AU2001276468A1 - Use of a bitumen/wax composition - Google Patents
Use of a bitumen/wax compositionInfo
- Publication number
- AU2001276468A1 AU2001276468A1 AU2001276468A AU2001276468A AU2001276468A1 AU 2001276468 A1 AU2001276468 A1 AU 2001276468A1 AU 2001276468 A AU2001276468 A AU 2001276468A AU 2001276468 A AU2001276468 A AU 2001276468A AU 2001276468 A1 AU2001276468 A1 AU 2001276468A1
- Authority
- AU
- Australia
- Prior art keywords
- wax
- bitumen
- waxes
- aggregate
- blend
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Description
USE OF A BITUMEN/WAX COMPOSITION
The present invention relates to a bitumen composition, in particular, one containing wax.
It is known to use bituminous compositions as pavings and coverings for a variety of surfaces, for example, roads and air fields. Such compositions comprise mixtures of aggregate and bitumen in specific proportions, and are generally laid and compacted while hot to provide a dense and durable surface.
For many applications, bitumen (known in the US as "asphalt") provides a sufficiently durable and adhesive binder for the aggregate. For high load applications, however, additives may be added to the bitumen in order to improve its mechanical properties. Various additives have been proposed for this purpose, including polymers such as ethylene and vinyl acetate co-polymers, random or block copolymers of styrene and conjugated dienes (eg SBS copolymers). More recently, synthetic waxes comprising blends of synthetic aliphatic hydrocarbons have also been used in bitumen blends (WO 99/11737). Such blends tend to be more resistant to deformation under high loads compared to their corresponding wax-free counterparts.
Fuels, such as diesel and gasoline have a damaging effect on bitumen. These fuels tend to dissolve or soften the bitumen component of bituminous surfaces. Thus, with prolonged use, the aggregate components of such surfaces tend to become less well bound, so the surface tends to disintegrate. Surprisingly, we have now found that waxes can be used to improve the fuel resistance of bitumen.
Accordingly, the present invention provides the use of a wax as a hydrocarbon
resistant, preferably lube oil or fuel resistant additive for a bitumen.
Suitable waxes include petroleum waxes and synthetic waxes, and in particular, ones having a softening point or melting point of above 50°C, preferably, from 60 to 150°C, and more preferably, from 60 to 120°C. Examples of petroleum wax include paraffin wax and microcrystalline wax. Such waxes are well known (see eg 3rd Edition Kirk-Othmer, Encyclopaedia of Chemical Technology, Volume 24, page 473 - 476, which is incorporated herein by reference), and are generally obtained from crude oil and/or crude oil distillates by known techniques. Paraffin waxes are macrocrystalline products, which are usually solid at room temperature (25°C). Microcrystalline waxes also tend to be solids at room temperature. As well as being obtainable from petroleum distillates, however, these waxes can also occur naturally, for example, as ozokerite. Ozokerite wax may be refined and bleached to produce cerasin wax, which is also suitable for use as the fuel resistant additive.
Suitable synthetic waxes include hydrocarbon waxes, for example, polyethylene waxes, and preferably, Fischer Tropsch waxes. Waxes with functional groups, for example, chemically modified hydrocarbon waxes, and waxy esters and amides may also be employed. These synthetic waxes are well-known, and described in detail in the 3rd Edition of Kirk-Othmer, Encyclopaedia of Chemical Technology, Volume 24, pages 477 to 479, which is incorporated herein by reference. Polyethylene waxes particularly suitable for the use of the present invention, include those having molecular weights of less than 10,000, preferably, less than 5,000. Such waxes may be employed on their own, or as mixtures, for example, with one or more of the petroleum waxes mentioned above. Such polyethylene waxes may be manufactured by any conventional technique, for example, by high pressure or low pressure polymerisation, or controlled thermal degradation of high molecular weight polyethylene. In addition to homopolyrners of ethylene, copolymers of ethylene, propylene, butadiene and acrylic acid may also be employed.
