AU2011260510B2 - Method for producing steam generator tubes - Google Patents

Method for producing steam generator tubes Download PDF

Info

Publication number
AU2011260510B2
AU2011260510B2 AU2011260510A AU2011260510A AU2011260510B2 AU 2011260510 B2 AU2011260510 B2 AU 2011260510B2 AU 2011260510 A AU2011260510 A AU 2011260510A AU 2011260510 A AU2011260510 A AU 2011260510A AU 2011260510 B2 AU2011260510 B2 AU 2011260510B2
Authority
AU
Australia
Prior art keywords
steam generator
insert
former shaft
tubes
former
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2011260510A
Other versions
AU2011260510A1 (en
Inventor
Jan Bruckner
Martin Effert
Joachim Franke
Lars Klemm
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Original Assignee
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG filed Critical Siemens AG
Publication of AU2011260510A1 publication Critical patent/AU2011260510A1/en
Application granted granted Critical
Publication of AU2011260510B2 publication Critical patent/AU2011260510B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • B21C37/15Making tubes of special shape; Making tube fittings
    • B21C37/22Making finned or ribbed tubes by fixing strip or like material to tubes
    • B21C37/26Making finned or ribbed tubes by fixing strip or like material to tubes helically-ribbed tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21FWORKING OR PROCESSING OF METAL WIRE
    • B21F3/00Coiling wire into particular forms
    • B21F3/02Coiling wire into particular forms helically
    • B21F3/04Coiling wire into particular forms helically externally on a mandrel or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21FWORKING OR PROCESSING OF METAL WIRE
    • B21F3/00Coiling wire into particular forms
    • B21F3/02Coiling wire into particular forms helically
    • B21F3/06Coiling wire into particular forms helically internally on a hollow form
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B29/00Steam boilers of forced-flow type
    • F22B29/06Steam boilers of forced-flow type of once-through type, i.e. built-up from tubes receiving water at one end and delivering superheated steam at the other end of the tubes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/02Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/10Water tubes; Accessories therefor
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/02Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/10Water tubes; Accessories therefor
    • F22B37/101Tubes having fins or ribs
    • F22B37/103Internally ribbed tubes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B37/00Component parts or details of steam boilers
    • F22B37/02Component parts or details of steam boilers applicable to more than one kind or type of steam boiler
    • F22B37/10Water tubes; Accessories therefor
    • F22B37/18Inserts, e.g. for receiving deposits from water

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Monitoring And Testing Of Nuclear Reactors (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

A method for producing steam generator tubes is intended to allow a technically particularly simple production process and at the same time allow particularly high flexibility with regard to the materials that can be used to achieve a particularly high efficiency of a steam generator. For this purpose, an insert is fixed in slots (4) of a former shaft (1), the former shaft (1) with the insert is introduced into a steam generator tube, the fixing of the insert on the former shaft (1) is released and the former shaft (1) is removed again from the steam generator tube.

