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide No. B.2 BALLAD® Plus 2-(2-(6-(3-chloro-2-methyl-phenoxy)-5-fluoro-pyrimidin-4 yloxy)-phenyl)-2-methoxyimino-N-methyl-acetamide No. B.3 RHAPSODY® 3-methoxy-2-(2-(N-(4-methoxy-phenyl)-cyclopropanecarb oximidoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester No. B.4 SERENADE® MAX 3-methoxy-2-(2-(N-(4-methoxy-phenyl)-cyclopropanecarb oxi midoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester No. B.3 SERENADE® ASO 3-methoxy-2-(2-(N-(4-methoxy-phenyl)-cyclopropanecarb oximidoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester No. B.3 SONATA® 3-methoxy-2-(2-(N-(4-methoxy-phenyl)-cyclopropanecarb oximidoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester No. B.4 BALLAD® Plus 3-methoxy-2-(2-(N-(4-methoxy-phenyl)-cyclopropanecarb oximidoylsulfanylmethyl)-phenyl)-acrylic acid methyl ester 5 Table 4 Active compound combinations of a component 1) and a component 2), conprising a compound I selected from group C): Mixture Component 1) Component 2) No. C.1 RHAPSODY® benalaxyl-M No. C.2 SERENADE® MAX benalaxyl-M No. C.3 SERENADE® ASO benalaxyl-M No. C.4 SONATA® benalaxyl-M No. C.5 BALLAD® Plus benalaxyl-M No. C.6 RHAPSODY® 2-amino-4-methyl-thiazole-5-carboxanilide No. C.7 SERENADE® MAX 2-amino-4-methyl-thiazole-5-carboxanilide No. C.8 SERENADE® ASO 2-amino-4-methyl-thiazole-5-carboxanilide 21 Mixture Component 1) Component 2) No. C.9 SONATA* 2-amino-4-methyl-thiazole-5-carboxanilide No. C.10 BALLAD 6 Plus 2-amino-4-methyl-thiazole-5-carboxanilide No. C. 11 RHAPSODY 0 2-chloro-N-(1,1,3-trimethyl-indan-4-yi)-nicotinamide No. C.12 SERENADE 0 MAX 2-chloro-N-( 1,1,3-trimethyl-indan-4-yl)-nicotinamide No. C.13 SERENADE 6 ASO 2-chloro-N-(1,1,3-trimethyl-indan-4-yl)-nicotinamide No. C.14 SONATA 0 2-chloro-N-(1,1,3-trimethyl-indan-4-yl)-nicotinamide No. C.15 BALLAD 6 Plus 2-chloro-N-(1,1,3-trimethyl-indan-4-yl)-nicotinamide No. C.16 RHAPSODY 6 N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyi-5 fluoro-1 H-pyrazole-4-carboxamide No. 0.17 SERENADE 6 MAX N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5 fluoro-1 H-pyrazole-4-carboxamide No. C.18 SERENADE 6 ASO N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5 fluoro-1 H-pyrazole-4-carboxamide No. C.19 SONATA® N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5 fluoro-1 H-pyrazoie-4-carboxamide No. C.20 BALLAD 6 Plus N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5 fluoro-i H-pyrazole-4-carboxamide No. C.21 RHAPSODY 6 N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 difluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.22 SERENADE® MAX N-(4'-chloro-3',5-difluoro-bipheny-2-yl)-3 difluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.23 SERENADE 0 ASO N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 difluoromethy-1-methyl-1 H-pyrazole-4-carboxamide No. C.24 SONATA® N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.25 BALLAD* Plus N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 difluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.26 RHAPSODY® N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 trifluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.27 SERENADE 6 MAX N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 trifluoromethyl-1 -methyl-i H-pyrazole-4-carboxamide No. C.28 SERENADE 6 ASO N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 trifiuoromethyl-1 -methyl-i H-pyrazole-4-carboxamide No. C.29 SONATA* N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 trifluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.30 BALLAD 6 Plus N-(4'-chloro-3',5-difluoro-biphenyl-2-yl)-3 trifluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.31 RHAPSODY® N-(3',4'-dichloro-5-fluoro-biphenyl-2-yl)-3 difluoromethyl-l-methyl-1 H-pyrazole-4-carboxamide 22 Mixture Component 1) Component 2) No. C.32 SERENADE* MAX N-(3',4'-dichloro-5-fluoro-biphenyl-2-yl)-3 difluoromethyl-l-methyl-1 H-pyrazole-4-carboxamide No. C.33 SERENADE® ASO N-(3',4'-dichloro-5-fluoro-biphenyl-2-yl)-3 diftuoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.34 SONATA* N-(3',4'-dichloro-5-fluoro-biphenyl-2-yl)-3 difluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.35 BALLAD 0 Plus N-(3',4'-dichloro-5-fluoro-biphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.36 RHAPSODY 0 N-(3',5-difluoro-4'-methyl-biphenyl-2-y)-3 difluoromethyl-1 -methyl-I H-pyrazole-4-carboxamide No. C.37 SERENADE 0 MAX N-(3',5-difluoro-4'-methyl-biphenyl-2-yI)-3 difluoromethyl-1-methyl-I H-pyrazole-4-carboxamide No. C.38 SERENADE® ASO N-(3',5-difluoro-4'-methyl-biphenyl-2-yl)-3 difluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.39 SONATA® N-(3',5-difluoro-4'-methyl-biphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.40 BALLAD® Plus N-(3',5-difluoro-4'-methyl-biphenyl-2-yl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.41 RHAPSODY® N-(3',5-difluoro-4'-methyl-biphenyl-2-y)-3 trifluoromethyl-1 -methyl-i H-pyrazole-4-carboxamide No. C.42 SERENADE® MAX N-(3',5-difluoro-4'-methyl-biphenyl-2-y)-3 trifluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.43 SERENADE® ASO N-(3',5-difluoro-4'-methyl-biphenyl-2-yl)-3 trifluoromethyl-I -methyl-1 H-pyrazole-4-carboxamide No. C.44 SONATA® N-(3',5-difluoro-4'-methyl-biphenyl-2-yl)-3 trifluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.45 BALLAD® Plus N-(3',5-difluoro-4'-methyl-biphenyl-2-y)-3 trifluoromethyl-i -methyl-I H-pyrazole-4-carboxamide No. C.46 RHAPSODY® N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl- I methyl-1 H-pyrazole-4-carboxamide No. C.47 SERENADE® MAX N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide No. C.48 SERENADE® ASO N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide No. C.49 SONATA® N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difluoromethyl-1 methyl-1 H-pyrazole-4-carboxamide No. C.50 BALLAD® Plus N-(cis-2-bicyclopropyl-2-yl-phenyl)-3-difl uoromethyl-1 I methyl-1 H-pyrazole-4-carboxamide 23 Mixture Component 1) Component 2) No. C.51 RHAPSODY* N-(trans-2-bicyclopropyl-2-yl-phenyl)-3 difluoromethyl-l-methyl-1 H-pyrazole-4-carboxamide No. C.52 SERENADE® MAX N-(trans-2-bicyclopropyl-2-yl-phenyl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.53 SERENADE 0 ASO N-(trans-2-bicyclopropyl-2-yl-phenyl)-3 difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide No. C.54 SONATA* N-(trans-2-bicyclopropyl-2-yl-phenyl)-3 difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.55 BALLAD 0 Plus N-(trans-2-bicyclopropyl-2-yl-phenyl)-3 difluoromethyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.56 RHAPSODY 0 fluopyram No. C.57 SERENADE 0 MAX fluopyram No. C.58 SERENADE 0 ASO fluopyram No. C.59 SONATA 0 fluopyram No. C.60 BALLAD* Plus fluopyram No. C.61 RHAPSODY® N-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formylamino 2-hydroxy-benzamide No. C.62 SERENADE® MAX N-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formylamino 2-hydroxy-benzamide No. C.63 SERENADE® ASO N-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formylamino 2-hydroxy-benzamide No. C.64 SONATA® N-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formylamino 2-hydroxy-benzamide No. C.65 BALLAD® Plus N-(3-ethyl-3,5-5-trimethyl-cyclohexyl)-3-formylamino 2-hydroxy-benzamide No. C.66 RHAPSODY® oxytetracyclin No. C.67 SERENADE® MAX oxytetracyclin No. C.68 SERENADE® ASO oxytetracyclin No. C.69 SONATA® oxytetracyclin No. C.70 BALLAD® Plus oxytetracyclin No. C.71 RHAPSODY® silthiofam No. C.72 SERENADE® MAX silthiofam No. C.73 SERENADE® ASO silthiofam No. C.74 SONATA® silthiofam No. C.75 BALLAD* Plus silthiofam No. C.76 RHAPSODY 0 N-(6-methoxy-pyridin-3-yl) cyclopropanecarboxamide No. C.77 SERENADE® MAX N-(6-methoxy-pyridin-3-y) cyclopropanecarboxamide No. C.78 SERENADE® ASO N-(6-methoxy-pyridin-3-yl) cyclopropanecarboxamide No. C.79 SONATA® N-(6-methoxy-pyridin-3-yl) cyclopropanecarboxamide 24 Mixture Component 1) Component 2) No. C.80 BALLAD' Plus N-(6-methoxy-pyridin-3-yl) cyciopropanecarboxamide No. C.81 RHAPSODY' N-(2'-fluoro-4'-chloro-5'-methylbipheny-2-y)-1 methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.82 SERENADE' MAX N-(2'-fluoro-4'-chloro-5'-methylbiphenyl-2-yl)-1 methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.83 SERENADE® ASO N-(2'-fluoro-4'-chloro-5'-methylbiphenyl-2-yI)-i methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.84 SONATA® N-(2'-fluoro-4'-chloro-5'-methylbiphenyl-2-yl)-1 methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.85 BALLAD* Plus N-(2'-fluoro-4'-chloro-5'-methylbiphenyl-2-y)-1 methyl-3-trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.86 RHAPSODY® N-(3',4',5'-trifluorobiphenyl-2-yl)-i -methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.87 SERENADE® MAX N-(3',4',5'-trifluorobiphenyl-2-yl)-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.88 SERENADE® ASO N-(3',4',5'-trifluorobiphenyl-2-y)-1 -methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.89 SONATA® N-(3',4',5'-trifluorobiphenyl-2-y)-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.90 BALLAD® Plus N-(3',4',5'-trifluorobiphenyl-2-y)-1-methyl-3 trifluoromethyl-1 H-pyrazole-4-carboxamide No. C.91 RHAPSODY® N-(3',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.92 SERENADE® MAX N-(3',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.93 SERENADE' ASO N-(3',4',5'-trifluorobiphenyl-2-y)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.94 SONATA® N-(3',4',5'-trifluorobiphenyl-2-yl)-1-methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.95 BALLAD® Plus N-(3',4',5'-trifluorobiphenyl-2-y)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.96 RHAPSODY* N-(2',4'5'-trifluorobiphenyl-2-yl)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.97 SERENADE' MAX N-(2',4',5'-trifluorobiphenyl-2-y)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.98 SERENADE® ASO N-(2',4',5'-trifluorobiphenyl-2-y)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.99 SONATA® N-(2',4',5'-trifluorobiphenyl-2-yl)-1-methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide 25 Mixture Component 1) Component 2) No. C.100 BALLAD 0 Plus N-(2',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3 difluoromethyl-1 H-pyrazole-4-carboxamide No. C.101 RHAPSODY 0 N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl 1-methyl-1 H-pyrazole-4-carboxamide No. C.102 SERENADE* MAX N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl S1-methyl-1 H-pyrazoie-4-carboxamide No. C.103 SERENADE 0 ASO N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl 1-methyl-1 H-pyrazole-4-carboxamide No. C.104 SONATA 0 N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl 