AU2013267026B2 - Weed control composition - Google Patents
Weed control composition Download PDFInfo
- Publication number
- AU2013267026B2 AU2013267026B2 AU2013267026A AU2013267026A AU2013267026B2 AU 2013267026 B2 AU2013267026 B2 AU 2013267026B2 AU 2013267026 A AU2013267026 A AU 2013267026A AU 2013267026 A AU2013267026 A AU 2013267026A AU 2013267026 B2 AU2013267026 B2 AU 2013267026B2
- Authority
- AU
- Australia
- Prior art keywords
- salt
- methyl
- ester
- inhibitors
- glyphosate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 241000196324 Embryophyta Species 0.000 title claims abstract description 170
- 239000000203 mixture Substances 0.000 title claims abstract description 100
- 239000013078 crystal Substances 0.000 claims abstract description 117
- FOUWCSDKDDHKQP-UHFFFAOYSA-N flumioxazin Chemical compound FC1=CC=2OCC(=O)N(CC#C)C=2C=C1N(C1=O)C(=O)C2=C1CCCC2 FOUWCSDKDDHKQP-UHFFFAOYSA-N 0.000 claims abstract description 103
- 150000001875 compounds Chemical class 0.000 claims abstract description 87
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 41
- 229910016523 CuKa Inorganic materials 0.000 claims abstract description 4
- 238000002050 diffraction method Methods 0.000 claims abstract description 4
- 239000003112 inhibitor Substances 0.000 claims description 78
- -1 isoxachlorotole Chemical compound 0.000 claims description 67
- 150000003839 salts Chemical class 0.000 claims description 67
- 150000002148 esters Chemical class 0.000 claims description 50
- 238000000034 method Methods 0.000 claims description 47
- 239000002689 soil Substances 0.000 claims description 46
- 239000004381 Choline salt Substances 0.000 claims description 42
- 235000019417 choline salt Nutrition 0.000 claims description 36
- 235000010469 Glycine max Nutrition 0.000 claims description 31
- 244000068988 Glycine max Species 0.000 claims description 31
- 239000004009 herbicide Substances 0.000 claims description 29
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 28
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 28
- 240000008042 Zea mays Species 0.000 claims description 25
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 25
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 25
- 235000005822 corn Nutrition 0.000 claims description 25
- 229920000742 Cotton Polymers 0.000 claims description 21
- 241000219146 Gossypium Species 0.000 claims description 21
- 159000000000 sodium salts Chemical class 0.000 claims description 20
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 claims description 17
- LIOPHZNMBKHGAV-UHFFFAOYSA-M potassium;2-(phosphonomethylamino)acetate Chemical class [K+].OC(=O)CNCP(O)([O-])=O LIOPHZNMBKHGAV-UHFFFAOYSA-M 0.000 claims description 17
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 claims description 15
- 239000004808 2-ethylhexylester Substances 0.000 claims description 15
- CASLETQIYIQFTQ-UHFFFAOYSA-N 3-[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylsulfonyl]-5,5-dimethyl-4h-1,2-oxazole Chemical compound CN1N=C(C(F)(F)F)C(CS(=O)(=O)C=2CC(C)(C)ON=2)=C1OC(F)F CASLETQIYIQFTQ-UHFFFAOYSA-N 0.000 claims description 14
- NSWAMPCUPHPTTC-UHFFFAOYSA-N chlorimuron-ethyl Chemical group CCOC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(Cl)=CC(OC)=N1 NSWAMPCUPHPTTC-UHFFFAOYSA-N 0.000 claims description 14
- 239000005504 Dicamba Substances 0.000 claims description 13
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 13
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 claims description 13
- NMDWGEGFJUBKLB-YFKPBYRVSA-N (2S)-2-hydroxy-2-methyl-3-oxobutanoic acid Chemical compound CC(=O)[C@](C)(O)C(O)=O NMDWGEGFJUBKLB-YFKPBYRVSA-N 0.000 claims description 12
- 239000005571 Isoxaflutole Substances 0.000 claims description 12
- 239000005620 Tembotrione Substances 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 12
- OYIKARCXOQLFHF-UHFFFAOYSA-N isoxaflutole Chemical compound CS(=O)(=O)C1=CC(C(F)(F)F)=CC=C1C(=O)C1=C(C2CC2)ON=C1 OYIKARCXOQLFHF-UHFFFAOYSA-N 0.000 claims description 12
- 229940088649 isoxaflutole Drugs 0.000 claims description 12
- IUQAXCIUEPFPSF-UHFFFAOYSA-N tembotrione Chemical compound ClC1=C(COCC(F)(F)F)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O IUQAXCIUEPFPSF-UHFFFAOYSA-N 0.000 claims description 12
- 239000005578 Mesotrione Substances 0.000 claims description 11
- 239000005583 Metribuzin Substances 0.000 claims description 11
- BIKACRYIQSLICJ-UHFFFAOYSA-N cloransulam-methyl Chemical group N=1N2C(OCC)=NC(F)=CC2=NC=1S(=O)(=O)NC1=C(Cl)C=CC=C1C(=O)OC BIKACRYIQSLICJ-UHFFFAOYSA-N 0.000 claims description 11
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 claims description 11
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 claims description 11
- 102000016680 Dioxygenases Human genes 0.000 claims description 10
- 108010028143 Dioxygenases Proteins 0.000 claims description 10
- RQVYBGPQFYCBGX-UHFFFAOYSA-N ametryn Chemical compound CCNC1=NC(NC(C)C)=NC(SC)=N1 RQVYBGPQFYCBGX-UHFFFAOYSA-N 0.000 claims description 10
- GNHDVXLWBQYPJE-UHFFFAOYSA-N saflufenacil Chemical compound C1=C(Cl)C(C(=O)NS(=O)(=O)N(C)C(C)C)=CC(N2C(N(C)C(=CC2=O)C(F)(F)F)=O)=C1F GNHDVXLWBQYPJE-UHFFFAOYSA-N 0.000 claims description 10
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims description 9
- 239000005562 Glyphosate Substances 0.000 claims description 9
- PDYXIVPKOMYDOK-UHFFFAOYSA-N Glyphosate-monoammonium Chemical class [NH4+].OC(=O)CNCP(O)([O-])=O PDYXIVPKOMYDOK-UHFFFAOYSA-N 0.000 claims description 9
- 240000000111 Saccharum officinarum Species 0.000 claims description 9
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 9
- 229940121373 acetyl-coa carboxylase inhibitor Drugs 0.000 claims description 9
- CPHCYTUHSKEDOI-UHFFFAOYSA-N diazanium;2-(phosphonatomethylamino)acetic acid Chemical class [NH4+].[NH4+].OC(=O)CNCP([O-])([O-])=O CPHCYTUHSKEDOI-UHFFFAOYSA-N 0.000 claims description 9
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 9
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 9
- 229940097068 glyphosate Drugs 0.000 claims description 9
- YWICANUUQPYHOW-UHFFFAOYSA-M sodium;2-(phosphonomethylamino)acetate Chemical compound [Na+].OP(O)(=O)CNCC([O-])=O YWICANUUQPYHOW-UHFFFAOYSA-M 0.000 claims description 9
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 8
- 244000105624 Arachis hypogaea Species 0.000 claims description 8
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 8
- 235000018262 Arachis monticola Nutrition 0.000 claims description 8
- 229930192334 Auxin Natural products 0.000 claims description 8
- 239000005630 Diquat Substances 0.000 claims description 8
- 108020001991 Protoporphyrinogen Oxidase Proteins 0.000 claims description 8
- 102000005135 Protoporphyrinogen oxidase Human genes 0.000 claims description 8
- 235000021307 Triticum Nutrition 0.000 claims description 8
- 241000209140 Triticum Species 0.000 claims description 8
- 239000002363 auxin Substances 0.000 claims description 8
- MZZBPDKVEFVLFF-UHFFFAOYSA-N cyanazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C#N)=N1 MZZBPDKVEFVLFF-UHFFFAOYSA-N 0.000 claims description 8
- 102000005396 glutamine synthetase Human genes 0.000 claims description 8
- 108020002326 glutamine synthetase Proteins 0.000 claims description 8
- RUCAXVJJQQJZGU-UHFFFAOYSA-M hydron;2-(phosphonatomethylamino)acetate;trimethylsulfanium Chemical class C[S+](C)C.OP(O)(=O)CNCC([O-])=O RUCAXVJJQQJZGU-UHFFFAOYSA-M 0.000 claims description 8
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims description 8
- 150000004702 methyl esters Chemical class 0.000 claims description 8
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 claims description 8
- 235000020232 peanut Nutrition 0.000 claims description 8
- JDRFUUBRGGDEIZ-UHFFFAOYSA-N 3,6-dichloro-2-methoxybenzoate;dimethylazanium Chemical class CNC.COC1=C(Cl)C=CC(Cl)=C1C(O)=O JDRFUUBRGGDEIZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000005561 Glufosinate Substances 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 108010060806 Photosystem II Protein Complex Proteins 0.000 claims description 7
- 108090000704 Tubulin Proteins 0.000 claims description 7
- 102000004243 Tubulin Human genes 0.000 claims description 7
- QRSHQJLLXXEYPS-UHFFFAOYSA-N azane;5-ethyl-2-(4-methyl-5-oxo-4-propan-2-yl-1h-imidazol-2-yl)pyridine-3-carboxylic acid Chemical group [NH4+].[O-]C(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 QRSHQJLLXXEYPS-UHFFFAOYSA-N 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 7
- 239000010452 phosphate Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 108010001545 phytoene dehydrogenase Proteins 0.000 claims description 7
- 238000003786 synthesis reaction Methods 0.000 claims description 7
- 150000004669 very long chain fatty acids Chemical class 0.000 claims description 7
- DLUOWQZURZVAEN-UHFFFAOYSA-N 3,6-dichloro-2-methoxybenzoic acid;propan-2-amine Chemical compound CC(C)N.COC1=C(Cl)C=CC(Cl)=C1C(O)=O DLUOWQZURZVAEN-UHFFFAOYSA-N 0.000 claims description 6
- XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000005623 Thifensulfuron-methyl Substances 0.000 claims description 6
- HLZCHRAMVPCKDU-UHFFFAOYSA-M dicamba-sodium Chemical compound [Na+].COC1=C(Cl)C=CC(Cl)=C1C([O-])=O HLZCHRAMVPCKDU-UHFFFAOYSA-M 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 claims description 6
- ROBSGBGTWRRYSK-SNVBAGLBSA-N (2r)-2-[4-(4-cyano-2-fluorophenoxy)phenoxy]propanoic acid Chemical compound C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=CC=C(C#N)C=C1F ROBSGBGTWRRYSK-SNVBAGLBSA-N 0.000 claims description 5
- ADDQHLREJDZPMT-AWEZNQCLSA-N (S)-metamifop Chemical compound O=C([C@@H](OC=1C=CC(OC=2OC3=CC(Cl)=CC=C3N=2)=CC=1)C)N(C)C1=CC=CC=C1F ADDQHLREJDZPMT-AWEZNQCLSA-N 0.000 claims description 5
- HKELWJONQIFBPO-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-5-(trichloromethyl)-1,2,4-triazole-3-carboxylic acid Chemical compound N1=C(C(=O)O)N=C(C(Cl)(Cl)Cl)N1C1=CC=C(Cl)C=C1Cl HKELWJONQIFBPO-UHFFFAOYSA-N 0.000 claims description 5
- HXMBBZAHRWCZOX-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetic acid;propan-2-amine Chemical compound CC(C)[NH3+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl HXMBBZAHRWCZOX-UHFFFAOYSA-N 0.000 claims description 5
- MZHCENGPTKEIGP-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-UHFFFAOYSA-N 0.000 claims description 5
- QURLONWWPWCPIC-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol;3,6-dichloro-2-methoxybenzoic acid Chemical compound NCCOCCO.COC1=C(Cl)C=CC(Cl)=C1C(O)=O QURLONWWPWCPIC-UHFFFAOYSA-N 0.000 claims description 5
- WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 claims description 5
- GOCUAJYOYBLQRH-UHFFFAOYSA-N 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl GOCUAJYOYBLQRH-UHFFFAOYSA-N 0.000 claims description 5
- YUVKUEAFAVKILW-UHFFFAOYSA-N 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 YUVKUEAFAVKILW-UHFFFAOYSA-N 0.000 claims description 5
- OOLBCHYXZDXLDS-UHFFFAOYSA-N 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CC=C(Cl)C=C1Cl OOLBCHYXZDXLDS-UHFFFAOYSA-N 0.000 claims description 5
- MPPOHAUSNPTFAJ-UHFFFAOYSA-N 2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 MPPOHAUSNPTFAJ-UHFFFAOYSA-N 0.000 claims description 5
- ABOOPXYCKNFDNJ-UHFFFAOYSA-N 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CN=C(C=C(Cl)C=C2)C2=N1 ABOOPXYCKNFDNJ-UHFFFAOYSA-N 0.000 claims description 5
- UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 claims description 5
- 239000005489 Bromoxynil Substances 0.000 claims description 5
- 239000005498 Clodinafop Substances 0.000 claims description 5
- 239000005506 Diclofop Substances 0.000 claims description 5
- 108010039731 Fatty Acid Synthases Proteins 0.000 claims description 5