Fischer Tropsch waxes are generally prepared by reacting carbon monoxide with hydrogen, typically, at high pressures over a metal catalyst to produce hydrocarbons. The waxes produced may comprise a blend of different compounds, including for example, polymethylene. Such waxes may have melting points between 65 and 105°C, for example, 68 to 105°C. Prefened Fischer Tropsch waxes are described in WO
99/11737, which is incorporated herein by reference. The waxes described in this document comprise more than 90 % n-paraffins. The remainder of the wax typically comprises iso-alkanes. The average carbon chain length of the wax maybe 30 to 105, preferably, 60 to 100, more preferably, 60 to 90, for example, 80. Such waxes maybe partially or fully oxidised. Oxidised waxes may be employed as fuel resistant additives on their own, or as mixtures with, for example, unoxidised Fischer Tropsch waxes. A prefened example of a Fischer Tropsch wax is that sold under the trade mark Sasobit ® (Schumann Sassol). This wax melts at approximately 100°C.
Suitable chemically modified hydrocarbon waxes include chemically modified waxes of the microcrystalline, polyethylene and polymethylene classes. For example, such waxes may be oxidised in air in the presence or absence of a catalyst. Alternatively, such waxes may be reacted with a polycarboxylic acid, such as maleic acid, at, for example, high temperatures. Thus modified, the wax may be further modified, for example, through saponification and/or esterification. Waxy amides may be produced by the amidation of fatty acids. Suitable fatty acids are those having 8 to 24, preferably, 12 to 22 carbon atoms. A prefened example is N,N'-distearoylethylenediamine. This compound has a melting point of approximately 140°C, an acid number of approximately 7, and a low melt viscosity. The waxes described above may be used to improve the fuel resistance of any bitumen. Suitable bitumens include naturally occurring bitumens, and manufactured bitumens and synthetic bitumens. Manufactured bitumens may be produced using a variety of known techniques, for example, by conventional or vacuum distillation of crude oil. Alternatively, the bitumen maybe produced by solvent de-asphalting, or blowing air through, for example, vacuum residues. The latter method involves blowing air through, for example, a topped asphaltic crude or soft grade bitumen. This process may optionally be carried out in the presence of a catalyst, to produce a catalytically oxidised bitumen. Suitable catalysts include ferric oxide and phosphoric acids. Polymer modified bitumens may also be employed. Suitable polymers include ethylene and vinyl acetate co-polymers, random or block copolymers of styrene and conjugated dienes (e.g. SBS copolymers). Blends of different types of bitumens may also be suitable, as may thythetic bitumens. The latter may be lightly coloured to facilitate pigmentation for decorative purposes.
The bitumens employed include those with penetrations in the range of 10 to 450 mm/10, as determined in accordance with EN 1426. The softening point of suitable bitumens may range from 30 to 110°C, preferably, 50 to 100°C, for example, 65 to 75° C, as determined in accordance with EN 1427. The penetration index of suitable 5 bitumens may range between +9 and -1. The viscosity at 60°C may be 10 to 20,000 Pas.
The fuel resistant waxes described above may be added to bitumens in an amount of 0.1 to 20 wt %, preferably, 0.5 to 10 wt %, more preferably, 1 to 7.5 wt %, even more preferably, 2.5 to 6 wt %, for example, 4 to 5 wt % of the resulting wax/bitumen blend.
The wax may be blended with the bitumen using any suitable method. For 10 instance, the wax may be added in divided form (eg as pellets, or as a powder), to the bitumen. The bitumen may be in the molten state, which is at a temperature sufficient to dissolve or disperse the wax. Suitable temperatures range between 120 and 200°C, preferably, 160 and 180°C. Alternatively, the wax may be blended with the bitumen, by a) forming an emulsion of wax and water, b) forming an emulsion of bitumen and water, and c) mixing the emulsions formed in steps a) and b).
