AU2010212522A1 - Measuring froth stability - Google Patents
Measuring froth stability Download PDFInfo
- Publication number
- AU2010212522A1 AU2010212522A1 AU2010212522A AU2010212522A AU2010212522A1 AU 2010212522 A1 AU2010212522 A1 AU 2010212522A1 AU 2010212522 A AU2010212522 A AU 2010212522A AU 2010212522 A AU2010212522 A AU 2010212522A AU 2010212522 A1 AU2010212522 A1 AU 2010212522A1
- Authority
- AU
- Australia
- Prior art keywords
- froth
- cell
- column
- stability
- measuring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/14—Flotation machines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/028—Control and monitoring of flotation processes; computer models therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/04—Froth-flotation processes by varying ambient atmospheric pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/06—Froth-flotation processes differential
Abstract
A method of measuring froth stability (as described herein) of a froth in a cell of a flotation circuit for a slurry of a mined mineral containing valuable material and gangue materials is disclosed. The method includes a step of measuring one or more than one froth stability parameter using a measurement column arranged to extend downwardly through the froth in the cell to a location below an interface between the froth and the slurry in the cell. A method of controlling the operation of a flotation cell that is based on the froth stability measurement method is also disclosed.
Description
AUSTRALIA Patents Act 1990 COMPLETE SPECIFICATION Divisional Patent Applicants: TECHNOLOGICAL RESOURCES PTY. LIMITED and UNIVERSITY OF MANCHESTER Invention Title: MEASURING FROTH STABILITY The following statement is a full description of this invention, including the best method for performing it known to us:
-IA
MEASURING FROTH STABILITY The present invention relates to recovering valuable material from mined minerals by means of froth 5 flotation of a slurry of the mined materials. The present invention relates particularly to a method of measuring froth stability in a cell of a flotation circuit for recovering valuable material from a 10 slurry of mined minerals containing valuable material and gangue material. The present invention also relates to an apparatus for measuring froth stability. 15 The present invention also relates to a method of controlling the operation of a flotation cell using froth stability as a control parameter for the method. 20 It has been long understood that the froth phase of a flotation cell has a significant influence on the overall performance of the flotation process. A froth is a three phase structure comprising air 25 bubbles, solids and water. The bubbles are defined by a thin water film or lamellae, which separates two bubbles, while the intersection of three lamellae results in the formation of a narrow water channel called a Plateau border. The entire froth is therefore made up of a 30 continuous network of narrow water channels in which water and solid particles can flow. The solids contained in the froth are either valuable material attached to lamellae or a mixture of valuable material and gangue material contained freely within the Plateau borders. 35 A froth is a highly dynamic system in which solids and water movement is governed by the following 1134051.2 (GHMatlrs) -2 processes: The flow of air bubbles from the pulp froth interface to the top surface of the froth. 5 Typically, 5-10% of the air entering the froth is carried over a cell weir into a concentrate launder and the other 90-95% leaves the top of the froth as bubbles burst. As the bubbles flow upwards they 10 carry valuable material which is directly attached to the bubble lamellae. The upward flow of bubbles also drags a portion of the water contained in Plateau borders upwards along with its load of entrained 15 particles (both valuable material and gangue material). Bubble coalescence. Water contained in the thin film lamellae defining each bubble 20 tends to flow towards the Plateau borders. As this takes place the lamellae become thin, and eventually break, resulting in the coalescence of two adjacent bubbles into a single larger bubble. The 25 coalescence process releases attached particles into the Plateau borders. The thinning and rupture of lamellae at the top surface of the froth results in bubbles bursting. This results in loss of air from 30 the froth and release of attached particles into the Plateau borders. The term "froth stability" is understood herein to mean the ability of bubbles in a froth to resist 35 coalescence and bursting. A more stable froth will have less coalescence i 1340512 (GHMatter) -3 and bursting events, a smaller mean bubble size and may carry more water. All of these factors will ultimately determine the structure and volume of the froth (water, solids and air) carried over the cell weir into the 5 concentrate launder and therefore the recovery of attached and unattached (carried in Plateau border) particles - in other words, the valuable material recovery and concentrate grade. 10 It is evident from the above-described processes that a more stable froth will recover a greater amount of valuable material attached to bubbles and within the Plateau borders. 15 It is also evident from the above that a more stable froth will also recover more gangue material. Accordingly, from a viewpoint of maximising recovery and concentrate grade, there is an optimum froth 20 stability for any given flotation cell and any given operating conditions for that cell. The term "operating conditions" is understood herein to mean: 25 (a) chemical conditions (frother, collector, pH and other modifiers or contaminants) of the cell; 30 (b) grade of hydrophobic particles in the cell feed (valuable material and gangue material); (c) slimes and clay content in the cell feed; 35 (d) particle size of the cell feed; 1134051_2 (GHMatters) -4 (e) air rate for the cell; and (f) pulp density of the slurry supplied to the cell. 5 Each of these variables can change rapidly or gradually over time and can significantly influence froth stability and the overall flotation performance. 