1-methyl-I H-pyrazole-4-carboxam ide No. C.105 BALLAD 0 Plus N-(3',4',5'-trifluorobiphenyl-2-yl)-3-chlorofluoromethyl 1-methyl-1 H-pyrazole-4-carboxamide No. C.106 RHAPSODY 0 N-(4'-trifluoromethylthio-biphenyl-2-yl)-3-difluoro methyl-1-methyl-1 H-pyrazole-4-carboxamide No. C.107 SERENADE® MAX N-(4'-trifluoromethylthio-biphenyl-2-yl)-3-difluoro methyl-I-methyl-1 H-pyrazole-4-carboxamide No. C.108 SERENADE ASO N-(4'-trifluoromethylthio-biphenyl-2-yl)-3-difluoro methyl-1 -methyl-1 H-pyrazole-4-carboxamide No. C.109 SONATA® N-(4'-trifluoromethylthio-biphenyl-2-yl)-3-difluoro methyl-I-methyl-1 H-pyrazole-4-carboxamide No. C.110 BALLAD® Plus N-(4'-trifluoromethylthio-biphenyl-2-yl)-3-difluoro methyl-1-methyl-i H-pyrazole-4-carboxamide No. C.111 RHAPSODY® N-(4'-trifluoromethylthio-biphenyl-2-y)-1 -methyl 3-trfluoromethyl-I H-pyrazole-4-carboxamide No. C.112 SERENADE® MAX N-(4'-trifluoromethylthio-biphenyl-2-yl)-1 -methyl 3-trfluoromethyl-1 H-pyrazole-4-carboxamide No. C.113 SERENADE® ASO N-(4'-trifluoromethylthio-biphenyl-2-yl)-1 -methyl 3-trfluoromethyl-1 H-pyrazole-4-carboxamide No. C.114 SONATA® N-(4'-trifluoromethylthio-biphenyl-2-yl)-1 -methyl 3-trfluoromethyl-1 H-pyrazole-4-carboxamide No. C.115 BALLAD® Plus N-(4'-trifluoromethylthio-biphenyl-2-yl)-1 -methyl 3-trfluoromethyl-1 H-pyrazole-4-carboxamide No. C.116 RHAPSODY® isopyrazam No. C.117 SERENADE® MAX isopyrazam No. C.118 SERENADE® ASO isopyrazam No. C.119 SONATA isopyrazam No. C.120 BALLAD® Plus isopyrazam 26 Table 5 Active compound combinations of a component 1) and a component 2), conprising a compound il selected from group D): Mixture Component 1) Component 2) No. D.1 RHAPSODY 0 2,3,5,6-tetrachloro-4-methanesulfonyl-pyridine No. D.2 SERENADE 0 MAX 2,3,5,6-tetrachloro-4-methanesulfonyl-pyridine No. D.3 SERENADE 0 ASO 2,3,5,6-tetrachloro-4-methanesulfonyl-pyridine No. D.4 SONATA 0 2,3,5,6-tetrachloro-4-methanesulfonyl-pyridine No. D.5 BALLAD 0 Plus 2,3,5,6-tetrachloro-4-methanesulfonyl-pyridine No. D.6 RHAPSODY 0 3,4,5-trichloro-pyridine-2,6-di-carbonitrile No. D.7 SERENADE 0 MAX 3,4,5-trichloro-pyridine-2,6-di-carbonitrile No. D.8 SERENADE 0 ASO 3,4,5-trichloro-pyridine-2,6-d i-carbonitrile No. D.9 SONATA 0 3,4,5-trichloro-pyridine-2,6-di-carbonitrile No. D.10 BALLAD 0 Plus 3,4,5-trichloro-pyridine-2,6-di-carbonitrile No. D.11 RHAPSODY* N-(1 -(5-bromo-3-chloro-pyridin-2-yl)-ethyl)-2,4 dichloro-nicotinamide No. D.12 SERENADE 0 MAX N-(1-(5-bromo-3-chloro-pyridin-2-yI)-ethyl)-2,4 dichloro-nicotinamide No. D.13 SERENADE 0 ASO N-(1 -(5-bromo-3-chloro-pyridin-2-yl)-ethyl)-2,4 dichloro-nicotinamide No. D.14 SONATA 0 N-(1 -(5-bromo-3-chloro-pyridin-2-yI)-ethyl)-2,4 dichloro-nicotinamide No. D.15 BALLAD 0 Plus N-(1 -(5-bromo-3-chloro-pyridin-2-yl)-ethyl)-2,4 dichloro-nicotinamide No. D.16 RHAPSODY 0 N-((5-bromo-3-chloro-pyridin-2-yI)-methyl)-2,4 dichloro-nicotinamide No. D.17 SERENADE 0 MAX N-((5-bromo-3-chloro-pyridin-2-yl)-methyl)-2,4 dichloro-nicotinamide No. D.18 SERENADE 0 ASO N-((5-bromo-3-chloro-pyridin-2-yl)-methyl)-2,4 dichloro-nicotinamide No. D.19 SONATA* N-((5-bromo-3-chloro-pyridin-2-yI)-methyl)-2,4 dichioro-nicotinamide No. D.20 BALLAD 0 Plus N-((5-bromo-3-chloro-pyrid in-2-yl)-methyl)-2,4 dichloro-nicotinamide No. D.21 RHAPSODY 0 diflumetorim No. D.22 SERENADE 0 MAX diflumetorim No. D.23 SERENADE 0 ASO diflumetorim No. D.24 SONATA 0 diflumetorim No. D.25 BALLAD 0 Plus diflumetorim No. 0.26 RHAPSODY 0 nitrapyrin 27 Mixture Component 1) Component 2) No. D.27 SERENADE 0 MAX nitrapyrin No. D.28 SERENADE ASO nitrapyrin No. D.29 SONATA 0 nitrapyrin No. D.30 BALLAD Plus nitrapyrin No. D.31 RHAPSODY* dodemorph-acetate No. D.32 SERENADE 0 MAX dodemorph-acetate No. D.33 SERENADE 0 ASO dodemorph-acetate No. D.34 SONATA 0 dodemorph-acetate No. D.35 BALLAD 0 Plus dodemorph-acetate No. D.36 RHAPSODY 0 fluoroimid No. D.37 SERENADE 0 MAX fluoroimid No. D.38 SERENADE 0 ASO fluoroimid No. D.39 SONATA 0 fluoroimid No. D.40 BALLAD 0 Plus fluoroimid No. D.41 RHAPSODY 0 blasticidin-S No. D.42 SERENADE 0 MAX blasticidin-S No. D.43 SERENADE 0 ASO blasticidin-S No. D.44 SONATA 0 blasticidin-S No. D.45 BALLAD 0 Plus blasticidin-S No. D.46 RHAPSODY 0 chinomethionat No. D.47 SERENADE 6 MAX chinomethionat No. D.48 SERENADE 0 ASO chinomethionat No. D.49 SONATA 0 chinomethionat No. D.50 BALLAD Plus chinomethionat No. D.51 RHAPSODY 0 debacarb No. D.52 SERENADE 0 MAX debacarb No. D.53 SERENADE 0 ASO debacarb No. D.54 SONATA 0 debacarb No. D.55 BALLAD Plus debacarb No. D.56 RHAPSODY 0 difenzoquat No. D.57 SERENADE 0 MAX difenzoquat No. D.58 SERENADE 0 ASO difenzoquat No. D.59 SONATA 0 difenzoquat No. D.60 BALLAD Plus difenzoquat No. D.61 RHAPSODY 0 difenzoquat-methylsulphat No. D.62 SERENADE 0 MAX difenzoquat-methylsulphat No. D.63 SERENADE 0 ASO difenzoquat-methylsulphat No. D.64 SONATA 0 difenzoquat-methylsulphat 28 Mixture Component 1) Component 2) No. D.65 BALLAD Plus difenzoquat-methylsulphat No. D.66 RHAPSODY 6 oxolinic acid No. D.67 SERENADE 6 MAX oxolinic acid No. D.68 SERENADE* 0 ASO oxolinic acid No. D.69 SONATA* oxolinic acid No. D.70 BALLAD* Plus oxolinic acid No. D.71 RHAPSODY* piperalin No. D.72 SERENADE 0 MAX piperalin No. D.73 SERENADE 0 ASO piperalin No. D.74 SONATA 0 piperalin No. D.75 BALLADO Plus piperalin No. D.76 RHAPSODY. 5-chloro-7-(4-methylpiperidin-1 -yl)-6-(2,4,6-trifluoro phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine No. D.77 SERENADE 0 MAX 5-chloro-7-(4-methylpiperid in-1 -yl)-6-(2,4,6-trifluoro phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine No. D.78 SERENADE 0 ASO 5-chloro-7-(4-methylpiperidin-1 -yl)-6-(2,4,6-trifluoro I phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine No. D.79 SONATA* 5-chloro-7-(4-methylpiperid in-1 -yl)-6-(2,4,6-trifluoro phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine No. D.80 BALLAD* Plus 5-chloro-7-(4-methylpiperidin-1-yI)-6-(2,4,6-trifluoro phenyl)-[1,2,4]triazolo[1,5-a]pyrimidine No. D.81 RHAPSODY 6 6-(3,4-dichlorophenyl)-5-methyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.82 SERENADE 0 MAX 6-(3,4-dichlorophenyl)-5-methyl-[1,2,4]triazolo[1,5 alpyrimidin-7-ylamine No. D.83 SERENADE 0 ASO 6-(3,4-dichlorophenyl)-5-methyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.84 SONATA® 6-(3,4-dichlorophenyl)-5-methyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.85 BALLAD® Plus 6-(3,4-dichlorophenyl)-5-methyi-[1,2,41triazolo[1,5 a]pyrimidin-7-ylamine No. D.86 RHAPSODY® 6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.87 SERENADE 6 MAX 6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.88 SERENADE 6 ASO 6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.89 SONATA® 6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5 I a]pyrimidin-7-ylamine 29 Mixture Component 1) Component 2) No. D.90 BALLAD 0 Pius 6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5 ajpyrimidin-7-ylamine No. D.91 RHAPSODY* 5-methyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 I _ _ a]pyri midin-7-ylamine No. D.92 SERENADES MAX 5-methyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. 0.93 SERENADE 0 ASO 5-nethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 I a]pyrimidin-7-ylamine No. D.94 SONATA 0 5-methyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 alpyrimidin-7-ylamine No. D.95 BALLAD* Plus 5-methyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.96 RHAPSODY 0 5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.97 SERENADE 0 MAX 5-methyl-6-octyl-[1,2,4]triazolo[1,5-ajpyrimidin-7 ylamine No. D.98 SERENADE 0 ASO 5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.99 SONATA* 5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. 0.100 BALLAD® Plus 5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.101 RHAPSODY® 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-2,7 diamine No. D.102 SERENADE 0 MAX 5-ethyl-6-octyl-[1,2,4]triazolo[1, 5-alpyrimidin-2,7 diamine No. D.103 SERENADE® ASO 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-2,7 diamine No. D.104 SONATA' 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-ajpyrimidin-2,7 diamine No. D.105 BALLAD® Plus 5-ethyl-6-octyl-[1,2,4]triazolo[1 ,5-a]pyrimidin-2,7 diamine No. D.106 RHAPSODY® 6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl amine No. D.107 SERENADE® MAX 6-ethyl-5-octyl-[1, 2,4]triazolo[ 1, 5-a]pyrimid in-7-yl amine No. D.108 SERENADE' ASO 6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-y amine 30 Mixture Component 1) Component 2) No. D.109 SONATA 6 6-ethyl-5-octyl-[1,2,4]triazolo[1,5-ajpyrimidin-7-yl amine No. D.110 BALLAD* Plus 6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl amine No. D.111 RHAPSODY 6 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-ajpyrimidin-7 ylamine No. D.112 SERENADE 6 MAX 5-ethyl-6-octyi-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.113 SERENADE 6 ASO 5-ethyl-6-octyl-{1,2,4]triazolo[1,5-ajpyrimidin-7 ylamine No. D.114 SONATA 6 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.115 BALLAD* Plus 5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.116 RHAPSODY 6 5-ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.117 SERENADE 6 MAX 5-ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.118 SERENADE 6 ASO 5-ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.119 SONATA® 5-ethyl-6-(3,5,5-trimethylhexy)-[1,2,4]triazolo[1,5 ajpyrimidin-7-ylamine No. D.120 BALLAD® Plus 5-ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5 I a]pyrimidin-7-ylamine No. D.121 RHAPSODY® 6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.122 SERENADE® MAX 6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.123 SERENADE 6 ASO 6-octyl-5-propyl-[1,2,4]triazolo[l,5-ajpyrimidin-7 ylamine No. D.124 SONATA® 6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.125 BALLAD® Plus 6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]pyrimidin-7 ylamine No. D.126 RHAPSODY® 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.127 SERENADE® MAX 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5 I_ , a]pyri mid in-7-ylamine 31 Mixture Component 1) Component 2) No. D.128 SERENADES ASO 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5 alpyrimid in-7-ylamine No. D.129 SONATA® 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.130 BALLAD Plus 5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.131 RHAPSODY* 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.132 SERENADE® MAX 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5 ajpyrimidin-7-ylamine No. D.133 SERENADE* ASO 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.134 SONATA 0 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5 