AU2011235953B2 - RTV silicone composition offering rapid bond strength - Google Patents

Abstract

The present invention provides for a room temperature vulcanizable silicone sealant composition that rapidly achieves a usable green strength shortly after application. Such a composition that develops a usable green strength is useful in the manufacture of architectural elements employing glazing such as windows and doors and when such a composition is used in a manufacturing process, the manufacturing process can be accelerated relative to a process that uses a silicone sealant that does not rapidly achieve a usable green strength. SPEC (DIV)_926499_BDJ_1 1.10.2011

Description

AUSTRALIA Patents Act COMPLETE SPECIFICATION (ORIGINAL) Class Int. Class Application Number: Lodged: Complete Specification Lodged: Accepted: Published: Priority Related Art: Name of Applicant: General Electric Company Actual Inventor(s): David A. Williams, Reuben Correia, Gary Morgan Lucas Address for Service and Correspondence: PHILLIPS ORMONDE FITZPATRICK Patent and Trade Mark Attorneys 367 Collins Street Melbourne 3000 AUSTRALIA Invention Title: RTV SILICONE COMPOSITION OFFERING RAPID BOND STRENGTH Our Ref: 926499 POF Code: 884/141848 The following statement is a full description of this invention, including the best method of performing it known to applicant(s): - 1- RTV SILICONE COMPOSITION OFFERING RAPID BOND STRENGTH The present application is a divisional application from Australian patent application number 2005219829, the entire disclosure of which is incorporated herein by reference. CROSS REFERENCE TO RELATED APPLICATIONS This application claims the benefit of U.S. Provisional Application Serial No. 60/548,969, filed March 1, 2004. BACKGROUND OF THE INVENTION Moisture curable compositions are described in the art for their use as sealants. Moisture curable compositions require a significant amount of time, commonly several days, in which to fully cure before reaching maximum strength. In certain applications that utilize sealant in assembly line applications (e.g. window assembly), it is desirable to use a sealant that can rapidly develop green strength. The discussion of documents, acts, materials, devices, articles and the like is included in this specification solely for the purpose of providing a context for the present invention. It is not suggested or represented that any or all of these matters formed part of the prior art base or were common general knowledge in the field relevant to the present invention as it existed before the priority date of each claim of this application. Where the terms "comprise", "comprises", "comprised" or "comprising" are used in this specification (including the claims) they are to be interpreted as specifying the presence of the stated features, integers, steps or components, but not precluding the presence of one or more other features, integers, steps or components, or group thereof. BRIEF DESCRIPTION OF THE INVENTION The present invention provides a curable two part sealant composition comprising a first component (A) and a second component (B):