The mixtures formed in step c) may then be mixed with aggregate, filler and/or sand. The resulting blend may then be applied to a road surface. 20 It is also possible to mix one or both of the emulsions formed in steps a) and b) with aggregate, filler and/or sand, prior to step c). The resulting blend may then be applied to a road surface.
It may be possible to add sufficient wax to the bitumen to produce a wax/bitumen blend of the desired final concentration. In certain applications, however, it may be 25 desirable to produce a concentrated blend or "masterbatch" of the wax and bitumen, which may be mixed with wax-free bitumens or low wax bitumen blends to produce blends of the desired final composition. Suitably, the masterbatch may comprise the wax in a concentration of 10 to 30 wt %.
The wax/bitumen blends produced as described above may be employed as a 30 binder for bituminous compositions with aggregates. The aggregates employed in such compositions include conventional aggregates such as granite. Optionally, fillers of, for example, limestone and cellulose may also be included in the bituminous composition.
Sand and dust may also be present.
When the wax/bitumen blend is employed as a binder for a bituminous composition with aggregates, the wax/bitumen blend may form 1 to 20 wt %, preferably, 2 to 15 wt %, more preferably, 5 to 10 wt %, and most preferably, 6 to 8 wt % of the overall composition. The aggregate content of the overall composition may be more than 50 wt %, preferably, more than 60 wt %, even more preferably, more than 70 wt %, for example, 75 to 90 wt %. The remainder of the composition may comprise sand, cellulose and/or limestone.
When preparing the overall composition, it may be possible to add the wax to the bitumen, in the presence of the aggregates and/or fillers. It may also be possible to mix the wax with the bitumen prior to the addition of aggregate and/or filler. Bituminous compositions comprising the wax/bitumen blends described above may be used as pavings and coverings for a variety of surfaces, particularly, those surfaces which come into contact with fuel, for example, through spillage. Such surfaces include high-load surfaces such as lorry parks, motorway road surfacing, and air fields. The bituminous composition is also suitable for medium to low-load surfaces, where the traffic of heavy commercial vehicles is low. Examples of such applications include residential roads, service station forecourts, car parks, taxi-ways and driveways. According to a second aspect of the present invention there is provided a residential road, service station forecourt, driveway, car park or taxi way comprising a paving and/or coating comprising a bituminous composition comprising a blend of wax and bitumen.
Preferably, the wax is selected from one of the waxes described above. The wax employed in the present invention may be used to impart fuel resistant properties against any hydrocarbon-containing fuel or lubricant. Examples of such fuels include motor fuels and aviation fuels, such as gasoline, diesel, av gas and jet fuel. Examples Example 1
A bituminous composition was prepared by mixing granite aggregate, a limestone filler, cellulose fibres and a binder, in the proportions below:
The binder used was a bitumen having a penetration of 40 mm/10, modified with 4wt % Sasobit® wax (FRB1)
This composition was then compacted into a cylindrical specimen (100mm (diameter) by 65mm (height)) using a "Gyropac" gyratory compactor Once compacted, the specimen was weighed and immersed in diesel at 20°C. The mass of the specimen was then determined at daily intervals, and the percentage weight loss calculated. The results are given in Table 1. Comparative Example A
Example 1 was repeated using a bitumen having a penetration of 55mm/10 as a binder. As can be seen from the results of Table 1, the weight loss observed with Example 1 is less than that observed with Comparative Example A. Table 1
Example 2
A bituminous composition was prepared by mixing the following components together:
Three different binders were tested: a) A bitumen having a penetration of 40 mm/10 modified with 4 wt % Sasobit® wax
(FRB1); b) An elastomeric bitumen modified with 4 wt % Sasobit® wax resulting in a bitumen composition having a penetration of 41mm/ 10 (FRB2); c) A bitumen having a penetration of 55 mm/10 (50 pen).