- CSPPKDPQLUUTND-NBVRZTHBSA-N Sethoxydim Chemical compound CCO\N=C(/CCC)C1=C(O)CC(CC(C)SCC)CC1=O CSPPKDPQLUUTND-NBVRZTHBSA-N 0.000 claims description 5
- YUIKUTLBPMDDNQ-MRVPVSSYSA-N clodinafop Chemical compound C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=NC=C(Cl)C=C1F YUIKUTLBPMDDNQ-MRVPVSSYSA-N 0.000 claims description 5
- RFOHRSIAXQACDB-UHFFFAOYSA-M sodium;2-(2,4-dichlorophenoxy)acetate Chemical compound [Na+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl RFOHRSIAXQACDB-UHFFFAOYSA-M 0.000 claims description 5
- VIXCLRUCUMWJFF-KGLIPLIRSA-N (1R,5S)-benzobicyclon Chemical compound CS(=O)(=O)c1ccc(C(=O)C2=C(Sc3ccccc3)[C@H]3CC[C@H](C3)C2=O)c(Cl)c1 VIXCLRUCUMWJFF-KGLIPLIRSA-N 0.000 claims description 4
- AIAYSXFWIUNXRC-PHIMTYICSA-N (1r,5s)-3-[hydroxy-[2-(2-methoxyethoxymethyl)-6-(trifluoromethyl)pyridin-3-yl]methylidene]bicyclo[3.2.1]octane-2,4-dione Chemical compound COCCOCC1=NC(C(F)(F)F)=CC=C1C(O)=C1C(=O)[C@@H](C2)CC[C@@H]2C1=O AIAYSXFWIUNXRC-PHIMTYICSA-N 0.000 claims description 4
- DQKWXTIYGWPGOO-UHFFFAOYSA-N (2,6-dibromo-4-cyanophenyl) octanoate Chemical compound CCCCCCCC(=O)OC1=C(Br)C=C(C#N)C=C1Br DQKWXTIYGWPGOO-UHFFFAOYSA-N 0.000 claims description 4
- WRXSEWUFHVTFEX-NUBCRITNSA-N (2r)-2-(2,4-dichlorophenoxy)propanoic acid;n-methylmethanamine Chemical compound CNC.OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1Cl WRXSEWUFHVTFEX-NUBCRITNSA-N 0.000 claims description 4
- MPPOHAUSNPTFAJ-SECBINFHSA-N (2r)-2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoic acid Chemical compound C1=CC(O[C@H](C)C(O)=O)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 MPPOHAUSNPTFAJ-SECBINFHSA-N 0.000 claims description 4
- MZHCENGPTKEIGP-RXMQYKEDSA-N (R)-dichlorprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-RXMQYKEDSA-N 0.000 claims description 4
- WNTGYJSOUMFZEP-SSDOTTSWSA-N (R)-mecoprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-SSDOTTSWSA-N 0.000 claims description 4
- WVQBLGZPHOPPFO-LBPRGKRZSA-N (S)-metolachlor Chemical compound CCC1=CC=CC(C)=C1N([C@@H](C)COC)C(=O)CCl WVQBLGZPHOPPFO-LBPRGKRZSA-N 0.000 claims description 4
- DHYXNIKICPUXJI-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-n-(2,4-difluorophenyl)-5-oxo-n-propan-2-yl-1,2,4-triazole-4-carboxamide Chemical compound C=1C=C(F)C=C(F)C=1N(C(C)C)C(=O)N(C1=O)C=NN1C1=CC=C(Cl)C=C1Cl DHYXNIKICPUXJI-UHFFFAOYSA-N 0.000 claims description 4
- PYCINWWWERDNKE-UHFFFAOYSA-N 1-(2-chloro-6-propylimidazo[1,2-b]pyridazin-3-yl)sulfonyl-3-(4,6-dimethoxypyrimidin-2-yl)urea Chemical compound N12N=C(CCC)C=CC2=NC(Cl)=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 PYCINWWWERDNKE-UHFFFAOYSA-N 0.000 claims description 4
- VQHHIQJPQOLZGF-UHFFFAOYSA-N 1-(2-iodophenyl)sulfonyl-3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)I)=N1 VQHHIQJPQOLZGF-UHFFFAOYSA-N 0.000 claims description 4
- RBSXHDIPCIWOMG-UHFFFAOYSA-N 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethylsulfonylimidazo[1,2-a]pyridin-3-yl)sulfonylurea Chemical compound CCS(=O)(=O)C=1N=C2C=CC=CN2C=1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 RBSXHDIPCIWOMG-UHFFFAOYSA-N 0.000 claims description 4
- IXWKBUKANTXHJH-UHFFFAOYSA-N 1-[5-chloro-2-methyl-4-(5-methyl-5,6-dihydro-1,4,2-dioxazin-3-yl)pyrazol-3-yl]sulfonyl-3-(4,6-dimethoxypyrimidin-2-yl)urea Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=C(Cl)C=2C=2OC(C)CON=2)C)=N1 IXWKBUKANTXHJH-UHFFFAOYSA-N 0.000 claims description 4
- 239000002794 2,4-DB Substances 0.000 claims description 4
- YOYAIZYFCNQIRF-UHFFFAOYSA-N 2,6-dichlorobenzonitrile Chemical compound ClC1=CC=CC(Cl)=C1C#N YOYAIZYFCNQIRF-UHFFFAOYSA-N 0.000 claims description 4
- KGKGSIUWJCAFPX-UHFFFAOYSA-N 2,6-dichlorothiobenzamide Chemical compound NC(=S)C1=C(Cl)C=CC=C1Cl KGKGSIUWJCAFPX-UHFFFAOYSA-N 0.000 claims description 4
- BDQWWOHKFDSADC-UHFFFAOYSA-N 2-(2,4-dichloro-3-methylphenoxy)-n-phenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C)OC1=CC=C(Cl)C(C)=C1Cl BDQWWOHKFDSADC-UHFFFAOYSA-N 0.000 claims description 4
- IUQJDHJVPLLKFL-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetate;dimethylazanium Chemical compound CNC.OC(=O)COC1=CC=C(Cl)C=C1Cl IUQJDHJVPLLKFL-UHFFFAOYSA-N 0.000 claims description 4
- FDMDZIBZKGXZPT-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)acetic acid;2-(2-hydroxyethylamino)ethanol Chemical compound OCCNCCO.OC(=O)COC1=CC=C(Cl)C=C1Cl FDMDZIBZKGXZPT-UHFFFAOYSA-N 0.000 claims description 4
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a composition comprising crystal of flumioxazin which shows a powder X-Ray diffraction 5 pattern having diffraction peaks with 20 values (0) shown in Table 1, said pattern being obtained by CuKa rays diffraction analysis, Table 1 20 value (0) 9.8 ±0.1 11.4 ±0.1 12.7 ±0.1 13.8 ±0.1 16.0 ±0.1 16.4 ±0.1 16.7 ±0.1 and one or more herbicidal compounds selected from the group 10 B-1, B-2, B-3, B-4, B-5, B-6, B-7, B-8, B-9, 3-10, B-11 and B-12 described in the specification. According to the present invention, a wide range of weeds can be controlled in a crop field, land under perennial crops, or non-crop land.
Description
The present invention relates to a composition comprising crystal of flumioxazin which shows a powder X-Ray diffraction pattern having diffraction peaks with 2Θ values (°) shown in Table 1, said pattern being obtained by CuKa rays diffraction analysis,
Table 1
and one or more herbicidal compounds selected from the group
B-l, B-2, B-3, B-4, B-5, B-6, B-7, B-8, B-9, B-10, B-ll andB-12 described in the specification.
According to the present invention, a wide range of weeds can be controlled in a crop field, land under perennial crops, or non-crop land.
Australian Patents Act 1990 - Regulation 3.2
2013267026 04 Dec 2013
ORIGINAL COMPLETE SPECIFICATION STANDARD PATENT
Invention Title Weed control composition
The following statement is a full description of this invention, including the best method of performing it known to me/us:1
2013267026 21 Mar 2018
BACKGROUND OF THE INVENTION
Field of the Invention [0001]
The present invention relates to a weed control composition.
Description of the Related Art [0002]
Many compounds are known as herbicides in order to control weeds. Also, flumioxazin is known as a herbicide.
PRIOR ART DOCUMENT [0003]
NON-PATENT DOCUMENTS
Non-patent Document 1: Crop Protection Handbook, vol. 97 (2011) Meister Publishing Company, ISBN: 1-892829-23-1) [0004]
SUMMARY OF THE INVENTION [0005]
In one or more aspects, the present invention provides a weed control composition having high herbicidal effect against weeds .
[0006]
The inventors of the present invention have la
2013267026 21 Mar 2018 found that a composition obtained by combining specified herbicides has a high herbicidal effect against weeds.
The present invention is as follows.
[0007] [1] A composition comprising crystal of flumioxazin which shows a powder X-Ray diffraction pattern having diffraction peaks with 2Θ values (°) shown in Table 1, said pattern being obtained by CuKo< rays diffraction analysis,
Table 1
and one or more herbicidal compounds selected from the group
B:
Group B:
B-l. Acetolactic acid synthase inhibitors;
B-2. Acetyl CoA carboxylase inhibitors;
B-3. Protoporphyrinogen IX oxidase inhibitors;
B-4 . 4-Hydroxyphenylpyrubic acid dioxygenase inhibitors;
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B-5. Phytoene desaturase inhibitors;
B-β. Photosystem II inhibitors;
B-7, Very-long-chain fatty acid synthesis inhibitors;
B-8. Tubulin synthesis inhibitors;
B-9. Auxin type herbicides;
B-10. Enolpyruvylshikimate phosphate synthase inhibitors;
B-ll. Glutamine synthetase inhibitors; and
B-12. Other herbicides.
[0008] [2] The weed control composition according to [1], wherein the compound of the group B is the following compound;
B-l. Acetolactic acid synthase inhibitors:
Pyrithiobac, pyrithiobac-sodium salt, pyriminobac, pyriminobac-methyl, bispyribac, bispyribac sodium salt, pyribenzoxira, pyrimisulfan, pyriftalid, triafamone, amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlorimuron, chlorimuron-ethyl, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, flupyrsulfuron methyl-sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazosulfuron, mesosulfuron, mesosulfuron-methyl, metazosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, primisulfuron-methyl, propyrisulfuron, pyrazosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron,
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2013267026 04 Dec 2013 sulfometuron-methyl, sulfosulfuron, trifloxysulfuron-sodium salt, trifloxysulfuron, chlorsulfuron, cinosulfuron, ethametsulfuron, ethametsulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, metsulfuron, metsulfuron-methyl, prosulfuron, thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, triflusulfuron, triflusulfuron-methyl, tritosulfuron, bencarbazone, flucarbazone, flucarbazone-sodium salt, ipfencarbazone, propoxycarbazone, propoxycarbazone-sodium salt, thiencarbazone, thiencarbazone-methyl, cloransulam, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam, pyroxsulam, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium salt, imazapic, imazapic-ammonium salt, imazapyr, imazapyr-isopropylammonium salt, imazaquin, imazaqu in-ammonium salt, imazethapyr, andimazethapyr-ammonium salt.
B-2. Acetyl CoA carboxylase inhibitors:
Clodinafop, clodinafop-propargyl, cyhalofop, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, metamifop, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P,
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2013267026 04 Dec 2013 quizalofop-P-ethyl, alloxydim, clethodim, sethoxydim, tepraloxydim, tralkoxydim, and pinoxaden.
B-3. Protoporphyrinogen IX oxidase inhibitors: Azafenidin, oxadiazone, oxadiargyl, carfentrazone, carfentrazone-ethyl, saflufenacil, cinidon, cinidon-ethyl, sulfentrazone, pyraclonil, pyraflufen, pyraflufen-ethyl, butafenacil, fluazolate, fluthiacet, fluthiacet-methyl, flufenpyr, flufenpyr-ethyl, flumiclorac, flumiclorac-pentyl, pentoxazone, oxyfluorfen, acifluorfen, aclonifen, chlorriethoxynil, chloronitrofen, nitrofen, bifenox, fluoroglycofene, fluoroglycofene-ethyl, fomesafen, fomesafen-sodium salt, lactofen, and compounds represented by the formula (I):
CHS
B-4. 4-Hydroxyphenylpyrubic acid dioxygenase inhibitors:
Benzobicyclon, bicyclopyrone, mesotrione, sulcotrione, tefuryltrione, tembotrione, isoxachlorotole, isoxaflutole, benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, and topramezone.
B-5. Phytoene desaturase inhibitors:
Diflufenican, picolinafen, beflubutamid, norflurazon, fluridone, flurochloridone, and flurtamone.
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B-6. Photosystem II inhibitors:
Ioxynil, ioxynil octanoate, bentazone, pyridate, bromoxynil, bromoxynil octanoate, chlorotoluron, dimefuron, diuron, linuron, fluometuron, isoproturon, isouron, tebuthiuron, benzthiazuron, methabenzthiazuron, propanil, metobromuron, metoxuron, monolinuron, siduron, simazine, atrazine, propazine, cyanazine, ametryne, simetryn, dimethametryn, prometryn, terbumeton, terbuthylazine, terbutryn, trietazine, hexazinone, metamitron, metribuzin, amicarbazone, bromacil, lenacil, terbacil, chloridazon, desmedipham, and phenmedipham.
B-7. Very-long-chain fatty acid synthase inhibitors:
Propachlor, metazachlor, alachlor, acetochlor, metolachlor, S-metolachlor, butachlor, pretilachlor, thenylchlor, indanofan, cafenstrole, fentrazamide, dimethenamid, dimethenamid-P, mefenacet, pyroxasulfone, fenoxasulfone, naproanilide, anilofos, and flufenacet.
B-8. Tubulin synthesis inhibitors:
Trifluralin, pendimethalin, ethafluralin, benfluralin, prodiamine, indaziflam, triaziflam, butamifos, dithiopyr, and thiazopyr.
