AU2006254533A1 - Device and method for purification of exhaust gases from an internal combustion engine - Google Patents

Device and method for purification of exhaust gases from an internal combustion engine Download PDF

Info

Publication number
AU2006254533A1
AU2006254533A1 AU2006254533A AU2006254533A AU2006254533A1 AU 2006254533 A1 AU2006254533 A1 AU 2006254533A1 AU 2006254533 A AU2006254533 A AU 2006254533A AU 2006254533 A AU2006254533 A AU 2006254533A AU 2006254533 A1 AU2006254533 A1 AU 2006254533A1
Authority
AU
Australia
Prior art keywords
fuel
exhaust gas
reformer
set forth
exhaust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU2006254533A
Other versions
AU2006254533B2 (en
AU2006254533A8 (en
Inventor
Matthias Boltze
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Enerday GmbH
Original Assignee
Webasto SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Webasto SE filed Critical Webasto SE
Publication of AU2006254533A1 publication Critical patent/AU2006254533A1/en
Publication of AU2006254533A8 publication Critical patent/AU2006254533A8/en
Application granted granted Critical
Publication of AU2006254533B2 publication Critical patent/AU2006254533B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386Catalytic partial combustion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0871Regulation of absorbents or adsorbents, e.g. purging
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066Selective catalytic reduction [SCR]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N9/00Electrical control of exhaust gas treating apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D43/00Conjoint electrical control of two or more functions, e.g. ignition, fuel-air mixture, recirculation, supercharging or exhaust-gas treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1685Control based on demand of downstream process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/169Controlling the feed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2240/00Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
    • F01N2240/30Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a fuel reformer
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/03Adding substances to exhaust gases the substance being hydrocarbons, e.g. engine fuel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00Adding substances to exhaust gases
    • F01N2610/04Adding substances to exhaust gases the substance being hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