a]pyri midin-7-ylamine No. D.135 BALLAD® Pius 6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5 a]pyrimidin-7-ylamine No. D.136 RHAPSODY® 5-trifluoromethyl-6-(3,5,5-trimethylhexyl) [1,2,4]triazolo[1,5-a]pyrimid in-7-ylamine No. D.137 SERENADE® MAX 5-trifluoromethyl-6-(3,5,5-trimethylhexyl) [1,2,4]triazolo[1,5-ajpyrimidin-7-ylamine No. D.138 SERENADE® ASO 5-trifluoromethyl-6-(3,5,5-trimethylhexyl) [1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine No. D.139 SONATA® 5-trifluoromethyl-6-(3,5,5-trimethylhexyl) [1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine No. D.140 BALLADS Plus 5-trifluoromethyl-6-(3,5,5-trimethylhexyl) [1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine Table 6 Active compound combinations of a component 1) and a component 2), conprising a compound I selected from group E): Mixture Component 1) Component 2) No. E.1 RHAPSODY® methasulphocarb No. E.2 SERENADE* MAX methasulphocarb No. E.3 SERENADE® ASO methasulphocarb No. E.4 SONATA® methasulphocarb No. E.5 BALLAD® Plus methasulphocarb No. E.6 RHAPSODY® propamocarb hydrochloride No. E.7 SERENADE® MAX propamocarb hydrochloride No. E.8 SERENADE® ASO propamocarb hydrochloride 32 Mixture Component 1) Component 2) No. E.9 SONATA* propamocarb hydrochloride No. E.10 BALLAD Plus propamocarb hydrochloride Table 7 Active compound combinations of a component 1) and a component 2), conprising a compound 1i selected from group F): Mixture Component 1) Component 2) No. F.1 RHAPSODY 0 metrafenone No. F.2 SERENADE 6 MAX metrafenone No. F.3 SERENADE* ASO metrafenone No. F.4 SONATA* metrafenone No. F.5 BALLADS Plus metrafenone No. F.6 RHAPSODY* dodine free base No. F.7 SERENADE* MAX dodine free base No. F.8 SERENADE ASO dodine free base No. F.9 SONATA* dodine free base No. F.10 BALLAD" Plus dodine free base No. F.1 1 RHAPSODY 0 guazatine-acetate No. F.12 SERENADE 6 MAX guazatine-acetate No. F.13 SERENADE 6 ASO guazatine-acetate No. F.14 SONATA 6 guazatine-acetate No. F.15 BALLAD* Plus guazatine-acetate No. F.16 RHAPSODY 6 iminoctadine-triacetate No. F.17 SERENADE 6 MAX iminoctadine-triacetate No. F.18 SERENADE 6 ASO iminoctadine-triacetate No. F.19 SONATA 6 iminoctadine-triacetate No. F.20 BALLAD' Plus iminoctadine-triacetate No. F.21 RHAPSODY 6 iminoctadine-tris(albesilate) No. F.22 SERENADE 6 MAX iminoctadine-tris(albesilate) No. F.23 SERENADE 6 ASO imi noctadine-tris(albesilate) No. F.24 SONATA 6 imi noctadine-tris(albesilate) No. F.25 BALLAD 6 Plus iminoctadine-tris(albesilate) No. F.26 RHAPSODY 6 kasugamycin-hydrochlorid-hydrat No. F.27 SERENADE 6 MAX kasugamycin-hydrochlorid-hydrat No. F.28 SERENADEO ASO kasugamycin-hydrochlorid-hydrat No. F.29 SONATA 6 kasugamycin-hydrochiorid-hydrat No. F.30 BALLAD Plus kasugamycin-hydrochlorid-hydrat No. F.31 RHAPSODY" dichlorophen 33 Mixture Component 1) Component 2) No. F.32 SERENADE* MAX dichlorophen No. F.33 SERENADE* ASO dichlorophen No. F.34 SONATA* dichlorophen No. F.35 BALLAD® Plus dichlorophen No. F.36 RHAPSODY* pentachlorophenol No. F.37 SERENADE 0 MAX pentachlorophenol No. F.38 SERENADE 0 ASO pentachlorophenol No. F.39 SONATA 0 pentachlorophenol No. F.40 BALLAD* Plus pentachlorophenol No. F.41 RHAPSODY® N-(4-chloro-2-nitro-phenyl)-N-ethyl-4-methyl benzenesulfonamide No. F.42 SERENADE® MAX N-(4-chloro-2-nitro-phenyl)-N-ethyl-4-methyl benzenesulfonamide No. F.43 SERENADE® ASO N-(4-chloro-2-nitro-phenyl)-N-ethyl-4-methyl benzenesulfonamide No. F.44 SONATA® N-(4-chloro-2-nitro-phenyl)-N-ethyl-4-methyi benzenesulfonamide No. F.45 BALLAD® Plus N-(4-chloro-2-nitro-phenyl)-N-ethyl-4-methyl benzenesulfonamide No. F.46 RHAPSODY* dicloran No. F.47 SERENADE® MAX dicloran No. F.48 SERENADE 0 ASO dicloran No. F.49 SONATA® dicloran No. F.50 BALLAD® Plus dicloran No. F.51 RHAPSODY® nitrothal-isopropyl No. F.52 SERENADE® MAX nitrothal-isopropyl No. F.53 SERENADE® ASO nitrothal-isopropyl No. F.54 SONATA* nitrothal-isopropyl No. F.55 BALLAD® Plus nitrothal-isopropyl No. F.56 RHAPSODY® tecnazen No. F.57 SERENADE® MAX tecnazen No. F.58 SERENADE® ASO tecnazen No. F.59 SONATA® tecnazen No. F.60 BALLAD® Plus tecnazen No. F.61 RHAPSODY® biphenyl No. F.62 SERENADE® MAX biphenyl No. F.63 SERENADE® ASO biphenyl No. F.64 SONATA® biphenyl 34 Mixture Component 1) Component 2) No. F.65 BALLAD' Plus biphenyl No. F.66 RHAPSODY* bronopol No. F.67 SERENADE 0 MAX bronopol No. F.68 SERENADE' ASO bronopol No. F.69 SONATA* bronopol No. F.70 BALLAD' Plus bronopol No. F.71 RHAPSODY 0 diphenylamine No. F.72 SERENADE* MAX diphenylamine No. F.73 SERENADE' ASO diphenylamine No. F.74 SONATA* diphenylamine No. F.75 BALLADS Plus diphenylamine No. F.76 RHAPSODY® mildiomycin No. F.77 SERENADE* MAX mildiomycin No. F.78 SERENADE* ASO mildiomycin No. F.79 SONATA 0 mildiomycin No. F.80 BALLAD' Plus mildiomycin No. F.81 RHAPSODY* oxin-copper No. F.82 SERENADE' MAX oxin-copper No. F.83 SERENADE® ASO oxin-copper No. F.84 SONATA' oxin-copper No. F.85 BALLAD® Plus oxin-copper No. F.86 RHAPSODY' prohexadione calcium No. F.87 SERENADE' MAX prohexadione calcium No. F.88 SERENADE' ASO prohexadione calcium No. F.89 SONATA 0 prohexadione calcium No. F.90 BALLAD' Plus prohexadione calcium No. F.91 RHAPSODY' N-(cyclopropylmethoxyimino-(6-difluoromethoxy 2,3-difluoro-phenyl)-methyl)-2-pheny acetamide No. F.92 SERENADE® MAX N-(cyclopropylmethoxyimino-(6-difluoromethoxy 2,3-difluoro-phenyl)-methyl)-2-phenyl acetamide No. F.93 SERENADE® ASO N-(cyclopropylmethoxyimino-(6-difluoromethoxy 2,3-difluoro-phenyl)-methyl)-2-pheny acetamide No. F.94 SONATA* N-(cyclopropylmethoxyimino-(6-difluoromethoxy 2,3-difluoro-phenyl)-methyl)-2-phenyl acetamide No. F.95 BALLAD' Plus N-(cyclopropylmethoxyimino-(6-difluoromethoxy 2,3-difluoro-phenyl)-methyl)-2-phenyl acetamide No. F.96 RHAPSODY* N'-(4-(4-chloro-3-trifluoromethyl-phenoxy)-2,5 d imethyl-phenyl)-N-ethyl-N-methyl formamidine 35 Mixture Component 1) Component 2) No. F.97 SERENADE 0 MAX N'-(4-(4-chloro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methy formamidine No. F.98 SERENADE ASO N'-(4-(4-chloro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.99 SONATA 0 N'-(4-(4-chloro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.100 BALLAD Plus N'-(4-(4-chloro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.101 RHAPSODY* N'-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.102 SERENADE 0 MAX N'-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.103 SERENADE® ASO N'-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.104 SONATA® N'-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.105 BALLAD® Plus N'-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5 dimethyl-phenyl)-N-ethyl-N-methyl formamidine No. F.106 RHAPSODY* N'-(2-methyl-5-trifluormethy-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F.107 SERENADE® MAX N'-(2-methyl-5-trifluormethyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethy-N-methyl formamidine No. F.108 SERENADE ASO N'-(2-methyl-5-trifluormethyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F.109 SONATA® N'-(2-methyl-5-trifluormethyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F.1 10 BALLAD* Plus N'-(2-methyl-5-trifluormethyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F 111 RHAPSODY® N'-(5-d ifluormethyl-2-methyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F.112 SERENADE® MAX N'-(5-difluormethyl-2-methyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F. 113 SERENADE 0 ASO N'-(5-difluormethyl-2-methyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F.114 SONATA® N'-(5-difluormethyl-2-methyl-4-(3-trimethylsilanyl propoxy)-phenyl)-N-ethyl-N-methyl formamidine No. F.115 BALLAD® Plus N'-(5-difluormethyl-2-methyl-4-(3-trimethylsilanyl propoxy)-pheny)-N-ethyl-N-methyl formamidine 36 The compositions comprising the components 1) and 2), or the simultaneous, that is joint or separate, use of a component 1) and a component 2), are distinguished by ex cellent activity against a broad spectrum of phytopathogenic fungi in particular from the classes of the Ascomycetes, Basidiomycetes, Deuteromycetes and Peronosporomy 5 cetes (syn. Oomycetes). Some of them are systemically active and can be used in crop protection as foliar fungicides, as soil fungicides and as fungicides for seed dressing. The compositions according to the invention are particularly important in the control of a multitude of phytopathogenic fungi on various cultivated plants, such as cereals, for 10 example wheat, rye, barley, triticale, oats or rice; beet, for example sugar beet or fod der beet; fruits, such as pomes, stone fruits or soft fruits, for example apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or goose berries; leguminous plants, such as lentils, peas, alfalfa or soybeans; oil plants, such as rape, mustard, olives, sunflowers, coconut, cocoa beans, castor oil plants, oil palms, 15 ground nuts or soybeans; cucurbits, such as squashes, cucumber or melons; fiber plants, such as cotton, flax, hemp or jute; citrus fruit, such as oranges, lemons, grapefruits or mandarins; vegetables, such as spinach, lettuce, asparagus, cabbages, carrots, onions, tomatoes, potatoes, cucurbits or paprika; laura ceous plants, such as avocados, cinnamon or camphor; energy and raw material 20 plants, such as corn, soybean, rape, sugar cane or oil palm; corn; tobacco; nuts; cof fee; tea; bananas; vines (table grapes and grape juice grape vines); hop; turf; natural rubber plants or ornamental and forestry plants, such as flowers, shrubs, broad-leaved trees or evergreens, for example conifers; and on the plant propagation material, such as seeds, and the crop material of these plants. 25 Preferably, compounds I and compositions thereof are used for controlling a multitude of fungi on field crops, such as potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rape, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes. 30 The term "plant propagation material" is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e. g. potatoes), which can be used for the multiplication of the plant. This in cludes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of 35 plants. Seedlings and young plants, which are to be transplanted after germination or after emergence from soil, may also be mentioned. These young plants may also be protected before transplantation by a total or partial treatment by immersion or pouring. Preferably, treatment of plant propagation materials with compounds I and composi 40 tions thereof is used for controlling a multitude of fungi on cereals, such as wheat, rye, barley and oats; rice, corn, cotton and soybeans.