B-9. Auxin type herbicides:
Dicamba and a salt thereof (diglycolamine salt, dimethylammonium salt, isopropylammoniumsalt, potassium salt, sodium salt, and choline salt), 2, 4-D and a salt or ester thereof
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2013267026 04 Dec 2013 (butotyl ester, dimethylammonium, salt, diolamine salt, ethylhexyl ester, isooctyl ester, isopropylammonium salt, sodium salt, and triisopropanolamine salt), 2,4-DB and a salt or ester thereof (dimethylammonium salt, isooctyl ester, and choline salt), MCPAanda salt or ester thereof (dimethylammonium salt, 2-ethylhexylester, isooctyl ester, sodium salt, and choline salt), MCPB, mecoprop and a salt or ester thereof (dimethylammonium salt, diolamine salt, ethadyl ester,
2-ethylhexylester, isooctyl ester, methyl ester, potassiumsalt, 10 sodium salt, tololamine salt, and choline salt) , mecoprop-P and a salt or ester thereof (dimethylammonium salt, 2-ethylhexyl ester, isobutyl salt, potassium salt, and choline salt), dichlorprop and a salt or ester thereof (butotyl ester, dimethylammonium salt, 2-ethylhexyl ester, isooctyl ester, methyl ester, potassium salt, sodium salt, and choline salt), dichlorprop-P, dichlorprop-P dimethylammonium, triclopyr and a salt or ester thereof (butotyl ester and triethylammonium salt), fluroxypyr, fluroxypyr-meptyl, picloram and a salt thereof (potassium salt, triisopanolammonium salt, and choline salt) , quinclorac, quinmerac, aminopyralid and a salt thereof (potassium salt, triisopanolammonium salt, and choline salt) , clopyralid and a salt thereof (olamine salt, potassium salt, triethylammonium salt, and choline salt), and clomeprop.
B-10. Enolpyruvylshikimate phosphate synthase inhibitors:
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Glyphosate, glyphosate-isopropylamine salt, glyphosate-trimesium salt, glyphosate-ammonium salt, glyphosate-diammonium, salt, glyphosate-sodium salt, glyphosate-potassium salt, and glyphosate-guanidine salt.
B-ll. Glutamine synthetase inhibitors:
Glufosinate, glufosinate-ammonium salt, glufosinate-P, glufosinate-P-sodium salt, and bialaphos.
B-12. Other herbicides.
Isoxaben, dichlobenil, methiozolin, diallate, butyrate, 10 triallate, chlorpropham, asulam, phenisopham, benthiocarb, molinate, esprocarb, pyributicarb, prosulfocarb, orbencarb,
EPTC, dimepiperate, Swep, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium, difenoxuron, methyl dymron, bromobutide, dymron, cumyluron, diflufenzopyr, etobenzanid, tridiphane, amitrole, fenchlorazole, clomazone, maleic hydrazide, oxaziclomefone, cinmethylin, benfuresate, ACN, dalapon, chlorthiamid, flupoxam, bensulide, paraquat, paraquat-dichloride, diquat, and diquat-dibromide.
[0009] [3] The weed control composition according to [1], wherein the compound of the group B is a compound selected from a glyphosate isopropylamine salt, a glyphosate-trimesium salt, a glyphosate-ammonium salt, a glyphosate-diammonium salt, a glyphosate-sodium salt, a glyphosate-potassium salt, and a
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2013267026 04 Dec 2013 glyphosate-guanidine salt.
[0010] [4] The weed control composition according to [1], wherein the compound of the group B is a glufosinate-ammonium salt.
[0011] [5] The weed control composition according to [1] , wherein the compound of the group B is chlorimuron-ethyl.
[0012] [6] The weed control composition according to [1], wherein 10 the compound of the group B is cloransulam-methyl.
[0013} [7] The weed control composition according to [1], wherein the compound of the group B is pyroxasulfone.
[0014] [8] The weed control composition according to [1], wherein the compound of the group B is a compound selected from dicamba, adicaraba-diglycolamine salt, a dicamba-dimethylammonium salt, a dicamba-isopropylammonium salt, a dicamba-potasslum salt, a dicamba-sodium salt, and a dicamba-choline salt.
[0015] [9] The weed control composition according to [1], wherein the compound of the group B is a compound selected from a 2,4-D, 2,4-D butotyl ester, a 2,4-D dimethylammonium salt, a 2,4-D diolamine salt, a 2,4-Dethylhexylester, a2,4-Disooctyl ester, a 2,4-D isopropylammonium salt, a 2, 4-D sodium salt, and a 2, 4-D
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2013267026 04 Dec 2013 triisopropanolammonium salt.
[0016] [10] The weed control composition according to [1] , wherein the compound of the group B is an imazethapyr-ammonium salt.
[0017] [11] The weed control composition according to [1], wherein the compound of the group B is metribuzin.
[0018] [12] The weedcontrol composition according to [1], wherein the compound of the group B is isoxaflntole.
[0019] [13] Theweedcontrolcompositionaccordingto [1], wherein the compound of the group B is mesotrione.
[0020] [14] The weed control composition according to [1], wherein the compound of the group B is tembotrione.
[0021] [15] The weedcontrol composition according to [1] , wherein the compound of the group B is ametryne.
[0022] [16] Amethod of controlling weeds, the method comprising applying an effective amount of flumioxazin constituted of crystals with crystal forms having diffraction peaks at the angles 20 (degrees) shown in Table 1 below in a powder X-ray diffraction pattern using Cu-Kct rays and one or more herbicidal
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2013267026 04 Dec 2013 compounds selected from the above group B to soil where the weeds are grown or to be grown, or weeds.
[0023] [17] The method according to [16], wherein the compound 5 of the group B is the following compound:
B-l. Acetolactic acid synthase inhibitors: Pyrithiobac, pyrithiobac-sodium salt, pyriminobac, pyriminobac-methyl, bispyribac, bispyribac sodium salt, pyribenzoxim, pyrimisulfan, pyriftalid, triafamone, amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlorimuron, chlorimuron-ethyl, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, f lupyrsulfuron, flupyrsulfuron methyl-sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazosulfuron, mesosulfuron, mesosulfuron-methyl, metazosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, primisulfuron-methyl, propyrisulfuron, pyrazosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron, sulfometuron-methyl, sulfosulfuron, trifloxysulfuron-sodium salt, trifloxysulfuron, chlorsulfuron, cinosulfuron, ethametsulfuron, ethametsulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, metsulfuron, metsulfuron-methyl, prosulfuron, thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, triflusulfuron,
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2013267026 04 Dec 2013 triflusulfuron-methyl, tritosulfuron, bencarbazone, flucarbazone, flucarbazone-sodium salt, ipfencarbazone, propoxycarbazone, propoxycarbazone-sodium salt, thiencarbazone, thiencarbazone-methyl, cloransulam, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam, pyroxsulam, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium salt, imazapic, imazapic-ammonium salt, imazapyr, imazapyr-isopropylammonium salt, imazaquin, imazaquin-ammoniumsalt, imazethapyr, andimazethapyr-ammonium salt.
B-2. Acetyl CoA carboxylase inhibitors:
Clodinafop, clodinafop-propargyl, cyhalofop, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, metamifop, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, alloxydim, clethodim, sethoxydim, tepraloxydim, tralkoxydim, and pinoxaden.
B-3. Protoporphyrinogen IX oxidase inhibitors:
Azafenidin, oxadiazone, oxadiargyl, carfentrazone, carfentrazone-ethyl, saflufenacil, cinidon, cinidon-ethyl, sulfentrazone, pyraclonil, pyraflufen, pyraflufen-ethyl, butafenacil, fluazolate, fluthiacet, fluthiacet-methyl,
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2013267026 04 Dec 2013 flufenpyr, flufenpyr-ethyl, flumiclorac, flumiclorac-pentyl, pentoxazone, oxyfluorfen, acifluorfen, aclonifen, chlomethoxynil, chloronitrofen, nitrofen, bifenox, fluoroglycofene, fluoroglycofene-ethyl, fomesafen, fomesafen-sodium salt, lactofen, and compounds represented by the formula (I):
B-4. 4-Hydroxyphenylpyrubic acid dioxygenase inhibitors:
Benzobicyclon, bicyclopyrone, mesotrione, sulcotrione, tefuryltrione, tembotrione, isoxachlorotole, isoxaflutole, benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, and topramezone.
B-5. Phytoene desaturase inhibitors:
Diflufenican, picolinafen, beflubutamid, norflurazon, 15 fluridone, flurochloridone, and flurtamone.
B-6. Photosystem II inhibitors:
Ioxynil, ioxynil octanoate, bentazone, pyridate, bromoxynil, bromoxynil octanoate, chlorotoluron, dimefuron, diuron, linuron, fluometuron, isoproturon, isouron, tebuthiuron, benzthiazuron, methabenzthiazuron, propanil, metobromuron, metoxuron, monolinuron, siduron, simazine, atrazine, propazine, cyanazine, ametryne, simetryn,
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2013267026 04 Dec 2013 dimethametryn, prometryn, terbumeton, terbuthylazine, terbutryn, trietazine, hexazinone, metamitron, metribuzin, amicarbazone, bromacil, lenacil, terbacil, chloridazon, desmedipham, and phenmedipham.
B-7. Very-long-chain fatty acid synthase inhibitors:
Propachlor, metazachlor, alachlor, acetochlor, metolachlor, S-metolachlor, butachlor, pretilachlor, thenylchlor, indanofan, cafenstrole, fentrazamide, dimethenamid, dimethenamid-P, mefenacet, pyroxasulfone, fenoxasulfone, naproanilide, anilofos, and flufenacet.
B-8. Tubulin synthesis inhibitors:
Trifluralin, pendimethalin, ethafluralin, benfluralin, prodiamine, indaziflara., triaziflam, butamifos, dithiopyr, and thiazopyr.
B-9, Auxin type herbicides:
Dicamba and a salt thereof (diglycolamine salt, dimethylammonium salt, isopropylammoniumsalt, potassium salt, sodium salt, and choline salt), 2, 4-D and a salt or ester thereof (butotyl ester, dimethylammonium salt, diolamine salt, ethylhexyl ester, isooctyl ester, isopropylammonium salt, sodium salt, and triisopropanolamine salt), 2,4-DB and a salt or ester thereof (dimethylammonium salt, isooctyl ester, and choline salt), MCPAand a salt or ester thereof (dimethylammonium salt, 2-ethylhexylester, isooctyl ester, sodium salt, and choline salt), MCPB, mecoprop and a salt or ester thereof
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2013267026 04 Dec 2013 (dimethylammonium salt, diolamine salt, ethadyl ester, 2-ethylhexyl ester, isooctyl ester, methyl ester, potassium salt, sodium salt, tololamine salt, and choline salt) , mecoprop-P and a salt or ester thereof (dimethylammonium salt, 2-ethylhexyl 5 ester, isobutyl salt, potassium salt, and choline salt), dichlorprop and a salt or ester thereof (butotyl ester, dimethylammonium salt, 2-ethylhexyl ester, isooctyl ester, methyl ester, potassium salt, sodium salt, and choline salt), dichlorprop-P, dichlorprop-P dimethylammonium, triclopyr and 10 a salt or ester thereof (butotyl ester and triethylammonium salt), fluroxypyr, fluroxypyr-meptyl, picloram and a salt thereof (potassium salt, triisopanolammonium salt, and choline salt), quinclorac, quinmerac, aminopyralid and a salt thereof (potassium salt, triisopanolammonium salt, and choline salt) , clopyralid and a salt thereof (olamine salt, potassium salt, triethylammonium salt, and choline salt), and clomeprop.
B-10. Enolpyruvylshikimate phosphate synthase inhibitors: .
Glyphosate, glyphosate-isopropylamine salt, glyphosate-trimesium salt, glyphosate-ammonium salt, glyphosate-diammonium salt, glyphosate-sodium salt, glyphosate-potassium salt, and glyphosate-guanidine salt.
B-ll. Glutamine synthetase inhibitors:
Glufosinate, glufosinate-ammonium salt, glufosinate-P, glufosinate-P~sodium salt, and bialaphos.
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B-12. Other herbicides.
Isoxaben, dichlobenil, methiozolin, diallate, butyrate, triallate, chlorpropham, asulam, phenisopham, benthiocarb, molinate, esprocarb, pyributicarb, prosulfocarb, orbencarb,
EPTC, dimepiperate, Swep, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium, difenoxuron, methyl dymron, bromobutide, dymron, cumyluron, diflufenzopyr, etobenzanid, tridiphane, amitrole, fenchlorazole, clomazone, maleic hydrazide, oxaziclomefone, cinmethylin, benfuresate, ACN, dalapon, chlorthiamid, flupoxam, bensulide, paraquat, paraquat-dichloride, diquat, and diquat-dibromide.
[0024] [18] The method according to [16], wherein the compound of the group B is a compound selected from, a glyphosate isopropylamine salt, a glyphosate-trimesium salt, a glyphosate-ammonium salt, a glyphosate-diammonium salt, a glyphosate-sodium salt, a glyphosate-potassium salt, and a glyphosate-guanidine salt.
[0025] [19] The method according to [16], wherein the compound of the group B is a glufosinate-ammonium salt.
[0026] [20] The method according to [16], wherein the compound 25 of the group B is chlorimuron-ethyl.
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S34182 [0027] [21] The method according to [16], wherein the compound of the group B is cloransulam-methyl.
[0028] [22] The method according to [16], wherein the compound of the group B is pyroxasulfone.
[0029] [23] The method according to [16], wherein the compound of the group B is a compound selected from dicamba, a dicamba-diglycolamine salt, a dicamba-dimethylammonium salt, a dicamba-isopropylammonium salt, a dicamba-potassium salt, a dicamba-sodium salt, and a dicamba--choline salt.
[0030] [24] The method according to [16], wherein the compound of the group B is a compound selected from a 2,4-D, 2,4-Dbutotyl ester, a 2, 4-D dimethylammonium salt, a 2,4-D diolamine salt, a 2,4-D ethylhexyl ester, a 2,4-D isooctyl ester, a 2,4-D isopropylammonium salt, a 2,4-D sodium salt, and a 2,4-D triisopropanolaramonium salt.