The compositions were compacted into a cylindrical specimen (100 mm [diameter] x 65mm[heighfJ) using a "Gyropac" gyratory compactor. The specimens were then weighed and immersed in diesel at 20 °C (+/- 0.5°C). The mass of the specimen was then determined at daily intervals, and the % weight loss calculated. The results are shown in the table below.
Example 3
A bituminous composition was prepared by mixing the following components together:
Four different binders were tested: a) A bitumen having a penetration of 66 mm/10 modified with 4 wt % Sasobit® wax (FRB3; b) An elastomeric bitumen modified with 4 wt % Sasobit® wax resulting in a bitumen
composition having a penetration of 4 lmm/ 10 (FRB4); c) A bitumen having a penetration of 55 mm/10 (50 pen). d) A bitumen having a penetration of 103 mm/ 10 ( 100 pen) .
The compositions were compacted into a cylindrical specimen (101 mm [diameter] x 63.5mm[height]) using a Marshall Hammer compactor. The specimens were then weighed and immersed in jet fuel (ATK) at 20 °C (+/- 0.5°C). The mass of the specimen was then determined at daily intervals, and the % weight loss calculated. The results are shown in the table below.
Claims (12)
1. Use of a wax as a hydrocarbon resistant, preferably fuel resistant additive for a bitumen.
2. Use as claimed in claim 1, where in the wax is a petroleum or synthetic having a softening point of above 50°C.
3. Use as claimed in any preceding claim, wherein the wax is a synthetic polyethylene wax.
4. Use as claimed in claim 3, wherein the wax is a Fischer Tropsch wax.
5. Use as claimed in claim 4, wherein the wax is obtainable by reacting carbon monoxide with hydrogen at high pressures over a metal catalyst.
6. Use as claimed in any preceding claim, wherein the bitumen has a penetration in the range of 10 to 450 mm/10, as determined in accordance with EN 1426.
7. Use as claimed in any preceding claim, wherein the bitumen is a polymer modified bitumen.
8. Use as claimed in any preceding claim, wherein the wax is added to a bitumen in an amount of 0.1 to 20 wt % of the resulting wax/bitumen blend.
9. Use as claimed in any preceding claim, wherein the wax is added to a bitumen to form a binder, which is mixed with aggregate.
10. Use as claimed in claim 8, wherein the wax and bitumen are mixed in the presence of the aggregate, or wherein the wax is mixed with the bitumen prior to the addition of aggregate.
11. Use as claimed in any preceding claim, as a gasoline, diesel, avgas and/or jet fuel resistant additive.
12. A residential road, service station forecourt, driveway, car park or taxi way comprising a paving and/or coating comprising a bituminous composition comprising a blend of wax and bitumen.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0021072.4 | 2000-08-25 | ||
GB0021072A GB0021072D0 (en) | 2000-08-25 | 2000-08-25 | Bitumen composition |
GB0024984A GB0024984D0 (en) | 2000-10-12 | 2000-10-12 | Bitumen composition |
GB0024984.7 | 2000-10-12 | ||
PCT/GB2001/003384 WO2002016499A1 (en) | 2000-08-25 | 2001-07-26 | Use of a bitumen/wax composition |
Publications (2)
Publication Number | Publication Date |
---|---|
AU2001276468A1 true AU2001276468A1 (en) | 2002-05-30 |
AU2001276468B2 AU2001276468B2 (en) | 2006-06-29 |
Family
ID=26244911
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001276468A Ceased AU2001276468B2 (en) | 2000-08-25 | 2001-07-26 | Use of a bitumen/wax composition |