37 The term "cultivated plants" is to be understood as including plants which have been modified by breeding, mutagenesis or genetic engineering. Genetically modified plants are plants, which genetic material has been so modified by the use of recombinant DNA techniques that under natural circumstances cannot readily be obtained by cross 5 breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant. The term "cultivated plants" is to be understood also including plants that have been 10 rendered tolerant to applications of specific classes of herbicides, such as hydroxy phenylpyruvate dioxygenase (HPPD) inhibitors; acetolactate synthase (ALS) inhibitors, such as sulfonyl ureas (see e. g. US 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98/02526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073) or imidazolinones (see 15 e. g. US 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98/02526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073); enolpyruvylshikimate-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate (see e. g. WO 92/00377); glutamine synthetase (GS) inhibitors, such as glufosinate (see e. g. EP-A-0242236, EP-A-242246) or oxynil herbi 20 cides (see e. g. US 5,559,024) as a result of conventional methods of breeding or ge netic engineering. Several cultivated plants have been rendered tolerant to herbicides by conventional methods of breeding (mutagenesis), for example Clearfield* summer rape (Canola) being tolerant to imidazolinones, e. g. imazamox. Genetic engineering methods have been used to render cultivated plants, such as soybean, cotton, corn, 25 beets and rape, tolerant to herbicides, such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady* (glyphosate) and LibertyLink* (glufosinate). The term "cultivated plants" is to be understood also including plants that are by the 30 use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as 6 -endotoxins, e. g. CryiA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylilIA, CrylllB(bl) or Cry9c; vegetative insecticidal proteins (VIP), e. g. VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nematodes, for 35 example Photorhabdus spp. or Xenorhabdus spp.; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; toxins produced by fungi, such Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine prote ase inhibitors, patatin, cystatin or papain inhibitors; ribosome-inactivating proteins 40 (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase, 38 cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase; ion channel block ers, such as blockers of sodium or calcium channels; juvenile hormone esterase; diu retic hormone receptors (helicokinin receptors); stilben synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention these insecticidal pro 5 teins or toxins are to be understood expressly also as pre-toxins, hybrid proteins, trun cated or otherwise modified proteins. Hybrid proteins are characterized by a new com bination of protein domains, (see, for example WO 02/015701). Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are dis closed, for example, in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, 10 EP-A 451 878, WO 03/018810 und WO 03/052073. The methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. These insecticidal pro teins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of athropods, especially 15 to beetles (Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nematoda). Genetically modified plants capable to synthesize one or more insecticidal proteins are, for example, described in the publications mentioned above, and some of which are 20 commercially available such as YieldGard* (corn cultivars producing the CrylAb toxin), YieldGard t Plus (corn cultivars producing CrylAb and Cry3Bb1 toxins), Starlink* (corn cultivars producing the Cry9c toxin), Herculex* RW (corn cultivars producing Cry34Abl, Cry35Ab1 and the enzyme Phosphinothricin-N-Acetyltransferase [PAT]); NuCOTN* 336 (cotton cultivars producing the CrylAc toxin), Bollgard* I (cotton culti 25 vars producing the CrylAc toxin), BollgardO 1i (cotton cultivars producing CrylAc and Cry2Ab2 toxins); VIPCOT* (cotton cultivars producing a VIP-toxin); NewLeafo (potato cultivars producing the Cry3A toxin); Bt-Xtra*, NatureGard®, KnockOut*, BiteGard*, Protecta*, Bt1 1 (e. g. Agrisure* CB) and Bt176 from Syngenta Seeds SAS, France, (corn cultivars producing the CrylAb toxin and PAT enyzme), MIR604 from Syngenta 30 Seeds SAS, France (corn cultivars producing a modified version of the Cry3A toxin, c.f. WO 03/018810), MON 863 from Monsanto Europe S.A., Belgium (corn cultivars produ cing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the CrylAc toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cryl F toxin and PAT enzyme). 35 The term "cultivated plants" is to be understood also including plants that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to in crease the resistance or tolerance of those plants to bacterial, viral or fungal patho gens. Examples of such proteins are the so-called " pathogenesis-related proteins" 40 (PR proteins, see, for example EP-A 0 392 225), plant disease resistance genes (for example potato cultivars, which express resistance genes acting against Phytophthora 39 infestans derived from the mexican wild potato Solanum bulbocastanum) or T4-lyso zym (e. g. potato cultivars capable of synthesizing these proteins with increased resis tance against bacteria such as Erwinia amylvora). The methods for producing such genetically modified plants are generally known to the person skilled in the art and are 5 described, for example, in the publications mentioned above. The term "cultivated plants" is to be understood also including plants that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e. g. bio mass production, grain yield, starch content, oil con 10 tent or protein content), tolerance to drought, salinity or other growth-limiting environ mental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants. The term "cultivated plants" is to be understood also including plants that contain by 15 the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve human or animal nutrition, for ex ample oil crops that produce health-promoting long-chain omega-3 fatty acids or un saturated omega-9 fatty acids (e. g. Nexera* rape). 20 The term "cultivated plants" is to be understood also including plants that contain by the use of recombinant DNA techniques a modified amount of substances of content or new substances of content, specifically to improve raw material production, for example potatoes that produce increased amounts of amylopectin (e. g. Amflora* potato). 25 The term "protein" as used herein is to be understood as an oligopeptide or polypeptide or molecule made up of polypeptides including expressly also pre-proteins, hybrid pro teins, peptides, truncated or otherwise modified proteins including those derived from post-transcriptional modifications such as acylation (e.g. acetylation, the addition of an acetyl group, usually at the N-terminus of the protein), alkylation, the addition of an 30 alkyl group (e.g. addition of ethyl or methyl, usually at lysine or arginine residues) or demethylation, amidation at C-terminus, biotinylation (acylation of conserved lysine residues with a biotin appendage), formylation, y -carboxylation dependent on Vitamin K, glutamylation (covalent linkage of glutamic acid residues), glycosylation (addition of a glycosyl group to either asparagine, hydroxylysine, serine, or threonine, resulting in a 35 glycoprotein), glycation (nonenzymatic attachment of sugars), glycylation (covalent linkage of one to more glycine residues), covalent attachment of a heme moiety, hydro xylation, iodination, isoprenylation (addition of an isoprenoid group such as farnesol and geranylgeraniol), lipoylation (attachment of a lipoate functionality) including prenyl ation, GPI anchor formation (e. g. myristoylation, farnesylation and geranylgeranyl 40 ation), covalent attachment of nucleotides or derivatives thereof including ADP-ribosyl ation and flavin attachment, oxidation, pegylation, covalent attachment of phosphatidyl- 40 inositol, phosphopantetheinylation (addition of a 4'-phosphopantetheinyl moiety from coenzyme A), phosphorylation (addition of a phosphate group, usually to serine, tyro sine, threonine or histidine), pyroglutamate formation, racemization of proline, tRNA mediated addition of amino acids such as arginylation, sulfation (addition of a sulfate 5 group to a tyrosine), selenoylation (co-translational incorporation of selenium in selenoproteins), ISGylation (covalent linkage to the ISG15 protein [Interferon stimulated Gene 15]), SUMOylation (covalent linkage to the SUMO protein [Small Ubiquitin-related MOdifier]), ubiquitination (covalent linkage to the protein ubiquitin or poly-ubiquitin), citrullination or deimination (conversion of arginine to citrulline), 10 deamidation (conversion of glutamine to glutamic acid or asparagine to aspartic acid), formation of disulfide bridges (covalent linkage of two cysteine amino acids) or proteolytic cleavage (cleavage of a protein at a peptide bond). The plants or seed treated with the combinations comprising components 1) and 2) 15 may by wildlife types, plants or seed obtained by breeding and transgenic plants as well as their seed. They are especially suitable for controlling the following phytopathogenic fungi: Alternaria atrans tenuissima Diaporthe phaseolorum var. caulivora Alternaria brassicae Drechslera glycini Alternaria spp. Epicoccum spp. Ascochyta tritici Erwinia amylovora Blumeria graminis Erysiphe graminis Botrytis cinerea Frogeye sojina Bremia lactucae Fusarium solani Bremia lucinae Fusarium culmorum Calonectria crotalariae Fusarium graminearum Cercospora canescens Gaeumannomyces graminis Cercospora kikuchii Leptosphaeria nodorum Cercospora sojina Leptosphaerulina trifolii Cercospora canescens Macrophomina phaseolina Choanephora infundibulifera Microdochium nivale Cladosporium herbarum Microsphaera diffusa Cochliobolus sativus Mycoleptodiscus terrestris Cochliobolus sativus Neocosmospora vasinfecta Colletotrichum truncatum Pellicularia sasakii Corynespora cassiicola Peronospora brassicae Dactuliophora glycines Peronospora manshurica Dematophora necatrix Peronospora brassicae Diaporthe phaseolorum Peronospora pisi 41 Phakopsora pachyrhizi Pyrenophora convohuli Phakopsora meibomiae Pyrenophora coppeyana Phialophora gregata Pyrenophora cytisi Phomopsis phaseoli Pyrenophora dactylidis Phyllostica sojaecola Pyrenophora dictyoides Physiological leaf spots Pyrenophora echinopis Phythium ultimum Pyrenophora ephemera Phytophthora megasperma Pyrenophora eryngicola Phytophthora infestans Pyrenophora erythrospila Phytopthora megasperma Pyrenophora euphorbiae Plasmopara viticola Pyrenophora freticola Podosphaera leucotricha Pyrenophora graminea Podosphaera leucotricha Pyrenophora graminea Pseudocercospora herpotrichoides Pyrenophora heraclei Pseudomonas lachrymans Pyrenophora hordes Pseudomonas syringae Pyrenophora horrida Pseudoperonospora cubensis Pyrenophora hyperici Pseudoperonospora humuli Pyrenophora japonica Puccinia hordes Pyrenophora kugitangi Puccinia recondita Pyrenophora lithophila Puccinia striiformis Pyrenophora Iolii Puccinia triticina Pyrenophora macrospora Pyrenochaeta glycines Pyrenophora metasequoiae Pyrenophora allosuri Pyrenophora minuertiae hirsutae Pyrenophora altermarina Pyrenophora moravica Pyrenophora avenae Pyrenophora moroczkowskii Pyrenophora bartramiae Pyrenophora muscorum Pyrenophora bondarzevii Pyrenophora osmanthi Pyrenophora bromi Pyrenophora phlei Pyrenophora bryophila Pyrenophora pimpinellae Pyrenophora buddleiae Pyrenophora pittospori Pyrenophora bupleuri Pyrenophora polytricha Pyrenophora calvertii Pyrenophora pontresinerisis Pyrenophora calvescens var. moravica Pyrenophora pulsatillae Pyrenophora carthanie Pyrenophora raetica Pyrenophora centranthi Pyrenophora rayssiae Pyrenophora cerastii Pyrenophora rugosa Pyrenophora chengii Pyrenophora ryohicola Pyrenophora chrysamthemi Pyrenophora saviczii 42 Pyrenophora schoeteri Rhizoctonia anomala Pyrenophora scholevskii Rhizoctonia apocynacearum Pyrenophora scirpi Rhizoctonia arachnion Pyrenophora scirpicola Rhizoctonia asclerotica Pyrenophora secalis Rhizoctonia batalicola Pyrenophora semeniperda Rhizoctonia borealis Pyrenophora semiusta Rhizoctonia callae Pyrenophora seseli Rhizoctonia carorae Pyrenophora seseli f. poterii Rhizoctonia cerealis Pyrenophora subalpina Rhizoctonia choussii Pyrenophora sudetica Rhizoctonia coniothecioides Pyrenophora suhantarctica Rhizoctonia cundida Pyrenophora syntrichiae Rhizoctonia dichoroma Pyrenophora szaferiana Rhizoctonia dimorpha Pyrenophora teres Rhizoctonia endophytica Pyrenophora teres f. makulata Rhizoctonia endophytica vor. filicata Pyrenophora teres subsp. graminea Rhizoctonia ferruginea Pyrenophora tetrahenae Rhizoctonia floccosa Pyrenophora