[0031] [25] The method according to [16], wherein the compound of the group B is an imazethapyr-ammonium salt.
[0032] [26] The method according to [16], wherein the compound 25 of the group B is metribuzin.
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2013267026 04 Dec 2013 [0033] [27] The method according to [16], wherein the compound of the group B is isoxaflutole.
[0034] [28] The method according to [16], wherein the compound of the group B is mesotrione.
[0035] [29] The method according to [16], wherein the compound of the group B is tembotrione.
[0036] [30] The method according to [16] of the group B is ametryne.
wherein the compound [0037] [31] The method according to any one of [16] to [30], which is a method of controlling weeds in a crop field, land under perennial crops, or non-crop land.
[0038] [32] The method according to [31], wherein the crop field is a field for soybean, peanut, corn, cotton, wheat, or sugarcane.
[0039] [33] The method according to [31], wherein the land under perennial crops is an orchard.
[0040]
EFFECT OF THE INVENTION [0041]
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A wide range of weeds can be controlled by the use of the weed control composition of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS [0042]
A weed control composition of the present invention (hereinafter referred to as the composition of the present invention) contains crystal of flumioxazin which shows a powder X-Ray dif fractionpatternhavingdif fractionpeaks with 20 values (°) shown in Table 1 above (hereinafter referred to as A-type crystal flumioxazin) and one or more specific herbicidal compounds as effective components.
[0043]
The A-type crystal flumioxazin used in the composition of the present invention may be prepared by the methods described in Examples and modified methods thereof. A flumioxazin solution or suspension may be used as a starting material to produce the A-type crystal flumioxazin. Also, a solution or suspension of a synthetic reaction crude product containing flumioxazin may be used. A seed crystal may be added in the crystallization and in this case, it ispreferable to use a crystal with the crystal form to be prepared. The amount of the seed crystals to be added is preferably 0.0005 parts by weight to 0.02 parts by weight, and more preferably 0.001 parts by weight to 0.01 parts by weight based on 1 part by weight of flumioxazin.
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S34182 [0044]
TheA-typecrystalflumioxazinmaybe isolated, for example, by filtration, centrifugation,· or gradient method. This A-type crystal flumioxazinmaybe washed with a proper solvent according to the need. Also, the obtained A-type crystal flumioxazin can be improved in purity and quality by recrystallization or slurry purification. Crystals of a solvate may be converted into crystals of a non-solvate by drying with heating under reduced pressure. The degree of dryness of the crystal maybe determined by analytical means such as gas chromatography. Also, the polymorph form purity of the crystal may be determined by subjecting the crystal to powder X-ray diffraction measurement to analyze the presence or absence and height of a diffraction peak specific to the solvate crystal. The A-type crystal flumioxazin is a solvate or non-solvate. When a specific hydrophilic organic solvent is used as a solvent for crystallization, there is the case where the A-type crystal flumioxazin forms a solvate. Anon-solvate is obtainedby drying the solvate with heating under reduced pressure.
[0045]
In the composition of the present invention, one or more specific herbicidal compounds selected from the group B are used in combination with the A-type crystal flumioxazin.
Group B: ·
B-l. Acetolactic acid synthase inhibitors;
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B-2. Acetyl CoA carboxylase inhibitors;
B-3. Protoporphyrinogen IX oxidase inhibitors;
B-4. 4-Hydroxyphenylpyrubic acid dioxygenase inhibitors;
B-5. Phytoene desaturase inhibitors;
B-6. Photosystem II inhibitors;
B-7. Very-long-chain fatty acid synthase inhibitors;
B-8. Tubulin synthesis inhibitors;
B-9. Auxin type herbicides;
B-10. Enolpyruvylshikimate phosphate synthase inhibitors;
B-ll. Glutamine synthetase inhibitors; and
B-12. Other herbicides.
[0046]
Specific examples of the herbicidal compounds of the group
B include the followings:
[0047]
B-l. Acetolactic acid synthase inhibitors: Pyrithiobac, pyrithiobac-sodium salt, pyriminobac, pyriminobac-methyl, bispyribac, bispyribac sodium salt, pyribenzoxim, pyrimisulfan, pyriftalid, triafamone, amidosulfuron, azimsulfuron, bensulfuron, bensul fur on-methyl, chlorimuron, chlorimuron-ethyl, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, flupyrsulfuron methyl-sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazosulfuron,
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2013267026 04 Dec 2013 mesosulfuron, mesosulfuron-methyl, metazosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, primisulfuron-methyl, propyrisulfuron, pyrazosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron, sulfometuron-raethyl, sulfosulfuron, trifloxysulfuron-sodium salt, trifloxysulfuron, chlorsulfuron, cinosulfuron, ethametsulfuron, ethametsulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, metsulfuron, metsulfuron-methyl, prosulfuron, thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, triflusulfuron, triflusulfuron-methyl,tritosulfuron, bencarbazone, flucarbazone, flucarbazone-sodium salt, ipfencarbazone, propoxycarbazone, propoxycarbazone-sodium salt, thiencarbazone, thiencarbazone-methyl, cloransulam, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam, pyroxsulam, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium salt, imazapic, imazapic-ammonium salt, imazapyr, imazapyr-isopropylammonium salt, imazaquin, imazaquin-ammoniumsalt, imazethapyr, andimazethapyr-ammonium salt.
[0048]
B-2. Acetyl CoA carboxylase inhibitors:
Clodinafop, clodinafop-propargyl, cyhalofop,
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2013267026 04 Dec 2013 cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, metamifop, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, alloxydim, clethodim, sethoxydim, tepraloxydim, tralkoxydim, and pinoxaden.
[0049]
B-3. Protoporphyrinogen IX oxidase inhibitors:
Azafenidin, oxadiazone, oxadiargyl, carfentrazone, carfentrazone-ethyl, saflufenacil, cinidon, cinidon-ethyl, sulfentrazone, pyraclonil, pyraflufen, pyraflufen-ethyl, butafenacil, fluazolate, fluthiacet, fluthiacet-methyl, flufenpyr, flufenpyr-ethyl, flumiclorac, flumiclorac-pentyl, pentoxazone, oxyfluorfen, acifluorfen, aclonifen, chlomethoxynil, chloronitrofen, nitrofen, bifenox, fluoroglycofene, fluoroglycofene-ethyl, fomesafen, fomesafen-sodium salt, lactofen, and compounds represented by the formula (I):
0 CHs .
B-4. 4-Hydroxyphenylpyrubic acid dioxygenase inhibitors: Benzobicyclon, bicyclopyrone, mesotrione, sulcotrione,
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2013267026 04 Dec 2013 tefuryltrione, tembotrione, isoxachlorotole, isoxaflutole, benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, and topramezone.
[0050]
B-5. Phytoene desaturase inhibitors:
Diflufenican, picolinafen, beflubutamid, norflurazon, fluridone, flurochloridone, and flurtamone.
[0051]
B-6. Photosystem II inhibitors:
Ioxynil, ioxynil octanoate, bentazone, pyridate, bromoxynil, bromoxynil octanoate, chlorotoluron, dimefuron, diuron, linuron, fluometuron, isoproturon, isouron, tebuthiuron, benzthiazuron, raethabenzthiazuron, propanil, metobromuron, metoxuron, monolinuron, siduron, simazine, atrazine, propazine, cyanazine, ametryne, simetryn, dimethametryn, prometryn, terbumeton, terbuthylazine, terbutryn, trietazine, hexazinone, metamitron, metribuzin, amicarbazone, bromacil, lenacil, terbacil, chloridazon, desmedipham, and phenmedipham.
[0052] ·
B-7. Very-long-chain fatty acid synthase inhibitors:
Propachlor, metazachlor, alachlor, acetochlor, metolachlor, S-metolachlor, butachlor, pretilachlor, thenylchlor, indanofan, cafenstrole, fentrazamide, dimethenamid, dimethenamid-P, mefenacet, pyroxasulfone,
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2013267026 04 Dec 2013 fenoxasulfone, naproanilide, anilofos, and flufenacet.
[0053]
B-8. Tubulin synthesis inhibitors:
Trifluralin, pendimethalin, ethafluralin, benfluralin, prodiamine, indaziflam, triaziflam, butamifos, dithiopyr, and thiazopyr.
[0054]
B-9. Auxin type herbicides:
Dicamba and a salt thereof (diglycolamine salt, dimethyl ammonium salt, isopropylammonium salt, potassium salt, sodium salt, and choline salt) , 2,4-D and a salt or ester thereof (butotyl ester, dimethylammonium salt, diolamine salt, ethylhexyl ester, isooctyl ester, isopropylammonium salt, sodium salt, and triisopropanolamine salt), 2,4-DB and a salt or ester thereof (dimethylammonium salt, isooctyl ester, and choline salt) , MCPA and a salt or ester thereof (dimethylammonium salt, 2-ethylhexylester, isooctyl ester, sodium salt, and choline salt), MCPB, mecoprop and a salt or ester thereof (dimethylammonium salt, diolamine salt, ethadyl ester,
2-ethylhexylester, isooctyl ester, methyl ester, potassiumsalt, sodium salt, tololamine salt, and choline salt) , mecoprop-P and a salt or ester thereof (dimethylammonium salt, 2-ethylhexyl ester, isobutyl salt, potassium salt, and choline salt), dichlorprop and a salt or ester thereof (butotyl ester, dimethylammonium salt, 2-ethylhexyl ester, isooctyl ester,
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2013267026 04 Dec 2013 methyl ester, potassium salt, sodium salt, and choline salt) , dichlorprop-P, dichlorprop-P dimethylammonium, triclopyr and a salt or ester thereof (butotyl ester and triethylammonium salt), fluroxypyr, fluroxypyr-meptyl, picloram and a salt thereof (potassiumsalt, triisopanolammonium salt, and choline salt), quinclorac, quinmerac, aminopyralid and a salt thereof (potassium salt, triisopanolammonium salt, and choline salt), clopyralid and a salt thereof (olamine salt, potassium salt, triethylammonium salt, and choline salt), and clomeprop.
[0055]
B-10. Enolpyruvylshikimate phosphate synthase inhibitors :
Glyphosate, glyphosate-isopropylamine salt, glyphosate-trimesium salt, glyphosate-ammonium salt, glyphosate-diammonium salt, glyphosate-sodium salt, glyphosate-potassium salt, and glyphosate-guanidine salt.
[0056]
B-ll. Glutamine synthetase inhibitors:
Glufosinate, glufosinate-ammonium salt, glufosinate-P, glufosinate-P-sodium salt, and bialaphos.
[0057]
B-12. Other herbicides.
Isoxaben, dichlobenil, methiozolin, diallate, butyrate, triallate, chlorpropham, asulam, phenisopham, benthiocarb, molinate, esprocarb, pyributicarb, prosulfocarb, orbencarb,
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EPTC, dimepiperate, Swep, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium, difenoxuron, methyl dymron, bromobutide, dymron, cumyluron, diflufenzopyr, etobenzanid, tridiphane, amitrole, fenchlorazole, clomazone, maleic hydrazide, oxaziclomefone, cinmethylin, benfuresate, ACN, dalapon, chlorthiamid, flupoxam, bensulide, paraquat, paraquat-dichloride, diquat, and diquat-dibromide.
[0058]
The compounds given as examples of the compound of the group B are compounds described in Non-patent Documents 1 and 2 and Patent Documents 3 to 5, and may be produced by publicly known production methods, and/or are commercially available as preparations containing the compounds.
[0059]
In the composition of the present invention, as the compound to be combined with the A-type crystal flumioxazin and selected from the group B, particularly, a glyphosate-isopropylamine salt, a glyphosate-trimesium salt, 20 a glyphosate-ammonium salt, a glyphosate-diammonium salt, a glyphosate-sodium salt, a glyphosate-potassium salt, a glyphosate-guanidine salt, a glufosinate-ammonium salt, chlorimuron-ethyl, cloransulam-methyl, pyroxasulfone, an imazethapyr-ammonium salt, metribuzin, 2, 4-D, a 2,4-D butotyl ester, a 2, 4-D dimethyl ammonium salt, a 2, 4-D diolamine salt,
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2013267026 04 Dec 2013 a 2,4-D ethylhexyl ester, a 2,4-D isooctyl ester, a 2,4-D isopropylammonium salt, a 2,4-D sodium salt, a 2,4-D triisopropanolamine salt, dicamba, a dicamba-diglycolamine salt, a dicamba-dimethylammonium salt, a dicamba-isopropylammonium salt, a dicamba-potassium salt, a dicamba-sodium salt, a dicamba-choline salt, mesotrione, tembotrione, isoxaflutole, and ametryne are preferable.
[0060]
In the composition of the present invention, a safener 10 may be further added to the combination of the A-type crystal flumioxazin and the compound selected from the group B for use.
Examples of the safener include the following compounds:
Benoxacor, cloquintocet, cloquintocet-mexyl, cyometrinil, cyprosulfamide, dichlormid, dicyclonon, dietholate, fenchlorazole, fenchlorazole-ethyl, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, isoxadifen-ethyl, mefenpyr, mefenpyr-diethyl, mephenate, naphthalic anhydride, and oxabetrinil.