IA

wherein the sealant composition is a two-part room temperature vulcanizing silicone composition curable in the presence of moisture; said first component (A) comprising: (a) a diorganopolysiloxane in an amount ranging from 5 weight percent to 80 weight percent of the total composition wherein the silicon atom at each polymer chain end is silanol terminated; (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated; said second component (B) comprising: (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated; (c) an alkylsilicate in an amount ranging from 0.1 weight percent to 10 weight percent of the total composition: (d) a condensation catalyst in an amount ranging from 0.001 weight percent to 1 weight percent of the total composition; and (e) an alkoxysilane adhesion promoter in an amount ranging from 0.1 weight percent to 20 weight percent of the total composition: wherein the weight ratio of first component (A) to second component (B) is approximately 13 to 1; and wherein said sealant composition has a green strength of from 6.895 kPa to 517.1 kPa as measured by WPSTM test C-1221 after curing for a time period of from 1 minute to 60 minutes. 1B The present invention further provides a manufacturing process for manufacturing architectural elements having a rate of manufacture of said architectural elements said architectural elements comprising a curable two part sealant composition comprising a first component (A) and a second component (B): said first component (A) comprising: (a) a diorganopolysiloxane in an amount ranging from 5 weight percent to 80 weight percent of the total composition wherein the silicon atom at each polymer chain end is silanol terminated; (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated; said second component (B) comprising: (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated; (c) an alkylsilicate in an amount ranging from 0.1 weight percent to 10 weight percent of the total composition; (d) a condensation catalyst in an amount ranging from 0.001 weight percent to 1 weight percent of the total composition; and (e) an alkoxysilane adhesion promoter in an amount ranging from 0.1 weight percent to 10 weight percent of the total composition wherein the weight ratio of first component (A) to second component (B) is approximately 13 to 1; and 1 C said sealant having a green strength between 6.895 kPa and 517.1 kPa after curing for a period of time ranging from 1 minute to 60 minutes, wherein said manufacturing process produces said architectural elements at a rate of manufacture faster than a similar manufacturing process using a sealant having a green strength of 0 kPa after 60 minutes. The present invention provides for a sealant composition comprising: (a) a diorganopolysiloxane in an amount ranging from about 5 weight percent to about 80 weight percent wherein the silicon atom at each polymer chain end is silanol terminated; (b) diorganopolysiloxane in an amount ranging from slightly about 0 weight percent to about 35 weight percent wherein the silicon atom at each polymer chain end is alkyl terminated; (c) an alkylsilicate in an amount ranging from about 0.1 weight percent to about 10 weight percent; (d) a condensation catalyst comprising an organotin compound in an amount ranging from about 0.001 weight percent to about I weight percent; (e) an alkoxysilane (adhesion promoter) in an amount ranging from about 0.1 weight percent to about 20 weight percent; 1 D 'WO 2005/085356 PCT/US2005/006049 (f) a reinforcing filler(s) selected from the group consisting of ground, precipitated and colloidal calcium carbonates which is treated with compounds such as stearate or stearic acid; reinforcing silicas such as fumed silicas, precipitated silicas, silica gels and hydrophobized silicas and silica gels; crushed and ground quartz, alumina, aluminum hydroxide, titanium hydroxide, clays such as kaolin, bentonite or montmorillonite, diatomaceous earth, iron oxide, carbon black and graphite in an amount ranging from about I weight percent to about 80 weight percent; (g) a non-ionic surfactant selected from the group of polyalkyleneoxide modified organosilicone co-polymer in an amount ranging from about 0 weight percent to about 10 weight percent; wherein said sealant composition has a green strength of from about I psi to about 75 psi as measured by WPSTM test C-1221 after a time period of from about I minute to about 60 minutes. The present invention further provides for a manufacturing process for manufacturing architectural elements said architectural elements comprising the sealant of claim I said sealant having a green strength between about I psi and about 75 psi after a period of time ranging from about I mins. to about 40 minutes, wherein said manufacturing process produces said architectural elements at a rate faster than a similar process using a sealant having a green strength of 0 psi after 60 mins. DESCRIPTION OF THE INVENTION We now disclose sealant compositions that rapidly develop green strength. These compositions have as an advantage allowing the sealant user to handle, package and ship the assembled construction after shorter cure times without deleterious effect to the assembled construction, thus increasing production line speed and lowering product inventory. The term "green strength" as defined herein means a high modulus skin of sufficient strength that elements of a construction can be formed and will maintain the desired configuration even if handled, packaged, and shipped after relatively short times, without showing permanent deformation. 2 WO 2005/085356 PCT/US2005/006049 The present invention is comprised of a 2-part room temperature vulcanizing (RTV) silicone composition curable in the presence of moisture. A general description of each of the components of the 2-part formulation are given as follows: (a) a diorganopolysiloxane wherein the silicon atom at each polymer chain end is silanol terminated; whereby the viscosity of the siloxane is about 1,000 to 200,000 cps at 250C; (b) a diorganopolysiloxane wherein the silicon atom at each polymer chain end is alkyl terminated; whereby the viscosity of the siloxane is about 1,000 to 200,000 cps at 25)C; (c) an alkylsilicate (cross-linker); (d) a condensation catalyst comprising organotin compounds being preferred and more specifically dibutyltin dilaurate being preferred (e) an alkoxysilane adhesion promoter; (f) an optional reinforcing filler (use of more than I filler is common); (g) an optional non-ionic surfactant selected. More specifically, the "A or first component" of the 2-part formulation usually comprises (a), (b) (f), and (g). Additionally, the "B or second component" usually comprises (b), (c), (d), (e), and (f); however other variations on the partitioning of these components would be known to be useful by the skilled artisan. In a typical formulation, the ratio of "component A" to "component B" is adjusted to provide optimal performance properties, more typically the A to B ratio for the preferred embodiment is approximately 13 to I by weight. The compositions of the present invention may be prepared using other ingredients that are conventionally employed in RTV silicone compositions such as colorants, pigments and plasticizers, as long as they do not interfere with the desired properties. 3 WO 2005/085356 PCT/US2005/006049 The level of incorporation of the diorganopolysiloxane wherein the silicon atom at each polymer chain end is silanol terminated (a) ranges from about 5 weight % to about 80 weight %, more preferably from about 15 weight % to about 60 weight %, and most preferably from about 35 weight % to about 45 weight % of the total composition. The silanol terminated diorganopolysiloxane generally has the formula: MaDhD'e with the subscript a = 2 and b equal to or greater than I and with the subscript c zero or positive where M = (H O)3.x.yR',R 2 YSiO 1/2; with the subscript x = 0, 1 or 2 and the subscript y is either 0 or 1, subject to the limitation that x + y is less than or equal to 2, where R' and R 2 are independently chosen monovalent C I to C60 hydrocarbon radicals; where D = R 3