tranzschelii Rhizoctonia fragariae Pyrenophora trifulii Rhizoctonia fraxini Pyrenophora triticil-repentis Rhizoctonia fuliginea Pyrenophora ushuwalensis Rhizoctonia fumigata Pyrenophora villose Rhizoctonia globularis Pyrenophora graminea Rhizoctonia goodyerae-repentis Pyrenophora teres Rhizoctonia gossypii Pyrenophora teres Rhizoctonia gossypii vor. anatolica Pyrenophora teres Rhizoctonia gracilis Pyrenophora tritici repentis Rhizoctonia griseo Pyricularia oryzae Rhizoctonia hiemalis Pythium aphanidermatum Rhizoctonia juniperi Pythium debaryanum Rhizoctonia lamallifera Pythium irregulare Rhizoctonia leguminicola Pythium myriotylum Rhizoctonia lilacina Pythium ultimum Rhizoctonia luoini Ramularia collocygni Rhizoctonia macrosclerotia Rhizoctonia aerea Rhizoctonia melongenae Rhizoctonia alba Rhizoctonia microsclerotia Rhizoctonia alpina Rhizoctonia monilioides Rhizoctonia anaticula Rhizoctonia monteithiana 43 Rhizoctonia muneratii Tilletia aegopogonis Rhizoctonia nandorii Tilletia ahamadiana Rhizoctonia oryzae Tilletia airina Rhizoctonia oryzae-sativae Tilletia ajrekari Rhizoctonia pallida Tilletia alopecuri Rhizoctonia pini-insignis Tilletia anthaxanthi Rhizoctonia praticola Tilletia apludae Rhizoctonia quercus Tilletia armdinellae Rhizoctonia ramicola Tilletia asperifolia Rhizoctonia robusta Tilletia asperitolioides Rhizoctonia rubi Tilletia atacamensis Rhizoctonia ruhiginosa Tilletia baldrati Rhizoctonia sclerotica Tilietia bambusae Rhizoctonia solani Tilletia banarasae Rhizoctonia solani f. paroketea Tilletia bangalorensis Rhizoctonia solani forma specialis Tilletia barclayana Rhizoctonia solani var. cedri-deodorae Tilletia biharica Rhizoctonia solani var. fuchsiae Tilletia boliviensis Rhizoctonia solani var. hortensis Tilletia boutelouae Rhizoctonia stahlii Tilletia brachypodii Rhizoctonia subtilis var. nigra Tilletia brachypodii-ramosi Rhizoctonia subtlillis Tilletia braomi-tectorum Rhizoctonia tomato Tilletia brevifaciens Rhizoctonia tuliparum Tilletia bromi Rhizoctonia veae Tilletia bromina Rhizoctonia versicolor Tilletia brunkii Rhizoctonia cerealis Tilletia buchloeana Rhynchosporium secalis Tilletia bulayi Scierotina rolfsii Tilletia caries Sclerotinia rolfsii Tilletia cathcariae Sclerotinia sclerotiorum Tilletia cerebrina Septoria glycines Tilletia chloridicola Septoria nodorum Tilletia contaoversa Septoria tritici Tilletia contraversa var. prostrata Sphaerotheca fuliginea Tilletia contraversa var. elyni Stagonospora nodorum Tilletia corona Stemphylium botryosum Tilletia cynasuri Thielaviopsis basicola Tilletia damacarae Tilletia aegilopis Tilletia deyeuxiae 44 Tilletia digitariicola Tilletia laguri Tilletia durangensis Tilletia leptochlase Tilletia earlei Tilletia lepturi Tilletia echinochlave Tilletia macrotuberculata Tilletia echinochloae Tilletia madeirensis Tilletia echinosperma Tilletia maglagonli Tilletia ehrhartae Tilletia makutensis Tilletia eleusines Tilletia milti Tilletia elymandrae Tilletia milti-vernalis Tilletia elymicola Tilletia montana Tilletia elyni Tilletia montemartinii Tilletia elythrophori Tilletia nanifica Tilletia eragrostidis Tilletia narasimhanii Tilletia euphorbiae Tilletia narayanaoana Tilletia fahrendorfii Tilletia narduri Tilletia festinca-octoflorana Tilletia nigrifaciens Tilletia foelida Tilletia obscura-reticulora Tilletia foliicola Tilletia oklahomae Tilletia fusca Tilletia okudoirae Tilletia fusca var. bromi-tectorum Tilletia oplistneni-cristati Tilletia fusca var. guyotiana Tilletia paae Tilletia fusca var.paragonica Tilletia pachyderma Tilletia georfischeri Tilletia pallida Tilletia gigaspora Tilletia panici Tilletia goloskokovii Tilletia panici. humilis Tilletia haynaldiae Tilletia paonensis Tilletia heterospora Tilletia paraloxa Tilletia hold Tilletia paspali Tilletia hordei var.spontanei Tilletia pennisetina Tilletia horrida Tilletia peritidis Tilletia hyalospora var.cuzcoensis Tilletia phalaridis Tilletia hyparrheniae Tilletia polypoganis Tilletia indica Tilletia prostrata Tilletia iniermedia Tilletia pulcherrima var. brachiariae Tilletia iovensis Tilletia redfieldiae Tilletia ixophari Tilletia rhei Tilletia koeleriae Tilletia rugispora Tilletia kuznetzoviana Tilletia sabaudiae Tilletia laevis Tilletia salzmanii 45 Tilletia savilel Ustilago agrostis-palustris Tilletia scrobiculata Ustilago airear-caespitosae Tilletia setariae Ustilago alismatis Tilletia setariae-paImiflorarae Ustilago almadina Tilletia setariicola Ustilago alopecurivara Tilletia sphaerococca Ustilago alsineae Tilletia sphenopie Ustilago altilis Tilletia sphenopodis Ustilago amadelpha var. glabriuscula Tilletia sterilis Ustilago amphilophidis Tilletia taiana Ustilago amplexa Tilletia texana Ustilago amthoxanthi Tilletia themedae-anatherae Ustilago andropogonis-tectorum Tilletia themedicola Ustilago anellemae Tilletia toguateei Ustilago anhweiona Tilletia trachypogonis Ustilago anomala var. avicularis Tilletia transiliensis Ustilago anomala var. carnea Tilletia transvaalensis Ustilago anomala var. cordai Tilletia tritici f. monococci Ustilago anomala var. microspora Tilletia tritici var. controversa Ustilago anomala var. muricata Tilletia tritici var. nanifica Ustilago anomala var. tovarae Tilletia tritici var. laevis Ustilago apscheronica Tilletia tritici-repentis Ustilago arabidia.alpinae Tilletia triticoides Ustilago arandinellae-hirtae Tilletia tuberculare Ustilago arctica Tilletia vertiveriae Ustilago argentina Tilletia viermotii Ustilago aristidarius Tilletia vittara Ustilago arotragostis Tilletia vittara var. burmahnii Ustilago asparagi-pygmaei Tilletia walker Ustilago asprellae Tilletia youngii Ustilago avanae subsp. alba Tilletia zundeiii Ustilago avenae Typhula incarnata Ustilago avenae Uromyces appendiculatus Ustilago avenae f. sp. perennars Ustilago aaeluropodis Ustilago avenariae-bryophyllae Ustilago abstrusa Ustilago avicularis Ustilago aegilopsidis Ustilago bahuichivoensis Ustilago affinis var. hilariae Ustilago barbari Ustilago agrestis Ustilago beckeropsis Ustilago agropyrina Ustilago belgiana 46 Ustilago bethelii Ustilago clelandii Ustilago bicolor Ustilago clintoniana Ustilago bistortarum ustiloginea Ustilago coloradensis Ustilago bistortarum var. pustulata Ustilago commelinae Ustilago boreatis Ustilago compacta Ustilago bothriochloae Ustilago concelata Ustilago bothriochloae-intermediae Ustilago condigna Ustilago bouriqueti Ustilago consimilis Ustilago braziliensis Ustilago constantineanui Ustilago brisae Ustilago controversa Ustilago bromi-arvensis Ustilago conventere-sexualis Ustilago bromi-erecti Ustilago cordai Ustilago bromi-mallis Ustilago corlarderiae var. araucana Ustilago bromina Ustilago coronariaw Ustilago bromivora f. brachypodil Ustilago coronata Ustilago bromivora var. microspora Ustilago courtoisii Ustilago bullata f. brachypodii-distachyi Ustilago crus-galli var. minor Ustilago bullata var. bonariesis Ustilago cryptica Ustilago bullata var. macrospora Ustilago curta Ustilago bungeana Ustilago custanaica Ustilago calanagrostidis Ustilago cynodontis Ustilago calanagrostidis var. scrobiculata Ustilago cynodontis Ustilago calanagrostidis var. typica Ustilago cyperi-lucidi Ustilago cardamines Ustilago davisii Ustilago cariciphila Ustilago deccanii Ustilago caricis-wallichianae Ustilago decipiens Ustilago carnea Ustilago deformitis Ustilago catherimae Ustilago dehiscens Ustilago caulicola Ustilago delicata Ustilago cenrtodomis Ustilago deyeuxiae Ustilago ceparum Ustilago dianthorum Ustilago cephalariae Ustilago distichlidis Ustilago chacoensis Ustilago dubiosa Ustilago chloridii Ustilago dumosa Ustilago chloridionis Ustilago earlei Ustilago chrysopoganis Ustilago echinochloae Ustilago chubulensis Ustilago ehrhartana Ustilago cichorii Ustilago eleocharidis Ustilago cilmodis Ustilago eleusines 47 Ustilago elymicola Ustilago hilarlicola Ustilago elytrigiae Ustilago hilubii Ustilago enneapogonis Ustilago himalensis Ustilago epicampida Ustilago histortarum var. marginalis Ustilago eragrostidis-japanicana Ustilago hitchcockiana Ustilago eriocauli Ustilago holci-avanacei Ustilago eriochloae Ustilago hordei Ustilago euphorbiae Ustilago hordei f. sp. avenae Ustilago fagopyri Ustilago hsuii Ustilago festucae Ustilago hyalino-bipolaris Ustilago festucorum Ustilago hydropiperis Ustilago filamenticola Ustilago hyparrheniae Ustilago fingerhuthiae Ustilago hypodyies f. congoensis Ustilago flectens Ustilago hypodytes f. sporaboli Ustilago flonersii Ustilago hypodytes var. agrestis Ustilago foliorum Ustilago idonea Ustilago formosana Ustilago imperatue Ustilago fueguina Ustilago induia Ustilago gageae Ustilago inouyei Ustilago garcesi Ustilago intercedens Ustilago gardneri Ustilago iranica Ustilago gausenii Ustilago isachnes Ustilago gayazana Ustilago ischaemi-akoensis Ustilago gigantispora Ustilago ischaemi-anthephoroides Ustilago glyceriae Ustilago ixiolirii Ustilago gregaria Ustilago ixophori Ustilago grossheimii Ustilago jacksonii Ustilago gunnerae Ustilago jacksonii var. vintonesis Ustilago haesendocki var. chloraphorae Ustilago jaczevskyana Ustilago haesendocki var. vargasii Ustilago jaczevskyana van. typica Ustilago halophiloides Ustilago jaczevskyana var. sibirica Ustilago haynalodiae Ustilago jagdishwari Ustilago heleochloae Ustilago jamalainentii Ustilago helictotrichi Ustilago jehudana Ustilago herteri var. Bicolor Ustilago johnstonii Ustilago herteri var. vargasii Ustilago kairamoi Ustilago hierochloae-adoratae Ustilago kasuchstemica Ustilago hieronymi var. insularis Ustilago kenjiana Ustilago hieronymi var. minor Ustilago kweichowensis 48 Ustilago kylingae Ustilago mrucata Ustilago lacjrymae-jobi Ustilago muda Ustilago lepyrodiclidis Ustilago muehlenbergiae var. lucumanensis Ustilago lidii Ustilago muscaribotryoidis Ustilago liebenbergii Ustilago nagarnyi Ustilago linderi Ustilago nannfeldtii Ustilago linearis Ustilago nauda var. horde! Ustilago lirove Ustilago nelsoniana Ustilago loliicola Ustilago nepalensis Ustilago longiflora Ustilago neyraudiae Ustilago longiseti Ustilago nigra Ustilago longissima var. dubiosa Ustilago nivalis Ustilago longissima var. paludificans Ustilago nuda Ustilago longissima var. typica Ustilago nuda Ustilago lupini Ustilago nuda var.tritici Ustilago lychnidis-dioicae Ustilago nyassae Ustilago lycoperdiformis Ustilago okudairae Ustilago lyginiae Ustilago olida Ustilago machili Ustilago olivacea var. macrospora Ustilago machringiae Ustilago onopordi Ustilago magalaspora Ustilago onumae Ustilago magellanica Ustilago opiziicola Ustilago mariscana Ustilago oplismeni Ustilago maydis Ustilago orientalis Ustilago melicae Ustilago otophora Ustilago merxmuellerana Ustilago ovarlicola Ustilago mesatlantica Ustilago overcemii Ustilago michnoana Ustilago pamirica Ustilago microspora Ustilago panici-geminati Ustilago microspora var. paspalicola Ustilago panjabensis Ustilago microstegii Ustilago pappophori Ustilago microthelis Ustilago pappophori var. magdalensis Ustilago milli Ustilago parasnothii Ustilago mobtagnei var. minor Ustilago parodii Ustilago modesta Ustilago parvula Ustilago moenchiae-manticae Ustilago paspalidiicola Ustilago monermae Ustilago patagonica Ustilago morinae Ustilago penniseti var. verruculosa Ustilago morobiana Ustilago perrara 49 Ustilago persicariae Ustilago scitaminea Ustilago petrakii Ustilago scitaminea var. sacchar-officinorum Ustilago phalaridis Ustilago scleranthi Ustilago phlei Ustilago scrobiculata Ustilago phlei-protensis Ustilago scutulata Ustilago phragmites Ustilago secalis var. elymi Ustilago picacea Ustilago seitaminea var. sacchari-barberi Ustilago pimprina Ustilago semenoviana Ustilago piperi (var.) rosulata Ustilago serena Ustilago poae Ustilago serpens Ustilago poae-bulbosae Ustilago sesleriae Ustilago poae-nemoralis Ustilago setariae-mambassanae Ustilago polygoni-alati Ustilago shastensis Ustilago polygoni-alpini Ustilago shimadae Ustilago polygoni-punctari Ustilago silenes-inflatae Ustilago polygoni-serrulati Ustilago silenes-nutantis Ustilago polytocae Ustilago sinkiangensis Ustilago polytocae-harbatas Ustilago sitanil Ustilago pospelovii Ustilago sleuneri Ustilago prostrata Ustilago sonoriana Ustilago pseudohieronymi Ustilago sorghi-stipoidei Ustilago puehlaensis Ustilago spadicea Ustilago puellaris Ustilago sparoboli-indici Ustilago pulvertulensa Ustilago sparti Ustilago raciborskiana Ustilago speculariae Ustilago radians Ustilago spegazzinii Ustilago ravida Ustilago spegazzinii var. agrestis Ustilago rechingeri Ustilago spermophora var. orientalis Ustilago reticulara Ustilago spermophoroides Ustilago reticulispora Ustilago spinulosa Ustilago rhei Ustilago sporoboli-trenuli Ustilago rhynchelytri Ustilago stellariae Ustilago ruandenis Ustilago sterilis Ustilago ruberculata Ustilago stewartli Ustilago sabouriana Ustilago stipae Ustilago salviae Ustilago striaeformis f. phlei Ustilago sanctae-catharinae Ustilago striaeformis f. poa... Ustilago scaura Ustilago striaeformis f. poae-pratensis Ustilago scillae Ustilago striiformis f. hierochloes-odoratae 