AU2011257038A1 - Reactor for the autothermal reforming of diesel - Google Patents
Reactor for the autothermal reforming of diesel Download PDFInfo
- Publication number
- AU2011257038A1 AU2011257038A1 AU2011257038A AU2011257038A AU2011257038A1 AU 2011257038 A1 AU2011257038 A1 AU 2011257038A1 AU 2011257038 A AU2011257038 A AU 2011257038A AU 2011257038 A AU2011257038 A AU 2011257038A AU 2011257038 A1 AU2011257038 A1 AU 2011257038A1
- Authority
- AU
- Australia
- Prior art keywords
- reforming
- hydrocarbon feed
- reactor
- reforming reactor
- autothermal reforming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/0085—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction promoting uninterrupted fluid flow, e.g. by filtering out particles in front of the catalyst layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00203—Coils
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00522—Controlling the temperature using inert heat absorbing solids outside the bed
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0883—Methods of cooling by indirect heat exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1023—Catalysts in the form of a monolith or honeycomb
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1029—Catalysts in the form of a foam
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1276—Mixing of different feed components
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1288—Evaporation of one or more of the different feed components
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
The invention relates to a method for the autothermal reforming of a hydrocarbon feed in a catalytic reforming reactor, including the steps that consist of: a) mixing the hydrocarbon feed with water vapour, and vaporising the hydrocarbon feed if not already vaporised; b) pre-distributing the vaporised mix of hydrocarbon feed and water across the section of the reforming reactor using a multipoint injector network; c) injecting a gaseous oxidising flow, preferably pure oxygen, into the pre-distributed mixture from step (b) at the injectors from step (b); d) distributing, in the presence of an autothermal reforming catalyst, the mixture obtained in step (c) homogeneously across the section of the reforming reactor; and e) reforming the mixture distributed in step (d) in the catalytic zone of the reforming reactor.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1002178A FR2960449B1 (en) | 2010-05-25 | 2010-05-25 | REACTOR FOR AUTOTHERMAL REFORMING OF GASOIL |
FR10/02178 | 2010-05-25 | ||
PCT/FR2011/000364 WO2011148068A2 (en) | 2010-05-25 | 2011-06-23 | Reactor for the autothermal reforming of diesel |
Publications (2)
Publication Number | Publication Date |
---|---|
AU2011257038A1 true AU2011257038A1 (en) | 2013-01-10 |
AU2011257038B2 AU2011257038B2 (en) | 2016-01-21 |
Family
ID=43426093
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2011257038A Active AU2011257038B2 (en) | 2010-05-25 | 2011-06-23 | Reactor for the autothermal reforming of diesel |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2576435B1 (en) |
AU (1) | AU2011257038B2 (en) |
ES (1) | ES2743725T3 (en) |
FR (1) | FR2960449B1 (en) |
WO (1) | WO2011148068A2 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102014018375A1 (en) * | 2014-12-15 | 2016-06-16 | Linde Aktiengesellschaft | reactor |
ES2828799T3 (en) | 2017-08-10 | 2021-05-27 | Sener Ing & Sist | System for reforming alcohol and hydrogen production, units of the system and their associated method |
EP3693338B1 (en) | 2019-02-07 | 2021-09-01 | Sener Ingenieria Y Sistemas, S.A. | High-pressure auto-thermal system for reforming alcohol and producing hydrogen, and method therefor |
FR3130642A1 (en) | 2021-12-16 | 2023-06-23 | Naval Group | REFORMER STRUCTURE |
FR3130639A1 (en) | 2021-12-16 | 2023-06-23 | Naval Group | REFORMER |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2630461A (en) * | 1953-03-03 | Production of acetylene by incom | ||
US4166834A (en) | 1977-09-27 | 1979-09-04 | John Zink Company | Air injector nozzle for secondary reformer |
US4865820A (en) * | 1987-08-14 | 1989-09-12 | Davy Mckee Corporation | Gas mixer and distributor for reactor |
US5980596A (en) * | 1997-04-25 | 1999-11-09 | Exxon Research And Engineering Co. | Multi-injector autothermal reforming process and apparatus for producing synthesis gas (law 565). |
US6444179B1 (en) * | 1999-10-05 | 2002-09-03 | Ballard Power Systems Inc. | Autothermal reformer |
AU2001231082A1 (en) * | 2000-01-24 | 2001-07-31 | International Fuel Cells, Llc | Autothermal fuel gas reformer assemblage |
US6596424B2 (en) * | 2001-03-30 | 2003-07-22 | General Motors Corporation | Apparatus for mixing fuel and an oxidant |
DE102004055425B4 (en) * | 2004-11-17 | 2007-06-14 | Forschungszentrum Jülich GmbH | Mixing chamber for a reformer and method for operating the same |
FR2924358B1 (en) * | 2007-11-30 | 2010-08-13 | Inst Francais Du Petrole | NEW REACTOR FOR REACTIONS AT VERY HIGH TEMPERATURE AND HIGH PRESSURE |
-
2010
- 2010-05-25 FR FR1002178A patent/FR2960449B1/en active Active
-
2011
- 2011-06-23 AU AU2011257038A patent/AU2011257038B2/en active Active
- 2011-06-23 WO PCT/FR2011/000364 patent/WO2011148068A2/en active Application Filing
- 2011-06-23 EP EP11743259.1A patent/EP2576435B1/en active Active
- 2011-06-23 ES ES11743259T patent/ES2743725T3/en active Active
Also Published As
Publication number | Publication date |
---|---|
FR2960449B1 (en) | 2012-08-03 |
AU2011257038B2 (en) | 2016-01-21 |
FR2960449A1 (en) | 2011-12-02 |
WO2011148068A2 (en) | 2011-12-01 |
EP2576435B1 (en) | 2019-08-14 |
EP2576435A2 (en) | 2013-04-10 |
ES2743725T3 (en) | 2020-02-20 |
WO2011148068A8 (en) | 2012-10-11 |
WO2011148068A3 (en) | 2012-03-22 |
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Legal Events
Date | Code | Title | Description |
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FGA | Letters patent sealed or granted (standard patent) |