R

4 SiO ,n; where R 3 and R 4 are independently chosen monovalent Cl to C60 hydrocarbon radicals; where D'= R 5

R

6 SiO 2 2 ; where R 5 and R( are independently chosen monovalent Cl to C60 hydrocarbon radicals. The level of incorporation of the diorganopolysiloxane wherein the silicon atom at each polymer chain end is alkyl terminated (b) ranges from slightly above 0 weight % to about 35 weight %, more preferably from about 5 weight % to about 25 weight %, and most preferably from about 8 weight % to about 20 weight % of the total composition. . The alkyl terminated diorganopolysiloxane generally has the formula: M"eD" 1 D"'V 4 WO 2005/085356 PCT/US2005/006049 with the subscript e = 2 and f equal to or greater than I and with the subscript g zero or positive where M = R 7 R 8

R

9 SiOin; where R 7 , R 8 and R 9 are independently chosen monovalent Cl to C60 hydrocarbon radicals; where D"= R 'OR'SiO 2 n; where R' and R" are independently chosen monovalent Cl to C60 hydrocarbon radicals; where D"'= R 1 2 R 3 SiO 2 n; where R 2 and R11 are independently chosen monovalent Cl to C60 hydrocarbon radicals. The level of incorporation of the alkylsilicate (crosslinker, c) ranges from about 0.1 weight % to about 10 weight %, more preferably from about 0.3 weight % to about 5 weight %, and most preferably from about 0.5 weight % to about 1.5 weight % of the total composition. The alkylsilicate generally has the formula: (R ' 4 0)(R 5 0)(R ' 6 0)(R' 7 O)Si where R' 4 , R", R"' and R 7 are independently chosen monovalent Cl to C60 hydrocarbon radicals. The RTV silicone composition of the present invention also comprises a condensation catalyst (d). The condensation catalyst can be any of those known to be useful for facilitating crosslinking in silicone sealant compositions. The condensation catalyst may include metal and non-metal catalysts. Examples of the metal portion of the metal condensation catalysts useful in the present invention include tin, titanium, zirconium, lead, iron cobalt, antimony, manganese, bismuth and zinc compounds. 5 WO 2005/085356 PCT/US2005/006049 The tin compounds useful for facilitating crosslinking in silicone sealant compositions include: tin compounds such as dibutyltindilaurate, dibutyltindiacetate, dibutyltindimethoxide, tinoctoate, isobutyltintriceroate, dibutyltinoxide, dibutyltin bis-diisooctylphthalate, bis-tripropoxysilyl dioctyltin, dibutyltin bis-acetylacetone, silylated dibutyltin dioxide, carbomethoxyphenyl tin tris-uberate, isobutyltin triceroate, dirnethyltin dibutyrate, dimethyltin di-neodecanoate, triethyltin tartarate, dibutyltin dibenzoate, tin oleate, tin naphthenate, butyltintri-2-ethylhexylhexoate, and tinbutyrate. In one embodiment, tin compounds and (CH 17