50 Ustilago striiformis var. agrostidis Ustilago tucumariensis Ustilago striiformis var. dactylidis Ustilago tumeformis Ustilago striiformis var. holci Ustilago turcomanica Ustilago striiformis var. phlei Ustilago turcomanica var. prostrata Ustilago strilformis var. poae Ustilago turcomanica var. typica Ustilago sumnevicziana Ustilago ugamica Ustilago superha Ustilago ugandensis var. macrospora Ustilago sydowiana Ustilago underwoodii Ustilago symbiotica Ustilago urginede Ustilago taenia Ustilago urochloana Ustilago taiana Ustilago ustilaginea Ustilago tanakue Ustilago ustriculosa var. cordai Ustilago tenuispora Ustilago ustriculosa var. reticulata Ustilago thaxteri Ustilago valentula Ustilago tinontiae Ustilago vavilori Ustilago togata Ustilago verecunda Ustilago tournenxii Ustilago verruculosa Ustilago tovarae Ustilago versatilis Ustilago trachophora var. pacifica Ustilago vetiveriae Ustilago trachyniae Ustilago violaceo-irregularis Ustilago trachypogonis Ustilago violaceu var. stellariae Ustilago tragana Ustilago violaceuverrucosa Ustilago tragi Ustilago williamsii Ustilago tragica Ustilago wynaadensis Ustilago tragi-racemosi Ustilago zambettakisii Ustilago trichoneurana Ustilago zernae Ustilago trichophora var. crus-galli Venturia inaequalis Ustilago trichophora var. panici-frumentacei Xanthomonas campestris Ustilago triseti Xanthomonas oryzae Ustilago tritici forma specialis The compositions comprising the components 1) and 2) are particularly suitable for controlling phytopathogenic fungi in barley (e.g. Pyrenophora teres,Rhynchosporium secalis,Puccinia hordei,Puccinia striiformis, Blumeria graminis, Ramularia collo-cygni / 5 Physiological leaf spots, Microdochium nivale, Typhula incarnata, Pseudocercosporella herpotrichoides, Fusariurm culmorum, Rhizoctonia cerealis, Gaeumannomyces graminis) and soybeans (e.g. Phakopsora pachyrhizi, Microsphaera diffusa, Septoria glycines, Cercospora sojina, Cercospora kikuchii, Corynespora cassiicola, Colletotrichum truncatum, Peronospora manshurica, Alternaria spp., Phomopsis 51 phaseoli, Diaporthe phaseolorum, Phialophora gregata, Fusarium solani, Sclerotinia sclerotiorum, Sclerotinia rolfsii, Phytopthora megasperma, Rhizoctonia solani, Dematophora necatrix, Macrophomina phaseolina). 5 The inventive compositions are particularly suitable for controlling phytopathogenic fungi in soybeans, vegetables and fruit crops. The compositions according to the invention are furthermore suitable for controlling harmful fungi in the protection of materials (for example wood, paper, paint dispersions, 10 fibers or fabrics) and in the protection of stored products. In the protection of wood, particular attention is paid to the following harmful fungi: Ascomycetes, such as Ophio stoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chae tomium spp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes, such as Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp., Pleurotus spp., Po 15 ria spp., Serpula spp. and Tyromyces spp., Deuteromycetes, such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichoderma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes, such as Mucor spp., additionally in the protection of materials the following yeasts: Candida spp. and Saccharomyces cerevisae. 20 Application of the inventive compositions to useful plants may also lead to an increase in the crop yield. The components 1) and 2) can be applied simultaneously, that is jointly or separately, or in succession, the sequence, in the case of separate application, generally not hav 25 ing any effect on the result of the control measures. When preparing the compositions, it is preferred to employ the commercially available formulations of components 1) and 2), to which further compounds active against harmful fungi or other pests, such as insects, arachnids or nematodes, or else herbi 30 cidal or growth-regulating active compounds or fertilizers may be added. Usually, compositions comprising component 1) and 2), wherein component 2) consists of only one active ingredient (11), are employed. However, in certain cases composi tions wherein component 2) consists of two or, if appropriate, more active components 35 may be advantageous. Suitable further active components in the above sense are in particular the active com pounds II mentioned at the outset, and in particular the preferred active compounds II mentioned above. 40 52 Components 1) and 2) are usually employed in a weight ratio of from 100:1 to 1:100, preferably from 30:1 to 1:30, in particular from 15:1 to 1:15. The further active components are, if desired, added in a ratio of from 20:1 to 1:20 to 5 component 1). Depending on the particular components and the desired effect, the application rates for component 1) are generally from 1 1 to 100 I broth containing the strain per hectare, preferably from 1 i to 50 I/ha, in particular from 1 to 20 I/ha. 10 Correspondingly, the application rates for component 2) are generally from 1 to 2000 g/ha, preferably from 10 to 1500 g/ha, in particular from 40 to 1000 g/ha. The method for controlling harmful fungi is carried out by the separate or joint applica 15 tion of a component 1) and a component 2), or a composition comprising components 1) and 2), by spraying or dusting the seeds, the plants or the soils before or after sow ing of the plants or before or after emergence of the plants. The compositions according to the invention, or the single components separately, can 20 be converted into customary formulations, for example solutions, emulsions, suspen sions, dusts, powders, pastes and granules. The use form depends on the particular intended purpose; in each case, it should ensure a fine and even distribution of the mixture according to the invention. 25 The formulations are prepared in a known manner, for example by extending the single components with solvents and/or carriers, if desired using emulsifiers and dispersants. Solvents/auxiliaries suitable for this purpose are essentially: - water, aromatic solvents (for example Solvesso* products, xylene), paraffins (for example mineral oil fractions), alcohols (for example methanol, butanol, pentanol, 30 benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone), pyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone), acetates (glycol diacetate), glycols, fatty acid dimethylamides, fatty acids and fatty acid esters. In principle, solvent mixtures may also be used. - carriers such as ground natural minerals (for example kaolins, clays, talc, chalk) and 35 ground synthetic minerals (for example highly disperse silica, silicates); emulsifiers such as nonionogenic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose. 40 Suitable surfactants used are alkali metal, alkaline earth metal and ammonium salts of lignosuifonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalene- 53 sulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxy 5 ethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, alkylaryl polyether alcohols, alcohol and fatty alcohol ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite 10 waste liquors and methylcellulose. Substances which are suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or 15 animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin, tetra hyd ronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, highly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone and water. 20 Powders, materials for spreading and dustable products can be prepared by mixing or concomitantly grinding the active substances with a solid carrier. Granules, for example coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active compounds to solid carriers. Examples 25 of solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, attaclay, limestone, lime, chalk, bole, less, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, ground synthetic materials, fertilizers, such as, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and 30 nutshell meal, cellulose powders and other solid carriers. In order to achieve good dispersion and adhesion of compositions within the present invention, it may be advantageous to formulate the whole broth culture, supernatant and/or metabolite with components that aid dispersion and adhesion. 35 In general, the formulations comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight, of the components. The active compounds (11) are employed in a purity of from 90% to 100%, preferably 95% to 100% (according to NMR spectrum). 40 The following are examples of formulations: 1. Products for dilution with water 54 A) Water-soluble concentrates (SL) 10 parts by weight of a composition according to the invention are dissolved in 90 parts by weight of water or in a water-soluble solvent. As an alternative, wetting agents or other auxiliaries are added. Dilution with water results in a formulation having a content 5 of 10% by weight of components 1) and 2) is obtained. B) Dispersible concentrates (DC) 20 parts by weight of a composition according to the invention are dissolved in 70 parts by weight of cyclohexanone with addition of 10 parts by weight of a dispersant, for 10 example polyvinylpyrrolidone. Dilution with water gives a dispersion having a content of 0% by weight of components 1) and 2). C) Emulsifiable concentrates (EC) 15 parts by weight of a composition according to the invention are dissolved in 75 parts 15 by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The formulation has a content of 15% by weight of components 1) and 2). D) Emulsions (EW, EO) 20 25 parts by weight of a composition according to the invention are dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This composition is introduced into 30 parts by weight of water by means of an emulsifying machine (Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion. The formulation 25 has a content of 25% by weight of components 1) and 2). E) Suspensions (SC, OD) In an agitated ball mill, 20 parts by weight of a composition according to the invention are comminuted with addition of 10 parts by weight of dispersants and wetting agents 30 and 70 parts by weight of water or an organic solvent to give a fine suspension. Dilution with water gives a stable suspension having a content of 20% by weight of components 1) and 2). F) Water-dispersible granules and water-soluble granules (WG, SG) 35 50 parts by weight of a composition according to the invention are ground finely with addition of 50 parts by weight of dispersants and wetting agents and prepared as water-dispersible or water-soluble granules by means of technical appliances (for example extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution having a content of 50% by weight of components 1) and 2). 40 55 G) Water-dispersible powders and water-soluble powders (WP, SP) 75 parts by weight of a composition according to the invention are ground in a rotor stator mill with addition of 25 parts by weight of dispersants, wetting agents and silica gel. Dilution with water gives a stable dispersion or solution having a content of 75% by 5 weight of components 1) and 2). 2. Products to be applied undiluted If) H) Dustable powders (DP) 5 parts by weight of a composition according to the invention are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dustable product having a content of 5% by weight of components 1) and 2). 15 J) Granules (GR, FG, GG, MG) 0.5 part by weight of a composition according to the invention is ground finely and associated with 99.5 parts by weight of carriers. Current methods are extrusion, spray drying or the fluidized bed. This gives granules to be applied undiluted having a content of 0.5% of weight of components 1) and 2). 20 K) ULV solutions (UL) 10 parts by weight of a composition according to the invention are dissolved in 90 parts by weight of an organic solvent, for example xylene. This gives a product to be applied undiluted having a compound content of 10% by weight of components 1) and 2). 25 Components 1) and 2) can be used as such, in the form of their formulations or the use forms prepared therefrom, for example in the form of directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading, or granules, by means of spraying, atomizing, 30 dusting, spreading or pouring. The use forms depend entirely on the intended purposes; they are intended to ensure in each case the finest possible distribution of components 1) and 2) according to the invention. Aqueous use forms can be prepared from emulsion concentrates, pastes or wettable 35 powders (sprayable powders, oil dispersions) by adding water. To prepare emulsions, pastes or oil dispersions, the substances, as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier. However, it is also possible to prepare concentrates composed of active substance, wetting agent, tackifier, dispersant or emulsifier and, if appropriate, solvent 40 or oil, and such concentrates are suitable for dilution with water.

