AU2004252511A1 - Fuels and lubricants using layered bed catalysts in hydrotreating waxy feeds, including Fischer-Tropsch wax - Google Patents

Description

WO 2005/001006 PCT/US2004/019253 FUELS AND LUBRICANTS USING LAYERED BED CATALYSTS IN HYDROTREATING WAXY FEEDS, INCLUDING FISCHER-TROPSCH WAX 5 FIELD OF THE INVENTION This invention relates to processes for converting waxy hydrocarbon feedstocks into salable products. More particularly, the invention relates to a process of converting a Fischer-Tropsch derived waxy feedstock to middle distillate fuels and lubricant base oils. 10 BACKGROUND OF THE INVENTION A Fischer-Tropsch synthesis process may be used to convert a gas composed primarily of CO and H 2 (commonly referred to as synthesis gas or syngas) under catalytic conditions to a wide variety of gaseous, liquid and solid hydrocarbonaceous 15 products. Many of these liquid and solid products contain waxy materials composed of high molecular weight paraffins. These paraffinic waxes can crystallize upon cooling, and products comprising these paraffinic waxes typically have unacceptably high pour points and high cloud points. Pour point is the temperature at which a sample will begin to flow under carefully controlled conditions and may be 20 measured according to ASTM D5950-96. Cloud point is the temperature at which a sample begins to develop a haze under controlled conditions and may be measured according to ASTM D5773-95. It is known to catalytically convert waxy paraffins in hydrocarbon feedstocks to lower boiling hydrocarbons within the middle distillate product range. This 25 conversion may be accomplished by hydroprocessing techniques, such as hydrocracking and hydroisomerization. Hydrocracking converts larger molecules into smaller ones and introduces some amount of branching into the cracked products. Hydroisomerization primarily introduces branching into the paraffinic molecules, thus improving properties, such as pour and cloud points. Unreacted 30 components of the hydrocarbon feed, which have not been hydrocracked and/or hydroisomerized, may be recycled for further treatment to provide additional products in the desired boiling range. 1 WO 2005/001006 PCT/US2004/019253 The combination of treating paraffinic hydrocarbon feeds by hydrocracking and hydroisomerization to produce middle distillate hydrocarbons is taught in EP 0544766 B1. EP 0544766 B1 teaches a process for preparing low pour point middle distillate hydrocarbons by contacting a hydrocarbonaceous feedstock with a large 5 pore hydrocracking catalyst and a catalyst comprising an intermediate pore size silicoaluminophosphate molecular sieve and a hydrogenation component. United States Patent No. 5,935,414 relates to a process for reducing the wax content of wax-containing hydrocarbon feedstocks to produce middle distillate products, which include a low freeze point jet fuel and/or a low pour point and low 10 cloud point diesel fuel and heating oil. In the process, the feedstock is contacted with a hydrocracking catalyst containing a carrier, at least one hydrogenation metal component of Group VIB and Group VIII metals, and a large pore zeolite such as a Y type zeolite, in a hydrocracking zone in the presence of hydrogen at elevated temperature and pressure. The entire effluent from the hydrocracking zone is 15 contacted with a dewaxing catalyst containing a crystalline, intermediate pore size molecular sieve selected from metallosilicates and silicoaluminophosphates in a hydrodewaxing zone in the presence of hydrogen at elevated temperature and pressure. United States Patent No. 5,139,647 relates to a process for making middle 20 distillates from a hydrocarbonaceous feedstock by a hydrocracking and isomerization. In the process the feedstock is contacted with a catalyst containing an intermediate pore size silicoaluminophosphate molecular sieve and a hydrogenation component. United States Patent No. 4,859,312 relates to a process for making middle 25 distillates. The process uses a catalyst comprising a silicoaluminophosphate molecular sieve such as SAPO-1 1 and SAPO-41, and platinum or palladium, a hydrogenation component, to simultaneously subject heavy oils to hydrocracking and isomerization reactions. The process selectively produces middle distillates in high yields having good low temperature fluid characteristics, especially reduced 30 pour point and viscosity. EP 0323092 A2 and United States Patent No. 4,943,672 relate to a process for converting Fischer Tropsch wax into a lubricating oil having a high viscosity index and a low pour point. In the process as disclosed first the wax is hydrotreated 2 WO 2005/001006 PCT/US2004/019253 under relatively severe conditions and thereafter the hydrotreated wax is hydroisomerized in the presence of hydrogen on a specified type of fluorided Group VIII metal-on-alumina catalyst. The hydroisomerate is then dewaxed to produce a premium lubricating oil base stock. 5 United States Patent No. 4,080,397 discloses a method for upgrading a 350'F+ product of Fischer-Tropsch synthesis. In the method as disclosed, the Fischer-Tropsch synthesis product is hydrotreated and the hydrotreated material boiling above about 600'F is selectively cracked. EP 0583836 Al discloses a process for preparing of hydrocarbon fuels. In 10 the process as disclosed a substantially paraffinic hydrocarbon product is prepared, and the hydrocarbon product is contacted with hydrogen in the presence of a hydroconversion catalyst under conditions such that substantially no isomerization or hydrocracking of the hydrocarbon product occurs. At least a portion of the hydrocarbon product from this process is contacted with hydrogen in the presence of 15 a hydroconversion catalyst under conditions such that hydrocracking and isomerization of the hydrocarbon feed occurs to yield a substantially paraffmic hydrocarbon fuel. EP 0147873 Al discloses a process for preparing middle distillates. Middle distillates are prepared from syngas by a two stage series-flow process. The process 20 comprises a Fischer Tropsch synthesis over a special Zr, Ti, or Cr promoted Co catalyst followed by hydroconverting the total synthesized product of a Fischer Tropsch synthesis over a supported noble metal catalyst. There remains a need for an efficient and economical process for converting waxy paraffinic feeds to both middle distillate fuels and lubricant base oils in high 25 yields without compromising the desirable properties of the paraffins in the original feed. It is desired that the primary product of the process be lubricant base oil having good low temperature properties (i.e., cloud point, pour point, cold filter plugging point, etc. and high viscosities). 30 SUMMARY OF THE INVENTION The present invention relates to a process for treating a waxy hydrocarbon feedstock. The process comprises contacting the feedstock with a hydrocracking catalyst in a hydrocracking zone, producing a hydrocracking effluent and contacting 3 WO 2005/001006 PCT/US2004/019253 the hydrocracking effluent with a molecular sieve hydroisomerization catalyst in a hydroisomerization zone, producing a hydroisomerization effluent. The hydroisomerization effluent is fractionated, providing a heavy fraction and a middle distillate fuel. A lubricant base oil fraction is isolated from the heavy fraction and 5 this lubricant base oil has a viscosity index of greater than 130, a pour point of less than -15"C, and a viscosity of greater than 3 cSt at 100 C. The present invention further relates to a process for treating a 650"F+ waxy hydrocarbon feedstock. The process comprises contacting the feedstock with a hydrocracking catalyst in a hydrocracking zone, producing a hydrocracking effluent, 10 and contacting the hydrocracking effluent with a molecular sieve hydroisomerization catalyst in a hydroisomerization zone, producing a hydroisomerization effluent. The hydroisomerization effluent is fractionated, providing a heavy fraction and a middle distillate fuel; and a lubricant base oil fraction is isolated from the heavy fraction. The lubricant base oil has a viscosity index of greater than 130, a pour point of less 15 than -15"C, and a viscosity of greater than 3 cSt at 100'C. Preferably, less than 60 weight % of the 650"F+ components in the feed are converted to 650"F- products. In a further embodiment, the present invention relates to a process for treating a 650*F+ waxy hydrocarbon feedstock. In the process the feedstock is contacted with a hydrocracking catalyst in a hydrocracking zone, producing a 20 hydrocracking effluent; and the hydrocracking effluent is contacted with a molecular sieve hydroisomerization catalyst in a hydroisomerization zone, producing a hydroisomerization effluent. The hydroisomerization effluent is fractionated, providing a heavy fraction and a middle distillate fuel; and a lubricant base oil fraction is isolated from the heavy fraction. The lubricant base oil produced from 25 this process has a viscosity index of greater than 130, a pour point of less than -15*C, and a yiscosity of greater than 3 cSt at 100 C, and the 650"F+ waxy hydrocarbon feedstock comprises greater than 20 weight % 900"F+ components. BRIEF DESCRIPTION OF THE DRAWINGS 30 FIGURE illustrates a schematic representation of one embodiment of the process of the present invention. 