)

2 SnO dissolved in (n C3H 9 0) 4 Si are used. In another embodiment, diorganotin bis @-diketonates are used. Other examples of tin compounds may be found in US 5,213,899, US 4,554,338, US 4,956,436, and US 5,489,479, the teachings of which are herewith and hereby specifically incorporated by reference. In yet another embodiment, chelated titanium compounds, for example, 1,3-propanedioxytitanium bis(ethylacetoacetate); di isopropoxytitanium bis(ethylacetoacetate); and tetra-alkyl titanates, for example, tetra n-butyl titanate and tetra-isopropyl titanate, are used. It is preferred that the condensation catalyst of the present invention is a metal catalyst. The preferred metal condensation catalyst is selected from the group consisting of tin compounds with dibutyltindilaurate being preferred. The level of incorporation of the condensation catalyst, component (d), ranges from about 0.001 weight % to about I weight %, more preferably from about 0.003 weight % to about 0.5 weight %, and most preferably from about 0.005 weight % to about 0.1 weight % of the total composition. The RTV silicone compositions of the present invention may also comprise an alkoxysilane or blend of alkoxysilanes as an adhesion promoter, the preferred combination being a blend of n-2-ami noethyl-3-aminopropyltrimethoxysi lane and 1,3,5-tris(trimethoxysilylpropyl)isocyanurate. Other adhesion promoters useful in the present invention are: n-2-aninoethyl-3-aminopropyltriethoxysilane, y aminopropyltriethoxysi lane, 6 WO 2005/085356 PCT/US2005/006049 y-aminopropyltri methoxysilane, aminopropyltrimethoxysi lane, bis-y trimethoxysilypropyl)ami ne, N-Phenyl-y-aminopropyltrimethoxysilane, triam i nofunctionaltri methoxysi lane, (-aminopropylmethyldiethoxysilane, 7- aminopropyl methyldiethox ysilane, methacryloxypropyltri methoxysilane, methylaminopropyltri methoxysilane, y-glycidoxypropylethyldimethoxysilane, y glycidoxypropyltrimethoxysi lane, y-gl ycidoxyethyltrimethoxysilane, -(3,4 epoxycyclohexyl)propyltrimethoxysilane, P-(3,4-epoxycyclohexyl) ethylmethyldimethoxysilane, isocyanatopropyltriethoxysilane, isocyanatopropylmethyldimethoxysilane, p-cyanoethyltrimethoxysilane, Y acryloxypropyltrimethoxysilane, -methacryloxypropylmethyldimethoxysilane, 4 amino-3,3,-dimethylbutyltrimethoxysilane, and n-ethyl-3-trimethoxysilyl-2 methylpropanamine. The level of incorporation of the alkoxysilane (adhesion promoter, e) ranges from about 0.1 weight % to about 20 weight %, more preferably from about 0.3 weight % to about 10 weight %, and most preferably from about 0.5 weight % to about 2 weight % of the total composition. The RTV (room temperature vulcanizable) silicone compositions of the present invention may also comprise a filler. The fillers useful in the present invention is a filler or mixture of fillers that is selected from those known to be useful in RTV silicone sealants. The fillers include ground, precipitated and colloidal calcium carbonates which is treated with compounds such as stearate or stearic acid; reinforcing silicas such as fumed silicas, precipitated silicas, silica gels and hydrophobized silicas and silica gels; crushed and ground quartz, alumina, aluminum hydroxide, titanium hydroxide, diatomaceous earth, iron oxide, carbon black and graphite or clays such as kaolin, bentonite or montmorillonite for example. Preferably, the filler is a calcium carbonate filler, silica filler or a mixture thereof. The type and amount of filler added depends upon the desired physical properties for the cured RTV silicone composition. The amount of filler useful in the present invention is from about 5 weight % to about 80 weight %, more preferably from about 7 'WO 2005/085356 PCTIUS2005/006049 20 weight % to about 60 weight %, and most preferably from about 37 weight % to about 49 weight % of the total composition. The filler may be a single species or a mixture of two or more species. Optional component (g) comprises a non-ionic surfactant compound selected from the group of surfactants consisting of polyethylene glycol, polypropylene glycol, ethoxylated castor oil, oleic acid ethoxylate, alkylphenol ethoxylates, copolymers of ethylene oxide (EO) and propylene oxide (PO) and copolymers of silicones and polyethers (silicone polyether copolymers), copolymers of silicones and copolymers of ethylene oxide and propylene oxide and mixtures thereof in an amount ranging from slightly above 0 weight % to about 10 weight %, more preferably from about 