10 A method by which froth stability can be measured online in a flotation circuit for the purposes of process monitoring and control would add great value to any flotation operation. 15 The present invention provides such a method. According to the present invention there is provided a method of measuring froth stability (as described herein) of a froth in a cell of a flotation 20 circuit for a slurry of a mined mineral containing valuable material and gangue material, which method includes a step of measuring one or more than one froth stability parameter using a measurement column arranged to extend downwardly through the froth in the cell to a 25 location below an interface between the froth and the slurry in the cell, and wherein the one or more than one froth stability parameter includes: (a) the rate or velocity of movement of froth 30 up the column from a pre-determined starting height to a maximum height of the froth in the column; and/or (b) the maximum height attained by the froth in 35 the column above a pre-determined starting height. 1134051_2 (GHMattm) -5 The froth stability parameter may be any parameter that provides information on the stability of the froth in the cell that can (a) be measured directly by means of the column or (b) be derived from measurements 5 made using the column. Preferably the method includes washing the column to collapse the froth in the column to the pre-determined starting height, for example the interface between the 10 slurry and the froth, and thereafter repeating the above described measurement step and measuring one or more than one froth stability parameter. According to the present invention there is also 15 provided an apparatus for measuring froth stability of a froth in a flotation cell in a plant and for controlling operating conditions of a flotation cell which includes: (a) a measurement column arranged to extend 20 downwardly through the froth in the cell to a location below an interface between the froth and the slurry in the cell; and (b) a means for measuring froth stability 25 parameters including: (i) the rate or velocity of movement of froth up the column from a pre determined starting height to a 30 maximum height of the froth in the column; and/or (ii) the maximum height attained by the froth in the column above a pre 35 determined starting height; and (c) a means for processing data measured 113,4051_2 (GHMattesm) -6 directly or indirectly from the column and adjusting one or more than one of the operating conditions of the cell (as described herein) to optimize cell 5 performance. According to the present invention there is also provided a method of controlling the operation of a flotation cell which includes the steps of: 10 (a) measuring froth stability (as described herein) of a froth in the cell in accordance with the method described above; 15 (b) inputting froth stability data into a model that relates froth stability and the performance of the cell (in terms of recovery of valuable material and concentrate grade) to assess the cell 20 performance; and (c) adjusting one or more than one of the operating conditions of the cell (as described herein) to optimize cell 25 performance. The term "froth stability data" is understood herein to mean data that is directly measured by means of the column or is derived from directly measured data. 30 Preferably the method includes repeating the measurement of the froth stability during the course of the operation of the cell and adjusting operating conditions of the cell based on the froth stability data. 35 The model may be any suitable model that relates froth stability and the performance of the cell (in terms 11340512 (GHMalers) -7 of recovery of valuable material and concentrate grade) to assess the cell performance. The model may be a fundamental model derived from 5 theoretical considerations. Alternatively, the model may be based on comparing measured froth stability data and data on the historical operation of the cell. 10 One particular model is a model that is being developed by the applicant. The development of the model has been supported 15 by testwork carried out by the applicant to determine how to measure selected froth stability parameters in a single laboratory batch flotation cell and along the rougher bank of a flotation circuit at one of the mines operated by the applicant. 20 As indicated above, the model relates froth stability and the performance of the cell (in terms of recovery of valuable material and concentrate grade). 25 The model is a fundamental model and is based on foam physics and interprets the effect of froth structure on flotation. The model links the flow rate of valuable material, gangue material, and water to froth structure. The mass flow rate of valuable material, gangue material, 30 and water are related to the flow rate of bubble surface area and the total volumetric flow rate of Plateau borders overflowing the weir. These last two parameters can be estimated through analysis of video images of the overflowing froth. 35 The testwork program carried out at the applicant's mine involved the use of a column 30cm square 1134051.2 (GHMatters) -8 by 165cm high constructed of perspex. The objective of the program was to investigate how to measure froth stability parameters. 5 The column was inserted into the pulp phase to a depth of 30cm and an operator manually recorded the level of the rising froth with time. At the end of the test, when the froth had 10 reached a stable maximum height, the data was entered into a spreadsheet and the appropriate parameters were calculated. Figure 1 shows a typical column froth height 15 versus time curve generated during the testwork. The graph has raw data as well as a "fitted model" for the data. The fitted model is a separate model to the previously described model. 20 Of significance is the close fit of the fitted model to the raw data. The fitted model has the form shown in equation (1) where Ho is the maximum height the froth reaches and T 25 is a fitted stability parameter.