Description

PUBLISHED SPECIFICATION VERIFICATION OF TRANSLATION I, ...Victor T. Smith... ..................... (insert translator's name) of ........... Artur-Kutscher-Platz 1, 80802 M0nchen, Germany........................ ................................................................................................. (translator's address) declare as follows: 1. That I am well acquainted with both the English and German languages, and 2. That the attached document is a true and correct translation made by me to the best of my knowledge and belief of: (a) The specification of International Bureau pamphlet numbered WO 2006/128449 International Application No. PCT/DE2006/000957 MuvdA ~A-i& ~c\k3V. 2-61 206-7 (Date) (Signature of Translator) (No witness required) - 1 PCT/DE2006/000957 Enerday GmbH 5 Device and method for emission control of an internal combustion engine 10 The invention relates to a device for emission control of an internal combustion engine including an exhaust tract comprising a NOx catalyst, and a reductant feeder de signed to deliver reductant to the exhaust tract upstream of the NOx catalyst. In addition the invention relates to 15 a method for emission control of an internal combustion engine wherein a NO catalyst provided in the exhaust tract is supplied with reductant. One problem associated with modern motor vehicles is the 20 emission of nitrous oxides (NOx) materializing in the combustion of gasoline or diesel in the engine, particu larly at high combustion chamber temperatures. To reduce NOx emissions catalyst systems are known for storing the NOx and reducing it to safe nitrogen. From the generic DE 25 102 33 66 5 Al it is already known for this purpose to inject reductant in the form of fuel into the exhaust tract upstream of the NOx catalyst. Instead of injecting pure fuel as is known from DE 102 33 66 5 Al use may be made of a reformate as the reductant. No matter what kind -2 of reductant is selected, it needs to be introduced into the exhaust tract in counteracting the fluctuating back pressure of the exhaust system. For this purpose prior art makes use of high-performance blowers, air compres 5 sors or injectors, all of which add to the costs and the nuisance of frequent servicing. The object of the present invention involves sophisticat ing generic devices and methods such that costly means 10 requiring frequent servicing for introducing the reduc tant in the exhaust tract counteracting the fluctuating back pressure of the exhaust system are now eliminated. This object is achieved by the features of the independ 15 ent claims. Advantageous aspects and further embodiments of the in vention read from the dependent claims. 20 The device in accordance with the invention is a sophis tication over generic prior art in that the reductant feeder comprises a reformer designed to react the gas exhausted by the engine and fuel into a reformate serving as the reductant. It is particularly with diesel engines 25 that the exhaust gas of the engine contains an apprecia ble proportion of oxygen which in addition to the fuel is feedstock for generating a reformate. When branching off this exhaust gas immediately downstream of the engine it has a corresponding high pressure level. Due to this high - 3 pressure level of the branched-off exhaust gas it is possible in accordance with the invention to introduce the reformate upstream of the NOx catalyst into the ex haust tract in thus eliminating costly means requiring 5 frequent servicing needed as in prior art to generate the pressure required to introduce the reformate. The branched-off exhaust gas and fuel are mixed in the re former and supplied to a reformer catalyst. In the subse quent reaction in the form of an exothermic partial oxi 10 dation a reformate gas having a proportion of the reduc ing gases hydrogen and carbon monoxide is generated. These gases are suitable for reducing the nitrous oxides in the NOx catalyst to safe nitrogen. 15 For the device in accordance with the invention it is considered to be particularly advantageous when it is provided for that the exhaust gas supplied to the re former is obtained via a exhaust tract branch-off dis posed directly downstream of the engine. Directly down 20 stream of the engine the exhaust gas pressure is high and thus well suited to introduce the reformate in counter acting the back pressure in the exhaust tract. In accordance with a preferred further embodiment of the 25 device in accordance with the invention it is provided for that the exhaust gas supplied to the reformer is obtained via a exhaust tract branch-off comprising an exhaust gas metering device. This exhaust gas metering device permits introducing the amount of exhaust gas as - 4 needed in each case to generate the reformate to be sup plied to the reformer. The exhaust gas metering device may work with open or closed loop control. 5 In conjunction with the arrangement as described above the exhaust gas metering device may comprise a valving apparatus. This valving apparatus may be, for example, a metering valve similar to a valve for returning the ex haust gas. 10 In addition or as an alternative thereto, it may be pro vided for in the device in accordance with the invention that the exhaust gas metering device comprises a blower which because of the high pressure level of the exhaust 15 gas supplied to the blower can be designed with a much lower power level than needed in prior art. The device in accordance with the invention can be so phisticated to advantage in that the exhaust gas supplied 20 to the reformer is obtained via a exhaust tract branch off disposed upstream of a further catalyst disposed upstream of the NOx catalyst. This further catalyst may be, for example, the main catalyst of the emission con trol system, the exhaust gas being obtained upstream of 25 the further catalyst and introduced into the NOx catalyst in the exhaust tract. At least in some aspects of the device in accordance with the invention it may be provided for that it comprises a - 5 fuel pump, designed to pump fuel from a fuel tank. The fuel pump may be in particular a fuel metering pump for pumping the fuel from the fuel tank in the amount as needed to generate the reformate in each case. This fuel 5 pump may also feature open or closed loop control. In accordance with yet another advantageous further em bodiment of the device in accordance with the invention it is provided for that the fuel is obtained from a fuel 10 line of the fuel system of the engine and that the fuel is supplied to the reformer via a fuel valving apparatus, the fuel line concerned may be, in particular, a pressur ized fuel line, for example a common rail return. The fuel valving apparatus may be, in particular, a fuel 15 metering valve which passes the amount of fuel as needed in each case to generate the reformate. This fuel valving apparatus may also feature open or closed loop control. The method in accordance with the invention is a sophis 20 tication over prior art in that use is made of reformate generated by a reformer as the reductant, the reformer generating the reformate from engine exhaust gas and fuel. This achievement has the same advantages and fea tures as recited for the device in accordance with the 25 invention and thus to avoid tedious repetition reference is made to the comments in conjunction with the device in accordance with the invention.