56 The concentrations of the components in the ready-to-use preparations can be varied within relatively wide ranges. In general, they are from 0.0001 to 100%, preferably from 0.01 to 100%. 5 Components 1) and 2) may also be used successfully in the ultra-low-volume process (ULV), it being possible to apply formulations comprising over 95% by weight of active compound, or even to apply components 1) and 2) without additives. Oils of various types, wetting agents or adjuvants may be added to the component 1) 10 or 2), even, if appropriate, not until immediately prior to use (tank mix). These agents are typically admixed with component 1) or 2) according to the invention in a weight ratio of from 1:100 to 100:1, preferably from 1:10 to 10:1. Suitable adjuvants in this sense are in particular: organically modified polysiloxanes, for 15 example Break Thru S 240*; alcohol alkoxylates, for example Atplus 245*, Atplus MBA 1303*, Plurafac LF 3000 and Lutensol ON 300; EO/PO block polymers, for example Pluronic RPE 2035* and Genapol Be; alcohol ethoxylates, for example Lutensol XP 80*; and sodium dioctylsulfosuccinate, for example Leophen RA*. 20 Components 1) and 2) or the composition comprising components 1) and 2), or the corresponding formulations, are applied by treating the harmful fungi, the plants, seeds, soils, areas, materials or spaces to be kept free from them with a fungicidally effective amount of the composition or, in the case of separate application, of the components 1) and 2) separately. Application can be before or after the infection by harmful fungi. 25 The fungicidal action of components 1) and 2) and of the compositions according to the invention was demonstrated by the tests below. Components 1) and 2), separately or jointly, were prepared as a stock solution 30 comprising 25 mg of active compound which was made up to 10 ml using a mixture of acetone and/or DMSO and the emulsifier Uniperol* EL (wetting agent having an emulsifying and dispersing action based on ethoxylated alkylphenols) in a ratio by volume of solvent/emulsifier of 99:1. The mixture was then made up to 100 ml with water. This stock solution was diluted with the solvent/emulsifier/water mixture 35 described to give the concentration of active compound stated below. The visually determined percentages of infected leaf areas were converted into efficacies in % of the untreated control: 40 The efficacy (E) is calculated as follows using Abbot's formula: E = (1 -aJ ) - 100 57 a corresponds to the fungicidal infection of the treated plants in % and 0 corresponds to the fungicidal infection of the untreated (control) plants in % An efficacy of 0 means that the infection level of the treated plants corresponds to that 5 of the untreated control plants; an efficacy of 100 means that the treated plants were not infected. The expected efficacies of active compound combinations were determined using Colby's formula (Colby, S.R. " Calculating synergistic and antagonistic responses of 10 herbicide combinations", Weeds, 15, pp. 20-22, 1967) and compared with the observed efficacies. Colby's formula: E = x + y- x. y/100 15 E expected efficacy, expressed in % of the untreated control, when using the mixture of the active compounds A and B at the concentrations a and b x efficacy, expressed in % of the untreated control, when using the active compound A at the concentration a y efficacy, expressed in % of the untreated control, when using the active 20 compound B at the concentration b