AU7646801A Pending AU7646801A (en) | 2000-08-25 | 2001-07-26 | Use of a bitumen/wax composition |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU7646801A Pending AU7646801A (en) | 2000-08-25 | 2001-07-26 | Use of a bitumen/wax composition |
Country Status (11)
Country | Link |
---|---|
US (2) | US20040102547A1 (en) |
EP (1) | EP1311619B1 (en) |
CN (1) | CN100354375C (en) |
AT (1) | ATE340226T1 (en) |
AU (2) | AU2001276468B2 (en) |
DE (1) | DE60123258T2 (en) |
DK (1) | DK1311619T3 (en) |
ES (1) | ES2271050T3 (en) |
NZ (1) | NZ524360A (en) |
PT (1) | PT1311619E (en) |
WO (1) | WO2002016499A1 (en) |
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US7114843B2 (en) | 2003-07-21 | 2006-10-03 | Htp Est | Method of manufacturing a bituminous coated aggregate mix |
FR2869320B1 (en) * | 2004-04-26 | 2006-07-21 | Total France Sa | BITUMEN COMPOSITION / POLYMER RESISTANT TO CHEMICAL AGRESSIONS AND COATING OBTAINED FROM AN ENROBE COMPRISING THIS COMPOSITION |
CN100457830C (en) * | 2005-01-04 | 2009-02-04 | 同济大学 | High-performance Sasobit and SBR modified emulsified asphalt, and its preparation method and uses |
CN100410328C (en) * | 2005-01-04 | 2008-08-13 | 同济大学 | Hgh-performance emulsified modified asphalt, and its preparation method and uses |
EP1754753A3 (en) * | 2005-08-16 | 2007-05-02 | GRISARD Bauprodukte Holding AG | Low temperature method for pavement with bituminous binder |
CA2628679A1 (en) * | 2005-11-10 | 2007-05-18 | Shell Internationale Research Maatschappij B.V. | Bitumen composition |
KR100770785B1 (en) | 2006-07-27 | 2007-10-26 | 중앙대학교 산학협력단 | Modified asphalt binder for pavement and manufacturing process thereof |
US20080073849A1 (en) * | 2006-09-22 | 2008-03-27 | Quinn Robert E | Asphalt-containing projectable targets |
KR101496145B1 (en) | 2007-05-10 | 2015-02-27 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | Paraffin wax composition |
US7815725B2 (en) | 2007-09-07 | 2010-10-19 | Alm Holding Co. | Warm asphalt binder compositions containing lubricating agents |
EP2062943A1 (en) | 2007-11-14 | 2009-05-27 | Akzo Nobel N.V. | Asphalt modifiers for "warm mix" applications including adhesion promoter |
WO2009105688A1 (en) | 2008-02-22 | 2009-08-27 | Alm Holding Company | Processing bituminous mixtures for paving at reduced temperatures |
CN102177207B (en) | 2008-08-05 | 2015-06-10 | A.L.M.控股公司 | Process for cold-in-place recycling using foamed asphalt and lubrication additive |
US9896582B2 (en) | 2009-03-08 | 2018-02-20 | Lehigh Technologies, Inc. | Micronized asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making |
US20100227954A1 (en) * | 2009-03-08 | 2010-09-09 | Asphalt & Wax Innovations, LLC. | Asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making |
US9884965B2 (en) | 2009-03-08 | 2018-02-06 | Lehigh Tehnologies, Inc. | Functional group asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making |
US20150105495A1 (en) * | 2009-03-08 | 2015-04-16 | Rheopave Technologies, Llc | Polymeric asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making |
US9617424B2 (en) * | 2009-03-08 | 2017-04-11 | Lehigh Technologies, Inc. | Polyolefin asphalt modifiers, methods of modifying asphalt, asphalt compositions and methods of making |
IT1395355B1 (en) * | 2009-07-23 | 2012-09-14 | Eni Spa | PROCEDURE FOR THE PREPARATION OF A BITUMINOUS MIXTURE WITH HIGH WORKABILITY |