H=H
0 (1-e't/) Equation (1) Other models may be appropriate also. 30 Figure 2 and 3 are graphs of column froth height versus time for selected operating conditions. What is clear from Figures 2 and 3 is that 35 alterations to operating conditions resulted in significantly different froth stability curves. These differences can be used to clearly explain differences in 1134051_2 (GHMatters) -9 metallurgical performance, ie recovery and concentrate grade, of a cell. An extension of the froth stability curves 5 discussed above comes with consideration of the bursting fraction (1 - a) of the froth. If all of the air entering the froth from the pulp was retained in the froth then the rise velocity 10 within the column would be equal to the superficial gas velocity Jg (where Jg equals the gas flow rate per unit area of the column). This would be the case if bubbles at the surface of the froth did not burst and release their contained air. This is obviously not the case with only a 15 small fraction of the airflow retained in the froth. It may be expected that the value of a in the column and the value of a for the entire cell at a given froth depth will be different. The relationship between a 20 in the column and the actual a achieved for the entire cell is the subject of current research. Given the considerations in the preceding paragraph, the following equation can be presented, 25 relating the froth rise velocity (u) to the superficial gas velocity and the fraction of air retained in the froth (a): U = Jg (1-a) Equation (2) 30 Given that the instantaneous rise velocity can be calculated from the froth stability curve and the superficial gas velocity can be measured, then the instantaneous bursting fraction (1-a) can be calculated 35 for a given froth height. The result is a plot of alpha versus height shown 1134051_2 (GHMatlers) - 10 in Figure 4. These graphs take the form: 5 c = ai(1-H/Ho) Equation (3) where a 1 is the fraction of airflow retained in the froth at a froth height of zero. 10 Using equations 1, 2 and 3 the following additional equations can be developed to assist with interpretation of the data: Ho = T J 9 a 1 Equation (4) 15 U = Jg a - H/t Equation (5) 1 = Ho/J 9 Equation (6) 20 where I is the dynamic froth stability factor. In summary, the above-described testwork determined how to measure two particular froth stability parameters, namely the maximum height attained by the 25 froth in the column and the rate or velocity of movement of froth up the column from a pre-determined starting height to a maximum height of the froth in the column. Figure 5 is a conceptual diagram of an apparatus 30 for measuring froth stability in a flotation cell in a plant and for controlling operating conditions of a flotation cell. The main, but not only, operating conditions that 35 can be adjusted in response to froth stability measurements include reagents (frother, collector, pH modifier or other modifier), air rate, pulp density, 1134051_2 (GHMatters) -11 particle size and ore blend. With reference to Figure 5, the apparatus includes a column (6) that is constructed from 300mm 5 diameter perspex pipe with a wear resistant and replaceable HDPE extension piece (9) which, in use, is inserted into the pulp in a cell. While the original column used in the testwork at 10 the applicant's mine was square, it is anticipated that a circular column will provide better movement of the froth as there is no interference from the corners. Having said this, a square column would still suffice. 15 The column (6) is constructed in a number of sections so the measurement height of the column can be reduced if necessary. The maximum height shown in Figure 5 will allow 20 for two metres of froth, which might typically be expected in a high grade rougher cell, whereas a shorter column might be used for a scavenger cell where less froth is generated. 25 Figure 5 illustrates a gridmesh walkway above the cell on which to secure the column (6). This may not always be the case and an alternate securing arrangement may be required. The column (6) is secured to the gridmesh via a securing plate (7) and the depth that the 30 column is inserted into the pulp can be adjusted slightly via the level adjustment bolts (8). When the column (6) is used at its maximum height the adjustable length tie down bars are required to 35 minimise any bending of the column as a result of the pulp movement at the base. 1134051_2 (GHMatters) -12 If the column is used in a shortened form the tie down bars may not be required. In use, the froth height inside the column (6) is 5 measured by an ultrasonic level sensor, although any other suitable means of continuously monitoring the froth level will suffice. In this case, the froth height data is monitored 10 by a commercially available Citect monitoring and control system, which collects the data and performs the calculation of the froth stability parameters described previously. 15 Any other suitable means of continuously logging and calculating the appropriate froth stability parameters for process control purposes will suffice. Froth stability data is supplied to the above 20 described model that relates froth stability and the performance of the cell (in terms of recovery of valuable material and concentrate grade) and the model assesses the cell performance and, if required, initiates adjustments to selected operating conditions of the cell to improve 25 the cell performance. Once the froth stability parameters are calculated to a satisfactory level of accuracy in a first measurement cycle, a water solenoid valve (2) is actuated 30 to wash down the froth. The measurement sequence, data input to the model, and adjustment of cell operating conditions is then repeated. Typically, the sequence requires a 20-60 minute period and can be repeated on a continuous or periodic basis during the operation of the 35 cell. The measurement sequence period may be any suitable period. 1134051.2 (GHMatters) - 13 Many modifications may be made to the preferred embodiment of the present invention described above without departing from the spirit and scope of the invention. 1134051_2 (GHMtIer)
Claims (6)
1. A method of measuring froth stability (as described herein) of a froth in a cell of a flotation 5 circuit for a slurry of a mined mineral containing valuable material and gangue material, which method includes a step of measuring one or more than one froth stability parameter using a measurement column arranged to extend downwardly through the froth in the cell to a 10 location below an interface between the froth and the slurry in the cell, and wherein the one or more than one froth stability parameter includes: (a) the rate or velocity of movement of froth 15 up the column from a pre-determined starting height to a maximum height of the froth in the column; and/or (b) the maximum height attained by the froth in 20 the column above a pre-determined starting height.
