AU2009286309B2

AU2009286309B2 - A novel method for production of iron ore concentrates suitable for iron and steel making processes.

Info

Publication number: AU2009286309B2
Application number: AU2009286309A
Authority: AU
Inventors: Tamal Kanti Ghosh; C. Raghu Kumar
Original assignee: Tata Steel Ltd
Current assignee: Tata Steel Ltd
Priority date: 2008-08-30
Filing date: 2009-08-28
Publication date: 2014-03-06
Anticipated expiration: 2029-08-28
Also published as: WO2010023692A1; WO2010023692A8; AU2009286309A8; BRPI0908735A2; ZA201006077B; AU2009286309A1; CN102317481A

Abstract

A method for production of iron ore concentrates comprising the steps of: crushing low grade ore, slimes and other deposits to produce iron ore particle of the size less than 1.5 mm; subjecting the said particles to the step of selective separation to isolate iron ore mineral from gangue minerals; and obtaining enriched ore with high iron content from (60% to 67%) using low intensity magnetic separator (LIMS) and high intensity magnetic separator (HIMS).

Description

WO 20101023692 PCT/IN2009/000474 TITLE: A NOVEL METHOD FOR PRODUCTION OF IRON ORE CONCENTRATES SUITABLE FOR IRON AND STEEL MAKING PROCESSES. FIELD OF THE INVENTION This invention relates to a novel method for production of iron ore concentrates 5 suitable for iron and steel making processes from iron ore deposits. Consequently this invention further relates to removal of the gangue minerals present in the ore bodies. These are achieved by using hindered settling classification techniques followed by magnetic separator on the basis of their physical properties. BACKGROUND OF THE INVENTION 10 Commonly run of mine (ROM) iron ore minerals are not directly used in iron and steel making processes. Till the recent past the high quality iron ore deposits are abundant all over the world. However, exponential increase in demand for steel all over the world is rapidly depleting above kind of high grade iron ore deposits. Hence, in search of alternative source of iron ores, the steel industries are forced to use the 15 low grade ores, mine tailings (slimes) and other deposits with high iron content as the source of raw materials. But these types of ore deposits demand new methods of beneficiation techniques which can generate the suitable quality of iron ore concentrates for iron and steel making processes because of higher concentration of gangue minerals than that in high quality iron ores. The most common methods so 20 far used in iron ore industry for treating these ores are crushing and sizing followed by gravity concentration (Jigs, Tables, etc) and magnetic separations. But these methods are not suitable for all types of ores and report appreciable loss of iron value in the tailings (lower recovery). Also the flow sheets are complex with series of unit operations which also makes it less attractive to economics. Since concentration 25 of gangue is high in low grade deposits some times this creates complex textural relationship with iron ore minerals due to complicated geological conditions to form 1 WO 20101023692 PCT/IN2009/000474 the ore bodies. Post formation processes such as weathering of such deposits some times results in formation of coatings made up of oxyhydroxyde minerals around iron ore minerals. These coatings are difficult to remove by conventional beneficiation techniques including magnetic operations. Therefore a novel method is 5 developed to beneficiate variety of iron ore deposits, products various stages of mines and beneficiation plant and other deposits containing sizable iron content. OBJECTS OF THE INVENTION An object of this present invention to propose a novel method for production of iron ore concentrates by selectively reducing the gangue minerals; 10 Another object of this invention is to propose a suitable beneficiation process for treating various types of iron ore deposit, slimes, tailings and other deposits containing high iron values; Further object of this invention is to propose the techniques of hindered settling classification on the basis of physical properties of iron ore minerals and gangue 15 minerals; Still further object of this invention is to propose hindered settling classification for oxidized ore. BRIEF DESCRIPTION OF THE PRESENT INVENTION: According to this invention there is provided a method for production of iron ore 20 concentrate comprising the steps of: crushing low grade ore, slimes and other deposits to produce iron ore particle of the size less than 1.5 mm; 2 WO 20101023692 PCT/IN2009/000474 Subjecting the said particles to the step of selective separation to isolate iron ore mineral from gangue minerals; and Obtaining enriched ore with high iron content from (60% to 67%) using low intensity magnetic separator (LIMS) and high intensity magnetic separator (HIMS). 5 BRIEF DESCRIPTIN OF THE ACCOMPANYING DRAWING: The invention is explained in greater details with the accompanying drawing: Figure 1: shows the textural relationship between iron ore minerals and gangue minerals. Figure 2: shows the proposed flow sheet for iron ore which is used for the 10 development of present invention. Figure 3: shows particle size distribution of underflow fraction and overflow fraction of the hinder settling classifier. DETAILED DESCRIPTION OF THE INVENTION In iron ore deposits hematite, magnetite and goethite are principle iron bearing 15 minerals. Based on the concentration of these minerals deposits are commonly classified into two types such as hematite and magnetite. Common gangue minerals are silicates and carbonates. Textural relationships between of these gangue minerals and ore minerals are dictated by geological conditions during the formation of the deposits and subsequent hydrothermal alterations and weathering. 