[0061]
Those given specifically below are more preferable as the composition of the present invention:
Combination of A-type crystal flumioxazin and glyphosate-isopropylamine salt;
Combination of A-type crystal flumioxazin and 25 glyphosate-trimesium salt;
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Combination of A-type crystal flumioxazin and glyphosate-ammonium salt;
Combination of A-type crystal flumioxazin and glyphosate-diammonium salt;
Combination of A-type crystal flumioxazin and glyphosate-sodium salt;
Combination of Ά-type crystal flumioxazin and glyphosate-potassium salt;
Combination of A-type crystal flumioxazin and 10 glyphosate-guanidine salt;
Combination of A-type crystal flumioxazin and glufosinate-ammonium salt;
Combination of A-type crystal flumioxazin and chlorimuron-ethyl;
Combination of A-type crystal flumioxazin and cloransulam-methyl;
Combination of A-type crystal flumioxazin, chlorimuron-ethyl and pyroxasulfone;
Combination of A-type crystal flumioxazin and pyroxasulfone;
Combination of A-type crystal flumioxazin and imazethapyr-ammonium salt;
Combination of A-type crystal flumioxazin and metribuzin; Combination of A-type crystal flumioxazin and 2, 4-D;
Combination of A-type crystal flumioxazin and 2, 4-D
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2013267026 04 Dec 2013 butotyl ester;
Combination of A-type dimethylammonium salt;
Combination of A-type diolamine salt;
Combination of A-type ethylhexyl ester;
Combination of A-type isooctyl ester;
Combination of A-type isopropylammonium salt;
crystal | flumioxazin | and | 2, 4-D |
crystal | flumioxazin | and | 2, 4-D |
crystal | flumioxazin | and | 2, 4-D |
crystal | flumioxazin | and | 2, 4-D |
crystal | flumioxazin | and | 2, 4-D |
Combination of A-type crystal flumicxazin and 2,4-D sodium salt;
Combination of A-type crystal triisopropanolamine salt;
Combination of A-type crystal
Combination of A-type crystal dicamba-diglycolamine salt;
Combination of A-type crystal dicamba-dimethylammonium salt;
Combination of A-type crystal dicamba-isopropylammonium salt;
Combination of A-type crystal dicamba-potassium salt;
Combination of A-type crystal flumioxazin and 2, 4-D flumioxazin and dicamba;
flumioxazin and flumioxazin and flumioxazin and flumioxazin and flumioxazin and
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2013267026 04 Dec 2013 dicamba-sodium salt;
Combination of A-type crystal flumioxazin and dicamba-choline salt;
Combination of A-type crystal flumioxazin, dicamba, and 5 isoxadifen-ethyl;
Combination of A-type crystal flumioxazin, dicamba-diglycolamine salt, and isoxadifen-ethyl;
Combination of A-type crystal flumioxazin, dicamba-dimethylammonium salt, and isoxadifen-ethyl;
Combination of A-type crystal flumioxazin, dicamba-isopropylammonium salt, and isoxadifen-ethyl; Combination of A-type crystal flumioxazin, dicaraba-potassiura salt, and isoxadifen-ethyl;
Combination of A-type crystal flumioxazin, dicamba-sodium salt, and isoxadifen-ethyl;
Combination of A-type crystal flumioxazin, dicamba-choline salt, and isoxadifen-ethyl;
Combination of A-type crystal flumioxazin and mesotrione; Combination of A-type crystal flumioxazin and tembotrione;
Combination of A-type crystal flumioxazin and isoxaflutole;
Combination of A-type crystal flumioxazin and ametryne; Combination of A-type crystal flumioxazin, isoxaf lutole, and cyprosulfamide;
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Combination of A-type crystal flumioxazin, tembotrione, and isoxadifen;
Combination of A-type crystal flumioxazin and saflufenacil;
Combination of A-type crystal flumioxazin, saflufenacil, and glyphosate-isopropylamine salt;
Combination of A-type crystal flumioxazin, saflufenacil, and glyphosate-potassium salt; and
Combination of A-type crystal flumioxazin, saflufenacil, and glyphosate-guanidine salt.
[0062]
The composition of the present invention has herbicidal effect against a wide range of weeds, and can control a wide range of weeds efficiently in a crop field, land under perennial crops, or non-crop land where usual tillage cultivation or non-tillage cultivation is carried out.
[0063]
Examples of the crop field in the present invention include fields for food crops such as soybean, corn, cotton, wheat, barley, rye, triticale, rice, peanut, commonbean, limabean, azukibean, cowpeas, mung bean, black lentil, scarlet runner bean, vigna umbellate, moth bean, tepary bean, broad bean, pea, garbanzo bean, lentil, lupine, pigeon pea, and potato; forage crops such as sorghum, oat, and alfalfa; industrial crops such as sugar beet, sunflower, rapeseed, and sugar cane; and garden crops
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2013267026 04 Dec 2013 including vegetables. Examples of the vegetables to which the present invention is applied include Solanaceae vegetables (for example, eggplant, tomato, green pepper, bell pepper, and hot pepper); Cucurbitaceae vegetables (for example, cucumber, pumpkin, zucchini, watermelon, and melon); Cruciferous vegetables (for example, Japanese radish,turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, brown mustard, broccoli, and cauliflower); Compositae vegetables (for example, burdock, garland chrysanthemum, artichoke, and lettuce); Liliaceae vegetables (for example, Welshonion, onion, garlic, asparagus); XJmbelliferae vegetables (carrot, parsley, celery, and parsnip) ; Chenopodiaceae vegetables (for example, spinach and Swiss chard); Labiatae vegetables (for example, Japanese mint, mint, basil, and lavender) ; strawberry; sweet potato; yam; and aroid.
[0064]
Also, the crop fields in the present invention include fields for cultivating so-called biomass crops such as Jatropha curcas, switchglass, Miscanthus, Arundo, reed canarygrass, bluestem, Erianthus, napier grass, and Spartina, used to produce 20 oil and fats or alcohols for fuels used in heat engines.
C 0065]
The composition of the present invention is particularly applied as a method efficiently controlling weeds in fields for cultivating soybean, peanut, corn, cotton, wheat, or sugarcane among the above crop fields.
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S34182 [0066]
When the composition of the present invention is applied to a field for sugarcane, stem fragments cut so as to have one stalk may be used as the stem fragment of sugar cane, or stem fragments having a size of 2 cm to 15 cm may be used in the cultivation of sugar cane. Sugar cane cultivationmethods using such stem fragments are publicly known (W009/000398, W009/000399, W009/000400, W009/000401, andW009/000402) and carried out under the brand name of Plene (trademark).
[0067]
Examples of the land under perennial crops in the present invention include orchards, tea gardens, mulberry gardens, coffee plantations, banana gardens, coconut gardens, flower/tree gardens, flower/tree fields, seeding fields, breeding farms, woodlands, and garden parks. Examples of fruit trees in the present invention include kernel fruits (for example, apples, European pears, Japanese pears, Chinese quince, and Quinces), stone fruits (for example, peaches, plums, nectarines, Japanese apricots, cherries, apricots, and prunes), citruses (Citrus unshiu, oranges, lemons, limes, and grapefruits), nut trees (for example, Japanese chest nuts, walnuts, hazel nuts, almonds, pistachios, cashew nuts, and macadamia nuts), berry fruits (for example, blueberries, cranberries, blackberries, and raspberries), grapes, permissions, olives, and loquats.
[0068]
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The composition of the present invention is applied as a method for efficiently controlling weeds, particularly, in orchards among the above lands under perennial crops.
[0069]
Examples of the non-crop lands in the present invention include playgrounds, vacant lands, railroad sides, parks, car parks, roadsides, riverbeds, areas under power cables, housing sites, and sites for factories.
[0070]
In the present invention, any type of crop may be used as the crops cultivated in crop field without any particular limitation insofar as it is a variety usually cultivated as crops .
This variety of plants includes plants to which resistance to protoporphyrinogen IX oxidase inhibitors such as flumioxazin;
4-hydroxyphenylpyrubic acid dioxygenase inhibitors such as isoxaflutole; acetolactic acid synthase inhibitors such as imazethapyr and thifensulfuron-methyl; acetyl-CoA carboxylase inhibitors such as sethoxydim;
5-enolpyruvylshikimate-3-phosphoric acid synthase inhibitors such as glyphosate; glutamine synthetase inhibitors such as glufosinate; auxin type herbicides such as 2,4-D and dicamba; and herbicides such as bromoxinyl are imparted by classical breeding methods or genetic modification technologies, [0071]
As examples of crops to which resistance has been imparted
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2013267026 04 Dec 2013 by classical breeding methods, corn resistant to imidazolinone type acetolactic acid synthase inhibitory herbicides such as imazethapyr is given and has already been commercially available under the trade name of Clearfield (trademark) . Examples of such crops include STS soybeans resistant to sulfonylurea type acetolactic acid synthase inhibitory herbicides such as thifensulfuron-methyl. Similarly, examples of a plant to which resistance to an acetyl CoA carboxylase inhibitor such as trione oxime-based or aryloxyphenoxypropionic acid-based herbicide has been imparted by classical breeding methods include SR corn.
Examples of a plant to which resistance has been imparted by genetic modification technologies include corn, soybeans and cotton resistant to glyphosate, and they have already been commercially available under the trade names of RoundupReady (registered trade mark), Agrisure (registered trademark) GT, Gly-Tol (registered trademark) and the like. Similarly, there are corn, soybeans and cotton resistant to glufosinate by genetic modification technologies, and they have already been commercially available under the trade names of LibertyLink (registered trademark) and the like. There are varieties of corn and soybeans under the trade names of Optimum (registered trademark) GAT (registered trade mark), which are resistant to both of glyphosate and acetolactic acid synthase inhibitors. Similarly, there are soybeans resistant to imidazolinone type acetolactic acid synthase inhibitors by genetic modification
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2013267026 04 Dec 2013 technologies, and they have been developed under the name of Cultivance. Similarly, there is cotton resistant to bromoxynil by genetic modification technologies, and this has already been commercially available under the trade name of BXN (registered trademark) . Similarly, there is a variety of soybean sold under the trade name of RoundupR.eady (registered trademark) 2 Xtend as a soybean resistant tobothof glyphosate and dicamba by genetic modification technologies. Similarly, there has been developed cotton resistant to both of glyphosate and dicamba by genetic modification technologies.
A gene encoding aryloxyalkanoate dioxygenase may be introduced to produce a crop which becomes resistant to phenoxy acid type herbicides such as 2,4-D, MCPA, dichlorprop and mecoprop, and aryloxyphenoxypropionic acid type herbicides such as quizalofop, haloxyfop, fluazifop, diclofop, fenoxaprop, metamifop, cyhalofop and clodinafop (Wright et al. 2010:
Proceedings of National Academy of Science. 107 (47) : 20240-20245). Cultivars of soybean and cotton, which show the resistance to 2,4-D, have been developed under the brand of
Enlist.
[0072]
A gene encoding a 4-hydroxypheny 1 pyruvic acid dioxygenase (hereinafter referred to as HPPD) inhibitor, the gene having resistance to HPPD, may be introduced to create a plant resistant to a HPPD inhibitor (US2004/0058427). A gene capable of
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2013267026 04 Dec 2013 synthesizing homogentisic acid which is a product of HPPD in a separate metabolic pathway even if HPPD is inhibited by a HPPD inhibitor is introduced, with the result that a plant having resistance to the HPPD inhibitor can be created (WO02/036787) .
A gene expressing excess HPPD may be introduced to produce HPPD in such an amount as not to adversely affect the growth of plants even in the presence of a HPPD inhibitor, with the result that a plant having resistance to the HPPD inhibitor can be created (WO96/38567). Besides introduction of the gene expressing 10 excess HPPD, a gene encoding prephenate dehydrogenase is introduced in order to increase the yield of p-hydroxyphenyl pyruvic acid which is a substrate of HPPD to create a plant having resistance to the HPPD inhibitor (Rippert P et. al., 2004 Engineering plant shikimate pathway for production of tocotrienol and improving herbicide resistance. Plant Physiol.
134: 92-100).
[0073]
Examples of a method of producing crops resistant to herbicides include, other than the above, the gene introducing methods described in WO98/20144, W02002/46387, and US2005/0246800.
[0074]
The above crops include, for example, crops which can synthesize selective toxins and the like known as the genus
Bacillus by using genetic modification technologies.
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Examples of the toxins developed in such genetically modified plants include insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; δ-endotoxins such as CrylAb, CrylAc, CrylF, CrylFa2, Cry2Ab, Cry3A, Cry3Bbl, Cry9C,
Cry34, and Cry35ab derived from Bacillus thuringiensis; insecticidal proteins such as VIP1, VIP2, VIP3, and VIP3A;
insecticidal proteins derived from nematodes; toxins produced by animals such as scorpion toxins, spider toxins, bee toxins, and neurotoxins specific to insects; filamentous fungus toxins;
plant lectins; agglutinin; trypsin inhibitors, serine protease inhibitors, and protease inhibitors such as patatin, cystatin, andpapain inhibitors; ribosome inactivatingproteins (RIP) such as lysine, corn-RIP, abrin, lufin, saporin, andbryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, and cholesterol oxidase; ecdysone inhibitors; HMG-CoA reductase; ion channel inhibitors such as sodium channel and calcium channel inhibitors; juvenile hormone esterase; diuretic hormone receptors; stilbene synthase; bibenzyl synthase; chitinase; and glucanase.
The toxins expressed in these transgenic plants include hybrid toxins, partially deficient toxins and modified toxins , which derive from δ-endotoxin proteins such as CrylAb, CrylAc, CrylF, CrylFa2, Cry2Ab, Cry3A, Cry3Bbl, Cry9C, Cry34Ab and Cry35Ab, and insecticidal proteins such as VIP1, VIP2, VIP3 and
VIP3A. The hybrid toxins are created by new combinations of
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2013267026 04 Dec 2013 domains having different proteins by using genetic modification technologies. As the partially defective toxins, CrylAb in which part of the amino acid sequences is missing is known. In the modified toxin, one or more of amino acids of a natural type toxin is replaced. Examples of these toxins and genetically modified plants capable of synthesizing these toxins are describedin, forexample, EP-A-0374753, W093/07278, WO95/34656, EP-A-0427529, EP-A-451878, and WO 03/052073. Resistance to noxious insects belonging to order Coleoptera, order Diptera, 10 and order Lepidoptera is imparted to plants by toxins contained in these genetically modified plants.