- 6 The same applies in accordance with the following pre ferred aspects of the method in accordance with the in vention, here too, reference being made to the comments in conjunction with the device in accordance with the 5 invention. In preferred aspects of the method in accordance with the invention it is provided for that the exhaust gas sup plied to the reformer is obtained via a exhaust tract 10 branch-off disposed directly downstream of the engine. It is likewise considered to be an advantage of the method in accordance with the invention that the exhaust gas supplied to the reformer is obtained via a exhaust 15 tract branch-off containing an exhaust gas metering de vice. In this arrangement it is considered to be an advantage that the exhaust gas metering device comprises a valving 20 apparatus. In addition to or as an alternative thereto it may be provided for that the exhaust gas metering device com prises a blower. 25 In certain aspects of the method in accordance with the invention it may be provided for that the exhaust gas supplied to the reformer is obtained via a exhaust tract -7 branch-off disposed at the input to a further catalyst disposed upstream of the NOx catalyst. In the method in accordance with the invention too, as 5 pects come into consideration in which it is provided for that a fuel pump is included, designed to pump fuel from a fuel tank. In this case it may be provided for in addition or as an 10 alternative thereto that the fuel is obtained from a fuel line of the fuel system of the engine and that the fuel is supplied to the reformer via a fuel valving apparatus. Of particularly advantage in the achievement in accor 15 dance with the invention is that it is independent of the exhaust back pressure of the exhaust system and thus of the load on the engine, because the reformer pressure is now always adapted to the level of the exhaust gas pres sure. In other words, via the reformer system the system 20 pressure is now always practically constant and independ ent of the load of the engine and exhaust back pressure. Preferred embodiments of the invention will now be ex plained by way of example with reference to the corre 25 sponding drawings in which FIG. 1 is a diagrammatic block diagram illustrating a first embodiment of the device in accordance with the invention suitable for implementing - 8 the method in accordance with the invention; and FIG. 2 is a diagrammatic block diagram illustrating a 5 second embodiment of the device in accordance with the invention likewise suitable for imple menting the method in accordance with the in vention. 10 Like components are identified in the drawings by like reference numerals as explained only once to avoid tedi ous repetition. Referring now to FIG. 1, there is illustrated how an 15 internal combustion engine 10 is assigned an exhaust tract 12 comprising a NOx catalyst 14 and a further cata lyst 24, the further catalyst 24 being the main catalyst. Disposed directly downstream of the engine 10 is a ex haust tract branch-off 20 connecting a reformer 18 via an 20 exhaust gas metering device 22. In the embodiment as shown in FIG. 1 the exhaust gas metering device 22 is formed by a exhaust gas metering valve. A fuel pump 26 is provided to supply the reformer 18 with fuel metered from a fuel tank 28. The exhaust tract branch-off 20, the 25 exhaust gas metering device 22, fuel pump 26 and reformer 18 all form together a reductant feeder. In the reformer 18 the branched-off exhaust gas and the fed fuel are mixed and supplied to a reformate catalyst (not shown) which is a component of the reformer 18. In the subse- - 9 quent reaction a gaseous reformate is generated contain ing a proportion of the reducing gases hydrogen and car bon monoxide. The reformate as generated this way is introduced into the exhaust tract 12 upstream of the NOx 5 catalyst 14. Because the reformer pressure is always adapted to the actual exhaust gas pressure no special means are needed to overcome the exhaust back pressure on introducing the reformate into the exhaust tract 12. Via the reformer 18 the system pressure is now by the 10 achievement in accordance with the invention practically constant and independent of the engine load and exhaust back pressure. Both the exhaust gas metering device 22 in the form of a metering valve as well as the fuel pump 26 can be operated with open or closed loop control. For 15 this purpose a controller (not shown) may be provided which is also capable of providing open or closed loop control of the other components of the reformer 18. Referring now to FIG. 2, there is illustrated a diagram 20 matic block diagram of a second embodiment of the device in accordance with the invention, likewise suitable for implementing the method in accordance with the invention. The embodiment as shown in FIG. 2 differs from the em bodiment as shown in FIG. 1 in that the exhaust gas me 25 tering device 22 is formed by a blower and that instead of a fuel pump a fuel valving apparatus 32 is provided. The blower forming the exhaust gas metering device 22 may be a relatively low power blower since the exhaust tract branch-off 20 is subjected to a high exhaust gas pres- - 10 sure. The fuel valving apparatus 32 is achieved by a fuel metering valve disposed between the fuel line 30 of the fuel system of the engine 10 and the reformer 18. The fuel line 30 of the fuel system of the engine 10 may be, 5 in particular, a fuel pressure line, for example a common rail return. This achievement is based on having discov ered that there is no need for a separate fuel pump when a sufficiently high fuel pressure is available anyway. 10 In the embodiment as shown in FIG. 2 too, a controller (not shown) may be provided for activating the corre sponding components as already explained in conjunction with with the comments as to FIG. 1. The advantage of operation independent of the exhaust back pressure and 15 engine load thus applies likewise to the embodiment as shown in FIG. 2. It will be appreciated, of course, that the exhaust gas metering device may also be formed in the embodiment as 20 shown in FIG. 2 too, by a valving apparatus; in the em bodiment as shown in FIG. 1 a blower can be put to use as an alternative. It is understood that the features of the invention as 25 disclosed in the above description, in the drawings and as claimed may be essential to achieving the invention both by themselves or in any combination.
- 11 List of reference numerals 5 10 engine 13 exhaust tract 14 NOx catalyst 16 reductant feeder 18 reformer 10 20 exhaust tract branch-off 22 exhaust gas metering device 24 further catalyst 26 fuel pump 28 fuel tank 15 30 fuel system line 32 fuel valving apparatus