Claims

1. A fungicidal composition for controlling phytopathogenic harmful fungi, comprising 1) Bacillus subtilis strain with NRRL Accession No. B-21661 or a mutant thereof having all the identifying characteristics of the strain, and 2) an active carboxamide compound selected from the group consisting of N (3',4'-dichloro-5-fluoro-biphenyl-2-yl)-3-difluoromethyl-1-methyl-iH-pyrazole-4 carboxamide, N-(3',4',5'-trifluorobiphenyl-2-yl)- 1 -methyl-3 -difluoromethyl- 1 H pyrazole-4-carboxamide, N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5-fluoro-1H pyrazole-4-carboxamide and fluopyram.

2. The fungicidal composition according to claim 1, comprising as component 1) a commercially available formulation of the Bacillus subtilis strain with NRRL Accession No. B-21661.

3. The fungicidal composition according to claim 1 or 2, comprising as component 2) N-(2-(1,3-dimethylbutyl)-phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide.

4. The fungicidal composition according to claim 1 or 2, comprising as component 2) fluopyram.

5. The fungicidal composition according to claim 1 or 2, comprising as component 2) N-(3',4',5'-trifluorobiphenyl-2-yl)-1 -methyl-3-difluoromethyl-1H-pyrazole-4 carboxamide.

6. The fungicidal composition according to claim 1 or 2, comprising an additional active compound V, selected from the groups G) to M): G) azoles selected from the group consisting of bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, 59 simeconazole, triadimefon, triadimenol, tebuconazole, tetraconazole, triticonazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamid, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole and hymexazole; H) strobilurins selected from the group consisting of azoxystrobin, dimoxy strobin, enestroburin, fluoxastrobin, kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, enestroburin, methyl (2-chloro-5-[1-(3 methylbenzyloxyimino)ethyl]benzyl)carbamate, methyl (2-chloro-5-[1-(6-methylpyridin 2-ylmethoxyimino)ethyl]benzyl)-carbamate and methyl 2-(ortho-(2,5 dimethylphenyloxymethylene)phenyl)-3-methoxyacrylate; J) carboxamides selected from the group consisting of carboxin, boscalid, fenhexamid, flutolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil, 3,4-dichloro-N-(2 cyanophenyl)isothiazole-5-carboxamide, dimethomorph, flumorph, flumetover, fluopicolide (picobenzamid), zoxamide, carpropamid, diclocymet, mandipropamid, N-(2 (4-[3-(4-chlorophenyl)prop-2-ynyloxy]-3-methoxy-phenyl)ethyl)-2 methanesulfonylamino-3-methylbutyramide, N-(2-(4-[3-(4-chlorophenyl)prop-2 ynyloxy]-3-methoxyphenyl)ethyl)-2-ethanesulfonyl-amino-3-methylbutyramide, methyl 3-(4-chlorophenyl)-3-(2-isopropoxy-carbonylamino-3-methylbutyrylamino)propionate, N-(4'-bromobiphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4' trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazole-5-carboxamide, N-(4' chloro-3'-fluorobiphenyl-2-yl)-4-difluoromethyl-2-methyl-thiazole-5-carboxamide, N (3',4'-dichloro-4-fluorobiphenyl-2-yl)-3-difluoro-methyl-1-methylpyrazole-4-carbox amide, N-(3',4'-dichloro-5-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methylpyrazole 4-carboxamide and N-(2-cyano-phenyl)-3,4-dichloroisothiazole-5-carboxamide; K) heterocyclic compounds selected from the group consisting of fluazinam, pyrifenox, bupirimate, cyprodinil, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil, triforine, fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodione, procymidone, vinclozolin, famoxadone, fenamidone, octhilinone, probenazole, anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole, 2 butoxy-6-iodo-3-propylchromen-4-one, acibenzolar-S-methyl, captafol, captan, dazomet, 60 folpet, fenoxanil, quinoxyfen and N,N-dimethyl-3-(3-bromo-6-fluoro-2-methylindole-1 sulfonyl)-[1,2,4]triazole-1-sulfonamide; L) carbamates selected from the group consisting of mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram, diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb, 4-fluorophenyl N-(1 -(1 -(4 cyanophenyl)ethanesulfonyl)but-2-yl)carbamate, methyl 3-(4-chlorophenyl)-3-(2 isopropoxycarbonylamino-3-methyl-butyrylamino)propanoate and carbamate oxime ethers of the formula VI C1 H3CO N N OH 3 VI, 0 OH 3 in which Z is N or CH; M) other fungicides selected from the group consisting of guanidine, dodine, iminoctadine, guazatine, antibiotics: kasugamycin, streptomycin, polyoxin, validamycin A, nitrophenyl derivatives: binapacryl, dinocap, dinobuton, sulfur containing heterocyclyl compounds: dithianon, isoprothiolane, organometallic compounds: fentin salts, organophosphorus compounds: edifenphos, iprobenfos, fosetyl, fosetyl-aluminum, phosphorous acid and its salts, pyrazophos, tolclofos-methyl, organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, hexachlorobenzene, phthalide, pencycuron, quintozene, thiophanate-methyl, tolylfluanid, inorganic active compounds: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur, others: cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl and spiroxamine.

7. The fungicidal composition according to any one of claims 1 to 6, comprising the components 1) and 2) in a weight ratio of from 100:1 to 1:100.

8. A fungicidal agent, comprising at least one liquid or solid carrier and a composition according to any one of claims 1 to 6. 61

9. A method for controlling phytopathogenic harmful fungi, wherein the fungi, their habitat or the plants to be protected against fungal attack, the soil, seed, areas, materials or spaces are/is treated with an effective amount of a component 1) and a component 2) according to any one of claims 1 to 6.

10. The method according to claim 9, wherein said components 1) and 2) are applied simultaneously, that is jointly or separately, or in succession.

11. Seed treated with a composition according to any one of claims 1 to 6.

12. The use of components 1) and 2) according to any one of claims 1 to 6 for preparing a fungicidal agent suitable for controlling harmful fungi.

13. The use of components 1) and 2) according to any one of claims 1 to 6 for treating transgenic plants or the seed thereof. BASFSE WATERMARK PATENT AND TRADE MARKS ATTORNEYS P32955AU01