0.1 weight % to about 5 weight %, and most preferably from about 0.5 weight % to about 0.75 weight % of the total composition. The use of silicone polyether as a non-ionic surfactant is described in US 5,744,703 the teachings of which are herewith and hereby specifically incorporated by reference. Furthermore, these compositions can be prepared using either batch or continuous modes of manufacture. Preferably, the ingredients such as silicone polymer, reinforcing filler, cure catalyst, adhesion promoter, plasticizers, process aids, and other additives are combined in a continuous compounding extruder to produce the desired sealant composition. Both the "A component" and the "B component" are prepared in this manner. The continuous compounding extruder can be any continuous compounding extruder such as the twin screw Werner-Pfleiderer extruder, or a Buss, or P.B. Kokneader extruder. In the broadest conception of the present invention, all the ingredients may be mixed in the continuous compounding extruder, that is silanol polymer, filler, plasticizer, a condensation catalyst and an adhesion promoter, etc. In such a process, which is continuous, the extruder is operated at a range of 40* to 1000 C., but more preferably in the range of 500 to 80* C and the extruder is operated at a partial vacuum so as to remove volatiles during the mixing process. 8 'WO 2005/085356 PCT/US2005/006049 As used herein the term architectural element denotes a prefabricated or manufactured unit useful or used in construction comprising glazing and caulking or adhesive to bond the glazing to structural elements comprising the architectural element. As used herein the term glazing has its ordinary meaning, a meaning that is inclusive of glass and glass substitutes such as polyacrylates, specifically polymethylmethacrylate and polycarbonates and the like including but not limited to the transparent, translucent and opaque varieties of glazing. As used herein the term caulking or adhesive encompasses or comprises the silicone compositions of the present invention. As used herein structural elements are materials used for the construction of buildings, e.g. wood, stone, brick, steel, aluminum, brass, iron, copper, concrete, plastic, plastic covered wood or metal and the like. A non-limiting list of exemplary architectural elements comprises among others: doors containing one or more windows, prefabricated windows, sliding doors with one or more windows, folding doors with one or more windows, curtainwall, shop glazing, structural glazing and the like. The compositions of the present invention are curable compositions that rapidly develop a green strength after curing for a period of time. These compositions develop a green strength ranging from about I psi to about 75 psi as measured by WPSTM test C-1221 after curing for a time period ranging from about 1 minute to about 60 minutes, preferably these compositions develop a green strength ranging from about I psi to about 45 psi as measured by WPSTM test C- 1221 after curing for a time period ranging from about I minute to about 60 minutes, more preferably these compositions develop a green strength ranging from about I psi to about 35 psi as measured by WPSTM test C-1221 after curing for a time period ranging from about I minute to about 60 minutes, and most preferably these compositions develop a green strength ranging from about I psi to about 25 psi as measured by WPSTM test C 1221 after curing for a time period ranging from about 1 minute to about 60 minutes. The curing time period for measurement of green strength may range from about I minute to about 60 minutes, preferably for a time period ranging from about I minute to about 45 minutes, more preferably for a time period ranging from about I minute to about 30 minutes, and most preferably for a time period ranging from about I minute to about 15 minutes. 