Also, genetically modified plants which contain one or more insecticidal genes resistant to harmful insects and develop one or more toxins have been already known and some of these p 1 ant shave been put on the market. Examples of these genetically modified plants include YieldGard (registered trademark) (corn variety expressing CrylAb toxin), YieldGard Rootworm (registered trademark) (corn variety expressing Cry3Bbl toxin), YieldGard Plus (registered trademark) (corn variety expressing
CrylAb and Cry3Bbl toxins), Herculex I (registered trademark) (corn variety expressing phosphinothricin N-acetyltransferase (PAT) for imparting resistance to a CrylFa2 toxin and glufosinate), NatureGard (registered trademark), AGRISURE (registeredtrademark) CBAdvantage (Btll cornborer (CB) trait) ,
Protecta (registered trademark); and the like.
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Also, genetically modified cotton which contains one or more insecticidal genes resistant toharmful insects and develops one or more toxins has been already known and some of cotton have been put on-the market. Examples of these genetically 5 modified cotton include BollGard (registered trademark) (cotton variety expressing CrylAc toxin), BollGard (registered trademark) II (cotton variety expressing CrylAc and Cry2Ab toxins), BollGard (registered trademark) III (cotton variety expressing CrylAc, Cry2Ab and VIP3A toxins), VipCot (registered trademark) (cotton variety expressing VIP3A and CrylAb toxins), WideStrike (registered trademark) (cotton variety expressing
CrylAc and CrylF toxins) and the like.
Examples of the plant used in the present invention also include plants such as soybeans into which a Ragl (Resistance
Aphid Gene 1) gene is introduced to impart resistance to an aphid.
The plants to be used in the present invention include those provided with resistance to nematodes by using a classical breedingmethodor genetic modification technologies. Examples of the genetic modification technologies used to provide the resistance to nematodes include RNAi.
[0075]
The above crops include those to which the ability to produce antipathogenic substances having a selective effect is impartedusing geneticmodif ication technologies . For example,
PR proteins are known as an example of the antipathogenic
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2013267026 04 Dec 2013 substance (PRPs, EP-A-0392225) . Such antipathogenic substances and genetically modified plants producing these antipathogenic substances are described in, for example,
EP-A-0392225, WO 95/33818, and EP-A-0353191. Examples of the 5 antipathogenic substances developed in such genetically modif ied plants include ion channel inhibitors such as a sodium channel inhibitor and calcium channel inhibitor (KP1, KP4, and
KP6 toxins produced by virus are known); stilbene synthase; bibenzyl synthase; chitinase; glucanase; PR protein;
antipathogenic substances produced by microorganisms such as peptide antibiotics, antibiotics having a heteroring, and a protein factor (referred to as a plant disease resistant gene and described in WO 03/000906) relating to plant disease resistance .
The above crops include plants to which useful traits such as an oil component reformation and amino acid-content reinforcing trait are given by genetic modification technologies. Examples of these plants include VISTIVE (trademark) (low linolenic soybean having a reduced linolenic content), high-lysine (high oil) corn (corn having an increased lysine or oil content) and the like.
Moreover, the above crops include stuck varieties obtained by combining two or more useful traits such as the above classical herbicide trait or herbicide resistant gene, gene resistant to insecticidal noxious insects, antipathogenic
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2013267026 04 Dec 2013 substance-producing gene, oil component reformation, and amino acid-content reinforcing trait, and allergen reduction trait.
[0076]
As the weeds which can be controlled by the composition 5 of the present invention, the following examples are given.
[0077]
Weeds of the family Urticaceae: Urtica urens; weeds of the family Polygonaceae: Polygonum convolvulus,
Polygonum lapathifolium, Polygonum pensylvanicum, Polygonum 10 persicaria, Polygonum longisetum, Polygonum aviculare,
Polygonum arenastrum, Polygonum cuspidatum, Rumex japonicas,
Rumex crispus, Rumex obtusifolius, and Rumex acetosa;
weeds of the family Portulacaceae: Portulaca oleracea; weeds of the family Caryophyllaceae: Stellaria media,
Cerastium holosteoides, Cerastium glomeratum, Spergula arvensis, and Silene gallica;
weeds of the family Molluginaceae: Mollugo verticillata; weeds of the family Chenopodiaceae: Chenopodium album,
Chenopodium ambrosioides, Kochia scoparia, Salsola kali, and
Atriplex spp.;
[0078] weeds of the familyAmaranthaceae: Amaranthus retroflexus, Amaranthus viridis, Amaranthus lividus, Amaranthus spinosus, Amaranthus hybridus, Amaranthus palmeri, Amaranthus rudis,
Amaranthus patulus, Amaranthus tuberculatos, Amaranthus
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2013267026 04 Dec 2013 blitoides, Amaranthus deflexus, Amaranthus quitensis, Alternanthera philoxeroides, Alternanthera sessilis, and
Alternanthera tenella;
weeds of the family Papaveraceae: Papaver rhoeas and 5 Argemone mexicana;
weeds of the family Brassicaceae: Raphanus raphanistrum, Raphanus sativus, Sinapis arvensis, Capsella bursa-pastoris, Brassica juncea, Brassica campestris, Descurainia pinnata, Rorippa islandica, Rorippa sylvestris, Thlaspi arvense, Myagrum rugosum, Lepidium virginicum, and Coronopus didymus;
weeds of the family Capparaceae: Cleome affinis;
[0079] weeds of the family Fabaceae: Aeschynoraene indica, Aeschynomene rudis, Sesbania exaltata, Cassia obtusifolia,
Cassia occidentalis, Desmodium tortuosum, Desmodium adscendens, Trifolium repens, Pueraria lobata, Vicia angustifolia,
Indigofera hirsute, Indigofera truxillensis, and Vigna sinensis;
weeds of the family Oxalidaceae: Oxalis corniculata,
Oxalis strica, and Oxalis oxyptera;
weeds of the family Geraniaceae: Geranium carolinense and
Erodium cicutarium;
weeds of the familyEuphorbiaceae: Euphorbia helioscopia, Euphorbia maculate, Euphorbia humistrata, Euphorbia esula,
Euphorbia heterophylla, Euphorbia brasiliensis, Acalypha
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2013267026 04 Dec 2013 australis, Croton glandulosus, Croton lobatus, Phyllanthus corcovadensis, and Ricinus communis;
[0080] weeds of the family Malvaceae: Abutilon theophrasti, Sida 5 rhombiforia, Sidacordifolia, Sidaspinosa, Sida glaziovii, Sida santaremnensis, Hibiscus trionum, Anoda cristata, and
Maivastrum coromandelianum;
weeds of the family Sterculiaceae: Waltheria indica;
weeds of the family Violaceae: Viola arvensis, and Viola tricolor;
weeds of the family Cucurbitaceae: Sicyos angulatus,
Echinocystis lobata, and Momordica charantia;
weeds of the family Lythraceae: Lythrum salicaria; weeds of the familyApiaceae : Hydrocotyle sibthorpioides;
weeds of the family Sapindaceae: Cardiospermum halicacabum;
weeds of the family Primulaceae: Anagallis arvensis; weeds of the family Asclepiadaceae: Asclepias syriaca and
Ampelamus albidus;
weeds of the family Rubiaceae: Galium aparine, Galium spurium var. echinospermon, Spermacoce latifolia, Richardia brasiliensis, and Borreria alata;
[0081] weeds of the family Convolvulaceae: Ipomoea nil, Ipomoea hederacea, Ipomoea purpurea, Ipomoea hederacea var.
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2013267026 04 Dec 2013 integriuscula, Ipomoea lacunose, Ipomoea triloba, Ipomoea acuminate, Ipomoea hederifolia, Ipomoea coccinea, Ipomoea quamoclit, Ipomoea grandifolia, Ipomoea aristolochiafolia, Ipomoea cairica, Convolvulus arvensis, Calystegia hederacea,
Calystegia japonica, Merremia hedeacea, Merremia aegyptia, Merremia cissoids, and Jacquemontia tamnifolia;
weeds of the family Boraginaceae: Myosotis arvensis/ weeds of the family Lamiaceae: Lamium purpureum, Lamium amplexicaule, Leonotis nepetaefolia, Hyptissuaveolens, Hyptis 10 lophanta, Leonurus sibiricus, and Stachys arvensis;
[0082] weeds of the familySoianaceae: Datura stramonium, Solanum nigrum, Solanum americanum, Solanum ptycanthum, Solanum sarrachoides, Solanum rostratum, Solanum. aculeatissimum,
Solanum sisymbriifolium, Solanum carolinense, Physalis angulata, Physalis subglabrata, and Nicandra physaloides;
weeds of the family Scrophulariaceae: Veronica hederaefolia, Veronica persica, and Veronica arvensis;
weeds of the family Plantaginaceae: Plantago asiatica;
[0083] weeds of the family Asteraceae: Xanthium pensylvanicum,
Xanthium Occident ale, Helianthus annuus, Matricaria chamomil la, Matricaria perforate, Chrysanthemum segetum, Matricaria matricarioides, Artemisia princeps, Artemisia vulgaris,
Artemisia verlotorum, Solidago altissima, Taraxacumof ficinale,
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Galinsoga ciliate, Galinsoga parviflora, Senecio vulgaris, Senecio brasiliensis, Senecio grisebachii, Conyzabonariensis, Conyza Canadensis, Ambrosia artemisiaefolia, Ambrosia trifida,
Bidens pilosa, Bidens frondosa, Bidens subalternans, Cirsium 5 arvense, Cirsium vulgare, Silybum marianum, Carduus nutans,
Lactuca serriola, Sonchus oleraceus, Sonchus asper, Wedelia glauca, Melampodium perfoliatum, Emilia sonchifolia, Tagetes minuta, Blainvillea latifolia, Tridax procumbens, Porophyllum ruderale, Acanthospermum australe, Acanthospermum hispidum,
Cardiospermum halicacabum, Ageratum conyzoides, Eupatorium perfoliatum, Eclipta alba, Erechtites hieracifolia, Gamochaeta spicata, Gnaphalium spicatum, Jaegeria hirta, Parthenium hysterophorus, Siegesbeckia orientalis, and Soliva sessilis;
[0084] weeds of the family Liliaceae: Allium canadense and Allium vineale;
weeds of the family Commelinaceae: Commelina communis, Commelina bengharensis, and Commelina erecta;
[0085] weeds of the family Poaceae: Echinochloa crus-galli,
Setaria viridis, Setaria faberi, Setaria glauca, Setaria geniculata, Digitaria ciliaris, Digitaria sanguinalis, Digitaria horizontalis, Digitaria insularis, Eleusine indica, Poa annua, Alospecurus aequalis, Alopecurus myosuroides, Avena fatua, Sorghum halepense, Sorghum vulgare, Agropyron repens,
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Lolium multiflorum, Lolium perenne, Lolium rigidum, Bromus secalinus, Bromus tectorum, Hordeum jubatum, Aegilops cylindrica, Phalaris arundinacea, Phalaris minor, Apera spica-venti, Panicum dichotomif lorum, Panicum t ex anum, Panicum 5 maximum, Brachiaria platyphylla, Brachiaria ruziziensis,
Brachiaria plantaginea, Brachiaria decumbens, Brachiaria brizantha, Brachiaria humidicola, Cenchrusechinatus, Cenchrus pauciflorus, Eriochloa villosa, Pennisetum setosum, Chloris gayana, Eragrostis pilosa, Rhynchelitrum repens,
Dactyloctenium aegyptium, Ischaemum rugosum, Oryza sativa,
Paspalum notatum, Paspalummaritimum, Pennisetum clandestinum,
Pennisetum setosum, and Rottboellia cochinchinensis;
[0086] weeds of the family Cyperaceae: Cyperus microiria, Cyperus iria, Cyperus odoratus, Cyperus rotundus, Cyperus esculentus, and Kyllinga gracillima; and weeds of the family Equisetaceae: Equisetum arvense and Equisetum palustre; and the like.
[0087]
In the composition of the present invention, the mixing ratio by weight of the A-type crystal flumioxazin to the compound selected from the group B is in a range from 1 : 0.01 to 1 : 500, preferably 1 : 0,05 to 1 : 200, and more preferably 1 :
0.1 to 1 : 100.
[0088]
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The composition of the present invention is usually mixed with a solid carrier, liquid carrier, or the like and, according to the need, formulated with surfactants and other preparation aids into preparations such as an emulsion, water-dispersible powder, suspension, and granule. These preparations each contain the A-type crystal flumioxazin and the compound selected from the group B in a total amount of usually 0.1 to 90% by weight and preferably 1 to 80% by weight.
[0089]
Examples of the solid carrier used for formulating the composition of the present invention include microparticles and granules of compounds such as clays (for example, Kaolinite, diatomaceous earth, synthetic water-containing silicon oxide, Fubasami clay, bentonite, and acid clay) , talc, other inorganic minerals (for example, sericite, quartz powder, sulfur powder, activated carbon, and calcium carbonate) , and chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, ammonium chloride, and urea), and examples of the liquid carrier include water, alcohols (for example, methanol and ethanol), ketones (for example, acetone, methyl ethyl ketone, and cyclohexanone), aromatic hydrocarbons (for example, toluene, xylene, ethylbenzene, and methylnaphthalene), non-aromatic hydrocarbons (hexane, cyclohexane, and kerosene), esters (for example, ethyl acetateandbutylacetate), nitriles (for example, acetonitrile and isobutyronitrile), ethers (for example,
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2013267026 04 Dec 2013 dioxane and diisopropyl ether), acid amides (for example, dimethylformamide and dimethyiacetamide), and halogenated hydrocarbons (for example, dichloroethane and trichloroethylene).