4 WO 2005/001006 PCT/US2004/019253 DETAILED DESCRIPTION OF ILLUSTRATIVE EMBODIMENTS The present invention relates to a process for producing high yields of high 5 quality lubricant base oils from waxy hydrocarbon feedstocks. It has been discovered that one can readily and economically convert waxy hydrocarbon feeds having high initial boiling points and containing high levels of paraffinic waxes, such as Fischer Tropsch waxes, into high quality middle distillate fuels and high quality lubricant base oils, with the lubricant base oils being the primary product. In 10 the processes of the present invention these waxy hydrocarbon feeds are contacted with a hydrocracking catalyst followed by a hydroisomerization catalyst, separated into a middle distillate product and a heavy fraction. From the heavy fraction a lubricant base oil is isolated. This process converts high boiling waxy hydrocarbon feeds into high quality middle distillate fuels with low pour and cloud points and 15 high quality lubricant base oils with high viscosity indexes, and low pour and cloud points. The process of the present invention results in less cracking of the high boiling end of the high boiling waxy feed (i.e., less conversion of the high boiling end of the feed to lighter products). Accordingly, high quality lubricant base oils with high viscosity indexes, and low pour and cloud points. 20 Definitions The following terms will be used throughout the specification and will have the following meanings unless otherwise indicated. "Heavy fraction" is the heavier fraction separated after hydrocracking and 25 hydroisomerization of a waxy hydrocarbon feedstock. The heavy fraction has an initial boiling point in the range of 600 to 750'F, an end boiling point in the range of 950 to greater than 1200 'F. The heavy fraction comprises lubricant base oil and wax. The heavy fraction may have a wax content between 0.1 and 5 weight percent. A heavy fraction may also be fractionated such that a bottoms fraction is obtained. 30 "Bottoms fraction" is a non-vaporized (i.e. residuum) fraction contained as a part of the heavy fraction. "Derived from a Fischer-Tropsch synthesis" means that the fuel or product in question originates from or is produced at some stage by a Fischer-Tropsch process. 5 WO 2005/001006 PCT/US2004/019253 "Waxy hydrocarbon feedstock" useful in the processes disclosed herein may be synthetic waxy feedstocks, such as Fischer Tropsch waxy hydrocarbons, or may be derived from natural sources, such as petroleum waxes. The waxy hydrocarbon feedstock contains greater than 50% wax, more preferably greater than about 80% 5 wax, most preferably greater than about 90% wax. As used herein, wax content is determined by a solvent dewaxing process. The solvent dewaxing process is a standard method, and well known in the art. In the process, 300 grams of a waxy product is diluted 50/50 by volume with a 4:1 mixture of methyl ethyl ketone and toluene which had been cooled to -20' C. The mixture is cooled at a uniform slow 10 rate in the range of about 0.50 to 4.5* C./min) to -15'C., and then filtered through a Coors funnel at -15' C. using Whatman No. 3 filter paper. The wax is removed from the filter and placed in a tarred 2 liter flask. Solvent remaining in the wax is removed on a hot plate and the wax weighed. "650'F+ waxy hydrocarbon feedstock" has an initial boiling point of 650'F 15 wherein at least 70 wt%, preferably at least 85 wt%, of the feedstock boils above 650 OF. "Middle distillate fuel" or "middle distillate fuel fraction" is the lighter fraction separated after hydrocracking and hydroisomerization of a waxy hydrocarbon feedstock. It is a material containing hydrocarbons with boiling points 20 between approximately 300 F to 650'F. The term "distillate" means that traditional fuels of this type could be generated from vapor overhead streams from distilling petroleum crude. Within the broad category of distillate fuels are specific fuels that include naphtha, jet fuel, diesel fuel, kerosene, aviation gas, fuel oil, and blends thereof. 25 "Lubricant base oil" means a fraction meeting specifications for a lubricant base oil. Lubricant base oil fractions are isolated from the heavy fractions according to the process of the present invention. Properties of the lubricant base oils provided according to the present invention include initial boiling points in the range of 600 to 750 0 F, end boiling points in the range of 900 to greater than 1200'F, viscosities in 30 the range of 3 to 15 cSt at 100'C, viscosity indices in the range of 115 to 160, preferably in the range of 130 to 180, and more preferably in the range of 140 to 6 WO 2005/001006 PCT/US2004/019253 180, pour points less then -9'C, preferably in the range of -10 to -24'C, and cloud points in the range of 0 to -20'C. "Hydrocarbon or hydrocarbonaceous" means a compound or substance that contains hydrogen and carbon atoms, which may also include heteroatoms such as 5 oxygen, sulfur or nitrogen. In the processes according to the present invention, a waxy hydrocarbon feedstock is converted to a middle distillate fuel product and a lubricant base oil product by contacting the feedstock with a hydrocracking catalyst and then a hydroisomerization catalyst. The process according to the present invention 10 provides a lubricant base oil product having a high viscosity index and low pour and cloud points. The process of the present invention results in less cracking of the high boiling end of the high boiling waxy feed (i.e., less conversion of the high boiling end of the feed to lighter products). Accordingly, high quality lubricant base oils with high viscosity indexes and low pour and cloud points are produced. 15 The processes as described herein are able to convert this heavy waxy feed to high quality middle distillate products and high quality lubricant base oil products. The waxy hydrocarbon feedstock has an initial boiling point of less than 700'F+. The waxy hydrocarbon feedstock has an end boiling point in the range of 1000 to greater than 1200 'F. Preferably the waxy hydrocarbon feedstock to the processes 20 as described herein comprises greater than 70 weight percent 650'F+ material, and even more preferably greater than 85 weight percent 650'F+ material. The feed preferably comprises greater than 20 weight percent 900 0 F+ material. The waxy feeds to the process of the present invention are comprised of greater than 80 weight % wax, preferably greater than 95 weight % wax. As used 25 herein, wax content is determined by a solvent dewaxing process. The solvent dewaxing process is a standard method, and well known in the art. In the process, 300 grams of a waxy product is diluted 50/50 by volume with a 4:1 mixture of methyl ethyl ketone and toluene which had been cooled to -20' C. The mixture is cooled at a uniform slow rate in the range of about 0.50 to 4.5* C./min to -15'C., and 30 then filtered through a Coors funnel at -15* C. using Whatman No. 3 filter paper. The wax is removed from the filter and placed in a tarred 2 liter flask. Solvent remaining in the wax is removed on a hot plate and the wax weighed. 7 WO 2005/001006 PCT/US2004/019253 The waxy hydrocarbon feedstocks useful in the processes disclosed herein may be synthetic waxy feedstocks, such as Fischer Tropsch waxy hydrocarbons, or may be derived from natural sources, such as petroleum waxes. Accordingly, the waxy feedstocks to the processes may comprise Fischer Tropsch derived waxy 5 feeds, petroleum waxes, waxy distillate stocks such as gas oils, lubricating oil stocks, high pour point polyalphaolefins, foots oils, normal alpha olefin waxes, slack waxes, deoiled waxes, and microcrystalline waxes, and mixtures thereof. Preferably, the waxy feedstocks are derived from Fischer Tropsch waxy feeds. The waxy hydrocarbon feedstock may be hydrotreated prior to the process as 10 described herein if desired. However, for Fischer Tropsch derived waxy feeds hydrotreating is typically not necessary. A preferred waxy feed of the present invention is a Fischer-Tropsch derived waxy feed. In Fischer-Tropsch chemistry, syngas is converted to liquid hydrocarbons by contact with a Fischer-Tropsch catalyst under reactive conditions. 15 Typically, methane and optionally heavier hydrocarbons (ethane and heavier) can be sent through a conventional syngas generator to provide synthesis gas. Generally, synthesis gas contains hydrogen and carbon monoxide, and may include minor amounts of carbon dioxide and/or water. The presence of sulfur, nitrogen, halogen, selenium, phosphorus and arsenic contaminants in the syngas is undesirable. For 20 this reason and depending on the quality of the syngas, it is preferred to remove sulfur and other contaminants from the feed before performing the Fischer-Tropsch chemistry. Means for removing these contaminants are well known to those of skill in the art. For example, ZnO guardbeds are preferred for removing sulfur impurities. Means for removing other contaminants are well known to those of skill 25 in the art. It also may be desirable to purify the syngas prior to the Fischer-Tropsch reactor to remove carbon dioxide produced during the syngas reaction and any additional sulfur compounds not already removed. This can be accomplished, for example, by contacting the syngas with a mildly alkaline solution (e.g., aqueous potassium carbonate) in a packed column. 30 In the Fischer-Tropsch process, contacting a synthesis gas comprising a mixture of H2 and CO with a Fischer-Tropsch catalyst under suitable temperature and pressure reactive conditions forms liquid and gaseous hydrocarbons. The Fischer-Tropsch reaction is typically conducted at temperatures of about 300-700"F 8 WO 2005/001006 PCT/US2004/019253 (149-371*C), preferably about 400-550*F (204-228*C); pressures of about 10-600 psia, (0.7-41 bars), preferably about 30-300 psia, (2-21 bars); and catalyst space velocities of about 100-10,000 cc/g/hr, preferably about 300-3,000 cc/g/hr. Examples of conditions for performing Fischer-Tropsch type reactions are well 5 known to those of skill in the art. The products of the Fischer-Tropsch synthesis process may range from C 1 to