Claims (9)

  1. 2. The device as set forth in claim 1, characterized in 20 that the exhaust gas supplied to the reformer (18) is obtained via a exhaust tract branch-off (20) disposed directly downstream of the engine (10).
  2. 3. The device as set forth in claim 1 or 2, character 25 ized in that the exhaust gas supplied to the reformer (18) is obtained via a exhaust tract branch-off (20) comprising an exhaust gas metering device (22). - 13 4. The device as set forth in claim 3, characterized in that the exhaust gas metering device (22) comprises a valving apparatus. 5 5. The device as set forth in claim 3 or 4, character ized in that the exhaust gas metering device (22) com prises a blower.
  3. 6. The device as set forth in any of the preceding 10 claims, characterized in that the exhaust gas supplied to the reformer (18) is obtained via a exhaust tract branch off (20) disposed upstream of a further catalyst (24) disposed upstream of the NOx catalyst (14). 15 7. The device as set forth in any of the preceding claims, characterized in that it comprises a fuel pump (26), designed to pump fuel from a fuel tank (28).
  4. 8. The device as set forth in any of the preceding 20 claims, characterized in that the fuel is obtained from a fuel line of the fuel system of the engine and that the fuel is supplied to the reformer (18) via a fuel valving apparatus (32). 25 9. A method for emission control of an internal combus tion engine (10) wherein a NOx catalyst (14) provided in the exhaust tract (12) is supplied with reductant, char acterized in that use is made of reformate generated by a - 14 reformer (18) as reductant, the reformer (18) generating the reformate from the engine (10) exhaust gas and fuel.
  5. 10. The method as set forth in claim 9, characterized in 5 that the exhaust gas supplied to the reformer (18) is obtained via a exhaust tract branch-off (20) disposed directly downstream of the engine (10).
  6. 11. The method as set forth in claim 9 or 10, character 10 ized in that the exhaust gas supplied to the reformer (18) is obtained via a exhaust tract branch-off (20) containing an exhaust gas metering device (22).
  7. 12. The method as set forth in claim 11, characterized 15 in that the exhaust gas metering device (22) comprises a valving apparatus.
  8. 13. The method as set forth in claim 11 or 12, charac terized in that the exhaust gas metering device (22) 20 comprises a blower.
  9. 14. The method as set forth in any of the claims 9 to 13, characterized in that the exhaust gas supplied to the reformer (18) is obtained via a exhaust tract branch-off 25 (20) disposed upstream of a further catalyst (24) dis posed upstream of the NOx catalyst (14). - s15 15. The method as set forth in any of the claims 9 to 14, characterized in that the fuel supplied to the re former (18) is delivered by a fuel pump (26). 5 16. The method as set forth in any of the claims 9 to 15, characterized in that the fuel is obtained from a fuel line of the fuel system of the engine and that the fuel is supplied to the reformer (18) via a fuel valving apparatus (32).
AU2006254533A 2005-06-02 2006-06-01 Device and method for purification of exhaust gases from an internal combustion engine Ceased AU2006254533B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005025455A DE102005025455B4 (en) 2005-06-02 2005-06-02 Apparatus and method for purifying exhaust gases of an internal combustion engine
DE102005025455.1 2005-06-02
PCT/DE2006/000957 WO2006128449A1 (en) 2005-06-02 2006-06-01 Device and method for purification of exhaust gases from an internal combustion engine