2. The method defined in claim 1 includes washing the column to collapse the froth in the column to the pre 25 determined starting height at the end of a measurement step and thereafter repeating the measurement step and measuring one or more than one froth stability parameter.
3. An apparatus for measuring froth stability of a 30 froth in a flotation cell in a plant and for controlling operating conditions of a flotation cell which includes: (a) a measurement column arranged to extend downwardly through the froth in the cell to 35 a location below an interface between the froth and the slurry in the cell; and 1134051_2 (GHMatters) - 15 (b) a means for measuring froth stability parameters including: (i) the rate or velocity of movement of 5 froth up the column from a pre determined starting height to a maximum height of the froth in the column; and/or 10 (ii) the maximum height attained by the froth in the column above a pre determined starting height; and (c) a means for processing data measured 15 directly or indirectly from the column and adjusting one or more than one of the operating conditions of the cell (as described herein) to optimize cell performance. 20
4. A method of controlling the operation of a flotation cell which includes the steps of: (a) measuring froth stability (as described 25 herein) of a froth in the cell in accordance with the method defined in claim 1 or claim 2; (b) inputting froth stability data into a model 30 that relates froth stability and the performance of the cell (in terms of recovery of valuable material and concentrate grade) to assess the cell performance; and 35 (c) adjusting one or more than one of the operating conditions of the cell (as 1134051_2 (GHMatter) -16 described herein) to optimize cell performance.
5. The method defined in claim 4 includes repeating 5 the measurement of the froth stability during the course of the operation of the cell and adjusting operating conditions of the cell based on the froth stability data.
6. The method defined in claim 4 or claim 5 wherein 10 the model is a model that relates froth stability and the performance of the cell (in terms of recovery of valuable material and concentrate grade) to assess the cell performance. 11 34051_2 (GHMatters)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2010212522A AU2010212522B2 (en) | 2003-03-13 | 2010-08-24 | Measuring froth stability |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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AU2003901142 | 2003-03-13 | ||
AU2003901142A AU2003901142A0 (en) | 2003-03-13 | 2003-03-13 | Measuring froth stability |
AU2004218778A AU2004218778A1 (en) | 2003-03-13 | 2004-03-12 | Measuring froth stability |
AU2010212522A AU2010212522B2 (en) | 2003-03-13 | 2010-08-24 | Measuring froth stability |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
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AU2004218778A Division AU2004218778A1 (en) | 2003-03-13 | 2004-03-12 | Measuring froth stability |
Publications (2)
Publication Number | Publication Date |
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AU2010212522A1 true AU2010212522A1 (en) | 2010-09-16 |
AU2010212522B2 AU2010212522B2 (en) | 2013-10-24 |
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AU2003901142A Abandoned AU2003901142A0 (en) | 2003-03-13 | 2003-03-13 | Measuring froth stability |
AU2004218778A Abandoned AU2004218778A1 (en) | 2003-03-13 | 2004-03-12 | Measuring froth stability |
AU2010212522A Ceased AU2010212522B2 (en) | 2003-03-13 | 2010-08-24 | Measuring froth stability |
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AU2003901142A Abandoned AU2003901142A0 (en) | 2003-03-13 | 2003-03-13 | Measuring froth stability |