C

200 + with a majority in the C 5 to C 1 00+ range. The reaction can be conducted in a variety of reactor types, such as fixed bed reactors containing one or more catalyst beds, slurry reactors, fluidized bed reactors, or a combination of different type 10 reactors. Such reaction processes and reactors are well known and documented in the literature. In general, Fischer-Tropsch catalysts contain a Group VIII transition metal on a metal oxide support. The catalysts may also contain a noble metal promoter(s) and/or crystalline molecular sieves. Certain catalysts are known to provide chain 15 growth probabilities that are relatively low to moderate, and the reaction products include a relatively high proportion of low molecular (C 2

-

8 ) weight olefins and a relatively low proportion of high molecular weight (C 3 0 +) waxes. Certain other catalysts are known to provide relatively high chain growth probabilities, and the reaction products include a relatively low proportion of low molecular (C 2 -s) weight 20 olefins and a relatively high proportion of high molecular weight (C 3 0 +) waxes. Such catalysts are well known to those of skill in the art and can be readily obtained and/or prepared. The product from a Fischer-Tropsch process contains predominantly paraffins; however, it may also contain C 2 + olefins, oxygenates, and heteroatom 25 impurities. The most abundant oxygenates in Fischer-Tropsch products are alcohols, and mostly primary linear alcohols. Less abundant types of oxygenates in Fischer-Tropsch products include other alcohol types such as secondary alcohols, acids, esters, aldehydes, and ketones. The products from Fischer-Tropsch reactions generally include a light reaction product and a waxy reaction product. The light 30 reaction product (i.e., the condensate fraction) includes hydrocarbons boiling below about 700'F (e.g., tail gases through middle distillate fuels), largely in the C 5

