AU2013206063B2 - Method and apparatus for preparing pulverized coal used to produce synthesis gas - Google Patents

Method and apparatus for preparing pulverized coal used to produce synthesis gas Download PDF

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AU2013206063B2
AU2013206063B2 AU2013206063A AU2013206063A AU2013206063B2 AU 2013206063 B2 AU2013206063 B2 AU 2013206063B2 AU 2013206063 A AU2013206063 A AU 2013206063A AU 2013206063 A AU2013206063 A AU 2013206063A AU 2013206063 B2 AU2013206063 B2 AU 2013206063B2
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coal
gas
turbine exhaust
exhaust gas
conveying
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AU2013206063A1 (en
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William N. Martin
Todd M. Sommer
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Babcock and Wilcox Co
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Babcock and Wilcox Co
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Assigned to THE BABCOCK & WILCOX COMPANY reassignment THE BABCOCK & WILCOX COMPANY Alteration of Name(s) of Applicant(s) under S113 Assignors: BABCOCK & WILCOX POWER GENERATION GROUP, INC.
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Abstract

A method for preparing coal for use in producing synthesis gas for use in gas turbines comprising the steps of grinding coal in a pulverizer to produce pulverized coal, combusting synthesis gas with air in a gas turbine to produce hot turbine exhaust gas, conveying a first portion of the hot turbine exhaust gas to the coal pulverizer to dry and convey the pulverized coal from the pulverizer to a coal/gas separation device. Conveying a second portion of the hot turbine exhaust gas through a waste heat recovery boiler to produce cooled turbine exhaust gas, removing NO, from the first portion of the hot turbine exhaust gas and from the second portion of the hot turbing exhaust gas, mixing the first portion of the turbine exhaust gas and the cooled turbine exhaust together and then conveying the mixture to the coal pulverizer, separating the pulverised coal from the turbine exhaust gas in the coal/gas separating device, conveying the separated pulverised coal from the coal/gas separation device to a pulverised coal storage bin and conveying the turbine exhaust gas from the coal/gas separation device to an environmental clean-up unit. 4380869_1 (GHMatters) P82001.AU.1 N N - ~ 4 t 6 cC 4 * Lit T