9 WO 2005/085356 PCT/US2005/006049 EXPERIMENTAL The following examples were prepared using the above continuous compounding process and are illustrative of the present invention. Example 1: This experiment demonstrates the rapid strength build offered by the sealants of the present invention with a typical commercial I-part window bedding sealant. As I-part sealants are well known to only slowly build strength, initial measurements were taken only after the sealant was allowed to cure for 24 hrs. The following data was generated using lap shear adhesion as measured by WPSTM test C-1221. In all instances, the lap shear adhesion data was generated using test panels comprising wood and glass substrates. The panels were prepared using 1 inch coupons overlapping V 2 inch using 1/16 inch of sealant in a wood to glass configuration. The samples were cured under 50%RH and 73F. Table 1: Comparison of strength build of experimental 2-part sealant versus commercial I -part Time (days) 2-part formulation (psi) I -part formulation (psi) 106 34 2 110 34 6 104 60 10 104 101 10 WO 2005/085356 PCT/US2005/006049 Table 2: Comparison of strength build of experimental 2-part sealant versus commercial I -part Adhesion Strength (psi) 2-part 1-part Time RapidStrengthTM SCS2511T 15 min 21 30 min 31 1hr 49 3 hrs 81 6 hrs 102 25 24 hrs 129 50 3days 122 52 7days 111 83 14 days 127 96 Note: ' denotes uncured ("wet") sealant with no measurable strength Example 2: This experiment is designed to demonstrate the rapid strength build of the primed and prinerless versions of the experimental sealants of the present invention. As described in example 2, the strength measurements of data were obtained using lap shear test specimens comprising vinyl to glass test panels. I I WO 2005/085356 PCT/US2005/006049 Table 3: Comparison of strength build of experimental 2-part sealant formulations Formulation I Formulation 2 (without primer) Time (with primer) Wood (psi) Vinyl (psi) Wood (psi) Vinyl (psi) 20 min. 14 7 21 9 40 min. 37 46 49 15 60 min. 58 88 78 23 180 min. 70 96 109 118 360 min. 76 138 134 88 I day 193 197 133 139 3 days 179 193 155 171 7 days 163 148 172 141 As shown in the above data (Table 3), these formulations demonstrate excellent strength build between wood and glass, as well as vinyl (plastic) and glass. Ingredients: Polymer 1: a mixture of polydimethylsiloxanes endblocked with hydroxyl groups and having an overall viscosity of approximately 10,000 cps comprising polymers described by the formula Precipitated Calcium Carbonate: a precipitated stearic acid treated calcium carbonate and having a particle size of approximately 0.07 microns. 12 'WO 2005/085356 PCT/US2005/006049 Plasticizer: polydimethylsiloxanes endblocked with trimethylsilyl groups and having a viscosity of approximately 100 cps. Rheology Additive: polyalkyleneoxide modified organosilicone co-polymer having a viscosity of about 100 to about 3000centipoise at 25C. Polymer 2: polydimethylsiloxanes endblocked with trimethylsilyl groups and having a viscosity of approximately 10,000 cps. Treated Silica: an octamethylcyclotetrasiloxane treated fumed silica filler with a surface area of approximately 200 1 20 m 2 /g. Pigment: a dispersion of approximately 50% by weight carbon black in polydimethylsiloxanes endblocked with trimethylsilyl groups Adhesion Promoter 1: aminoethylaminopropyltrimethoxysilane Adhesion Promoter 2: tris-trimethoxysilylpropylisocyanurate NPS: tetra-N-propylsilicate DBTDL: Dibutyltin dilaurate 13 WO 2005/085356 PCTfUS2005/006049 Table 4: Examples of experimental compositions Formulation I Formulation 2 Ingredients (weight %) Part I Polymer 1 42.8 42.8 Ppt. Calcium Carbonate 45.0 45.0 Plasticizer I 1.5 11.5 Rheology Additive 0.7 0.7 Part 2 Polymer 2 59.76 55.61 Treated Silica 11.6 10.6 Pigment 0.74 0.74 Adhesion Promoter 1 15.8 15.9 Adhesion Promoter 2 - 4.0 NPS 11.63 12.83 DBTDL 0.47 0.32 14 'WO 2005/085356 PCT/US2005/006049 GREEN STRENGTH MEASUREMENT BY LAP SHEAR Green strength was measured by the following procedure: The surfaces of all substrates (glass, vinyl, wood, etc) were cleaned prior to preparation of the lap shear test coupon. Glass and vinyl substrates were cleaned using a soap (Ajax®* Dish Liquid) and water solution. After cleaning, the surfaces of the substrates were immediately wiped dry with a clean Kimwipe*. The wood substrates were wiped using a dry Kimwipe*, The test specimens measuring I inch by 3 inches, were prepared using a jig assembly in order to ensure the reproducibility of the bond line thickness (1/16 of an inch) and overlap (0.50 inches) of the lap shear test specimen. The test specimens were cured under standard conditions 250 C and 50% relative humidity (RH) for the time specified. Performance measurements were obtained using a standard tensile tester. Each test specimen was pulled (at a crosshead speed of 0.5 in. per minute) to failure. The lap shear strength (psi) was calculated in accordance with the following formula: Lap Shear Strength (psi)= Peak load (lb.) Bonded Area (sq. in.) 15