Publications (3)

Publication Number Publication Date
AU2006254533A1 true AU2006254533A1 (en) 2006-12-07
AU2006254533A8 AU2006254533A8 (en) 2008-02-21
AU2006254533B2 AU2006254533B2 (en) 2009-10-22

Family

ID=36926325

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2006254533A Ceased AU2006254533B2 (en) 2005-06-02 2006-06-01 Device and method for purification of exhaust gases from an internal combustion engine

Country Status (9)

Country Link
US (1) US20090044519A1 (en)
EP (1) EP1888889A1 (en)
JP (1) JP2008542606A (en)
KR (1) KR100923521B1 (en)
CN (1) CN101273189A (en)
AU (1) AU2006254533B2 (en)
CA (1) CA2611027A1 (en)
DE (2) DE102005025455B4 (en)
WO (1) WO2006128449A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009162157A (en) * 2008-01-08 2009-07-23 Honda Motor Co Ltd Exhaust emission control device for internal combustion engine
JP6116360B2 (en) * 2013-05-16 2017-04-19 株式会社堀場製作所 Exhaust gas flow meter and exhaust gas analysis system
DE102014202291A1 (en) * 2014-02-07 2015-08-13 Volkswagen Aktiengesellschaft Exhaust gas purification device and motor vehicle with such
DE102015209156A1 (en) * 2015-05-19 2016-11-24 Mtu Friedrichshafen Gmbh Exhaust line for an internal combustion engine and internal combustion engine

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0787829B2 (en) * 1990-06-25 1995-09-27 積水化学工業株式会社 How to install an apron in front of the bathtub and bathtub with an apron in front
JPH0454926U (en) * 1990-09-20 1992-05-12
JPH1089057A (en) * 1996-09-18 1998-04-07 Mitsubishi Motors Corp Exhaust emission control device of engine
JP3565035B2 (en) * 1998-07-10 2004-09-15 三菱ふそうトラック・バス株式会社 NOx reduction system for combustion exhaust gas
JP2002106338A (en) * 2000-10-02 2002-04-10 Nissan Motor Co Ltd Hydrogen contained gas producing apparatus and exhaust emission control system
JP3685052B2 (en) * 2000-11-30 2005-08-17 日産自動車株式会社 Exhaust gas purification device for internal combustion engine
US6928359B2 (en) * 2001-08-09 2005-08-09 Ford Global Technologies, Llc High efficiency conversion of nitrogen oxides in an exhaust aftertreatment device at low temperature
DE10203034A1 (en) * 2002-01-26 2003-07-31 Ballard Power Systems Process for reducing nitrogen oxides in engine exhaust gas involves coarsely adjusting the amount of oxygen-rich gas, and finely adjusting the stoichiometric amount necessary for the production of hydrogen-rich gas
US20030226350A1 (en) * 2002-06-11 2003-12-11 Ke Liu Reducing oxides of nitrogen using reformate generated from engine fuel, water and/or air
CA2406386C (en) * 2002-10-02 2004-05-18 Westport Research Inc. Method and apparatus for regenerating nox adsorbers
US20050022450A1 (en) * 2003-02-12 2005-02-03 Cher-Dip Tan Reformer system, a method of producing hydrogen in the reformer system, and a method of using the reformer system
DE10313704A1 (en) * 2003-03-27 2004-10-07 Daimlerchrysler Ag Exhaust gas purification device for vehicle engine comprises nitrogen oxides adsorber with adsorber channels connected in parallel
EP1484103A1 (en) * 2003-06-06 2004-12-08 Umicore AG & Co. KG Process and apparatus for catalytic conversion of hydrocarbons for generating a gas rich in hydrogen
US6964156B2 (en) * 2003-10-23 2005-11-15 Hydrogensource Llc Intermittent application of syngas to NOx trap and/or diesel engine
US20070197903A1 (en) * 2004-03-10 2007-08-23 Mugler John P Iii System and method for improved detection and assessment of changes in lung-tissue structure
US7213395B2 (en) * 2004-07-14 2007-05-08 Eaton Corporation Hybrid catalyst system for exhaust emissions reduction
US20060053774A1 (en) * 2004-09-15 2006-03-16 Kabasin Daniel F Exhaust treatment system and methods using the same