-C

2 0 range, with decreasing amounts up to about C 3 0 . The waxy reaction product (i.e., the wax fraction) includes hydrocarbons boiling above about 600'F (e.g., vacuum gas 9 WO 2005/001006 PCT/US2004/019253 oil through heavy paraffins), largely in the C 20 + range, with decreasing amounts down to CIa. Both the light reaction product and the waxy product are substantially paraffinic. The waxy product generally comprises greater than 70 weight % normal 5 paraffins, and often greater than 80 weight % normal paraffins. The light reaction product comprises paraffmic products with a significant proportion of alcohols and olefins. In some cases, the light reaction product may comprise as much as 50 weight %, and even higher, alcohols and olefins. It is the waxy reaction product (i.e., the wax fraction) that may be used as a feedstock for the processes of the 10 present invention. According to the present invention, the waxy hydrocarbon feedstock is contacted with a hydrocracking catalyst in a hydrocracking zone, producing a hydrocracking effluent and the hydrocracking effluent is contacted with a molecular sieve hydroisomerization catalyst in a hydroisomerization zone, producing a 15 hydroisomerization effluent. The hydrocracking catalyst and hydroisomerization catalyst may be arranged in a variety of design options so long as the entire effluent from the hydrocracking zone is passed to the hydroisomerization zone. Accordingly, the hydrocracking and hydroisomerization catalysts may be layered in a single reaction zone in a single reactor, or the hydrocracking and 20 hydroisomerization catalysts may be layered in close-coupled series reactors with no heating, product withdrawal or feed inlet between reactors. The preferred catalyst system is a layered catalyst system, with the hydrocracking catalyst layered above the hydroisomerization catalyst, preferably in a ratio of about 1:1 to 15:1. The hydrocracking zone of the process includes a hydrocracking catalyst. 25 During hydrocracking, the high molecular weight wax molecules are cracked into a desirable boiling range. During cracking, at least some of the cracked molecules may also be isomerized. The resulting cracked product largely comprises a mixture of paraffins and isoparaffms, which boil in the desired fuel or lubricant oil product range According to the present process, it is desired to minimize the cracking of the 30 feedstock so that a smaller amount of light products will be produced. Hydrocracking catalysts are well known to those of skill in the art. Conventional hydrocracking catalysts generally comprise a cracking component, a 10 WO 2005/001006 PCT/US2004/019253 hydrogenation component and a binder or matrix. Such catalysts are well known in the art. The matrix component can be of many types including some that have acidic catalytic activity. Ones that have acidic activity include amorphous silica-alumina. 5 The catalyst may also contain a large pore zeolitic or non-zeolitic crystalline molecular sieve, where large pore is defined as having a pore diameter of greater than 7.1 A. Examples of suitable molecular sieves include zeolite Y, zeolite X and the so called ultra stable zeolite Y and high structural silica: alumina ratio zeolite Y such as that described in U.S. Patent No. 4,401,556, 4,820,402 and 5,059,567. 10 Small crystal size zeolite Y, such as that described in U.S. Patent No. 5,073,530, can also be used. Non-zeolitic molecular sieves which can be used include, for example, silicoaluminophosphates (SAPO), ferroaluminophosphate, titanium aluminophosphate and the various ELAPO molecular sieves described in U.S. Patent No. 4,913,799 and the references cited therein. Details regarding the preparation of 15 various non-zeolite molecular sieves can be found in U.S. Patent No. 5,114,563 (SAPO); 4,913,799 and the various references cited in U.S. Patent No. 4,913,799. Mesoporous molecular sieves can also be used, for example the M41S family of materials (J. Am. Chem. Soc., 114:10834-10843(1992)), MCM-41 (U.S. Patent Nos. 5,246,689; 5,198,203; 5,334,368), and MCM-48 (Kresge et al., Nature 359:710 20 (1992)). The contents of each of the patents and publications referred to above are hereby incorporated by reference in their entirety. Perferably, the molecular sieve content of the hydrocracking catalyst is less than 2 wt%. Suitable matrix materials may also include synthetic or natural substances as well as inorganic materials such as clay, silica and/or metal oxides such as silica 25 alumina, silica-magnesia, silica-zirconia, silica-thoria, silica-berylia, silica-titania as well as ternary compositions, such as silica-alumina-thoria, silica-alumina-zirconia, silica-alumina-magnesia, and silica-magnesia zirconia. The latter may be either naturally occurring or in the form of gelatinous precipitates or gels including mixtures of silica and metal oxides. Naturally occurring clays which can be 30 composited with the catalyst include those of the montmorillonite and kaolin families. These clays can be used in the raw state as originally mined or initially subjected to calumniation, acid treatment or chemical modification. 11 WO 2005/001006 PCT/US2004/019253 The hydrogenation component will be a Group VI, Group VII, or Group VIII metal or oxide or sulfide thereof, preferably one or more of molybdenum, tungsten, cobalt, or nickel, or the sulfides or oxides thereof If present in the catalyst, these hydrogenation components generally make up from about 5 weight % to about 40 5 weight % of the catalyst. Alternatively, platinum group metals, especially platinum and/or palladium, may be present as the hydrogenation component, either alone or in combination with the base metal hydrogenation components such as molybdenum, tungsten, cobalt, or nickel. If present, the platinum group metals will generally make up from about 0.1 weight % to about 2 weight % of the catalyst. The 10 hydrogenation component can be added to the catalyst by methods such as co mulling, impregnation, or ion-exchange. Typical hydrocracking conditions include: reaction temperature of from about 400 to 950'F (204 to 510 C), preferably 600 to 750'F (316 to 399'C); reaction pressure of from about 300 to 5000 psig (2.1 to 34.5 MPa), preferably 500 15 2000 psig (5.2-13.8 MPa); liquid hourly space velocity (LHSV) of from about 0.1 to 15 hr1, preferably 0.25 to 2.5 hf; and hydrogen recycle rate of from about 500 to 5000 standard cubic feet (SCF) per barrel of liquid hydrocarbon feed (89.1 to 890 m 3