Description

PCT/EP2011/057426 / 201OP01440WO 1 Description Method for producing steam generator tubes The invention relates to a method for producing steam generator tubes. A steam generator is a closed, heated vessel or a pressure pipe or tube system which serves the purpose of producing steam at high pressure and high temperature for heating and operational purposes (e.g. for the operation of a steam turbine). With particularly high steam capacities and pressures, such as, for example, during energy production in power stations, water-tube boilers are used in which the flow medium, usually water, is located in steam generator tubes. Water-tube boilers are also used in applications involving the combustion of solids, since the combustion chamber in which the heat generation takes place through combustion of the respective raw material can be configured at will by the arrangement of tube walls. A steam generator of said type designed in the manner of a water-tube boiler accordingly comprises a combustion chamber, the encompassing wall of which is formed at least partially by tube walls, i.e. steam generator tubes which are welded so as to be gas-tight. On the flow medium side, these steam generator tubes, as evaporation heating surfaces, initially form an evaporator into which unevaporated medium is introduced and evaporated. The evaporator is in this case usually arranged in the hottest area of the combustion chamber. Arranged downstream of this, on the flow medium side, where appropriate, is a device for separating water and steam, and a superheater in which the steam is heated further above its evaporation temperature in order to attain a high degree of efficiency in a following PCT/EP2011/057426 / 2010P01440WO 2 thermal engine such as, for example, a steam turbine. Connected upstream of the evaporator on the flow medium side there can be a preheater (referred to as an economizer), which preheats the feedwater by making use of waste or residual heat and thereby likewise increases the degree of efficiency of the system as a whole. For evaporator heating surfaces in steam generators, smooth tubes or tubes with internal ribbing are used. Tubes with internal ribbing are used when the aim is to impose a swirl on the flow of the flow medium in the steam generator tubes, which has the effect of imparting a higher velocity to the fluid on the inner surface of the steam generator tubes. The use of tubes with internal ribbing may in this case be necessary for various reasons, such as, for example, with a low mass flow density of the evaporator under full load. Even at high heat flow densities, the use of tubes with internal ribbing may be necessary (in drum-type boilers, for example): In this situation there is the risk of film boiling, i.e. a film of steam forms on the inside of the steam generator tubes, which, in contrast with well-mixed fluid, has a high heat-insulating effect in the event of bubble or nucleate boiling. The consequence of this is that, while the heat flow density remains the same, the wall temperature may rise sharply, which can lead to the destruction of the heating surfaces. Not least, the use of tubes with internal ribbing can avoid flow layering (separation of the water and steam phase) in normal load operation (such as, for example, at minimum load in helically-tubed steam generators). According to the prior art, the internal ribbing of the tubes is produced in a cold-drawing process. According to present knowledge, tubes with internal ribbing can only be manufactured with materials with a maximum chromium content of 5%. If the use 3 of tubes with internal ribbing made of alloy steels with a higher chromium content is necessary, due, for example, to a further rise in the steam parameters in order to raise the degree of efficiency, then the internally ribbed tubes cannot be manufactured with the processes available today. OBJECT It is the object of the present invention to substantially overcome or ameliorate one or more of the disadvantages of the prior art. SUMMARY The present invention provides a method for producing steam generator tubes, wherein an insert is fixed in grooves of a former shaft, the former shaft is introduced with the insert into a steam generator tube, the fixing of the insert to the former shaft is released, and the former shaft is removed again from the steam generator tube. The invention is based here on the consideration that a particularly high level of flexibility in respect of the materials which can be used could be achieved in that the internally ribbed tubes are not produced in one integrated manufacturing process, but rather that a subsequent introduction of swirl-inducing inserts into smooth tubes should be carried out. This enables the materials of steam generator tubes and inserts to be selected independently of one another. A particularly simple production of the insert can be achieved in this case with the aid of a former shaft. A negative mold of the insert is introduced into the former shaft such that the production of the insert can be carried out by simple integral molding. A former shaft of said type additionally allows for particularly easy fitting of the insert in steam generator tubes PCT/EP2011/057426 / 2010P01440WO 4 in that the insert is fixed on the former shaft, the latter is introduced with the integrally molded insert into the steam generator tube, the fixing is released there, and the former shaft is removed again from the steam generator tube. In an advantageous embodiment of the method, the insert is fixed to the former shaft with a pretension. As a result of such pretension it is possible for the insert, after release of the fixing to the former shaft, to be lifted out of the grooves of the former shaft and therefore fixed independently in the steam generator tube, without further manual fixing being necessary. In a further advantageous embodiment, a number of grooves are introduced in the manner of helix into the former shaft. A former shaft of this type naturally produces a helical-shaped insert, which is particularly well-suited for inducing swirl in the flow medium. In an additional advantageous embodiment, the former shaft is rotated out of the steam generator tube after the release of the fixing of insert and former shaft. This is possible due to the symmetry of the helix, and simplifies the removal of the former shaft from the steam generator tube provided with the insert. This allows for an even simpler manufacturing process of an internally ribbed steam generator tube. Advantageously, in this arrangement, the grooves of the former shaft are implemented in a conical design. The conical implementation ensures easier joining and backward rotation of the former shaft when it is removed from the steam generator tube.