Also Published As

Publication number Publication date
JP2008542606A (en) 2008-11-27
AU2006254533B2 (en) 2009-10-22
KR100923521B1 (en) 2009-10-27
DE102005025455B4 (en) 2009-03-19
CN101273189A (en) 2008-09-24
KR20080015019A (en) 2008-02-15
EP1888889A1 (en) 2008-02-20
DE102005025455A1 (en) 2006-12-07
CA2611027A1 (en) 2006-12-07
WO2006128449A1 (en) 2006-12-07
US20090044519A1 (en) 2009-02-19
AU2006254533A8 (en) 2008-02-21
DE102005063323A1 (en) 2006-12-07

Similar Documents

Publication Publication Date Title
EP1244512B1 (en) Device and method for subsequently treating exhaust gases
US7357900B2 (en) NOx reduction system for diesel engines, using hydrogen selective catalytic reduction
US20070084423A1 (en) Hydrogen peroxide injection engine and combustion fuel supplamentation
EP1888907B1 (en) Method and apparatus for supplying air to emission abatement device by use of turbocharger
US7131265B2 (en) Motor vehicle with a cryotank
AU2006254533A1 (en) Device and method for purification of exhaust gases from an internal combustion engine
US20180320607A1 (en) A method and an apparatus for controlling an internal combustion engine with a high pressure gas injection
KR102042887B1 (en) Selective catalytic reuction system and power generating apparatus
US20100107607A1 (en) Method and device for producing ammonia for the exhaust gas treatment in internal combustion engines in a motor vehicle
EP1947321A1 (en) Petroleum fuel supply method and circuit
CN103026020A (en) Aftertreatment burner air supply system
US20130066536A1 (en) Sensor output modifier
US20140157764A1 (en) Auxiliary Power and Emission-Control System Using Vented Gaseous Fuel Recovery and Method
JP2010133337A (en) Dual fuel diesel engine
JP2006511755A (en) Method for controlling execution element of basic operation of internal combustion engine
CN103201474A (en) Fuel reformer
JP5620715B2 (en) Exhaust purification device
GB2357047A (en) Exhaust gas purification system
KR19980080272A (en) Method and apparatus for reducing harmful substances in combustion exhaust gas from an internal combustion engine having an exhaust gas catalyst
EP4314534A1 (en) Ethanol reforming system for generating hydrogen and a method for generating hydrogen through an ethanol reforming system
JP5774300B2 (en) Exhaust purification equipment
CN107534172B (en) Exhaust purification system with power generation function
WO2024012792A1 (en) Exhaust gas aftertreatment system in the exhaust gas system of an ammonia combustion engine, method for exhaust gas aftertreatment, and use of an n2o decomposition catalyst
WO2019148241A1 (en) An exhaust after-treatment system and method

Legal Events

Date Code Title Description
TH Corrigenda

Free format text: IN VOL 22, NO 2, PAGE(S) 213 UNDER THE HEADING PCT APPLICATIONS THAT HAVE ENTERED THE NATIONAL PHASE -NAME INDEX UNDER THE NAME WEBASTO AG, APPLICATION NO. 2006254533, UNDER INID (71), CORRECTED THE APPLICANT NAME TO ENERDAY GMBH.

FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired