AU2007207277B2 - A high efficiency purifying method for recycling coal slurry water - Google Patents

A high efficiency purifying method for recycling coal slurry water Download PDF

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Publication number
AU2007207277B2
AU2007207277B2 AU2007207277A AU2007207277A AU2007207277B2 AU 2007207277 B2 AU2007207277 B2 AU 2007207277B2 AU 2007207277 A AU2007207277 A AU 2007207277A AU 2007207277 A AU2007207277 A AU 2007207277A AU 2007207277 B2 AU2007207277 B2 AU 2007207277B2
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AU
Australia
Prior art keywords
water
coal slurry
hardness
slurry water
water quality
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AU2007207277A
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AU2007207277A1 (en
Inventor
Jiongtian Liu
Mingqing Zhang
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China University of Mining and Technology CUMT
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China University of Mining and Technology CUMT
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5209Regulation methods for flocculation or precipitation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/05Conductivity or salinity
    • C02F2209/055Hardness

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Description

A High Efficiency Purifying Method for Recycling Coal Slurry Water Field of the Invention The present invention relates to a high-efficiency clarifying purifying method for recycling coal slurry water, which is especially applicable to recycling coal slurry water that is difficult to purify, and is also applicable to treatment of industrial waste water that consists of substances similar to coal slurry water. Background of the Invention The recycling coal slurry water in coal washery is difficult to purify due to the following reasons: 1) the recycling coal slurry water has high content of clay minerals, which tend to sludge into fine particles with negative charges and thereby cause the recycling coal slurry water to enter into a strongly dispersed state; 2) the charge particles adsorb positive ions in water severely that degrades the water quality and aggravate settlement stability of the fine particles in water; 3) the recycling coal slurry water has low hardness and high clay content, and causes the fine particles to circulate and aggregate in water. At present, polymeric flocculants are usually used to flocculate and settle coal slurry water. Though polymeric flocculants can realize the coal slurry water settlement theoretically, the technique has the following drawbacks in actual applications: 1) itis hard to clarify the coal slurry water coal. The coal slurry water contains a great deal of fine particles. If a small amount of flocculating agent is used, some fine particles will be left and can't be captured during the flocculation process; if a large amount of flocculating agent is used, it will be infeasible in economic aspect, though the coal slurry water can be purified; therefore, the flocculation result is not ideal; 2) the flocculating agent is consumed heavily and steady operation of the system can't be ensured. The coal slurry water in coal washery is usually heavy in volume and circulates at a high rate; therefore, a great deal of flocculating agent has to be added for purifying the coal slurry water thoroughly. Due to the fact that the fluctuations in volume of coal slurry water and content of solid particles are heavy, the technique can't ensure stable content of the recycling coal slurry water and thereby will have influence on stable operation of the system; 3) the cost of coal slurry water treatment is high. A great deal of flocculating agent aggregates with the coal slurry and then is discharged along with the coal slurry, and is not recovered and reused; therefore, the cost of flocculating agent in coal slurry water treatment is very high; 4) the monomers in flocculating agent have some toxicity and will cause secondary contamination. The working principle of polymeric flocculant technique is adsorption and bridging. The present invention utilizes a cheap material and implements purification of coal slurry water by water quality adjustment and control, and therefore has high economical efficiency and applicability. Summary of the Invention In view of the drawbacks in the prior art, the present invention provides a high efficiency purifying method for recycling coal slurry water, which has strong purification effect, consumes less agent, doesn't cause secondary contamination, and low in cost. To attain the object, the present invention employs the following technical scheme: adding adjustment reagent of water quality into the coal slurry water, wherein, the adjustment reagent of water quality can be mineral flocculant or compound powder of soluble calcium salts or magnesium salts, or waste water with hardness higher than 10.0 mmol/L and turbidity lower than 5 FTU can be used. The adding quantity of the adjustment reagent of water quality is determined by detecting the hardness of the recycling coal slurry water; when the detection result of water hardness is lower than the critical value, the adjustment reagent of water quality is added or added further; the critical value of water hardness is the critical water hardness for settlement of the coal slurry water, and is obtained by measurement during operation of the coal slurry water system; the mineral flocculant or the compound powder of soluble calcium salts or magnesium salts is added at a location where the water flow is rapid and favorable for dissolution of the power agent. The adding quantity of the mineral flocculant or the compound powder of soluble calcium salts or magnesium salts can be calculated with the following formula: m g/L = (Cstd-C) mmol/L + p mmol/g, wherein, Cstd is the critical water hardness, C is the hardness of the recycling coal slurry water, and p is the content of soluble calcium ions or magnesium ions in the adjustment reagent of water quality. The adding quantity of the waste water in high hardness and low turbidity can be calculated with the following formula: V L/L = (Cstd - C) mmol/L (C' - Cstd) mmol/L, wherein, Cstd is the critical water hardness, C is the hardness of the recycling coal slurry water, and C' is the hardness of the waste water. The high efficiency purifying method for recycling coal slurry water provided in the present invention has the following beneficial efficacies: 1) It provides a good water quality environment, which improves settling characteristics of the particles. By increasing water hardness through water quality modification, most of the fine particles agglomerate and settle. Compared to macromolecular flocculi, the agglomerates are in high density and settle quickly, so that the coal slurry water is purified completely, and the system can operate stably; 2) It consumes less adjustment reagent of water quality and ensures stable operation of the system. As the coal slurry water circulates, the water hardness fluctuations are very low; therefore, after the water quality is stabilized, the consumption of the adjustment reagent of water quality is very low. The stable water quality ensures clear coal slurry water circulation and thereby keeps the system operating stably; 2 3) It consumes less agent and is low in cost. Natural mineral substances, soluble salts, and waste water in low turbidity are low in cost; in addition, after the system is stabilized, little agents is added; therefore, the cost is very low. 4) It will not cause secondary contamination and ensures a "green" coal slurry water treatment process. The adjustment reagent of water quality adjusts the settlement environment with calcium ions and magnesium ions, and therefore will not cause secondary contamination. Detailed Description of the Embodiments The high efficiency purifying method for recycling coal slurry water provided in the present invention is to add adjustment reagent of water quality into the coal slurry water. The adding quantity of the adjustment reagent of water quality is determined by detecting the hardness of the coal slurry water; when the detection result is lower than the critical value, add the adjustment reagent of water quality which can be mineral flocculant or soluble calcium salts or magnesium salts, wherein the mineral flocculant can be natural plaster; alternatively, waste water in high hardness and low turbidity can be used as adjustment reagent of water quality. The powder agent can be added at a location where the water flow is rapid and favorable for dissolution of the powder agent in the coal slurry water system, such as the overflow weir of the concentrating equipment. An embodiment is as follows: If the adjustment reagent of water quality is mineral flocculant or compound power of soluble calcium salts or magnesium salts: 1. First, ascertain the water quality of the coal slurry water. Suppose the critical hardness for coal slurry water purification is 10.0 mmol/L and the actual hardness of the recycling coal slurry water is measured as 2.Ommol/L with a hardometer when the system operates stably, the measured hardness is lower than the critical value, and adjustment reagent of water quality should be added; 2. Determine the adding quantity of the adjustment reagent of water quality. Suppose the content of soluble calcium ions and magnesium ions in the adjustment reagent of water quality is measured as 20.Ommol/g with a hardometer, the adding quantity of the adjustment reagent of water quality can be calculated with the following formula: m g/L = (Cstd - C) mmol/L + p mmol/g, wherein, Cstd is critical water hardness, C is hardness of the recycling coal slurry water, and P is the content of soluble calcium ions and magnesium ions in the adjustment reagent of water quality. In this embodiment, it is (10.0 - 2.0) mmol/L + 20.0 mmol/g = 0.4 g/L. The adjustment reagent of water quality can be added according to the calculation result. If the adjustment reagent of water quality is waste water with hardness higher than 10.0 mmol/L and turbidity lower than 5 FTU: 3 1. First, ascertain the water quality of the coal slurry water. Suppose the critical hardness for coal slurry water purification is 10.0 mmol/L and the actual hardness of the recycling coal slurry water is measured as 2.Ommol/L with a hardometer when the system operates stably, the measured hardness is lower than the critical value, and adjustment reagent of water quality should be added; 2. Determine the adding quantity of the adjustment reagent of water quality. Suppose the hardness of the waste water is measured as 20.Ommol/L with a hardometer, the adding quantity of the adjustment reagent of water quality can be calculated with the following formula: V L/L = (Cstd - C) mmol/L + (C' - Cstd) mmol/L, wherein, Cstd is the critical water hardness, C is the hardness of the recycling coal slurry water, and C' is the hardness of the waste water. In this embodiment, it is (10.0 - 2.0) mmol/L + (20.0 - 10.0) mmol/L = 0.8 L/L. The waste water can be added according to the calculation result. The working principle is as follows: the substances that are difficult to settle in coal slurry water are mainly clay minerals and coal, both of which carry strong negative charges and are repulsive mutually, and thereby increase stability of the water system. The powder-form adjustment reagent of water quality is dissolved in the coal slurry water and releases calcium ions and magnesium ions. A great deal of calcium ions and magnesium ions are dissolved in high-hardness waste water itself. The attachment of calcium ions and magnesium ions to the surfaces of coal and clay particles compresses the double charged layers on the particle surfaces and reduces the Zeta potential of the particles, and thereby increases the efficiency of collision adhesion among the particles and facilitates formation of agglomerates in high density. The agglomerates settle quickly. In that way, the object of purifying coal slurry water is attained. The two types of ions are not affected by external factors severely and can exist stably, and function as the water recycles. Therefore, after the water quality is stabilized, little adjustment reagent of water quality is consumed. 4