Claims (24)

1. A curable two part sealant composition comprising a first component (A) and a second component (B) wherein the sealant composition is a two-part room temperature vulcanizing silicone composition curable in the presence of moisture: said first component (A) comprising: (a) a diorganopolysiloxane in an amount ranging from 5 weight percent to 80 weight percent of the total composition wherein the silicon atom at each polymer chain end is silanol terminated; (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated; said second component (B) comprising: (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated. (c) an alkylsilicate in an amount ranging from 0.1 weight percent to 10 weight percent of the total composition; (d) a condensation catalyst in an amount ranging from 0.001 weight percent to 1 weight percent of the total composition; and (e) an alkoxysilane adhesion promoter in an amount ranging from 0.1 weight percent to 20 weight percent of the total composition; 16 wherein the weight ratio of first component (A) to second component (B) is approximately 13 to 1; and wherein said sealant composition has a green strength of from 6.895 kPa to 517.1 kPa as measured by WPSTM test C-1221 after curing for a time period of from 1 minute to 60 minutes.

2. The sealant composition of claim 1 further comprising a reinforcing filler selected from the group consisting of ground calcium carbonate, precipitated calcium carbonate, colloidal calcium carbonate, calcium carbonate treated with compounds stearate or stearic acid; fumed silica, precipitated silica, silica gels, d hydrophobized silicas, hydrophilic silica gels; crushed quartz, ground quartz, alumina, aluminum hydroxide, titanium hydroxide, clay, kaolin, bentonite montmorillonite, diatomaceous earth, iron oxide, carbon black and graphite and mixtures thereof in an amount ranging from 1 weight percent to 80 weight percent.

3. The sealant composition of claim 1 or claim 2 further comprising a non-ionic surfactant selected from the group of surfactants consisting of polyethylene glycol, polypropylene glycol, ethoxylated castor oil, oleic acid ethoxylate, alkylphenol ethoxylates, copolymers of ethylene oxide and propylene oxide and copolymers of silicones and polyethers, copolymers of silicones and copolymers of ethylene oxide and propylene oxide and mixtures thereof in an amount ranging from slightly above 0 weight percent to 10 weight percent.

4. The sealant composition of claim 3 further wherein the non-ionic surfactant selected from the group of surfactants consisting of copolymers of ethylene oxide and propylene oxide, copolymers of silicones and polyethers, copolymers of silicones and copolymers of ethylene oxide and propylene oxide and mixtures thereof.

5. The sealant composition of claim 4 wherein the amount of the silanol terminated diorganopolysiloxane, component (a), ranges from in amount from 35 weight % to 45 weight % of the total composition. 17

6. The sealant composition of claim 5 wherein the amount of the alkyl terminated diorganopolysiloxane, component (b), ranges in amount from 8 weight % to 20 weight % of the total composition.

7. The sealant composition of claim 6 wherein the amount of the alkyl silicate, component (c), ranges in amount from 0.5 weight % to 1.5 weight % of the total composition.

8. The sealant composition of claim 7 wherein the amount of condensation catalyst, component (d), ranges in amount from 0.005 weight % to 0.1 weight % of the total composition.

9. The sealant composition of claim 8 wherein the amount of reinforcing filler, component (f), ranges in amount from 37 weight % to 49 weight % of the total composition.

10. The sealant composition of claim 9 wherein the amount of alkoxysilane adhesion promoter, component (e), ranges in amount from 0.5 weight percent to 2 weight percent of the total composition.