Description

- 1 METHOD AND APPARATUS FOR PREPARING PULVERIZED COAL USED TO PRODUCE SYNTHESIS GAS FIELD AND BACKGROUND OF THE INVENTION The present invention relates generally to pulverized coal preparation and, in 5 particular, to a method and apparatus for preparing pulverized coal used in the production of synthesis gas combusted in gas turbines used in integrated gasification combined cycle power plants. Integrated gasification combined cycle (IGCC) power plants produce synthesis gas fuel in gasifiers via the partial combustion of coal. The synthesis gas is used as fuel for gas 10 turbines of these IGCC power plants. The coal used to produce the synthesis gas is ground or pulverized to a desired particle size. The pulverized coal is heated by a drying stream to remove a portion of the moisture in the coal. The pulverized coal, after being separated from the drying stream, is then transported to a temporary storage location from where it is then 15 conveyed to the gasifier to produce the synthesis gas; systems of this type are known as indirect or bin systems. Moisture is removed so that the pulverized coal does not agglomerate when stored in the bin. However, in removing the moisture, the drying stream itself retains moisture removed from the coal. One current system uses a closed loop coal drying/grinding/ transport gas of nitrogen 20 with very low oxygen concentration, thus reducing the risk of coal combustion. Since the nitrogen is drying the coal, the moisture must be removed from the nitrogen by cooling it below the dew point, and removing the moisture, and then reheating it for recirculation to the pulverizer to dry and transport more coal. This system requires a cooler, a heater, associated pumps, valves and piping and continuous use of steam 25 and cooling water. Since the nitrogen would have to be purchased, the coal preparation and drying system would be operated as a closed system in order to minimize nitrogen losses from the system, and one or more heat exchangers would be required to remove moisture from the recirculating nitrogen drying stream. 30 SUMMARY OF THE INVENTION It would be advantageous if the invention would provide an improved method and apparatus for preparing coal for use in producing synthesis gas fuel used by gas turbines of power plants to produce electricity. 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02/16 -2 It would also be advantageous if the invention would provide an improved method and apparatus for preparing coal for use in producing synthesis gas fuel which does not require a closed loop system. Furthermore, embodiments of the present invention provide an improved method and 5 apparatus for preparing coal for use in producing synthesis gas fuel which does not require heat exchangers to remove moisture from the drying stream. In accordance with a first aspect of the present invention, there is provided a method for preparing coal for use in producing synthesis gas for use in gas turbines comprising the steps of: 10 grinding coal in a pulverizer to produce pulverized coal; combusting synthesis gas with air in a gas turbine to produce hot turbine exhaust gas at a temperature of 650F to 700F; and conveying a first portion of the hot turbine exhast gas to the coal pulverizer to dry and convey the pulverized coal from the pulverizer to a coal/gas separation device; 15 conveying a second portion of the hot turbine exhaust gas through a waste heat recovery boiler to produce cooled turbine exhaust gas at a temperature of about 300F or less; removing NOx from the first portion of the hot turbine exhaust gas and from the second portion of the hot turbine exhaust gas; 20 mixing the first portion of the turbine exhaust gas and the cooled turbine exhaust together and then conveying the mixture to the coal pulverizer; separating the pulverised coal from the turbine exhaust gas in the coal/gas separating device; conveying the separated pulverised coal from the coal/gas separation device to 25 a pulverised coal storage bin; and conveying the turbine exhaust gas away from the coal/gas separation device. In one embodiment of the present invention, the method for preparing coal for use in producing synthesis gas for use in gas turbines comprises the step of regulating the 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02/16 -3 relative amounts of hot turbine exhaust gas and cooled turbine gas provided to the coal pulveriser to achieve a desired pulverised coal mill outlet temperature. In accordance with a second aspect of the present invention, there is provided an apparatus for preparing coal for use in producing synthesis gas for use in gas turbines 5 comprising: a grinder adapted to grind coal to produce pulverised coal; means for combusting synthesis gas with air in a gas turbine to produce hot turbine exhaust gas at a temperature of 650F to 700F; means for conveying a first portion of the hot turbine exhaust gas to the coal 10 pulveriser to dry and convey the pulverised coal from the pulveriser to a coal/gas separation device; means for conveying a second portion of the hot turbine exhaust gas through a waste heat recovery boiler to produce cooled turbine exhaust gas at a temperature of about 300F or less; 15 means for removing NOx from the first portion of the hot turbine exhaust gas and from the second portion of the hot turbine exhaust gas; a mixer for mixing the first portion of the turbine exhaust gas and the cooled turbine exhaust together to form a mixture; means for conveying the mixture to the coal pulveriser; 20 a separator for separating the pulverised coal from the turbine exhaust gas in the coal/gas separating device; means for conveying the separated pulverised coal from the coal/gas separation device to a pulverised coal storage bin; and means for conveying the turbine exhaust gas away from the coal/gas 25 separation device. The various features of novelty which characterize the embodiments of the present invention are pointed out with particularity in the claims annexed to and forming a part of this disclosure. For a better understanding of the embodiments of the present invention, their operating advantages and specific objects attained by their uses, 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02/16 -4 reference is made to the accompanying drawings and descriptive matter in which a preferred embodiment of the invention is illustrated. BRIEF DESCRIPTION OF THE DRAWING 5 The sole Figure is a schematic drawing of the apparatus utilized in a preferred embodiment of the present invention. DESCRIPTION OF THE PREFERRED EMBODIMENT The Figure is a schematic illustration of a portion of an IGCC power plant, generally 10 designated 10, which employs the principles of the embodiments of the present invention to prepare pulverized coal used in the production of synthesis gas to generate power. Synthesis gas 12 from a gasifier 90 and air 14 are combusted in gas turbine 16 to produce energy for the IGCC power plant 