20 Therefore it is vital to understand the detailed textural relationships and their effect on liberation analysis of these ore bodies. For this invention state of the art equipments were used to carryout detailed textural and liberation analysis. Also it is 3 WO 20101023692 PCT/IN2009/000474 identify the type of gangue minerals (quartz, alumino silicates, calcite, dolomite, oxyhydroxy minerals) and their physical properties. This data was used to select the comminution (crushing and grinding) parameters and subsequent unit operation. Iron ore minerals are commonly heavier than gangue minerals and also their 5 crushing properties are different compared to associated gangue minerals due to difference in hardness and cleavage. Therefore, in comminution the gangue minerals reduce to finer size whereas most of iron ore minerals form coarse size. In this inventive process, the iron ore minerals and gangue ininerals are separated by using difference in their physical properties, size and density. When the solids 10 particles are dropped in the fluid medium they settle according to the different in size, shape and density (buoyancy force). In the hinder settling classification, the separation of these settling solid particles in fluid medium is controlled by adjusting a flow and density of fluid medium (pseudo liquid formed by solid suspended in the medium). In this process, the heavier and coarser particles settles down below 15 fluidized zone and termed as an underflow fraction which is collected from the bottom of the classifier. On the other hand, the lighter and finer particles flows along with the fluid medium from the side of the classifier and this fraction is called overflow fraction. In this invention, the size distribution of feed particles was controlled in the range of 20 0 - 1 mm size and velocity of fluid medium (teeter water) was adjusted in innovative way to separate heavy and large iron ore minerals from lighter and fine gangue minerals. The teeter water flow rate depends on the design parameters of the unit (hinder settling classification). In present invention, the iron ore minerals with > 75 microns size and 4 - 5.5 gm/cc density were collected as a underflow fraction and in 25 overflow fraction the gangue minerals with 75 - 200 microns size and 2 - 4 gm/cc density were reported. An exemplary embodiment of the present invention provides a novel method for simultaneously desliming the ore minerals with beneficiation. In view of the 4 WO 20101023692 PCT/IN2009/000474 association of gangue minerals and their fine size range (generated during the comminution), the de-sliming operation is generally carried out after size reduction to remove the slimes, the separation of which is difficult in subsequent beneficiation unit operations. The flow of fluid medium and attritioning effect caused by particle 5 movement was used in innovative way to remove the coatings on the ore minerals and also to de-slime. Hence, the hindered settling classifier is best option as compared to the conventional de-sliming operations like cyclones because also acts as concentrating unit operation by separating gangue phases on the basis of particle size and density difference. 10 One of the major advantages of this innovative process is simultaneously concentrating magnetite and hematite ore minerals. When ore body contains magnetite and hematite minerals, in conventional beneficiation process (after de sliming), first magnetite is separated from the feed using low intensity magnetic separator (LIMS) and then the non-magnetic fraction of this process is further 15 treated in high intensity magnetic separator (HIMS) to recover the hematite ore minerals. This two step process is required as magnetite is ferromagnetic and hematite is paramagnetic minerals. In both magnetic separation techniques, more than two cycles (steps) are essential to achieve the desired quality of concentrates. Hence, in conventional process the loss of Fe values (Fe recovery) is much higher 20 due to three stages of operations namely de-slime, LIMS and HIMS. On the other hand, the innovative process can simultaneously perfumes de-sliming and recovery of both hematite and magnetite in one step, and thereby generate a desired quality concentrates with higher Fe recovery values. In the present invention, for achieve further improvement in Fe values (grade of the 25 concentrate) the additional beneficiation of underflow of hinder settling classifier is carried out by using conventional techniques. The magnetic and gravity separation techniques were used in present invention to recover Fe values from overflow fraction of hinder settling classifier. 5 EXAMPLE: Weathered Magnetite ore (Fe distribution -50% Magnetite, 30% hematite and 20% goethite) The experiments were carried out using this novel process and using magnetite ore containing 55% to 65% of iron. In one trial, 1 tonne of ROM was crushed and ground to less than 1 mm 5 size and then was treated in hinder settling classifier. The experimental conditions were like feed pulp density 20 - 30% wt, feed rate 0.1 - 0.5 t/hr, teeter bed pressure 0.04 - 0.09 bar, and teeter water flow rate 3 -12 LPM. The concentrate with 64 - 67.5% Fe was achieved by this process. The results of experiments (hindered settling classifier) are depicted in Figure 3. The overflow fraction was treated in LIMS and/or HIMS and about 60% of ore minerals were 0 separated as a magnetic fraction. The underflow concentrate of ranging from 64% to 66% Fe was also treated in LIMS and/or HIMS to generate concentrate of +67% Fe grade. The term "comprise" and variants of the term such as "comprises" or "comprising" are used herein to denote the inclusion of a stated integer or stated integers but not to exclude any other [5 integer or any other integers, unless in the context or usage an exclusive interpretation of the term is required. 6

Claims

1. A method for production of iron ore concentrates comprising the steps of: crushing low grade ore, slimes and other deposits to produce iron ore particles of a size less than 1.5 mm; subjecting said particles to the step of selective separation to isolate iron ore mineral from gangue minerals; and obtaining enriched ore with a high iron content of 60% to 67% using low intensity magnetic separator (LIMS) and high intensity magnetic separator (HIMS).

2. The method as claimed in claim 1 wherein the step of selective separation is done by using hindered settling classifiers.

3. The method as claimed in claim 1 or claim 2 wherein the iron ore are selected from magnetite, hematite, weathered iron ores, low grade iron ores, slimes, mine fines, beneficiation tailings, and other Fe containing ores and their combinations.

4. The method as claimed in claim 2, wherein the desired feed size for hinder settling is between 0-1 mm size.

5. The method as claimed in any one of claims 1 to 4, wherein said iron ore concentrates comprise 64 to 67.5% Fe (Total) with Fe recovery values ranging from 80-90%.

6. The method as claimed in claim 5, wherein said Fe (Total) is bulk concentration of iron in ore.

7. A method for production of iron ore concentrates as defined in claim 1, and substantially as hereinbefore described with reference to the accompanying example and Figure 2. Dated: 11 February 2014 7