H

2 /m 3 feed). The effluent from the hydrocracking zone is then contacted with an 20 intermediate pore size molecular sieve hydroisomerization catalyst in a hydroisomerization zone. The phrase "intermediate pore size," as used herein means an effective pore aperture in the range of from about 4.8 to about 7.1 A when the porous inorganic oxide is in the calcined form. 25 Hydroisomerization dewaxing is intended to improve the cold flow properties of a lubricating base oil by the selective addition of branching into the molecular structure. Hydroisomerization dewaxing ideally will achieve high conversion levels of waxy feed to non-waxy iso-paraffins while at the same time minimizing the conversion by cracking. 30 A hydroisomerization dewaxing catalyst useful in the present invention comprises a shape selective intermediate pore size molecular sieve and optionally a catalytically active metal hydrogenation component on a refractory oxide support. The shape selective intermediate pore size molecular sieves used in the practice of 12 WO 2005/001006 PCT/US2004/019253 the present invention are generally 1-D 10-, 11- or 12-ring molecular sieves. The preferred molecular sieves of the invention are of the 1-D 10-ring variety, where 10 (or 11-or 12-) ring molecular sieves have 10 (or 11 or 12) tetrahedrally-coordinated atoms (T-atoms) joined by oxygens. In the 1-D molecular sieve, the 10-ring (or 5 larger) pores are parallel with each other, and do not interconnect. The classification of intrazeolite channels as 1-D, 2-D and 3-D is set forth by R. M. Barrer in Zeolites, Science and Technology, edited by F. R. Rodrigues, L.D. Rollman and C. Naccache, NATO ASI Series, 1984 which classification is incorporated in its entirety by reference (see particularly page 75). 10 Preferred shape selective intermediate pore size molecular sieves used for hydroisomerization dewaxing are based upon aluminum phosphates, such as SAPO 11, SAPO-31, and SAPO-41. SAPO-11 and SAPO-31 are more preferred, with SAPO-1 1 being most preferred. SM-3 is a particularly preferred shape selective intermediate pore size SAPO, which has a crystalline structure falling within that of 15 the SAPO-1 1 molecular sieves. The preparation of SM-3 and its unique characteristics are described in U.S. Patent Nos. 4,943,424 and 5,158,665. Also preferred shape selective intermediate pore size molecular sieves used for hydroisomerization dewaxing are zeolites, such as ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-57, SSZ-32, offretite, and ferrierite. SSZ-32 and ZSM-23 are more 20 preferred. A particularly preferred intermediate pore size molecular sieve, which is useful in the present process is described, for example, in United States Patents No. 5,135,638 and 5,282,958, the contents of which are hereby incorporated by reference in their entirety. In United States Patent No.5,282,958, such an intermediate pore 25 size molecular sieve has a crystallite size of no more than about 0.5 microns and pores with a minimum diameter of at least about 4.8 A and with a maximum diameter of about 7.1 A. The catalyst has sufficient acidity so that 0.5 grams thereof when positioned in a tube reactor converts at least 50% of hexadecane at 370'C, a pressure of 1200 psig, a hydrogen flow of 160 ml/min, and a feed rate of 1 ml/hr. 30 The catalyst also exhibits isomerization selectivity of 40 or greater (isomerization selectivity is determined as follows: 100 x (weight % branched C 16 in product) / (weight % branched C16 in product + weight % C13- in product) when used under 13 WO 2005/001006 PCT/US2004/019253 conditions leading to 96% conversion of normal hexadecane (n-C16) to other species. Such a particularly preferred molecular sieve may further be characterized by pores or channels having a crystallographic free diameter in the range of from about 5 4.0 to about 7.1 A, and preferably in the range of 4.0 to 6.5 A. , The crystallographic free diameters of the channels of molecular sieves are published in the "Atlas of Zeolite Framework Types", Fifth Revised Edition, 2001, by Ch. Baerlocher, W.M. Meier, and D.H. Olson, Elsevier, pp 10-15, which is incorporated herein by reference. 10 If the crystallographic free diameters of the channels of a molecular sieve are unknown, the effective pore size of the molecular sieve can be measured using standard adsorption techniques and hydrocarbonaceous compounds of known minimum kinetic diameters. See Breck, Zeolite Molecular Sieves, 1974 (especially Chapter 8); Anderson et al. J. Catalysis 58, 114 (1979); and U.S. Pat. No. 4,440,871, 15 the pertinent portions of which are incorporated herein by reference. In performing adsorption measurements to determine pore size, standard techniques are used. It is convenient to consider a particular molecule as excluded if does not reach at least 95% of its equilibrium adsorption value on the molecular sieve in less than about 10 minutes (p/po=0.5;25 0 C). Intermediate pore size molecular sieves will typically 20 admit molecules having kinetic diameters of 5.3 to 6.5 Angstrom with little hindrance. Hydroisomerization dewaxing catalysts useful in the present invention optionally comprise a catalytically active hydrogenation metal. The presence of a catalytically active hydrogenation metal leads to product improvement, especially 25 VI and stability. Typical catalytically active hydrogenation metals include chromium, molybdenum, nickel, vanadium, cobalt, tungsten, zinc, platinum, and palladium. The metals platinum and palladium are especially preferred, with platinum most especially preferred. If platinum and/or palladium is used, the total amount of active hydrogenation metal is typically in the range of 0.1 to 5 weight 30 percent of the total catalyst, usually from 0.1 to 2 weight percent, and not to exceed 10 weight percent. 14 WO 2005/001006 PCT/US2004/019253 The refractory oxide support may be selected from those oxide supports which are conventionally used for catalysts, including silica, alumina, silica alumina, magnesia, titania and combinations thereof. The intermediate pore molecular sieve hydroisomerization catalyst is 5 particularly suited for hydroisomerizing normal paraffins to produce a low cloud point, low pour point product. Thus, distillate fuel fractions recovered from the hydroisomerization step have reduced cloud points. Furthermore, the hydroisomerization step reduces the pour point of the heavy fraction, and permits at least a portion of the heavy fraction to be recovered for lubricant oils. While it is 10 expected that some cracking conversion will also occur over the hydroisomerization catalyst, the conditions in the hydroisomerization step are maintained such that the hydroisomerization reaction dominates. With previous hydroisomerization processes, we have found that the cloud point of the lubricant base oil can be high (above 0 'C). While additional 15 isomerization can reduce cloud point, this results in a loss of base oil yield, viscosity index, and viscosity due to cracking and excessive branching. With this hydrocracking/hydroisomerization process, cracking conversion is minimized while achieving low pour points in the lubricant base oil and middle distillate fuel products. The process of the present invention results in less cracking 20 of the high boiling end of the high boiling waxy feed (i.e., less conversion of the high boiling end of the feed to lighter products). Accordingly, high quality lubricant base oils with high viscosity indexes, low pour points, and higher viscosities are produced. According to the process of the present invention, preferably less than 60 weight percent of the 650*F+ products is the feed is converted to 650"F- products. 25 Therefore, with this process, cracking conversion is minimized while achieving low pour points in the products. In addition, since there is less cracking, high yields of high quality lubricant base oil products are provided. The product of this hydrocracking/hydroisomerization process is fractionated by conventional methods to provide at least a middle distillate fuel fraction and a 30 heavy fraction. The fractionation can be accomplished by conventional methods of distillation with an appropriate cut point for isolating the middle distillate fuel fraction and heavy fraction. 15 WO 2005/001006 PCT/US2004/019253 A lubricant base oil is isolated from heavy fraction. The heavy fraction may be fractionated by convention methods, including vacuum distillation, to provide the lubricant base oil fraction and optionally, a bottoms fraction may also be isolated. The bottoms fraction may be recycled to the hydrocracking reaction zone. When 5 recycling all or a portion of the bottoms fraction, the bottoms fraction may be subjected to the hydrocracking step of the present invention alone or may be combined with another waxy hydrocarbon feedstock. Recycling all or a portion of the bottoms fraction increases the yield of the process. According to the present invention, a high quality lubricant base oil is 10 isolated from the heavy fraction without the need for an additional dewaxing step. A high viscosity lubricant base oil is provided by the processes of the present invention due to less cracking of the high boiling end of the waxy feedstock. Preferably less than 60 weight percent of the 650'F+ in the feed is converted to 650*F- products. The lubricant base oil recovered from the process of the present invention has a 15 viscosity index of greater than 130, preferably greater than 140, and more preferably greater than 150. The lubricant base oil provided also has a pour point of less than -15*C. The lubricant base oil has a viscosity of greater than 3 cSt at 100*C, preferably greater than 4 cSt at 100'C, and more preferably greater than 5 cSt at 100 0 C. 20 The recovered lubricant oil may optionally be subjected to hydrofinishing in. a mild hydrogenation process to improve its stability to heat and oxidation. The hydrofinishing can be conventionally carried out in the presence of a metallic hydrogenation catalyst such as, for example, platinum on alumina. The hydrofinishing can be carried out at a temperature of from about 190 to about 25 340'C, a pressure of from about 300 to about 3000 psig (2.76 to 20.7 Mpa), a LHSV between about 0.1 and 20, and hydrogen recycle rates of about 400 to about 1500 SCF/bbl. The lubricant base oil recovered from the processes of the present invention may be used as such as a lubricant, or it may be blended with another refined 30 lubricant stock having different properties. Alternatively, the lubricant base oil, prior to use as a lubricant, may be blended with one or more additives, for example, as antioxidants, extreme pressure additives, viscosity index improvers, and the like. 16 WO 2005/001006 PCT/US2004/019253 Illustrative Embodiment The FIGURE illustrates a schematic representation of one embodiment of the present invention. Referring to the FIGURE, a waxy hydrocarbon feedstock (10) is fed into a single reactor (100) containing a hydrocracking catalyst in a 5 hydrocracking zone (110) and a hydroisomerization catalyst in a hydroisomerization zone (120), wherein the hydrocracking zone (110) is above the hydroisomerization zone (120). The waxy hydrocarbon feedstock (10) is first contacted with the hydrocracking catalyst in the hydrocracking zone (110) and the effluent from the hydrocracking zone (110) is next contacted with the hydroisomerization catalyst in 10 the hydroisomerization zone (120). The entire effluent (20) from the hydroisomerization zone (120) is then fractioned in a fractionator (200), providing a heavy fraction (30), a middle distillate fuel (50) and a lighter product (70). From the heavy fraction (30), a lubricant base oil (60) and optionally a bottoms fraction (40) are obtained. The lubricant base oil has a viscosity index of greater than 130, a pour 15 point of less than -15'C, and a viscosity at 100 0 C of greater than 3 cSt. Optionally, the bottoms fraction (40) may be recycled to the hydrocracking zone (110) in the reactor (100). In addition to the lubricant base oil (60), the fractionation also produces a middle distillate product (50). Finally, the lubricant base oil (60) may be optionally hydrofinished in a hydrofinishing unit (300) to provide a hydrofmished 20 lube oil (70). The invention will now be illustrated by the following examples which is intended to be merely exemplary and in no manner limiting. 25 Examples Example 1 A 450'F+ Arab Heavy VGO first stage product was hydrocracked at 68% 700'F+ conversion at 1.2 hf1 LHSV and 1800 psig over a 30 nickel-tungsten/silica-alumina hydrocracking catalyst (Catalyst A), the 700'F+ bottoms had a +21*C pour point and 125 VI. By contrast, using a layered bed of 2:1 Catalyst A/Pt SAPO-1 1 hydroisomerization catalyst (Catalyst B) at the same conditions yielded a 725'F+ product (4 cSt at 100 C) of -20'C pour point and 127 17 WO 2005/001006 PCT/US2004/019253 VI. Cloud point in the diesel cut was decreased and cetane index increased versus the case with Catalyst A alone. Total mid-distillate was 56.9 weight %, versus 53.1 weight % with Catalyst A alone, due in part to an extension of the diesel endpoint from 700*F to 725'F. 5 Example 2 A light Fischer-Tropsch wax (Table I) was hydrocracked over a sulfided nickel-tungsten/silica-alumina catalyst followed at 1 hr 1 LHSV, 1000 psig, 685'F, and 6300 standard cubic feet (SCF)/Bbl. At these conditions, conversion below 10 650 0 F was 80.4 weight %. The liquid product was cut at about 350'F and about 675'F to give a diesel fraction. Yields and properties of the diesel cut and 675'F+ bottoms are given in Table II. The cloud point of the bottoms fraction (+29'C) was too high to be preferred for lube use. 15 Table I Description Light Fischer-Tropsch Wax Gravity, API 42.5 Nitrogen, ppm 3.2 Sim. Dist., LV%, OF ST/5 728/771 10/30 789/811 50 839 70/90 858/885 95/EP 898/943 Table II Conversion <650-F, Weight % 80.4 Yield, Weight %

C-C

2 0.03 Cr-C4 5.06

C

5 -180 0 F 17.77 180-350"F 20.85 350-650OF 37.51 650 0 F+ 19.71 18 WO 2005/001006 PCT/US2004/019253 95.49 350-675OF Weight % of Feed 52.9 Gravity, API 50.7 Viscosity, 40'C, cSt 2.631 Cloud Point, 'C -26 Aromatics, (SFC), Weight % Total <0.5 PNA Not Detected Cetane Index 75.9 Refractive Index 1.4342 Density, g/mL 0.7745 Molecular Weight 253 P/N/A Carbon 100/0/0 Sim. Dist., LV%, 0 F ST/5 288/342 10/30 368/448 50 523 70/90 594/673 95/EP 697/743 675 0 F+ Weight % of Feed 14.1 Cloud Point, IC +29 Viscosity, 1001C, cSt 3.364 Sim. Dist., LV%, 'F ST/5 700/722 10/30 732/777 50 808 70/90 829/857 95/EP 871/900 Example 3 The same feed as in Example 2 was hydrocracked over a sulfided 3/1 layered bed of the same catalyst as in Example 2 and then over a Pt/SAPO-1 1 catalyst bound 5 with 15 weight % alumina. Conditions were the same as in Example 2, that is 1.0 hr' overall LHSV, 1000 psig, 685'F, and 6.3 MSCF/Bbl H 2 . Conversion below 650'F was 74.6 weigh %. The product was cut at about 350'F and about 6501F to give a diesel cut. Yields and properties of the diesel cut and 650'F+ bottoms are 19 WO 2005/001006 PCT/US2004/019253 given in Table III. The diesel was high temperature stable by ASTM test D6468. Aromatics in the diesel were less than 0.5 weight %. The cetane index was very high (73.8) and the cloud point very low (-57'C). The 650'F+ stripper bottoms were found to be a 3 cSt (at 1 00C) oil with low pour and cloud points and high VI. 5 Table III Conversion <650'F, Weight % 74.6 Yield, Weight % C1-C 2 0.08 Cr-C4 5.16

C

5 -180 0 F 13.02 180-350*F 15.70 350-650OF 40.97 650 0 F+ 25.59 C5+ 95.36 350-650OF Weight % of Feed 43.1 Gravity, API 51.3 Viscosity, 40'C, cSt 2.206 Cloud Point, C -57 Olefins, Weight % (GC-MS) Not Detected Aromatics, (SFC), Weight % Total <0.5 PNA Not Detected High Temperature Stability, 150'C, % Reflectance, ASTM D6468 1.5 Hr 99.7 3.0 Hr 99.8 Cetane Index 73.8 Refractive Index 1.4318 Density, g/mL 0.7699 Molecular Weight 239 P/N/A Carbon 100/0/0 Sim. Dist., LV%, -F ST/5 314/352 10/30 370/433 20 WO 2005/001006 PCT/US2004/019253 50 496 70/90 549/606 95/EP 629/676 650 0 F+ Weight % of Feed 29.7 Pour Point, 'C -39 Cloud Point, 'C -26 Viscosity, 40'C, cSt 10.69 100'C, cSt 2.849 VI 114 Sim. Dist., LV%, -F ST/5 602/627 10/30 641/690 50 736 70/90 798/837 95/EP 851/880 Example 4 The run of Example 3 was continued, but at a catalyst temperature of 670'F. At this temperature, conversion below 650'F was 40.1 weight %. Yields and 5 properties of the 650'F+ stripper bottoms are given in Table IV. This is found to be a 3.4 cSt (at 100 C) oil of high VI. Table IV Conversion <650'F, Weight % 40.1 Yield, Weight % C1-C2 0.08 Cr-C4 5.69

C

5 -180 0 F 7.36 180-350OF 6.60 350-650OF 20.61 650 0 F+ 60.25 C5+ 94.83 650 0 F+ Weight % of Feed 64.4 Pour Point, C -8 21 WO 2005/001006 PCT/US2004/019253 Cloud Point, 'C 0 Viscosity, 40'C, cSt 13.33 100 0 C, eSt 3.433 VI 138 Sim. Dist., LV%, *F ST/5 587/639 10/30 678/775 50 817 70/90 840/869 95/EP 881/911 Example 5 A 700-1 000'F hydrotreated Fischer-Tropsch Wax (Table V) was hydrocracked over the same layered bed catalyst system of Example 3. Conditions 5 included a 1.0 hr 4 overall LHSV, reactor pressure of 300 psig, 680'F for the top catalyst and 690'F for the bottom catalyst, and 6.3 MSCF/Bbl H 2 . Conversion below 650'F was 58.2 weight %. The product was cut at about 300'F and about 650F to give a diesel cut. Yields and properties of the diesel cut and 650'F+ bottoms are given in Table VI. The diesel was high temperature stable by ASTM 10 test D6468. Aromatics in the diesel were 6.1 weight %. The cetane index was high (67.6) and the cloud point was -44'C. The 650'F+ stripper bottoms were found to be a 5 cSt (at 100 C) oil with low pour and cloud points and very high VI. Table V Description 700-1000'F Hydrotreated Fischer-Tropsch Wax Gravity, API 42.3 Sim. Dist., LV%, -F ST/5 691/804 10/30 824/884 50 919 70/90 940/974 95/EP 991/1031 15 Table VI 22 WO 2005/001006 PCT/US2004/019253 Conversion <650'F, Weight % 58.2 Yield, Weight %

C-C

2 0

C

3

-C

4 4.78

C

5 -180*F 14.93 180-350*F 15.53 350-650*F 23.22 650 0 F+ 41.92 C5+ 95.7 350-650OF Weight % of Feed 31.1 Gravity, API 50.1 Viscosity, 40'C, cSt 2.027 Cloud Point, 'C -44 Olefins, Weight % (GC-MS) Not Detected Aromatics, (SFC), Weight % Total 6.1 PNA 0.5 High Temperature Stability, 150'C, % Reflectance, ASTM D6468 1.5 Hr 99.2 3.0 Hr 99.2 Cetane Index 67.6 Refractive Index 1.4348 Density, g/mL 0.7741 Molecular Weight 196 P/N/A Carbon 92.40/5.01/2.59 Sim. Dist., LV%, -F ST/5 266/300 10/30 325/396 50 472 70/90 561/645 95/EP 667/698 650"F+ Weight % of Feed 41.0 Pour Point, *C -26 Cloud Point, 'C -5 23 WO 2005/001006 PCT/US2004/019253 Viscosity, 40'C, cSt 22.04 100 0 C, cSt 4.882 VI 151 Sim. Dist., LV%, 'F ST/5 681/710 10/30 732/803 50 856 70/90 896/937 95/EP 954/990 Example 6 A full boiling range hydrotreated Fischer-Tropsch Wax (Table VII), from which the feed of Table V was prepared, was hydrocracked over the same layered 5 bed catalyst system of Example 3. Conditions included a 1.0 hr' overall LHSV, reactor pressure of 1000 psig, 680'F for the top catalyst and 691'F for the bottom catalyst, and 6.3 MSCF/Bbl H 2 . Conversion below 650'F was 45.9 weight %. Yields and properties of the 650'F+ stripper bottoms are given in Table VIII. This was found to be a 5.5 eSt (at 100 C) oil with low pour point and very high VI. 10 Table VII Description Full Boiling Range Hydrotreated Fischer-Tropsch Wax Gravity, API 38.2 Nitrogen, ppm 1.9 Sim. Dist., LV%, 'F ST/5 791/856 10/30 876/942 50 995 70/90 1031/1085 95/EP 1107/1133 Table VIII Conversion <650'F, Weight % 45.9 Yield, Weight %

C-C

2 0.06 24 WO 2005/001006 PCT/US2004/019253 Cr-C4 3.99

C

5 -180 0 F 5.76 180-350OF 8.21 350-650OF 27.91 650 0 F+ 54.34 Cs+ 96.44 650 0 F+ Weight % of Feed 52.5 Pour Point, 'C -18 Cloud Point, C +10 Viscosity, 40'C, cSt 26.58 100 0 C, cSt 5.529 VI 152 Sim. Dist., LV%, IF ST/5 666/706 10/30 739/847 50 909 70/90 966/1056 95/EP 1083/1138 Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention. Other objects and advantages will become apparent to those skilled in the 5 art from a review of the preceding description. 25

Claims (32)

1. A process for treating a waxy hydrocarbon feedstock comprising the steps of: a) contacting the feedstock with a hydrocracking catalyst in a hydrocracking zone, producing a hydrocracking effluent; b) contacting the hydrocracking effluent with an intermediate pore size molecular sieve hydroisomerization catalyst in a hydroisomerization zone, producing a hydroisomerization effluent; c) fractionating the hydroisomerization effluent, providing a heavy fraction and a middle distillate fuel; and d) isolating from the heavy fraction a lubricant base oil fraction having a viscosity index of greater than 130, a pour point of less than -15 0 C, and a viscosity of greater than 3 cSt at 1OO 0 C.

2. A process according to claim 1, wherein the lubricant base oil has a viscosity index of greater than 140, a pour point of less than -15"C, and a viscosity of greater than 4 cSt at 100 0 C.

3. A process according to claim 1, wherein the lubricant base oil has a viscosity index of greater than 150, a pour point of less than -15*C, and a viscosity of greater than 5 cSt at 100'C.

4. A process according to claim 1, wherein the total hydrocracking effluent is contacted with the hydroisomerization catalyst in a hydroisomerization zone.

5. A process according to claim 1, wherein the hydrocracking catalyst and the hydroisomerization catalyst are layered in a single reaction zone in a single reactor.

6. A process according to claim 1, wherein the hydrocracking catalyst and the hydroisomerization catalyst are layered in a single reaction zone in close coupled series reactors with no product withdrawal or feed inlet between reactors. 26 WO 2005/001006 PCT/US2004/019253

7. A process according to claim 1, further comprising recycling a heavy bottoms fraction to the hydrocracking zone.

8. A process according to claim 1, wherein the waxy hydrocarbon feedstock comprises a Fischer Tropsch derived 650"F+ feed.

9. A process according to claim 1, wherein the waxy hydrocarbon feedstock comprises greater than 20 weight % 900"F+ components.

10. A process according to claim 1, wherein the waxy hydrocarbon feedstock comprises greater than 85 wt % 650 0 F+ components and wherein less than 60 weight % of the 650*F+ components are converted to 650"F- products.

11. A process for treating a 650"F+ waxy hydrocarbon feedstock comprising the steps of: a) contacting the feedstock with a hydrocracking catalyst in a hydrocracking zone, producing a hydrocracking effluent; b) contacting the hydrocracking effluent with an intermediate pore size molecular sieve hydroisomerization catalyst in a hydroisomerization zone, producing a hydroisomerization effluent; c) fractionating the hydroisomerization effluent, providing a heavy fraction and a middle distillate fuel; and d) isolating a lubricant base oil fraction from the heavy fraction, said lubricant base oil fraction having a viscosity index of greater than 130, a pour point of less than -15"C, and a viscosity of greater than 3 cSt at 100 C, and wherein less than 60 weight % of the 650"F+ components are converted to 650*F- products.

12. A process according to claim 11, wherein the lubricant base oil has a viscosity index of greater than 140, a pour point of less than -15*C, and a viscosity of greater than 4 cSt at 100 C. 27 WO 2005/001006 PCT/US2004/019253

13. A process according to claim 11, wherein the lubricant base oil has a viscosity index of greater than 150, a pour point of less than -15"C, and a viscosity of greater than 5 cSt at 100 0 C.

14. A process according to claim 11, wherein the hydrocracking catalyst and the hydroisomerization catalyst are layered in a single reaction zone in a single reactor.

15. A process according to claim 11, wherein the 650*F+ waxy hydrocarbon feedstock is derived from a Fischer Tropsch process.

16. A process according to claim 15, wherein the 650'F+ waxy hydrocarbon feedstock is not hydrotreated prior to hydrocracking.

17. A process according to claim 11, wherein the 650"F+ waxy hydrocarbon feedstock comprises greater than 20 weight % 900"F+ components.

18. A process according to claim 11, wherein the 650'F+ waxy hydrocarbon feedstock comprises greater than 85 wt % 650*F+ components.

19. A process according to claim 11, wherein the hydrocracking catalyst and the hydroisomerization catalyst are layered in a single reaction zone in close coupled series reactors with no product withdrawal, or feed inlet between reactors.

20. A process according to claim 11 further comprising recycling a heavy bottoms fraction to the hydrocracking zone.

21. A process for treating a 650"F+ waxy hydrocarbon feedstock comprising the steps of: 28 WO 2005/001006 PCT/US2004/019253 a) contacting the feedstock with a hydrocracking catalyst in a hydrocracking zone, producing a hydrocracking effluent; b) contacting the hydrocracking effluent with an intermediate pore size molecular sieve hydroisomerization catalyst in a hydroisomerization zone, producing a hydroisomerization effluent; c) fractionating the hydroisomerization effluent, providing a heavy fraction and a middle distillate fuel; and d) isolating from the heavy fraction a lubricant base oil fraction having a viscosity index of greater than 130, a pour point of less than -15*C, and a viscosity of greater than 4 cSt at 100 C, and wherein the 650"F+ waxy hydrocarbon feedstock comprises greater than 20 weight% 900*F+ components.

22. A process according to claim 21, wherein the 650"F+ waxy hydrocarbon feedstock comprises greater than 40 weight% 900*F+ components.

23. A process according to claim 21, wherein the 650*F+ waxy hydrocarbon feedstock comprises greater than 60 weight% 900'F+ components.

24. A process according to claim 21, wherein the lubricant base oil has a viscosity index of greater than 140, a pour point of less than -15*C, and a viscosity of greater than 4 cSt at 100 C.

25. A process according to claim 21, wherein the lubricant base oil has a viscosity index of greater than 150, a pour point of less than -15*C, and a viscosity of greater than 5 cSt at 100 C.

26. A process according to claim 21, wherein the hydrocracking catalyst and the hydroisomerization catalyst are layered in a single reaction zone in a single reactor. 29 WO 2005/001006 PCT/US2004/019253

27. A process according to claim 21, wherein the 650"F+ waxy hydrocarbon feedstock is derived from a Fischer Tropsch process.

28. A process according to claim 21, wherein the hydrocracking catalyst and the hydroisomerization catalyst are layered in a single reaction zone in close coupled series reactors with no product withdrawal or feed inlet between reactors.

29. A process according to claim 21, further comprising isolating a bottoms fraction from the heavy fraction, and recycling the bottoms fraction to the hydrocracking zone.

30. A process according to claim 23, wherein the lubricant base oil has a viscosity index of greater than 140, a pour point of less than -15"C, and a viscosity of greater than 4 cSt at 100 C.

31. A process according to claim 23, wherein the lubricant base oil has a viscosity index of greater than 150, a pour point of less than -15"C, and a viscosity of greater than 5 cSt at 100C.

32. A process according to claim 21, wherein less than 60 weight % of the 650*F+ components of the 650*F+ waxy hydrocarbon feed are converted to 650*F- products. 30