PCT/EP2011/057426 / 2010P01440WO 5 In a particularly advantageous embodiment, the insert comprises a number of wires. Specifically, as a result of the production of the insert by means of a former shaft which comprises a number of grooves, the insert can be manufactured in a particularly simple manner by appropriate shaping of wires into the grooves. This means not only a particularly economical but also a technically simple production of an insert for a steam generator tube. In an advantageous embodiment, a steam generator tube manufactured in accordance with the method described hereintofore is used in a steam generator. The advantages achieved with the invention consist in particular in that through the introduction of an insert into a steam generator tube by means of a former shaft a particularly simple technical solution for the production and positioning of an insert is now provided, which solution allows tubes which are internally ribbed by means of an insert to be manufactured using alloy steels with higher chromium content which are suited to particularly high steam parameters and therefore a particularly high degree of efficiency of a steam generator. The production of the insert can therefore be achieved particularly economically, because the former shaft can be rotated completely out of the tube again and used for the production of the next insert. The significant cost advantages in comparison with cold drawn tubes with internal ribs make the production method according to the invention attractive even in the case of materials having less than 5% chromium. By the use of a former element in the form of grooves on a former shaft, the insert has low tolerances in respect of its geometry in the assembled state. As a result of assembly with PCT/EP2011/057426 / 2010P01440WO 6 the former shaft, moreover, no cross-braces or similar ancillary devices are needed in order to ensure the desired geometry of the swirl insert in the assembled state. Swirl inserts can be produced with the aid of a former shaft in commercially available lengths (e.g. 12 m). The invention is explained in greater detail with reference to a drawing, in which: FIG 1 shows a former shaft for carrying out the method according to the invention, FIG 2 shows a magnified view of the former shaft in section, FIG 3 shows a flow diagram of the method according to the invention, and FIG 4 is a schematic diagram of a once-through steam generator in a tower design format. Like parts are labeled with the same reference numerals in all the figures. FIG 1 shows a former shaft 1 which is provided in a main area 2 with grooves 4 running around the shaft in helical fashion. In this case the grooves 4 are arranged in the form of a threefold helix around the cylindrical body of the former shaft 1. Depending on the desired profile of the insert which is to be produced, the grooves 4 can also be embodied as a helix having almost any desired number. Depending on the requirement, the desired grooves 4 can be produced individually (number, pitch, dimensions) by means of a metal-cutting machining process. The length of the main area 2 of the former shaft 1 is slightly PCT/EP2011/057426 / 2010P01440WO 7 greater than the smooth tube into which the insert is intended to be introduced. The main area 2 of the former shaft 1 is followed in the axial direction by a connection area 6 which is not provided with grooves 4 and which serves to handle the former shaft 1 during the method according to the invention. FIG 2 shows the former shaft 1 in section, in a magnified representation. The profile of the grooves 4 incorporated into the former shaft 1 can be identified at the cut face 8. The grooves 4 have a conical profile. Such a profile allows for a simpler joining and backward rotation of the former shaft 1 during the manufacturing process of the insert (not shown in greater detail) for a steam generator tube. FIG 3 shows a schematic diagram depicting the individual steps of the production process according to the invention. In step A, one or more wires are inserted into the former shaft 1, according to the number of grooves 4 which are to be introduced into it. This results in the production of the one-pitch or multi-pitch swirl insert. In step B, the wire or wires is/are fixed to the former shaft 1 under pretension. In step C, the former shaft 1 is introduced into a steam generator tube which is smooth on the inside, and the insert is in this way positioned in the steam generator tube. In step D, the fixing of the insert formed of wires on the former shaft 1 is released. As a result of the preceding fixing with pretension in step B, the release of the fixing leads to a lifting of the insert out of the grooves 4. In step E, the former shaft 1 is rotated out of the steam generator tube in the manner of a screw, along the helical-shaped grooves 4. This is assisted by the conical shape of the grooves 4. As a result of the release of the fixing and by the reverse rotation of the PCT/EP2011/057426 / 2010P01440WO 8 former shaft 1, the insert is released from the former shaft 1, and, assisted by the internal stress, comes into firm contact with the inner wall of the steam generator tube. The former shaft 1 is rotated completely out of the tube, and can be used in step F for the production of the next insert. The once-through steam generator 10 according to FIG 4 is implemented in a tower design format and as a two-pass steam generator. It has an encompassing wall 12 which, at the lower end of the first gas pass formed by it, transitions into a funnel-shaped base 14. The encompassing wall 12 is formed in a lower area, or evaporator area, from evaporation tubes 16, and in an upper area, or superheater area, from superheater tubes 16'. The evaporator tubes 16 and superheater tubes 16' are joined to one another, for example welded, in a gas-tight manner on their longitudinal sides. The base 14 comprises a discharge aperture 18 for ash (not shown in greater detail). The evaporator tubes 16 of the encompassing wall 12, through which a flow medium, in particular water or a water-steam mixture, flows from bottom to top, are connected at their inlet ends to an inlet manifold 20. On the outlet side the evaporator tubes 16 are connected by means of a water separation system (not shown in greater detail) to the superheater tubes 16' which follow downstream on the flow medium side. The evaporator tubes 16 of the encompassing wall 12 form an evaporation heating surface 22 in the section of the gas pass located between the inlet manifold 20 and the water separation system. This is followed by a reheater or superheater heating surface 24 formed from the superheater tubes 16'. In addition, arranged in the second gas pass 26, through which the hot gases flow downward, and in the transverse pass 28, connecting it on PCT/EP2011/057426 / 2010P01440WO 9 the hot gas side to the first gas pass, are further heating surfaces 30, only represented schematically, such as an economizer and convective superheater heating surfaces. Mounted in the lower area of the encompassing wall 12 are a number of burners for a fossil fuel, in each case in an aperture 32 of the encompassing wall 12. Four apertures 32 are visible in FIG 1. At an aperture 32 of this kind the evaporator tubes 16 of the encompassing wall 12 are curved so as to circumvent the respective aperture 32, and run on the outside of the vertical gas pass. These apertures can, for example, also be provided for air nozzles. As a result of the use of steam generator tubes with internal ribbing in the steam generator 10, produced according to the described method, it is possible to make use also of steels having a chromium content of more than 5% for their manufacture. Such steam generator tubes are suitable for particularly high steam parameters, and so enable a particularly high degree of efficiency of a steam generator to be achieved.