Claims (1)

10.0 mmol/L and turbidity lower than 5 FTU: a) first, ascertaining the water quality of the coal slurry water, measuring the critical hardness CStd for coal slurry water purification; b) then, measuring the actual hardness C of the recycling coal slurry water with a hardometer, adding adjustment reagent of water quality if the measured hardness is lower than the critical value; c) finally, determining the adding quantity of the adjustment reagent, measuring the hardness of the waste water C' in high hardness and low turbidity, the adding quantity of the adjustment reagent can be calculated with V L/L = (Cstd - C) mmol/L + (C' - Cstd) mmol/L. 5
AU2007207277A 2006-01-20 2007-01-22 A high efficiency purifying method for recycling coal slurry water Ceased AU2007207277B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN200610037993.5 2006-01-20
CNB2006100379935A CN100429156C (en) 2006-01-20 2006-01-20 Highly efficient clarification method of circulating black water
PCT/CN2007/000236 WO2007082492A1 (en) 2006-01-20 2007-01-22 A high efficiency purifying method for recycling coal slurry water

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AU2007207277A1 AU2007207277A1 (en) 2007-07-26
AU2007207277B2 true AU2007207277B2 (en) 2011-03-03

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AU (1) AU2007207277B2 (en)
WO (1) WO2007082492A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104229963B (en) * 2014-09-16 2016-05-18 中国矿业大学(北京) A kind of flocculating agent of black water clarification adds control method
CN104588199B (en) * 2015-01-19 2017-05-31 中国矿业大学 Argillization suppressing method during a kind of coal washing
CN105903547A (en) * 2016-05-16 2016-08-31 中国矿业大学 Coal slime argillization inhibition method based on adjustment and control of solution chemical properties
CN112239253A (en) * 2020-06-16 2021-01-19 鄂尔多斯市中钰泰德煤炭有限公司 Efficient coal slurry pretreatment system and method for power coal preparation plant

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB481499A (en) * 1936-06-06 1938-03-07 Frederick George Francis Improvements in and relating to the flocculation of solid in liquid suspensions
CN1180667A (en) * 1996-10-22 1998-05-06 中国矿业大学 Method for using mineral coagulant
WO1999022871A1 (en) * 1997-11-03 1999-05-14 Selective Oil Agglomeration Process Pty. Ltd. Controlled production and recovery of fine-coal agglomerates
US20020139754A1 (en) * 2001-02-16 2002-10-03 Miller Olen O. Method and apparatus for dewatering coal tailings and slurries and removing contaminants therefrom

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1048698C (en) * 1990-11-10 2000-01-26 柳生 Compound water purifying agent and making method as well as application thereof
CN1055451C (en) * 1993-04-06 2000-08-16 中国矿业大学 Cation coagulant
GB9801524D0 (en) * 1998-01-23 1998-03-25 Allied Colloids Ltd Thickening of aqueous mineral suspensions
CN1262233A (en) * 1999-01-25 2000-08-09 陈弓 Coagulant for treating waste water and preparing process thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB481499A (en) * 1936-06-06 1938-03-07 Frederick George Francis Improvements in and relating to the flocculation of solid in liquid suspensions
CN1180667A (en) * 1996-10-22 1998-05-06 中国矿业大学 Method for using mineral coagulant
WO1999022871A1 (en) * 1997-11-03 1999-05-14 Selective Oil Agglomeration Process Pty. Ltd. Controlled production and recovery of fine-coal agglomerates
US20020139754A1 (en) * 2001-02-16 2002-10-03 Miller Olen O. Method and apparatus for dewatering coal tailings and slurries and removing contaminants therefrom

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AU2007207277A1 (en) 2007-07-26
WO2007082492A1 (en) 2007-07-26
CN1803653A (en) 2006-07-19
CN100429156C (en) 2008-10-29

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