AU2004218778A Abandoned AU2004218778A1 (en) | 2003-03-13 | 2004-03-12 | Measuring froth stability |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP1613434B1 (en) |
AT (1) | ATE509704T1 (en) |
AU (3) | AU2003901142A0 (en) |
DK (1) | DK1613434T3 (en) |
ES (1) | ES2371311T3 (en) |
PL (1) | PL1613434T3 (en) |
WO (1) | WO2004080600A1 (en) |
ZA (1) | ZA200507463B (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0719432D0 (en) * | 2007-10-04 | 2007-11-14 | Imp Innovations Ltd | Method of flotation control |
WO2012065221A1 (en) * | 2010-11-16 | 2012-05-24 | Technological Resources Pty. Limited | Controlling froth flotation |
GB2487344A (en) * | 2010-11-19 | 2012-07-25 | Imp Innovations Ltd | Controlling a froth flotation cell |
CA2822521C (en) | 2010-12-28 | 2018-06-12 | Akzo Nobel Chemicals International B.V. | Amine-containing formulations for reverse froth flotation of silicates from iron ore |
GB2491134A (en) * | 2011-05-23 | 2012-11-28 | Imp Innovations Ltd | Method and apparatus for froth flotation control for optimising gas recovery |
AU2013262465A1 (en) * | 2012-05-14 | 2014-11-27 | Technological Resources Pty. Limited | Controlling froth flotation |
CN113393432A (en) * | 2021-06-09 | 2021-09-14 | 紫金矿业集团股份有限公司 | Intelligent froth flotation detection system |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3474902A (en) * | 1968-09-26 | 1969-10-28 | Westinghouse Electric Corp | Froth height and liquid slurry level determination for a floatation cell |
AU548578B2 (en) * | 1981-08-28 | 1985-12-19 | Nauchno-Proizvodstvennoe Obiedinenie "Sojuztsvetmetavtomatica" | Froth flotation |
US4552651A (en) | 1983-11-14 | 1985-11-12 | Conoco Inc. | Control of froth cell performance through the use of differential bubbler tubes |
SU1717237A1 (en) | 1989-07-05 | 1992-03-07 | Институт Горной Механики Им.Г.А.Цулукидзе | Device for adjusting flotation |
FR2677768B1 (en) * | 1991-06-11 | 1994-08-05 | Agronomique Inst Nat Rech | DEVICE FOR CHARACTERIZING THE FOAMING PROPERTIES OF AN AT LEAST PARTIALLY SOLUBLE PRODUCT. |
AU1590901A (en) | 1999-11-12 | 2001-06-06 | Baker Hughes Incorporated | Froth flow measurement system |
US6778881B1 (en) * | 1999-11-24 | 2004-08-17 | Outokumpu Oyj | Monitoring and control of a froth flotation plant |
-
2003
- 2003-03-13 AU AU2003901142A patent/AU2003901142A0/en not_active Abandoned
-
2004
- 2004-03-12 EP EP04719877A patent/EP1613434B1/en not_active Expired - Lifetime
- 2004-03-12 ES ES04719877T patent/ES2371311T3/en not_active Expired - Lifetime
- 2004-03-12 AT AT04719877T patent/ATE509704T1/en not_active IP Right Cessation
- 2004-03-12 WO PCT/AU2004/000311 patent/WO2004080600A1/en active Application Filing
- 2004-03-12 PL PL04719877T patent/PL1613434T3/en unknown
- 2004-03-12 AU AU2004218778A patent/AU2004218778A1/en not_active Abandoned
- 2004-03-12 DK DK04719877.5T patent/DK1613434T3/en active
-
2005
- 2005-09-28 ZA ZA200507463A patent/ZA200507463B/en unknown
-
2010
- 2010-08-24 AU AU2010212522A patent/AU2010212522B2/en not_active Ceased
Also Published As
Publication number | Publication date |
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AU2010212522B2 (en) | 2013-10-24 |
EP1613434B1 (en) | 2011-05-18 |
DK1613434T3 (en) | 2011-09-05 |
ATE509704T1 (en) | 2011-06-15 |
AU2003901142A0 (en) | 2003-03-27 |
AU2004218778A1 (en) | 2004-09-23 |
WO2004080600A1 (en) | 2004-09-23 |
EP1613434A4 (en) | 2007-07-04 |
PL1613434T3 (en) | 2012-02-29 |
ZA200507463B (en) | 2006-12-27 |
EP1613434A1 (en) | 2006-01-11 |
ES2371311T3 (en) | 2011-12-29 |
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Owner name: TECHNOLOGICAL RESOURCES PTY. LIMITED; CILLIERS, JO Free format text: FORMER APPLICANT(S): TECHNOLOGICAL RESOURCES PTY. LIMITED; UNIVERSITY OF MANCHESTER |
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