Claims (9)

1. A method for producing steam generator tubes, wherein an insert is fixed in grooves of a former shaft, the former shaft is introduced with the insert into a steam generator tube, the fixing of the insert to the former shaft is released, and the former shaft is removed again from the steam generator tube.
2. The method as claimed in claim 1, wherein the insert is fixed to the former shaft with a pretension.
3. The method as claimed in any one of the preceding claims, wherein a number of grooves are introduced in a helical shape into the former shaft.
4. The method as claimed in claim 3, wherein the former shaft is rotated out of the steam generator tube.
5. The method as claimed in any one of the preceding claims, wherein the grooves are implemented as conical.
6. The method as claimed in any one of the preceding claims, wherein the insert comprises a number of wires.
7. A steam generator tube, produced by means of the method as claimed in any one of claims 1 to 6.
8. A steam generator having a steam generator tube as claimed in claim 7.
9. A method for producing steam generator tubes substantially as hereinbefore described with reference to the accompanying drawings. Siemens Aktiengesellschaft Patent Attorneys for the Applicant/Nominated Person SPRUSON & FERGUSON
AU2011260510A 2010-05-31 2011-05-09 Method for producing steam generator tubes Ceased AU2011260510B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10164426A EP2390567A1 (en) 2010-05-31 2010-05-31 Device for producing fixture units for steam generator pipes
EP10164426.8 2010-05-31
PCT/EP2011/057426 WO2011151135A2 (en) 2010-05-31 2011-05-09 Method for producing steam generator tubes

Publications (2)

Publication Number Publication Date
AU2011260510A1 AU2011260510A1 (en) 2012-11-15
AU2011260510B2 true AU2011260510B2 (en) 2014-03-20

Family

ID=43536619

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2011260510A Ceased AU2011260510B2 (en) 2010-05-31 2011-05-09 Method for producing steam generator tubes

Country Status (8)

Country Link
US (1) US20130087106A1 (en)
EP (2) EP2390567A1 (en)
JP (1) JP2013532267A (en)
KR (1) KR20130090765A (en)
CN (1) CN102933899A (en)
AU (1) AU2011260510B2 (en)
PL (1) PL2577160T3 (en)
WO (1) WO2011151135A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012219898B4 (en) * 2012-10-31 2014-09-11 Siemens Aktiengesellschaft Resistance spot welding machine
RU2699841C1 (en) * 2016-07-07 2019-09-11 Сименс Акциенгезелльшафт Method of making steam generator pipe with built-in swirling element