11. A manufacturing process for manufacturing architectural elements having a rate of manufacture of said architectural elements said architectural elements comprising a curable two part sealant composition comprising a first component (A) and a second component (B): said first component (A) comprising: (a) a diorganopolysiloxane in an amount ranging from 5 weight percent to 80 weight percent of the total composition wherein the silicon atom at each polymer chain end is silanol terminated; (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated; said second component (B) comprising: 18 (b) diorganopolysiloxane in an amount ranging from 5 weight percent to 35 weight percent of the total composition wherein the silicon atom at each polymer chain end is alkyl terminated; (c) an alkylsilicate in an amount ranging from 0.1 weight percent to 10 weight percent of the total composition; (d) a condensation catalyst in an amount ranging from 0.001 weight percent to 1 weight percent of the total composition; and (e) an alkoxysilane adhesion promoter in an amount ranging from 0.1 weight percent to 10 weight percent of the total composition wherein the weight ratio of first component (A) to second component (B) is approximately 13 to 1; and said sealant having a green strength between 6.895 kPa and 517.1 kPa after curing for a period of time ranging from 1 minute to 60 minutes, wherein said manufacturing process produces said architectural elements at a rate of manufacture faster than a similar manufacturing process using a sealant having a green strength of 0 kPa after 60 minutes.

12. The manufacturing process of claim 11 wherein said sealant has a green strength between about 6.895 kPa and about 310.3 kPa after curing for a period of time ranging from about 1 minute to about 60 minutes.

13. The manufacturing process of claim 12 wherein the sealant composition further comprises a reinforcing filler selected from the group consisting of ground calcium carbonate, precipitated calcium carbonate, colloidal calcium carbonate, calcium carbonate treated with compounds stearate or stearic acid; fumed silica, precipitated silica, silica gels, hydrophobized silicas, hydrophilic silica gels; crushed quartz, ground quartz, alumina, aluminum hydroxide, titanium hydroxide, clay, kaolin, bentonite montmorillonite, diatomaceous earth, iron oxide, 19 carbon black and graphite and mixtures thereof in an amount ranging from 1 weight percent to 80 weight percent.

14. The manufacturing process of claim 12 wherein the sealant composition further comprises a non-ionic surfactant selected from the group of surfactants consisting of polyethylene glycol, polypropylene glycol, ethoxylated castor oil, oleic acid ethoxylate, alkylphenol ethoxylates, copolymers of ethylene oxide and propylene oxide and copolymers of silicones and polyethers, copolymers of silicones and copolymers of ethylene oxide and propylene oxide and mixtures thereof in an amount ranging from slightly above 0 weight percent to 10 weight percent.

15. The manufacturing process of claim 14 wherein the non-ionic surfactant selected from the group of surfactants consisting of copolymers of ethylene oxide and propylene oxide, copolymers of silicones and polyethers, copolymers of silicones and copolymers of ethylene oxide and propylene oxide and mixtures thereof.

16. The manufacturing process of claim 14 wherein the amount of the silanol terminated diorganopolysiloxane, component (a), ranges from in amount from 35 weight % to 45 weight % of the total composition.

17. The manufacturing process of claim 16 wherein the amount of the alkyl terminated diorganopolysiloxane, component (b), ranges in amount from 8 weight % to 20 weight % of the total composition.

18. The manufacturing process of claim 17 wherein the amount of the alkyl silicate, component (c), ranges in amount from 0.5 weight % to 1.5 weight % of the total composition.

19. The manufacturing process of claim 18 wherein the amount of condensation catalyst, component (d), ranges in amount from 0.005 weight % to 0.1 weight % of the total composition.

20. The manufacturing process of claim 19 wherein the amount of reinforcing filler, component (f), ranges in amount from 37 weight % to 49 weight % of the total composition. 20 -

21. An architectural element comprising the cured composition of any one of claims 1 to 10 or manufactured by the process of any one of claims 11 to 20.

22. The architectural element of claim 21 wherein said architectural element a window, a door, structural glazing or a curtainwall.

23. The sealant composition of claim 1 substantially as hereinbefore described with reference to the Examples.

24. The manufacturing process of claim 11 substantially as hereinbefore described with reference to the Examples. 21