FR2952065B1 (en) * | 2009-10-29 | 2012-04-06 | Total Raffinage Marketing | USE OF FATTY ACID DERIVATIVES IN BITUMINOUS COMPOSITIONS TO IMPROVE THEIR RESISTANCE TO CHEMICAL AGRESSIONS AND BITUMINOUS COMPOSITIONS COMPRISING SAID DERIVATIVES |
FR2952066B1 (en) | 2009-10-29 | 2012-01-20 | Total Raffinage Marketing | USE OF WAXES IN A BITUMEN COMPOSITION / RETICULATED POLYMER FOR IMPROVING ITS RESISTANCE TO CHEMICAL AGRESSIONS AND BITUMEN COMPOSITION / RETICULATED POLYMER COMPRISING THE SAID WAXES |
FR2959504B1 (en) | 2010-04-30 | 2012-06-29 | Total Raffinage Marketing | USE OF ORGANOGELERATING MOLECULES IN BITUMINOUS COMPOSITIONS TO IMPROVE THEIR RESISTANCE TO CHEMICAL AGRESSIONS |
EP2386606B1 (en) | 2010-04-30 | 2018-03-21 | Total Marketing Services | Use of organogelator derivatives in bituminous compositions to improve the resistance thereof to chemical attacks |
CN102453335A (en) * | 2010-10-15 | 2012-05-16 | 中国石油化工股份有限公司 | Environment-friendly oil-resistant asphalt pavement material and preparation method thereof |
EP3155171A1 (en) | 2014-06-12 | 2017-04-19 | Akzo Nobel Chemicals International B.V. | Method for producing bituminous coatings with reduced tackiness |
EP3115506A1 (en) | 2015-07-07 | 2017-01-11 | Wachs-Chemie Elsteraue e.K. | Sugar cane wax consisting of long-chain fatty acids, long-chain alcohols and long-chain aliphatic hydrocarbons and their mixtures with other waxes for bitumen modification, which are made of renewable biomass (pressmus, bagasse) derived from sugar cane after the sugar production process |
EP3249017A1 (en) | 2016-05-27 | 2017-11-29 | Sasol Wax GmbH | A bitumen composition comprising a wax mixture consisting of a petroleum slack wax and a fischer-tropsch wax, the use of the wax mixture in bitumen compositions, the use of the bitumen composition in asphalt compositions, asphalt compositions comprising the bitumen composition and the method of producing asphalt pavements thereof |
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FR2528439B1 (en) * | 1982-06-10 | 1985-11-22 | Elf France | PROCESS FOR THE PREPARATION OF BITUMEN-POLYMER COMPOSITIONS, APPLICATION OF SUCH COMPOSITIONS TO THE PRODUCTION OF COATINGS, AND MOTHER POLYMER SOLUTION FOR USE IN OBTAINING THE SAME |
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-
2001
- 2001-07-26 AU AU2001276468A patent/AU2001276468B2/en not_active Ceased
- 2001-07-26 EP EP20010954119 patent/EP1311619B1/en not_active Revoked
- 2001-07-26 DE DE2001623258 patent/DE60123258T2/en not_active Expired - Lifetime
- 2001-07-26 CN CNB018146597A patent/CN100354375C/en not_active Expired - Fee Related
- 2001-07-26 ES ES01954119T patent/ES2271050T3/en not_active Expired - Lifetime
- 2001-07-26 PT PT01954119T patent/PT1311619E/en unknown
- 2001-07-26 AT AT01954119T patent/ATE340226T1/en active
- 2001-07-26 WO PCT/GB2001/003384 patent/WO2002016499A1/en active IP Right Grant
- 2001-07-26 AU AU7646801A patent/AU7646801A/en active Pending
- 2001-07-26 NZ NZ524360A patent/NZ524360A/en not_active IP Right Cessation
- 2001-07-26 US US10/362,818 patent/US20040102547A1/en not_active Abandoned
- 2001-07-26 DK DK01954119T patent/DK1311619T3/en active
-
2005
- 2005-04-20 US US11/110,007 patent/US20050187317A1/en not_active Abandoned
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