[0090]
Examples of the surfactant used for formulating the composition of the present invention include alkyl sulfates, alkyl sulfonates, alkylaryl sulfonates, alkyl aryl ethers and polyoxyethylene products thereof, polyethylene glycol ethers, 10 polyhydric alcohol esters, and sugar alcohol derivatives.
Examples of the other preparation aids include binders and dispersants such as casein, gelatin, polysaccharides (for example, starch, gum arable, cellulose derivatives, and alginic acid) , lignin derivatives, bentonite, synthetic water-soluble polymers (for example, polyvinyl alcohol, polyvinyl pyrrolidone, and polyacrylic acids), and stabilizers such as PAP (acidic isopropyl phosphate), BHT (2,6-tert-butyl-4-methylphenol), BHA (2-/3-tert“butyl-4“methoxyphenol), vegetable oil, mineral oil, fatty acid, and fatty acid ester.
[0091]
The composition of the present invention is prepared by formulating each component into a preparation by the aforementioned preparation methods, followed by mixing each preparation.
The composition of the present invention formulated into
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2013267026 04 Dec 2013 a preparation in this manner may be sprayed on soil or plant body either as it is, or after it is made into a dilute solution by diluting it with water or the like. The composition of the present invention may be further mixed with other herbicides for use, so that an increase in herbicidal effect is expected. Also, the composition of the present invention may be further used together with, for example, insecticides, germicides, plant growth regulators, fertilizers, and soil conditioners.
[0092]
The amount of the composition to be used is usually 1 to
3000 g in terms of total amount of each compound/ha though this differs depending on the mixing ratio of the A-type crystal flumioxazin to the compound selected from the group B, weather conditions, preparation form, time of use, method of use, place of use, weeds to be controlled, and object crop. When the composition of the present invention is used in the form of emulsion, water-dispersible powder, suspension, or the like, a specified amount of the emulsion, water-dispersible powder, suspension, or the like is usually diluted with 100 to 2000 L/ha for use. Also, when the composition of the present invention is used to perform stem leaves treatment of weeds, adjuvants are added to the dilute solution of the composition of the present invention in order to increase the herbicidal effect against weeds.
[0093]
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Weeds or places where weeds are expected to grow are treated with the composition of the present invention. Examples of the treatment of weeds include treatment of weeds themselves and treatment of soil after weeds grow. The treatment of the place where weeds are expected to grow includes treatment of the surface of soil before weeds grow. Also, examples of the method of controlling weeds according to the present invention include methods in which the A-type crystal flumioxazin and the compound selected from the group B are applied separately to weeds or 10 places where weeds are expected to grow.
[0094]
The following aspects are given as examples of the method of treatment with the compound of the present invention:
a method in which the compound of the present invention is sprayed on the surface of soil before crops are sowed and before weeds grow;
a method in which the compound of the present invention is sprayed on the surface of soil before crops are sowed and after weeds grow;
a method in which the compound of the present invention is sprayed on weeds before crops are sowed and after the weeds grow;
a method in which the compound of the present invention is sprayed on the surface of soil after crops are sowed but before they germinate, and before weeds grow;
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2013267026 04 Dec 2013 a method in which the compound of the present invention is sprayed on the surface of soil after crops are sowed but before they germinate, and after weeds grow;
a method in which the compound of the present invention is sprayed on weeds after crops are sowedbutbefore they germinate, and after the weeds grow;
a method in which the compound of the present invention is sprayed on the surface of soil in the presence of crops before germination of weeds;
a method in which the compound of the present invention is sprayed on the surface of soil in the presence of crops after weeds grow; and/or a method in which the compound of the present invention is sprayed on the surface of soil in the presence of crops after germination of the weeds.
Examples [0095]
Hereinbelow, the present invention will be described in detailbywayof examples, but the present invention isnot limited to these examples.
[0097] [Production Example]
Production Examples of A-type crystal flumioxazin used 25 in the method of the present invention will be shown below.
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Production Example 1
Flumioxazin (100 mg) was dissolved in methylisobutylketone at 60°C so as to adjust its concentration to 10.1 mg/mL. The solvent was rapidly cooled to 0°C, followed by being left to stand to obtain A-type crystals.
By X'Pert Pro MPD (manufactured by Nederland PANalytical
B.V.), a powder X-ray diffraction pattern of the obtained crystals was measured for each crystal at a scanning range from 2.0° to 40.0° (2Θ) using CuKa rays (40 kV, 30 mA).
The pattern of the obtained crystals had the peaks with as 2Θ values as shown in Table 2.
Table 2
2Θ value (°) | d value (A) | Relative intensity (%) |
9.8 | 9.0179 | 61.1 |
11.4 | 7.7556 | 13.1 |
12.7 | 6.9645 | 100.0 |
13.8 | 6.4117 | 24.1 |
16.0 | 5.5347 | 37.9 |
16.4 | 5.4006 | 32.4 |
16.7 | 5.3042 | 29.1 |
[0096] [Preparation Examples]
Preparation Examples will be shown below. Here, the parts represent parts by weight.
[0097]
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Preparation Example 1
A-type crystal flumioxazin (1 part), a glyphosate-isopropylamine salt (20 parts), polyoxyethylene sorbitan monooleate (3 parts), CMC (carboxymethyl cellulose, 5 the same shall apply hereinbelow) (3 parts), and water (73 parts) are mixed with one another and the mixture is wet-milled to the extent that it has a grain size of 5 micrometer or less to obtain a suspension.
[0098]
Preparation Example 2
A-type crystal flumioxazin (1 part), a glufosinate-ammonium salt (20parts), polyoxyethylene sorbitan monooleate (3 parts) , CMC (3 parts) , and water (73 parts) are mixed with one another and the mixture is wet-milled to the extent that it has a grain size of 5 micrometer or less to obtain a suspension.
[0099]
Preparation Example 3
A-type crystal flumioxazin (0.2 parts), a 2,4-D 20 isopropylamine salt (4 parts), polyoxyethylene sterylphenyl ether (14 parts), calcium dodecylbenzenesulfonate (6 parts), xylene (30 parts) , and N,N~dimethylformamide (45.8 parts) are mixed to obtain an emulsion.
Preparation Example 4
A-type crystal flumioxazin (0.2 parts),
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2013267026 04 Dec 2013 dicamba-glycolaramonium (4 parts) , polyoxyethylene sterylphenyl ether (14 parts), calcium dodecylbenzenesulfonate (6 parts), xylene (30 parts) , and N, N-dimethylformamide (45,8 parts) are mixed to obtain an emulsion.
[0100]
Preparation Example 5
A-type crystal flumioxazin (0.5 parts), cloransulam-methyl (0.8 parts), polyoxyethylene sterylphenyl ether (14 parts), calcium dodecvlbenzenesulfonate (6 parts), 10 xylene (30 parts) , and N,N-dimethylformamide (48.7 parts) are mixed to obtain an emulsion.
[0101]
Preparation Example 6
A-type crystal flumioxazin (3 parts) , pyroxasulfone (4 parts), sodium laurylsulfate (2 parts), and synthetic water-containing silicon oxide (91 parts) are thoroughly milled and mixed to obtain a hydrate.
[0102]
Preparation Example 7
A-type crystal flumioxazin (30 parts), chlorimuron-ethyl (10 parts), sodium laurylsulfate ¢2 parts) , and synthetic water-containing silicon oxide (58 parts) are thoroughly milled and mixed to obtain a hydrate.
[0103]
Preparation Example 8
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A-type crystal flumioxazin (3 parts) , chlorimuron-ethyl (lpart), pyroxasulfone (4parts), sodiumlaurylsulfate (2parts), and synthetic water-containing silicon oxide (90 parts) are thoroughly milled and mixed to obtain a hydrate.
[0104]
Preparation Example 9
A-type crystal flumioxazin (2 parts), metribuzin (10 parts), sodium laurylsulfate (2 parts), and synthetic water-containing silicon oxide (86 parts) are thoroughly milled and mixed to obtain a hydrate.
[0105]
Preparation Example 10
A-type crystal flumioxazin (10 parts), isoxaflutole (10 parts), sodium laurylsulfate (2 parts), and synthetic water-containing silicon oxide (78 parts) are thoroughly milled and mixed to obtain a hydrate.
[0106]
Preparation Example 11
A-type crystal flumioxazin (10 parts), mesotrione (10 parts), sodium laurylsulfate (2 parts), and synthetic water-containing silicon oxide (78parts) are thoroughly milled and mixed to obtain a hydrate.
[0107]
Preparation Example 12
A-type crystal flumioxazin (10 parts), tembotrione (10
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[0108]
Preparation Example 13
A~type crystal flumioxazin (2 parts) , an imazethapyr-ammonium salt (20parts), polyoxyethylene sorbitan monooleate (3 parts), CMC (3 parts), and water (72 parts) are mixed with one another and themixture is wet-milled to the extent that it has a grain size of 5 micrometer or less to obtain a suspension.
[0109]
Preparation Example 14
A-type crystal flumioxazin (lpart), saflufenacil (lpart), a glyphosate-isopropylamine salt (20 parts) , polyoxyethylene sorbitanmonooleate (3parts), CMC (3parts), and water (72parts) are mixed with one another and the mixture is wet-milled to the extent that it has a grain size of 5 micrometer or less to obtain a suspension.
[0110] [Test Examples]
In Test Examples, the herbicidal effect is evaluated as follows.
[Herbicidal effect]
In the evaluationof the herbicidal effect, the germination
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[0111]
Example 1
Weeds are sowed in a plastic pot filled with soil. A mixture solution of A-type crystal flumioxazin and a glyphosate-isopropylamine salt is uniformly sprayed from above germinated plants three weeks after the weeds are sowed. After the mixture solution is sprayed, soybean, peanut, corn, cotton, or wheat is sowed and the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0112]
Example 2
Weeds are sowed in a plastic pot filled with soil. A mixture solution of A-type crystal flumioxazin and a glyphosate-potassium salt is uniformly sprayed from above germinated plants three weeks after the weeds are sowed. After the mixture solution is sprayed, soybean, peanut, corn, cotton, or wheat is sowed and the pot is brought in a greenhouse. As
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[0113]
Example 3
Weeds are sowed in a plastic pot filled with soil. A 5 mixture solution of A-type crystal flumioxazin and a glufosinate-ammonium salt is uniformly sprayed from above germinated plants three weeks after the weeds are sowed. After the mixture solution is sprayed, soybean, peanut, corn, cotton, or wheat is sowed and the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0114]
Example 4
Weeds are sowed in a plastic pot filled with soil. A mixture solution of A-type crystal flurai oxazin and a dicamba-glycolamine salt is uniformly sprayed onto the surface of the soil or from above germinated plants on the day when or three weeks after the weeds are sowed. After the mixture solution is sprayed, corn is sowed and the pot is brought in a greenhouse.
As a result, high herbicidal effect is found.
[0115]
Example 5
Weeds are sowed in a plastic pot filled with soil. A mixture solution of A-type crystal flumioxazin and a dicamba-dimethylammonium salt is uniformly sprayed onto the surface of the soil or from above germinated plants on the day
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[0116]
Example 6
Weeds are sowed in a plastic pot filled with soil. A mixture solution of A-type crystal flumioxazin and a 2,4-D isopropylamine salt is uniformly sprayed from above germinated plants three weeks after the weeds are sowed. After the mixture solution is sprayed, corn is sowed and the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0117]
Example 7
Soybeans and weeds are sowed in a plastic pot filled with 15 soil. Then, a mixture solution of A-type crystal flumioxazin and chlorimuron-ethyl is uniformly sprayed onto the surface of the soil on the day when the soybeans and weeds are sowed. After themixture solution is sprayed, the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0118]
Example 8
Soybeans and weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal flumioxazin and cloransulam-methyl is uniformly sprayed onto the surface of the soil on the day when the soybeans and weeds are sowed.
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After the mixture solution is sprayed, the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0119]
Example 9
Soybeans and weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal flumioxazin and metribuzin is uniformly sprayed onto the surface of the soil on the day when the soybeans and weeds are sowed. After the mixture solution is sprayed, the pot is brought in a greenhouse.
As a result, high herbicidal effect is found.
[0120]
Example 10
Soybeans and weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal flumioxazin and pyroxasulfone is uniformly sprayed onto the surface of the soil on the day when the soybeans and weeds are sowed. After themixture solution is sprayed, the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0121]
Example 11
Soybeans and weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal flumioxazin, chlorimuron-ethyl and pyroxasulfone is uniformly sprayed onto the surface of the soil on the day when the soybeans and weeds are sowed. After the mixture solution is sprayed, the pot is
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[0122]
Example 12
Soybeans and weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal flumioxazin and an imazethapyr-ammonium salt is uniformly sprayed onto the surface of the soil on the day when the soybeans and weeds are sowed. After the mixture solution is sprayed, the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0123]
Example 13
Sugarcane and weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal flumioxazin and ametryne is uniformly sprayed onto the surface of the soil on the day when the soybeans and weeds are sowed. After the mixture solution is sprayed, the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0124]
Example 14
Weeds are sowed in a plastic pot filled with soil. Then, amixture solutionof A-type crystal flumioxazin and isoxaf lutole is uniformly sprayed onto the surface of the soil on the day when the weeds are sowed. After the mixture solution is sprayed, corn is sowed and the pot is brought in a greenhouse. As a result,
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[0125]
Example 15
Weeds are sowed in a plastic pot filled with soil. Then, 5 a mixture solution of A-type crystal f lumioxazin and mesotrione is uniformly sprayed onto the surface of the soil on the day when the weeds are sowed. After the mixture solution is sprayed, corn is sowed and the pot is brought in a greenhouse. As a result, high herbicidal effect is found.