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2184536A1 (en) * 2008-09-09 2010-05-12 Siemens Aktiengesellschaft Steam generator pipe, accompanying production method and once-through steam generator

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE100563C (en) *
GB390347A (en) * 1932-05-30 1933-04-06 Arthur Kuhlmann Arrangement for producing helical flow of gases, steam and liquids
US2708306A (en) * 1952-07-09 1955-05-17 Hughes Tool Co Method of rifling metal tubes
US3088494A (en) * 1959-12-28 1963-05-07 Babcock & Wilcox Co Ribbed vapor generating tubes
FR1433888A (en) * 1965-05-14 1966-04-01 Device eliminating instantaneous vaporization in the boiler tubes
FR1592381A (en) * 1968-11-20 1970-05-11
US6302194B1 (en) * 1991-03-13 2001-10-16 Siemens Aktiengesellschaft Pipe with ribs on its inner surface forming a multiple thread and steam generator for using the pipe
JPH051892A (en) * 1991-06-24 1993-01-08 Hitachi Ltd Whirling flow promoting type boiling heat transfer tube
DE4417524C2 (en) * 1994-05-19 2001-04-26 Behr Gmbh & Co Process for the production and assembly of wire-wound turbulators in heat exchanger tubes and device for carrying out the process
CN1876265A (en) * 2005-06-07 2006-12-13 三井巴布科克(美国)有限公司 Device and method for forming inner rib or ribbed pipe
EP1793164A1 (en) * 2005-12-05 2007-06-06 Siemens Aktiengesellschaft Steam generator tube, method of manufacturing the same and once-through steam generator
EP1793163A1 (en) * 2005-12-05 2007-06-06 Siemens Aktiengesellschaft Steam generator tube, method of manufacturing the same and once-through steam generator
US8350176B2 (en) * 2008-06-06 2013-01-08 Babcock & Wilcox Power Generation Group, Inc. Method of forming, inserting and permanently bonding ribs in boiler tubes
CN201273787Y (en) * 2008-07-30 2009-07-15 保定市金能换热设备有限公司 Helical groove heat exchange tube with fins
DE102009024587A1 (en) * 2009-06-10 2010-12-16 Siemens Aktiengesellschaft Flow evaporator
US20110083619A1 (en) * 2009-10-08 2011-04-14 Master Bashir I Dual enhanced tube for vapor generator

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2184536A1 (en) * 2008-09-09 2010-05-12 Siemens Aktiengesellschaft Steam generator pipe, accompanying production method and once-through steam generator

Also Published As

Publication number Publication date
PL2577160T3 (en) 2020-12-14
CN102933899A (en) 2013-02-13
WO2011151135A3 (en) 2012-10-11
AU2011260510A1 (en) 2012-11-15
KR20130090765A (en) 2013-08-14
EP2577160B1 (en) 2020-07-15
EP2390567A1 (en) 2011-11-30
US20130087106A1 (en) 2013-04-11
WO2011151135A2 (en) 2011-12-08
JP2013532267A (en) 2013-08-15
EP2577160A2 (en) 2013-04-10

Similar Documents

Publication Publication Date Title
CN105580087B (en) Steam generator and in steam generator antivibration stationary heat exchangers pipe method
EP3204691B1 (en) Once-through vertical tubed supercritical evaporator coil for an hrsg
KR20110128849A (en) Continuous evaporator
US7878157B2 (en) Fossil-fuel heated continuous steam generator
EP3770528A3 (en) Heat exchanger for boiler
AU2011260510B2 (en) Method for producing steam generator tubes
KR20120027021A (en) Continuous evaporator
KR101663850B1 (en) Continuous evaporator
MXPA05003380A (en) Once-through evaporator for a steam generator.
TW201418567A (en) Rapid startup heat recovery steam generator
JP2012502248A (en) Once-through boiler
KR101662348B1 (en) Continuous evaporator
EP1929205B1 (en) Water tube boiler
US10928058B2 (en) Flash boiler
DK2577159T3 (en) Device for the manufacture of integral elements for steam generator pipes
EP2044365B1 (en) Method of producing steam in a gas tube steam boiler and gas tube steam boiler
JP2013532814A (en) Forced once-through steam generator
EP2600092A1 (en) Vertical heat exchanger

Legal Events

Date Code Title Description
FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired