AU2002214196A1 - Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands - Google Patents

Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands

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Publication number
AU2002214196A1
AU2002214196A1 AU2002214196A AU1419602A AU2002214196A1 AU 2002214196 A1 AU2002214196 A1 AU 2002214196A1 AU 2002214196 A AU2002214196 A AU 2002214196A AU 1419602 A AU1419602 A AU 1419602A AU 2002214196 A1 AU2002214196 A1 AU 2002214196A1
Authority
AU
Australia
Prior art keywords
iminocarbonyl
hydrogenation
carbonyl
compounds
ruthenium catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2002214196A
Inventor
Kamaluddin Abdur-Rashid
Raphael Churlaud
Robert Harold Morris
Valentin Rautenstrauch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Firmenich SA
Original Assignee
Firmenich SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich SA filed Critical Firmenich SA
Publication of AU2002214196A1 publication Critical patent/AU2002214196A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/52—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of imines or imino-ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0255—Ligands comprising the N2S2 or N2P2 donor atom set, e.g. diiminodithiolates or diiminodiphosphines with complete pi-conjugation between all donor centres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AU2002214196A 2000-11-17 2001-11-16 Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands Abandoned AU2002214196A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IB0001693 2000-11-17
WOIB00/01693 2000-11-17
PCT/IB2001/002166 WO2002040155A1 (en) 2000-11-17 2001-11-16 Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands

Publications (1)

Publication Number Publication Date
AU2002214196A1 true AU2002214196A1 (en) 2002-05-27

Family

ID=11004000

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2002214196A Abandoned AU2002214196A1 (en) 2000-11-17 2001-11-16 Process for hydrogenation of carbonyl and iminocarbonyl compounds using ruthenium catalysts comprising tetradentate diimino-diphosphine ligands

Country Status (7)

Country Link
US (1) US6878852B2 (en)
EP (1) EP1337334A1 (en)
JP (1) JP4243481B2 (en)
AU (1) AU2002214196A1 (en)
CA (1) CA2428824C (en)
IL (2) IL155869A0 (en)
WO (1) WO2002040155A1 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5345270B2 (en) * 2000-09-13 2013-11-20 フイルメニツヒ ソシエテ アノニム Catalytic hydrogenation method
ES2432561T3 (en) * 2005-04-05 2013-12-04 Firmenich Sa Hydrogenation of esters with Ru / tetradentate ligand complexes
US7989665B2 (en) * 2005-04-05 2011-08-02 Firmenich Sa Hydrogenation of esters with Ru/tetradentate ligands complexes
WO2006106483A1 (en) * 2005-04-05 2006-10-12 Firmenich Sa Hydrogenation of esters with ru/bidentate ligands complexes
EP1757571A1 (en) * 2005-07-29 2007-02-28 Laboratorios Del Dr. Esteve, S.A. Process for the homogeneous hydrogenation of ketones using ruthenium catalytic systems.
EP1792887A1 (en) * 2005-12-05 2007-06-06 Laboratorios Del Dr. Esteve, S.A. Process for the homogeneous hydrogenation of ketones using ruthenium catalytic systems
WO2007082927A1 (en) * 2006-01-23 2007-07-26 Basf Se Chemical transformation process in the presence of a ruthenium catalyst
US7777083B2 (en) * 2007-05-31 2010-08-17 Kanata Chemical Technologies Inc. Iridium catalysts for catalytic hydrogenation
ITPD20070237A1 (en) * 2007-07-11 2009-01-12 Univ Degli Studi Udine NEW BINDERS OF THE BENZO CLASS [CH]
ATE515502T1 (en) 2007-10-23 2011-07-15 Firmenich & Cie METHOD FOR PRODUCING TETRANORLABAND DERIVATIVES
US7615671B2 (en) 2007-11-30 2009-11-10 Eastman Chemical Company Hydrogenation process for the preparation of 1,2-diols
EP2370207A1 (en) 2008-11-28 2011-10-05 Firmenich S.A. Hydrogenation of ester, ketone or aldehyde groups with ruthenium complexes having a di-amine and a phosphorous-nitrogen bidentate ligand
EP2655303B1 (en) 2010-12-21 2017-02-22 Firmenich SA Hydrogenation of esters or carbonyl groups with tetradentate amino/imino-thioether based ruthenium complexes
US9090534B2 (en) 2011-10-06 2015-07-28 Firemenich Sa Selective hydrogenation of aldehyde with ru/bidentate ligands complexes
BR112015022807A2 (en) 2013-03-15 2017-07-18 Firmenich & Cie selective hydrogenation of aldehydes with ru / bidentate ligand complexes
JP6246202B2 (en) 2013-06-20 2017-12-13 株式会社クラレ Metal complex having tridentate aminodicarbene ligand and hydroreduction method using the same
US11498901B2 (en) * 2018-03-02 2022-11-15 Firmenich Sa Hydrogenation of imines with Ru complexes
CN113797977B (en) * 2020-06-12 2022-11-29 沈阳中化农药化工研发有限公司 Ruthenium catalyst and application thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1047597C (en) * 1997-06-02 1999-12-22 厦门大学 Chiral phosphine aminate-metal coordinate compound, the prepn. method thereof and the application in the asymmetrically catalytic hydrogenation
DE10002975A1 (en) 2000-01-24 2001-07-26 Degussa Use of molecular weight increased catalysts in a process for asymmetric continuous hydrogenation, new molecular weight increased ligands and catalysts

Also Published As

Publication number Publication date
CA2428824A1 (en) 2002-05-23
WO2002040155A1 (en) 2002-05-23
EP1337334A1 (en) 2003-08-27
US6878852B2 (en) 2005-04-12
IL155869A0 (en) 2003-12-23
JP4243481B2 (en) 2009-03-25
CA2428824C (en) 2007-09-11
US20040015017A1 (en) 2004-01-22
IL155869A (en) 2006-10-05
JP2004513929A (en) 2004-05-13

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