10. The gas turbine is coupled to an electric generator (not shown) which produces a portion of the electricity 15 produced by IGCC plant 10. Hot turbine exhaust gas 18 is emitted from gas turbine 16 as a result of the combustion of the synthesis gas 12 and air 14. The hot turbine exhaust gas 18 is then conveyed to a NO, reduction device, such as a selective catalytic reduction (SCR) device 20, of known design and operation. A portion 22 of the hot turbine exhaust gas 18 is then conveyed through a waste heat 20 recovery boiler 40 of known design, while a second portion 24 of the hot turbine exhaust gas is directed to a coal pulverizer 60, as described below. The purpose of waste heat recovery boiler 40 is to generate steam to power a steam turbine and electric generator (not shown) for additional electric power generation by the IGCC plant 10. The temperature of the hot turbine exhaust gas flowing through the boiler 40 25 is reduced due to the heat transfer taking place within the boiler 40 and which produces the steam for the steam turbine (not shown). Cooled turbine exhaust gas exits from the boiler 40. Another portion 26 of the cooled turbine exhaust gas exiting from the boiler 40 is also directed to the coal pulverizer 60, as described below. The balance 28 of the cooled turbine exhaust gas exiting from the boiler 40 is then 30 conveyed to an environmental clean up unit (schematically indicated at 110) of known design and thereafter to a boiler stack 120. The environmental clean up unit would actually be positioned so as to receive and treat the flow stream 28 and the gas exiting via line 7 from a coal/gas separation device 70 described below. The environmental clean up unit 110 may, for example, comprise wet or dry scrubbers of known design 35 used to remove sulfur oxides from the turbine exhaust gas. 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02/16 -5 While the Figure illustrates a series arrangement of gas turbine 16, SCR 20 and waste heat recovery boiler 40, it will be appreciated by those skilled in the art that the SCR is probably integrated with the waste heat recovery boiler 40. Since the preferred inlet gas temperature entering the SCR 20 is about 700F, it is likely that the designer would 5 actually place some high temperature sections off the waste heat recovery boiler 40 in between the gas turbine 16 and the SCR 20, and then locate some low temperature sections off the waste heat recovery boiler 40 downstream of the SCR 20. In one embodiment of the present invention, it is preferred that the hot turbine exhaust gas 24, from which some of the NO, has been removed, be provided at a gas temperature of 10 about 650F, with the cooled turbine exhaust gas 26 exiting from the waste heat recovery boiler 40 at a gas temperature of about 300F or less. This provides sufficient heat and cooling capability in the turbine exhaust gas for use as a drying agent in the coal pulverizer 60 as described below. The hot 24 and cooled 26 turbine exhaust gas are conveyed to the coal pulverizer 60 15 to dry and convey pulverized coal from the pulverizer to a coal/gas separation device 70 in a controlled fashion, as described below. The turbine exhaust gas has a low oxygen concentration, reducing the risk of coal combustion. Raw coal 30 is supplied to one or more coal pulverizers 60 and ground to a desired fineness to produce a stream of pulverized coal. The hot turbine exhaust gas 24 is 20 mixed with the cooled turbine exhaust gas 26 at 32, and blown into the pulverizer 60 by hot pulverizer fan 50. The relative amounts of hot turbine gas 24 and cooled turbine gas 26 provided to the coal pulverizer 60 are regulated by motor operated gas dampers 34, 36 under the control of a controller (not shown) which operates to achieve a desired pulverized coal mill outlet temperature as measured by temperature sensor 25 38. The turbine exhaust gas dries the pulverized coal and transports it from the pulverizer 60. The dried pulverized coal exits from the pulverizer 60 and is conveyed to a coal/gas separation device 70, where the pulverized coal is separated from the gas. The mixed turbine exhaust gas which was conveyed to the coal pulverizer 60 removes the moisture from the pulverized coal. A direct fired-air heater (not shown) may be 30 utilized to supply heat to the coal pulverizer exhaust gas input line if hot turbine exhaust gas is not available. The coal/gas separation device 70 is advantageously a fabric filter, a cyclonic separation device, an electrostatic precipitator, or a combination thereof, and separates the pulverized coal from the turbine exhaust gas conveying stream. If device 35 70 is a fabric filter, it may be a single module, intermediate pressure, pulse-jet collector 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02/16 -6 with automated cleaning of the filter bags in an on-line cleaning mode. The device 70 may include a pre-cleaner inlet to reduce the grain loading to the bags. Such a design provides for both separation of particles from the gas stream and reduces the gas stream velocity by introducing a cross-flow gas pattern into the side of the device 70. A 5 compressed nitrogen system 100 may be provided for device 70 to provide nitrogen pulse jets to dislodge accumulated pulverized coal from the bags of the fabric filter. The nitrogen pulse jets also provide a nitrogen blanket over the pulverized coal to reduce the chance of combustion. Infiltration of air into the device 70 is also reduced by the positive pressure established by the hot pulverizer fan 50. 10 The pulverized coal separated from the exhaust gas in device 70 is collected in hoppers and then conveyed to pulverized coal storage bins 80 for eventual transport to the gasifier 90 where the synthesis gas is produced. The relatively clean exhaust gas is then conveyed from the coal/gas separator 70 to the environmental clean up unit 110 for final clean-up prior to discharge to the atmosphere. 15 Embodiments of the present invention may be employed in the construction of new IGCC power plants or in the repair, modification or retrofit of existing IGCC power plants. It is also understood that, depending upon the specific applications, certain features of the invention may be employed without other features of the invention. Thus, while a specific embodiment of the invention has been shown and described in 20 detail to illustrate the application of the principles of the invention, it will be understood that the invention may be embodied otherwise without departing from such principles. In the claims which follow and in the preceding description of the invention, except where the context requires otherwise due to express language or necessary 25 implication, the word "comprise" or variations such as "comprises" or "comprising" is used in an inclusive sense, i.e. to specify the presence of the stated features in various embodiments of the invention. 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02/16

Claims (3)

1. A method for preparing coal for use in producing synthesis gas for use in gas turbines comprising the steps of: 5 grinding coal in a pulverizer to produce pulverized coal; combusting synthesis gas with air in a gas turbine to produce hot turbine exhaust gas at a temperature of 650F to 700F; conveying a first portion of the hot turbine exhaust gas to the coal pulverizer to dry and convey the pulverized coal from the pulverizer to a coal/gas separation device; 10 conveying a second portion of the hot turbine exhaust gas through a waste heat recovery boiler to produce cooled turbine exhaust gas at a temperature of about 300F or less; removing NO, from the first portion of the hot turbine exhaust gas and from the second portion of the hot turbing exhaust gas; 15 mixing the first portion of the turbine exhaust gas and the cooled turbine exhaust together and then conveying the mixture to the coal pulverizer; separating the pulverised coal from the turbine exhaust gas in the coal/gas separating device; conveying the separated pulverised coal from the coal/gas separation device to 20 a pulverised coal storage bin; and conveying the turbine exhaust gas away from the coal/gas separation device.
2. The method according to claim 1, comprising the steps of: regulating the relative amounts of hot turbine exhaust gas and cooled turbine 25 gas provided to the coal pulveriser to achieve a desired pulverised coal mill outlet temperature.
3. An apparatus for preparing coal for use in producing synthesis gas for use in gas turbines comprising: 30 a grinder adapted to grind coal to produce pulverised coal; means for combusting synthesis gas with air in a gas turbine to produce hot turbine exhaust gas at a temperature of 650F to 700F; means for conveying a first portion of the hot turbine exhaust gas to the coal pulveriser to dry and convey the pulverised coal from the pulverizer to a coal/gas 35 separation device; means for conveying a second portion of the hot turbine exhaust gas through a waste heat recovery boiler to produce cooled turbine exhaust gas at a temperature of 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02/16 about 300F or less; means for removing NO, from the first portion of the hot turbine exhaust gas and from the second portion of the hot turbine exhaust gas; a mixer for mixing the first portion of the turbine exhaust gas and the cooled 5 turbine exhaust together to form a mixture; means for conveying the mixture to the coal pulverizer; a separator for separating the pulverized coal from the turbine exhaust gas in the coal/gas separating device; means for conveying the separated pulverised coal from the coal/gas 10 separation device to a pulverized coal storage bin; and means for conveying the turbine exhaust gas away from the coal/gas separation device. 7356293_1 (GHMatters) P82001.AU.1 SOPHIER 9/02116
AU2013206063A 2007-04-06 2013-05-29 Method and apparatus for preparing pulverized coal used to produce synthesis gas Ceased AU2013206063B2 (en)

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US60/910,547 2007-04-06
US12/060,459 2008-04-01
AU2008237357A AU2008237357A1 (en) 2007-04-06 2008-04-02 Method and apparatus for preparing pulverized coal used to produce synthesis gas
AU2013206063A AU2013206063B2 (en) 2007-04-06 2013-05-29 Method and apparatus for preparing pulverized coal used to produce synthesis gas

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4689949A (en) * 1985-01-30 1987-09-01 Mitsubishi Jukogyo Kabushiki Kaisha Coal gasification composite power generator
US5456066A (en) * 1993-07-12 1995-10-10 The United States Of America As Represented By The United States Department Of Energy Fuel supply system and method for coal-fired prime mover
WO2004002611A1 (en) * 2002-06-28 2004-01-08 Johnson Matthey Public Limited Company Doped ceria-containing zeolite-based nh3 scr catalyst

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4689949A (en) * 1985-01-30 1987-09-01 Mitsubishi Jukogyo Kabushiki Kaisha Coal gasification composite power generator
US5456066A (en) * 1993-07-12 1995-10-10 The United States Of America As Represented By The United States Department Of Energy Fuel supply system and method for coal-fired prime mover
WO2004002611A1 (en) * 2002-06-28 2004-01-08 Johnson Matthey Public Limited Company Doped ceria-containing zeolite-based nh3 scr catalyst

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