[0126]
Example 16
Weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal f lumioxazin and tembotrione is uniformly sprayed onto the surface of the soil on the day when the weeds are sowed. After the mixture solution is sprayed, corn is sowed and the pot is brought in a greenhouse . As a result, high herbicidal effect is found, [0127]
Example 17
Weeds are sowed in a plastic pot filled with soil. Then, a mixture solution of A-type crystal flumioxazin, saflufenacil, and a glyphosate-potassium salt is uniformly sprayed on the surface of the soil three weeks after the weeds are sowed. After the mixture solution is sprayed, soybean, peanut, corn, cotton, and wheat are sowed and the pot is brought in a greenhouse. As
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[0128]
Example 18
A mixture solution of A-type crystal flumioxazin and a 5 glyphosate-isopropyl salt is uniformly sprayed onto the surface of soil in a pot where grapes, Citrus unshiu, peaches, or almonds are cultivated. The plants are grown in the open. As a result, high herbicidal effect is found.
[0129]
Example 19
A mixture solution of A-type crystal flumioxazin and a glyphosate-potassium salt is uniformly sprayed onto the surface of soil in a pot where grapes, Citrus unshiu, peaches, or almonds are cultivated. The plants are grown in the open. As a result, high herbicidal effect is found.
[0130]
Example 20
A mixture solution of A-type crystal flumioxazin and a glufosinate-ammonium salt is uniformly sprayed onto the surface of soil in a pot where grapes, Citrus unshiu, peaches, or almonds are cultivated. The plants are grown in the open. As a result, high herbicidal effect is found.
[0131]
According to the present invention, a wide range of weeds can be controlled in a crop field, land under perennial crops,
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The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.
Throughout this specification and the claims which follow, unless the context requires otherwise, the word comprise, and variations such as comprises and comprising, will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
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Claims (19)
- THE CLAIMS DEFINING THE INVENTION ARE AS FOLLOWS:1 A composition comprising crystal of flumioxazin which shows a powder X-Ray di f fraction pattern having diffraction peaks5 with 2Q values (°) shown in Table 1, said pattern being obtained by CuKa rays diffraction analysis,Table 1
- 2Θ value (°)9.8 ±0.111.4 ±0.112.7 ±0.1_13.8 +0.1_16.0' ±0.1_16.4 ±0.1 16.7 +0.1 and one or more herbicidal compounds selected from the groupB;10 Group B:B-lAcetolactic acid synthase inhibitors;B-2B-3B-4B-5Acetyl CoA carboxylase inhibitors;Protoporphyrinogen IX oxidase inhibitors;4-Hydroxyphenylpyrubic acid dioxygenase inhibitors;Phytoene desaturase inhibitors;B-6Photosystem II inhibitors;B-7. Very-long-chain fatty acid synthesis inhibitors;B-8. Tubulin synthesis inhibitors;B-9. Auxin type herbicides;2013267026 21 Mar 2018B-10. Enolpyruvylshikimate phosphate synthase inhibitors;B-ll. Glutamine synthetase inhibitors; andB-12. Other herbicides.5 2 The composition according to claim 1, wherein the compound of the group B is selected from the following compounds:B-l. Acetolactic acid synthase inhibitors:Pyrithiobac, pyrithiobac-sodium salt, pyriminobac, pyriminobac-methyl, bispyribac, bispyribac sodium salt,10 pyribenzoxim, pyrimisulfan, pyriftalid, triafamone, amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlorimuron, chlorimuron-ethyl, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, flupyrsulfuron methyl-sodium, foramsulfuron, halosulfuron, halosulfuron-methyl,15 imazosulfuron, mesosulfuron, mesosulfuron-methyl, metazosulfuron, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, primisulfuron-methyl, propyrisulfuron, pyrazosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron, sulfometuron-methyl, sulfosulfuron, trifloxysulfuron-sodium20 salt, trifloxysulfuron, chlorsulfuron, cinosulfuron, ethametsulfuron, ethametsulfuron-methyl, iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, metsulfuron, metsulfuron-methyl,2013-11-27 14:26:55Fax:06-6220-3389Page 74/82S341822013267026 04 Dec 2013 prosulfuron, thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, triflusulfuron, triflusulfuron-methyl, tritosulfuron, bencarbazone, flucarbazone, flucarbazone-sodium salt, ipfencarbazone,5 propoxycarbazone, propoxycarbazone-sodium salt, thiencarbazone, thiencarbazone-methyl, cloransulam, cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam, pyroxsulam, imazamethabenz, imazamethabenz-methyl, imazamox, imazartiox-ammonium salt,10 imazapic, imazapic-ammonium salt, imazapyr, imazapyr-isopropylammonium salt, imazaquin, imazaquin-ammoniumsalt, imazethapyr, andimazethapyr-ammonium salt.B-2. Acetyl CoA carboxylase inhibitors:15 Clodinafop, clodinafop-propargyl, cyhalofop, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, metamifop,20 propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, alloxydim, clethodim, sethoxydim, tepraloxydim, tralkoxydim, and pinoxaden.B-3. Protoporphyrinogen IX oxidase inhibitors: Azafenidin, oxadiazone, oxadiargyl, carfentrazone,25 carfentrazone-ethyl, saflufenacil, cinidon, cinidon-ethyl,2013-11-27 14:27:23Fax:06-6220-3389Page 75/82S341822013267026 04 Dec 2013 sulfentrazone, pyraclonil, pyraflufen, pyraflufen-ethyl, butafenacil, fluazolate, fluthiacet, fluthiacet-methyl, flufenpyr, flufenpyr-ethyl, flumiclorac, flumiclorac-pentyl, pentoxazone, oxyfluorfen, acifluorfen, aclonifen,5 chlomethoxynil, chloronitrofen, nitrofen, bifenox, fluoroglycofene, fluoroglycofene-ethyl, fomesafen, fomesafen-sodium salt, lactofen, and compounds represented by the formula (I) ;ch310 B-4. 4-Hydroxyphenylpyrubic acid dioxygenase inhibitors:Benzobicyclon, bicyclopyrone, mesotrione, sulcotrione, tefuryltrione, tembotrione, isoxachlorotole, isoxaflutole, benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, and topramezone.15 B-5. Phytoene desaturase inhibitors:Diflufenican, · picolinafen, beflubutamid, norflurazon, fluridone, flurochloridone, and flurtamone.B-6. Photosystem II inhibitors:loxynil, ioxynil octanoate, bentazone, pyridate,20 bromoxynil, bromoxynil octanoate, chlorotoluron, dimefuron, diuron, linuron, fluometuron, isoproturon, isouron, tebuthiuron, benzthiazuron, methabenzthiazuron, propanil,2013-11-27 14:27:47Fax:06-6220-3389Page 76/82S341822013267026 04 Dec 2013 metobromuron, metoxuron, monolinuron, siduron, simazine, atrazine, propazine, cyanazine, ametryne, simetryn, dimethametryn, prometryn, terbumeton, terbuthylazine, terbutryn, trietazine, hexazinone, metamitron, metribuzin,5 amicarbazone, bromacil, lenacil, terbacil, chloridazon, desmedipham, and phenmedipham.B-7, Very-long-chain fatty acid synthase inhibitors: Propachlor, metazachlor, alachlor, acetochlor, metolachlor, S-metolachlor, butachlor, pretilachlor,10 thenylchlor, indanofan, cafenstrole, fentrazamide, dimethenamid, dimethenamid-P, mefenacet, pyroxasulfone, fenoxasulfone, naproanilide, anilofos, and flufenacet.B-8. Tubulin synthesis inhibitors:Trifluralin, pendimethalin, ethafluralin, benfluralin,15 prodiamine, indaziflam, triaziflam, butamifos, dithiopyr, and thiazopyr.B-9. Auxin type herbicides:Dicamba and a salt thereof (diglycolamine salt, dimethyl ammonium salt, isopropylammoniumsalt, potassium salt,20 sodium salt, and choline salt), 2, 4-D and a salt or ester thereof (butotyl ester, dimethylammonlum salt, diolamine salt, ethylhexyl ester, isooctyl ester, isopropylammonium salt, sodium salt, and triisopropanolamine salt), 2,4-DB and a salt or ester thereof (dimethylammonium salt, isooctyl ester, and25 choline salt), MCPA and a salt or ester thereof (dimethylammonlum2013-11-27 14:28:14Fax:06-6220-3389Page 77/82S341822013267026 04 Dec 2013 salt, 2-ethylhexylester, isooctyl ester, sodium salt, and choline salt), MCPB, mecoprop and a salt or ester thereof (dimethylammonium salt, diolamine salt, ethadyl ester,2-ethylhexylester, isooctyl ester, methyl ester, potassiumsalt, 5 sodium salt, tololamine salt, and choline salt), mecoprop-P and a salt or ester thereof (dimethylammonium salt, 2-ethylhexyl ester, isobutyl salt, potassium salt, and choline salt), dichlorprop and a salt or ester thereof (butotyl ester, dimethylammonium salt, 2-ethylhexyl ester, isooctyl ester,10 methyl ester, potassium salt, sodium salt, and choline salt), dichlorprop-P, dichlorprop-P dimethylammonium, triclopyr and a salt or ester thereof (butotyl ester andtriethylammonium salt), fluroxypyr, fluroxypyr-meptyl, picloram and a salt thereof (potassium salt, triisopanolammonium salt, and choline salt) ,15 quinclorac, quinmerac, aminopyralid and a salt thereof (potassium salt, triisopanolammonium salt, and choline salt) , clopyralid and a salt thereof (olamine salt, potassium salt, triethylammonium salt, and choline salt), and clomeprop.B-10. Enolpyruvylshikimate phosphate synthase20 inhibitors:Glyphosate, glyphosate-isopropylamine salt, qlyphosate-trimesium salt, glyphosate-ammonium salt, glyphosate-diammonium salt, glyphosate-sodium salt, glyphosate-potassium salt, and glyphosate-guanidine salt.25 B-ll. Glutamine synthetase inhibitors:2013267026 21 Mar 2018Glufosinate, glutosinate-ammonium salt, glutosinate-P, glutosinate-P-sodium salt, and bialaphos.B-12. Other herbicides.Isoxaben, dichlobenil, methiozolin, diallate, butyrate,5 triallate, chlorpropham, asulam, phenisopham, benthiocarb, molinate, esprocarb, pyributicarb, prosulfocarb, orbencarb,EPTC, dimepiperate, Swep, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachlor-potassium, difenoxuron, methyl dymron, bromobutide, dymron, cumyluron,10 diflufenzopyr, etobenzanid, tridiphane, amitrole, fenchlorazole, clomazone, maleic hydrazide, oxaziclomefone, cinmethylin, benfuresate, ACN, dalapon, chlorthiamid, flupoxam, bensulide, paraquat, paraquat-dichloride, diquat, and diquat-dibromide.
- 3 The composition according to claim 1, wherein the compound of the group B is a compound selected from a glyphosate isopropylamine salt, a glyphosate-trimesium salt, a glyphosate-ammonium salt, a glyphosate-diammonium salt, a20 glyphosate-sodium salt, a glyphosate-potassium salt, and a glyphosate-guanidine salt.
- 4 The composition according to claim 1, wherein the compound of the group B is a glutosinate-ammonium salt.2013267026 21 Mar 2018
- 5 The composition according to claim 1, wherein the compound of the group B is chlorimuron-ethyl.
- 6 The composition according to claim 1, wherein the5 compound of the group B is cloransulam-methyl.
- 7 The composition according to claim 1, wherein the compound of the group B is pyroxasulfone.10
- 8 The composition according to claim 1, wherein the compound of the group B is a compound selected from dicamba, a dicamba-diglycolamine salt, a dicamba-dimethylammonium salt, a dicamba-isopropylammonium salt, a dicamba-potassium salt, a dicamba-sodium salt, and a dicamba-choline salt.
- 9 The composition according to claim 1, wherein the compound of the group B is a compound selected from a 2,4-D,2,4-D butotyl ester, a 2,4-D dimethylammonium salt, a 2,4-D diolamine salt, a 2,4-D ethylhexyl ester, a 2,4-D isooctyl ester,20 a 2,4-D isopropylammonium salt, a 2, 4-D sodium salt, and a 2,4-D triisopropanolammonium salt.
- 10 The composition according to claim 1, wherein the compound of the group B is an imazethapyr-ammonium salt.2013267026 21 Mar 2018
- 11 The composition according to claim 1, wherein the compound of the group B is metribuzin.
- 12 The composition according to claim 1, wherein the compound of the group B is isoxaflutole.
- 13 The composition according to claim 1, wherein the compound of the group B is mesotrione.10
- 14 The composition according to claim 1, wherein the compound of the group B is tembotrione.
- 15 The composition according to claim 1, wherein the compound of the group B is ametryne.
- 16 A method of controlling weeds, the method comprising applying an effective amount of the composition of any one of claims 1-15 to soil where the weeds are grown or to be grown, or weeds .
- 17 The method according to claim 16, which is a method of controlling weeds in a crop field, land under perennial crops, or non-crop land.25
- 18 The method according to claim 17, wherein the crop2013267026 21 Mar 2018 field is a field for soybean, peanut, corn, cotton, wheat, or sugarcane .
- 19 The method according to claim 17, wherein the land under5 perennial crops is an orchard.
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US20100248964A1 (en) * | 2007-09-14 | 2010-09-30 | Sumitomo Chemical Company, Limited | Herbicidal composition |
WO2013122241A1 (en) * | 2012-02-16 | 2013-08-22 | Sumitomo Chemical Company, Limited | Crystal of flumioxazin |
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WO2013122241A1 (en) * | 2012-02-16 | 2013-08-22 | Sumitomo Chemical Company, Limited | Crystal of flumioxazin |
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